#------------------------------------------------------------------------------
#$Date: 2025-08-04 10:03:09 +0300 (Mon, 04 Aug 2025) $
#$Revision: 301442 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/05/65/7056594.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7056594
loop_
_publ_author_name
'Cao, Yue'
'Lv, Jinghua'
'Yu, Kai'
'Wang, Chunmei'
'Su, Zhanhua'
'Wang, Lu'
'Zhou, Baibin'
_publ_section_title
;
 Synthesis and photo-/electro-catalytic properties of Keggin
 polyoxometalate inorganic-organic hybrid layers based on d10 metal and
 rigid benzo-diazole/-triazole ligands
;
_journal_issue                   21
_journal_name_full               'New J. Chem.'
_journal_page_first              12459
_journal_page_last               12469
_journal_paper_doi               10.1039/C7NJ02615C
_journal_volume                  41
_journal_year                    2017
_chemical_formula_moiety         'C36 H26 Ag7 As N18 O40 W12'
_chemical_formula_sum            'C36 H26 Ag7 As N18 O40 W12'
_chemical_formula_weight         4386.84
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_audit_update_record
;
2016-02-18 deposited with the CCDC.
2017-09-12 downloaded from the CCDC.
;
_cell_angle_alpha                95.9940(10)
_cell_angle_beta                 111.0330(10)
_cell_angle_gamma                106.860(2)
_cell_formula_units_Z            1
_cell_length_a                   11.6544(8)
_cell_length_b                   12.8654(9)
_cell_length_c                   13.5532(9)
_cell_measurement_reflns_used    14695
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      28.28
_cell_measurement_theta_min      1.66
_cell_volume                     1765.1(2)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device_type  'Bruker Smart APEX CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0301
_diffrn_reflns_av_sigmaI/netI    0.0463
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            14695
_diffrn_reflns_theta_full        28.28
_diffrn_reflns_theta_max         28.28
_diffrn_reflns_theta_min         1.66
_exptl_absorpt_coefficient_mu    21.915
_exptl_absorpt_correction_T_max  0.0529
_exptl_absorpt_correction_T_min  0.0353
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    4.127
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1938
_exptl_crystal_size_max          0.21
_exptl_crystal_size_mid          0.19
_exptl_crystal_size_min          0.15
_refine_diff_density_max         2.347
_refine_diff_density_min         -1.923
_refine_diff_density_rms         0.278
_refine_ls_extinction_coef       0.00109(10)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.073
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     536
_refine_ls_number_reflns         8726
_refine_ls_number_restraints     34
_refine_ls_restrained_S_all      1.081
_refine_ls_R_factor_all          0.0803
_refine_ls_R_factor_gt           0.0741
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0374P)²+41.5594P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1050
_refine_ls_wR_factor_ref         0.1174
_reflns_number_gt                7726
_reflns_number_total             8726
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c7nj02615c2.cif
_cod_data_source_block           zhn20140605_1227_0m
_cod_database_code               7056594
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
W1 W 0.67502(8) -0.07695(7) 0.79809(7) 0.0177(2) Uani 1 1 d .
W3 W 1.25577(8) 0.22772(7) 0.99501(7) 0.0179(2) Uani 1 1 d .
W6 W 0.92212(9) -0.13629(8) 0.73101(7) 0.0243(2) Uani 1 1 d .
W4 W 0.99843(9) 0.27644(7) 1.05444(8) 0.0236(2) Uani 1 1 d U
W2 W 0.93383(9) 0.14377(7) 0.78673(7) 0.0189(2) Uani 1 1 d .
W5 W 0.74946(9) 0.04884(9) 1.07072(8) 0.0242(2) Uani 1 1 d U
Ag1 Ag 0.21892(19) 0.47153(19) 0.50334(18) 0.0373(5) Uani 1 1 d .
Ag3 Ag 0.0000 0.0000 0.5000 0.0455(8) Uani 1 2 d S
Ag2 Ag -0.2697(3) 0.10337(19) 0.3541(2) 0.0465(6) Uani 1 1 d .
