#------------------------------------------------------------------------------
#$Date: 2017-10-12 02:23:09 +0300 (Thu, 12 Oct 2017) $
#$Revision: 201926 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/10/15/7101537.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7101537
loop_
_publ_author_name
P.Govindaswamy
D.Linder
J.Lacour
G.Suss-Fink
B.Therrien
_publ_section_title
;
Self-assembled hexanuclear arene ruthenium
metallo-prisms with unexpected double helical chirality
;
_journal_issue                   45
_journal_name_full               'Chemical Communications'
_journal_paper_doi               10.1039/b610155k
_journal_year                    2006
_chemical_formula_moiety         'C102 H108 N12 O12 Ru6, (C F3 O3 S)6'
_chemical_formula_sum            'C108 H108 F18 N12 O30 Ru6 S6'
_chemical_formula_weight         3194.84
_chemical_name_systematic        ?
_space_group_crystal_system      trigonal
_space_group_IT_number           158
_space_group_name_Hall           'P 3 -2"c'
_space_group_name_H-M_alt        'P 3 c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                120.00
_cell_formula_units_Z            2
_cell_length_a                   18.100(3)
_cell_length_b                   18.100(3)
_cell_length_c                   25.705(5)
_cell_measurement_reflns_used    8000
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      25.85
_cell_measurement_theta_min      2.00
_cell_volume                     7293(2)
_computing_cell_refinement       'CELL (Stoe & Cie, 2000)'
_computing_data_collection       'EXPOSE (Stoe & Cie, 2000)'
_computing_data_reduction        'INTEGRATE (Stoe & Cie, 2000)'
_computing_molecular_graphics    'ORTEP-32 (Farrugia, 1997)'
_computing_publication_material  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      173(2)
_diffrn_detector_area_resol_mean 0.81\%A
_diffrn_measured_fraction_theta_full 0.768
_diffrn_measured_fraction_theta_max 0.768
_diffrn_measurement_device_type  'STOE IPDS'
_diffrn_measurement_method       'phi oscillation'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0709
_diffrn_reflns_av_sigmaI/netI    0.1132
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -22
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -22
_diffrn_reflns_limit_l_max       30
_diffrn_reflns_limit_l_min       -31
_diffrn_reflns_number            12150
_diffrn_reflns_theta_full        25.93
_diffrn_reflns_theta_max         25.93
_diffrn_reflns_theta_min         2.05
_diffrn_standards_decay_%        0
_diffrn_standards_interval_time  0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    0.781
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    1.455
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       rod
_exptl_crystal_F_000             3204
_exptl_crystal_size_max          0.18
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.10
_refine_diff_density_max         0.503
_refine_diff_density_min         -0.449
_refine_diff_density_rms         0.087
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   0.43(6)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.831
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     439
_refine_ls_number_reflns         6305
_refine_ls_number_restraints     4
_refine_ls_restrained_S_all      0.831
_refine_ls_R_factor_all          0.1210
_refine_ls_R_factor_gt           0.0647
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0914P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1505
_refine_ls_wR_factor_ref         0.1713
_reflns_number_gt                2910
_reflns_number_total             6305
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b610155k.txt
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Trigonal' changed to 'trigonal' according
to '/home/saulius/struct/CIF-dictionaries/cif_core.dic' dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_sg_symbol_H-M      'P 3c1'
_cod_database_code               7101537
loop_
_space_group_symop_id
_space_group_symop_operation_xyz
1 'x, y, z'
2 '-y, x-y, z'
3 '-y, -x, z+1/2'
4 '-x+y, -x, z'
5 'x, x-y, z+1/2'
6 '-x+y, y, z+1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
C1 C 0.5098(19) 0.401(2) 0.3750(8) 0.144(3) Uani 1 1 d .
C2 C 0.4351(18) 0.3807(18) 0.3980(7) 0.144(3) Uani 1 1 d .
H2 H 0.4018 0.3276 0.4135 0.173 Uiso 1 1 calc R
C3 C 0.4065(17) 0.4480(18) 0.3978(7) 0.144(3) Uani 1 1 d .
H3 H 0.3553 0.4380 0.4125 0.173 Uiso 1 1 calc R
C4 C 0.467(2) 0.530(2) 0.3725(7) 0.144(3) Uani 1 1 d .
C5 C 0.5264(19) 0.536(2) 0.3541(7) 0.144(3) Uani 1 1 d .
H5 H 0.5617 0.5894 0.3390 0.173 Uiso 1 1 calc R
C6 C 0.5570(19) 0.4780(18) 0.3501(7) 0.144(3) Uani 1 1 d .
H6 H 0.6062 0.4911 0.3317 0.173 Uiso 1 1 calc R
C7 C 0.5331(19) 0.3335(17) 0.3790(7) 0.144(3) Uani 1 1 d .
H7A H 0.5824 0.3530 0.4008 0.216 Uiso 1 1 calc R
H7B H 0.5456 0.3208 0.3449 0.216 Uiso 1 1 calc R
H7C H 0.4863 0.2831 0.3937 0.216 Uiso 1 1 calc R
C8 C 0.4240(17) 0.5903(14) 0.3710(6) 0.144(3) Uani 1 1 d .
H8 H 0.3625 0.5534 0.3655 0.173 Uiso 1 1 calc R
C9 C 0.4565(15) 0.6469(14) 0.3287(6) 0.144(3) Uani 1 1 d .
H9A H 0.5007 0.7015 0.3407 0.216 Uiso 1 1 calc R
H9B H 0.4116 0.6528 0.3132 0.216 Uiso 1 1 calc R
H9C H 0.4796 0.6249 0.3034 0.216 Uiso 1 1 calc R
C10 C 0.4365(15) 0.6233(16) 0.4241(6) 0.144(3) Uani 1 1 d .
H10A H 0.4468 0.6808 0.4235 0.216 Uiso 1 1 calc R
H10B H 0.4846 0.6227 0.4394 0.216 Uiso 1 1 calc R
H10C H 0.3864 0.5883 0.4444 0.216 Uiso 1 1 calc R
C11 C 0.3727(15) 0.5101(15) 0.0575(7) 0.118(2) Uani 1 1 d .
C12 C 0.4493(15) 0.5672(16) 0.0821(6) 0.118(2) Uani 1 1 d .
H12 H 0.4551 0.6156 0.0985 0.141 Uiso 1 1 calc R
C13 C 0.5170(15) 0.5510(16) 0.0817(6) 0.118(2) Uani 1 1 d .
