#------------------------------------------------------------------------------
#$Date: 2016-03-26 02:36:26 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180147 $
#$URL: svn://www.crystallography.net/cod/cif/7/10/44/7104444.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7104444
loop_
_publ_author_name
'Guo, Li-Rong'
'Bao, Song-Song'
'Li, Yi-Zhi'
'Zheng, Li-Min'
_publ_section_title
;
 Ag(I)-mediated formation of pyrophosphonate coupled with C-C bond
 cleavage of acetonitrile.
;
_journal_issue                   20
_journal_name_full
'Chemical communications (Cambridge, England)'
_journal_page_first              2893
_journal_page_last               2895
_journal_paper_doi               10.1039/b902162k
_journal_volume                  34
_journal_year                    2009
_chemical_formula_moiety         'C41 H28 Ag5 N O10 P4'
_chemical_formula_sum            'C41 H28 Ag5 N O10 P4'
_chemical_formula_weight         1357.87
_chemical_name_systematic
;
?
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 93.826(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   33.325(2)
_cell_length_b                   13.821(3)
_cell_length_c                   8.807(1)
_cell_measurement_reflns_used    1838
_cell_measurement_temperature    291(2)
_cell_measurement_theta_max      24.44
_cell_measurement_theta_min      2.35
_cell_volume                     4047.3(10)
_computing_cell_refinement       SMART
_computing_data_collection       'SMART (Bruker, 2000)'
_computing_data_reduction        'SAINT (Bruker, 2000)'
_computing_molecular_graphics    SHELXTL
_computing_publication_material  SHELXTL
_computing_structure_refinement  SHELXTL
_computing_structure_solution    'SHELXTL (Bruker, 2000)'
_diffrn_ambient_temperature      291(2)
_diffrn_measured_fraction_theta_full 0.994
_diffrn_measured_fraction_theta_max 0.994
_diffrn_measurement_device_type  'Bruker Smart Apex CCD'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0507
_diffrn_reflns_av_sigmaI/netI    0.0801
_diffrn_reflns_limit_h_max       40
_diffrn_reflns_limit_h_min       -28
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       10
_diffrn_reflns_limit_l_min       -10
_diffrn_reflns_number            10734
_diffrn_reflns_theta_full        26.00
_diffrn_reflns_theta_max         26.00
_diffrn_reflns_theta_min         2.36
_exptl_absorpt_coefficient_mu    2.597
_exptl_absorpt_correction_T_max  0.73
_exptl_absorpt_correction_T_min  0.53
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS; Bruker, 2000'
_exptl_crystal_colour            'pale yellow'
_exptl_crystal_density_diffrn    2.228
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             2624
_exptl_crystal_size_max          0.27
_exptl_crystal_size_mid          0.21
_exptl_crystal_size_min          0.12
_refine_diff_density_max         0.960
_refine_diff_density_min         -0.901
_refine_diff_density_rms         0.156
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.063
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     276
_refine_ls_number_reflns         3951
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.063
_refine_ls_R_factor_all          0.0883
_refine_ls_R_factor_gt           0.0532
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0554P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1065
_refine_ls_wR_factor_ref         0.1146
_reflns_number_gt                2923
_reflns_number_total             3951
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b902162k.txt
_cod_data_source_block           80109c
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_sg_symbol_H-M      'C2/c '
_cod_database_code               7104444
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.009374(16) 0.11422(4) 0.04705(7) 0.03341(16) Uani 1 1 d . . .
Ag3 Ag 0.0000 0.45687(6) 0.2500 0.0337(2) Uani 1 2 d S . .
C1 C 0.1200(2) 0.2219(6) 0.3220(8) 0.0348(16) Uani 1 1 d . . .
C2 C 0.1463(3) 0.2853(6) 0.2579(9) 0.045(2) Uani 1 1 d . . .
H2 H 0.1362 0.3334 0.1922 0.053 Uiso 1 1 calc R . .