Ag4 Ag 0.0686(3) 0.2728(2) 0.5803(2) 0.0476(6) Uani 1 1 d .
C1 C -0.598(4) -0.286(3) 0.139(3) 0.057(9) Uani 1 1 d .
H12 H -0.6862 -0.3014 0.0964 0.068 Uiso 1 1 calc R
O3 O 1.1688(19) 0.2994(18) 1.0554(16) 0.040(3) Uani 1 1 d U
O6 O 1.1176(19) 0.2046(18) 0.8565(17) 0.040(2) Uani 1 1 d U
O8 O 0.9317(19) 0.2419(18) 0.9013(16) 0.040(2) Uani 1 1 d U
O16 O 0.761(2) 0.0548(17) 0.7678(18) 0.041(2) Uani 1 1 d U
O22 O 0.670(2) 0.0073(16) 0.9159(16) 0.038(3) Uani 1 1 d U
O21 O 0.836(2) 0.1882(19) 1.0494(18) 0.045(3) Uani 1 1 d U
O4 O 0.8831(19) -0.2001(16) 0.6026(15) 0.036(4) Uani 1 1 d U
O5 O 0.635(2) 0.0728(18) 1.1062(17) 0.037(4) Uani 1 1 d U
O13 O 0.904(2) 0.210(2) 0.6850(17) 0.041(4) Uani 1 1 d U
O20 O 1.002(2) 0.4059(16) 1.0821(18) 0.041(4) Uani 1 1 d U
O15 O 1.375(2) 0.3359(19) 0.9949(18) 0.050(5) Uani 1 1 d U
O7 O 0.5218(19) -0.1148(17) 0.7042(18) 0.042(4) Uani 1 1 d U
O11 O 0.7552(19) -0.1509(17) 0.7262(18) 0.040(3) Uani 1 1 d U
O9 O 0.9437(19) 0.0145(17) 0.7178(18) 0.042(3) Uani 1 1 d U
O12 O 1.339(2) 0.1988(17) 1.1319(16) 0.040(3) Uani 1 1 d U
N2 N -0.176(2) 0.2799(18) 0.3790(18) 0.028(4) Uani 1 1 d .
N9 N -0.050(2) 0.3255(17) 0.4482(17) 0.027(4) Uani 1 1 d .
N1 N 0.012(2) 0.4164(17) 0.4226(17) 0.026(4) Uani 1 1 d .
C2 C -0.076(2) 0.4308(18) 0.3348(19) 0.021(4) Uani 1 1 d .
C3 C -0.196(2) 0.3439(18) 0.304(2) 0.023(4) Uani 1 1 d .
C4 C -0.308(2) 0.334(2) 0.213(2) 0.030(5) Uani 1 1 d .
H4 H -0.3867 0.2752 0.1916 0.036 Uiso 1 1 calc R
N3 N -0.290(2) -0.067(2) 0.331(2) 0.040(6) Uani 1 1 d .
N8 N -0.185(2) -0.097(2) 0.376(2) 0.033(5) Uani 1 1 d .
C5 C -0.389(3) -0.161(2) 0.263(2) 0.032(6) Uani 1 1 d .
N6 N -0.213(2) -0.2051(19) 0.3399(18) 0.030(5) Uani 1 1 d .
C6 C -0.067(3) 0.515(2) 0.275(2) 0.027(5) Uani 1 1 d .
H14 H 0.0122 0.5733 0.2943 0.033 Uiso 1 1 calc R
C7 C -0.177(3) 0.506(2) 0.188(2) 0.034(6) Uani 1 1 d .
H3 H -0.1737 0.5614 0.1489 0.041 Uiso 1 1 calc R
C8 C -0.422(3) -0.357(2) 0.206(2) 0.032(6) Uani 1 1 d .
H10 H -0.3916 -0.4167 0.2087 0.038 Uiso 1 1 calc R
C9 C -0.340(3) -0.248(2) 0.268(2) 0.032(5) Uani 1 1 d .
