#------------------------------------------------------------------------------
#$Date: 2016-03-26 19:34:25 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180440 $
#$URL: svn://www.crystallography.net/cod/cif/7/21/09/7210942.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7210942
loop_
_publ_author_name
'Niranjana, P.'
'Pati, Anita'
'Porwal, Suheel K.'
'Ramkumar, Venkatachalam'
'Gharpure, Santosh J.'
'Chand, Dillip Kumar'
_publ_section_title
;
 Coordination polymers via self-assembly of silver(i) and
 cis-bis-nitrile-oxa-bowl derivatives
;
_journal_issue                   45
_journal_name_full               CrystEngComm
_journal_page_first              9623
_journal_paper_doi               10.1039/c3ce41003j
_journal_volume                  15
_journal_year                    2013
_chemical_formula_moiety         'C22 H23 Ag N4 O4, F6 P'
_chemical_formula_sum            'C22 H23 Ag F6 N4 O4 P'
_chemical_formula_weight         660.28
_chemical_name_systematic
;

 ?

;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 92.214(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   11.2301(6)
_cell_length_b                   19.1920(11)
_cell_length_c                   11.8597(6)
_cell_measurement_reflns_used    5891
_cell_measurement_temperature    298(2)
_cell_measurement_theta_max      25.67
_cell_measurement_theta_min      2.67
_cell_volume                     2554.2(2)
_computing_cell_refinement       APEXII,Bruker,2004
_computing_data_collection       APEXII,Bruker,2004
_computing_data_reduction        SAINT,Bruker,2004
_computing_molecular_graphics    'ORTEP-3 (Farrugia, 1997)'
_computing_publication_material  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      298(2)
_diffrn_measured_fraction_theta_full 0.927
_diffrn_measured_fraction_theta_max 0.927
_diffrn_measurement_device_type  'Bruker APEXII CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0278
_diffrn_reflns_av_sigmaI/netI    0.0277
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       22
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       11
_diffrn_reflns_limit_l_min       -14
_diffrn_reflns_number            15074
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         1.81
_exptl_absorpt_coefficient_mu    0.933
_exptl_absorpt_correction_T_max  0.8963
_exptl_absorpt_correction_T_min  0.8354
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS (Bruker,2004)'
_exptl_crystal_colour            white
_exptl_crystal_density_diffrn    1.717
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Block
_exptl_crystal_F_000             1324
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.12
_refine_diff_density_max         0.948
_refine_diff_density_min         -0.714
_refine_diff_density_rms         0.095
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.054
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     343
_refine_ls_number_reflns         4169
_refine_ls_number_restraints     2
_refine_ls_restrained_S_all      1.054
_refine_ls_R_factor_all          0.0823
_refine_ls_R_factor_gt           0.0631
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0932P)²+8.2549P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1737
_refine_ls_wR_factor_ref         0.1949
_reflns_number_gt                3112
_reflns_number_total             4169
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c3ce41003j.txt
_cod_data_source_block           new
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 1891 2012-01-12 08:04:46Z andrius 
;
_cod_original_sg_symbol_H-M      P2(1)/c
_cod_database_code               7210942
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ag1 Ag 0.44732(5) 0.74442(3) 0.38642(5) 0.0660(3) Uani 1 1 d .
C1 C 0.5791(12) 0.4166(5) 0.8160(8) 0.158(7) Uani 1 1 d D
H1 H 0.5084 0.4310 0.7709 0.189 Uiso 1 1 calc R
C2 C 0.7790(13) 0.4136(8) 0.7845(17) 0.33(2) Uani 1 1 d D
H2A H 0.8370 0.4104 0.7263 0.398 Uiso 1 1 calc R
H2B H 0.8076 0.3874 0.8500 0.398 Uiso 1 1 calc R
C3 C 0.7564(10) 0.4866(8) 0.8141(9) 0.133(5) Uani 1 1 d .
C4 C 0.7458(8) 0.5416(5) 0.7244(8) 0.093(3) Uani 1 1 d .
H4 H 0.8070 0.5772 0.7391 0.111 Uiso 1 1 calc R
C5 C 0.7463(12) 0.5206(5) 0.6016(10) 0.110(4) Uani 1 1 d .
H5A H 0.7693 0.5593 0.5547 0.132 Uiso 1 1 calc R
H5B H 0.8005 0.4820 0.5907 0.132 Uiso 1 1 calc R
C6 C 0.5574(10) 0.5481(5) 0.6274(8) 0.101(3) Uani 1 1 d .
H6 H 0.4841 0.5246 0.6488 0.121 Uiso 1 1 calc R
C7 C 0.6234(8) 0.5742(4) 0.7356(7) 0.078(2) Uani 1 1 d .
H7 H 0.6288 0.6252 0.7358 0.093 Uiso 1 1 calc R
C8 C 0.5750(8) 0.5483(4) 0.8430(7) 0.086(2) Uani 1 1 d .
H8A H 0.4899 0.5399 0.8340 0.103 Uiso 1 1 calc R
H8B H 0.5889 0.5820 0.9030 0.103 Uiso 1 1 calc R
C9 C 0.6405(8) 0.4811(4) 0.8698(6) 0.078(2) Uani 1 1 d .
H9 H 0.6527 0.4751 0.9514 0.093 Uiso 1 1 calc R
C10 C 0.5246(9) 0.6063(5) 0.5497(8) 0.088(3) Uani 1 1 d .
