#------------------------------------------------------------------------------
#$Date: 2016-03-26 02:00:26 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180118 $
#$URL: svn://www.crystallography.net/cod/cif/7/10/16/7101601.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7101601
loop_
_publ_author_name
'Chuan-Ming Jin'
'Jing Huang'
'Huan Lu'
'Ling-Yan Wu'
_publ_section_title
;A New Infinite Inorganic [n]Catenane From Silver and
Bis(2-methylimidazolyl)methane Ligand
;
_journal_issue                   48
_journal_name_full               'Chemical Communications'
_journal_paper_doi               10.1039/b612885h
_journal_year                    2006
_chemical_formula_sum            'C36 H48 Ag4 N20 O15'
_chemical_formula_weight         1432.42
_chemical_name_systematic
;
?
;
_space_group_IT_number           12
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2y'
_symmetry_space_group_name_H-M   'C 1 2/m 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 118.808(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   20.913(2)
_cell_length_b                   14.8336(15)
_cell_length_c                   18.2903(19)
_cell_measurement_reflns_used    5993
_cell_measurement_temperature    292(2)
_cell_measurement_theta_max      21.85
_cell_measurement_theta_min      2.44
_cell_volume                     4971.6(9)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      292(2)
_diffrn_measured_fraction_theta_full 0.982
_diffrn_measured_fraction_theta_max 0.982
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.1191
_diffrn_reflns_av_sigmaI/netI    0.0609
_diffrn_reflns_limit_h_max       24
_diffrn_reflns_limit_h_min       -24
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_number            23676
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         1.77
_exptl_absorpt_coefficient_mu    1.638
_exptl_absorpt_correction_T_max  0.7353
_exptl_absorpt_correction_T_min  0.6392
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.914
_exptl_crystal_density_meas      0
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       needle
_exptl_crystal_F_000             2848
_exptl_crystal_size_max          0.30
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.20
_refine_diff_density_max         1.012
_refine_diff_density_min         -1.158
_refine_diff_density_rms         0.141
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.008
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     366
_refine_ls_number_reflns         4483
_refine_ls_number_restraints     81
_refine_ls_restrained_S_all      1.016
_refine_ls_R_factor_all          0.1025
_refine_ls_R_factor_gt           0.0769
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1530P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2123
_refine_ls_wR_factor_ref         0.2341
_reflns_number_gt                2790
_reflns_number_total             4483
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b612885h.txt
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_sg_symbol_H-M      C2/m
_cod_database_code               7101601
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z'
'-x, -y, -z'
'x, -y, z'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ag1 Ag 0.69786(6) 0.5000 0.93718(6) 0.1312(5) Uani 1 2 d S
Ag2 Ag 0.5000 0.87708(8) 0.5000 0.1881(9) Uani 1 2 d S
Ag3 Ag 0.5000 0.63062(6) 0.5000 0.1131(4) Uani 1 2 d S
Ag4 Ag 0.61766(7) 1.0000 0.18220(7) 0.1378(5) Uani 1 2 d S
C1 C 0.7447(5) 0.6764(8) 0.8484(6) 0.133(3) Uani 1 1 d .
H1A H 0.7855 0.6405 0.8861 0.199 Uiso 1 1 calc R
H1B H 0.7620 0.7317 0.8369 0.199 Uiso 1 1 calc R
H1C H 0.7167 0.6438 0.7974 0.199 Uiso 1 1 calc R
C2 C 0.6967(4) 0.6975(5) 0.8879(4) 0.0874(17) Uani 1 1 d .
C3 C 0.6414(4) 0.6854(6) 0.9581(4) 0.0955(19) Uani 1 1 d .
H3 H 0.6216 0.6604 0.9894 0.115 Uiso 1 1 calc R
C4 C 0.6338(4) 0.7675(6) 0.9346(5) 0.0948(19) Uani 1 1 d .
H4 H 0.6097 0.8124 0.9473 0.114 Uiso 1 1 calc R
C5 C 0.6688(5) 0.8618(5) 0.8457(5) 0.101(2) Uani 1 1 d .
H5A H 0.6684 0.9126 0.8789 0.121 Uiso 1 1 calc R
H5B H 0.7134 0.8649 0.8419 0.121 Uiso 1 1 calc R
C6 C 0.6675(9) 0.8437(12) 0.6740(9) 0.204(7) Uani 1 1 d .
H6A H 0.6583 0.8680 0.6211 0.306 Uiso 1 1 calc R
H6B H 0.6752 0.7798 0.6746 0.306 Uiso 1 1 calc R
H6C H 0.7102 0.8717 0.7178 0.306 Uiso 1 1 calc R
C7 C 0.6044(8) 0.8616(6) 0.6868(6) 0.128(3) Uani 1 1 d .
