#------------------------------------------------------------------------------
#$Date: 2017-05-06 01:18:33 +0300 (Sat, 06 May 2017) $
#$Revision: 196488 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/05/60/7056049.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7056049
loop_
_publ_author_name
'Durini, Sara'
'Ardizzoia, G. Attilio'
'Therrien, Bruno'
'Brenna, Stefano'
_publ_section_title
;
 Tuning the fluorescence emission in mononuclear heteroleptic trigonal
 silver(i) complexes
;
_journal_issue                   8
_journal_name_full               'New J. Chem.'
_journal_page_first              3006
_journal_paper_doi               10.1039/C6NJ04058F
_journal_volume                  41
_journal_year                    2017
_chemical_formula_moiety         'C36 H28 Ag N3 O P, N O3'
_chemical_formula_sum            'C36 H28 Ag N4 O4 P'
_chemical_formula_weight         719.46
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_Hall           '-C 2yc'
_space_group_name_H-M_alt        'C 1 2/c 1'
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   mixed
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2017-02-21 deposited with the CCDC.
2017-03-08 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 108.445(4)
_cell_angle_gamma                90
_cell_formula_units_Z            8
_cell_length_a                   30.9447(16)
_cell_length_b                   9.9074(3)
_cell_length_c                   21.4664(11)
_cell_measurement_reflns_used    8000
_cell_measurement_temperature    203(2)
_cell_measurement_theta_max      28.85
_cell_measurement_theta_min      2.60
_cell_volume                     6243.1(5)
_computing_cell_refinement       'CELL (Stoe IPDS Software, 2000)'
_computing_data_collection       'EXPOSE (Stoe IPDS Software, 2000)'
_computing_data_reduction        'INTEGRATE (Stoe IPDS Software, 2000)'
_computing_molecular_graphics    'ORTEP (Farrugia, 1997)'
_computing_publication_material  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      203(2)
_diffrn_detector_area_resol_mean 0.81\%A
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'STOE IPDS'
_diffrn_measurement_method       'phi oscillation'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0514
_diffrn_reflns_av_unetI/netI     0.0355
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 1.000
_diffrn_reflns_limit_h_max       38
_diffrn_reflns_limit_h_min       -38
_diffrn_reflns_limit_k_max       11
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       26
_diffrn_reflns_limit_l_min       -26
_diffrn_reflns_number            43681
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 1.000
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         25.999
_diffrn_reflns_theta_min         2.000
_diffrn_source                   'fine-focus sealed tube'
_exptl_absorpt_coefficient_mu    0.744
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.531
_exptl_crystal_description       block
_exptl_crystal_F_000             2928
_exptl_crystal_size_max          0.21
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.17
_refine_diff_density_max         0.461
_refine_diff_density_min         -0.329
_refine_diff_density_rms         0.049
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.928
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     436
_refine_ls_number_reflns         6130
_refine_ls_number_restraints     25
_refine_ls_restrained_S_all      0.939
_refine_ls_R_factor_all          0.0411
_refine_ls_R_factor_gt           0.0260
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0298P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0509
_refine_ls_wR_factor_ref         0.0533
_reflns_Friedel_coverage         0.000
_reflns_number_gt                4828
_reflns_number_total             6130
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c6nj04058f2.cif
_cod_data_source_block           complex1
_cod_depositor_comments
'Adding full bibliography for 7056048--7056051.cif.'
_cod_database_code               7056049
_shelx_shelxl_version_number     2014/7
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C -0.04421(7) 0.5579(2) 0.10526(11) 0.0340(5) Uani 1 1 d . . . . .
H1 H -0.0361 0.6036 0.1451 0.041 Uiso 1 1 calc R U . . .
C2 C -0.08519(7) 0.5904(3) 0.05874(12) 0.0390(5) Uani 1 1 d . . . . .
H2 H -0.1041 0.6565 0.0669 0.047 Uiso 1 1 calc R U . . .
C3 C -0.09725(7) 0.5218(3) -0.00013(12) 0.0412(6) Uani 1 1 d . . . . .
H3 H -0.1246 0.5408 -0.0326 0.049 Uiso 1 1 calc R U . . .
C4 C -0.06824(7) 0.4245(3) -0.01028(11) 0.0354(5) Uani 1 1 d . . . . .
