#------------------------------------------------------------------------------
#$Date: 2016-03-26 02:06:25 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180123 $
#$URL: svn://www.crystallography.net/cod/cif/7/10/21/7102120.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7102120
loop_
_publ_author_name
'Feng, Yuhua'
'Guo, Yang'
'OuYang, Yan'
'Liu, Zhanquan'
'Liao, Daizheng'
'Cheng, Peng'
'Yan, Shiping'
'Jiang, Zonghui'
_publ_section_title
;
 2D warp-and-woof interwoven networks constructed by helical chains
 with different chirality.
;
_journal_issue                   35
_journal_name_full
'Chemical communications (Cambridge, England)'
_journal_page_first              3643
_journal_page_last               3645
_journal_paper_doi               10.1039/b707356a
_journal_year                    2007
_chemical_formula_moiety         'C72 H58 Au4 Mn4 N16 O9'
_chemical_formula_sum            'C72 H58 Au4 Mn4 N16 O9'
_chemical_formula_weight         2298.97
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                94.217(3)
_cell_angle_beta                 107.932(4)
_cell_angle_gamma                90.853(6)
_cell_formula_units_Z            2
_cell_length_a                   13.382(5)
_cell_length_b                   14.081(5)
_cell_length_c                   20.242(8)
_cell_measurement_reflns_used    7534
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      27.9
_cell_measurement_theta_min      1.5
_cell_volume                     3616(2)
_computing_cell_refinement       CrystalClear
_computing_data_collection       CrystalClear
_computing_data_reduction        CrystalClear
_computing_publication_material  'CrystalStructure 3.7.0'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_detector_area_resol_mean 7.31
_diffrn_measured_fraction_theta_full 0.986
_diffrn_measured_fraction_theta_max 0.986
_diffrn_measurement_device_type  'Rigaku Saturn'
_diffrn_measurement_method       ω
_diffrn_radiation_monochromator  confocal
_diffrn_radiation_source         'rotating anode'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71070
_diffrn_reflns_av_R_equivalents  0.0505
_diffrn_reflns_av_sigmaI/netI    0.0819
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_k_max       8
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       26
_diffrn_reflns_limit_l_min       -26
_diffrn_reflns_number            28281
_diffrn_reflns_theta_full        27.89
_diffrn_reflns_theta_max         27.89
_diffrn_reflns_theta_min         1.45
_exptl_absorpt_coefficient_mu    8.824
_exptl_absorpt_correction_T_max  0.244
_exptl_absorpt_correction_T_min  0.150
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   crystalclear
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    2.111
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             2180
_exptl_crystal_size_max          0.22
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.16
_refine_diff_density_max         1.581
_refine_diff_density_min         -2.144
_refine_diff_density_rms         0.184
_refine_ls_extinction_coef       0.00064(4)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   0.965
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     947
_refine_ls_number_reflns         17061
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.965
_refine_ls_R_factor_all          0.0840
_refine_ls_R_factor_gt           0.0492
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0421P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1009
_refine_ls_wR_factor_ref         0.1172
_reflns_number_gt                10784
_reflns_number_total             17061
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b707356a.txt
_cod_data_source_block           1
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7102120
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Au1 Au -0.02879(2) 0.35409(2) 0.168730(17) 0.04055(9) Uani 1 1 d .
Au2 Au 0.53841(2) 0.88646(2) 0.336312(17) 0.03974(9) Uani 1 1 d .
Au3 Au 0.45925(2) 0.86556(2) 0.175048(17) 0.04017(9) Uani 1 1 d .
Au4 Au 1.03993(2) 0.37699(2) 0.332706(17) 0.04076(9) Uani 1 1 d .
Mn1 Mn -0.31673(8) 0.19680(7) 0.26043(6) 0.0344(3) Uani 1 1 d .
Mn2 Mn 0.32337(8) 0.55463(8) 0.23768(6) 0.0346(3) Uani 1 1 d .
Mn3 Mn 0.17041(8) 1.06216(8) 0.24750(6) 0.0369(3) Uani 1 1 d .
Mn4 Mn 0.80203(8) 0.66825(7) 0.25564(6) 0.0293(2) Uani 1 1 d .
N1 N -0.2334(5) 0.2696(5) 0.1897(4) 0.0511(18) Uani 1 1 d .
N2 N 0.1857(5) 0.4506(5) 0.1743(4) 0.0478(17) Uani 1 1 d .
N3 N 0.4411(5) 0.6796(5) 0.3154(4) 0.0506(18) Uani 1 1 d .
N4 N 0.6235(5) 1.0911(5) 0.3292(4) 0.0484(17) Uani 1 1 d .
N5 N 0.2537(5) 0.9654(5) 0.1800(4) 0.0496(18) Uani 1 1 d .
N6 N 0.6623(5) 0.7520(4) 0.1914(4) 0.0531(19) Uani 1 1 d .
N7 N 0.9283(5) 0.5705(4) 0.3199(3) 0.0433(16) Uani 1 1 d .
N8 N 1.1267(5) 0.1735(5) 0.3221(4) 0.0555(19) Uani 1 1 d .
N9 N -0.3429(5) 0.0835(4) 0.1926(4) 0.0432(16) Uani 1 1 d .
N10 N -0.1792(4) 0.1381(4) 0.2984(3) 0.0355(14) Uani 1 1 d .
N11 N 0.2421(4) 0.5708(4) 0.3052(4) 0.0392(15) Uani 1 1 d .
N12 N 0.2428(5) 0.6645(4) 0.1972(3) 0.0396(15) Uani 1 1 d .
N13 N 0.3144(5) 1.0828(4) 0.3119(3) 0.0422(16) Uani 1 1 d .
N14 N 0.2142(5) 1.1697(4) 0.2043(4) 0.0428(16) Uani 1 1 d .
N15 N 0.7170(4) 0.6352(4) 0.3157(4) 0.0417(15) Uani 1 1 d .
N16 N 0.7328(4) 0.5480(4) 0.2026(3) 0.0340(13) Uani 1 1 d .
O1 O -0.4457(4) 0.2471(4) 0.2151(3) 0.0422(13) Uani 1 1 d .
O2 O -0.2832(4) 0.2961(3) 0.3309(3) 0.0405(13) Uani 1 1 d .
O3 O 0.4041(4) 0.4608(3) 0.2863(3) 0.0399(12) Uani 1 1 d .
O4 O 0.3930(4) 0.5487(3) 0.1715(3) 0.0406(12) Uani 1 1 d .
O5 O 0.1413(4) 0.9584(4) 0.2920(3) 0.0479(14) Uani 1 1 d .
O6 O 0.0367(4) 1.0545(4) 0.1817(3) 0.0476(14) Uani 1 1 d .
O7 O 0.8606(4) 0.7792(3) 0.3128(3) 0.0412(12) Uani 1 1 d .
O8 O 0.8806(4) 0.6844(3) 0.1943(3) 0.0400(12) Uani 1 1 d .
C1 C -0.1623(6) 0.2982(5) 0.1765(4) 0.0424(19) Uani 1 1 d .
C2 C 0.1059(6) 0.4135(5) 0.1682(4) 0.0388(17) Uani 1 1 d .
C3 C 0.4754(6) 0.7546(6) 0.3274(4) 0.0429(19) Uani 1 1 d .
C4 C 0.5967(6) 1.0169(6) 0.3364(4) 0.0376(17) Uani 1 1 d .
C5 C 0.3275(6) 0.9325(5) 0.1749(4) 0.0434(19) Uani 1 1 d .
C6 C 0.5905(6) 0.7937(5) 0.1825(4) 0.0430(19) Uani 1 1 d .