C8 C 0.5359(6) 0.8786(7) 0.7468(6) 0.134(4) Uani 1 1 d .
H8 H 0.5189 0.8798 0.7853 0.161 Uiso 1 1 calc R
C9 C 0.4979(8) 0.8863(7) 0.6665(6) 0.153(5) Uani 1 1 d .
H9 H 0.4481 0.8985 0.6380 0.184 Uiso 1 1 calc R
C10 C 0.6499(6) 0.6625(14) 0.4700(6) 0.215(8) Uani 1 1 d .
H10A H 0.6461 0.7157 0.4975 0.323 Uiso 1 1 calc R
H10B H 0.6871 0.6710 0.4541 0.323 Uiso 1 1 calc R
H10C H 0.6624 0.6120 0.5072 0.323 Uiso 1 1 calc R
C11 C 0.5799(4) 0.6453(6) 0.3954(4) 0.097(2) Uani 1 1 d .
C12 C 0.4661(5) 0.6240(6) 0.3135(6) 0.117(3) Uani 1 1 d .
H12 H 0.4165 0.6159 0.2947 0.141 Uiso 1 1 calc R
C13 C 0.4957(5) 0.6262(6) 0.2654(5) 0.114(3) Uani 1 1 d .
H13 H 0.4719 0.6211 0.2076 0.137 Uiso 1 1 calc R
C14 C 0.6264(6) 0.6433(8) 0.2908(6) 0.142(4) Uani 1 1 d .
H14A H 0.6739 0.6471 0.3401 0.171 Uiso 1 1 calc R
H14B H 0.6254 0.5892 0.2605 0.171 Uiso 1 1 calc R
C15 C 0.6885(7) 0.8331(12) 0.3462(6) 0.191(6) Uani 1 1 d .
H15A H 0.7195 0.8819 0.3483 0.287 Uiso 1 1 calc R
H15B H 0.7177 0.7809 0.3724 0.287 Uiso 1 1 calc R
H15C H 0.6622 0.8501 0.3749 0.287 Uiso 1 1 calc R
C16 C 0.6356(5) 0.8119(11) 0.2572(5) 0.129(4) Uani 1 1 d .
C17 C 0.5691(5) 0.8027(10) 0.1229(5) 0.134(4) Uani 1 1 d .
H17 H 0.5456 0.8213 0.0675 0.160 Uiso 1 1 calc R
C18 C 0.5687(6) 0.7213(9) 0.1481(5) 0.132(3) Uani 1 1 d .
H18 H 0.5435 0.6720 0.1154 0.158 Uiso 1 1 calc R
N1 N 0.6829(4) 0.6388(4) 0.9305(4) 0.0998(18) Uani 1 1 d .
N2 N 0.6677(3) 0.7773(4) 0.8872(3) 0.0842(14) Uani 1 1 d .
N3 N 0.6067(4) 0.8681(3) 0.7630(3) 0.0927(17) Uani 1 1 d .
N4 N 0.5397(6) 0.8745(4) 0.6292(4) 0.135(3) Uani 1 1 d .
N5 N 0.5173(3) 0.6350(4) 0.3952(4) 0.0957(17) Uani 1 1 d .
N6 N 0.5687(4) 0.6374(4) 0.3163(4) 0.1009(18) Uani 1 1 d .
N7 N 0.6154(5) 0.7226(8) 0.2377(5) 0.130(3) Uani 1 1 d .
N8 N 0.6105(4) 0.8591(6) 0.1918(5) 0.122(2) Uani 1 1 d .