H13 H 0.5687 0.5896 0.0970 0.141 Uiso 1 1 calc R
C14 C 0.5076(16) 0.4767(17) 0.0583(7) 0.118(2) Uani 1 1 d .
C15 C 0.4388(14) 0.4207(15) 0.0296(7) 0.118(2) Uani 1 1 d .
H15 H 0.4382 0.3753 0.0123 0.141 Uiso 1 1 calc R
C16 C 0.3640(15) 0.4350(15) 0.0271(7) 0.118(2) Uani 1 1 d .
H16 H 0.3154 0.3997 0.0079 0.141 Uiso 1 1 calc R
C17 C 0.2971(13) 0.5186(15) 0.0657(6) 0.118(2) Uani 1 1 d .
H17A H 0.3136 0.5722 0.0822 0.177 Uiso 1 1 calc R
H17B H 0.2571 0.4728 0.0874 0.177 Uiso 1 1 calc R
H17C H 0.2710 0.5163 0.0327 0.177 Uiso 1 1 calc R
C18 C 0.5836(15) 0.4545(15) 0.0679(6) 0.118(2) Uani 1 1 d .
H18 H 0.6029 0.4700 0.1039 0.141 Uiso 1 1 calc R
C19 C 0.5630(15) 0.3662(15) 0.0604(6) 0.118(2) Uani 1 1 d .
H19A H 0.5122 0.3289 0.0795 0.177 Uiso 1 1 calc R
H19B H 0.6095 0.3596 0.0727 0.177 Uiso 1 1 calc R
H19C H 0.5539 0.3522 0.0240 0.177 Uiso 1 1 calc R
C20 C 0.6587(14) 0.5228(14) 0.0307(6) 0.118(2) Uani 1 1 d .
H20A H 0.6605 0.5767 0.0327 0.177 Uiso 1 1 calc R
H20B H 0.6478 0.5027 -0.0046 0.177 Uiso 1 1 calc R
H20C H 0.7124 0.5297 0.0418 0.177 Uiso 1 1 calc R
C21 C 0.3027(12) 0.2281(12) 0.3059(6) 0.083(5) Uani 1 1 d .
H21 H 0.3533 0.2275 0.3110 0.099 Uiso 1 1 calc R
C22 C 0.2336(9) 0.1567(9) 0.2989(4) 0.061(3) Uani 1 1 d .
H22 H 0.2358 0.1065 0.2966 0.074 Uiso 1 1 calc R
C23 C 0.1533(9) 0.1537(9) 0.2946(4) 0.057(3) Uani 1 1 d .
C24 C 0.1555(10) 0.2321(10) 0.2943(4) 0.063(4) Uani 1 1 d .
H24 H 0.1059 0.2349 0.2907 0.076 Uiso 1 1 calc R
C25 C 0.2348(13) 0.3057(12) 0.2995(5) 0.084(5) Uani 1 1 d .
H25 H 0.2375 0.3584 0.2981 0.100 Uiso 1 1 calc R
C26 C 0.0708(10) 0.0719(9) 0.2896(4) 0.058(4) Uani 1 1 d .
C27 C 0.2918(13) 0.2454(13) 0.1163(5) 0.089(5) Uani 1 1 d .
H27 H 0.3429 0.2482 0.1070 0.107 Uiso 1 1 calc R
C28 C 0.2225(11) 0.1650(9) 0.1206(4) 0.065(4) Uani 1 1 d .
H28 H 0.2267 0.1170 0.1132 0.078 Uiso 1 1 calc R
C29 C 0.1485(7) 0.1578(8) 0.1358(4) 0.051(3) Uani 1 1 d .
C30 C 0.1459(10) 0.2339(9) 0.1451(4) 0.064(4) Uani 1 1 d .
H30 H 0.0952 0.2320 0.1543 0.077 Uiso 1 1 calc R
C31 C 0.2199(10) 0.3097(8) 0.1402(4) 0.060(4) Uani 1 1 d .
H31 H 0.2187 0.3590 0.1488 0.072 Uiso 1 1 calc R
C32 C 0.0695(9) 0.0742(9) 0.1405(3) 0.059(4) Uani 1 1 d .
C33 C 0.4460(11) 0.4084(10) 0.2117(5) 0.073(5) Uani 1 1 d .
C34 C 0.3953(9) 0.4566(9) 0.2192(6) 0.066(4) Uani 1 1 d .
C35 C 0.713(2) 0.656(2) 0.2100(8) 0.147(11) Uani 1 1 d .
C36 C 0.2924(14) 0.2492(15) -0.0952(6) 0.097(6) Uani 1 1 d .
N1 N 0.3052(8) 0.3038(10) 0.3061(4) 0.078(4) Uani 1 1 d .
N2 N 0.0771(7) 0.0018(8) 0.2891(3) 0.058(3) Uani 1 1 d .
N3 N 0.2953(8) 0.3186(7) 0.1236(4) 0.067(3) Uani 1 1 d .
N4 N 0.0789(7) 0.0062(7) 0.1407(3) 0.047(2) Uani 1 1 d .
O1 O 0.4638(7) 0.3827(7) 0.2522(3) 0.077(3) Uani 1 1 d .
O2 O 0.3797(7) 0.4702(6) 0.2651(3) 0.074(3) Uani 1 1 d .
O3 O 0.4591(7) 0.3950(7) 0.1667(4) 0.072(3) Uani 1 1 d .
O4 O 0.3707(6) 0.4764(6) 0.1783(3) 0.066(2) Uani 1 1 d .
O5 O 0.5661(8) 0.5838(7) 0.2169(5) 0.104(4) Uani 1 1 d .
O6 O 0.6264(10) 0.7109(8) 0.1631(4) 0.138(6) Uani 1 1 d .
O7 O 0.6400(11) 0.7231(13) 0.2581(7) 0.179(9) Uani 1 1 d .
O8 O 0.399(3) 0.253(2) -0.0488(15) 0.29(2) Uani 1 1 d .
O9 O 0.292(2) 0.2109(15) -0.0046(6) 0.275(17) Uani 1 1 d .
O10 O 0.305(2) 0.1230(17) -0.0669(6) 0.257(14) Uani 1 1 d .
F1 F 0.7887(11) 0.7430(16) 0.2088(7) 0.248(13) Uani 1 1 d .
F2 F 0.7319(10) 0.6258(10) 0.2477(5) 0.151(5) Uani 1 1 d .
F3 F 0.7221(11) 0.6319(12) 0.1660(5) 0.166(6) Uani 1 1 d .