C3 C 0.1878(3) 0.2777(6) 0.2908(11) 0.049(2) Uani 1 1 d . . .
H3 H 0.2053 0.3200 0.2465 0.059 Uiso 1 1 calc R . .
C4 C 0.2027(3) 0.2055(6) 0.3915(10) 0.047(2) Uani 1 1 d . . .
H4 H 0.2302 0.2000 0.4146 0.056 Uiso 1 1 calc R . .
C5 C 0.1348(2) 0.1483(6) 0.4278(9) 0.0372(17) Uani 1 1 d . . .
C6 C 0.1764(2) 0.1421(6) 0.4566(10) 0.0405(19) Uani 1 1 d . . .
C7 C 0.1920(3) 0.0731(6) 0.5559(10) 0.045(2) Uani 1 1 d . . .
H7 H 0.2197 0.0696 0.5770 0.054 Uiso 1 1 calc R . .
C8 C 0.1672(3) 0.0088(7) 0.6250(11) 0.051(2) Uani 1 1 d . . .
H8 H 0.1784 -0.0380 0.6909 0.062 Uiso 1 1 calc R . .
C9 C 0.1259(2) 0.0135(7) 0.5967(10) 0.047(2) Uani 1 1 d . . .
H9 H 0.1091 -0.0293 0.6437 0.057 Uiso 1 1 calc R . .
C10 C 0.1097(3) 0.0837(6) 0.4964(9) 0.0420(18) Uani 1 1 d . . .
H10 H 0.0821 0.0872 0.4754 0.050 Uiso 1 1 calc R . .
C11 C 0.1124(2) 0.3955(6) 0.5896(10) 0.0423(19) Uani 1 1 d . . .
C12 C 0.1338(3) 0.4702(6) 0.5270(10) 0.0451(19) Uani 1 1 d . . .
H12 H 0.1213 0.5108 0.4541 0.054 Uiso 1 1 calc R . .
C13 C 0.1741(2) 0.4840(6) 0.5736(10) 0.047(2) Uani 1 1 d . . .
H13 H 0.1885 0.5349 0.5343 0.057 Uiso 1 1 calc R . .
C14 C 0.1926(3) 0.4216(7) 0.6787(10) 0.045(2) Uani 1 1 d . . .
H14 H 0.2196 0.4299 0.7105 0.054 Uiso 1 1 calc R . .
C15 C 0.1303(3) 0.3338(6) 0.6933(11) 0.045(2) Uani 1 1 d . . .
C16 C 0.1712(2) 0.3483(6) 0.7351(9) 0.0415(19) Uani 1 1 d . . .
C17 C 0.1912(3) 0.2864(6) 0.8396(10) 0.045(2) Uani 1 1 d . . .
H17 H 0.2182 0.2968 0.8688 0.054 Uiso 1 1 calc R . .
C18 C 0.1709(3) 0.2092(7) 0.9001(10) 0.047(2) Uani 1 1 d . . .
H18 H 0.1846 0.1661 0.9661 0.057 Uiso 1 1 calc R . .
C19 C 0.1301(2) 0.1962(6) 0.8623(10) 0.045(2) Uani 1 1 d . . .
H19 H 0.1162 0.1459 0.9057 0.055 Uiso 1 1 calc R . .
C20 C 0.1099(3) 0.2588(6) 0.7587(10) 0.0434(19) Uani 1 1 d . . .
H20 H 0.0826 0.2502 0.7335 0.052 Uiso 1 1 calc R . .
C21 C 0.0011(2) 0.0937(6) -0.1869(8) 0.0450(18) Uani 0.50 1 d P . .
N1 N 0.0011(2) 0.0937(6) -0.1869(8) 0.0450(18) Uani 0.50 1 d P . .
O1 O 0.05326(16) 0.2847(4) 0.4380(6) 0.0408(12) Uani 1 1 d . . .
O2 O 0.04568(16) 0.1505(4) 0.2518(6) 0.0400(13) Uani 1 1 d . . .