C7 C 0.9724(6) 0.5020(5) 0.3294(4) 0.0395(18) Uani 1 1 d .
C8 C 1.0990(6) 0.2495(6) 0.3306(4) 0.0453(19) Uani 1 1 d .
C9 C -0.5054(6) 0.2270(6) 0.1493(4) 0.046(2) Uani 1 1 d .
C10 C -0.5790(6) 0.2928(7) 0.1184(5) 0.057(2) Uani 1 1 d .
H10 H -0.5826 0.3504 0.1430 0.068 Uiso 1 1 calc R
C11 C -0.6454(7) 0.2733(9) 0.0525(6) 0.078(3) Uani 1 1 d .
H11 H -0.6936 0.3183 0.0330 0.094 Uiso 1 1 calc R
C12 C -0.6439(9) 0.1897(10) 0.0140(6) 0.094(4) Uani 1 1 d .
H12 H -0.6901 0.1781 -0.0310 0.113 Uiso 1 1 calc R
C13 C -0.5717(8) 0.1221(8) 0.0433(5) 0.077(3) Uani 1 1 d .
H13 H -0.5717 0.0638 0.0186 0.093 Uiso 1 1 calc R
C14 C -0.4990(7) 0.1419(7) 0.1099(4) 0.055(2) Uani 1 1 d .
C15 C -0.4191(7) 0.0740(6) 0.1353(5) 0.058(2) Uani 1 1 d .
H15 H -0.4233 0.0177 0.1074 0.070 Uiso 1 1 calc R
C16 C -0.2638(6) 0.0107(5) 0.2133(5) 0.054(2) Uani 1 1 d .
H16A H -0.2828 -0.0310 0.2440 0.064 Uiso 1 1 calc R
H16B H -0.2596 -0.0277 0.1725 0.064 Uiso 1 1 calc R
C17 C -0.1629(6) 0.0602(5) 0.2492(4) 0.0439(19) Uani 1 1 d .
H17A H -0.1343 0.0866 0.2156 0.053 Uiso 1 1 calc R
H17B H -0.1134 0.0159 0.2746 0.053 Uiso 1 1 calc R
C18 C -0.1109(6) 0.1635(5) 0.3564(4) 0.0426(19) Uani 1 1 d .
H18 H -0.0519 0.1269 0.3704 0.051 Uiso 1 1 calc R
C19 C -0.1178(5) 0.2451(5) 0.4025(4) 0.0363(17) Uani 1 1 d .
C20 C -0.0302(6) 0.2662(6) 0.4631(4) 0.052(2) Uani 1 1 d .
H20 H 0.0249 0.2247 0.4730 0.063 Uiso 1 1 calc R
C21 C -0.0248(6) 0.3456(6) 0.5073(5) 0.055(2) Uani 1 1 d .
H21 H 0.0331 0.3585 0.5468 0.066 Uiso 1 1 calc R
C22 C -0.1079(7) 0.4064(6) 0.4917(4) 0.054(2) Uani 1 1 d .
H22 H -0.1050 0.4610 0.5212 0.064 Uiso 1 1 calc R
C23 C -0.1939(6) 0.3884(5) 0.4343(4) 0.0445(19) Uani 1 1 d .
H23 H -0.2489 0.4301 0.4259 0.053 Uiso 1 1 calc R
C24 C -0.2002(5) 0.3082(5) 0.3880(4) 0.0370(17) Uani 1 1 d .
C25 C 0.4131(6) 0.4382(5) 0.3496(4) 0.0426(19) Uani 1 1 d .
C26 C 0.4946(6) 0.3792(5) 0.3809(5) 0.050(2) Uani 1 1 d .
H26 H 0.5404 0.3582 0.3570 0.060 Uiso 1 1 calc R
C27 C 0.5077(7) 0.3517(6) 0.4476(5) 0.065(3) Uani 1 1 d .
H27 H 0.5635 0.3142 0.4684 0.078 Uiso 1 1 calc R
C28 C 0.4383(9) 0.3796(8) 0.4832(6) 0.077(3) Uani 1 1 d .
H28 H 0.4453 0.3586 0.5269 0.092 Uiso 1 1 calc R
C29 C 0.3597(7) 0.4381(7) 0.4535(5) 0.066(3) Uani 1 1 d .
H29 H 0.3138 0.4573 0.4778 0.079 Uiso 1 1 calc R
C30 C 0.3458(6) 0.4701(6) 0.3878(4) 0.046(2) Uani 1 1 d .
C31 C 0.2634(6) 0.5350(6) 0.3629(4) 0.048(2) Uani 1 1 d .
H31 H 0.2227 0.5518 0.3914 0.057 Uiso 1 1 calc R
C32 C 0.1536(7) 0.6363(6) 0.2800(5) 0.058(2) Uani 1 1 d .
H32A H 0.0923 0.6006 0.2491 0.070 Uiso 1 1 calc R
H32B H 0.1350 0.6658 0.3192 0.070 Uiso 1 1 calc R
C33 C 0.1865(6) 0.7077(6) 0.2437(5) 0.053(2) Uani 1 1 d .
H33A H 0.2325 0.7549 0.2771 0.064 Uiso 1 1 calc R
H33B H 0.1257 0.7396 0.2164 0.064 Uiso 1 1 calc R
C34 C 0.2440(6) 0.7003(5) 0.1414(4) 0.046(2) Uani 1 1 d .
H34 H 0.1990 0.7497 0.1272 0.055 Uiso 1 1 calc R
C35 C 0.3073(6) 0.6723(5) 0.0981(4) 0.0398(17) Uani 1 1 d .
C36 C 0.3039(7) 0.7232(6) 0.0414(5) 0.057(2) Uani 1 1 d .
H36 H 0.2542 0.7695 0.0288 0.069 Uiso 1 1 calc R
C37 C 0.3711(9) 0.7072(7) 0.0036(5) 0.068(3) Uani 1 1 d .
H37 H 0.3690 0.7437 -0.0332 0.081 Uiso 1 1 calc R
C38 C 0.4426(8) 0.6363(7) 0.0207(5) 0.066(3) Uani 1 1 d .
H38 H 0.4871 0.6239 -0.0060 0.079 Uiso 1 1 calc R
C39 C 0.4493(6) 0.5838(6) 0.0763(4) 0.048(2) Uani 1 1 d .
H39 H 0.4990 0.5372 0.0872 0.057 Uiso 1 1 calc R
C40 C 0.3816(6) 0.5998(5) 0.1171(4) 0.0374(17) Uani 1 1 d .
C41 C 0.1963(6) 0.9287(5) 0.3519(4) 0.0407(18) Uani 1 1 d .
C42 C 0.1512(7) 0.8594(6) 0.3812(5) 0.054(2) Uani 1 1 d .
H42 H 0.0831 0.8360 0.3581 0.064 Uiso 1 1 calc R
C43 C 0.2042(9) 0.8263(7) 0.4417(5) 0.071(3) Uani 1 1 d .
H43 H 0.1720 0.7785 0.4583 0.085 Uiso 1 1 calc R
C44 C 0.3045(10) 0.8591(8) 0.4811(6) 0.080(3) Uani 1 1 d .
H44 H 0.3387 0.8364 0.5240 0.096 Uiso 1 1 calc R
C45 C 0.3511(8) 0.9275(7) 0.4532(5) 0.070(3) Uani 1 1 d .
H45 H 0.4194 0.9497 0.4773 0.083 Uiso 1 1 calc R
C46 C 0.2982(7) 0.9648(6) 0.3893(4) 0.046(2) Uani 1 1 d .