H4 H -0.0761 0.3774 -0.0498 0.043 Uiso 1 1 calc R U . . .
C5 C -0.02717(6) 0.3968(2) 0.03860(10) 0.0256(4) Uani 1 1 d . . . . .
C6 C 0.00578(6) 0.2958(2) 0.03252(9) 0.0232(4) Uani 1 1 d . . . . .
C7 C 0.00527(6) 0.2076(2) -0.01815(9) 0.0248(4) Uani 1 1 d . . . . .
C8 C -0.02448(7) 0.1733(2) -0.08178(10) 0.0316(5) Uani 1 1 d . . . . .
H8 H -0.0513 0.2217 -0.1001 0.038 Uiso 1 1 calc R U . . .
C9 C -0.01360(8) 0.0703(3) -0.11537(10) 0.0365(5) Uani 1 1 d . . . . .
H9 H -0.0332 0.0479 -0.1567 0.044 Uiso 1 1 calc R U . . .
C10 C 0.02724(8) -0.0041(2) -0.08865(10) 0.0347(5) Uani 1 1 d . . . . .
H10 H 0.0339 -0.0756 -0.1122 0.042 Uiso 1 1 calc R U . . .
C11 C 0.05655(7) 0.0283(2) -0.02920(10) 0.0298(5) Uani 1 1 d . . . . .
H11 H 0.0834 -0.0203 -0.0117 0.036 Uiso 1 1 calc R U . . .
C12 C 0.06945(6) 0.1811(2) 0.06738(9) 0.0235(4) Uani 1 1 d . . . . .
C13 C 0.11373(7) 0.1312(2) 0.10890(10) 0.0260(4) Uani 1 1 d . . . . .
C14 C 0.12010(7) 0.1032(2) 0.17528(10) 0.0294(5) Uani 1 1 d . . . . .
H14 H 0.0958 0.1128 0.1916 0.035 Uiso 1 1 calc R U . . .
C15 C 0.16192(8) 0.0614(2) 0.21690(11) 0.0389(6) Uani 1 1 d . . . . .
H15 H 0.1655 0.0422 0.2607 0.047 Uiso 1 1 calc R U . . .
C16 C 0.19833(8) 0.0482(3) 0.19313(12) 0.0429(6) Uani 1 1 d . . . . .
H16 H 0.2264 0.0198 0.2211 0.052 Uiso 1 1 calc R U . . .
C17 C 0.19340(7) 0.0767(3) 0.12841(12) 0.0381(5) Uani 1 1 d . . . . .
H17 H 0.2181 0.0672 0.1129 0.046 Uiso 1 1 calc R U . . .
C18 C 0.15147(7) 0.1198(2) 0.08617(10) 0.0294(5) Uani 1 1 d . . . . .
C19 C 0.16473(7) 0.5322(2) 0.20770(10) 0.0296(5) Uani 1 1 d . . . . .
C20 C 0.18507(7) 0.4198(3) 0.18935(11) 0.0353(5) Uani 1 1 d . . . . .
H20 H 0.1790 0.3341 0.2022 0.042 Uiso 1 1 calc R U . . .
C21 C 0.21419(8) 0.4346(3) 0.15218(12) 0.0416(6) Uani 1 1 d . . . . .
H21 H 0.2277 0.3590 0.1406 0.050 Uiso 1 1 calc R U . . .
C22 C 0.22308(9) 0.5602(3) 0.13239(13) 0.0501(7) Uani 1 1 d . . . . .
H22 H 0.2424 0.5699 0.1072 0.060 Uiso 1 1 calc R U . . .
C23 C 0.20308(10) 0.6725(3) 0.15004(15) 0.0567(8) Uani 1 1 d . . . . .
H23 H 0.2091 0.7578 0.1367 0.068 Uiso 1 1 calc R U . . .
C24 C 0.17411(9) 0.6588(3) 0.18756(13) 0.0450(6) Uani 1 1 d . . . . .
H24 H 0.1609 0.7350 0.1992 0.054 Uiso 1 1 calc R U . . .
C25 C 0.14600(7) 0.4024(2) 0.31972(10) 0.0284(4) Uani 1 1 d . . . . .
C26 C 0.19238(8) 0.3957(3) 0.35256(13) 0.0501(7) Uani 1 1 d . . . . .
