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#$Date: 2016-03-26 02:20:11 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180133 $
#$URL: svn://www.crystallography.net/cod/cif/7/10/31/7103179.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7103179
loop_
_publ_author_name
'Geier, Stephen J'
'Stephan, Douglas W'
_publ_section_title
;
 Activation of P5R5 (R = Ph, Et) by a Rh-beta-diketiminate complex.
;
_journal_issue                   24
_journal_name_full
'Chemical communications (Cambridge, England)'
_journal_page_first              2779
_journal_page_last               2781
_journal_paper_doi               10.1039/b803277g
_journal_year                    2008
_chemical_formula_sum            'C62 H73 N2 P5 Rh'
_chemical_formula_weight         1103.98
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 105.382(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   12.652(2)
_cell_length_b                   23.285(4)
_cell_length_c                   20.121(4)
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      25.0
_cell_measurement_theta_min      2.0
_cell_volume                     5715.3(18)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.927
_diffrn_measured_fraction_theta_max 0.927
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.1099
_diffrn_reflns_av_sigmaI/netI    0.1099
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       31
_diffrn_reflns_limit_k_min       -30
_diffrn_reflns_limit_l_max       25
_diffrn_reflns_limit_l_min       -26
_diffrn_reflns_number            63117
_diffrn_reflns_theta_full        28.29
_diffrn_reflns_theta_max         28.29
_diffrn_reflns_theta_min         1.75
_exptl_absorpt_coefficient_mu    0.479
_exptl_absorpt_correction_T_max  1.0000
_exptl_absorpt_correction_T_min  0.753099
_exptl_absorpt_correction_type   empirical
_exptl_crystal_density_diffrn    1.283
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             2316
_exptl_crystal_size_max          0.25
_exptl_crystal_size_mid          0.24
_exptl_crystal_size_min          0.19
_refine_diff_density_max         0.772
_refine_diff_density_min         -0.376
_refine_diff_density_rms         0.088
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.022
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     631
_refine_ls_number_reflns         13164
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.022
_refine_ls_R_factor_all          0.1377
_refine_ls_R_factor_gt           0.0568
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0568P)²+1.7371P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1090
_refine_ls_wR_factor_ref         0.1434
_reflns_number_gt                7128
_reflns_number_total             13164
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b803277g.txt
_cod_data_source_block           (NacNac)Rh(P5Ph5)C3H7
_cod_original_sg_symbol_H-M      P21/c
_cod_database_code               7103179
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Rh1 Rh 0.41857(3) 0.645218(14) 0.787820(17) 0.03154(11) Uani 1 1 d . . .
P1 P 0.45143(9) 0.73027(5) 0.84235(6) 0.0327(3) Uani 1 1 d . . .
P2 P 0.27039(9) 0.70277(5) 0.74682(6) 0.0351(3) Uani 1 1 d . . .
P3 P 0.37517(10) 0.77909(5) 0.74963(6) 0.0384(3) Uani 1 1 d . . .
P4 P 0.18473(10) 0.71406(5) 0.83042(6) 0.0394(3) Uani 1 1 d . . .
P5 P 0.33379(10) 0.74419(5) 0.90769(6) 0.0381(3) Uani 1 1 d . . .
N1 N 0.3584(3) 0.56619(15) 0.74237(18) 0.0408(9) Uani 1 1 d . . .
N2 N 0.5741(3) 0.60957(15) 0.82313(17) 0.0344(8) Uani 1 1 d . . .
C1 C 0.2536(4) 0.56102(19) 0.6925(2) 0.0438(12) Uani 1 1 d . . .
C2 C 0.1595(4) 0.5476(2) 0.7145(3) 0.0529(13) Uani 1 1 d . . .
C3 C 0.0646(5) 0.5333(3) 0.6645(3) 0.0735(18) Uani 1 1 d . . .
H3A H 0.0019 0.5233 0.6777 0.088 Uiso 1 1 calc R . .
C4 C 0.0618(6) 0.5336(3) 0.5956(3) 0.084(2) Uani 1 1 d . . .