C10 C -0.296(3) 0.416(2) 0.157(2) 0.034(6) Uani 1 1 d .
H6 H -0.3681 0.4116 0.0957 0.041 Uiso 1 1 calc R
O14 O 0.718(2) -0.1029(18) 1.0693(16) 0.042(3) Uani 1 1 d U
O10 O 1.108(2) -0.0855(19) 0.7931(19) 0.048(3) Uani 1 1 d U
C11 C -0.550(3) -0.371(3) 0.143(3) 0.048(8) Uani 1 1 d .
H11 H -0.6062 -0.4423 0.1006 0.057 Uiso 1 1 calc R
C12 C -0.521(4) -0.180(3) 0.196(3) 0.057(9) Uani 1 1 d .
H13 H -0.5536 -0.1221 0.1916 0.069 Uiso 1 1 calc R
O17 O 0.9217(19) -0.254(2) 0.8017(19) 0.048(3) Uani 1 1 d U
As1 As 1.0000 0.0000 1.0000 0.0222(5) Uani 1 2 d S
O18 O 0.916(3) -0.007(3) 0.879(3) 0.030(2) Uani 0.50 1 d PU
O2 O 1.148(3) 0.049(3) 1.026(3) 0.027(3) Uani 0.50 1 d PU
O19 O 1.034(3) 0.111(3) 0.969(3) 0.030(2) Uani 0.50 1 d PU
O1 O 0.966(3) 0.084(3) 1.071(3) 0.028(2) Uani 0.50 1 d PU
N4 N 0.416(2) 0.4992(18) 0.5993(17) 0.026(4) Uani 1 1 d .
C13 C 0.488(2) 0.431(2) 0.5925(19) 0.024(5) Uani 1 1 d .
N7 N 0.502(3) 0.595(2) 0.670(2) 0.047(6) Uani 1 1 d .
C14 C 0.620(2) 0.492(2) 0.662(2) 0.027(5) Uani 1 1 d .
C15 C 0.451(3) 0.324(2) 0.537(2) 0.033(6) Uani 1 1 d .
H5 H 0.3630 0.2825 0.4937 0.040 Uiso 1 1 calc R
C16 C 0.719(3) 0.446(2) 0.677(2) 0.036(6) Uani 1 1 d .
H8 H 0.8059 0.4851 0.7246 0.044 Uiso 1 1 calc R
C17 C 0.678(3) 0.337(3) 0.616(3) 0.047(8) Uani 1 1 d .
H7 H 0.7393 0.3029 0.6224 0.056 Uiso 1 1 calc R
C18 C 0.547(3) 0.279(3) 0.547(3) 0.048(7) Uani 1 1 d .
H9 H 0.5236 0.2082 0.5057 0.058 Uiso 1 1 calc R
N5 N 0.623(2) 0.5916(19) 0.7088(18) 0.031(5) Uani 1 1 d .
H1 H 0.6922 0.6443 0.7559 0.038 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
W W -0.8490 6.8722 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
As As 0.0499 2.0058 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O7 W1 O22 102.6(10) . .
O7 W1 O16 102.4(10) . .
O22 W1 O16 89.7(9) . .
O7 W1 O12 101.0(10) . 2_757
O22 W1 O12 88.1(8) . 2_757
O16 W1 O12 156.3(10) . 2_757
O7 W1 O11 102.6(10) . .
O22 W1 O11 154.6(9) . .
O16 W1 O11 87.5(8) . .
O12 W1 O11 84.6(9) 2_757 .
O7 W1 O2 158.3(11) . 2_757
O22 W1 O2 64.2(9) . 2_757
O16 W1 O2 95.0(10) . 2_757
O12 W1 O2 63.0(10) 2_757 2_757
O11 W1 O2 90.9(10) . 2_757
O7 W1 O18 159.3(11) . .
O22 W1 O18 92.2(10) . .
O16 W1 O18 62.8(10) . .