H26 H 0.2129 0.4379 0.3353 0.060 Uiso 1 1 calc R U . . .
C27 C 0.20792(10) 0.3255(4) 0.41143(14) 0.0671(9) Uani 1 1 d . . . . .
H27 H 0.2390 0.3207 0.4335 0.081 Uiso 1 1 calc R U . . .
C28 C 0.17779(10) 0.2629(3) 0.43750(13) 0.0557(7) Uani 1 1 d . . . . .
H28 H 0.1885 0.2174 0.4773 0.067 Uiso 1 1 calc R U . . .
C29 C 0.13211(9) 0.2682(3) 0.40450(12) 0.0422(6) Uani 1 1 d . . . . .
H29 H 0.1117 0.2253 0.4218 0.051 Uiso 1 1 calc R U . . .
C30 C 0.11610(7) 0.3368(2) 0.34559(11) 0.0334(5) Uani 1 1 d . . . . .
H30 H 0.0850 0.3390 0.3232 0.040 Uiso 1 1 calc R U . . .
C31 C 0.11653(7) 0.6708(2) 0.28290(10) 0.0282(4) Uani 1 1 d . . . . .
C32 C 0.15365(8) 0.7290(3) 0.33078(11) 0.0381(5) Uani 1 1 d . . . . .
H32 H 0.1813 0.6832 0.3452 0.046 Uiso 1 1 calc R U . . .
C33 C 0.14945(10) 0.8538(3) 0.35670(13) 0.0476(7) Uani 1 1 d . . . . .
H33 H 0.1743 0.8921 0.3884 0.057 Uiso 1 1 calc R U . . .
C34 C 0.10867(10) 0.9217(3) 0.33582(13) 0.0515(7) Uani 1 1 d . . . . .
H34 H 0.1061 1.0060 0.3533 0.062 Uiso 1 1 calc R U . . .
C35 C 0.07160(10) 0.8659(3) 0.28924(13) 0.0466(6) Uani 1 1 d . . . . .
H35 H 0.0441 0.9123 0.2756 0.056 Uiso 1 1 calc R U . . .
C36 C 0.07535(8) 0.7401(2) 0.26252(11) 0.0351(5) Uani 1 1 d . . . . .
H36 H 0.0503 0.7024 0.2310 0.042 Uiso 1 1 calc R U . . .
Ag Ag 0.05455(2) 0.41371(2) 0.17335(2) 0.02821(5) Uani 1 1 d . . . . .
N1 N -0.01553(6) 0.46462(18) 0.09626(8) 0.0276(4) Uani 1 1 d . . . . .
N2 N 0.04521(5) 0.27615(17) 0.08393(8) 0.0233(3) Uani 1 1 d . . . . .
N3 N 0.04623(5) 0.13441(17) 0.00521(8) 0.0236(4) Uani 1 1 d . . . . .
N4 N 0.0000 0.2418(3) 0.2500 0.0285(6) Uani 1 2 d S T P . .
O1 O 0.14584(5) 0.15403(18) 0.02271(7) 0.0372(4) Uani 1 1 d . . . . .
H1A H 0.1706 0.1740 0.0189 0.056 Uiso 1 1 calc R U . . .
O2 O 0.02396(6) 0.1823(2) 0.22215(9) 0.0570(5) Uani 1 1 d . . . . .
O3 O 0.0000 0.3679(2) 0.2500 0.0415(6) Uani 1 2 d S T P . .
P P 0.12088(2) 0.50703(6) 0.24702(3) 0.02591(12) Uani 1 1 d . . . . .
N5 N 0.24756(19) 0.2986(6) -0.0040(2) 0.0523(11) Uani 0.5 1 d D U P A -1
O4 O 0.2553(3) 0.1975(9) -0.0263(5) 0.144(3) Uani 0.5 1 d D U P A -1
O5 O 0.27383(13) 0.3907(5) -0.0008(2) 0.0726(12) Uani 0.5 1 d D U P A -1
O6 O 0.21320(19) 0.3101(6) 0.0130(3) 0.105(2) Uani 0.5 1 d D U P A -1
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
N1 C1 C2 123.8(2) .
N1 C1 H1 118.1 .
C2 C1 H1 118.1 .
C3 C2 C1 117.9(2) .
