#------------------------------------------------------------------------------
#$Date: 2016-03-26 02:06:25 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180123 $
#$URL: svn://www.crystallography.net/cod/cif/7/10/21/7102119.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7102119
loop_
_publ_author_name
'Feng, Yuhua'
'Guo, Yang'
'OuYang, Yan'
'Liu, Zhanquan'
'Liao, Daizheng'
'Cheng, Peng'
'Yan, Shiping'
'Jiang, Zonghui'
_publ_section_title
;
 2D warp-and-woof interwoven networks constructed by helical chains
 with different chirality.
;
_journal_issue                   35
_journal_name_full
'Chemical communications (Cambridge, England)'
_journal_page_first              3643
_journal_page_last               3645
_journal_paper_doi               10.1039/b707356a
_journal_year                    2007
_chemical_formula_sum            'C28 H36 Ag2 Mn2 N8 O4'
_chemical_formula_weight         874.27
_chemical_name_systematic
;
?
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 105.690(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   20.388(4)
_cell_length_b                   20.161(4)
_cell_length_c                   17.384(3)
_cell_measurement_reflns_used    3578
_cell_measurement_temperature    294(2)
_cell_measurement_theta_max      22.86
_cell_measurement_theta_min      2.36
_cell_volume                     6880(2)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      294(2)
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0405
_diffrn_reflns_av_sigmaI/netI    0.0503
_diffrn_reflns_limit_h_max       24
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       23
_diffrn_reflns_limit_k_min       -21
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            17294
_diffrn_reflns_theta_full        25.01
_diffrn_reflns_theta_max         25.01
_diffrn_reflns_theta_min         1.45
_exptl_absorpt_coefficient_mu    1.883
_exptl_absorpt_correction_T_max  0.7527
_exptl_absorpt_correction_T_min  0.6821
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_density_diffrn    1.688
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             3488
_exptl_crystal_size_max          0.22
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.16
_refine_diff_density_max         0.281
_refine_diff_density_min         -0.353
_refine_diff_density_rms         0.063
_refine_ls_extinction_coef       0.00049(2)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.029
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     407
_refine_ls_number_reflns         6047
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.029
_refine_ls_R_factor_all          0.0881
_refine_ls_R_factor_gt           0.0346
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0260P)²+5.3227P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0661
_refine_ls_wR_factor_ref         0.0857
_reflns_number_gt                3367
_reflns_number_total             6047
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b707356a.txt
_cod_data_source_block           060519d
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from
2010-06-29.

'_exptl_absorpt_correction_type' value 'MULTI-SCAN' changed
to 'multi-scan' according to
'/home/saulius/struct/CIF-dictionaries/cif_core.dic' dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 

The following automatic conversions were performed:

'_exptl_crystal_density_meas' value 'none' was changed to '?' - the
value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 3008 2015-01-20 13:52:24Z robertas 
;
_cod_original_sg_symbol_H-M      C2/c
_cod_database_code               7102119
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ag1 Ag 0.27363(2) 0.18608(2) 0.34553(2) 0.08083(17) Uani 1 1 d .
Ag2 Ag 0.228289(19) 0.19120(2) 0.16063(2) 0.08116(17) Uani 1 1 d .
Mn1 Mn 0.23751(3) -0.06550(4) 0.25883(4) 0.0519(2) Uani 1 1 d .
Mn2 Mn 0.0000 0.20382(5) 0.2500 0.0565(3) Uani 1 2 d S
Mn3 Mn 0.5000 0.18295(5) 0.2500 0.0554(3) Uani 1 2 d S
O1 O 0.28821(14) -0.02893(15) 0.19144(18) 0.0610(8) Uani 1 1 d .
O2 O 0.31780(13) -0.10354(15) 0.32777(18) 0.0621(8) Uani 1 1 d .
O3 O 0.05271(15) 0.13796(15) 0.31905(19) 0.0652(9) Uani 1 1 d .
O4 O 0.48176(14) 0.24946(15) 0.31959(18) 0.0634(9) Uani 1 1 d .