F4 F 0.3059(10) 0.3235(10) -0.0829(4) 0.151(5) Uani 1 1 d .
F5 F 0.3364(11) 0.2515(9) -0.1387(5) 0.200(9) Uani 1 1 d .
F6 F 0.2095(12) 0.2000(13) -0.1070(5) 0.187(7) Uani 1 1 d .
S1 S 0.6277(4) 0.6695(3) 0.21332(18) 0.1038(17) Uani 1 1 d .
S2 S 0.3284(8) 0.2054(7) -0.0487(3) 0.169(4) Uani 1 1 d .
Ru1 Ru 0.42490(9) 0.41913(8) 0.32083(4) 0.0810(4) Uani 1 1 d .
Ru2 Ru 0.40265(8) 0.43779(7) 0.10914(3) 0.0662(3) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ru Ru -1.2594 0.8363 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C2 C1 C6 121(3) . .
C2 C1 C7 114(3) . .
C6 C1 C7 125(3) . .
C2 C1 Ru1 69.1(16) . .
C6 C1 Ru1 71.6(17) . .
C7 C1 Ru1 131.8(16) . .
C1 C2 C3 118(3) . .
C1 C2 Ru1 75.0(15) . .
C3 C2 Ru1 67.9(11) . .
C1 C2 H2 121.1 . .
C3 C2 H2 121.1 . .
Ru1 C2 H2 128.0 . .
C4 C3 C2 115(2) . .
C4 C3 Ru1 72.9(11) . .
C2 C3 Ru1 69.6(11) . .
C4 C3 H3 122.6 . .
C2 C3 H3 122.6 . .
Ru1 C3 H3 126.6 . .
C5 C4 C3 119(3) . .
C5 C4 C8 132(3) . .
C3 C4 C8 109(2) . .
C5 C4 Ru1 73.9(19) . .
C3 C4 Ru1 67.0(13) . .
C8 C4 Ru1 122.3(16) . .
C4 C5 C6 131(4) . .
C4 C5 Ru1 76(2) . .
C6 C5 Ru1 72.4(16) . .
C4 C5 H5 114.5 . .
C6 C5 H5 114.5 . .
Ru1 C5 H5 130.6 . .
C1 C6 C5 116(3) . .
C1 C6 Ru1 72.2(17) . .
C5 C6 Ru1 69.7(16) . .
C1 C6 H6 121.9 . .
C5 C6 H6 121.9 . .
Ru1 C6 H6 128.1 . .
C1 C7 H7A 109.5 . .
C1 C7 H7B 109.5 . .
H7A C7 H7B 109.5 . .
C1 C7 H7C 109.5 . .
H7A C7 H7C 109.5 . .
H7B C7 H7C 109.5 . .
C9 C8 C10 120.1(19) . .
C9 C8 C4 110(2) . .
C10 C8 C4 103.0(16) . .
C9 C8 H8 107.7 . .
C10 C8 H8 107.7 . .
C4 C8 H8 107.7 . .
C8 C9 H9A 109.5 . .
C8 C9 H9B 109.5 . .
H9A C9 H9B 109.5 . .
C8 C9 H9C 109.5 . .
H9A C9 H9C 109.5 . .
H9B C9 H9C 109.5 . .
C8 C10 H10A 109.5 . .
C8 C10 H10B 109.5 . .
H10A C10 H10B 109.5 . .
C8 C10 H10C 109.5 . .
H10A C10 H10C 109.5 . .
H10B C10 H10C 109.5 . .
C12 C11 C17 119(2) . .
C12 C11 C16 121(2) . .
C17 C11 C16 119(2) . .
C12 C11 Ru2 73.0(13) . .
C17 C11 Ru2 121.1(12) . .
C16 C11 Ru2 73.2(12) . .
C13 C12 C11 119(2) . .
C13 C12 Ru2 71.6(13) . .
C11 C12 Ru2 68.9(13) . .
C13 C12 H12 120.3 . .
C11 C12 H12 120.3 . .
Ru2 C12 H12 132.1 . .
C12 C13 C14 120(2) . .
C12 C13 Ru2 71.0(13) . .
C14 C13 Ru2 68.6(13) . .
C12 C13 H13 119.8 . .
C14 C13 H13 119.8 . .
Ru2 C13 H13 134.1 . .
C15 C14 C13 125(2) . .
C15 C14 C18 118(2) . .
C13 C14 C18 117(2) . .
C15 C14 Ru2 75.7(13) . .
C13 C14 Ru2 73.3(12) . .
C18 C14 Ru2 123.4(11) . .
C14 C15 C16 117(2) . .
C14 C15 Ru2 67.7(11) . .
C16 C15 Ru2 70.2(10) . .
C14 C15 H15 121.3 . .
C16 C15 H15 121.3 . .
Ru2 C15 H15 133.8 . .
C15 C16 C11 116(2) . .
C15 C16 Ru2 70.2(11) . .
C11 C16 Ru2 66.2(11) . .
C15 C16 H16 122.0 . .
C11 C16 H16 122.0 . .
Ru2 C16 H16 134.5 . .
C11 C17 H17A 109.5 . .
C11 C17 H17B 109.5 . .
H17A C17 H17B 109.5 . .
C11 C17 H17C 109.5 . .
H17A C17 H17C 109.5 . .
H17B C17 H17C 109.5 . .
C19 C18 C20 114.6(17) . .
C19 C18 C14 118(2) . .
C20 C18 C14 102.2(16) . .
C19 C18 H18 107.2 . .
C20 C18 H18 107.2 . .
C14 C18 H18 107.2 . .
C18 C19 H19A 109.5 . .
C18 C19 H19B 109.5 . .
H19A C19 H19B 109.5 . .
C18 C19 H19C 109.5 . .
H19A C19 H19C 109.5 . .
H19B C19 H19C 109.5 . .
C18 C20 H20A 109.5 . .
C18 C20 H20B 109.5 . .
H20A C20 H20B 109.5 . .
C18 C20 H20C 109.5 . .
H20A C20 H20C 109.5 . .
H20B C20 H20C 109.5 . .
C22 C21 N1 123.0(15) . .
C22 C21 H21 118.5 . .
N1 C21 H21 118.5 . .
C21 C22 C23 120.5(14) . .
C21 C22 H22 119.8 . .
C23 C22 H22 119.8 . .
C24 C23 C22 116.7(12) . .
C24 C23 C26 120.9(12) . .
C22 C23 C26 122.5(13) . .
C25 C24 C23 117.7(14) . .