C3 C2 H2 121.0 .
C1 C2 H2 121.0 .
C2 C3 C4 119.2(2) .
C2 C3 H3 120.4 .
C4 C3 H3 120.4 .
C3 C4 C5 120.1(2) .
C3 C4 H4 119.9 .
C5 C4 H4 119.9 .
N1 C5 C4 120.4(2) .
N1 C5 C6 115.44(17) .
C4 C5 C6 124.20(19) .
N2 C6 C7 109.01(17) .
N2 C6 C5 119.45(17) .
C7 C6 C5 131.53(18) .
C6 C7 N3 105.01(16) .
C6 C7 C8 138.0(2) .
N3 C7 C8 117.01(19) .
C9 C8 C7 119.8(2) .
C9 C8 H8 120.1 .
C7 C8 H8 120.1 .
C8 C9 C10 121.14(19) .
C8 C9 H9 119.4 .
C10 C9 H9 119.4 .
C11 C10 C9 120.3(2) .
C11 C10 H10 119.8 .
C9 C10 H10 119.8 .
C10 C11 N3 119.2(2) .
C10 C11 H11 120.4 .
N3 C11 H11 120.4 .
N2 C12 N3 109.46(16) .
N2 C12 C13 125.37(17) .
N3 C12 C13 125.17(18) .
C14 C13 C18 118.13(18) .
C14 C13 C12 119.27(18) .
C18 C13 C12 122.43(18) .
C15 C14 C13 121.2(2) .
C15 C14 H14 119.4 .
C13 C14 H14 119.4 .
C16 C15 C14 119.7(2) .
C16 C15 H15 120.2 .
C14 C15 H15 120.2 .
C17 C16 C15 120.7(2) .
C17 C16 H16 119.7 .
C15 C16 H16 119.7 .
C16 C17 C18 120.1(2) .
C16 C17 H17 119.9 .
C18 C17 H17 119.9 .
O1 C18 C17 121.70(19) .
O1 C18 C13 118.05(18) .
C17 C18 C13 120.2(2) .
C24 C19 C20 118.4(2) .
C24 C19 P 121.78(17) .
C20 C19 P 119.21(17) .
C21 C20 C19 120.7(2) .
C21 C20 H20 119.6 .
C19 C20 H20 119.6 .
C22 C21 C20 120.3(2) .
C22 C21 H21 119.8 .
C20 C21 H21 119.8 .
C21 C22 C23 119.6(2) .
C21 C22 H22 120.2 .
C23 C22 H22 120.2 .
C22 C23 C24 120.5(3) .
C22 C23 H23 119.8 .
C24 C23 H23 119.8 .
C19 C24 C23 120.4(2) .
C19 C24 H24 119.8 .
C23 C24 H24 119.8 .
C30 C25 C26 119.3(2) .
C30 C25 P 116.82(15) .
C26 C25 P 123.59(18) .
C25 C26 C27 119.5(2) .
C25 C26 H26 120.3 .
C27 C26 H26 120.3 .
C28 C27 C26 120.7(2) .
C28 C27 H27 119.6 .
C26 C27 H27 119.6 .
C29 C28 C27 119.6(2) .
C29 C28 H28 120.2 .
C27 C28 H28 120.2 .
C28 C29 C30 120.4(2) .
C28 C29 H29 119.8 .
C30 C29 H29 119.8 .
C29 C30 C25 120.5(2) .
C29 C30 H30 119.8 .
C25 C30 H30 119.8 .
C36 C31 C32 119.0(2) .
C36 C31 P 119.34(16) .
C32 C31 P 121.62(17) .
C33 C32 C31 120.3(2) .
C33 C32 H32 119.8 .
C31 C32 H32 119.8 .
C34 C33 C32 120.1(2) .
C34 C33 H33 120.0 .
C32 C33 H33 120.0 .
C33 C34 C35 120.6(2) .
C33 C34 H34 119.7 .
C35 C34 H34 119.7 .
C34 C35 C36 120.0(2) .
C34 C35 H35 120.0 .
C36 C35 H35 120.0 .
C31 C36 C35 120.0(2) .
C31 C36 H36 120.0 .
C35 C36 H36 120.0 .
N2 Ag N1 72.06(6) .
N2 Ag P 130.44(4) .
N1 Ag P 144.31(5) .
