#------------------------------------------------------------------------------
#$Date: 2016-02-14 06:40:26 +0200 (Sun, 14 Feb 2016) $
#$Revision: 176432 $
#$URL: svn://www.crystallography.net/cod/cif/7/10/69/7106914.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7106914
loop_
_publ_author_name
'Po-Heng Lin'
'Wen-Bin Sun'
'Mang-Fei Yu'
'Guang-Ming Li'
'Peng-Fei Yan'
'Muralee Murugesu'
_publ_section_title
;
 An unsymmetrical coordination environment leading to two slow relaxation
 modes in a Dy2 single-molecule magnet
;
_journal_name_full               Chem.Commun.
_journal_page_first              10993
_journal_paper_doi               10.1039/c1cc14223b
_journal_volume                  47
_journal_year                    2011
_chemical_formula_moiety         'C66 H78 Dy4 N6 O18'
_chemical_formula_sum            'C66 H78 Dy4 N6 O18'
_chemical_formula_weight         1893.34
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                112.4560(10)
_cell_angle_beta                 101.5560(10)
_cell_angle_gamma                105.7770(10)
_cell_formula_units_Z            1
_cell_length_a                   11.9873(5)
_cell_length_b                   12.6398(5)
_cell_length_c                   14.0357(9)
_cell_measurement_temperature    296(2)
_cell_volume                     1777.28(16)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.992
_diffrn_measured_fraction_theta_max 0.992
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0171
_diffrn_reflns_av_sigmaI/netI    0.0340
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            13167
_diffrn_reflns_theta_full        28.33
_diffrn_reflns_theta_max         28.33
_diffrn_reflns_theta_min         1.67
_exptl_absorpt_coefficient_mu    4.226
_exptl_absorpt_correction_T_max  0.5167
_exptl_absorpt_correction_T_min  0.4303
_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_density_diffrn    1.769
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             924
_exptl_crystal_size_max          0.24
_exptl_crystal_size_mid          0.21
_exptl_crystal_size_min          0.18
_refine_diff_density_max         0.856
_refine_diff_density_min         -0.682
_refine_diff_density_rms         0.097
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.037
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     434
_refine_ls_number_reflns         8774
_refine_ls_number_restraints     1
_refine_ls_restrained_S_all      1.037
_refine_ls_R_factor_all          0.0374
_refine_ls_R_factor_gt           0.0253
_refine_ls_shift/su_max          0.008
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0233P)²+0.5183P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0542
_refine_ls_wR_factor_ref         0.0601
_reflns_number_gt                7028
_reflns_number_total             8774
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c1cc14223b.txt
_cod_data_source_block           36
_cod_original_cell_volume        1777.28(15)
_cod_original_sg_symbol_Hall     '-p 1'
_cod_database_code               7106914
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Dy1 Dy 0.447250(13) 0.547908(13) 0.388909(12) 0.02955(5) Uani 1 1 d .
Dy2 Dy 0.687331(14) 0.783831(14) 0.642472(12) 0.03363(5) Uani 1 1 d .
C28 C 0.3688(3) 0.6907(3) 0.6190(3) 0.0385(8) Uani 1 1 d .
O6 O 0.6001(2) 0.5200(2) 0.31290(19) 0.0393(5) Uani 1 1 d .
O3 O 0.6202(2) 0.5743(2) 0.52520(17) 0.0307(5) Uani 1 1 d D
O1 O 0.6668(2) 0.6689(2) 0.74218(17) 0.0364(5) Uani 1 1 d .
O8 O 0.4575(2) 0.6862(2) 0.58249(18) 0.0365(5) Uani 1 1 d .
O2 O 0.5836(2) 0.7618(2) 0.47269(19) 0.0387(5) Uani 1 1 d .
O7 O 0.4063(2) 0.5826(2) 0.23791(19) 0.0417(6) Uani 1 1 d .
O9 O 0.2609(2) 0.5655(3) 0.3760(2) 0.0469(6) Uani 1 1 d .
O4 O 0.6741(3) 0.9187(2) 0.7993(2) 0.0529(7) Uani 1 1 d .
O5 O 0.7883(3) 0.9836(2) 0.6719(2) 0.0596(8) Uani 1 1 d .
N2 N 0.8305(3) 0.7796(3) 0.5296(2) 0.0406(7) Uani 1 1 d .
C30 C 0.1977(3) 0.5821(3) 0.4385(3) 0.0425(8) Uani 1 1 d .
N1 N 0.8974(3) 0.8049(3) 0.7393(3) 0.0471(8) Uani 1 1 d .
C5 C 0.7244(3) 0.7255(3) 0.8498(3) 0.0397(8) Uani 1 1 d .
C23 C 0.6376(3) 0.5471(3) 0.2430(3) 0.0423(8) Uani 1 1 d .
C25 C 0.4655(4) 0.6001(3) 0.1759(3) 0.0447(9) Uani 1 1 d .
C4 C 0.8538(3) 0.7948(3) 0.8973(3) 0.0457(9) Uani 1 1 d .
C27 C 0.3993(4) 0.7605(4) 0.7410(3) 0.0517(10) Uani 1 1 d .
H27A H 0.4611 0.7410 0.7779 0.078 Uiso 1 1 calc R
H27B H 0.3263 0.7370 0.7590 0.078 Uiso 1 1 calc R
H27C H 0.4298 0.8480 0.7639 0.078 Uiso 1 1 calc R
C2 C 0.9355(3) 0.7510(4) 0.5674(3) 0.0499(10) Uani 1 1 d .
H2A H 0.9956 0.7704 0.5333 0.060 Uiso 1 1 calc R
H2B H 0.9084 0.6633 0.5470 0.060 Uiso 1 1 calc R
C10 C 0.8326(3) 0.8254(3) 0.4636(3) 0.0460(9) Uani 1 1 d .
H10A H 0.8998 0.8332 0.4394 0.055 Uiso 1 1 calc R
C24 C 0.5748(4) 0.5843(4) 0.1759(3) 0.0480(9) Uani 1 1 d .
H24A H 0.6094 0.5999 0.1266 0.058 Uiso 1 1 calc R
C12 C 0.6231(4) 0.8364(3) 0.4300(3) 0.0430(9) Uani 1 1 d .
C29 C 0.2449(3) 0.6366(4) 0.5527(3) 0.0448(9) Uani 1 1 d .
