#------------------------------------------------------------------------------
#$Date: 2019-11-17 13:53:16 +0200 (Sun, 17 Nov 2019) $
#$Revision: 230299 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/05/68/7056812.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7056812
loop_
_publ_author_name
'Chen, Sihuai'
'Mereacre, Valeriu'
'Zhao, Zhiying'
'Zhang, Wanwan'
'He, Zhangzhen'
_publ_section_title
;
 Synthesis, structures and magnetic properties of linear {CoII2LnIII2}
 coordination clusters
;
_journal_issue                   2
_journal_name_full               'New Journal of Chemistry'
_journal_page_first              1284
_journal_paper_doi               10.1039/C7NJ04022A
_journal_volume                  42
_journal_year                    2018
_chemical_formula_moiety         'C66 H64 Co2 Dy2 N2 O20'
_chemical_formula_sum            'C66 H64 Co2 Dy2 N2 O20'
_chemical_formula_weight         1648.05
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     direct
_audit_creation_date             2017-08-10
_audit_creation_method
;
Olex2 1.2
(compiled 2017.07.20 svn.r3457 for OlexSys, GUI svn.r5370)
;
_audit_update_record
;
2017-12-13 deposited with the CCDC.
2017-12-13 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 113.435(2)
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   12.513(2)
_cell_length_b                   23.560(4)
_cell_length_c                   12.192(2)
_cell_measurement_reflns_used    10577
_cell_measurement_temperature    293.1500
_cell_measurement_theta_max      27.4971
_cell_measurement_theta_min      2.0154
_cell_volume                     3297.8(9)
_computing_cell_refinement       'CrystalClear (Rigaku Inc., 2008)'
_computing_data_collection       'CrystalClear (Rigaku Inc., 2008)'
_computing_data_reduction        'CrystalClear (Rigaku Inc., 2008)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution
;
????
;
_diffrn_ambient_temperature      293.1500
_diffrn_detector_area_resol_mean 28.5714
_diffrn_measured_fraction_theta_full 0.991
_diffrn_measured_fraction_theta_max 0.991
_diffrn_measurement_details
;
scan:
    Number of images: 360
               Slice: -118.0000 - 62.0000
         Image width: 0.5000
            Exp time: 8.0000
       Rotation axis: Omega
               Omega: 0.0000
                 Chi: 45.0000
                 Phi: 180.0000
                 XTD: 50.1411
              2theta: -27.5896
scan:
    Number of images: 280
               Slice: -118.0000 - 22.0000
         Image width: 0.5000
            Exp time: 8.0000
       Rotation axis: Omega
               Omega: 0.0000
                 Chi: 45.0000
                 Phi: 90.0000
                 XTD: 50.1411
              2theta: -27.5896
scan:
    Number of images: 160
               Slice: -118.0000 - -38.0000
         Image width: 0.5000
            Exp time: 8.0000
       Rotation axis: Omega
               Omega: 0.0000
                 Chi: 45.0000
                 Phi: 0.0000
                 XTD: 50.1411
              2theta: -27.5896
;
_diffrn_measurement_device
;
Saturn724+ (2x2 bin mode)
;
_diffrn_measurement_device_details
;
AFC10: Fixed Chi 2 circle
;
_diffrn_measurement_device_type
;
Saturn724+ (2x2 bin mode)
;
_diffrn_measurement_method       CCD_Profile_fitting
_diffrn_orient_matrix_type       d*Trek
_diffrn_orient_matrix_UB_11      0.0498
_diffrn_orient_matrix_UB_12      0.0081
_diffrn_orient_matrix_UB_13      -0.0738
_diffrn_orient_matrix_UB_21      0.0351
_diffrn_orient_matrix_UB_22      -0.0064
_diffrn_orient_matrix_UB_23      0.0230
_diffrn_orient_matrix_UB_31      0.0132
_diffrn_orient_matrix_UB_32      -0.0755
_diffrn_orient_matrix_UB_33      -0.0413
_diffrn_radiation_detector       CCD
_diffrn_radiation_monochromator  Confocal
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0207
_diffrn_reflns_av_unetI/netI     0.0198
_diffrn_reflns_Laue_measured_fraction_full 0.991
_diffrn_reflns_Laue_measured_fraction_max 0.991
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       28
_diffrn_reflns_limit_k_min       -29
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_number            23401
_diffrn_reflns_point_group_measured_fraction_full 0.991
_diffrn_reflns_point_group_measured_fraction_max 0.991
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         26.372
_diffrn_reflns_theta_min         2.511
_diffrn_source                   'Sealed Tube'
_diffrn_source_current           16.0000
_diffrn_source_power             0.8000
_diffrn_source_voltage           50.0000
_exptl_absorpt_coefficient_mu    2.808
_exptl_absorpt_correction_T_max  1.0000
_exptl_absorpt_correction_T_min  0.8151
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
    Higashi, T. (1995). Program for Absorption Correction.