O12 W1 O18 93.8(10) 2_757 .
O11 W1 O18 64.2(10) . .
O2 W1 O18 42.4(11) 2_757 .
O15 W3 O3 101.4(11) . .
O15 W3 O12 101.1(11) . .
O3 W3 O12 89.0(9) . .
O15 W3 O14 103.3(12) . 2_757
O3 W3 O14 155.2(10) . 2_757
O12 W3 O14 87.8(8) . 2_757
O15 W3 O6 102.2(11) . .
O3 W3 O6 87.4(8) . .
O12 W3 O6 156.6(10) . .
O14 W3 O6 85.9(8) 2_757 .
O15 W3 O2 159.4(12) . .
O3 W3 O2 92.1(10) . .
O12 W3 O2 63.3(10) . .
O14 W3 O2 64.5(10) 2_757 .
O6 W3 O2 93.7(10) . .
O15 W3 O19 159.0(12) . .
O3 W3 O19 64.3(10) . .
O12 W3 O19 94.2(11) . .
O14 W3 O19 91.4(11) 2_757 .
O6 W3 O19 63.5(10) . .
O2 W3 O19 41.5(11) . .
O4 W6 O11 101.0(9) . .
O4 W6 O17 102.1(11) . .
O11 W6 O17 89.2(9) . .
O4 W6 O10 102.8(10) . .
O11 W6 O10 156.1(11) . .
O17 W6 O10 88.7(9) . .
O4 W6 O9 101.0(10) . .
O11 W6 O9 87.5(9) . .
O17 W6 O9 156.9(11) . .
O10 W6 O9 85.2(9) . .
O4 W6 O1 158.2(10) . 2_757
O11 W6 O1 95.4(10) . 2_757
O17 W6 O1 63.6(11) . 2_757
O10 W6 O1 62.5(10) . 2_757
O9 W6 O1 93.9(10) . 2_757
O4 W6 O18 156.7(10) . .
O11 W6 O18 63.8(10) . .
O17 W6 O18 95.4(11) . .
O10 W6 O18 92.7(11) . .
O9 W6 O18 62.7(10) . .
O1 W6 O18 45.0(11) 2_757 .
O20 W4 O21 104.0(11) . .
O20 W4 O8 102.2(10) . .
O21 W4 O8 91.0(9) . .
O20 W4 O3 102.2(10) . .
O21 W4 O3 153.5(10) . .
O8 W4 O3 87.3(8) . .
O20 W4 O17 101.5(11) . 2_757
O21 W4 O17 87.5(9) . 2_757
O8 W4 O17 155.9(10) . 2_757
O3 W4 O17 83.5(9) . 2_757
O20 W4 O1 157.7(11) . .
O21 W4 O1 61.5(10) . .
O8 W4 O1 95.3(10) . .
O3 W4 O1 92.3(10) . .
O17 W4 O1 63.1(11) 2_757 .
O13 W2 O9 100.8(11) . .
O13 W2 O6 101.5(10) . .
O9 W2 O6 90.2(9) . .
O13 W2 O8 102.5(11) . .
O9 W2 O8 156.7(10) . .
O6 W2 O8 87.0(8) . .
O13 W2 O16 102.7(10) . .
O9 W2 O16 87.6(8) . .
O6 W2 O16 155.7(10) . .
O8 W2 O16 85.6(9) . .
O13 W2 O18 159.1(12) . .
O9 W2 O18 65.0(10) . .
O6 W2 O18 94.1(11) . .
O8 W2 O18 92.1(11) . .
O16 W2 O18 63.1(10) . .
O13 W2 O19 160.2(12) . .
O9 W2 O19 92.8(11) . .
O6 W2 O19 63.7(10) . .
O8 W2 O19 65.2(10) . .
O16 W2 O19 92.2(10) . .
O18 W2 O19 40.8(12) . .
O5 W5 O14 102.9(10) . .
O5 W5 O10 101.7(11) . 2_757
O14 W5 O10 89.0(10) . 2_757
O5 W5 O21 103.2(11) . .