H4A H -0.0020 0.5230 0.5628 0.101 Uiso 1 1 calc R . .
C5 C 0.1527(6) 0.5493(3) 0.5751(3) 0.0753(18) Uani 1 1 d . . .
H5A H 0.1485 0.5507 0.5283 0.090 Uiso 1 1 calc R . .
C6 C 0.2502(5) 0.5630(2) 0.6221(3) 0.0565(14) Uani 1 1 d . . .
C7 C 0.1599(4) 0.5502(2) 0.7896(3) 0.0587(15) Uani 1 1 d . . .
H7A H 0.2083 0.5821 0.8096 0.070 Uiso 1 1 calc R . .
C8 C 0.2069(6) 0.4974(3) 0.8315(3) 0.087(2) Uani 1 1 d . . .
H8A H 0.2770 0.4885 0.8242 0.130 Uiso 1 1 calc R . .
H8B H 0.1581 0.4655 0.8172 0.130 Uiso 1 1 calc R . .
H8C H 0.2152 0.5050 0.8795 0.130 Uiso 1 1 calc R . .
C9 C 0.0479(5) 0.5642(3) 0.8019(3) 0.085(2) Uani 1 1 d . . .
H9A H 0.0177 0.5976 0.7757 0.128 Uiso 1 1 calc R . .
H9B H 0.0569 0.5715 0.8500 0.128 Uiso 1 1 calc R . .
H9C H -0.0008 0.5323 0.7877 0.128 Uiso 1 1 calc R . .
C10 C 0.3526(6) 0.5764(3) 0.5985(3) 0.0784(19) Uani 1 1 d . . .
H10A H 0.4124 0.5837 0.6399 0.094 Uiso 1 1 calc R . .
C11 C 0.3886(10) 0.5290(4) 0.5598(6) 0.214(7) Uani 1 1 d . . .
H11A H 0.4532 0.5406 0.5469 0.321 Uiso 1 1 calc R . .
H11B H 0.3312 0.5204 0.5191 0.321 Uiso 1 1 calc R . .
H11C H 0.4045 0.4954 0.5884 0.321 Uiso 1 1 calc R . .
C12 C 0.3402(9) 0.6281(3) 0.5551(6) 0.172(5) Uani 1 1 d . . .
H12A H 0.4066 0.6346 0.5418 0.258 Uiso 1 1 calc R . .
H12B H 0.3254 0.6606 0.5806 0.258 Uiso 1 1 calc R . .
H12C H 0.2805 0.6227 0.5147 0.258 Uiso 1 1 calc R . .
C13 C 0.3639(5) 0.4606(2) 0.7221(3) 0.0675(17) Uani 1 1 d . . .
H13A H 0.2890 0.4670 0.6970 0.101 Uiso 1 1 calc R . .
H13B H 0.3666 0.4331 0.7581 0.101 Uiso 1 1 calc R . .
H13C H 0.4040 0.4461 0.6913 0.101 Uiso 1 1 calc R . .
C14 C 0.4148(4) 0.51702(19) 0.7536(2) 0.0448(12) Uani 1 1 d . . .
C15 C 0.5240(4) 0.5117(2) 0.7908(2) 0.0487(13) Uani 1 1 d . . .
H15A H 0.5500 0.4743 0.7984 0.058 Uiso 1 1 calc R . .
C16 C 0.5995(4) 0.5545(2) 0.8182(2) 0.0408(11) Uani 1 1 d . . .
C17 C 0.7180(4) 0.5346(2) 0.8399(3) 0.0548(14) Uani 1 1 d . . .
H17A H 0.7646 0.5666 0.8580 0.082 Uiso 1 1 calc R . .
H17B H 0.7380 0.5191 0.8007 0.082 Uiso 1 1 calc R . .
H17C H 0.7263 0.5055 0.8747 0.082 Uiso 1 1 calc R . .
C18 C 0.6686(3) 0.64650(19) 0.8429(2) 0.0380(10) Uani 1 1 d . . .