    Rigaku Corporation, Tokyo, Japan.
;
_exptl_crystal_colour            Pink
_exptl_crystal_density_diffrn    1.660
_exptl_crystal_description       Prism
_exptl_crystal_F_000             1640
_exptl_crystal_size_max          0.15
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.10
_refine_diff_density_max         1.901
_refine_diff_density_min         -0.748
_refine_diff_density_rms         0.093
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.083
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     420
_refine_ls_number_reflns         6676
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.083
_refine_ls_R_factor_all          0.0278
_refine_ls_R_factor_gt           0.0261
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0431P)²+2.8400P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0739
_refine_ls_wR_factor_ref         0.0748
_reflns_Friedel_coverage         0.000
_reflns_number_gt                6219
_reflns_number_total             6676
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c7nj04022a2.cif
_cod_data_source_block           Co2Dy2
_cod_depositor_comments
;
The following automatic conversions were performed:

'_exptl_absorpt_correction_type' value 'Multi-scan' changed to
'multi-scan' according to
/home/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 4973 2017-02-22 13:04:09Z antanas 

 Adding full bibliography for 7056812--7056814.cif.
;
_cod_database_code               7056812
_shelx_shelxl_version_number     2014/7
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_diffrn_number_total             7681
_olex2_refinement_description
;
1. Others
 Fixed Uiso: H3(0.054) H4(0.075) H5(0.078) H6(0.072) H7(0.056) H10(0.051)
 H11(0.07) H12(0.078) H13(0.076) H14(0.056) H16(0.056) H18(0.055) H19(0.065)
 H20(0.064) H21(0.069) H24(0.059) H25(0.089) H26(0.097) H27(0.085) H28(0.059)
 H29A(0.061) H29B(0.061) H30A(0.043) H30B(0.043) H31A(0.062) H31B(0.062)
 H32A(0.049) H32B(0.049) H33A(0.097) H33B(0.097) H33C(0.097)
 Fixed X: H3(0.7186) H4(0.8708) H5(1.0417) H6(1.0594) H7(0.9059) H10(0.6311)
 H11(0.6959) H12(0.7461) H13(0.7333) H14(0.6701) H16(0.4317) H18(0.4206)
 H19(0.3279) H20(0.2958) H21(0.3493) H24(0.824) H25(0.955) H26(1.0942)
 H27(1.1036) H28(0.9715) H29A(0.7771) H29B(0.7878) H30A(0.6031) H30B(0.5835)
 H31A(0.82) H31B(0.6885) H32A(0.6952) H32B(0.7897) H33A(0.9172) H33B(0.9476)
 H33C(0.9317)
 Fixed Y: H3(-0.1121) H4(-0.1647) H5(-0.1729) H6(-0.1303) H7(-0.0777)
 H10(0.113) H11(0.1929) H12(0.2727) H13(0.2721) H14(0.1918) H16(0.2)
 H18(0.1885) H19(0.2751) H20(0.3263) H21(0.289) H24(0.1153) H25(0.1719)
 H26(0.2215) H27(0.217) H28(0.1616) H29A(-0.1057) H29B(-0.0566) H30A(-0.0913)
 H30B(-0.0886) H31A(-0.0727) H31B(-0.0778) H32A(-0.0205) H32B(0.019)
 H33A(0.0065) H33B(-0.0503) H33C(0.0058)
 Fixed Z: H3(0.4112) H4(0.4045) H5(0.571) H6(0.7492) H7(0.7567) H10(0.2527)
 H11(0.1898) H12(0.309) H13(0.4909) H14(0.5569) H16(0.6562) H18(0.9788)
 H19(0.9485) H20(0.7772) H21(0.6322) H24(0.708) H25(0.6685) H26(0.8189)
 H27(1.011) H28(1.0531) H29A(0.9892) H29B(0.9072) H30A(0.816) H30B(0.9352)
 H31A(1.2131) H31B(1.1251) H32A(1.283) H32B(1.2672) H33A(1.0392) H33B(1.112)
 H33C(1.173)
;
_olex2_submission_special_instructions 'No special instructions were received'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
Dy1 Dy 0.55810(2) 0.02748(2) 0.67290(2) 0.02495(6) Uani 1 1 d .