H29A H 0.1875 0.6369 0.5886 0.054 Uiso 1 1 calc R
C11 C 0.7423(4) 0.8669(3) 0.4219(3) 0.0462(9) Uani 1 1 d .
C6 C 0.6599(4) 0.7165(4) 0.9212(3) 0.0515(10) Uani 1 1 d .
H6A H 0.5751 0.6716 0.8924 0.062 Uiso 1 1 calc R
C3 C 0.9317(4) 0.8122(4) 0.8343(3) 0.0539(10) Uani 1 1 d .
H3A H 1.0149 0.8304 0.8659 0.065 Uiso 1 1 calc R
C19 C 0.7677(4) 1.1211(4) 0.8279(3) 0.0600(11) Uani 1 1 d .
H19A H 0.7865 1.2043 0.8733 0.072 Uiso 1 1 calc R
C18 C 0.8025(4) 1.0909(3) 0.7364(4) 0.0559(11) Uani 1 1 d .
C31 C 0.0618(3) 0.5409(4) 0.3831(3) 0.0598(11) Uani 1 1 d .
H31A H 0.0482 0.5895 0.3468 0.090 Uiso 1 1 calc R
H31B H 0.0217 0.5520 0.4368 0.090 Uiso 1 1 calc R
H31C H 0.0285 0.4549 0.3301 0.090 Uiso 1 1 calc R
C22 C 0.7565(4) 0.5342(4) 0.2340(4) 0.0623(12) Uani 1 1 d .
H22A H 0.8092 0.5528 0.3043 0.093 Uiso 1 1 calc R
H22B H 0.7967 0.5908 0.2098 0.093 Uiso 1 1 calc R
H22C H 0.7395 0.4508 0.1820 0.093 Uiso 1 1 calc R
C1 C 0.9928(3) 0.8262(4) 0.6899(3) 0.0593(11) Uani 1 1 d .
H1A H 1.0577 0.8022 0.7169 0.071 Uiso 1 1 calc R
H1B H 1.0289 0.9136 0.7098 0.071 Uiso 1 1 calc R
C9 C 0.9112(4) 0.8465(4) 1.0113(3) 0.0660(13) Uani 1 1 d .
H9A H 0.9965 0.8883 1.0416 0.079 Uiso 1 1 calc R
C16 C 0.7752(4) 0.9426(4) 0.3721(4) 0.0660(13) Uani 1 1 d .
H16A H 0.8521 0.9602 0.3638 0.079 Uiso 1 1 calc R
C13 C 0.5464(4) 0.8865(4) 0.3917(4) 0.0637(12) Uani 1 1 d .
H13A H 0.4681 0.8681 0.3971 0.076 Uiso 1 1 calc R
C20 C 0.7060(4) 1.0338(4) 0.8557(3) 0.0498(9) Uani 1 1 d .
C8 C 0.8459(5) 0.8374(4) 1.0790(3) 0.0723(14) Uani 1 1 d .
H8A H 0.8859 0.8740 1.1544 0.087 Uiso 1 1 calc R
C26 C 0.4089(5) 0.6424(5) 0.0975(4) 0.0716(14) Uani 1 1 d .
H26A H 0.3315 0.5779 0.0453 0.107 Uiso 1 1 calc R
H26B H 0.4637 0.6604 0.0594 0.107 Uiso 1 1 calc R
H26C H 0.3956 0.7157 0.1381 0.107 Uiso 1 1 calc R
C7 C 0.7195(5) 0.7730(4) 1.0340(3) 0.0646(13) Uani 1 1 d .
H7A H 0.6740 0.7675 1.0795 0.077 Uiso 1 1 calc R
C14 C 0.5836(5) 0.9640(5) 0.3452(4) 0.0790(16) Uani 1 1 d .
H14A H 0.5307 0.9972 0.3207 0.095 Uiso 1 1 calc R
C15 C 0.6982(5) 0.9907(5) 0.3358(5) 0.0870(18) Uani 1 1 d .
H15A H 0.7232 1.0419 0.3046 0.104 Uiso 1 1 calc R
C21 C 0.6737(5) 1.0740(5) 0.9584(4) 0.0912(18) Uani 1 1 d .
H21A H 0.5858 1.0483 0.9391 0.137 Uiso 1 1 calc R
H21B H 0.7121 1.1626 1.0006 0.137 Uiso 1 1 calc R
H21C H 0.7025 1.0366 1.0009 0.137 Uiso 1 1 calc R
C33 C 0.0035(7) 0.4183(6) 0.0939(5) 0.0923(18) Uani 1 1 d .
C17 C 0.8657(6) 1.1936(4) 0.7107(5) 0.109(2) Uani 1 1 d .
H17A H 0.8518 1.1597 0.6334 0.164 Uiso 1 1 calc R
H17B H 0.9527 1.2292 0.7505 0.164 Uiso 1 1 calc R
H17C H 0.8325 1.2566 0.7320 0.164 Uiso 1 1 calc R
N3 N -0.0952(6) 0.3744(7) 0.0944(5) 0.143(3) Uani 1 1 d .
C32 C 0.1216(5) 0.4730(6) 0.0957(5) 0.103(2) Uani 1 1 d .
H32A H 0.1241 0.5350 0.0718 0.155 Uiso 1 1 calc R
H32B H 0.1437 0.4109 0.0476 0.155 Uiso 1 1 calc R
H32C H 0.1789 0.5108 0.1691 0.155 Uiso 1 1 calc R
H3O H 0.668(5) 0.561(6) 0.490(5) 0.155 Uiso 1 1 d D
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O9 Dy1 O7 77.76(8) . .
O9 Dy1 O6 150.55(8) . .
O7 Dy1 O6 73.79(8) . .
O9 Dy1 O3 138.23(8) . .
O7 Dy1 O3 138.66(7) . .
O6 Dy1 O3 70.96(8) . .
O9 Dy1 O3 83.04(8) . 2_666
O7 Dy1 O3 147.51(8) . 2_666
O6 Dy1 O3 118.10(8) . 2_666
O3 Dy1 O3 70.88(8) . 2_666
O9 Dy1 O2 101.02(9) . .
O7 Dy1 O2 81.10(8) . .
O6 Dy1 O2 82.08(8) . .
O3 Dy1 O2 73.37(8) . .
O3 Dy1 O2 128.63(7) 2_666 .