N1 N 0.2563(2) 0.0289(2) 0.3362(2) 0.0727(12) Uani 1 1 d .
N2 N 0.0756(2) 0.2029(2) 0.1726(3) 0.0789(13) Uani 1 1 d .
N3 N 0.3876(2) 0.1812(2) 0.1774(2) 0.0713(12) Uani 1 1 d .
N4 N 0.28231(19) 0.3414(2) 0.3203(2) 0.0701(12) Uani 1 1 d .
N5 N 0.17885(17) -0.10413(19) 0.3218(2) 0.0578(10) Uani 1 1 d .
N6 N 0.15095(17) -0.02574(19) 0.1954(2) 0.0600(10) Uani 1 1 d .
N7 N 0.0545(2) 0.2774(2) 0.3122(3) 0.0714(12) Uani 1 1 d .
N8 N 0.47750(19) 0.1099(2) 0.3152(3) 0.0701(12) Uani 1 1 d .
C1 C 0.2637(2) 0.0841(3) 0.3450(3) 0.0669(14) Uani 1 1 d .
C2 C 0.1281(3) 0.1988(2) 0.1633(3) 0.0680(14) Uani 1 1 d .
C3 C 0.3305(3) 0.1830(2) 0.1663(3) 0.0655(14) Uani 1 1 d .
C4 C 0.2814(2) 0.2871(3) 0.3359(3) 0.0635(14) Uani 1 1 d .
C5 C 0.3156(3) 0.0160(2) 0.0783(3) 0.0820(16) Uani 1 1 d .
H5A H 0.3446 0.0517 0.1035 0.123 Uiso 1 1 calc R
H5B H 0.2922 0.0282 0.0245 0.123 Uiso 1 1 calc R
H5C H 0.3427 -0.0229 0.0776 0.123 Uiso 1 1 calc R
C6 C 0.2641(3) 0.0015(2) 0.1244(3) 0.0579(12) Uani 1 1 d .
C7 C 0.1974(3) 0.0208(2) 0.0950(3) 0.0723(15) Uani 1 1 d .
H7 H 0.1864 0.0441 0.0470 0.087 Uiso 1 1 calc R
C8 C 0.1439(2) 0.0089(2) 0.1306(3) 0.0642(14) Uani 1 1 d .
C9 C 0.0743(3) 0.0390(3) 0.0877(3) 0.101(2) Uani 1 1 d .
H9A H 0.0426 0.0040 0.0665 0.151 Uiso 1 1 calc R
H9B H 0.0791 0.0670 0.0449 0.151 Uiso 1 1 calc R
H9C H 0.0577 0.0647 0.1250 0.151 Uiso 1 1 calc R
C10 C 0.0949(2) -0.0338(3) 0.2332(3) 0.0908(18) Uani 1 1 d .
H10A H 0.0517 -0.0356 0.1925 0.109 Uiso 1 1 calc R
H10B H 0.0939 0.0037 0.2678 0.109 Uiso 1 1 calc R
C11 C 0.1057(2) -0.0964(3) 0.2808(3) 0.0882(18) Uani 1 1 d .
H11A H 0.0796 -0.0951 0.3199 0.106 Uiso 1 1 calc R
H11B H 0.0901 -0.1340 0.2458 0.106 Uiso 1 1 calc R
C12 C 0.1485(3) -0.1678(3) 0.4289(3) 0.0865(17) Uani 1 1 d .
H12A H 0.1245 -0.1327 0.4470 0.130 Uiso 1 1 calc R
H12B H 0.1727 -0.1940 0.4737 0.130 Uiso 1 1 calc R
H12C H 0.1166 -0.1953 0.3917 0.130 Uiso 1 1 calc R
C13 C 0.1992(3) -0.1380(2) 0.3877(3) 0.0601(13) Uani 1 1 d .
C14 C 0.2692(3) -0.1497(2) 0.4247(3) 0.0621(13) Uani 1 1 d .
H14 H 0.2797 -0.1715 0.4736 0.075 Uiso 1 1 calc R
C15 C 0.3229(2) -0.1322(2) 0.3961(3) 0.0549(12) Uani 1 1 d .