Co1 Co 0.65881(3) 0.04349(2) 0.98568(3) 0.02839(9) Uani 1 1 d .
O1 O 0.7107(2) -0.03198(10) 0.6856(2) 0.0457(6) Uani 1 1 d .
O2 O 0.6110(2) -0.04505(11) 0.4938(2) 0.0454(6) Uani 1 1 d .
O3 O 0.6190(2) 0.08696(10) 0.55969(19) 0.0415(5) Uani 1 1 d .
O4 O 0.4526(2) -0.05579(10) 0.62868(19) 0.0413(5) Uani 1 1 d .
O5 O 0.5408(2) 0.10852(9) 0.93988(19) 0.0386(5) Uani 1 1 d .
O6 O 0.4819(2) 0.10078(10) 0.7429(2) 0.0430(6) Uani 1 1 d .
O7 O 0.7966(2) 0.09847(10) 1.0121(2) 0.0438(5) Uani 1 1 d .
O8 O 0.7212(2) 0.07022(11) 0.8260(2) 0.0467(6) Uani 1 1 d .
O9 O 0.6315(2) 0.02823(9) 1.13736(19) 0.0350(5) Uani 1 1 d .
O10 O 0.57306(18) -0.01370(9) 0.85857(17) 0.0283(4) Uani 1 1 d .
N1 N 0.7815(2) -0.02762(11) 1.0614(2) 0.0337(6) Uani 1 1 d .
C1 C 0.6997(3) -0.05339(13) 0.5872(3) 0.0337(6) Uani 1 1 d .
C2 C 0.7967(3) -0.08888(13) 0.5832(3) 0.0338(6) Uani 1 1 d .
C3 C 0.7871(3) -0.11541(16) 0.4793(3) 0.0450(8) Uani 1 1 d .
H3 H 0.7186 -0.1121 0.4112 0.054 Uiso 1 1 calc R
C4 C 0.8783(4) -0.14687(19) 0.4753(4) 0.0624(11) Uani 1 1 d .
H4 H 0.8708 -0.1647 0.4045 0.075 Uiso 1 1 calc R
C5 C 0.9800(4) -0.15212(19) 0.5747(4) 0.0649(12) Uani 1 1 d .
H5 H 1.0417 -0.1729 0.5710 0.078 Uiso 1 1 calc R
C6 C 0.9909(3) -0.1264(2) 0.6812(4) 0.0596(11) Uani 1 1 d .
H6 H 1.0594 -0.1303 0.7492 0.072 Uiso 1 1 calc R
C7 C 0.8992(3) -0.09489(17) 0.6856(3) 0.0470(8) Uani 1 1 d .
H7 H 0.9059 -0.0777 0.7567 0.056 Uiso 1 1 calc R
C8 C 0.6001(3) 0.09165(13) 0.4506(3) 0.0326(6) Uani 1 1 d .