O9 Dy1 O1 86.98(9) . 2_666
O7 Dy1 O1 84.92(8) . 2_666
O6 Dy1 O1 83.12(8) . 2_666
O3 Dy1 O1 111.20(8) . 2_666
O3 Dy1 O1 68.00(7) 2_666 2_666
O2 Dy1 O1 161.97(7) . 2_666
O9 Dy1 O8 72.24(8) . .
O7 Dy1 O8 126.88(8) . .
O6 Dy1 O8 132.39(8) . .
O3 Dy1 O8 68.37(7) . .
O3 Dy1 O8 69.61(7) 2_666 .
O2 Dy1 O8 63.50(7) . .
O1 Dy1 O8 134.52(7) 2_666 .
O9 Dy1 Dy2 112.72(7) . .
O7 Dy1 Dy2 120.37(6) . .
O6 Dy1 Dy2 88.52(6) . .
O3 Dy1 Dy2 39.17(5) . .
O3 Dy1 Dy2 91.15(5) 2_666 .
O2 Dy1 Dy2 39.67(5) . .
O1 Dy1 Dy2 149.91(5) 2_666 .
O8 Dy1 Dy2 43.97(5) . .
O9 Dy1 Dy1 112.52(6) . 2_666
O7 Dy1 Dy1 168.09(6) . 2_666
O6 Dy1 Dy1 95.11(6) . 2_666
O3 Dy1 Dy1 35.46(5) . 2_666
O3 Dy1 Dy1 35.42(5) 2_666 2_666
O2 Dy1 Dy1 101.99(5) . 2_666
O1 Dy1 Dy1 89.53(5) 2_666 2_666
O8 Dy1 Dy1 63.89(5) . 2_666
Dy2 Dy1 Dy1 62.407(6) . 2_666
O9 Dy1 Dy2 91.33(7) . 2_666
O7 Dy1 Dy2 120.41(6) . 2_666
O6 Dy1 Dy2 96.48(6) . 2_666
O3 Dy1 Dy2 84.73(5) . 2_666
O3 Dy1 Dy2 33.74(5) 2_666 2_666
O2 Dy1 Dy2 157.32(5) . 2_666
O1 Dy1 Dy2 35.67(5) 2_666 2_666
O8 Dy1 Dy2 103.30(5) . 2_666
Dy2 Dy1 Dy2 117.869(5) . 2_666
Dy1 Dy1 Dy2 55.462(4) 2_666 2_666
O4 Dy2 O3 141.91(8) . .
O4 Dy2 O5 71.69(9) . .
O3 Dy2 O5 146.18(8) . .
O4 Dy2 O2 120.58(9) . .
O3 Dy2 O2 75.76(8) . .
O5 Dy2 O2 81.72(9) . .
O4 Dy2 O1 77.63(9) . .
O3 Dy2 O1 69.81(7) . .
O5 Dy2 O1 139.63(9) . .
O2 Dy2 O1 137.57(8) . .
O4 Dy2 N1 92.88(10) . .
O3 Dy2 N1 95.01(9) . .
O5 Dy2 N1 84.30(11) . .
O2 Dy2 N1 136.71(9) . .
O1 Dy2 N1 71.52(9) . .
O4 Dy2 O8 85.18(9) . .
O3 Dy2 O8 70.35(7) . .
O5 Dy2 O8 121.95(10) . .
O2 Dy2 O8 65.51(7) . .
O1 Dy2 O8 79.85(8) . .
N1 Dy2 O8 151.01(9) . .
O4 Dy2 N2 138.74(9) . .
O3 Dy2 N2 77.62(8) . .
O5 Dy2 N2 71.21(9) . .
O2 Dy2 N2 70.61(9) . .
O1 Dy2 N2 122.95(9) . .
N1 Dy2 N2 66.10(10) . .
O8 Dy2 N2 130.40(8) . .
O4 Dy2 Dy1 129.99(7) . .
O3 Dy2 Dy1 40.33(6) . .
O5 Dy2 Dy1 122.87(7) . .
O2 Dy2 Dy1 41.16(5) . .
O1 Dy2 Dy1 96.90(5) . .
N1 Dy2 Dy1 133.01(8) . .
O8 Dy2 Dy1 45.41(5) . .
N2 Dy2 Dy1 86.00(7) . .
O4 Dy2 Dy1 108.38(6) . 2_666
O3 Dy2 Dy1 34.73(5) . 2_666
O5 Dy2 Dy1 173.75(8) . 2_666
O2 Dy2 Dy1 103.20(5) . 2_666
O1 Dy2 Dy1 36.54(5) . 2_666
N1 Dy2 Dy1 89.46(7) . 2_666
O8 Dy2 Dy1 64.06(5) . 2_666
N2 Dy2 Dy1 106.54(6) . 2_666
Dy1 Dy2 Dy1 62.131(5) . 2_666
O8 C28 C29 124.1(3) . .
O8 C28 C27 118.2(3) . .
C29 C28 C27 117.7(3) . .
C23 O6 Dy1 134.3(2) . .
Dy2 O3 Dy1 100.49(8) . .
Dy2 O3 Dy1 111.52(8) . 2_666
Dy1 O3 Dy1 109.12(8) . 2_666
Dy2 O3 H3O 110(5) . .
Dy1 O3 H3O 102(4) . .
Dy1 O3 H3O 121(5) 2_666 .
C5 O1 Dy2 119.78(19) . .
C5 O1 Dy1 132.1(2) . 2_666
Dy2 O1 Dy1 107.79(8) . 2_666
C28 O8 Dy2 141.0(2) . .
C28 O8 Dy1 128.4(2) . .
Dy2 O8 Dy1 90.62(7) . .
C12 O2 Dy2 125.5(2) . .
C12 O2 Dy1 131.8(2) . .
Dy2 O2 Dy1 99.17(8) . .
C25 O7 Dy1 135.0(2) . .
C30 O9 Dy1 135.5(2) . .
C20 O4 Dy2 139.0(3) . .
C18 O5 Dy2 137.2(3) . .
C10 N2 C2 118.4(3) . .
C10 N2 Dy2 125.2(3) . .
C2 N2 Dy2 114.3(2) . .
O9 C30 C29 125.2(3) . .
O9 C30 C31 116.0(3) . .
C29 C30 C31 118.8(3) . .
C3 N1 C1 117.0(3) . .
C3 N1 Dy2 124.7(3) . .
C1 N1 Dy2 117.8(2) . .
O1 C5 C6 121.0(3) . .
O1 C5 C4 121.6(3) . .