C1 N1 C5 118.60(18) .
C1 N1 Ag 123.95(14) .
C5 N1 Ag 117.44(13) .
C12 N2 C6 108.69(16) .
C12 N2 Ag 135.72(13) .
C6 N2 Ag 115.56(13) .
C11 N3 C12 129.47(18) .
C11 N3 C7 122.47(17) .
C12 N3 C7 107.83(16) .
O2 N4 O2 123.1(3) 2
O2 N4 O3 118.44(15) 2
O2 N4 O3 118.44(15) .
C18 O1 H1A 109.5 .
C31 P C19 103.81(10) .
C31 P C25 102.28(10) .
C19 P C25 107.10(10) .
C31 P Ag 118.06(7) .
C19 P Ag 111.17(7) .
C25 P Ag 113.35(7) .
O4 N5 O5 116.7(6) .
O4 N5 O6 120.7(6) .
O5 N5 O6 122.6(6) .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C1 N1 1.337(3) .
C1 C2 1.381(3) .
C1 H1 0.9300 .
C2 C3 1.379(4) .
C2 H2 0.9300 .
C3 C4 1.381(3) .
C3 H3 0.9300 .
C4 C5 1.395(3) .
C4 H4 0.9300 .
C5 N1 1.353(3) .
C5 C6 1.463(3) .
C6 N2 1.376(2) .
C6 C7 1.392(3) .
C7 N3 1.408(3) .
C7 C8 1.426(3) .
C8 C9 1.352(3) .
C8 H8 0.9300 .
C9 C10 1.418(3) .
C9 H9 0.9300 .
C10 C11 1.350(3) .
C10 H10 0.9300 .
C11 N3 1.379(3) .
C11 H11 0.9300 .
C12 N2 1.321(3) .
C12 N3 1.380(2) .
C12 C13 1.464(3) .
C13 C14 1.403(3) .
C13 C18 1.405(3) .
C14 C15 1.383(3) .
C14 H14 0.9300 .
C15 C16 1.382(3) .
C15 H15 0.9300 .
C16 C17 1.378(3) .
C16 H16 0.9300 .
C17 C18 1.394(3) .
C17 H17 0.9300 .
C18 O1 1.361(3) .
C19 C24 1.387(3) .
C19 C20 1.396(3) .
C19 P 1.828(2) .
C20 C21 1.387(3) .
C20 H20 0.9300 .
C21 C22 1.371(4) .
C21 H21 0.9300 .
C22 C23 1.383(4) .
C22 H22 0.9300 .
C23 C24 1.389(3) .
C23 H23 0.9300 .
C24 H24 0.9300 .
C25 C30 1.383(3) .
C25 C26 1.386(3) .
C25 P 1.829(2) .
C26 C27 1.388(4) .
C26 H26 0.9300 .
C27 C28 1.378(4) .
C27 H27 0.9300 .
C28 C29 1.367(4) .
C28 H28 0.9300 .
C29 C30 1.382(3) .
C29 H29 0.9300 .
C30 H30 0.9300 .
C31 C36 1.390(3) .
C31 C32 1.400(3) .
C31 P 1.820(2) .
C32 C33 1.379(4) .
C32 H32 0.9300 .
C33 C34 1.374(4) .
C33 H33 0.9300 .
C34 C35 1.377(4) .
C34 H34 0.9300 .
C35 C36 1.393(3) .
C35 H35 0.9300 .
C36 H36 0.9300 .
Ag N2 2.2965(16) .
Ag N1 2.3291(17) .
Ag P 2.3483(5) .
N4 O2 1.239(2) 2
N4 O2 1.239(2) .
N4 O3 1.249(3) .
O1 H1A 0.8200 .
N5 O4 1.168(7) .
N5 O5 1.210(7) .