C9 C 0.6441(3) 0.14407(13) 0.4116(3) 0.0328(6) Uani 1 1 d .
C10 C 0.6520(3) 0.14500(15) 0.3014(3) 0.0424(8) Uani 1 1 d .
H10 H 0.6311 0.1130 0.2527 0.051 Uiso 1 1 calc R
C11 C 0.6903(4) 0.19270(18) 0.2636(4) 0.0583(10) Uani 1 1 d .
H11 H 0.6959 0.1929 0.1898 0.070 Uiso 1 1 calc R
C12 C 0.7205(4) 0.24027(18) 0.3348(4) 0.0648(12) Uani 1 1 d .
H12 H 0.7461 0.2727 0.3090 0.078 Uiso 1 1 calc R
C13 C 0.7128(4) 0.23983(17) 0.4430(4) 0.0630(12) Uani 1 1 d .
H13 H 0.7333 0.2721 0.4909 0.076 Uiso 1 1 calc R
C14 C 0.6748(3) 0.19182(15) 0.4827(3) 0.0469(8) Uani 1 1 d .
H14 H 0.6701 0.1918 0.5569 0.056 Uiso 1 1 calc R
C15 C 0.4912(3) 0.12730(13) 0.8360(3) 0.0310(6) Uani 1 1 d .
C16 C 0.4127(4) 0.21538(15) 0.7163(3) 0.0468(9) Uani 1 1 d .
H16 H 0.4317 0.2000 0.6562 0.056 Uiso 1 1 calc R
C17 C 0.4353(3) 0.18478(14) 0.8203(2) 0.0310(6) Uani 1 1 d .
C18 C 0.4047(3) 0.20811(15) 0.9078(3) 0.0462(8) Uani 1 1 d .
H18 H 0.4206 0.1885 0.9788 0.055 Uiso 1 1 calc R
C19 C 0.3508(4) 0.26036(16) 0.8905(4) 0.0543(10) Uani 1 1 d .
H19 H 0.3279 0.2751 0.9485 0.065 Uiso 1 1 calc R
C20 C 0.3306(4) 0.29074(16) 0.7878(4) 0.0535(10) Uani 1 1 d .
H20 H 0.2958 0.3263 0.7772 0.064 Uiso 1 1 calc R
C21 C 0.3621(4) 0.26839(16) 0.7013(4) 0.0575(11) Uani 1 1 d .
H21 H 0.3493 0.2890 0.6322 0.069 Uiso 1 1 calc R
C22 C 0.7956(3) 0.09904(13) 0.9084(3) 0.0334(6) Uani 1 1 d .
C23 C 0.8834(3) 0.13323(13) 0.8838(3) 0.0348(7) Uani 1 1 d .
C24 C 0.8795(3) 0.13598(17) 0.7692(4) 0.0495(9) Uani 1 1 d .
H24 H 0.8240 0.1153 0.7080 0.059 Uiso 1 1 calc R
C25 C 0.9583(4) 0.1695(2) 0.7460(5) 0.0738(14) Uani 1 1 d .
H25 H 0.9550 0.1719 0.6685 0.089 Uiso 1 1 calc R
C26 C 1.0411(4) 0.1992(2) 0.8356(6) 0.0812(16) Uani 1 1 d .
H26 H 1.0942 0.2215 0.8189 0.097 Uiso 1 1 calc R
C27 C 1.0468(4) 0.19657(19) 0.9503(5) 0.0705(13) Uani 1 1 d .
H27 H 1.1036 0.2170 1.0110 0.085 Uiso 1 1 calc R
C28 C 0.9680(3) 0.16356(15) 0.9756(4) 0.0489(9) Uani 1 1 d .
H28 H 0.9715 0.1616 1.0531 0.059 Uiso 1 1 calc R
C29 C 0.7497(3) -0.06801(17) 0.9591(3) 0.0506(9) Uani 1 1 d .