C6 C5 C4 117.4(3) . .
O6 C23 C24 124.2(3) . .
O6 C23 C22 116.1(3) . .
C24 C23 C22 119.7(3) . .
O7 C25 C24 125.1(3) . .
O7 C25 C26 115.8(4) . .
C24 C25 C26 119.1(3) . .
C9 C4 C5 119.2(4) . .
C9 C4 C3 117.3(4) . .
C5 C4 C3 123.5(3) . .
C28 C27 H27A 109.5 . .
C28 C27 H27B 109.5 . .
H27A C27 H27B 109.5 . .
C28 C27 H27C 109.5 . .
H27A C27 H27C 109.5 . .
H27B C27 H27C 109.5 . .
N2 C2 C1 109.1(3) . .
N2 C2 H2A 109.9 . .
C1 C2 H2A 109.9 . .
N2 C2 H2B 109.9 . .
C1 C2 H2B 109.9 . .
H2A C2 H2B 108.3 . .
N2 C10 C11 127.1(3) . .
N2 C10 H10A 116.5 . .
C11 C10 H10A 116.5 . .
C25 C24 C23 125.6(3) . .
C25 C24 H24A 117.2 . .
C23 C24 H24A 117.2 . .
O2 C12 C13 119.8(4) . .
O2 C12 C11 122.2(3) . .
C13 C12 C11 118.0(3) . .
C30 C29 C28 127.0(3) . .
C30 C29 H29A 116.5 . .
C28 C29 H29A 116.5 . .
C16 C11 C12 118.6(4) . .
C16 C11 C10 118.2(4) . .
C12 C11 C10 123.2(3) . .
C7 C6 C5 121.6(4) . .
C7 C6 H6A 119.2 . .
C5 C6 H6A 119.2 . .
N1 C3 C4 126.1(4) . .
N1 C3 H3A 116.9 . .
C4 C3 H3A 116.9 . .
C18 C19 C20 123.3(4) . .
C18 C19 H19A 118.3 . .
C20 C19 H19A 118.3 . .
O5 C18 C19 124.7(4) . .
O5 C18 C17 116.0(4) . .
C19 C18 C17 119.3(4) . .
C30 C31 H31A 109.5 . .
C30 C31 H31B 109.5 . .
H31A C31 H31B 109.5 . .
C30 C31 H31C 109.5 . .
H31A C31 H31C 109.5 . .
H31B C31 H31C 109.5 . .
C23 C22 H22A 109.5 . .
C23 C22 H22B 109.5 . .
H22A C22 H22B 109.5 . .
C23 C22 H22C 109.5 . .
H22A C22 H22C 109.5 . .
H22B C22 H22C 109.5 . .
N1 C1 C2 109.0(3) . .
N1 C1 H1A 109.9 . .
C2 C1 H1A 109.9 . .
N1 C1 H1B 109.9 . .
C2 C1 H1B 109.9 . .
H1A C1 H1B 108.3 . .
C8 C9 C4 122.1(4) . .
C8 C9 H9A 118.9 . .
C4 C9 H9A 118.9 . .
C15 C16 C11 122.0(4) . .
C15 C16 H16A 119.0 . .
C11 C16 H16A 119.0 . .
C12 C13 C14 121.7(4) . .
C12 C13 H13A 119.2 . .
C14 C13 H13A 119.2 . .
O4 C20 C19 123.7(4) . .
O4 C20 C21 116.0(4) . .
C19 C20 C21 120.3(4) . .
C9 C8 C7 119.1(4) . .
C9 C8 H8A 120.5 . .
C7 C8 H8A 120.5 . .
C25 C26 H26A 109.5 . .
C25 C26 H26B 109.5 . .
H26A C26 H26B 109.5 . .
C25 C26 H26C 109.5 . .
H26A C26 H26C 109.5 . .
H26B C26 H26C 109.5 . .
C8 C7 C6 120.6(4) . .
C8 C7 H7A 119.7 . .
C6 C7 H7A 119.7 . .
C15 C14 C13 119.7(5) . .
C15 C14 H14A 120.1 . .
C13 C14 H14A 120.1 . .
C16 C15 C14 119.9(4) . .
C16 C15 H15A 120.0 . .
C14 C15 H15A 120.0 . .
C20 C21 H21A 109.5 . .
C20 C21 H21B 109.5 . .
H21A C21 H21B 109.5 . .
C20 C21 H21C 109.5 . .
H21A C21 H21C 109.5 . .
H21B C21 H21C 109.5 . .
N3 C33 C32 178.6(8) . .
C18 C17 H17A 109.5 . .
C18 C17 H17B 109.5 . .
H17A C17 H17B 109.5 . .
C18 C17 H17C 109.5 . .
H17A C17 H17C 109.5 . .
H17B C17 H17C 109.5 . .
C33 C32 H32A 109.5 . .
C33 C32 H32B 109.5 . .
H32A C32 H32B 109.5 . .
C33 C32 H32C 109.5 . .
H32A C32 H32C 109.5 . .
H32B C32 H32C 109.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Dy1 O9 2.283(2) .
Dy1 O7 2.310(2) .
Dy1 O6 2.338(2) .
Dy1 O3 2.370(2) .
Dy1 O3 2.372(2) 2_666
Dy1 O2 2.400(2) .
Dy1 O1 2.422(2) 2_666
Dy1 O8 2.564(2) .
Dy1 Dy2 3.6004(3) .
Dy1 Dy1 3.8638(3) 2_666
Dy1 Dy2 3.8736(3) 2_666
Dy2 O4 2.279(3) .
Dy2 O3 2.313(2) .
Dy2 O5 2.313(2) .
Dy2 O2 2.328(2) .
Dy2 O1 2.372(2) .
Dy2 N1 2.499(3) .
Dy2 O8 2.500(2) .
Dy2 N2 2.556(3) .
Dy2 Dy1 3.8736(3) 2_666
C28 O8 1.275(4) .
C28 C29 1.396(5) .
C28 C27 1.504(5) .
O6 C23 1.277(4) .
O3 Dy1 2.372(2) 2_666
O3 H3O 0.838(10) .
O1 C5 1.326(4) .
O1 Dy1 2.422(2) 2_666
O2 C12 1.333(4) .
O7 C25 1.273(4) .
O9 C30 1.265(4) .
O4 C20 1.260(4) .
O5 C18 1.250(5) .
N2 C10 1.268(4) .