C19 C 0.7182(4) 0.65907(18) 0.9123(2) 0.0396(11) Uani 1 1 d . . .
C20 C 0.8186(4) 0.6869(2) 0.9274(3) 0.0552(14) Uani 1 1 d . . .
H20A H 0.8546 0.6942 0.9733 0.066 Uiso 1 1 calc R . .
C21 C 0.8669(4) 0.7043(2) 0.8772(3) 0.0654(16) Uani 1 1 d . . .
H21A H 0.9346 0.7226 0.8891 0.078 Uiso 1 1 calc R . .
C22 C 0.8139(4) 0.6943(2) 0.8093(3) 0.0602(15) Uani 1 1 d . . .
H22A H 0.8459 0.7067 0.7752 0.072 Uiso 1 1 calc R . .
C23 C 0.7145(4) 0.6663(2) 0.7904(3) 0.0463(12) Uani 1 1 d . . .
C24 C 0.6662(4) 0.6424(2) 0.9694(2) 0.0472(12) Uani 1 1 d . . .
H24A H 0.5887 0.6531 0.9535 0.057 Uiso 1 1 calc R . .
C25 C 0.7132(5) 0.6745(3) 1.0367(3) 0.0725(17) Uani 1 1 d . . .
H25A H 0.7116 0.7150 1.0279 0.109 Uiso 1 1 calc R . .
H25B H 0.7875 0.6624 1.0565 0.109 Uiso 1 1 calc R . .
H25C H 0.6701 0.6661 1.0683 0.109 Uiso 1 1 calc R . .
C26 C 0.6691(5) 0.5781(2) 0.9869(3) 0.0694(17) Uani 1 1 d . . .
H26A H 0.6403 0.5564 0.9455 0.104 Uiso 1 1 calc R . .
H26B H 0.6254 0.5712 1.0185 0.104 Uiso 1 1 calc R . .
H26C H 0.7434 0.5666 1.0078 0.104 Uiso 1 1 calc R . .
C27 C 0.6594(5) 0.6565(3) 0.7145(3) 0.0661(17) Uani 1 1 d . . .
H27A H 0.5888 0.6380 0.7116 0.079 Uiso 1 1 calc R . .
C28 C 0.6361(7) 0.7104(3) 0.6742(3) 0.117(3) Uani 1 1 d . . .
H28A H 0.5951 0.7359 0.6955 0.176 Uiso 1 1 calc R . .
H28B H 0.5942 0.7019 0.6281 0.176 Uiso 1 1 calc R . .
H28C H 0.7038 0.7284 0.6730 0.176 Uiso 1 1 calc R . .
C29 C 0.7232(9) 0.6168(3) 0.6807(4) 0.152(4) Uani 1 1 d . . .
H29A H 0.6850 0.6121 0.6330 0.228 Uiso 1 1 calc R . .
H29B H 0.7309 0.5801 0.7033 0.228 Uiso 1 1 calc R . .
H29C H 0.7945 0.6327 0.6844 0.228 Uiso 1 1 calc R . .
C30 C 0.5683(4) 0.77577(18) 0.8854(2) 0.0374(10) Uani 1 1 d . . .
C31 C 0.5838(4) 0.7953(2) 0.9519(3) 0.0592(15) Uani 1 1 d . . .
H31A H 0.5394 0.7821 0.9787 0.071 Uiso 1 1 calc R . .
C32 C 0.6663(5) 0.8351(3) 0.9788(3) 0.0761(19) Uani 1 1 d . . .
H32A H 0.6758 0.8485 1.0235 0.091 Uiso 1 1 calc R . .
C33 C 0.7332(5) 0.8547(3) 0.9408(4) 0.0731(18) Uani 1 1 d . . .
H33A H 0.7868 0.8819 0.9590 0.088 Uiso 1 1 calc R . .
C34 C 0.7207(4) 0.8340(2) 0.8756(3) 0.0631(16) Uani 1 1 d . . .