H29A H 0.7771 -0.1057 0.9892 0.061 Uiso 1 1 calc R
H29B H 0.7878 -0.0566 0.9072 0.061 Uiso 1 1 calc R
C30 C 0.6202(3) -0.06963(13) 0.8887(3) 0.0362(7) Uani 1 1 d .
H30A H 0.6031 -0.0913 0.8160 0.043 Uiso 1 1 calc R
H30B H 0.5835 -0.0886 0.9352 0.043 Uiso 1 1 calc R
C31 C 0.7535(4) -0.05170(18) 1.1583(3) 0.0519(9) Uani 1 1 d .
H31A H 0.8200 -0.0727 1.2131 0.062 Uiso 1 1 calc R
H31B H 0.6885 -0.0778 1.1251 0.062 Uiso 1 1 calc R
C32 C 0.7223(3) -0.00465(16) 1.2251(3) 0.0405(7) Uani 1 1 d .
H32A H 0.6952 -0.0205 1.2830 0.049 Uiso 1 1 calc R
H32B H 0.7897 0.0190 1.2672 0.049 Uiso 1 1 calc R
C33 C 0.9050(3) -0.0154(2) 1.0997(5) 0.0650(12) Uani 1 1 d .
H33A H 0.9172 0.0065 1.0392 0.097 Uiso 1 1 calc GR
H33B H 0.9476 -0.0503 1.1120 0.097 Uiso 1 1 calc GR
H33C H 0.9317 0.0058 1.1730 0.097 Uiso 1 1 calc GR
H9 H 0.562(4) 0.0223(15) 1.139(4) 0.047(11) Uiso 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Co Co 0.3494 0.9721 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O1 Dy1 O8 77.08(9) . .
O1 Dy1 O10 86.54(8) . .
O2 Dy1 O1 127.32(9) 3_656 .
O2 Dy1 O8 144.53(9) 3_656 .
O2 Dy1 O10 126.99(8) 3_656 .
O3 Dy1 O1 87.01(9) . .
O3 Dy1 O2 76.65(9) . 3_656
O3 Dy1 O4 132.36(8) . .
O3 Dy1 O8 80.03(8) . .
O3 Dy1 O10 153.15(7) . .
O4 Dy1 O1 83.19(9) . .
O4 Dy1 O2 73.06(9) . 3_656
O4 Dy1 O8 141.09(8) . .
O4 Dy1 O10 72.50(7) . .
O6 Dy1 O1 151.76(9) . .
O6 Dy1 O2 79.75(9) . 3_656
O6 Dy1 O3 92.89(9) . .
O6 Dy1 O4 116.32(9) . .
O6 Dy1 O8 75.11(9) . .
O6 Dy1 O10 80.89(8) . .
O8 Dy1 O10 73.13(8) . .
O5 Co1 O7 92.28(10) . .
O5 Co1 N1 170.95(9) . .
O7 Co1 N1 90.69(10) . .
O9 Co1 O5 90.95(9) . .
O9 Co1 O7 113.40(10) . .
O9 Co1 N1 80.03(9) . .
O10 Co1 O5 100.69(9) . .
O10 Co1 O7 133.86(9) . .
O10 Co1 O9 110.47(9) . .
O10 Co1 N1 83.29(9) . .
C1 O1 Dy1 113.8(2) . .
C1 O2 Dy1 176.9(2) . 3_656
C8 O3 Dy1 136.0(2) . .
C8 O4 Dy1 146.1(2) 3_656 .
C15 O5 Co1 123.8(2) . .
C15 O6 Dy1 143.6(2) . .
C22 O7 Co1 100.08(19) . .
C22 O8 Dy1 170.3(2) . .
Co1 O9 H9 124(3) . .
C32 O9 Co1 113.69(19) . .
C32 O9 H9 113(3) . .
Co1 O10 Dy1 105.87(9) . .
C30 O10 Dy1 118.92(17) . .
C30 O10 Co1 112.34(17) . .
C29 N1 Co1 102.96(19) . .
C31 N1 Co1 106.2(2) . .
C31 N1 C29 110.8(3) . .
C33 N1 Co1 117.1(2) . .