O14 W5 O21 153.8(11) . .
O10 W5 O21 87.4(9) 2_757 .
O5 W5 O22 104.8(10) . .
O14 W5 O22 87.9(8) . .
O10 W5 O22 153.3(10) 2_757 .
O21 W5 O22 83.7(9) . .
O5 W5 O1 157.2(11) . .
O14 W5 O1 93.9(11) . .
O10 W5 O1 62.8(11) 2_757 .
O21 W5 O1 61.6(11) . .
O22 W5 O1 90.9(10) . .
N4 Ag1 N1 168.2(8) . .
N4 Ag1 Ag4 102.5(6) . .
N1 Ag1 Ag4 65.7(6) . .
N8 Ag3 N8 179.999(2) 2_556 .
N8 Ag3 Ag4 61.2(6) 2_556 .
N8 Ag3 Ag4 118.8(6) . .
N8 Ag3 Ag4 118.8(6) 2_556 2_556
N8 Ag3 Ag4 61.2(6) . 2_556
Ag4 Ag3 Ag4 180.0 . 2_556
N3 Ag2 N2 157.8(9) . .
N6 Ag4 N9 156.1(8) 2_556 .
N6 Ag4 Ag1 104.2(6) 2_556 .
N9 Ag4 Ag1 63.6(6) . .
N6 Ag4 Ag3 62.1(7) 2_556 .
N9 Ag4 Ag3 108.0(6) . .
Ag1 Ag4 Ag3 128.68(9) . .
C12 C1 C11 122(4) . .
W3 O3 W4 140.6(12) . .
W2 O6 W3 139.8(13) . .
W4 O8 W2 139.2(12) . .
W1 O16 W2 139.7(13) . .
W1 O22 W5 141.5(11) . .
W4 O21 W5 142.1(14) . .
W6 O11 W1 139.5(12) . .
W2 O9 W6 139.2(12) . .
W3 O12 W1 138.9(12) . 2_757
N9 N2 C3 106.9(19) . .
N9 N2 Ag2 117.3(15) . .
C3 N2 Ag2 127.8(17) . .
N2 N9 N1 111.5(19) . .
N2 N9 Ag4 132.1(16) . .
N1 N9 Ag4 116.2(16) . .
C2 N1 N9 107(2) . .
C2 N1 Ag1 137.1(17) . .
N9 N1 Ag1 114.0(15) . .
N1 C2 C3 108(2) . .
N1 C2 C6 132(2) . .
C3 C2 C6 120(2) . .
N2 C3 C4 132(2) . .
N2 C3 C2 106(2) . .
C4 C3 C2 122(2) . .
C10 C4 C3 117(2) . .
N8 N3 C5 106(2) . .
N8 N3 Ag2 120.1(19) . .
C5 N3 Ag2 132.8(18) . .
N6 N8 N3 111(2) . .
N6 N8 Ag3 120.2(17) . .
N3 N8 Ag3 128.4(19) . .
N3 C5 C9 108(2) . .
N3 C5 C12 131(3) . .
C9 C5 C12 121(3) . .
N8 N6 C9 108(2) . .
N8 N6 Ag4 116.5(17) . 2_556
C9 N6 Ag4 135.1(19) . 2_556
C7 C6 C2 118(2) . .
C6 C7 C10 121(2) . .
C11 C8 C9 116(3) . .
N6 C9 C5 107(3) . .
N6 C9 C8 132(2) . .
C5 C9 C8 121(3) . .
C4 C10 C7 122(2) . .
W5 O14 W3 140.5(13) . 2_757
W5 O10 W6 140.3(14) 2_757 .
C8 C11 C1 123(3) . .
C1 C12 C5 117(3) . .
W6 O17 W4 138.9(14) . 2_757
O19 As1 O19 179.998(8) . 2_757
O19 As1 O2 111.0(17) . 2_757
O19 As1 O2 69.0(17) 2_757 2_757
O19 As1 O2 69.0(17) . .