C47 C 0.3515(6) 1.0387(6) 0.3668(5) 0.051(2) Uani 1 1 d .
H47 H 0.4195 1.0563 0.3947 0.061 Uiso 1 1 calc R
C48 C 0.3776(7) 1.1545(6) 0.2895(6) 0.067(3) Uani 1 1 d .
H48A H 0.4290 1.1870 0.3299 0.080 Uiso 1 1 calc R
H48B H 0.4147 1.1231 0.2602 0.080 Uiso 1 1 calc R
C49 C 0.3066(7) 1.2230(7) 0.2508(5) 0.060(2) Uani 1 1 d .
H49A H 0.3410 1.2584 0.2241 0.072 Uiso 1 1 calc R
H49B H 0.2862 1.2677 0.2826 0.072 Uiso 1 1 calc R
C50 C 0.1714(6) 1.1897(5) 0.1415(5) 0.044(2) Uani 1 1 d .
H50 H 0.2040 1.2371 0.1248 0.053 Uiso 1 1 calc R
C51 C 0.0768(6) 1.1444(6) 0.0951(5) 0.047(2) Uani 1 1 d .
C52 C 0.0471(8) 1.1644(6) 0.0246(5) 0.063(3) Uani 1 1 d .
H52 H 0.0905 1.2029 0.0086 0.076 Uiso 1 1 calc R
C53 C -0.0474(8) 1.1262(7) -0.0207(5) 0.069(3) Uani 1 1 d .
H53 H -0.0666 1.1383 -0.0675 0.082 Uiso 1 1 calc R
C54 C -0.1120(8) 1.0716(6) 0.0022(6) 0.066(3) Uani 1 1 d .
H54 H -0.1754 1.0477 -0.0292 0.079 Uiso 1 1 calc R
C55 C -0.0861(7) 1.0503(6) 0.0713(5) 0.054(2) Uani 1 1 d .
H55 H -0.1327 1.0146 0.0864 0.065 Uiso 1 1 calc R
C56 C 0.0107(6) 1.0833(5) 0.1176(4) 0.0414(19) Uani 1 1 d .
C57 C 0.8396(6) 0.8156(5) 0.3694(4) 0.0376(18) Uani 1 1 d .
C58 C 0.8870(6) 0.9051(5) 0.4001(4) 0.047(2) Uani 1 1 d .
H58 H 0.9314 0.9360 0.3803 0.056 Uiso 1 1 calc R
C59 C 0.8691(7) 0.9471(6) 0.4582(5) 0.063(3) Uani 1 1 d .
H59 H 0.8980 1.0077 0.4758 0.075 Uiso 1 1 calc R
C60 C 0.8085(8) 0.9007(8) 0.4912(5) 0.071(3) Uani 1 1 d .
H60 H 0.7997 0.9282 0.5322 0.085 Uiso 1 1 calc R
C61 C 0.7616(7) 0.8135(7) 0.4627(4) 0.059(2) Uani 1 1 d .
H61 H 0.7195 0.7828 0.4842 0.070 Uiso 1 1 calc R
C62 C 0.7755(5) 0.7696(5) 0.4020(4) 0.0378(17) Uani 1 1 d .
C63 C 0.7180(6) 0.6819(5) 0.3725(4) 0.0418(18) Uani 1 1 d .
H63 H 0.6772 0.6563 0.3972 0.050 Uiso 1 1 calc R
C64 C 0.6424(9) 0.5550(7) 0.2860(6) 0.083(3) Uani 1 1 d .
H64A H 0.6348 0.5188 0.3233 0.100 Uiso 1 1 calc R
H64B H 0.5742 0.5790 0.2622 0.100 Uiso 1 1 calc R
C65 C 0.6745(8) 0.4953(7) 0.2395(6) 0.077(3) Uani 1 1 d .
H65A H 0.6133 0.4629 0.2059 0.092 Uiso 1 1 calc R
H65B H 0.7186 0.4473 0.2645 0.092 Uiso 1 1 calc R
C66 C 0.7428(5) 0.5134(5) 0.1453(4) 0.0377(18) Uani 1 1 d .
H66 H 0.7042 0.4575 0.1250 0.045 Uiso 1 1 calc R
C67 C 0.8086(5) 0.5528(5) 0.1087(4) 0.0371(17) Uani 1 1 d .
C68 C 0.8101(6) 0.5029(5) 0.0467(4) 0.0459(19) Uani 1 1 d .
H68 H 0.7681 0.4476 0.0307 0.055 Uiso 1 1 calc R
C69 C 0.8716(7) 0.5335(6) 0.0091(5) 0.061(3) Uani 1 1 d .
H69 H 0.8703 0.5007 -0.0328 0.073 Uiso 1 1 calc R
C70 C 0.9356(7) 0.6136(6) 0.0345(4) 0.051(2) Uani 1 1 d .
H70 H 0.9788 0.6344 0.0098 0.061 Uiso 1 1 calc R
C71 C 0.9371(6) 0.6642(5) 0.0961(4) 0.0440(19) Uani 1 1 d .
H71 H 0.9807 0.7186 0.1119 0.053 Uiso 1 1 calc R
C72 C 0.8742(5) 0.6345(5) 0.1345(4) 0.0311(15) Uani 1 1 d .
O9 O 0.9187(7) 0.8786(5) 0.1710(5) 0.121(3) Uani 1 1 d .
H9A H 0.9684 0.8737 0.2086 0.181 Uiso 1 1 d R
H9B H 0.8792 0.8286 0.1635 0.181 Uiso 1 1 d R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Mn Mn 0.3368 0.7283 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C2 Au1 C1 175.8(3) . .
C2 Au1 Au4 91.6(2) . 1_455
C1 Au1 Au4 84.4(2) . 1_455
C4 Au2 C3 175.1(3) . .
C4 Au2 Au3 91.1(2) . .
C3 Au2 Au3 84.1(2) . .
C5 Au3 C6 175.2(3) . .
C5 Au3 Au2 90.6(2) . .
C6 Au3 Au2 85.5(2) . .
C8 Au4 C7 176.2(3) . .
C8 Au4 Au1 87.0(2) . 1_655
C7 Au4 Au1 90.1(2) . 1_655
O1 Mn1 O2 92.6(2) . .
O1 Mn1 N9 92.6(2) . .
O2 Mn1 N9 174.2(2) . .
O1 Mn1 N10 173.7(2) . .
O2 Mn1 N10 92.7(2) . .
N9 Mn1 N10 82.3(3) . .
O1 Mn1 N1 92.3(2) . .
O2 Mn1 N1 95.1(2) . .
N9 Mn1 N1 87.2(3) . .
N10 Mn1 N1 83.9(2) . .
O1 Mn1 N4 98.2(2) . 1_445
O2 Mn1 N4 93.3(2) . 1_445
N9 Mn1 N4 83.4(3) . 1_445
N10 Mn1 N4 84.8(2) . 1_445
N1 Mn1 N4 166.2(2) . 1_445
O4 Mn2 O3 92.4(2) . .
O4 Mn2 N12 91.9(2) . .
O3 Mn2 N12 172.8(2) . .
O4 Mn2 N11 175.0(2) . .
O3 Mn2 N11 92.6(2) . .
N12 Mn2 N11 83.1(3) . .
O4 Mn2 N2 95.4(2) . .
O3 Mn2 N2 94.9(2) . .
N12 Mn2 N2 90.5(2) . .
N11 Mn2 N2 84.8(2) . .
O4 Mn2 N3 95.4(2) . .