O3 O 0.06072(18) 0.3206(4) 0.1615(7) 0.0469(14) Uani 1 1 d . . .
O4 O 0.05008(17) 0.4654(4) 0.4279(7) 0.0470(14) Uani 1 1 d . . .
Ag2 Ag 0.038816(18) 0.64658(4) 0.42735(7) 0.03634(17) Uani 1 1 d . . .
O5 O 0.03283(17) 0.3752(4) 0.6592(7) 0.0412(13) Uani 1 1 d . . .
P1 P 0.06720(7) 0.24363(15) 0.2786(3) 0.0414(5) Uani 1 1 d . . .
P2 P 0.05907(7) 0.38479(16) 0.5302(3) 0.0449(5) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C21 Ag1 O2 152.6(3) . . ?
C21 Ag1 Ag1 67.2(2) . 5 ?
O2 Ag1 Ag1 121.03(15) . 5 ?
O4 Ag3 O4 173.9(3) 2 . ?
O4 Ag3 Ag2 123.38(15) 2 . ?
O4 Ag3 Ag2 50.57(14) . . ?
O4 Ag3 Ag2 50.57(14) 2 2 ?
O4 Ag3 Ag2 123.38(15) . 2 ?
Ag2 Ag3 Ag2 73.57(3) . 2 ?
C2 C1 C5 120.6(7) . . ?
C2 C1 P1 116.3(6) . . ?
C5 C1 P1 122.8(6) . . ?
C1 C2 C3 120.8(8) . . ?
C1 C2 H2 119.6 . . ?
C3 C2 H2 119.6 . . ?
C2 C3 C4 119.2(8) . . ?
C2 C3 H3 120.4 . . ?
C4 C3 H3 120.4 . . ?
C6 C4 C3 120.2(8) . . ?
C6 C4 H4 119.9 . . ?
C3 C4 H4 119.9 . . ?
C10 C5 C6 120.0(8) . . ?
C10 C5 C1 122.9(7) . . ?
C6 C5 C1 117.0(8) . . ?
C7 C6 C4 118.6(8) . . ?
C7 C6 C5 119.2(8) . . ?
C4 C6 C5 122.2(8) . . ?
C6 C7 C8 121.1(8) . . ?
C6 C7 H7 119.5 . . ?
C8 C7 H7 119.5 . . ?
C7 C8 C9 120.4(8) . . ?
C7 C8 H8 119.8 . . ?
C9 C8 H8 119.8 . . ?
C8 C9 C10 118.9(8) . . ?
C8 C9 H9 120.5 . . ?
C10 C9 H9 120.5 . . ?
C5 C10 C9 120.3(8) . . ?
C5 C10 H10 119.8 . . ?
C9 C10 H10 119.8 . . ?
C15 C11 C12 121.2(8) . . ?
C15 C11 P2 121.2(6) . . ?
C12 C11 P2 117.6(7) . . ?
C11 C12 C13 119.8(9) . . ?
C11 C12 H12 120.1 . . ?
C13 C12 H12 120.1 . . ?
C14 C13 C12 119.4(8) . . ?
C14 C13 H13 120.3 . . ?
C12 C13 H13 120.3 . . ?
C16 C14 C13 119.4(8) . . ?
C16 C14 H14 120.3 . . ?
C13 C14 H14 120.3 . . ?
C11 C15 C20 122.9(8) . . ?
C11 C15 C16 117.6(8) . . ?
C20 C15 C16 119.6(8) . . ?
C14 C16 C17 117.5(8) . . ?
C14 C16 C15 122.6(8) . . ?
C17 C16 C15 119.9(9) . . ?
C18 C17 C16 120.1(8) . . ?
C18 C17 H17 119.9 . . ?
C16 C17 H17 119.9 . . ?
C17 C18 C19 120.1(8) . . ?
C17 C18 H18 120.0 . . ?
C19 C18 H18 120.0 . . ?
C18 C19 C20 119.8(9) . . ?