N9 N 0.6609(5) 0.5000 0.1222(7) 0.116(3) Uani 1 2 d SDU
N10 N 0.6903(6) 1.0000 0.5292(7) 0.123(3) Uani 1 2 d SDU
N11 N 0.3346(10) 0.5000 0.3468(12) 0.143(4) Uani 1 2 d SU
N12 N 0.5983(5) 1.0000 0.9849(5) 0.081(2) Uani 1 2 d S
O1 O 0.6810(12) 0.5000 0.1966(9) 0.318(12) Uani 1 2 d SDU
O2 O 0.7053(8) 0.5000 0.0979(9) 0.199(5) Uani 1 2 d SDU
O3 O 0.5961(7) 0.5000 0.0729(14) 0.47(2) Uani 1 2 d SDU
O4 O 0.7522(6) 1.0000 0.5833(8) 0.177(4) Uani 1 2 d SDU
O5 O 0.6240(7) 1.0000 0.4925(12) 0.234(7) Uani 1 2 d SDU
O6 O 0.6783(8) 0.9194(6) 0.5104(7) 0.223(5) Uani 1 1 d DU
O7 O 0.3849(9) 0.5000 0.4149(10) 0.194(5) Uani 1 2 d SU
O8 O 0.2883(11) 0.5000 0.2785(13) 0.218(6) Uani 1 2 d SU
O9 O 0.3335(9) 0.4044(11) 0.3505(8) 0.241(5) Uani 1 1 d U
O13 O 0.4795(9) 0.5000 0.0870(9) 0.207(6) Uani 1 2 d S
O11 O 0.6109(15) 1.0000 0.9351(11) 0.280(13) Uani 1 2 d S
O12 O 0.6030(13) 0.9488(8) 1.0269(9) 0.330(11) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N1 Ag1 N1 164.8(4) . 6_565
N4 Ag2 N4 177.9(4) 2_656 .
N5 Ag3 N5 176.5(3) . 2_656
N8 Ag4 N8 164.7(4) . 6_575
C2 C1 H1A 109.5 . .
C2 C1 H1B 109.5 . .
H1A C1 H1B 109.5 . .
C2 C1 H1C 109.5 . .
H1A C1 H1C 109.5 . .
H1B C1 H1C 109.5 . .
N1 C2 N2 111.9(7) . .
N1 C2 C1 122.5(8) . .
N2 C2 C1 125.5(8) . .
C4 C3 N1 110.6(7) . .
C4 C3 H3 124.7 . .
N1 C3 H3 124.7 . .
C3 C4 N2 107.3(7) . .
C3 C4 H4 126.4 . .
N2 C4 H4 126.4 . .
N3 C5 N2 111.4(5) . .
N3 C5 H5A 109.4 . .
N2 C5 H5A 109.4 . .
N3 C5 H5B 109.4 . .
N2 C5 H5B 109.4 . .
H5A C5 H5B 108.0 . .
C7 C6 H6A 109.5 . .
C7 C6 H6B 109.5 . .
H6A C6 H6B 109.5 . .
C7 C6 H6C 109.5 . .
H6A C6 H6C 109.5 . .
H6B C6 H6C 109.5 . .
N4 C7 N3 109.6(11) . .
N4 C7 C6 125.1(10) . .
N3 C7 C6 125.3(12) . .
C9 C8 N3 105.3(11) . .
C9 C8 H8 127.3 . .
N3 C8 H8 127.3 . .
C8 C9 N4 111.4(11) . .
C8 C9 H9 124.3 . .
N4 C9 H9 124.3 . .
C11 C10 H10A 109.5 . .
C11 C10 H10B 109.5 . .
H10A C10 H10B 109.5 . .
C11 C10 H10C 109.5 . .
H10A C10 H10C 109.5 . .
H10B C10 H10C 109.5 . .
N5 C11 N6 109.0(6) . .
N5 C11 C10 124.7(7) . .
N6 C11 C10 126.3(8) . .
C13 C12 N5 111.1(8) . .
C13 C12 H12 124.4 . .
N5 C12 H12 124.4 . .
C12 C13 N6 106.5(8) . .
C12 C13 H13 126.8 . .
N6 C13 H13 126.8 . .
N7 C14 N6 111.2(6) . .
N7 C14 H14A 109.4 . .
N6 C14 H14A 109.4 . .
N7 C14 H14B 109.4 . .
N6 C14 H14B 109.4 . .
H14A C14 H14B 108.0 . .
C16 C15 H15A 109.5 . .
C16 C15 H15B 109.5 . .
H15A C15 H15B 109.5 . .
C16 C15 H15C 109.5 . .
H15A C15 H15C 109.5 . .
H15B C15 H15C 109.5 . .
N8 C16 N7 110.6(9) . .
N8 C16 C15 131.8(15) . .
N7 C16 C15 117.1(12) . .
C18 C17 N8 110.0(8) . .
C18 C17 H17 125.0 . .
N8 C17 H17 125.0 . .
C17 C18 N7 105.9(10) . .
C17 C18 H18 127.1 . .
N7 C18 H18 127.1 . .
C2 N1 C3 104.2(6) . .
C2 N1 Ag1 129.3(6) . .
C3 N1 Ag1 125.2(6) . .
C2 N2 C4 105.9(6) . .
C2 N2 C5 130.1(6) . .
C4 N2 C5 124.0(6) . .
C8 N3 C7 106.3(8) . .
C8 N3 C5 124.4(7) . .