C25 C24 H24 121.2 . .
C23 C24 H24 121.2 . .
N1 C25 C24 122.6(15) . .
N1 C25 H25 118.7 . .
C24 C25 H25 118.7 . .
N2 C26 N2 126.5(13) . 2
N2 C26 C23 115.3(15) . .
N2 C26 C23 118.1(13) 2 .
N3 C27 C28 128.2(15) . .
N3 C27 H27 115.9 . .
C28 C27 H27 115.9 . .
C29 C28 C27 117.9(13) . .
C29 C28 H28 121.1 . .
C27 C28 H28 121.1 . .
C28 C29 C30 118.2(12) . .
C28 C29 C32 122.1(13) . .
C30 C29 C32 119.6(12) . .
C31 C30 C29 117.9(12) . .
C31 C30 H30 121.1 . .
C29 C30 H30 121.1 . .
N3 C31 C30 124.9(11) . .
N3 C31 H31 117.6 . .
C30 C31 H31 117.6 . .
N4 C32 N4 125.4(14) . 2
N4 C32 C29 116.3(13) . .
N4 C32 C29 118.1(13) 2 .
O3 C33 O1 127.1(18) . .
O3 C33 C34 116.8(14) . .
O1 C33 C34 115.9(11) . .
O4 C34 O2 125.3(16) . .
O4 C34 C33 116.3(12) . .
O2 C34 C33 118.3(12) . .
F2 C35 F3 116(2) . .
F2 C35 F1 100(2) . .
F3 C35 F1 98(2) . .
F2 C35 S1 120(2) . .
F3 C35 S1 112.5(18) . .
F1 C35 S1 106.2(19) . .
F4 C36 F6 108(2) . .
F4 C36 F5 111.8(18) . .
F6 C36 F5 106.2(14) . .
F4 C36 S2 113.0(13) . .
F6 C36 S2 113.8(18) . .
F5 C36 S2 103.4(18) . .
C25 N1 C21 119.4(15) . .
C25 N1 Ru1 121.2(12) . .
C21 N1 Ru1 119.4(11) . .
C26 N2 C26 113.5(13) . 4
C27 N3 C31 112.8(13) . .
C27 N3 Ru2 124.6(12) . .
C31 N3 Ru2 122.5(9) . .
C32 N4 C32 114.6(14) . 4
C33 O1 Ru1 113.0(10) . .
C34 O2 Ru1 112.3(10) . .
C33 O3 Ru2 113.9(11) . .
C34 O4 Ru2 114.7(10) . .
O5 S1 O7 117.7(11) . .
O5 S1 O6 114.3(8) . .
O7 S1 O6 112.7(13) . .
O5 S1 C35 97.3(14) . .
O7 S1 C35 106.9(12) . .
O6 S1 C35 105.8(12) . .
O8 S2 O9 111(2) . .
O8 S2 O10 116(2) . .
O9 S2 O10 117.4(16) . .
O8 S2 C36 101(2) . .
O9 S2 C36 103.8(18) . .
O10 S2 C36 105.7(11) . .
O2 Ru1 C3 112.9(8) . .
O2 Ru1 O1 80.3(3) . .
C3 Ru1 O1 166.3(8) . .
O2 Ru1 C2 154.0(8) . .
C3 Ru1 C2 42.5(9) . .
O1 Ru1 C2 125.0(8) . .
O2 Ru1 N1 83.2(4) . .
C3 Ru1 N1 101.3(8) . .
O1 Ru1 N1 83.3(4) . .
C2 Ru1 N1 93.2(8) . .
O2 Ru1 C5 99.5(8) . .
C3 Ru1 C5 63.3(9) . .
O1 Ru1 C5 112.4(7) . .
C2 Ru1 C5 77.5(10) . .
N1 Ru1 C5 164.3(7) . .
O2 Ru1 C4 92.6(8) . .
C3 Ru1 C4 40.0(9) . .
O1 Ru1 C4 140.2(9) . .
C2 Ru1 C4 71.9(10) . .
N1 Ru1 C4 135.1(9) . .
C5 Ru1 C4 29.9(8) . .
O2 Ru1 C6 126.3(8) . .
C3 Ru1 C6 80.1(9) . .
O1 Ru1 C6 89.2(6) . .
C2 Ru1 C6 65.9(9) . .
N1 Ru1 C6 147.9(8) . .
C5 Ru1 C6 37.9(8) . .
C4 Ru1 C6 63.6(10) . .
O2 Ru1 C1 162.4(9) . .
C3 Ru1 C1 69.7(9) . .
O1 Ru1 C1 96.6(7) . .
C2 Ru1 C1 36.0(9) . .
N1 Ru1 C1 113.8(9) . .
C5 Ru1 C1 65.5(10) . .
C4 Ru1 C1 78.6(11) . .
C6 Ru1 C1 36.2(9) . .
N3 Ru2 O4 85.6(4) . .
N3 Ru2 C14 132.1(8) . .
O4 Ru2 C14 139.9(8) . .
N3 Ru2 C11 110.9(7) . .
O4 Ru2 C11 97.3(6) . .
C14 Ru2 C11 82.6(8) . .
N3 Ru2 O3 82.5(4) . .
O4 Ru2 O3 78.2(4) . .
C14 Ru2 O3 92.1(6) . .
C11 Ru2 O3 165.7(7) . .
N3 Ru2 C12 146.1(7) . .
O4 Ru2 C12 86.3(6) . .
C14 Ru2 C12 69.0(8) . .
C11 Ru2 C12 38.1(7) . .
O3 Ru2 C12 127.7(7) . .
N3 Ru2 C13 169.7(6) . .
O4 Ru2 C13 104.6(6) . .
C14 Ru2 C13 38.1(8) . .
C11 Ru2 C13 68.4(8) . .
O3 Ru2 C13 99.4(6) . .
C12 Ru2 C13 37.5(7) . .
N3 Ru2 C16 91.5(7) . .
O4 Ru2 C16 132.8(7) . .
C14 Ru2 C16 68.9(8) . .
C11 Ru2 C16 40.7(8) . .
O3 Ru2 C16 148.1(7) . .
C12 Ru2 C16 70.6(8) . .
C13 Ru2 C16 81.6(8) . .
N3 Ru2 C15 102.0(6) . .
O4 Ru2 C15 168.6(7) . .
C14 Ru2 C15 36.6(8) . .
C11 Ru2 C15 72.2(8) . .
O3 Ru2 C15 111.0(6) . .
C12 Ru2 C15 82.7(8) . .