C18 C19 H19 120.1 . . ?
C20 C19 H19 120.1 . . ?
C15 C20 C19 120.5(8) . . ?
C15 C20 H20 119.8 . . ?
C19 C20 H20 119.8 . . ?
N1 C21 Ag1 171.3(5) 2_554 . ?
C21 C21 Ag1 171.3(5) 2_554 . ?
P2 O1 P1 135.3(4) . . ?
P1 O2 Ag1 124.8(3) . . ?
P1 O3 Ag2 145.6(4) . 6_565 ?
P2 O4 Ag3 120.9(4) . . ?
P2 O4 Ag2 141.7(3) . . ?
Ag3 O4 Ag2 86.93(19) . . ?
O3 Ag2 O5 164.4(2) 6_566 6_565 ?
O3 Ag2 O5 124.7(2) 6_566 5_566 ?
O5 Ag2 O5 70.3(2) 6_565 5_566 ?
O3 Ag2 O4 99.4(2) 6_566 . ?
O5 Ag2 O4 83.08(18) 6_565 . ?
O5 Ag2 O4 91.17(18) 5_566 . ?
O3 Ag2 Ag3 135.38(16) 6_566 . ?
O5 Ag2 Ag3 54.56(13) 6_565 . ?
O5 Ag2 Ag3 54.10(12) 5_566 . ?
O4 Ag2 Ag3 42.50(13) . . ?
P2 O5 Ag2 139.2(3) . 6_566 ?
P2 O5 Ag2 112.3(3) . 5_566 ?
Ag2 O5 Ag2 107.8(2) 6_566 5_566 ?
O2 P1 O3 117.6(3) . . ?
O2 P1 O1 106.2(3) . . ?
O3 P1 O1 108.3(3) . . ?
O2 P1 C1 110.1(3) . . ?
O3 P1 C1 111.2(4) . . ?
O1 P1 C1 102.0(3) . . ?
O4 P2 O5 115.8(3) . . ?
O4 P2 O1 109.5(3) . . ?
O5 P2 O1 104.6(3) . . ?
O4 P2 C11 105.8(4) . . ?
O5 P2 C11 113.6(4) . . ?
O1 P2 C11 107.3(3) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 C21 2.080(7) . ?
Ag1 O2 2.163(6) . ?
Ag1 Ag1 3.3131(13) 5 ?
Ag3 O4 2.215(6) 2 ?
Ag3 O4 2.215(6) . ?
Ag3 Ag2 3.2738(9) . ?
Ag3 Ag2 3.2738(9) 2 ?
C1 C2 1.387(12) . ?
C1 C5 1.443(11) . ?
C1 P1 1.801(8) . ?
C2 C3 1.397(12) . ?
C2 H2 0.9300 . ?
C3 C4 1.404(13) . ?
C3 H3 0.9300 . ?
C4 C6 1.389(13) . ?
C4 H4 0.9300 . ?
C5 C10 1.389(12) . ?
C5 C6 1.395(11) . ?
C6 C7 1.372(12) . ?
C7 C8 1.382(13) . ?
C7 H7 0.9300 . ?
C8 C9 1.386(12) . ?
C8 H8 0.9300 . ?
C9 C10 1.395(12) . ?
C9 H9 0.9300 . ?
C10 H10 0.9300 . ?
C11 C15 1.359(13) . ?
C11 C12 1.390(11) . ?
C11 P2 1.824(9) . ?
C12 C13 1.392(12) . ?
C12 H12 0.9300 . ?
C13 C14 1.380(13) . ?
C13 H13 0.9300 . ?
C14 C16 1.354(13) . ?
C14 H14 0.9300 . ?
C15 C20 1.385(12) . ?
C15 C16 1.401(12) . ?
C16 C17 1.394(12) . ?
C17 C18 1.389(13) . ?
C17 H17 0.9300 . ?
C18 C19 1.389(12) . ?
C18 H18 0.9300 . ?
C19 C20 1.397(12) . ?