C16 C 0.3949(2) -0.1455(3) 0.4441(3) 0.0794(15) Uani 1 1 d .
H16A H 0.4157 -0.1766 0.4160 0.119 Uiso 1 1 calc R
H16B H 0.3948 -0.1636 0.4951 0.119 Uiso 1 1 calc R
H16C H 0.4203 -0.1048 0.4517 0.119 Uiso 1 1 calc R
C17 C 0.1238(2) 0.0870(3) 0.4334(3) 0.0885(17) Uani 1 1 d .
H17A H 0.0855 0.0633 0.4418 0.133 Uiso 1 1 calc R
H17B H 0.1538 0.0994 0.4841 0.133 Uiso 1 1 calc R
H17C H 0.1478 0.0592 0.4053 0.133 Uiso 1 1 calc R
C18 C 0.0991(2) 0.1486(3) 0.3849(3) 0.0621(13) Uani 1 1 d .
C19 C 0.1267(2) 0.2093(3) 0.4119(3) 0.0738(15) Uani 1 1 d .
H19 H 0.1621 0.2096 0.4586 0.089 Uiso 1 1 calc R
C20 C 0.1062(3) 0.2707(3) 0.3753(4) 0.0772(17) Uani 1 1 d .
C21 C 0.1469(3) 0.3318(3) 0.4137(3) 0.106(2) Uani 1 1 d .
H21A H 0.1604 0.3568 0.3735 0.159 Uiso 1 1 calc R
H21B H 0.1867 0.3178 0.4540 0.159 Uiso 1 1 calc R
H21C H 0.1191 0.3590 0.4375 0.159 Uiso 1 1 calc R
C22 C 0.0368(3) 0.3418(3) 0.2720(4) 0.108(2) Uani 1 1 d .
H22A H 0.0641 0.3492 0.2349 0.130 Uiso 1 1 calc R
H22B H 0.0461 0.3772 0.3111 0.130 Uiso 1 1 calc R
C23 C 0.4646(2) 0.3027(3) 0.4335(3) 0.0895(18) Uani 1 1 d .
H23A H 0.5067 0.3265 0.4409 0.134 Uiso 1 1 calc R
H23B H 0.4582 0.2916 0.4847 0.134 Uiso 1 1 calc R
H23C H 0.4275 0.3300 0.4046 0.134 Uiso 1 1 calc R
C24 C 0.4669(2) 0.2403(3) 0.3872(3) 0.0602(13) Uani 1 1 d .
C25 C 0.4543(2) 0.1801(3) 0.4152(3) 0.0805(17) Uani 1 1 d .
H25 H 0.4420 0.1802 0.4629 0.097 Uiso 1 1 calc R
C26 C 0.4576(2) 0.1181(3) 0.3809(4) 0.0724(16) Uani 1 1 d .
C27 C 0.4379(3) 0.0564(3) 0.4212(4) 0.121(3) Uani 1 1 d .
H27A H 0.4036 0.0320 0.3831 0.182 Uiso 1 1 calc R
H27B H 0.4205 0.0698 0.4649 0.182 Uiso 1 1 calc R
H27C H 0.4774 0.0289 0.4409 0.182 Uiso 1 1 calc R
C28 C 0.4759(3) 0.0455(3) 0.2753(3) 0.111(2) Uani 1 1 d .
H28A H 0.4301 0.0366 0.2425 0.133 Uiso 1 1 calc R
H28B H 0.4884 0.0107 0.3151 0.133 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Mn Mn 0.3368 0.7283 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C4 Ag1 C1 175.25(19) . .
C4 Ag1 Ag2 83.69(13) . .
C1 Ag1 Ag2 91.57(14) . .
C2 Ag2 C3 176.08(18) . .
C2 Ag2 Ag1 89.91(13) . .
C3 Ag2 Ag1 86.18(13) . .
O1 Mn1 O2 91.48(13) . .
O1 Mn1 N6 92.91(15) . .