C33 N1 C29 106.9(3) . .
C33 N1 C31 112.4(3) . .
O1 C1 C2 118.3(3) . .
O2 C1 O1 121.8(3) . .
O2 C1 C2 119.9(3) . .
C3 C2 C1 120.8(3) . .
C3 C2 C7 119.3(3) . .
C7 C2 C1 119.9(3) . .
C2 C3 H3 119.7 . .
C2 C3 C4 120.5(3) . .
C4 C3 H3 119.7 . .
C3 C4 H4 119.7 . .
C5 C4 C3 120.5(4) . .
C5 C4 H4 119.7 . .
C4 C5 H5 120.0 . .
C4 C5 C6 119.9(4) . .
C6 C5 H5 120.0 . .
C5 C6 H6 120.2 . .
C7 C6 C5 119.6(4) . .
C7 C6 H6 120.2 . .
C2 C7 H7 120.0 . .
C6 C7 C2 120.1(3) . .
C6 C7 H7 120.0 . .
O3 C8 C9 117.8(3) . .
O4 C8 O3 125.0(3) 3_656 .
O4 C8 C9 117.1(3) 3_656 .
C10 C9 C8 119.7(3) . .
C14 C9 C8 121.1(3) . .
C14 C9 C10 119.2(3) . .
C9 C10 H10 119.7 . .
C11 C10 C9 120.5(3) . .
C11 C10 H10 119.7 . .
C10 C11 H11 120.0 . .
C10 C11 C12 120.0(4) . .
C12 C11 H11 120.0 . .
C11 C12 H12 120.1 . .
C13 C12 C11 119.9(4) . .
C13 C12 H12 120.1 . .
C12 C13 H13 119.6 . .
C12 C13 C14 120.7(4) . .
C14 C13 H13 119.6 . .
C9 C14 C13 119.6(3) . .
C9 C14 H14 120.2 . .
C13 C14 H14 120.2 . .
O5 C15 O6 124.6(3) . .
O5 C15 C17 117.9(3) . .
O6 C15 C17 117.5(3) . .
C17 C16 H16 119.7 . .
C21 C16 H16 119.7 . .
C21 C16 C17 120.5(3) . .
C16 C17 C15 120.0(3) . .
C18 C17 C15 121.2(3) . .
C18 C17 C16 118.7(3) . .
C17 C18 H18 119.8 . .
C19 C18 C17 120.4(3) . .
C19 C18 H18 119.8 . .
C18 C19 H19 119.8 . .
C20 C19 C18 120.4(3) . .
C20 C19 H19 119.8 . .
C19 C20 H20 120.1 . .
C21 C20 C19 119.7(3) . .
C21 C20 H20 120.1 . .
C16 C21 H21 119.9 . .
C20 C21 C16 120.2(3) . .
C20 C21 H21 119.9 . .
O7 C22 O8 120.2(3) . .
O7 C22 C23 119.7(3) . .
O8 C22 C23 120.1(3) . .
C24 C23 C22 119.9(3) . .
C24 C23 C28 119.9(3) . .
C28 C23 C22 120.2(3) . .
C23 C24 H24 120.2 . .
C25 C24 C23 119.7(4) . .
C25 C24 H24 120.2 . .
C24 C25 H25 119.8 . .
C26 C25 C24 120.5(5) . .
C26 C25 H25 119.8 . .
C25 C26 H26 119.7 . .
C25 C26 C27 120.6(4) . .
C27 C26 H26 119.7 . .
C26 C27 H27 120.0 . .
C26 C27 C28 119.9(4) . .
C28 C27 H27 120.0 . .
C23 C28 H28 120.3 . .
C27 C28 C23 119.4(4) . .
C27 C28 H28 120.3 . .
N1 C29 H29A 109.4 . .
N1 C29 H29B 109.4 . .
N1 C29 C30 111.3(3) . .
H29A C29 H29B 108.0 . .
C30 C29 H29A 109.4 . .
C30 C29 H29B 109.4 . .