H34A H 0.7676 0.8461 0.8498 0.076 Uiso 1 1 calc R . .
C35 C 0.6379(4) 0.7951(2) 0.8481(3) 0.0498(13) Uani 1 1 d . . .
H35A H 0.6292 0.7818 0.8034 0.060 Uiso 1 1 calc R . .
C36 C 0.1645(4) 0.7049(2) 0.6647(2) 0.0416(11) Uani 1 1 d . . .
C37 C 0.0669(4) 0.6755(2) 0.6564(3) 0.0590(15) Uani 1 1 d . . .
H37A H 0.0534 0.6552 0.6931 0.071 Uiso 1 1 calc R . .
C38 C -0.0110(5) 0.6763(3) 0.5928(3) 0.0714(17) Uani 1 1 d . . .
H38A H -0.0768 0.6567 0.5874 0.086 Uiso 1 1 calc R . .
C39 C 0.0080(5) 0.7053(3) 0.5390(3) 0.0750(19) Uani 1 1 d . . .
H39A H -0.0446 0.7056 0.4967 0.090 Uiso 1 1 calc R . .
C40 C 0.1039(5) 0.7341(3) 0.5466(3) 0.0715(17) Uani 1 1 d . . .
H40A H 0.1168 0.7536 0.5092 0.086 Uiso 1 1 calc R . .
C41 C 0.1829(4) 0.7347(2) 0.6093(3) 0.0568(14) Uani 1 1 d . . .
H41A H 0.2479 0.7549 0.6141 0.068 Uiso 1 1 calc R . .
C42 C 0.3136(4) 0.84546(19) 0.7719(3) 0.0440(12) Uani 1 1 d . . .
C43 C 0.3657(5) 0.8783(2) 0.8278(3) 0.0606(15) Uani 1 1 d . . .
H43A H 0.4314 0.8656 0.8570 0.073 Uiso 1 1 calc R . .
C44 C 0.3218(6) 0.9301(2) 0.8412(3) 0.0760(18) Uani 1 1 d . . .
H44A H 0.3583 0.9520 0.8790 0.091 Uiso 1 1 calc R . .
C45 C 0.2245(6) 0.9493(2) 0.7988(4) 0.0743(19) Uani 1 1 d . . .
H45A H 0.1941 0.9837 0.8083 0.089 Uiso 1 1 calc R . .
C46 C 0.1726(5) 0.9173(2) 0.7423(4) 0.0714(18) Uani 1 1 d . . .
H46A H 0.1070 0.9303 0.7132 0.086 Uiso 1 1 calc R . .
C47 C 0.2172(4) 0.8658(2) 0.7285(3) 0.0573(14) Uani 1 1 d . . .
H47A H 0.1819 0.8448 0.6897 0.069 Uiso 1 1 calc R . .
C48 C 0.0996(4) 0.78004(19) 0.8172(3) 0.0436(12) Uani 1 1 d . . .
C49 C 0.0140(4) 0.7858(2) 0.7580(3) 0.0556(14) Uani 1 1 d . . .
H49A H 0.0053 0.7589 0.7228 0.067 Uiso 1 1 calc R . .
C50 C -0.0590(5) 0.8315(3) 0.7508(4) 0.0716(18) Uani 1 1 d . . .
H50A H -0.1155 0.8353 0.7107 0.086 Uiso 1 1 calc R . .
C51 C -0.0478(5) 0.8708(3) 0.8026(4) 0.0761(19) Uani 1 1 d . . .
H51A H -0.0965 0.9014 0.7975 0.091 Uiso 1 1 calc R . .
C52 C 0.0342(5) 0.8653(2) 0.8614(4) 0.0711(17) Uani 1 1 d . . .
H52A H 0.0407 0.8915 0.8971 0.085 Uiso 1 1 calc R . .
C53 C 0.1077(4) 0.8205(2) 0.8680(3) 0.0585(14) Uani 1 1 d . . .
H53A H 0.1646 0.8176 0.9081 0.070 Uiso 1 1 calc R . .