N2 C2 1.457(5) .
C30 C29 1.395(5) .
C30 C31 1.501(5) .
N1 C3 1.273(5) .
N1 C1 1.468(5) .
C5 C6 1.401(5) .
C5 C4 1.421(5) .
C23 C24 1.387(5) .
C23 C22 1.502(5) .
C25 C24 1.378(5) .
C25 C26 1.519(5) .
C4 C9 1.407(5) .
C4 C3 1.438(5) .
C27 H27A 0.9600 .
C27 H27B 0.9600 .
C27 H27C 0.9600 .
C2 C1 1.502(5) .
C2 H2A 0.9700 .
C2 H2B 0.9700 .
C10 C11 1.441(6) .
C10 H10A 0.9300 .
C24 H24A 0.9300 .
C12 C13 1.383(6) .
C12 C11 1.415(5) .
C29 H29A 0.9300 .
C11 C16 1.405(5) .
C6 C7 1.390(5) .
C6 H6A 0.9300 .
C3 H3A 0.9300 .
C19 C18 1.377(6) .
C19 C20 1.384(6) .
C19 H19A 0.9300 .
C18 C17 1.524(6) .
C31 H31A 0.9600 .
C31 H31B 0.9600 .
C31 H31C 0.9600 .
C22 H22A 0.9600 .
C22 H22B 0.9600 .
C22 H22C 0.9600 .
C1 H1A 0.9700 .
C1 H1B 0.9700 .
C9 C8 1.364(6) .
C9 H9A 0.9300 .
C16 C15 1.354(7) .
C16 H16A 0.9300 .
C13 C14 1.397(6) .
C13 H13A 0.9300 .
C20 C21 1.502(6) .
C8 C7 1.382(6) .
C8 H8A 0.9300 .
C26 H26A 0.9600 .
C26 H26B 0.9600 .
C26 H26C 0.9600 .
C7 H7A 0.9300 .
C14 C15 1.369(7) .
C14 H14A 0.9300 .
C15 H15A 0.9300 .
C21 H21A 0.9600 .
C21 H21B 0.9600 .
C21 H21C 0.9600 .
C33 N3 1.165(8) .
C33 C32 1.387(8) .
C17 H17A 0.9600 .
C17 H17B 0.9600 .
C17 H17C 0.9600 .
C32 H32A 0.9600 .
C32 H32B 0.9600 .
C32 H32C 0.9600 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O9 Dy1 Dy2 O4 13.20(11) . .
O7 Dy1 Dy2 O4 101.99(11) . .
O6 Dy1 Dy2 O4 172.19(10) . .
O3 Dy1 Dy2 O4 -126.82(11) . .
O3 Dy1 Dy2 O4 -69.73(10) 2_666 .
O2 Dy1 Dy2 O4 92.83(12) . .
O1 Dy1 Dy2 O4 -114.28(14) 2_666 .
O8 Dy1 Dy2 O4 -11.25(11) . .
Dy1 Dy1 Dy2 O4 -91.26(9) 2_666 .
Dy2 Dy1 Dy2 O4 -91.26(9) 2_666 .
O9 Dy1 Dy2 O3 140.02(10) . .
O7 Dy1 Dy2 O3 -131.19(10) . .
O6 Dy1 Dy2 O3 -60.99(9) . .
O3 Dy1 Dy2 O3 57.09(11) 2_666 .
O2 Dy1 Dy2 O3 -140.35(12) . .
O1 Dy1 Dy2 O3 12.54(12) 2_666 .
O8 Dy1 Dy2 O3 115.57(10) . .
Dy1 Dy1 Dy2 O3 35.56(7) 2_666 .
Dy2 Dy1 Dy2 O3 35.56(7) 2_666 .
O9 Dy1 Dy2 O5 -79.88(11) . .
O7 Dy1 Dy2 O5 8.90(11) . .
O6 Dy1 Dy2 O5 79.10(11) . .
O3 Dy1 Dy2 O5 140.10(12) . .
O3 Dy1 Dy2 O5 -162.82(10) 2_666 .
O2 Dy1 Dy2 O5 -0.25(12) . .
O1 Dy1 Dy2 O5 152.63(14) 2_666 .
O8 Dy1 Dy2 O5 -104.33(11) . .
Dy1 Dy1 Dy2 O5 175.65(9) 2_666 .
Dy2 Dy1 Dy2 O5 175.65(9) 2_666 .
O9 Dy1 Dy2 O2 -79.63(11) . .
O7 Dy1 Dy2 O2 9.16(11) . .
O6 Dy1 Dy2 O2 79.36(11) . .
O3 Dy1 Dy2 O2 140.35(12) . .
O3 Dy1 Dy2 O2 -162.56(10) 2_666 .
O1 Dy1 Dy2 O2 152.89(14) 2_666 .
O8 Dy1 Dy2 O2 -104.08(11) . .
Dy1 Dy1 Dy2 O2 175.91(9) 2_666 .
Dy2 Dy1 Dy2 O2 175.91(9) 2_666 .
O9 Dy1 Dy2 O1 92.83(9) . .
O7 Dy1 Dy2 O1 -178.38(9) . .
O6 Dy1 Dy2 O1 -108.18(8) . .
O3 Dy1 Dy2 O1 -47.19(10) . .
O3 Dy1 Dy2 O1 9.90(8) 2_666 .
O2 Dy1 Dy2 O1 172.46(11) . .
O1 Dy1 Dy2 O1 -34.66(16) 2_666 .
O8 Dy1 Dy2 O1 68.38(9) . .
Dy1 Dy1 Dy2 O1 -11.63(6) 2_666 .
Dy2 Dy1 Dy2 O1 -11.63(6) 2_666 .
O9 Dy1 Dy2 N1 163.93(11) . .
O7 Dy1 Dy2 N1 -107.28(12) . .
O6 Dy1 Dy2 N1 -37.08(11) . .
O3 Dy1 Dy2 N1 23.91(12) . .
O3 Dy1 Dy2 N1 81.00(11) 2_666 .
O2 Dy1 Dy2 N1 -116.44(13) . .
O1 Dy1 Dy2 N1 36.45(14) 2_666 .
O8 Dy1 Dy2 N1 139.48(12) . .
Dy1 Dy1 Dy2 N1 59.47(9) 2_666 .
Dy2 Dy1 Dy2 N1 59.47(9) 2_666 .
O9 Dy1 Dy2 O8 24.45(10) . .