C13 Ru2 C15 67.9(8) . .
C16 Ru2 C15 39.6(7) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C1 C2 1.35(4) .
C1 C6 1.37(3) .
C1 C7 1.49(3) .
C1 Ru1 2.21(3) .
C2 C3 1.54(4) .
C2 Ru1 2.14(2) .
C2 H2 0.9300 .
C3 C4 1.48(4) .
C3 Ru1 2.116(19) .
C3 H3 0.9300 .
C4 C5 1.13(3) .
C4 C8 1.63(4) .
C4 Ru1 2.20(2) .
C5 C6 1.42(3) .
C5 Ru1 2.17(3) .
C5 H5 0.9300 .
C6 Ru1 2.21(3) .
C6 H6 0.9300 .
C7 H7A 0.9600 .
C7 H7B 0.9600 .
C7 H7C 0.9600 .
C8 C9 1.405(18) .
C8 C10 1.46(2) .
C8 H8 0.9800 .
C9 H9A 0.9600 .
C9 H9B 0.9600 .
C9 H9C 0.9600 .
C10 H10A 0.9600 .
C10 H10B 0.9600 .
C10 H10C 0.9600 .
C11 C12 1.40(3) .
C11 C17 1.47(3) .
C11 C16 1.51(3) .
C11 Ru2 2.12(2) .
C12 C13 1.40(3) .
C12 Ru2 2.17(2) .
C12 H12 0.9300 .
C13 C14 1.40(3) .
C13 Ru2 2.18(2) .
C13 H13 0.9300 .
C14 C15 1.36(3) .
C14 C18 1.63(3) .
C14 Ru2 2.116(19) .
C15 C16 1.50(3) .
C15 Ru2 2.215(19) .
C15 H15 0.9300 .
C16 Ru2 2.215(19) .
C16 H16 0.9300 .
C17 H17A 0.9600 .
C17 H17B 0.9600 .
C17 H17C 0.9600 .
C18 C19 1.46(3) .
C18 C20 1.62(3) .
C18 H18 0.9800 .
C19 H19A 0.9600 .
C19 H19B 0.9600 .
C19 H19C 0.9600 .
C20 H20A 0.9600 .
C20 H20B 0.9600 .
C20 H20C 0.9600 .
C21 C22 1.28(2) .
C21 N1 1.35(2) .
C21 H21 0.9300 .
C22 C23 1.432(18) .
C22 H22 0.9300 .
C23 C24 1.399(18) .
C23 C26 1.493(19) .
C24 C25 1.39(2) .
C24 H24 0.9300 .
C25 N1 1.30(2) .
C25 H25 0.9300 .
C26 N2 1.328(15) .
C26 N2 1.346(16) 2
C27 N3 1.309(19) .
C27 C28 1.37(2) .
C27 H27 0.9300 .
C28 C29 1.338(18) .
C28 H28 0.9300 .
C29 C30 1.421(18) .
C29 C32 1.479(17) .
C30 C31 1.362(18) .
C30 H30 0.9300 .
C31 N3 1.360(18) .
C31 H31 0.9300 .
C32 N4 1.326(16) .
C32 N4 1.356(16) 2
C33 O3 1.228(15) .
C33 O1 1.247(19) .
C33 C34 1.56(2) .
C34 O4 1.263(17) .
C34 O2 1.265(16) .
C35 F2 1.24(2) .
C35 F3 1.25(2) .
C35 F1 1.48(3) .
C35 S1 1.68(3) .
C36 F4 1.28(2) .
C36 F6 1.34(2) .
C36 F5 1.36(2) .
C36 S2 1.73(2) .
N1 Ru1 2.162(14) .
N2 C26 1.346(16) 4
N3 Ru2 2.092(12) .
N4 C32 1.356(16) 4
O1 Ru1 2.122(10) .
O2 Ru1 2.081(10) .
O3 Ru2 2.151(10) .
O4 Ru2 2.094(9) .
O5 S1 1.389(11) .
O6 S1 1.499(12) .
O7 S1 1.448(15) .
O8 S2 1.13(4) .
O9 S2 1.34(2) .
O10 S2 1.41(2) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
C6 C1 C2 C3 -3(3) . .
C7 C1 C2 C3 177.9(16) . .
Ru1 C1 C2 C3 -54.4(16) . .
C6 C1 C2 Ru1 51(2) . .
C7 C1 C2 Ru1 -127.7(17) . .
C1 C2 C3 C4 -1(3) . .
Ru1 C2 C3 C4 -58.9(15) . .
C1 C2 C3 Ru1 57.9(17) . .
C2 C3 C4 C5 2(3) . .
Ru1 C3 C4 C5 -55(2) . .
C2 C3 C4 C8 175.1(15) . .
Ru1 C3 C4 C8 118.0(15) . .
C2 C3 C4 Ru1 57.1(14) . .
C3 C4 C5 C6 0(4) . .
C8 C4 C5 C6 -170(2) . .
Ru1 C4 C5 C6 -51(2) . .
C3 C4 C5 Ru1 51.4(19) . .
C8 C4 C5 Ru1 -119(3) . .
C2 C1 C6 C5 5(3) . .
C7 C1 C6 C5 -175.6(19) . .
Ru1 C1 C6 C5 55.7(17) . .
C2 C1 C6 Ru1 -50(2) . .
C7 C1 C6 Ru1 129(2) . .
C4 C5 C6 C1 -4(4) . .
Ru1 C5 C6 C1 -56.9(18) . .
C4 C5 C6 Ru1 53(3) . .
C5 C4 C8 C9 19(4) . .
C3 C4 C8 C9 -152.6(16) . .
Ru1 C4 C8 C9 -78(2) . .
C5 C4 C8 C10 -110(3) . .
C3 C4 C8 C10 78(2) . .
Ru1 C4 C8 C10 152.4(17) . .
C17 C11 C12 C13 169.2(15) . .
C16 C11 C12 C13 -5(3) . .
Ru2 C11 C12 C13 52.6(14) . .
C17 C11 C12 Ru2 116.6(16) . .
C16 C11 C12 Ru2 -57.4(15) . .
C11 C12 C13 C14 -2(2) . .
Ru2 C12 C13 C14 49.4(15) . .
C11 C12 C13 Ru2 -51.4(14) . .
C12 C13 C14 C15 8(3) . .
Ru2 C13 C14 C15 58.3(17) . .
C12 C13 C14 C18 -170.0(14) . .
Ru2 C13 C14 C18 -119.5(14) . .