C7 N3 C5 129.2(9) . .
C7 N4 C9 106.9(8) . .
C7 N4 Ag2 128.7(9) . .
C9 N4 Ag2 124.3(8) . .
C11 N5 C12 105.7(7) . .
C11 N5 Ag3 127.2(5) . .
C12 N5 Ag3 127.0(6) . .
C11 N6 C13 107.6(7) . .
C11 N6 C14 125.4(7) . .
C13 N6 C14 127.0(7) . .
C16 N7 C18 105.1(9) . .
C16 N7 C14 131.6(9) . .
C18 N7 C14 122.8(11) . .
C16 N8 C17 108.3(10) . .
C16 N8 Ag4 128.0(9) . .
C17 N8 Ag4 123.4(7) . .
O2 N9 O3 120.4(9) . .
O2 N9 O1 120.0(9) . .
O3 N9 O1 119.6(9) . .
O4 N10 O5 162.3(16) . .
O4 N10 O6 103.0(9) . 6_575
O5 N10 O6 79.7(9) . 6_575
O4 N10 O6 103.0(9) . .
O5 N10 O6 79.7(9) . .
O6 N10 O6 150.6(17) 6_575 .
O8 N11 O7 176.0(18) . .
O8 N11 O9 91.6(11) . 6_565
O7 N11 O9 88.7(11) . 6_565
O8 N11 O9 91.6(11) . .
O7 N11 O9 88.7(11) . .
O9 N11 O9 173.4(15) 6_565 .
O12 N12 O12 92.7(15) . 6_575
O12 N12 O11 130.6(10) . .
O12 N12 O11 130.6(10) 6_575 .
N10 O5 O6 50.7(5) . 6_575
N12 O12 O12 43.7(7) . 6_575
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 N1 2.077(6) .
Ag1 N1 2.077(6) 6_565
Ag2 N4 2.095(7) 2_656
Ag2 N4 2.095(7) .
Ag3 N5 2.116(6) .
Ag3 N5 2.116(6) 2_656
Ag4 N8 2.109(8) .
Ag4 N8 2.109(8) 6_575
C1 C2 1.524(11) .
C1 H1A 0.9600 .
C1 H1B 0.9600 .
C1 H1C 0.9600 .
C2 N1 1.289(10) .
C2 N2 1.327(9) .
C3 C4 1.276(10) .
C3 N1 1.383(10) .
C3 H3 0.9300 .
C4 N2 1.366(9) .
C4 H4 0.9300 .
C5 N3 1.445(10) .
C5 N2 1.472(9) .
C5 H5A 0.9700 .
C5 H5B 0.9700 .
C6 C7 1.472(19) .
C6 H6A 0.9600 .
C6 H6B 0.9600 .
C6 H6C 0.9600 .
C7 N4 1.265(14) .
C7 N3 1.373(10) .
C8 C9 1.296(13) .
C8 N3 1.372(13) .
C8 H8 0.9300 .
C9 N4 1.355(16) .
C9 H9 0.9300 .
C10 C11 1.464(13) .
C10 H10A 0.9600 .
C10 H10B 0.9600 .
C10 H10C 0.9600 .
C11 N5 1.316(9) .
C11 N6 1.354(9) .
C12 C13 1.296(14) .
C12 N5 1.366(11) .
C12 H12 0.9300 .
C13 N6 1.361(11) .
C13 H13 0.9300 .
C14 N7 1.470(13) .
C14 N6 1.492(11) .
C14 H14A 0.9700 .
C14 H14B 0.9700 .
C15 C16 1.495(13) .
C15 H15A 0.9600 .
C15 H15B 0.9600 .
C15 H15C 0.9600 .
C16 N8 1.261(13) .
C16 N7 1.383(15) .
C17 C18 1.295(15) .
C17 N8 1.409(13) .
C17 H17 0.9300 .
C18 N7 1.448(12) .
C18 H18 0.9300 .
N9 O2 1.208(7) .
N9 O3 1.213(8) .
N9 O1 1.215(8) .
N10 O4 1.192(8) .
N10 O5 1.215(9) .
N10 O6 1.235(8) 6_575
N10 O6 1.235(8) .
N11 O8 1.15(2) .
N11 O7 1.181(19) .
N11 O9 1.421(16) 6_565
N11 O9 1.421(16) .
N12 O12 1.050(11) .
N12 O12 1.050(11) 6_575
N12 O11 1.063(12) .