C19 H19 0.9300 . ?
C20 H20 0.9300 . ?
C21 N1 1.109(15) 2_554 ?
C21 C21 1.109(15) 2_554 ?
O1 P2 1.608(6) . ?
O1 P1 1.612(6) . ?
O2 P1 1.484(6) . ?
O3 P1 1.488(6) . ?
O3 Ag2 2.189(6) 6_565 ?
O4 P2 1.451(6) . ?
O4 Ag2 2.532(6) . ?
Ag2 O3 2.189(6) 6_566 ?
Ag2 O5 2.376(6) 6_565 ?
Ag2 O5 2.476(5) 5_566 ?
O5 P2 1.485(7) . ?
O5 Ag2 2.376(6) 6_566 ?
O5 Ag2 2.476(5) 5_566 ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C5 C1 C2 C3 1.8(12) . . . . ?
P1 C1 C2 C3 176.7(6) . . . . ?
C1 C2 C3 C4 -0.7(13) . . . . ?
C2 C3 C4 C6 0.4(12) . . . . ?
C2 C1 C5 C10 179.3(7) . . . . ?
P1 C1 C5 C10 4.8(11) . . . . ?
C2 C1 C5 C6 -2.5(11) . . . . ?
P1 C1 C5 C6 -177.0(6) . . . . ?
C3 C4 C6 C7 -179.3(8) . . . . ?
C3 C4 C6 C5 -1.1(12) . . . . ?
C10 C5 C6 C7 -1.5(12) . . . . ?
C1 C5 C6 C7 -179.7(7) . . . . ?
C10 C5 C6 C4 -179.6(7) . . . . ?
C1 C5 C6 C4 2.2(11) . . . . ?
C4 C6 C7 C8 179.5(8) . . . . ?
C5 C6 C7 C8 1.3(12) . . . . ?
C6 C7 C8 C9 -0.8(13) . . . . ?
C7 C8 C9 C10 0.6(13) . . . . ?
C6 C5 C10 C9 1.2(12) . . . . ?
C1 C5 C10 C9 179.4(8) . . . . ?
C8 C9 C10 C5 -0.8(13) . . . . ?
C15 C11 C12 C13 -1.7(12) . . . . ?
P2 C11 C12 C13 177.2(6) . . . . ?
C11 C12 C13 C14 1.7(12) . . . . ?
C12 C13 C14 C16 -0.3(12) . . . . ?
C12 C11 C15 C20 179.7(8) . . . . ?
P2 C11 C15 C20 0.8(12) . . . . ?
C12 C11 C15 C16 0.2(12) . . . . ?
P2 C11 C15 C16 -178.7(6) . . . . ?
C13 C14 C16 C17 179.3(8) . . . . ?
C13 C14 C16 C15 -1.3(12) . . . . ?
C11 C15 C16 C14 1.3(12) . . . . ?
C20 C15 C16 C14 -178.2(8) . . . . ?
C11 C15 C16 C17 -179.2(8) . . . . ?
C20 C15 C16 C17 1.3(12) . . . . ?
C14 C16 C17 C18 -179.3(8) . . . . ?
C15 C16 C17 C18 1.2(12) . . . . ?
C16 C17 C18 C19 -3.1(12) . . . . ?
C17 C18 C19 C20 2.4(13) . . . . ?
C11 C15 C20 C19 178.6(8) . . . . ?
C16 C15 C20 C19 -1.9(12) . . . . ?
C18 C19 C20 C15 0.1(13) . . . . ?
C21 Ag1 O2 P1 57.9(7) . . . . ?
Ag1 Ag1 O2 P1 158.1(3) 5 . . . ?
Ag2 Ag3 O4 P2 152.1(5) . . . . ?
Ag2 Ag3 O4 P2 163.5(3) 2 . . . ?
Ag2 Ag3 O4 Ag2 11.4(2) 2 . . . ?
P2 O4 Ag2 O3 13.0(6) . . . 6_566 ?