O10 C30 C29 111.4(3) . .
O10 C30 H30A 109.4 . .
O10 C30 H30B 109.4 . .
C29 C30 H30A 109.4 . .
C29 C30 H30B 109.4 . .
H30A C30 H30B 108.0 . .
N1 C31 H31A 109.6 . .
N1 C31 H31B 109.6 . .
N1 C31 C32 110.1(3) . .
H31A C31 H31B 108.2 . .
C32 C31 H31A 109.6 . .
C32 C31 H31B 109.6 . .
O9 C32 C31 106.8(3) . .
O9 C32 H32A 110.4 . .
O9 C32 H32B 110.4 . .
C31 C32 H32A 110.4 . .
C31 C32 H32B 110.4 . .
H32A C32 H32B 108.6 . .
N1 C33 H33A 109.5 . .
N1 C33 H33B 109.5 . .
N1 C33 H33C 109.5 . .
H33A C33 H33B 109.5 . .
H33A C33 H33C 109.5 . .
H33B C33 H33C 109.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Dy1 O1 2.323(2) .
Dy1 O2 2.315(2) 3_656
Dy1 O3 2.299(2) .
Dy1 O4 2.305(2) .
Dy1 O6 2.295(2) .
Dy1 O8 2.374(2) .
Dy1 O10 2.4008(19) .
Co1 O5 2.045(2) .
Co1 O7 2.077(2) .
Co1 O9 2.042(2) .
Co1 O10 2.011(2) .
Co1 N1 2.211(2) .
O1 C1 1.257(4) .
O2 Dy1 2.315(2) 3_656
O2 C1 1.250(4) .
O3 C8 1.260(4) .
O4 C8 1.255(4) 3_656
O5 C15 1.249(4) .
O6 C15 1.260(4) .
O7 C22 1.259(4) .
O8 C22 1.263(4) .
O9 C32 1.438(4) .
O9 H9 0.89(5) .
O10 C30 1.431(4) .
N1 C29 1.492(5) .
N1 C31 1.473(5) .
N1 C33 1.455(5) .
C1 C2 1.490(4) .
C2 C3 1.375(5) .
C2 C7 1.396(5) .
C3 H3 0.9300 .
C3 C4 1.378(5) .
C4 H4 0.9300 .
C4 C5 1.371(6) .
C5 H5 0.9300 .
C5 C6 1.389(6) .
C6 H6 0.9300 .
C6 C7 1.386(5) .
C7 H7 0.9300 .
C8 O4 1.255(4) 3_656
C8 C9 1.504(4) .
C9 C10 1.385(4) .
C9 C14 1.379(5) .
C10 H10 0.9300 .
C10 C11 1.372(5) .
C11 H11 0.9300 .
C11 C12 1.375(6) .
C12 H12 0.9300 .
C12 C13 1.360(6) .
C13 H13 0.9300 .
C13 C14 1.387(5) .
C14 H14 0.9300 .
C15 C17 1.501(4) .
C16 H16 0.9300 .
C16 C17 1.387(4) .
C16 C21 1.379(5) .
C17 C18 1.382(4) .
C18 H18 0.9300 .
C18 C19 1.379(5) .
C19 H19 0.9300 .
C19 C20 1.375(5) .
C20 H20 0.9300 .
C20 C21 1.369(5) .
C21 H21 0.9300 .
C22 C23 1.485(4) .
C23 C24 1.381(5) .
C23 C28 1.394(5) .
C24 H24 0.9300 .
C24 C25 1.378(6) .
C25 H25 0.9300 .
C25 C26 1.362(8) .
C26 H26 0.9300 .
C26 C27 1.373(7) .
C27 H27 0.9300 .
C27 C28 1.383(6) .
C28 H28 0.9300 .
C29 H29A 0.9700 .
C29 H29B 0.9700 .
C29 C30 1.502(5) .
C30 H30A 0.9700 .
C30 H30B 0.9700 .
C31 H31A 0.9700 .
C31 H31B 0.9700 .
C31 C32 1.516(5) .