C54 C 0.3672(4) 0.6820(2) 0.9659(2) 0.0401(11) Uani 1 1 d . . .
C55 C 0.4016(4) 0.6944(2) 1.0360(3) 0.0558(14) Uani 1 1 d . . .
H55A H 0.4058 0.7323 1.0509 0.067 Uiso 1 1 calc R . .
C56 C 0.4296(5) 0.6502(3) 1.0834(3) 0.0734(18) Uani 1 1 d . . .
H56A H 0.4534 0.6586 1.1302 0.088 Uiso 1 1 calc R . .
C57 C 0.4225(5) 0.5945(3) 1.0618(3) 0.0769(19) Uani 1 1 d . . .
H57A H 0.4404 0.5651 1.0942 0.092 Uiso 1 1 calc R . .
C58 C 0.3895(5) 0.5814(2) 0.9937(3) 0.0661(16) Uani 1 1 d . . .
H58A H 0.3857 0.5433 0.9793 0.079 Uiso 1 1 calc R . .
C59 C 0.3615(4) 0.6252(2) 0.9458(3) 0.0513(13) Uani 1 1 d . . .
H59A H 0.3383 0.6162 0.8992 0.062 Uiso 1 1 calc R . .
C102 C 1.065(2) 0.5654(9) 1.0244(13) 0.39(2) Uani 1 1 d . . .
H10B H 1.1319 0.5475 1.0207 0.466 Uiso 1 1 calc R . .
H10F H 1.0681 0.5619 1.0730 0.466 Uiso 1 1 calc R . .
C101 C 1.0952(14) 0.6135(6) 1.0262(9) 0.244(8) Uani 1 1 d . . .
H10C H 1.1738 0.6144 1.0413 0.366 Uiso 1 1 calc R . .
H10D H 1.0655 0.6351 1.0577 0.366 Uiso 1 1 calc R . .
H10E H 1.0711 0.6301 0.9810 0.366 Uiso 1 1 calc R . .
C103 C 1.0082(14) 0.5273(6) 1.0057(11) 0.251(10) Uani 1 1 d . . .
H10L H 0.9708 0.5415 0.9603 0.301 Uiso 1 1 calc R . .
H10M H 0.9562 0.5338 1.0327 0.301 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N2 Rh1 N1 89.99(14) . . ?
N2 Rh1 P1 98.58(10) . . ?
N1 Rh1 P1 168.65(11) . . ?
N2 Rh1 P2 166.80(10) . . ?
N1 Rh1 P2 100.91(11) . . ?
P1 Rh1 P2 71.69(4) . . ?
C30 P1 P3 102.77(15) . . ?
C30 P1 Rh1 139.36(15) . . ?
P3 P1 Rh1 93.39(6) . . ?
C30 P1 P5 102.42(16) . . ?
P3 P1 P5 102.32(7) . . ?
Rh1 P1 P5 110.23(6) . . ?
C30 P1 P2 156.07(15) . . ?
P3 P1 P2 53.38(5) . . ?
Rh1 P1 P2 54.59(4) . . ?
P5 P1 P2 83.14(6) . . ?
C36 P2 P3 106.98(16) . . ?
C36 P2 P4 106.83(16) . . ?
P3 P2 P4 106.99(7) . . ?
C36 P2 Rh1 132.76(15) . . ?
P3 P2 Rh1 91.92(5) . . ?
P4 P2 Rh1 108.21(6) . . ?
C36 P2 P1 158.95(17) . . ?
P3 P2 P1 52.36(5) . . ?
P4 P2 P1 85.66(6) . . ?
Rh1 P2 P1 53.71(4) . . ?
C42 P3 P1 110.48(16) . . ?
C42 P3 P2 113.10(16) . . ?
P1 P3 P2 74.26(6) . . ?
C48 P4 P5 101.09(17) . . ?
C48 P4 P2 111.52(16) . . ?
P5 P4 P2 94.17(6) . . ?
C54 P5 P4 101.92(16) . . ?