Ag3 O4 Ag2 O3 152.6(2) . . . 6_566 ?
P2 O4 Ag2 O5 177.5(6) . . . 6_565 ?
Ag3 O4 Ag2 O5 -42.9(2) . . . 6_565 ?
P2 O4 Ag2 O5 -112.5(6) . . . 5_566 ?
Ag3 O4 Ag2 O5 27.1(2) . . . 5_566 ?
P2 O4 Ag2 Ag3 -139.6(7) . . . . ?
O4 Ag3 Ag2 O3 140.4(3) 2 . . 6_566 ?
O4 Ag3 Ag2 O3 -40.3(3) . . . 6_566 ?
Ag2 Ag3 Ag2 O3 149.6(2) 2 . . 6_566 ?
O4 Ag3 Ag2 O5 -55.3(2) 2 . . 6_565 ?
O4 Ag3 Ag2 O5 123.9(3) . . . 6_565 ?
Ag2 Ag3 Ag2 O5 -46.16(16) 2 . . 6_565 ?
O4 Ag3 Ag2 O5 34.9(3) 2 . . 5_566 ?
O4 Ag3 Ag2 O5 -145.8(3) . . . 5_566 ?
Ag2 Ag3 Ag2 O5 44.12(17) 2 . . 5_566 ?
O4 Ag3 Ag2 O4 -179.2(3) 2 . . . ?
Ag2 Ag3 Ag2 O4 -170.1(2) 2 . . . ?
Ag1 O2 P1 O3 5.2(5) . . . . ?
Ag1 O2 P1 O1 126.7(4) . . . . ?
Ag1 O2 P1 C1 -123.6(4) . . . . ?
Ag2 O3 P1 O2 -16.4(8) 6_565 . . . ?
Ag2 O3 P1 O1 -136.8(6) 6_565 . . . ?
Ag2 O3 P1 C1 111.9(7) 6_565 . . . ?
P2 O1 P1 O2 -171.1(5) . . . . ?
P2 O1 P1 O3 -43.8(6) . . . . ?
P2 O1 P1 C1 73.6(6) . . . . ?
C2 C1 P1 O2 139.8(6) . . . . ?
C5 C1 P1 O2 -45.5(7) . . . . ?
C2 C1 P1 O3 7.6(7) . . . . ?
C5 C1 P1 O3 -177.7(6) . . . . ?
C2 C1 P1 O1 -107.7(6) . . . . ?
C5 C1 P1 O1 67.0(7) . . . . ?
Ag3 O4 P2 O5 -79.4(4) . . . . ?
Ag2 O4 P2 O5 51.6(7) . . . . ?
Ag3 O4 P2 O1 38.5(5) . . . . ?
Ag2 O4 P2 O1 169.5(5) . . . . ?
Ag3 O4 P2 C11 153.8(4) . . . . ?
Ag2 O4 P2 C11 -75.2(6) . . . . ?
Ag2 O5 P2 O4 -130.8(5) 6_566 . . . ?
Ag2 O5 P2 O4 59.8(4) 5_566 . . . ?
Ag2 O5 P2 O1 108.6(5) 6_566 . . . ?
Ag2 O5 P2 O1 -60.8(3) 5_566 . . . ?
Ag2 O5 P2 C11 -8.0(6) 6_566 . . . ?
Ag2 O5 P2 C11 -177.4(3) 5_566 . . . ?
P1 O1 P2 O4 47.6(6) . . . . ?
P1 O1 P2 O5 172.3(5) . . . . ?
P1 O1 P2 C11 -66.8(6) . . . . ?
C15 C11 P2 O4 176.4(7) . . . . ?
C12 C11 P2 O4 -2.5(7) . . . . ?
C15 C11 P2 O5 48.2(8) . . . . ?
C12 C11 P2 O5 -130.7(6) . . . . ?
C15 C11 P2 O1 -66.8(8) . . . . ?
C12 C11 P2 O1 114.3(6) . . . . ?