O3 Mn2 N3 90.6(2) . .
N12 Mn2 N3 83.2(2) . .
N11 Mn2 N3 83.9(2) . .
N2 Mn2 N3 167.7(2) . .
O5 Mn3 O6 93.0(2) . .
O5 Mn3 N13 93.3(3) . .
O6 Mn3 N13 173.6(3) . .
O5 Mn3 N14 175.0(2) . .
O6 Mn3 N14 91.7(3) . .
N13 Mn3 N14 82.0(3) . .
O5 Mn3 N8 94.1(3) . 1_465
O6 Mn3 N8 94.5(3) . 1_465
N13 Mn3 N8 84.8(3) . 1_465
N14 Mn3 N8 87.4(3) . 1_465
O5 Mn3 N5 92.4(2) . .
O6 Mn3 N5 96.5(2) . .
N13 Mn3 N5 83.6(2) . .
N14 Mn3 N5 85.3(3) . .
N8 Mn3 N5 167.0(3) 1_465 .
O7 Mn4 O8 93.8(2) . .
O7 Mn4 N15 92.6(3) . .
O8 Mn4 N15 173.2(2) . .
O7 Mn4 N16 174.0(2) . .
O8 Mn4 N16 92.2(2) . .
N15 Mn4 N16 81.4(3) . .
O7 Mn4 N6 90.9(2) . .
O8 Mn4 N6 93.4(2) . .
N15 Mn4 N6 88.7(3) . .
N16 Mn4 N6 89.5(2) . .
O7 Mn4 N7 93.9(2) . .
O8 Mn4 N7 90.8(2) . .
N15 Mn4 N7 86.6(2) . .
N16 Mn4 N7 85.4(2) . .
N6 Mn4 N7 173.5(2) . .
C1 N1 Mn1 154.2(7) . .
C2 N2 Mn2 149.7(6) . .
C3 N3 Mn2 151.7(7) . .
C4 N4 Mn1 149.4(7) . 1_665
C5 N5 Mn3 148.8(7) . .
C6 N6 Mn4 155.8(7) . .
C7 N7 Mn4 154.5(6) . .
C8 N8 Mn3 147.1(7) . 1_645
C15 N9 C16 122.4(7) . .
C15 N9 Mn1 124.4(6) . .
C16 N9 Mn1 113.2(5) . .
C18 N10 C17 122.8(6) . .
C18 N10 Mn1 125.5(5) . .
C17 N10 Mn1 111.6(5) . .
C31 N11 C32 123.4(7) . .
C31 N11 Mn2 125.7(5) . .
C32 N11 Mn2 110.9(5) . .
C34 N12 C33 122.5(7) . .
C34 N12 Mn2 126.0(5) . .
C33 N12 Mn2 111.2(5) . .
C47 N13 C48 122.8(7) . .
C47 N13 Mn3 124.3(6) . .
C48 N13 Mn3 112.9(5) . .
C50 N14 C49 122.1(7) . .
C50 N14 Mn3 125.1(6) . .
C49 N14 Mn3 112.7(5) . .
C63 N15 C64 120.9(7) . .
C63 N15 Mn4 125.5(5) . .
C64 N15 Mn4 113.4(6) . .
C66 N16 C65 121.1(7) . .
C66 N16 Mn4 125.6(5) . .
C65 N16 Mn4 113.0(5) . .
C9 O1 Mn1 127.7(5) . .
C24 O2 Mn1 129.4(4) . .
C25 O3 Mn2 128.0(5) . .
C40 O4 Mn2 129.9(4) . .
C41 O5 Mn3 128.6(5) . .
C56 O6 Mn3 126.8(5) . .
C57 O7 Mn4 128.5(5) . .
C72 O8 Mn4 129.1(4) . .
N1 C1 Au1 171.3(8) . .
N2 C2 Au1 173.7(7) . .
N3 C3 Au2 172.5(8) . .
N4 C4 Au2 172.6(7) . .
N5 C5 Au3 173.5(8) . .
N6 C6 Au3 174.4(8) . .
N7 C7 Au4 172.3(7) . .
N8 C8 Au4 172.7(8) . .
O1 C9 C10 118.4(8) . .
O1 C9 C14 123.1(7) . .
C10 C9 C14 118.5(8) . .
C11 C10 C9 120.5(10) . .
C11 C10 H10 119.7 . .
C9 C10 H10 119.7 . .
C10 C11 C12 122.3(10) . .
C10 C11 H11 118.9 . .
C12 C11 H11 118.9 . .
C11 C12 C13 118.8(10) . .
C11 C12 H12 120.6 . .
C13 C12 H12 120.6 . .
C12 C13 C14 120.3(11) . .
C12 C13 H13 119.9 . .
C14 C13 H13 119.9 . .
C13 C14 C9 119.4(9) . .
C13 C14 C15 118.4(9) . .
C9 C14 C15 122.3(8) . .
N9 C15 C14 126.5(8) . .
N9 C15 H15 116.7 . .
C14 C15 H15 116.7 . .
C17 C16 N9 107.6(6) . .
C17 C16 H16A 110.2 . .
N9 C16 H16A 110.2 . .
C17 C16 H16B 110.2 . .
N9 C16 H16B 110.2 . .
H16A C16 H16B 108.5 . .
C16 C17 N10 108.7(6) . .
C16 C17 H17A 109.9 . .
N10 C17 H17A 109.9 . .
C16 C17 H17B 109.9 . .
N10 C17 H17B 109.9 . .
H17A C17 H17B 108.3 . .
N10 C18 C19 125.0(6) . .
N10 C18 H18 117.5 . .
C19 C18 H18 117.5 . .
C24 C19 C20 118.6(7) . .
C24 C19 C18 124.3(7) . .
C20 C19 C18 116.9(7) . .
C21 C20 C19 121.9(7) . .
C21 C20 H20 119.1 . .
C19 C20 H20 119.1 . .
C20 C21 C22 118.2(8) . .
C20 C21 H21 120.9 . .
C22 C21 H21 120.9 . .
C23 C22 C21 121.8(8) . .
C23 C22 H22 119.1 . .
C21 C22 H22 119.1 . .
C22 C23 C24 120.8(7) . .
C22 C23 H23 119.6 . .
C24 C23 H23 119.6 . .
O2 C24 C23 118.6(6) . .
O2 C24 C19 122.6(7) . .
C23 C24 C19 118.8(7) . .
O3 C25 C26 117.7(7) . .
O3 C25 C30 124.0(7) . .
C26 C25 C30 118.3(8) . .
C27 C26 C25 120.5(8) . .
C27 C26 H26 119.7 . .
C25 C26 H26 119.7 . .
C28 C27 C26 120.6(9) . .
C28 C27 H27 119.7 . .
C26 C27 H27 119.7 . .
C29 C28 C27 119.1(10) . .
C29 C28 H28 120.4 . .
C27 C28 H28 120.4 . .
C28 C29 C30 122.2(9) . .
C28 C29 H29 118.9 . .
C30 C29 H29 118.9 . .
C29 C30 C25 119.1(8) . .
C29 C30 C31 117.5(8) . .
C25 C30 C31 123.4(8) . .
N11 C31 C30 124.9(8) . .
N11 C31 H31 117.6 . .
C30 C31 H31 117.6 . .
C33 C32 N11 108.5(7) . .
C33 C32 H32A 110.0 . .
N11 C32 H32A 110.0 . .
C33 C32 H32B 110.0 . .
N11 C32 H32B 110.0 . .
H32A C32 H32B 108.4 . .
C32 C33 N12 110.5(7) . .
C32 C33 H33A 109.6 . .