C12 C13 C14 Ru2 -50.5(14) . .
C13 C14 C15 C16 -6(3) . .
C18 C14 C15 C16 171.8(13) . .
Ru2 C14 C15 C16 51.2(14) . .
C13 C14 C15 Ru2 -57.3(17) . .
C18 C14 C15 Ru2 120.6(15) . .
C14 C15 C16 C11 -1(2) . .
Ru2 C15 C16 C11 49.2(13) . .
C14 C15 C16 Ru2 -50.1(14) . .
C12 C11 C16 C15 6(2) . .
C17 C11 C16 C15 -167.9(14) . .
Ru2 C11 C16 C15 -51.2(13) . .
C12 C11 C16 Ru2 57.4(15) . .
C17 C11 C16 Ru2 -116.7(16) . .
C15 C14 C18 C19 -19(2) . .
C13 C14 C18 C19 158.8(16) . .
Ru2 C14 C18 C19 72(2) . .
C15 C14 C18 C20 107.3(19) . .
C13 C14 C18 C20 -74.7(19) . .
Ru2 C14 C18 C20 -162.0(16) . .
N1 C21 C22 C23 -5(2) . .
C21 C22 C23 C24 4.9(17) . .
C21 C22 C23 C26 -176.2(12) . .
C22 C23 C24 C25 -1.6(16) . .
C26 C23 C24 C25 179.5(10) . .
C23 C24 C25 N1 -2.2(19) . .
C24 C23 C26 N2 178.3(9) . .
C22 C23 C26 N2 -0.5(15) . .
C24 C23 C26 N2 -5.2(15) . 2
C22 C23 C26 N2 176.0(9) . 2
N3 C27 C28 C29 -3(2) . .
C27 C28 C29 C30 1.7(17) . .
C27 C28 C29 C32 178.6(11) . .
C28 C29 C30 C31 -2.8(16) . .
C32 C29 C30 C31 -179.7(9) . .
C29 C30 C31 N3 4.6(17) . .
C28 C29 C32 N4 15.1(14) . .
C30 C29 C32 N4 -168.1(9) . .
C28 C29 C32 N4 -160.6(10) . 2
C30 C29 C32 N4 16.2(13) . 2
O3 C33 C34 O4 1.2(19) . .
O1 C33 C34 O4 -174.2(11) . .
O3 C33 C34 O2 179.0(9) . .
O1 C33 C34 O2 3.6(19) . .
C24 C25 N1 C21 2.9(19) . .
C24 C25 N1 Ru1 -174.5(9) . .
C22 C21 N1 C25 1(2) . .
C22 C21 N1 Ru1 178.0(11) . .
N2 C26 N2 C26 -2.2(19) 2 4
C23 C26 N2 C26 173.9(5) . 4
C28 C27 N3 C31 4(2) . .
C28 C27 N3 Ru2 -174.0(12) . .
C30 C31 N3 C27 -4.9(17) . .
C30 C31 N3 Ru2 173.0(9) . .
N4 C32 N4 C32 0.8(17) 2 4
C29 C32 N4 C32 -174.5(5) . 4
O3 C33 O1 Ru1 -178.1(11) . .
C34 C33 O1 Ru1 -3.2(16) . .
O4 C34 O2 Ru1 175.7(10) . .
C33 C34 O2 Ru1 -1.8(14) . .
O1 C33 O3 Ru2 172.3(13) . .
C34 C33 O3 Ru2 -2.5(15) . .
O2 C34 O4 Ru2 -176.7(9) . .
C33 C34 O4 Ru2 0.9(15) . .
F2 C35 S1 O5 -65(3) . .
F3 C35 S1 O5 77(2) . .
F1 C35 S1 O5 -176.9(14) . .
F2 C35 S1 O7 57(3) . .
F3 C35 S1 O7 -162(2) . .
F1 C35 S1 O7 -55.0(18) . .
F2 C35 S1 O6 178(2) . .
F3 C35 S1 O6 -41(3) . .
F1 C35 S1 O6 65.3(15) . .
F4 C36 S2 O8 -62(3) . .
F6 C36 S2 O8 174(2) . .
F5 C36 S2 O8 59(2) . .
F4 C36 S2 O9 53(2) . .
F6 C36 S2 O9 -71.3(19) . .
F5 C36 S2 O9 173.9(17) . .
F4 C36 S2 O10 177.0(19) . .
F6 C36 S2 O10 53(2) . .
F5 C36 S2 O10 -61.9(19) . .
C34 O2 Ru1 C3 176.3(11) . .
C34 O2 Ru1 O1 0.1(8) . .
C34 O2 Ru1 C2 -167.5(18) . .
C34 O2 Ru1 N1 -84.2(8) . .
C34 O2 Ru1 C5 111.5(10) . .
C34 O2 Ru1 C4 140.7(11) . .
C34 O2 Ru1 C6 81.9(11) . .
C34 O2 Ru1 C1 81(2) . .
C4 C3 Ru1 O2 -64.8(17) . .
C2 C3 Ru1 O2 169.6(13) . .
C4 C3 Ru1 O1 99(4) . .
C2 C3 Ru1 O1 -26(4) . .
C4 C3 Ru1 C2 126(2) . .
C4 C3 Ru1 N1 -152.2(15) . .
C2 C3 Ru1 N1 82.3(15) . .
C4 C3 Ru1 C5 24.5(16) . .
C2 C3 Ru1 C5 -101.1(17) . .
C2 C3 Ru1 C4 -126(2) . .
C4 C3 Ru1 C6 60.5(16) . .
C2 C3 Ru1 C6 -65.1(15) . .
C4 C3 Ru1 C1 96.5(18) . .
C2 C3 Ru1 C1 -29.1(16) . .
C33 O1 Ru1 O2 1.9(10) . .
C33 O1 Ru1 C3 -163(3) . .
C33 O1 Ru1 C2 175.3(12) . .
C33 O1 Ru1 N1 86.1(10) . .
C33 O1 Ru1 C5 -94.5(13) . .
C33 O1 Ru1 C4 -80.4(16) . .
C33 O1 Ru1 C6 -125.2(12) . .
C33 O1 Ru1 C1 -160.6(12) . .
C1 C2 Ru1 O2 -151.3(16) . .
C3 C2 Ru1 O2 -22(3) . .
C1 C2 Ru1 C3 -129(3) . .
C1 C2 Ru1 O1 44(2) . .
C3 C2 Ru1 O1 172.6(12) . .
C1 C2 Ru1 N1 127.6(18) . .