O2 Mn1 N6 175.06(15) . .
O1 Mn1 N5 175.73(14) . .
O2 Mn1 N5 92.19(15) . .
N6 Mn1 N5 83.52(17) . .
O1 Mn1 N4 89.12(14) . 4_545
O2 Mn1 N4 91.71(14) . 4_545
N6 Mn1 N4 90.64(14) . 4_545
N5 Mn1 N4 88.58(15) . 4_545
O1 Mn1 N1 90.40(14) . .
O2 Mn1 N1 89.23(14) . .
N6 Mn1 N1 88.46(15) . .
N5 Mn1 N1 91.84(15) . .
N4 Mn1 N1 178.95(16) 4_545 .
O3 Mn2 O3 92.1(2) 2 .
O3 Mn2 N7 174.40(16) 2 .
O3 Mn2 N7 92.28(17) . .
O3 Mn2 N7 92.28(17) 2 2
O3 Mn2 N7 174.41(16) . 2
N7 Mn2 N7 83.5(3) . 2
O3 Mn2 N2 88.80(14) 2 .
O3 Mn2 N2 90.55(14) . .
N7 Mn2 N2 87.70(15) . .
N7 Mn2 N2 93.00(16) 2 .
O3 Mn2 N2 90.55(14) 2 2
O3 Mn2 N2 88.80(14) . 2
N7 Mn2 N2 93.01(16) . 2
N7 Mn2 N2 87.70(15) 2 2
N2 Mn2 N2 179.1(2) . 2
O4 Mn3 O4 90.73(19) . 2_655
O4 Mn3 N8 175.69(16) . 2_655
O4 Mn3 N8 92.59(17) 2_655 2_655
O4 Mn3 N8 92.59(17) . .
O4 Mn3 N8 175.70(16) 2_655 .
N8 Mn3 N8 84.2(3) 2_655 .
O4 Mn3 N3 89.93(13) . 2_655
O4 Mn3 N3 91.27(14) 2_655 2_655
N8 Mn3 N3 87.26(15) 2_655 2_655
N8 Mn3 N3 91.47(15) . 2_655
O4 Mn3 N3 91.27(14) . .
O4 Mn3 N3 89.93(13) 2_655 .
N8 Mn3 N3 91.47(15) 2_655 .
N8 Mn3 N3 87.26(15) . .
N3 Mn3 N3 178.3(2) 2_655 .
C6 O1 Mn1 126.9(3) . .
C15 O2 Mn1 126.6(3) . .
C18 O3 Mn2 126.5(3) . .
C24 O4 Mn3 127.2(3) . .
C1 N1 Mn1 152.9(5) . .
C2 N2 Mn2 153.5(4) . .
C3 N3 Mn3 157.4(4) . .
C4 N4 Mn1 157.5(4) . 4
C13 N5 C11 121.4(4) . .
C13 N5 Mn1 126.5(3) . .
C11 N5 Mn1 111.9(3) . .
C8 N6 C10 121.9(4) . .
C8 N6 Mn1 125.0(3) . .
C10 N6 Mn1 112.9(3) . .
C20 N7 C22 121.9(5) . .
C20 N7 Mn2 125.8(4) . .
C22 N7 Mn2 111.7(4) . .
C26 N8 C28 123.1(5) . .
C26 N8 Mn3 124.9(4) . .
C28 N8 Mn3 111.5(4) . .
N1 C1 Ag1 172.7(5) . .
N2 C2 Ag2 173.3(5) . .
N3 C3 Ag2 172.6(4) . .
N4 C4 Ag1 171.1(5) . .
C6 C5 H5A 109.5 . .
C6 C5 H5B 109.5 . .
H5A C5 H5B 109.5 . .
C6 C5 H5C 109.5 . .
H5A C5 H5C 109.5 . .
H5B C5 H5C 109.5 . .
O1 C6 C7 124.6(5) . .
O1 C6 C5 114.9(4) . .
C7 C6 C5 120.5(5) . .
C6 C7 C8 126.3(5) . .
C6 C7 H7 116.8 . .