N12 C33 H33A 109.6 . .
C32 C33 H33B 109.6 . .
N12 C33 H33B 109.6 . .
H33A C33 H33B 108.1 . .
N12 C34 C35 126.8(7) . .
N12 C34 H34 116.6 . .
C35 C34 H34 116.6 . .
C36 C35 C40 119.6(8) . .
C36 C35 C34 119.4(8) . .
C40 C35 C34 120.6(7) . .
C37 C36 C35 121.9(9) . .
C37 C36 H36 119.1 . .
C35 C36 H36 119.1 . .
C36 C37 C38 119.2(9) . .
C36 C37 H37 120.4 . .
C38 C37 H37 120.4 . .
C39 C38 C37 121.3(9) . .
C39 C38 H38 119.3 . .
C37 C38 H38 119.3 . .
C38 C39 C40 120.7(8) . .
C38 C39 H39 119.7 . .
C40 C39 H39 119.7 . .
O4 C40 C39 118.4(7) . .
O4 C40 C35 124.3(7) . .
C39 C40 C35 117.3(7) . .
O5 C41 C42 118.9(7) . .
O5 C41 C46 123.2(7) . .
C42 C41 C46 117.9(8) . .
C43 C42 C41 121.2(9) . .
C43 C42 H42 119.4 . .
C41 C42 H42 119.4 . .
C42 C43 C44 123.6(10) . .
C42 C43 H43 118.2 . .
C44 C43 H43 118.2 . .
C45 C44 C43 116.4(10) . .
C45 C44 H44 121.8 . .
C43 C44 H44 121.8 . .
C44 C45 C46 122.1(10) . .
C44 C45 H45 119.0 . .
C46 C45 H45 119.0 . .
C41 C46 C45 118.7(9) . .
C41 C46 C47 123.6(7) . .
C45 C46 C47 117.6(9) . .
N13 C47 C46 126.1(8) . .
N13 C47 H47 116.9 . .
C46 C47 H47 116.9 . .
C49 C48 N13 108.5(7) . .
C49 C48 H48A 110.0 . .
N13 C48 H48A 110.0 . .
C49 C48 H48B 110.0 . .
N13 C48 H48B 110.0 . .
H48A C48 H48B 108.4 . .
C48 C49 N14 107.6(7) . .
C48 C49 H49A 110.2 . .
N14 C49 H49A 110.2 . .
C48 C49 H49B 110.2 . .
N14 C49 H49B 110.2 . .
H49A C49 H49B 108.5 . .
N14 C50 C51 124.6(7) . .
N14 C50 H50 117.7 . .
C51 C50 H50 117.7 . .
C52 C51 C56 119.2(8) . .
C52 C51 C50 118.0(8) . .
C56 C51 C50 122.8(8) . .
C53 C52 C51 119.3(9) . .
C53 C52 H52 120.4 . .
C51 C52 H52 120.4 . .
C54 C53 C52 120.9(10) . .
C54 C53 H53 119.6 . .
C52 C53 H53 119.6 . .
C53 C54 C55 121.8(10) . .
C53 C54 H54 119.1 . .
C55 C54 H54 119.1 . .
C54 C55 C56 119.0(9) . .
C54 C55 H55 120.5 . .
C56 C55 H55 120.5 . .
O6 C56 C55 117.3(7) . .
O6 C56 C51 123.1(7) . .
C55 C56 C51 119.6(8) . .
O7 C57 C62 124.4(7) . .
O7 C57 C58 117.9(7) . .
C62 C57 C58 117.7(7) . .
C59 C58 C57 121.3(9) . .
C59 C58 H58 119.4 . .
C57 C58 H58 119.4 . .
C58 C59 C60 120.9(9) . .
C58 C59 H59 119.6 . .
C60 C59 H59 119.6 . .
C61 C60 C59 119.1(9) . .
C61 C60 H60 120.5 . .
C59 C60 H60 120.5 . .
C60 C61 C62 121.6(9) . .
C60 C61 H61 119.2 . .
C62 C61 H61 119.2 . .
C61 C62 C57 119.4(8) . .
C61 C62 C63 118.4(8) . .
C57 C62 C63 122.0(7) . .
N15 C63 C62 126.6(7) . .
N15 C63 H63 116.7 . .
C62 C63 H63 116.7 . .
C65 C64 N15 112.0(8) . .
C65 C64 H64A 109.2 . .
N15 C64 H64A 109.2 . .
C65 C64 H64B 109.2 . .
N15 C64 H64B 109.2 . .
H64A C64 H64B 107.9 . .
C64 C65 N16 111.7(8) . .
C64 C65 H65A 109.3 . .
N16 C65 H65A 109.3 . .
C64 C65 H65B 109.3 . .
N16 C65 H65B 109.3 . .
H65A C65 H65B 107.9 . .
N16 C66 C67 126.1(7) . .
N16 C66 H66 117.0 . .
C67 C66 H66 117.0 . .
C68 C67 C72 119.5(7) . .
C68 C67 C66 117.3(7) . .
C72 C67 C66 123.1(7) . .
C69 C68 C67 121.6(8) . .
C69 C68 H68 119.2 . .
C67 C68 H68 119.2 . .
C68 C69 C70 118.6(8) . .
C68 C69 H69 120.7 . .
C70 C69 H69 120.7 . .
C69 C70 C71 121.4(8) . .
C69 C70 H70 119.3 . .
C71 C70 H70 119.3 . .
C70 C71 C72 120.6(8) . .
C70 C71 H71 119.7 . .
C72 C71 H71 119.7 . .
O8 C72 C71 118.2(7) . .
O8 C72 C67 123.6(6) . .
C71 C72 C67 118.3(7) . .
H9A O9 H9B 107.7 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Au1 C2 1.978(8) .
Au1 C1 1.996(8) .
Au1 Au4 3.1497(13) 1_455
Au2 C4 1.985(8) .
Au2 C3 2.000(8) .
Au2 Au3 3.0959(13) .
Au3 C5 2.010(8) .
Au3 C6 2.011(8) .
Au4 C8 1.976(8) .
Au4 C7 1.987(7) .
Au4 Au1 3.1497(13) 1_655
Mn1 O1 1.866(5) .
Mn1 O2 1.867(5) .
Mn1 N9 1.979(6) .
Mn1 N10 1.982(5) .
Mn1 N1 2.346(7) .
Mn1 N4 2.397(7) 1_445
Mn2 O4 1.851(5) .
Mn2 O3 1.860(5) .
Mn2 N12 1.979(6) .
Mn2 N11 1.994(6) .
Mn2 N2 2.318(7) .
Mn2 N3 2.457(7) .
Mn3 O5 1.869(5) .
Mn3 O6 1.869(5) .
Mn3 N13 1.969(6) .
Mn3 N14 1.971(7) .
Mn3 N8 2.303(7) 1_465
Mn3 N5 2.382(7) .
Mn4 O7 1.879(5) .
Mn4 O8 1.881(5) .
Mn4 N15 1.977(6) .
Mn4 N16 1.988(6) .
Mn4 N6 2.318(6) .
Mn4 N7 2.328(6) .
N1 C1 1.141(10) .
N2 C2 1.150(9) .
N3 C3 1.125(9) .
N4 C4 1.134(9) .
N4 Mn1 2.397(7) 1_665
N5 C5 1.128(9) .
N6 C6 1.107(8) .
N7 C7 1.136(8) .
N8 C8 1.155(9) .
N8 Mn3 2.303(7) 1_645
N9 C15 1.283(10) .
N9 C16 1.473(9) .
N10 C18 1.268(9) .