C3 C2 Ru1 N1 -103.3(15) . .
C1 C2 Ru1 C5 -65.2(18) . .
C3 C2 Ru1 C5 63.8(16) . .
C1 C2 Ru1 C4 -95.6(19) . .
C3 C2 Ru1 C4 33.4(15) . .
C1 C2 Ru1 C6 -27.1(17) . .
C3 C2 Ru1 C6 102.0(16) . .
C3 C2 Ru1 C1 129(3) . .
C25 N1 Ru1 O2 -40.3(10) . .
C21 N1 Ru1 O2 142.4(10) . .
C25 N1 Ru1 C3 71.8(13) . .
C21 N1 Ru1 C3 -105.6(12) . .
C25 N1 Ru1 O1 -121.3(10) . .
C21 N1 Ru1 O1 61.4(10) . .
C25 N1 Ru1 C2 113.9(12) . .
C21 N1 Ru1 C2 -63.5(12) . .
C25 N1 Ru1 C5 61(3) . .
C21 N1 Ru1 C5 -117(3) . .
C25 N1 Ru1 C4 46.6(16) . .
C21 N1 Ru1 C4 -130.8(13) . .
C25 N1 Ru1 C6 161.1(13) . .
C21 N1 Ru1 C6 -16.3(16) . .
C25 N1 Ru1 C1 144.4(11) . .
C21 N1 Ru1 C1 -32.9(12) . .
C4 C5 Ru1 O2 79(2) . .
C6 C5 Ru1 O2 -139.6(13) . .
C4 C5 Ru1 C3 -32(2) . .
C6 C5 Ru1 C3 109.5(17) . .
C4 C5 Ru1 O1 161.9(19) . .
C6 C5 Ru1 O1 -56.3(14) . .
C4 C5 Ru1 C2 -75(2) . .
C6 C5 Ru1 C2 66.7(14) . .
C4 C5 Ru1 N1 -20(5) . .
C6 C5 Ru1 N1 122(3) . .
C6 C5 Ru1 C4 142(3) . .
C4 C5 Ru1 C6 -142(3) . .
C4 C5 Ru1 C1 -111(2) . .
C6 C5 Ru1 C1 30.8(12) . .
C5 C4 Ru1 O2 -105(2) . .
C3 C4 Ru1 O2 123.4(15) . .
C8 C4 Ru1 O2 25(2) . .
C5 C4 Ru1 C3 132(3) . .
C8 C4 Ru1 C3 -98(3) . .
C5 C4 Ru1 O1 -27(3) . .
C3 C4 Ru1 O1 -158.7(12) . .
C8 C4 Ru1 O1 103(2) . .
C5 C4 Ru1 C2 97(2) . .
C3 C4 Ru1 C2 -35.3(15) . .
C8 C4 Ru1 C2 -134(2) . .
C5 C4 Ru1 N1 172.4(17) . .
C3 C4 Ru1 N1 40(2) . .
C8 C4 Ru1 N1 -58(2) . .
C3 C4 Ru1 C5 -132(3) . .
C8 C4 Ru1 C5 130(3) . .
C5 C4 Ru1 C6 25(2) . .
C3 C4 Ru1 C6 -106.9(18) . .
C8 C4 Ru1 C6 155(2) . .
C5 C4 Ru1 C1 60(2) . .
C3 C4 Ru1 C1 -71.9(16) . .
C8 C4 Ru1 C1 -170(2) . .
C1 C6 Ru1 O2 -179.7(13) . .
C5 C6 Ru1 O2 52.4(15) . .
C1 C6 Ru1 C3 69.1(16) . .
C5 C6 Ru1 C3 -58.7(15) . .
C1 C6 Ru1 O1 -102.4(15) . .
C5 C6 Ru1 O1 129.7(13) . .
C1 C6 Ru1 C2 27.0(15) . .
C5 C6 Ru1 C2 -100.9(15) . .
C1 C6 Ru1 N1 -26(2) . .
C5 C6 Ru1 N1 -154.3(12) . .
C1 C6 Ru1 C5 128(2) . .
C1 C6 Ru1 C4 107.8(17) . .
C5 C6 Ru1 C4 -20.1(14) . .
C5 C6 Ru1 C1 -128(2) . .
C2 C1 Ru1 O2 136(2) . .
C6 C1 Ru1 O2 1(3) . .
C7 C1 Ru1 O2 -121(3) . .
C2 C1 Ru1 C3 34.0(18) . .
C6 C1 Ru1 C3 -101.2(17) . .
C7 C1 Ru1 C3 138(3) . .
C2 C1 Ru1 O1 -145.4(17) . .
C6 C1 Ru1 O1 79.5(15) . .
C7 C1 Ru1 O1 -42(3) . .
C6 C1 Ru1 C2 -135(3) . .
C7 C1 Ru1 C2 104(4) . .
C2 C1 Ru1 N1 -59.8(19) . .
C6 C1 Ru1 N1 165.0(13) . .
C7 C1 Ru1 N1 44(3) . .
C2 C1 Ru1 C5 103.0(19) . .
C6 C1 Ru1 C5 -32.2(14) . .
C7 C1 Ru1 C5 -153(3) . .
C2 C1 Ru1 C4 74.7(18) . .
C6 C1 Ru1 C4 -60.5(16) . .
C7 C1 Ru1 C4 178(3) . .
C2 C1 Ru1 C6 135(3) . .
C7 C1 Ru1 C6 -121(3) . .
C27 N3 Ru2 O4 -139.3(11) . .
C31 N3 Ru2 O4 43.1(9) . .
C27 N3 Ru2 C14 25.5(15) . .
C31 N3 Ru2 C14 -152.2(11) . .
C27 N3 Ru2 C11 124.6(12) . .
C31 N3 Ru2 C11 -53.0(11) . .
C27 N3 Ru2 O3 -60.6(11) . .
C31 N3 Ru2 O3 121.8(9) . .
C27 N3 Ru2 C12 144.0(13) . .
C31 N3 Ru2 C12 -33.6(15) . .
C27 N3 Ru2 C13 41(4) . .
C31 N3 Ru2 C13 -137(4) . .
C27 N3 Ru2 C16 87.9(12) . .
C31 N3 Ru2 C16 -89.7(10) . .
C27 N3 Ru2 C15 49.4(12) . .
C31 N3 Ru2 C15 -128.2(10) . .
C34 O4 Ru2 N3 81.7(9) . .
C34 O4 Ru2 C14 -80.7(13) . .
C34 O4 Ru2 C11 -167.8(10) . .