C8 C7 H7 116.8 . .
N6 C8 C7 123.6(4) . .
N6 C8 C9 120.2(5) . .
C7 C8 C9 116.2(5) . .
C8 C9 H9A 109.5 . .
C8 C9 H9B 109.5 . .
H9A C9 H9B 109.5 . .
C8 C9 H9C 109.5 . .
H9A C9 H9C 109.5 . .
H9B C9 H9C 109.5 . .
N6 C10 C11 109.0(4) . .
N6 C10 H10A 109.9 . .
C11 C10 H10A 109.9 . .
N6 C10 H10B 109.9 . .
C11 C10 H10B 109.9 . .
H10A C10 H10B 108.3 . .
N5 C11 C10 109.5(4) . .
N5 C11 H11A 109.8 . .
C10 C11 H11A 109.8 . .
N5 C11 H11B 109.8 . .
C10 C11 H11B 109.8 . .
H11A C11 H11B 108.2 . .
C13 C12 H12A 109.5 . .
C13 C12 H12B 109.5 . .
H12A C12 H12B 109.5 . .
C13 C12 H12C 109.5 . .
H12A C12 H12C 109.5 . .
H12B C12 H12C 109.5 . .
N5 C13 C14 122.0(4) . .
N5 C13 C12 121.5(5) . .
C14 C13 C12 116.5(5) . .
C15 C14 C13 126.8(4) . .
C15 C14 H14 116.6 . .
C13 C14 H14 116.6 . .
O2 C15 C14 125.0(4) . .
O2 C15 C16 114.3(4) . .
C14 C15 C16 120.7(5) . .
C15 C16 H16A 109.5 . .
C15 C16 H16B 109.5 . .
H16A C16 H16B 109.5 . .
C15 C16 H16C 109.5 . .
H16A C16 H16C 109.5 . .
H16B C16 H16C 109.5 . .
C18 C17 H17A 109.5 . .
C18 C17 H17B 109.5 . .
H17A C17 H17B 109.5 . .
C18 C17 H17C 109.5 . .
H17A C17 H17C 109.5 . .
H17B C17 H17C 109.5 . .
O3 C18 C19 125.7(5) . .
O3 C18 C17 114.4(5) . .
C19 C18 C17 119.9(5) . .
C18 C19 C20 126.0(5) . .
C18 C19 H19 117.0 . .
C20 C19 H19 117.0 . .
N7 C20 C19 123.0(5) . .
N7 C20 C21 120.1(6) . .
C19 C20 C21 116.9(6) . .
C20 C21 H21A 109.5 . .
C20 C21 H21B 109.5 . .
H21A C21 H21B 109.5 . .
C20 C21 H21C 109.5 . .
H21A C21 H21C 109.5 . .
H21B C21 H21C 109.5 . .
N7 C22 C22 109.1(4) . 2
N7 C22 H22A 109.9 . .
C22 C22 H22A 109.9 2 .
N7 C22 H22B 109.9 . .
C22 C22 H22B 109.9 2 .
H22A C22 H22B 108.3 . .
C24 C23 H23A 109.5 . .
C24 C23 H23B 109.5 . .
H23A C23 H23B 109.5 . .
C24 C23 H23C 109.5 . .
H23A C23 H23C 109.5 . .
H23B C23 H23C 109.5 . .
O4 C24 C25 124.2(5) . .
O4 C24 C23 114.4(5) . .
C25 C24 C23 121.4(5) . .
C24 C25 C26 127.8(5) . .
C24 C25 H25 116.1 . .
C26 C25 H25 116.1 . .
N8 C26 C25 122.9(5) . .
N8 C26 C27 118.2(6) . .
C25 C26 C27 118.9(6) . .
C26 C27 H27A 109.5 . .
C26 C27 H27B 109.5 . .
H27A C27 H27B 109.5 . .
C26 C27 H27C 109.5 . .
H27A C27 H27C 109.5 . .
H27B C27 H27C 109.5 . .
N8 C28 C28 110.2(4) . 2_655
N8 C28 H28A 109.6 . .