O7 Dy1 Dy2 O8 113.24(10) . .
O6 Dy1 Dy2 O8 -176.56(9) . .
O3 Dy1 Dy2 O8 -115.57(10) . .
O3 Dy1 Dy2 O8 -58.48(9) 2_666 .
O2 Dy1 Dy2 O8 104.08(11) . .
O1 Dy1 Dy2 O8 -103.03(13) 2_666 .
Dy1 Dy1 Dy2 O8 -80.01(7) 2_666 .
Dy2 Dy1 Dy2 O8 -80.01(7) 2_666 .
O9 Dy1 Dy2 N2 -144.44(10) . .
O7 Dy1 Dy2 N2 -55.65(10) . .
O6 Dy1 Dy2 N2 14.55(9) . .
O3 Dy1 Dy2 N2 75.54(10) . .
O3 Dy1 Dy2 N2 132.63(9) 2_666 .
O2 Dy1 Dy2 N2 -64.81(11) . .
O1 Dy1 Dy2 N2 88.07(12) 2_666 .
O8 Dy1 Dy2 N2 -168.89(10) . .
Dy1 Dy1 Dy2 N2 111.10(7) 2_666 .
Dy2 Dy1 Dy2 N2 111.10(7) 2_666 .
O9 Dy1 Dy2 Dy1 104.46(7) . 2_666
O7 Dy1 Dy2 Dy1 -166.75(7) . 2_666
O6 Dy1 Dy2 Dy1 -96.55(6) . 2_666
O3 Dy1 Dy2 Dy1 -35.56(7) . 2_666
O3 Dy1 Dy2 Dy1 21.53(5) 2_666 2_666
O2 Dy1 Dy2 Dy1 -175.91(9) . 2_666
O1 Dy1 Dy2 Dy1 -23.02(10) 2_666 2_666
O8 Dy1 Dy2 Dy1 80.01(7) . 2_666
Dy2 Dy1 Dy2 Dy1 0.0 2_666 2_666
O9 Dy1 O6 C23 30.1(4) . .
O7 Dy1 O6 C23 14.7(3) . .
O3 Dy1 O6 C23 -143.4(3) . .
O3 Dy1 O6 C23 161.9(3) 2_666 .
O2 Dy1 O6 C23 -68.3(3) . .
O1 Dy1 O6 C23 101.4(3) 2_666 .
O8 Dy1 O6 C23 -110.8(3) . .
Dy2 Dy1 O6 C23 -107.6(3) . .
Dy1 Dy1 O6 C23 -169.7(3) 2_666 .
Dy2 Dy1 O6 C23 134.5(3) 2_666 .
O4 Dy2 O3 Dy1 96.13(15) . .
O5 Dy2 O3 Dy1 -75.45(18) . .
O2 Dy2 O3 Dy1 -25.68(8) . .
O1 Dy2 O3 Dy1 129.10(9) . .
N1 Dy2 O3 Dy1 -162.69(9) . .
O8 Dy2 O3 Dy1 43.01(7) . .
N2 Dy2 O3 Dy1 -98.52(9) . .
Dy1 Dy2 O3 Dy1 115.54(11) 2_666 .
O4 Dy2 O3 Dy1 -19.41(19) . 2_666
O5 Dy2 O3 Dy1 169.01(14) . 2_666
O2 Dy2 O3 Dy1 -141.22(10) . 2_666
O1 Dy2 O3 Dy1 13.56(8) . 2_666
N1 Dy2 O3 Dy1 81.76(10) . 2_666
O8 Dy2 O3 Dy1 -72.54(9) . 2_666
N2 Dy2 O3 Dy1 145.93(11) . 2_666
Dy1 Dy2 O3 Dy1 -115.54(11) . 2_666
O9 Dy1 O3 Dy2 -62.84(14) . .
O7 Dy1 O3 Dy2 79.43(13) . .
O6 Dy1 O3 Dy2 112.35(9) . .
O3 Dy1 O3 Dy2 -117.33(11) 2_666 .
O2 Dy1 O3 Dy2 25.16(7) . .
O1 Dy1 O3 Dy2 -173.30(6) 2_666 .
O8 Dy1 O3 Dy2 -42.36(7) . .
Dy1 Dy1 O3 Dy2 -117.33(11) 2_666 .
Dy2 Dy1 O3 Dy2 -148.92(6) 2_666 .
O9 Dy1 O3 Dy1 54.49(16) . 2_666
O7 Dy1 O3 Dy1 -163.24(10) . 2_666
O6 Dy1 O3 Dy1 -130.32(11) . 2_666
O3 Dy1 O3 Dy1 0.0 2_666 2_666
O2 Dy1 O3 Dy1 142.49(10) . 2_666
O1 Dy1 O3 Dy1 -55.97(10) 2_666 2_666
O8 Dy1 O3 Dy1 74.97(9) . 2_666
Dy2 Dy1 O3 Dy1 117.33(11) . 2_666
Dy2 Dy1 O3 Dy1 -31.59(7) 2_666 2_666
O4 Dy2 O1 C5 -39.3(2) . .
O3 Dy2 O1 C5 160.8(3) . .
O5 Dy2 O1 C5 1.7(3) . .
O2 Dy2 O1 C5 -161.5(2) . .
N1 Dy2 O1 C5 58.0(3) . .
O8 Dy2 O1 C5 -126.5(3) . .
N2 Dy2 O1 C5 101.5(3) . .
Dy1 Dy2 O1 C5 -168.8(2) . .
Dy1 Dy2 O1 C5 173.8(3) 2_666 .
O4 Dy2 O1 Dy1 146.93(11) . 2_666
O3 Dy2 O1 Dy1 -12.97(8) . 2_666
O5 Dy2 O1 Dy1 -172.04(12) . 2_666
O2 Dy2 O1 Dy1 24.78(16) . 2_666
N1 Dy2 O1 Dy1 -115.74(12) . 2_666
O8 Dy2 O1 Dy1 59.69(9) . 2_666
N2 Dy2 O1 Dy1 -72.27(12) . 2_666
Dy1 Dy2 O1 Dy1 17.42(8) . 2_666
C29 C28 O8 Dy2 166.3(3) . .
C27 C28 O8 Dy2 -12.5(5) . .
C29 C28 O8 Dy1 -13.5(5) . .
C27 C28 O8 Dy1 167.8(2) . .
O4 Dy2 O8 C28 -8.4(3) . .