O19 As1 O2 111.0(17) 2_757 .
O2 As1 O2 180.000(9) 2_757 .
O19 As1 O18 67.3(18) . .
O19 As1 O18 112.7(18) 2_757 .
O2 As1 O18 69.6(17) 2_757 .
O2 As1 O18 110.4(17) . .
O19 As1 O18 112.7(18) . 2_757
O19 As1 O18 67.3(18) 2_757 2_757
O2 As1 O18 110.4(17) 2_757 2_757
O2 As1 O18 69.6(17) . 2_757
O18 As1 O18 179.998(14) . 2_757
O19 As1 O1 107.8(17) . 2_757
O19 As1 O1 72.2(17) 2_757 2_757
O2 As1 O1 108.5(17) 2_757 2_757
O2 As1 O1 71.5(17) . 2_757
O18 As1 O1 73.7(17) . 2_757
O18 As1 O1 106.3(17) 2_757 2_757
O19 As1 O1 72.2(17) . .
O19 As1 O1 107.8(17) 2_757 .
O2 As1 O1 71.5(17) 2_757 .
O2 As1 O1 108.5(17) . .
O18 As1 O1 106.3(17) . .
O18 As1 O1 73.7(17) 2_757 .
O1 As1 O1 179.999(15) 2_757 .
As1 O18 O19 55.2(16) . .
As1 O18 O2 55.0(15) . 2_757
O19 O18 O2 93(2) . 2_757
As1 O18 W2 126.4(19) . .
O19 O18 W2 71.2(16) . .
O2 O18 W2 137(2) 2_757 .
As1 O18 W1 123.3(17) . .
O19 O18 W1 134(2) . .
O2 O18 W1 68.2(15) 2_757 .
W2 O18 W1 93.7(11) . .
As1 O18 W6 120.0(17) . .
O19 O18 W6 131(2) . .
O2 O18 W6 125(2) 2_757 .
W2 O18 W6 92.6(11) . .
W1 O18 W6 92.0(12) . .
As1 O2 O19 54.6(15) . .
As1 O2 O18 55.4(15) . 2_757
O19 O2 O18 94(2) . 2_757
As1 O2 W3 124.7(17) . .
O19 O2 W3 70.1(15) . .
O18 O2 W3 135(2) 2_757 .
As1 O2 W1 124.8(16) . 2_757
O19 O2 W1 137(2) . 2_757
O18 O2 W1 69.4(15) 2_757 2_757
W3 O2 W1 94.0(11) . 2_757
As1 O19 O18 57.5(16) . .
As1 O19 O2 56.4(15) . .
O18 O19 O2 96(2) . .
As1 O19 W3 124.8(18) . .
O18 O19 W3 135(2) . .
O2 O19 W3 68.4(15) . .
As1 O19 W2 125.5(19) . .
O18 O19 W2 68.1(16) . .
O2 O19 W2 134(2) . .
W3 O19 W2 92.3(11) . .
As1 O1 W4 122.4(17) . .
As1 O1 W6 121.1(16) . 2_757
W4 O1 W6 93.8(11) . 2_757
As1 O1 W5 123.8(18) . .
W4 O1 W5 94.2(11) . .
W6 O1 W5 93.7(11) 2_757 .
N7 N4 C13 107(2) . .
N7 N4 Ag1 124.6(17) . .
C13 N4 Ag1 128.1(16) . .
C15 C13 N4 132(2) . .
C15 C13 C14 121(2) . .
N4 C13 C14 107(2) . .
N5 N7 N4 111(2) . .
N5 C14 C13 106(2) . .
N5 C14 C16 132(2) . .
C13 C14 C16 122(2) . .
C13 C15 C18 118(3) . .
C17 C16 C14 115(2) . .
C18 C17 C16 121(3) . .
C15 C18 C17 122(3) . .
N7 N5 C14 109(2) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
W1 O7 1.667(19) .
W1 O22 1.864(19) .
W1 O16 1.87(2) .