C28 C28 H28A 109.6 2_655 .
N8 C28 H28B 109.6 . .
C28 C28 H28B 109.6 2_655 .
H28A C28 H28B 108.1 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 C4 2.054(6) .
Ag1 C1 2.066(6) .
Ag1 Ag2 3.0967(8) .
Ag2 C2 2.062(5) .
Ag2 C3 2.065(5) .
Mn1 O1 1.908(3) .
Mn1 O2 1.909(3) .
Mn1 N6 1.980(4) .
Mn1 N5 1.986(4) .
Mn1 N4 2.298(4) 4_545
Mn1 N1 2.302(4) .
Mn2 O3 1.913(3) 2
Mn2 O3 1.913(3) .
Mn2 N7 1.989(4) .
Mn2 N7 1.989(4) 2
Mn2 N2 2.304(4) .
Mn2 N2 2.304(4) 2
Mn3 O4 1.909(3) .
Mn3 O4 1.909(3) 2_655
Mn3 N8 1.986(4) 2_655
Mn3 N8 1.986(4) .
Mn3 N3 2.298(4) 2_655
Mn3 N3 2.298(4) .
O1 C6 1.291(5) .
O2 C15 1.299(5) .
O3 C18 1.290(5) .
O4 C24 1.303(5) .
N1 C1 1.127(5) .
N2 C2 1.127(5) .
N3 C3 1.129(5) .
N4 C4 1.128(5) .
N4 Mn1 2.298(4) 4
N5 C13 1.301(5) .
N5 C11 1.477(5) .
N6 C8 1.300(6) .
N6 C10 1.473(6) .
N7 C20 1.306(6) .
N7 C22 1.472(6) .
N8 C26 1.323(6) .
N8 C28 1.467(6) .
C5 C6 1.511(6) .
C5 H5A 0.9600 .
C5 H5B 0.9600 .
C5 H5C 0.9600 .
C6 C7 1.374(6) .
C7 C8 1.413(7) .
C7 H7 0.9300 .
C8 C9 1.538(6) .
C9 H9A 0.9600 .
C9 H9B 0.9600 .
C9 H9C 0.9600 .
C10 C11 1.494(7) .
C10 H10A 0.9700 .
C10 H10B 0.9700 .
C11 H11A 0.9700 .
C11 H11B 0.9700 .
C12 C13 1.531(6) .
C12 H12A 0.9600 .
C12 H12B 0.9600 .
C12 H12C 0.9600 .
C13 C14 1.418(6) .
C14 C15 1.365(6) .
C14 H14 0.9300 .
C15 C16 1.504(5) .
C16 H16A 0.9600 .
C16 H16B 0.9600 .
C16 H16C 0.9600 .
C17 C18 1.508(6) .
C17 H17A 0.9600 .
C17 H17B 0.9600 .
C17 H17C 0.9600 .
C18 C19 1.375(7) .
C19 C20 1.403(7) .
C19 H19 0.9300 .
C20 C21 1.533(7) .
C21 H21A 0.9600 .
C21 H21B 0.9600 .
C21 H21C 0.9600 .
C22 C22 1.488(10) 2
C22 H22A 0.9700 .
C22 H22B 0.9700 .
C23 C24 1.502(6) .
C23 H23A 0.9600 .
C23 H23B 0.9600 .
C23 H23C 0.9600 .
C24 C25 1.359(7) .
C25 C26 1.394(7) .
C25 H25 0.9300 .
C26 C27 1.532(7) .
C27 H27A 0.9600 .
C27 H27B 0.9600 .
C27 H27C 0.9600 .
C28 C28 1.486(11) 2_655
C28 H28A 0.9700 .
C28 H28B 0.9700 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
C4 Ag1 Ag2 C2 -91.56(19) . .
C1 Ag1 Ag2 C2 88.74(19) . .
C4 Ag1 Ag2 C3 88.65(19) . .
C1 Ag1 Ag2 C3 -91.05(19) . .
O2 Mn1 O1 C6 174.0(4) . .