C34 O4 Ru2 O3 -1.6(8) . .
C34 O4 Ru2 C12 -131.3(11) . .
C34 O4 Ru2 C13 -98.3(10) . .
C34 O4 Ru2 C16 169.7(11) . .
C34 O4 Ru2 C15 -146(3) . .
C15 C14 Ru2 N3 41.7(17) . .
C13 C14 Ru2 N3 175.6(10) . .
C18 C14 Ru2 N3 -72(2) . .
C15 C14 Ru2 O4 -162.4(12) . .
C13 C14 Ru2 O4 -28.5(17) . .
C18 C14 Ru2 O4 84(2) . .
C15 C14 Ru2 C11 -69.8(14) . .
C13 C14 Ru2 C11 64.1(13) . .
C18 C14 Ru2 C11 176(2) . .
C15 C14 Ru2 O3 123.5(14) . .
C13 C14 Ru2 O3 -102.6(12) . .
C18 C14 Ru2 O3 9(2) . .
C15 C14 Ru2 C12 -106.7(15) . .
C13 C14 Ru2 C12 27.3(12) . .
C18 C14 Ru2 C12 139(2) . .
C15 C14 Ru2 C13 -134(2) . .
C18 C14 Ru2 C13 112(2) . .
C15 C14 Ru2 C16 -30.2(13) . .
C13 C14 Ru2 C16 103.7(14) . .
C18 C14 Ru2 C16 -144(2) . .
C13 C14 Ru2 C15 134(2) . .
C18 C14 Ru2 C15 -114(3) . .
C12 C11 Ru2 N3 162.5(11) . .
C17 C11 Ru2 N3 48(2) . .
C16 C11 Ru2 N3 -66.4(12) . .
C12 C11 Ru2 O4 74.4(12) . .
C17 C11 Ru2 O4 -40(2) . .
C16 C11 Ru2 O4 -154.5(11) . .
C12 C11 Ru2 C14 -65.1(13) . .
C17 C11 Ru2 C14 -180(2) . .
C16 C11 Ru2 C14 66.0(13) . .
C12 C11 Ru2 O3 4(3) . .
C17 C11 Ru2 O3 -111(3) . .
C16 C11 Ru2 O3 135(2) . .
C17 C11 Ru2 C12 -115(2) . .
C16 C11 Ru2 C12 131.1(18) . .
C12 C11 Ru2 C13 -28.5(11) . .
C17 C11 Ru2 C13 -143(2) . .
C16 C11 Ru2 C13 102.6(13) . .
C12 C11 Ru2 C16 -131.1(18) . .
C17 C11 Ru2 C16 114(3) . .
C12 C11 Ru2 C15 -101.2(13) . .
C17 C11 Ru2 C15 144(2) . .
C16 C11 Ru2 C15 29.9(12) . .
C33 O3 Ru2 N3 -84.8(9) . .
C33 O3 Ru2 O4 2.3(9) . .
C33 O3 Ru2 C14 143.1(11) . .
C33 O3 Ru2 C11 75(3) . .
C33 O3 Ru2 C12 78.2(11) . .
C33 O3 Ru2 C13 105.4(10) . .
C33 O3 Ru2 C16 -165.5(14) . .
C33 O3 Ru2 C15 175.2(11) . .
C13 C12 Ru2 N3 -163.4(10) . .
C11 C12 Ru2 N3 -30.2(17) . .
C13 C12 Ru2 O4 120.1(12) . .
C11 C12 Ru2 O4 -106.8(12) . .
C13 C12 Ru2 C14 -27.7(12) . .
C11 C12 Ru2 C14 105.5(13) . .
C13 C12 Ru2 C11 -133.2(17) . .
C13 C12 Ru2 O3 48.0(13) . .
C11 C12 Ru2 O3 -178.8(10) . .
C11 C12 Ru2 C13 133.2(17) . .
C13 C12 Ru2 C16 -101.8(13) . .
C11 C12 Ru2 C16 31.4(12) . .
C13 C12 Ru2 C15 -62.9(12) . .
C11 C12 Ru2 C15 70.3(12) . .
C12 C13 Ru2 N3 117(4) . .
C14 C13 Ru2 N3 -19(4) . .
C12 C13 Ru2 O4 -63.2(12) . .
C14 C13 Ru2 O4 161.5(11) . .
C12 C13 Ru2 C14 135.3(18) . .
C12 C13 Ru2 C11 28.9(11) . .
C14 C13 Ru2 C11 -106.4(14) . .
C12 C13 Ru2 O3 -143.4(11) . .
C14 C13 Ru2 O3 81.3(12) . .
C14 C13 Ru2 C12 -135.3(18) . .
C12 C13 Ru2 C16 68.9(13) . .
C14 C13 Ru2 C16 -66.4(13) . .
C12 C13 Ru2 C15 107.7(13) . .
C14 C13 Ru2 C15 -27.6(12) . .
C15 C16 Ru2 N3 -107.1(12) . .
C11 C16 Ru2 N3 121.1(12) . .
C15 C16 Ru2 O4 167.5(10) . .
C11 C16 Ru2 O4 35.6(15) . .
C15 C16 Ru2 C14 28.1(13) . .
C11 C16 Ru2 C14 -103.8(14) . .
C15 C16 Ru2 C11 131.9(19) . .
C15 C16 Ru2 O3 -29(2) . .
C11 C16 Ru2 O3 -160.7(11) . .
C15 C16 Ru2 C12 102.4(14) . .
C11 C16 Ru2 C12 -29.5(12) . .
C15 C16 Ru2 C13 65.3(13) . .
C11 C16 Ru2 C13 -66.5(13) . .
C11 C16 Ru2 C15 -131.9(19) . .
C14 C15 Ru2 N3 -149.7(14) . .
C16 C15 Ru2 N3 77.7(13) . .
C14 C15 Ru2 O4 79(4) . .
C16 C15 Ru2 O4 -53(4) . .
C16 C15 Ru2 C14 -133(2) . .
C14 C15 Ru2 C11 102.0(15) . .
C16 C15 Ru2 C11 -30.7(14) . .
C14 C15 Ru2 O3 -63.2(15) . .
C16 C15 Ru2 O3 164.1(11) . .
C14 C15 Ru2 C12 64.4(15) . .
C16 C15 Ru2 C12 -68.2(13) . .
C14 C15 Ru2 C13 28.7(14) . .
C16 C15 Ru2 C13 -104.0(14) . .
C14 C15 Ru2 C16 133(2) . .