N10 C17 1.491(9) .
N11 C31 1.259(9) .
N11 C32 1.497(9) .
N12 C34 1.274(10) .
N12 C33 1.481(10) .
N13 C47 1.280(10) .
N13 C48 1.490(10) .
N14 C50 1.278(10) .
N14 C49 1.459(10) .
N15 C63 1.277(9) .
N15 C64 1.460(10) .
N16 C66 1.272(9) .
N16 C65 1.462(10) .
O1 C9 1.332(9) .
O2 C24 1.332(8) .
O3 C25 1.313(9) .
O4 C40 1.330(9) .
O5 C41 1.312(9) .
O6 C56 1.332(9) .
O7 C57 1.330(9) .
O8 C72 1.334(8) .
C9 C10 1.398(10) .
C9 C14 1.409(12) .
C10 C11 1.361(13) .
C10 H10 0.9300 .
C11 C12 1.367(15) .
C11 H11 0.9300 .
C12 C13 1.396(14) .
C12 H12 0.9300 .
C13 C14 1.404(12) .
C13 H13 0.9300 .
C14 C15 1.445(12) .
C15 H15 0.9300 .
C16 C17 1.460(10) .
C16 H16A 0.9700 .
C16 H16B 0.9700 .
C17 H17A 0.9700 .
C17 H17B 0.9700 .
C18 C19 1.449(11) .
C18 H18 0.9300 .
C19 C24 1.400(9) .
C19 C20 1.420(10) .
C20 C21 1.367(11) .
C20 H20 0.9300 .
C21 C22 1.387(11) .
C21 H21 0.9300 .
C22 C23 1.365(11) .
C22 H22 0.9300 .
C23 C24 1.398(10) .
C23 H23 0.9300 .
C25 C26 1.401(10) .
C25 C30 1.415(11) .
C26 C27 1.391(12) .
C26 H26 0.9300 .
C27 C28 1.385(14) .
C27 H27 0.9300 .
C28 C29 1.362(13) .
C28 H28 0.9300 .
C29 C30 1.393(12) .
C29 H29 0.9300 .
C30 C31 1.436(11) .
C31 H31 0.9300 .
C32 C33 1.428(12) .
C32 H32A 0.9700 .
C32 H32B 0.9700 .
C33 H33A 0.9700 .
C33 H33B 0.9700 .
C34 C35 1.434(11) .
C34 H34 0.9300 .
C35 C36 1.387(11) .
C35 C40 1.426(10) .
C36 C37 1.360(13) .
C36 H36 0.9300 .
C37 C38 1.382(13) .
C37 H37 0.9300 .
C38 C39 1.372(12) .
C38 H38 0.9300 .
C39 C40 1.412(10) .
C39 H39 0.9300 .
C41 C42 1.398(11) .
C41 C46 1.407(11) .
C42 C43 1.333(12) .
C42 H42 0.9300 .
C43 C44 1.386(14) .
C43 H43 0.9300 .
C44 C45 1.384(15) .
C44 H44 0.9300 .
C45 C46 1.413(11) .
C45 H45 0.9300 .
C46 C47 1.430(12) .
C47 H47 0.9300 .
C48 C49 1.458(11) .
C48 H48A 0.9700 .
C48 H48B 0.9700 .
C49 H49A 0.9700 .
C49 H49B 0.9700 .
C50 C51 1.431(11) .
C50 H50 0.9300 .
C51 C52 1.410(12) .
C51 C56 1.419(11) .
C52 C53 1.387(13) .
C52 H52 0.9300 .
C53 C54 1.355(14) .
C53 H53 0.9300 .
C54 C55 1.390(13) .
C54 H54 0.9300 .
C55 C56 1.394(11) .
C55 H55 0.9300 .
C57 C62 1.410(11) .
C57 C58 1.412(10) .
C58 C59 1.367(12) .
C58 H58 0.9300 .
C59 C60 1.383(14) .
C59 H59 0.9300 .
C60 C61 1.373(13) .
C60 H60 0.9300 .
C61 C62 1.399(10) .
C61 H61 0.9300 .
C62 C63 1.434(10) .
C63 H63 0.9300 .
C64 C65 1.386(13) .
C64 H64A 0.9700 .
C64 H64B 0.9700 .
C65 H65A 0.9700 .
C65 H65B 0.9700 .
C66 C67 1.441(11) .
C66 H66 0.9300 .
C67 C68 1.398(10) .
C67 C72 1.402(10) .
C68 C69 1.366(12) .
C68 H68 0.9300 .
C69 C70 1.374(12) .
C69 H69 0.9300 .
C70 C71 1.384(11) .
C70 H70 0.9300 .
C71 C72 1.388(10) .
C71 H71 0.9300 .
O9 H9A 0.8500 .
O9 H9B 0.8499 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
C4 Au2 Au3 C5 -84.3(3) .
C3 Au2 Au3 C5 95.6(3) .
C4 Au2 Au3 C6 98.5(3) .
C3 Au2 Au3 C6 -81.6(3) .
O1 Mn1 N1 C1 159.7(16) .
O2 Mn1 N1 C1 66.9(16) .
N9 Mn1 N1 C1 -107.8(16) .
N10 Mn1 N1 C1 -25.2(16) .
N4 Mn1 N1 C1 -60(2) 1_445
O4 Mn2 N2 C2 -174.5(12) .
O3 Mn2 N2 C2 92.7(12) .
N12 Mn2 N2 C2 -82.6(12) .
N11 Mn2 N2 C2 0.5(12) .
N3 Mn2 N2 C2 -23(2) .
O4 Mn2 N3 C3 66.1(14) .
O3 Mn2 N3 C3 158.6(14) .
N12 Mn2 N3 C3 -25.1(14) .
N11 Mn2 N3 C3 -108.9(14) .
N2 Mn2 N3 C3 -85.0(19) .
O5 Mn3 N5 C5 -88.6(13) .
O6 Mn3 N5 C5 178.0(13) .
N13 Mn3 N5 C5 4.4(13) .
N14 Mn3 N5 C5 86.9(13) .
N8 Mn3 N5 C5 31(2) 1_465
O7 Mn4 N6 C6 -65.2(16) .
O8 Mn4 N6 C6 -159.1(16) .
N15 Mn4 N6 C6 27.4(16) .
N16 Mn4 N6 C6 108.8(16) .
N7 Mn4 N6 C6 71(3) .
O7 Mn4 N7 C7 -166.8(14) .
O8 Mn4 N7 C7 -72.9(14) .
N15 Mn4 N7 C7 100.8(14) .
N16 Mn4 N7 C7 19.2(14) .
N6 Mn4 N7 C7 57(3) .
O1 Mn1 N9 C15 10.0(8) .
O2 Mn1 N9 C15 164(2) .
N10 Mn1 N9 C15 -166.3(8) .
N1 Mn1 N9 C15 -82.1(7) .
N4 Mn1 N9 C15 108.0(7) 1_445
O1 Mn1 N9 C16 -171.5(5) .
O2 Mn1 N9 C16 -18(3) .
N10 Mn1 N9 C16 12.1(5) .
N1 Mn1 N9 C16 96.4(5) .
N4 Mn1 N9 C16 -73.5(5) 1_445
O1 Mn1 N10 C18 156(2) .
O2 Mn1 N10 C18 8.3(7) .
N9 Mn1 N10 C18 -168.8(7) .
N1 Mn1 N10 C18 103.1(7) .
N4 Mn1 N10 C18 -84.8(7) 1_445
O1 Mn1 N10 C17 -23(3) .
O2 Mn1 N10 C17 -170.2(5) .