O3 Dy2 O8 C28 141.9(3) . .
O5 Dy2 O8 C28 -73.3(3) . .
O2 Dy2 O8 C28 -135.3(3) . .
O1 Dy2 O8 C28 69.8(3) . .
N1 Dy2 O8 C28 78.8(4) . .
N2 Dy2 O8 C28 -165.2(3) . .
Dy1 Dy2 O8 C28 -179.8(4) . .
Dy1 Dy2 O8 C28 104.7(3) 2_666 .
O4 Dy2 O8 Dy1 171.37(8) . .
O3 Dy2 O8 Dy1 -38.31(7) . .
O5 Dy2 O8 Dy1 106.47(9) . .
O2 Dy2 O8 Dy1 44.54(7) . .
O1 Dy2 O8 Dy1 -110.35(8) . .
N1 Dy2 O8 Dy1 -101.37(18) . .
N2 Dy2 O8 Dy1 14.62(13) . .
Dy1 Dy2 O8 Dy1 -75.50(5) 2_666 .
O9 Dy1 O8 C28 23.5(3) . .
O7 Dy1 O8 C28 82.2(3) . .
O6 Dy1 O8 C28 -175.5(2) . .
O3 Dy1 O8 C28 -142.3(3) . .
O3 Dy1 O8 C28 -65.6(3) 2_666 .
O2 Dy1 O8 C28 136.1(3) . .
O1 Dy1 O8 C28 -43.4(3) 2_666 .
Dy2 Dy1 O8 C28 179.9(3) . .
Dy1 Dy1 O8 C28 -103.7(3) 2_666 .
Dy2 Dy1 O8 C28 -63.6(3) 2_666 .
O9 Dy1 O8 Dy2 -156.36(10) . .
O7 Dy1 O8 Dy2 -97.61(10) . .
O6 Dy1 O8 Dy2 4.66(12) . .
O3 Dy1 O8 Dy2 37.81(6) . .
O3 Dy1 O8 Dy2 114.59(8) 2_666 .
O2 Dy1 O8 Dy2 -43.78(7) . .
O1 Dy1 O8 Dy2 136.75(9) 2_666 .
Dy1 Dy1 O8 Dy2 76.41(5) 2_666 .
Dy2 Dy1 O8 Dy2 116.54(5) 2_666 .
O4 Dy2 O2 C12 81.9(3) . .
O3 Dy2 O2 C12 -135.6(3) . .
O5 Dy2 O2 C12 18.9(3) . .
O1 Dy2 O2 C12 -172.0(2) . .
N1 Dy2 O2 C12 -53.6(3) . .
O8 Dy2 O2 C12 149.8(3) . .
N2 Dy2 O2 C12 -54.0(3) . .
Dy1 Dy2 O2 C12 -160.9(3) . .
Dy1 Dy2 O2 C12 -157.1(3) 2_666 .
O4 Dy2 O2 Dy1 -117.27(9) . .
O3 Dy2 O2 Dy1 25.22(8) . .
O5 Dy2 O2 Dy1 179.79(10) . .
O1 Dy2 O2 Dy1 -11.13(16) . .
N1 Dy2 O2 Dy1 107.29(13) . .
O8 Dy2 O2 Dy1 -49.38(8) . .
N2 Dy2 O2 Dy1 106.87(10) . .
Dy1 Dy2 O2 Dy1 3.72(8) 2_666 .
O9 Dy1 O2 C12 -88.6(3) . .
O7 Dy1 O2 C12 -13.0(3) . .
O6 Dy1 O2 C12 61.7(3) . .
O3 Dy1 O2 C12 134.1(3) . .
O3 Dy1 O2 C12 -178.4(3) 2_666 .
O1 Dy1 O2 C12 26.6(5) 2_666 .
O8 Dy1 O2 C12 -152.2(3) . .
Dy2 Dy1 O2 C12 159.0(4) . .
Dy1 Dy1 O2 C12 155.3(3) 2_666 .
Dy2 Dy1 O2 C12 149.6(3) 2_666 .
O9 Dy1 O2 Dy2 112.42(9) . .
O7 Dy1 O2 Dy2 -172.01(10) . .
O6 Dy1 O2 Dy2 -97.29(9) . .
O3 Dy1 O2 Dy2 -24.88(8) . .
O3 Dy1 O2 Dy2 22.55(13) 2_666 .
O1 Dy1 O2 Dy2 -132.4(2) 2_666 .
O8 Dy1 O2 Dy2 48.80(8) . .
Dy1 Dy1 O2 Dy2 -3.71(8) 2_666 .
Dy2 Dy1 O2 Dy2 -9.4(2) 2_666 .
O9 Dy1 O7 C25 174.3(3) . .
O6 Dy1 O7 C25 -13.4(3) . .
O3 Dy1 O7 C25 19.0(4) . .
O3 Dy1 O7 C25 -130.5(3) 2_666 .
O2 Dy1 O7 C25 70.9(3) . .
O1 Dy1 O7 C25 -97.7(3) 2_666 .
O8 Dy1 O7 C25 117.9(3) . .
Dy2 Dy1 O7 C25 65.0(3) . .
Dy1 Dy1 O7 C25 -35.2(5) 2_666 .
Dy2 Dy1 O7 C25 -101.4(3) 2_666 .
O7 Dy1 O9 C30 -164.7(4) . .
O6 Dy1 O9 C30 -179.8(3) . .
O3 Dy1 O9 C30 -9.1(4) . .
O3 Dy1 O9 C30 41.7(3) 2_666 .
O2 Dy1 O9 C30 -86.4(3) . .
O1 Dy1 O9 C30 109.9(3) 2_666 .
O8 Dy1 O9 C30 -29.1(3) . .
Dy2 Dy1 O9 C30 -46.6(4) . .
Dy1 Dy1 O9 C30 21.6(4) 2_666 .
Dy2 Dy1 O9 C30 74.5(3) 2_666 .
O3 Dy2 O4 C20 -173.2(4) . .
O5 Dy2 O4 C20 1.9(4) . .
O2 Dy2 O4 C20 -66.3(4) . .
O1 Dy2 O4 C20 155.3(4) . .
N1 Dy2 O4 C20 84.9(4) . .
O8 Dy2 O4 C20 -124.1(4) . .
N2 Dy2 O4 C20 28.8(5) . .
Dy1 Dy2 O4 C20 -116.1(4) . .