O5 O6 1.570(16) 6_575
O12 O12 1.52(2) 6_575
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
C1 H1A O12 0.96 2.48 3.43(2) 173.5 7_667
C1 H1C O8 0.96 2.52 3.342(15) 143.7 2_656
C1 H1C O9 0.96 2.49 3.409(17) 160.4 5_666
C5 H5B O2 0.97 2.51 3.095(14) 118.4 4_656
C10 H10C O9 0.96 2.57 3.283(15) 131.0 5_666
C12 H12 O9 0.93 2.42 3.185(18) 139.5 6_565
C15 H15A O9 0.96 2.39 3.18(2) 139.0 3
C17 H17 O12 0.93 2.54 3.080(18) 117.6 1_554
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
N1 C3 C4 N2 2.6(8) . .
N3 C8 C9 N4 4.7(13) . .
N5 C12 C13 N6 1.1(10) . .
N8 C17 C18 N7 -3.3(11) . .
N2 C2 N1 C3 0.5(8) . .
C1 C2 N1 C3 177.2(7) . .
N2 C2 N1 Ag1 168.3(4) . .
C1 C2 N1 Ag1 -15.0(10) . .
C4 C3 N1 C2 -2.0(8) . .
C4 C3 N1 Ag1 -170.4(5) . .
N1 Ag1 N1 C2 -117.2(15) 6_565 .
N1 Ag1 N1 C3 48.3(18) 6_565 .
N1 C2 N2 C4 1.0(7) . .
C1 C2 N2 C4 -175.6(7) . .
N1 C2 N2 C5 -178.8(6) . .
C1 C2 N2 C5 4.5(11) . .
C3 C4 N2 C2 -2.2(8) . .
C3 C4 N2 C5 177.7(6) . .
N3 C5 N2 C2 90.7(9) . .
N3 C5 N2 C4 -89.1(8) . .
C9 C8 N3 C7 -5.8(11) . .
C9 C8 N3 C5 176.5(7) . .
N4 C7 N3 C8 5.0(10) . .
C6 C7 N3 C8 -175.7(11) . .
N4 C7 N3 C5 -177.4(7) . .
C6 C7 N3 C5 1.9(14) . .
N2 C5 N3 C8 68.5(10) . .
N2 C5 N3 C7 -108.7(8) . .
N3 C7 N4 C9 -2.2(10) . .
C6 C7 N4 C9 178.6(11) . .
N3 C7 N4 Ag2 178.2(5) . .
C6 C7 N4 Ag2 -1.0(15) . .
C8 C9 N4 C7 -1.7(13) . .
C8 C9 N4 Ag2 177.9(7) . .
N4 Ag2 N4 C7 79.7(8) 2_656 .
N4 Ag2 N4 C9 -99.8(8) 2_656 .
N6 C11 N5 C12 -2.3(9) . .
C10 C11 N5 C12 177.7(12) . .
N6 C11 N5 Ag3 175.2(5) . .
C10 C11 N5 Ag3 -4.8(15) . .
C13 C12 N5 C11 0.8(10) . .
C13 C12 N5 Ag3 -176.7(6) . .
N5 Ag3 N5 C11 82.9(7) 2_656 .
N5 Ag3 N5 C12 -100.1(7) 2_656 .
N5 C11 N6 C13 3.0(9) . .
C10 C11 N6 C13 -177.0(12) . .
N5 C11 N6 C14 -178.9(8) . .
C10 C11 N6 C14 1.0(15) . .
C12 C13 N6 C11 -2.5(9) . .
C12 C13 N6 C14 179.5(8) . .
N7 C14 N6 C11 -114.7(9) . .
N7 C14 N6 C13 63.0(13) . .
N8 C16 N7 C18 -3.5(10) . .
C15 C16 N7 C18 -176.3(9) . .
N8 C16 N7 C14 -175.3(8) . .
C15 C16 N7 C14 11.9(14) . .
C17 C18 N7 C16 4.1(10) . .
C17 C18 N7 C14 176.8(8) . .
N6 C14 N7 C16 84.1(12) . .
N6 C14 N7 C18 -86.4(11) . .
N7 C16 N8 C17 1.6(10) . .
C15 C16 N8 C17 173.0(11) . .
N7 C16 N8 Ag4 176.0(5) . .
C15 C16 N8 Ag4 -12.6(15) . .
C18 C17 N8 C16 1.2(11) . .
C18 C17 N8 Ag4 -173.5(7) . .
N8 Ag4 N8 C16 -59(2) 6_575 .
N8 Ag4 N8 C17 115.2(16) 6_575 .
O4 N10 O5 O6 100.5(7) . 6_575
O6 N10 O5 O6 -158.9(14) . 6_575
O11 N12 O12 O12 154(4) . 6_575