C54 P5 P1 100.48(15) . . ?
P4 P5 P1 96.65(6) . . ?
C14 N1 C1 113.4(4) . . ?
C14 N1 Rh1 124.1(3) . . ?
C1 N1 Rh1 122.4(3) . . ?
C16 N2 C18 113.4(4) . . ?
C16 N2 Rh1 125.7(3) . . ?
C18 N2 Rh1 119.8(3) . . ?
C6 C1 C2 121.3(5) . . ?
C6 C1 N1 118.4(5) . . ?
C2 C1 N1 119.9(4) . . ?
C3 C2 C1 117.8(5) . . ?
C3 C2 C7 120.5(5) . . ?
C1 C2 C7 121.7(4) . . ?
C4 C3 C2 121.0(6) . . ?
C5 C4 C3 120.3(6) . . ?
C4 C5 C6 121.7(6) . . ?
C5 C6 C1 117.8(5) . . ?
C5 C6 C10 120.9(5) . . ?
C1 C6 C10 121.2(5) . . ?
C2 C7 C8 114.8(5) . . ?
C2 C7 C9 114.3(5) . . ?
C8 C7 C9 108.9(5) . . ?
C12 C10 C11 107.1(6) . . ?
C12 C10 C6 112.7(6) . . ?
C11 C10 C6 114.5(6) . . ?
N1 C14 C15 125.2(4) . . ?
N1 C14 C13 121.3(4) . . ?
C15 C14 C13 113.4(4) . . ?
C16 C15 C14 129.0(4) . . ?
N2 C16 C15 124.5(4) . . ?
N2 C16 C17 120.7(4) . . ?
C15 C16 C17 114.7(4) . . ?
C19 C18 C23 120.8(4) . . ?
C19 C18 N2 121.3(4) . . ?
C23 C18 N2 117.7(4) . . ?
C20 C19 C18 117.3(4) . . ?
C20 C19 C24 120.7(4) . . ?
C18 C19 C24 122.0(4) . . ?
C21 C20 C19 122.5(5) . . ?
C20 C21 C22 119.2(5) . . ?
C21 C22 C23 121.6(5) . . ?
C22 C23 C18 118.3(5) . . ?
C22 C23 C27 119.4(5) . . ?
C18 C23 C27 122.2(4) . . ?
C19 C24 C25 113.7(4) . . ?
C19 C24 C26 115.8(4) . . ?
C25 C24 C26 107.1(4) . . ?
C28 C27 C29 109.1(5) . . ?
C28 C27 C23 113.2(5) . . ?
C29 C27 C23 112.9(5) . . ?
C35 C30 C31 118.4(4) . . ?
C35 C30 P1 118.8(4) . . ?
C31 C30 P1 122.6(4) . . ?
C30 C31 C32 119.8(5) . . ?
C33 C32 C31 121.2(6) . . ?
C32 C33 C34 119.3(6) . . ?
C33 C34 C35 119.8(5) . . ?
C30 C35 C34 121.4(5) . . ?
C37 C36 C41 119.1(4) . . ?
C37 C36 P2 120.8(4) . . ?
C41 C36 P2 120.1(4) . . ?
C36 C37 C38 119.7(5) . . ?
C39 C38 C37 120.7(6) . . ?
C38 C39 C40 120.0(5) . . ?
C39 C40 C41 121.0(6) . . ?
C36 C41 C40 119.6(5) . . ?
C43 C42 C47 118.5(5) . . ?
C43 C42 P3 121.6(4) . . ?
C47 C42 P3 119.6(4) . . ?
C42 C43 C44 120.9(6) . . ?
C45 C44 C43 120.2(6) . . ?
C46 C45 C44 119.5(6) . . ?
C45 C46 C47 120.4(6) . . ?
C42 C47 C46 120.6(6) . . ?
C53 C48 C49 117.4(5) . . ?
C53 C48 P4 122.3(4) . . ?
C49 C48 P4 119.7(4) . . ?
C48 C49 C50 120.6(5) . . ?