Dy1 Dy2 O4 C20 175.3(4) 2_666 .
O4 Dy2 O5 C18 -7.3(4) . .
O3 Dy2 O5 C18 167.3(4) . .
O2 Dy2 O5 C18 118.9(4) . .
O1 Dy2 O5 C18 -49.7(5) . .
N1 Dy2 O5 C18 -102.2(4) . .
O8 Dy2 O5 C18 64.6(4) . .
N2 Dy2 O5 C18 -168.9(5) . .
Dy1 Dy2 O5 C18 119.0(4) . .
Dy1 Dy2 O5 C18 -98.9(7) 2_666 .
O4 Dy2 N2 C10 -79.4(3) . .
O3 Dy2 N2 C10 114.3(3) . .
O5 Dy2 N2 C10 -52.4(3) . .
O2 Dy2 N2 C10 35.2(3) . .
O1 Dy2 N2 C10 170.0(3) . .
N1 Dy2 N2 C10 -144.5(3) . .
O8 Dy2 N2 C10 64.0(3) . .
Dy1 Dy2 N2 C10 74.4(3) . .
Dy1 Dy2 N2 C10 133.7(3) 2_666 .
O4 Dy2 N2 C2 84.2(3) . .
O3 Dy2 N2 C2 -82.1(2) . .
O5 Dy2 N2 C2 111.2(2) . .
O2 Dy2 N2 C2 -161.2(2) . .
O1 Dy2 N2 C2 -26.4(3) . .
N1 Dy2 N2 C2 19.1(2) . .
O8 Dy2 N2 C2 -132.4(2) . .
Dy1 Dy2 N2 C2 -122.0(2) . .
Dy1 Dy2 N2 C2 -62.7(2) 2_666 .
Dy1 O9 C30 C29 23.3(6) . .
Dy1 O9 C30 C31 -157.8(3) . .
O4 Dy2 N1 C3 39.6(3) . .
O3 Dy2 N1 C3 -103.1(3) . .
O5 Dy2 N1 C3 110.8(3) . .
O2 Dy2 N1 C3 -177.7(3) . .
O1 Dy2 N1 C3 -36.4(3) . .
O8 Dy2 N1 C3 -45.7(4) . .
N2 Dy2 N1 C3 -177.2(4) . .
Dy1 Dy2 N1 C3 -118.4(3) . .
Dy1 Dy2 N1 C3 -68.8(3) 2_666 .
O4 Dy2 N1 C1 -132.3(3) . .
O3 Dy2 N1 C1 85.0(3) . .
O5 Dy2 N1 C1 -61.0(3) . .
O2 Dy2 N1 C1 10.5(4) . .
O1 Dy2 N1 C1 151.8(3) . .
O8 Dy2 N1 C1 142.4(3) . .
N2 Dy2 N1 C1 10.9(3) . .
Dy1 Dy2 N1 C1 69.7(3) . .
Dy1 Dy2 N1 C1 119.3(3) 2_666 .
Dy2 O1 C5 C6 126.7(3) . .
Dy1 O1 C5 C6 -61.3(5) 2_666 .
Dy2 O1 C5 C4 -54.9(4) . .
Dy1 O1 C5 C4 117.0(3) 2_666 .
Dy1 O6 C23 C24 -13.0(5) . .
Dy1 O6 C23 C22 168.3(3) . .
Dy1 O7 C25 C24 10.3(6) . .
Dy1 O7 C25 C26 -169.3(3) . .
O1 C5 C4 C9 -176.1(4) . .
C6 C5 C4 C9 2.3(6) . .
O1 C5 C4 C3 1.7(6) . .
C6 C5 C4 C3 -179.9(4) . .
C10 N2 C2 C1 119.0(4) . .
Dy2 N2 C2 C1 -45.7(3) . .
C2 N2 C10 C11 -176.0(4) . .
Dy2 N2 C10 C11 -13.0(5) . .
O7 C25 C24 C23 -0.1(7) . .
C26 C25 C24 C23 179.5(4) . .
O6 C23 C24 C25 1.5(6) . .
C22 C23 C24 C25 -179.8(4) . .
Dy2 O2 C12 C13 -128.2(3) . .
Dy1 O2 C12 C13 77.5(4) . .
Dy2 O2 C12 C11 51.8(4) . .
Dy1 O2 C12 C11 -102.5(4) . .
O9 C30 C29 C28 5.3(6) . .
C31 C30 C29 C28 -173.7(4) . .
O8 C28 C29 C30 -7.6(6) . .
C27 C28 C29 C30 171.1(4) . .
O2 C12 C11 C16 177.7(4) . .
C13 C12 C11 C16 -2.3(6) . .
O2 C12 C11 C10 -3.1(6) . .
C13 C12 C11 C10 177.0(4) . .
N2 C10 C11 C16 164.3(4) . .
N2 C10 C11 C12 -14.9(6) . .
O1 C5 C6 C7 178.5(4) . .
C4 C5 C6 C7 0.1(6) . .
C1 N1 C3 C4 179.9(4) . .
Dy2 N1 C3 C4 8.0(6) . .
C9 C4 C3 N1 -158.8(4) . .
C5 C4 C3 N1 23.4(7) . .
Dy2 O5 C18 C19 9.6(8) . .
Dy2 O5 C18 C17 -171.8(4) . .
C20 C19 C18 O5 -3.7(8) . .
C20 C19 C18 C17 177.7(5) . .
C3 N1 C1 C2 149.4(4) . .
Dy2 N1 C1 C2 -38.1(4) . .
N2 C2 C1 N1 53.9(4) . .
C5 C4 C9 C8 -3.2(7) . .
C3 C4 C9 C8 178.9(5) . .
C12 C11 C16 C15 2.7(7) . .
C10 C11 C16 C15 -176.6(5) . .
O2 C12 C13 C14 -179.3(4) . .
C11 C12 C13 C14 0.7(7) . .
Dy2 O4 C20 C19 1.0(7) . .
Dy2 O4 C20 C21 -178.8(3) . .
C18 C19 C20 O4 -1.3(7) . .
C18 C19 C20 C21 178.5(5) . .
C4 C9 C8 C7 1.4(8) . .
C9 C8 C7 C6 1.1(8) . .
C5 C6 C7 C8 -1.9(7) . .
C12 C13 C14 C15 0.6(8) . .
C11 C16 C15 C14 -1.4(9) . .
C13 C14 C15 C16 -0.3(9) . .