N9 Mn1 N10 C17 12.7(5) .
N1 Mn1 N10 C17 -75.3(5) .
N4 Mn1 N10 C17 96.8(5) 1_445
O4 Mn2 N11 C31 -162(3) .
O3 Mn2 N11 C31 9.9(7) .
N12 Mn2 N11 C31 -164.3(7) .
N2 Mn2 N11 C31 104.5(7) .
N3 Mn2 N11 C31 -80.5(7) .
O4 Mn2 N11 C32 15(3) .
O3 Mn2 N11 C32 -173.1(5) .
N12 Mn2 N11 C32 12.8(5) .
N2 Mn2 N11 C32 -78.4(5) .
N3 Mn2 N11 C32 96.6(5) .
O4 Mn2 N12 C34 5.5(7) .
O3 Mn2 N12 C34 131.5(19) .
N11 Mn2 N12 C34 -174.6(7) .
N2 Mn2 N12 C34 -89.9(7) .
N3 Mn2 N12 C34 100.7(7) .
O4 Mn2 N12 C33 -169.1(5) .
O3 Mn2 N12 C33 -43(2) .
N11 Mn2 N12 C33 10.7(5) .
N2 Mn2 N12 C33 95.4(5) .
N3 Mn2 N12 C33 -74.0(5) .
O5 Mn3 N13 C47 -7.5(7) .
O6 Mn3 N13 C47 170(2) .
N14 Mn3 N13 C47 174.4(7) .
N8 Mn3 N13 C47 86.3(7) 1_465
N5 Mn3 N13 C47 -99.5(7) .
O5 Mn3 N13 C48 171.4(6) .
O6 Mn3 N13 C48 -11(3) .
N14 Mn3 N13 C48 -6.8(6) .
N8 Mn3 N13 C48 -94.9(6) 1_465
N5 Mn3 N13 C48 79.3(6) .
O5 Mn3 N14 C50 138(3) .
O6 Mn3 N14 C50 -21.5(6) .
N13 Mn3 N14 C50 159.0(7) .
N8 Mn3 N14 C50 -115.9(6) 1_465
N5 Mn3 N14 C50 74.8(6) .
O5 Mn3 N14 C49 -39(3) .
O6 Mn3 N14 C49 161.7(6) .
N13 Mn3 N14 C49 -17.8(5) .
N8 Mn3 N14 C49 67.3(6) 1_465
N5 Mn3 N14 C49 -102.0(6) .
O7 Mn4 N15 C63 -2.4(6) .
O8 Mn4 N15 C63 158.1(18) .
N16 Mn4 N15 C63 177.2(7) .
N6 Mn4 N15 C63 -93.2(6) .
N7 Mn4 N15 C63 91.4(6) .
O7 Mn4 N15 C64 172.1(6) .
O8 Mn4 N15 C64 -27(2) .
N16 Mn4 N15 C64 -8.4(6) .
N6 Mn4 N15 C64 81.3(6) .
N7 Mn4 N15 C64 -94.2(6) .
O7 Mn4 N16 C66 -178.8(19) .
O8 Mn4 N16 C66 -5.6(6) .
N15 Mn4 N16 C66 176.6(6) .
N6 Mn4 N16 C66 87.8(6) .
N7 Mn4 N16 C66 -96.1(6) .
O7 Mn4 N16 C65 -4(2) .
O8 Mn4 N16 C65 168.8(6) .
N15 Mn4 N16 C65 -9.0(6) .
N6 Mn4 N16 C65 -97.8(6) .
N7 Mn4 N16 C65 78.2(6) .
O2 Mn1 O1 C9 161.5(6) .
N9 Mn1 O1 C9 -21.0(6) .
N10 Mn1 O1 C9 14(3) .
N1 Mn1 O1 C9 66.3(6) .
N4 Mn1 O1 C9 -104.8(6) 1_445
O1 Mn1 O2 C24 176.0(6) .
N9 Mn1 O2 C24 22(3) .
N10 Mn1 O2 C24 -7.3(7) .
N1 Mn1 O2 C24 -91.5(6) .
N4 Mn1 O2 C24 77.6(6) 1_445
O4 Mn2 O3 C25 165.7(6) .
N12 Mn2 O3 C25 40(2) .
N11 Mn2 O3 C25 -13.7(6) .
N2 Mn2 O3 C25 -98.7(6) .
N3 Mn2 O3 C25 70.3(6) .
O3 Mn2 O4 C40 -177.5(6) .
N12 Mn2 O4 C40 -3.3(6) .
N11 Mn2 O4 C40 -5(3) .
N2 Mn2 O4 C40 87.4(6) .
N3 Mn2 O4 C40 -86.7(6) .
O6 Mn3 O5 C41 -168.8(6) .
N13 Mn3 O5 C41 10.9(6) .
N14 Mn3 O5 C41 32(3) .
N8 Mn3 O5 C41 -74.1(6) 1_465
N5 Mn3 O5 C41 94.6(6) .
O5 Mn3 O6 C56 -153.2(6) .
N13 Mn3 O6 C56 30(3) .
N14 Mn3 O6 C56 25.0(6) .
N8 Mn3 O6 C56 112.5(6) 1_465
N5 Mn3 O6 C56 -60.5(6) .
O8 Mn4 O7 C57 179.1(6) .
N15 Mn4 O7 C57 -3.2(6) .
N16 Mn4 O7 C57 -8(2) .
N6 Mn4 O7 C57 85.6(6) .
N7 Mn4 O7 C57 -89.9(6) .
O7 Mn4 O8 C72 -173.7(5) .
N15 Mn4 O8 C72 26(2) .
N16 Mn4 O8 C72 7.0(6) .
N6 Mn4 O8 C72 -82.6(6) .
N7 Mn4 O8 C72 92.4(6) .
Mn1 N1 C1 Au1 -35(6) .
C2 Au1 C1 N1 -10(7) .
Au4 Au1 C1 N1 6(4) 1_455
Mn2 N2 C2 Au1 -14(7) .
C1 Au1 C2 N2 3(9) .
Au4 Au1 C2 N2 -13(6) 1_455
Mn2 N3 C3 Au2 -46(6) .
C4 Au2 C3 N3 24(8) .
Au3 Au2 C3 N3 23(5) .
Mn1 N4 C4 Au2 -44(6) 1_665
C3 Au2 C4 N4 14(8) .
Au3 Au2 C4 N4 15(5) .
Mn3 N5 C5 Au3 63(7) .
C6 Au3 C5 N5 -4(10) .
Au2 Au3 C5 N5 -39(7) .
Mn4 N6 C6 Au3 -14(9) .
C5 Au3 C6 N6 -6(10) .
Au2 Au3 C6 N6 30(8) .
Mn4 N7 C7 Au4 12(6) .
C8 Au4 C7 N7 -26(9) .
Au1 Au4 C7 N7 14(5) 1_655
Mn3 N8 C8 Au4 39(7) 1_645
C7 Au4 C8 N8 21(9) .
Au1 Au4 C8 N8 -20(6) 1_655
Mn1 O1 C9 C10 -158.7(6) .
Mn1 O1 C9 C14 22.4(11) .
O1 C9 C10 C11 -176.6(8) .
C14 C9 C10 C11 2.3(13) .
C9 C10 C11 C12 0.2(16) .
C10 C11 C12 C13 0.0(18) .
C11 C12 C13 C14 -2.9(18) .
C12 C13 C14 C9 5.4(16) .
C12 C13 C14 C15 -173.9(10) .
O1 C9 C14 C13 173.8(9) .