N5 O6 1.234(7) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
N1 C1 C2 C3 0.5(3)
C1 C2 C3 C4 -0.1(3)
C2 C3 C4 C5 -0.2(4)
C3 C4 C5 N1 0.2(3)
C3 C4 C5 C6 -180.0(2)
N1 C5 C6 N2 0.1(3)
C4 C5 C6 N2 -179.73(19)
N1 C5 C6 C7 179.3(2)
C4 C5 C6 C7 -0.6(3)
N2 C6 C7 N3 -0.1(2)
C5 C6 C7 N3 -179.31(19)
N2 C6 C7 C8 177.9(2)
C5 C6 C7 C8 -1.3(4)
C6 C7 C8 C9 -174.9(2)
N3 C7 C8 C9 2.9(3)
C7 C8 C9 C10 -0.5(3)
C8 C9 C10 C11 -1.1(3)
C9 C10 C11 N3 0.1(3)
N2 C12 C13 C14 44.7(3)
N3 C12 C13 C14 -134.2(2)
N2 C12 C13 C18 -130.3(2)
N3 C12 C13 C18 50.8(3)
C18 C13 C14 C15 -1.9(3)
C12 C13 C14 C15 -177.2(2)
C13 C14 C15 C16 0.7(3)
C14 C15 C16 C17 0.2(4)
C15 C16 C17 C18 0.2(4)
C16 C17 C18 O1 177.3(2)
C16 C17 C18 C13 -1.6(4)
C14 C13 C18 O1 -176.52(19)
C12 C13 C18 O1 -1.4(3)
C14 C13 C18 C17 2.4(3)
C12 C13 C18 C17 177.5(2)
C24 C19 C20 C21 0.4(3)
P C19 C20 C21 171.87(17)
C19 C20 C21 C22 -0.6(4)
C20 C21 C22 C23 0.4(4)
C21 C22 C23 C24 0.0(4)
C20 C19 C24 C23 0.0(4)
P C19 C24 C23 -171.3(2)
C22 C23 C24 C19 -0.2(4)
C30 C25 C26 C27 -1.2(4)
P C25 C26 C27 172.8(2)
C25 C26 C27 C28 -0.1(5)
C26 C27 C28 C29 1.1(5)
C27 C28 C29 C30 -0.6(4)
C28 C29 C30 C25 -0.8(4)
C26 C25 C30 C29 1.7(3)
P C25 C30 C29 -172.75(18)
C36 C31 C32 C33 -0.7(3)
P C31 C32 C33 179.47(19)
C31 C32 C33 C34 0.3(4)
C32 C33 C34 C35 0.3(4)
C33 C34 C35 C36 -0.5(4)
C32 C31 C36 C35 0.6(3)
P C31 C36 C35 -179.59(17)
C34 C35 C36 C31 0.0(4)
C2 C1 N1 C5 -0.5(3)
C2 C1 N1 Ag 178.18(17)
C4 C5 N1 C1 0.2(3)
C6 C5 N1 C1 -179.68(18)
C4 C5 N1 Ag -178.59(15)
C6 C5 N1 Ag 1.5(2)
N3 C12 N2 C6 -1.0(2)
C13 C12 N2 C6 179.97(18)
N3 C12 N2 Ag -178.75(13)
C13 C12 N2 Ag 2.2(3)
C7 C6 N2 C12 0.7(2)
C5 C6 N2 C12 -179.98(17)
C7 C6 N2 Ag 178.95(12)
C5 C6 N2 Ag -1.7(2)
C10 C11 N3 C12 176.3(2)
C10 C11 N3 C7 2.5(3)
N2 C12 N3 C11 -173.56(18)
C13 C12 N3 C11 5.4(3)
N2 C12 N3 C7 0.9(2)
C13 C12 N3 C7 179.96(18)
C6 C7 N3 C11 174.49(17)
C8 C7 N3 C11 -4.0(3)
C6 C7 N3 C12 -0.5(2)
C8 C7 N3 C12 -178.99(17)
C36 C31 P C19 119.02(18)
C32 C31 P C19 -61.2(2)
C36 C31 P C25 -129.67(18)
C32 C31 P C25 50.2(2)
C36 C31 P Ag -4.5(2)
C32 C31 P Ag 175.31(15)
C24 C19 P C31 -24.8(2)
C20 C19 P C31 164.05(17)
C24 C19 P C25 -132.5(2)
C20 C19 P C25 56.31(19)
C24 C19 P Ag 103.14(19)
C20 C19 P Ag -68.02(18)
C30 C25 P C31 90.30(18)
C26 C25 P C31 -83.9(2)
C30 C25 P C19 -160.88(17)
C26 C25 P C19 24.9(2)
C30 C25 P Ag -37.89(19)
C26 C25 P Ag 147.9(2)