N6 Mn1 O1 C6 -8.2(4) . .
N5 Mn1 O1 C6 25(2) . .
N4 Mn1 O1 C6 82.4(4) 4_545 .
N1 Mn1 O1 C6 -96.7(4) . .
O1 Mn1 O2 C15 171.9(4) . .
N6 Mn1 O2 C15 19.4(19) . .
N5 Mn1 O2 C15 -10.3(4) . .
N4 Mn1 O2 C15 -98.9(4) 4_545 .
N1 Mn1 O2 C15 81.5(4) . .
O3 Mn2 O3 C18 -176.4(4) 2 .
N7 Mn2 O3 C18 7.1(4) . .
N7 Mn2 O3 C18 -34.6(17) 2 .
N2 Mn2 O3 C18 94.8(4) . .
N2 Mn2 O3 C18 -85.9(4) 2 .
O4 Mn3 O4 C24 -177.3(4) 2_655 .
N8 Mn3 O4 C24 -37(2) 2_655 .
N8 Mn3 O4 C24 5.5(3) . .
N3 Mn3 O4 C24 -86.0(3) 2_655 .
N3 Mn3 O4 C24 92.8(3) . .
O1 Mn1 N1 C1 33.6(9) . .
O2 Mn1 N1 C1 125.1(9) . .
N6 Mn1 N1 C1 -59.3(9) . .
N5 Mn1 N1 C1 -142.7(9) . .
N4 Mn1 N1 C1 -29(8) 4_545 .
O3 Mn2 N2 C2 -127.6(9) 2 .
O3 Mn2 N2 C2 -35.5(9) . .
N7 Mn2 N2 C2 56.7(9) . .
N7 Mn2 N2 C2 140.1(9) 2 .
N2 Mn2 N2 C2 -81.6(9) 2 .
O4 Mn3 N3 C3 -37.9(11) . .
O4 Mn3 N3 C3 -128.7(11) 2_655 .
N8 Mn3 N3 C3 138.7(11) 2_655 .
N8 Mn3 N3 C3 54.6(11) . .
N3 Mn3 N3 C3 96.7(11) 2_655 .
O1 Mn1 N5 C13 152.9(18) . .
O2 Mn1 N5 C13 3.7(4) . .
N6 Mn1 N5 C13 -173.8(4) . .
N4 Mn1 N5 C13 95.4(4) 4_545 .
N1 Mn1 N5 C13 -85.6(4) . .
O1 Mn1 N5 C11 -21(2) . .
O2 Mn1 N5 C11 -170.1(3) . .
N6 Mn1 N5 C11 12.3(3) . .
N4 Mn1 N5 C11 -78.5(3) 4_545 .
N1 Mn1 N5 C11 100.6(3) . .
O1 Mn1 N6 C8 2.5(4) . .
O2 Mn1 N6 C8 154.9(15) . .
N5 Mn1 N6 C8 -175.2(4) . .
N4 Mn1 N6 C8 -86.7(4) 4_545 .
N1 Mn1 N6 C8 92.8(4) . .
O1 Mn1 N6 C10 -172.0(3) . .
O2 Mn1 N6 C10 -19.6(19) . .
N5 Mn1 N6 C10 10.3(3) . .
N4 Mn1 N6 C10 98.8(3) 4_545 .
N1 Mn1 N6 C10 -81.7(3) . .
O3 Mn2 N7 C20 -141.1(15) 2 .
O3 Mn2 N7 C20 0.6(4) . .
N7 Mn2 N7 C20 176.9(5) 2 .
N2 Mn2 N7 C20 -89.8(4) . .
N2 Mn2 N7 C20 89.5(4) 2 .
O3 Mn2 N7 C22 30.1(18) 2 .
O3 Mn2 N7 C22 171.9(3) . .
N7 Mn2 N7 C22 -11.9(3) 2 .
N2 Mn2 N7 C22 81.4(4) . .
N2 Mn2 N7 C22 -99.2(4) 2 .
O4 Mn3 N8 C26 0.4(4) . .