C10 C9 C14 C13 -5.0(13) .
O1 C9 C14 C15 -6.9(13) .
C10 C9 C14 C15 174.2(8) .
C16 N9 C15 C14 -178.7(8) .
Mn1 N9 C15 C14 -0.4(13) .
C13 C14 C15 N9 175.1(10) .
C9 C14 C15 N9 -4.1(15) .
C15 N9 C16 C17 144.0(8) .
Mn1 N9 C16 C17 -34.5(8) .
N9 C16 C17 N10 43.9(9) .
C18 N10 C17 C16 146.3(8) .
Mn1 N10 C17 C16 -35.2(8) .
C17 N10 C18 C19 172.9(7) .
Mn1 N10 C18 C19 -5.4(11) .
N10 C18 C19 C24 -1.5(12) .
N10 C18 C19 C20 -175.9(8) .
C24 C19 C20 C21 0.2(13) .
C18 C19 C20 C21 174.8(8) .
C19 C20 C21 C22 0.1(14) .
C20 C21 C22 C23 0.5(15) .
C21 C22 C23 C24 -1.3(14) .
Mn1 O2 C24 C23 -178.6(5) .
Mn1 O2 C24 C19 3.3(11) .
C22 C23 C24 O2 -176.7(8) .
C22 C23 C24 C19 1.5(12) .
C20 C19 C24 O2 177.1(7) .
C18 C19 C24 O2 2.9(12) .
C20 C19 C24 C23 -1.0(11) .
C18 C19 C24 C23 -175.2(7) .
Mn2 O3 C25 C26 -166.9(5) .
Mn2 O3 C25 C30 12.8(11) .
O3 C25 C26 C27 -179.3(8) .
C30 C25 C26 C27 1.0(12) .
C25 C26 C27 C28 2.1(14) .
C26 C27 C28 C29 -3.0(16) .
C27 C28 C29 C30 0.8(16) .
C28 C29 C30 C25 2.3(14) .
C28 C29 C30 C31 -177.2(9) .
O3 C25 C30 C29 177.2(8) .
C26 C25 C30 C29 -3.2(12) .
O3 C25 C30 C31 -3.3(12) .
C26 C25 C30 C31 176.4(7) .
C32 N11 C31 C30 178.3(7) .
Mn2 N11 C31 C30 -5.0(12) .
C29 C30 C31 N11 179.2(8) .
C25 C30 C31 N11 -0.4(13) .
C31 N11 C32 C33 142.7(8) .
Mn2 N11 C32 C33 -34.4(9) .
N11 C32 C33 N12 43.6(10) .
C34 N12 C33 C32 151.6(8) .
Mn2 N12 C33 C32 -33.6(8) .
C33 N12 C34 C35 170.6(7) .
Mn2 N12 C34 C35 -3.5(12) .
N12 C34 C35 C36 -175.7(8) .
N12 C34 C35 C40 -2.6(13) .
C40 C35 C36 C37 -1.2(13) .
C34 C35 C36 C37 172.0(8) .
C35 C36 C37 C38 2.2(14) .
C36 C37 C38 C39 -2.1(14) .
C37 C38 C39 C40 1.1(14) .
Mn2 O4 C40 C39 176.9(5) .
Mn2 O4 C40 C35 -1.1(10) .
C38 C39 C40 O4 -178.3(7) .
C38 C39 C40 C35 -0.2(12) .
C36 C35 C40 O4 178.2(7) .
C34 C35 C40 O4 5.1(11) .
C36 C35 C40 C39 0.2(11) .
C34 C35 C40 C39 -172.9(7) .
Mn3 O5 C41 C42 169.1(5) .
Mn3 O5 C41 C46 -9.5(10) .
O5 C41 C42 C43 179.3(8) .
C46 C41 C42 C43 -2.0(12) .
C41 C42 C43 C44 2.3(14) .
C42 C43 C44 C45 -2.4(15) .
C43 C44 C45 C46 2.3(15) .
O5 C41 C46 C45 -179.5(7) .
C42 C41 C46 C45 1.9(11) .
O5 C41 C46 C47 1.5(11) .
C42 C41 C46 C47 -177.2(7) .
C44 C45 C46 C41 -2.2(13) .
C44 C45 C46 C47 176.9(9) .
C48 N13 C47 C46 -175.7(8) .
Mn3 N13 C47 C46 3.0(12) .
C41 C46 C47 N13 1.7(13) .
C45 C46 C47 N13 -177.4(8) .
C47 N13 C48 C49 -151.5(8) .
Mn3 N13 C48 C49 29.7(9) .
N13 C48 C49 N14 -42.9(10) .
C50 N14 C49 C48 -138.2(8) .
Mn3 N14 C49 C48 38.7(9) .
C49 N14 C50 C51 -175.5(7) .
Mn3 N14 C50 C51 8.0(11) .
N14 C50 C51 C52 -171.2(7) .
N14 C50 C51 C56 11.0(12) .
C56 C51 C52 C53 1.8(12) .
C50 C51 C52 C53 -176.1(8) .
C51 C52 C53 C54 1.2(14) .
C52 C53 C54 C55 -1.0(14) .
C53 C54 C55 C56 -2.4(13) .
Mn3 O6 C56 C55 164.5(5) .
Mn3 O6 C56 C51 -15.1(10) .
C54 C55 C56 O6 -174.2(7) .
C54 C55 C56 C51 5.4(11) .
C52 C51 C56 O6 174.4(7) .
C50 C51 C56 O6 -7.8(11) .
C52 C51 C56 C55 -5.1(11) .
C50 C51 C56 C55 172.7(7) .
Mn4 O7 C57 C62 7.7(10) .
Mn4 O7 C57 C58 -174.3(5) .
O7 C57 C58 C59 179.9(7) .
C62 C57 C58 C59 -1.9(11) .
C57 C58 C59 C60 3.8(13) .
C58 C59 C60 C61 -3.5(14) .
C59 C60 C61 C62 1.5(14) .
C60 C61 C62 C57 0.3(12) .
C60 C61 C62 C63 -175.5(8) .
O7 C57 C62 C61 178.0(7) .
C58 C57 C62 C61 -0.1(10) .
O7 C57 C62 C63 -6.4(11) .
C58 C57 C62 C63 175.6(6) .
C64 N15 C63 C62 -170.3(8) .
Mn4 N15 C63 C62 3.8(11) .
C61 C62 C63 N15 176.0(7) .
C57 C62 C63 N15 0.3(12) .
C63 N15 C64 C65 -160.0(9) .
Mn4 N15 C64 C65 25.2(12) .
N15 C64 C65 N16 -32.4(14) .
C66 N16 C65 C64 -159.7(9) .
Mn4 N16 C65 C64 25.6(12) .
C65 N16 C66 C67 -171.9(8) .
Mn4 N16 C66 C67 2.0(10) .
N16 C66 C67 C68 179.0(7) .
N16 C66 C67 C72 2.7(11) .
C72 C67 C68 C69 -2.1(11) .
C66 C67 C68 C69 -178.6(7) .
C67 C68 C69 C70 2.0(13) .
C68 C69 C70 C71 -1.2(13) .
C69 C70 C71 C72 0.6(12) .
Mn4 O8 C72 C71 176.1(5) .
Mn4 O8 C72 C67 -4.8(9) .
C70 C71 C72 O8 178.4(7) .
C70 C71 C72 C67 -0.7(11) .
C68 C67 C72 O8 -177.6(6) .
C66 C67 C72 O8 -1.4(10) .
C68 C67 C72 C71 1.4(10) .
C66 C67 C72 C71 177.7(6) .