C51 C50 C49 120.1(6) . . ?
C52 C51 C50 120.2(6) . . ?
C51 C52 C53 119.7(6) . . ?
C48 C53 C52 122.1(6) . . ?
C59 C54 C55 118.3(5) . . ?
C59 C54 P5 125.7(4) . . ?
C55 C54 P5 116.0(4) . . ?
C56 C55 C54 119.9(5) . . ?
C57 C56 C55 120.3(5) . . ?
C58 C57 C56 120.8(5) . . ?
C57 C58 C59 119.4(6) . . ?
C54 C59 C58 121.3(5) . . ?
C103 C102 C101 157(3) . . ?
C102 C103 C103 152(3) . 3_767 ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Rh1 N2 2.079(3) . ?
Rh1 N1 2.105(4) . ?
Rh1 P1 2.2488(12) . ?
Rh1 P2 2.2739(12) . ?
P1 C30 1.839(4) . ?
P1 P3 2.1791(16) . ?
P1 P5 2.2554(17) . ?
P1 P2 2.6486(16) . ?
P2 C36 1.831(4) . ?
P2 P3 2.2088(17) . ?
P2 P4 2.2452(17) . ?
P3 C42 1.839(5) . ?
P4 C48 1.855(5) . ?
P4 P5 2.2160(18) . ?
P5 C54 1.839(5) . ?
N1 C14 1.336(6) . ?
N1 C1 1.439(6) . ?
N2 C16 1.333(5) . ?
N2 C18 1.440(5) . ?
C1 C6 1.407(6) . ?
C1 C2 1.412(7) . ?
C2 C3 1.387(7) . ?
C2 C7 1.510(7) . ?
C3 C4 1.379(8) . ?
C4 C5 1.370(8) . ?
C5 C6 1.378(7) . ?
C6 C10 1.526(8) . ?
C7 C8 1.518(7) . ?
C7 C9 1.536(8) . ?
C10 C12 1.470(9) . ?
C10 C11 1.490(10) . ?
C13 C14 1.525(6) . ?
C14 C15 1.391(7) . ?
C15 C16 1.389(6) . ?
C16 C17 1.518(6) . ?
C18 C19 1.401(6) . ?
C18 C23 1.412(6) . ?
C19 C20 1.386(6) . ?
C19 C24 1.518(6) . ?
C20 C21 1.371(7) . ?
C21 C22 1.373(7) . ?
C22 C23 1.377(7) . ?
C23 C27 1.519(7) . ?
C24 C25 1.523(7) . ?
C24 C26 1.535(7) . ?
C27 C28 1.481(8) . ?
C27 C29 1.502(9) . ?
C30 C35 1.376(6) . ?
C30 C31 1.377(6) . ?
C31 C32 1.392(7) . ?
C32 C33 1.362(8) . ?
C33 C34 1.366(8) . ?
C34 C35 1.384(7) . ?
C36 C37 1.383(7) . ?
C36 C41 1.385(6) . ?
C37 C38 1.393(7) . ?
C38 C39 1.352(8) . ?
C39 C40 1.359(8) . ?
C40 C41 1.387(7) . ?
C42 C43 1.376(7) . ?
C42 C47 1.382(7) . ?
C43 C44 1.384(7) . ?
C44 C45 1.373(8) . ?
C45 C46 1.371(8) . ?
C46 C47 1.384(7) . ?
C48 C53 1.374(7) . ?
C48 C49 1.388(7) . ?
C49 C50 1.390(7) . ?
C50 C51 1.366(8) . ?
C51 C52 1.358(8) . ?
C52 C53 1.380(7) . ?
C54 C59 1.378(7) . ?
C54 C55 1.392(6) . ?
C55 C56 1.384(7) . ?
C56 C57 1.363(8) . ?
C57 C58 1.358(8) . ?
C58 C59 1.383(7) . ?
C102 C103 1.139(18) . ?
C102 C101 1.182(18) . ?
C103 C103 1.30(3) 3_767 ?