O4 Mn3 N8 C26 -140.1(19) 2_655 .
N8 Mn3 N8 C26 177.5(4) 2_655 .
N3 Mn3 N8 C26 90.4(4) 2_655 .
N3 Mn3 N8 C26 -90.7(4) . .
O4 Mn3 N8 C28 172.1(4) . .
O4 Mn3 N8 C28 32(2) 2_655 .
N8 Mn3 N8 C28 -10.8(3) 2_655 .
N3 Mn3 N8 C28 -97.9(4) 2_655 .
N3 Mn3 N8 C28 81.0(4) . .
Mn1 N1 C1 Ag1 10(4) . .
C4 Ag1 C1 N1 -3(5) . .
Ag2 Ag1 C1 N1 0(4) . .
Mn2 N2 C2 Ag2 -6(5) . .
C3 Ag2 C2 N2 4(6) . .
Ag1 Ag2 C2 N2 1(4) . .
Mn3 N3 C3 Ag2 16(5) . .
C2 Ag2 C3 N3 -27(6) . .
Ag1 Ag2 C3 N3 -24(4) . .
Mn1 N4 C4 Ag1 6(4) 4 .
C1 Ag1 C4 N4 9(5) . .
Ag2 Ag1 C4 N4 5(3) . .
Mn1 O1 C6 C7 9.4(6) . .
Mn1 O1 C6 C5 -171.2(3) . .
O1 C6 C7 C8 -2.7(8) . .
C5 C6 C7 C8 178.1(4) . .
C10 N6 C8 C7 176.3(5) . .
Mn1 N6 C8 C7 2.3(7) . .
C10 N6 C8 C9 -4.2(7) . .
Mn1 N6 C8 C9 -178.3(3) . .
C6 C7 C8 N6 -3.6(8) . .
C6 C7 C8 C9 177.0(4) . .
C8 N6 C10 C11 155.1(5) . .
Mn1 N6 C10 C11 -30.2(5) . .
C13 N5 C11 C10 153.8(4) . .
Mn1 N5 C11 C10 -32.0(5) . .
N6 C10 C11 N5 39.7(6) . .
C11 N5 C13 C14 175.5(4) . .
Mn1 N5 C13 C14 2.2(6) . .
C11 N5 C13 C12 -4.0(7) . .
Mn1 N5 C13 C12 -177.4(3) . .
N5 C13 C14 C15 -4.5(7) . .
C12 C13 C14 C15 175.0(4) . .
Mn1 O2 C15 C14 11.2(6) . .
Mn1 O2 C15 C16 -168.7(3) . .
C13 C14 C15 O2 -2.5(8) . .
C13 C14 C15 C16 177.4(4) . .
Mn2 O3 C18 C19 -10.3(6) . .
Mn2 O3 C18 C17 170.3(3) . .
O3 C18 C19 C20 4.3(8) . .
C17 C18 C19 C20 -176.4(4) . .
C22 N7 C20 C19 -176.0(5) . .
Mn2 N7 C20 C19 -5.6(7) . .
C22 N7 C20 C21 5.0(7) . .
Mn2 N7 C20 C21 175.4(3) . .
C18 C19 C20 N7 4.2(8) . .
C18 C19 C20 C21 -176.7(4) . .
C20 N7 C22 C22 -155.5(5) . 2
Mn2 N7 C22 C22 32.8(7) . 2
Mn3 O4 C24 C25 -7.8(6) . .
Mn3 O4 C24 C23 172.1(3) . .
O4 C24 C25 C26 3.1(8) . .
C23 C24 C25 C26 -176.8(5) . .
C28 N8 C26 C25 -175.0(5) . .
Mn3 N8 C26 C25 -4.2(7) . .
C28 N8 C26 C27 5.5(7) . .
Mn3 N8 C26 C27 176.2(3) . .
C24 C25 C26 N8 3.3(8) . .
C24 C25 C26 C27 -177.2(4) . .
C26 N8 C28 C28 -158.2(5) . 2_655
Mn3 N8 C28 C28 30.0(7) . 2_655