W1 O12 1.91(2) 2_757
W1 O11 1.924(19) .
W1 O2 2.44(3) 2_757
W1 O18 2.46(3) .
W3 O15 1.658(18) .
W3 O3 1.878(19) .
W3 O12 1.893(19) .
W3 O14 1.90(2) 2_757
W3 O6 1.91(2) .
W3 O2 2.43(3) .
W3 O19 2.46(3) .
W6 O4 1.681(17) .
W6 O11 1.876(19) .
W6 O17 1.88(2) .
W6 O10 1.89(2) .
W6 O9 1.92(2) .
W6 O1 2.44(3) 2_757
W6 O18 2.50(3) .
W4 O20 1.655(18) .
W4 O21 1.88(2) .
W4 O8 1.89(2) .
W4 O3 1.916(19) .
W4 O17 1.93(2) 2_757
W4 O1 2.44(3) .
W2 O13 1.682(19) .
W2 O9 1.88(2) .
W2 O6 1.87(2) .
W2 O8 1.908(19) .
W2 O16 1.92(2) .
W2 O18 2.42(3) .
W2 O19 2.47(3) .
W5 O5 1.666(17) .
W5 O14 1.88(2) .
W5 O10 1.89(2) 2_757
W5 O21 1.89(2) .
W5 O22 1.905(19) .
W5 O1 2.43(3) .
Ag1 N4 2.10(2) .
Ag1 N1 2.11(2) .
Ag1 Ag4 3.156(3) .
Ag3 N8 2.10(3) 2_556
Ag3 N8 2.10(3) .
Ag3 Ag4 3.330(3) .
Ag3 Ag4 3.331(3) 2_556
Ag2 N3 2.12(2) .
Ag2 N2 2.14(2) .
Ag4 N6 2.12(2) 2_556
Ag4 N9 2.15(2) .
C1 C12 1.36(5) .
C1 C11 1.37(5) .
O12 W1 1.91(2) 2_757
N2 N9 1.33(3) .
N2 C3 1.37(3) .
N9 N1 1.34(3) .
N1 C2 1.34(3) .
C2 C3 1.40(3) .
C2 C6 1.42(3) .
C3 C4 1.40(3) .
C4 C10 1.36(4) .
N3 N8 1.35(3) .
N3 C5 1.35(4) .
N8 N6 1.32(3) .
C5 C9 1.39(3) .
C5 C12 1.41(5) .
N6 C9 1.35(4) .
N6 Ag4 2.12(2) 2_556
C6 C7 1.36(4) .
C7 C10 1.41(4) .
C8 C11 1.37(4) .
C8 C9 1.41(4) .
O14 W3 1.90(2) 2_757
O10 W5 1.89(2) 2_757
O17 W4 1.93(2) 2_757
As1 O19 1.51(3) .
As1 O19 1.51(3) 2_757
As1 O2 1.55(3) 2_757
As1 O2 1.55(3) .
As1 O18 1.55(3) .
As1 O18 1.55(3) 2_757
As1 O1 1.60(3) 2_757
As1 O1 1.60(3) .
O18 O19 1.70(5) .
O18 O2 1.77(4) 2_757
O2 O19 1.73(4) .
O2 O18 1.77(4) 2_757
O2 W1 2.44(3) 2_757
O1 W6 2.44(3) 2_757
N4 N7 1.34(3) .
N4 C13 1.40(3) .
C13 C15 1.36(4) .
C13 C14 1.40(3) .
N7 N5 1.34(3) .
C14 N5 1.36(3) .
C14 C16 1.40(4) .
C15 C18 1.37(4) .
C16 C17 1.40(4) .
C17 C18 1.39(5) .
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
N5 H1 O11 0.86 2.65 3.17(3) 119.8 1_565
N5 H1 O12 0.86 2.59 3.09(3) 118.4 2_767
N5 H1 O17 0.86 2.43 3.16(3) 142.9 1_565
N5 H1 O3 0.86 2.37 3.10(3) 142.9 2_767