C32 H32A 0.9700 .
C32 H32B 0.9700 .
C33 H33A 0.9600 .
C33 H33B 0.9600 .
C33 H33C 0.9600 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
Dy1 O1 C1 O2 -3.5(4) . .
Dy1 O1 C1 C2 175.6(2) . .
Dy1 O3 C8 O4 -10.3(5) . 3_656
Dy1 O3 C8 C9 169.8(2) . .
Dy1 O6 C15 O5 -19.6(6) . .
Dy1 O6 C15 C17 162.4(3) . .
Dy1 O10 C30 C29 91.0(3) . .
Co1 O5 C15 O6 19.7(5) . .
Co1 O5 C15 C17 -162.3(2) . .
Co1 O7 C22 O8 0.2(3) . .
Co1 O7 C22 C23 -179.0(2) . .
Co1 O9 C32 C31 -42.5(3) . .
Co1 O10 C30 C29 -33.4(3) . .
Co1 N1 C29 C30 -38.3(3) . .
Co1 N1 C31 C32 -38.0(3) . .
O1 C1 C2 C3 177.1(3) . .
O1 C1 C2 C7 -3.7(5) . .
O2 C1 C2 C3 -3.8(5) . .
O2 C1 C2 C7 175.4(3) . .
O3 C8 C9 C10 163.8(3) . .
O3 C8 C9 C14 -17.5(5) . .
O4 C8 C9 C10 -16.0(5) 3_656 .
O4 C8 C9 C14 162.7(3) 3_656 .
O5 C15 C17 C16 159.3(3) . .
O5 C15 C17 C18 -21.1(5) . .
O6 C15 C17 C16 -22.5(5) . .
O6 C15 C17 C18 157.0(3) . .
O7 C22 C23 C24 -177.2(3) . .
O7 C22 C23 C28 1.4(5) . .
O8 C22 C23 C24 3.5(5) . .
O8 C22 C23 C28 -177.9(3) . .
N1 C29 C30 O10 49.8(4) . .
N1 C31 C32 O9 53.5(4) . .
C1 C2 C3 C4 178.2(4) . .
C1 C2 C7 C6 -178.0(4) . .
C2 C3 C4 C5 -0.1(7) . .
C3 C2 C7 C6 1.3(6) . .
C3 C4 C5 C6 1.1(7) . .
C4 C5 C6 C7 -0.8(7) . .
C5 C6 C7 C2 -0.3(7) . .
C7 C2 C3 C4 -1.1(6) . .
C8 C9 C10 C11 179.0(3) . .
C8 C9 C14 C13 -178.7(4) . .
C9 C10 C11 C12 -0.5(6) . .
C10 C9 C14 C13 0.0(6) . .
C10 C11 C12 C13 0.3(7) . .
C11 C12 C13 C14 0.0(8) . .
C12 C13 C14 C9 -0.2(7) . .
C14 C9 C10 C11 0.3(5) . .
C15 C17 C18 C19 -178.3(4) . .
C16 C17 C18 C19 1.2(6) . .
C17 C16 C21 C20 -1.8(7) . .
C17 C18 C19 C20 -2.4(7) . .
C18 C19 C20 C21 1.4(7) . .
C19 C20 C21 C16 0.7(7) . .
C21 C16 C17 C15 -179.5(4) . .
C21 C16 C17 C18 0.9(6) . .
C22 C23 C24 C25 177.5(4) . .
C22 C23 C28 C27 -178.0(3) . .
C23 C24 C25 C26 1.1(7) . .
C24 C23 C28 C27 0.6(5) . .
C24 C25 C26 C27 -0.5(8) . .
C25 C26 C27 C28 0.0(8) . .
C26 C27 C28 C23 0.0(7) . .
C28 C23 C24 C25 -1.1(6) . .
C29 N1 C31 C32 -149.2(3) . .
C31 N1 C29 C30 74.9(4) . .
C33 N1 C29 C30 -162.3(3) . .
C33 N1 C31 C32 91.3(4) . .