C11 C 0.7335(7) 0.7260(4) 0.3148(6) 0.0618(17) Uani 1 1 d .
C12 C 0.8621(6) 0.7191(4) 0.3410(5) 0.0571(16) Uani 1 1 d .
H12 H 0.8959 0.6833 0.2928 0.068 Uiso 1 1 calc R
C13 C 0.8897(6) 0.7014(3) 0.4661(5) 0.0546(15) Uani 1 1 d .
H13 H 0.8190 0.6827 0.5015 0.066 Uiso 1 1 calc R
C14 C 0.9973(6) 0.6523(4) 0.4849(6) 0.0631(18) Uani 1 1 d .
H14A H 0.9712 0.6059 0.5050 0.076 Uiso 1 1 calc R
H14B H 1.0432 0.6493 0.4174 0.076 Uiso 1 1 calc R
C15 C 1.0711(6) 0.6852(4) 0.5818(5) 0.0566(16) Uani 1 1 d .
H15 H 1.0456 0.6703 0.6561 0.068 Uiso 1 1 calc R
C16 C 1.2045(6) 0.6756(4) 0.5675(5) 0.0624(17) Uani 1 1 d .
H16 H 1.2209 0.6276 0.5449 0.075 Uiso 1 1 calc R
C17 C 1.1530(7) 0.7799(4) 0.4804(7) 0.071(2) Uani 1 1 d .
H17A H 1.1187 0.7874 0.4050 0.086 Uiso 1 1 calc R
H17B H 1.1951 0.8219 0.5041 0.086 Uiso 1 1 calc R
C18 C 1.0547(6) 0.7638(3) 0.5617(6) 0.0586(17) Uani 1 1 d .
H18 H 1.0681 0.7895 0.6325 0.070 Uiso 1 1 calc R
C19 C 0.9263(6) 0.7721(3) 0.5182(6) 0.0580(16) Uani 1 1 d .
H19 H 0.8752 0.7832 0.5809 0.070 Uiso 1 1 calc R
C20 C 0.9049(7) 0.8241(4) 0.4228(7) 0.073(2) Uani 1 1 d .
H20A H 0.8255 0.8437 0.4247 0.088 Uiso 1 1 calc R
H20B H 0.9627 0.8616 0.4277 0.088 Uiso 1 1 calc R
C21 C 0.4539(10) 0.8647(5) 0.6007(8) 0.091(3) Uani 1 1 d .
C22 C 0.2757(6) 0.8068(4) 0.1721(6) 0.0599(17) Uani 1 1 d .
F1 F 0.7482(11) 0.4601(6) 0.2658(16) 0.291(9) Uani 1 1 d .
F2 F 0.7887(13) 0.5631(5) 0.3034(9) 0.236(6) Uani 1 1 d .
F3 F 0.7445(14) 0.5393(9) 0.1376(10) 0.289(8) Uani 1 1 d .
F4 F 0.9199(11) 0.5668(6) 0.1887(14) 0.271(7) Uani 1 1 d .
F5 F 0.875(2) 0.4665(9) 0.1308(13) 0.367(11) Uani 1 1 d .
F6 F 0.9238(11) 0.4778(9) 0.2884(17) 0.334(11) Uani 1 1 d .
N1 N 0.4986(8) 0.6508(4) 0.4943(7) 0.103(3) Uani 1 1 d .
N2 N 0.6359(7) 0.7351(4) 0.2965(7) 0.092(2) Uani 1 1 d .
N3 N 0.4761(8) 0.8258(4) 0.5335(6) 0.094(2) Uani 1 1 d .
N4 N 0.3310(6) 0.7903(4) 0.2486(5) 0.0750(17) Uani 1 1 d .
O1 O 0.6659(15) 0.3889(5) 0.7446(9) 0.297(12) Uani 1 1 d D
O2 O 0.6281(11) 0.5007(3) 0.5767(7) 0.147(4) Uani 1 1 d .
O3 O 1.2341(5) 0.7219(3) 0.4801(4) 0.0751(14) Uani 1 1 d .
O4 O 0.9186(5) 0.7839(3) 0.3222(4) 0.0730(14) Uani 1 1 d .
P1 P 0.8337(2) 0.51057(13) 0.2174(2) 0.0902(7) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N4 Ag1 N1 148.7(3) . .
N4 Ag1 N3 109.9(3) . .
N1 Ag1 N3 94.8(3) . .
N4 Ag1 N2 101.8(3) . .
N1 Ag1 N2 89.0(3) . .
N3 Ag1 N2 106.2(3) . .
O1 C1 C21 110.3(8) . 2_646
O1 C1 C9 103.9(8) . .
C21 C1 C9 112.9(7) 2_646 .
O1 C1 H1 109.9 . .
C21 C1 H1 109.9 2_646 .
C9 C1 H1 109.9 . .
O1 C2 C3 103.8(9) . .
O1 C2 H2A 111.0 . .
C3 C2 H2A 111.0 . .
O1 C2 H2B 111.0 . .
C3 C2 H2B 111.0 . .
H2A C2 H2B 109.0 . .
C2 C3 C9 101.6(13) . .
C2 C3 C4 120.7(12) . .
C9 C3 C4 108.6(8) . .
C3 C4 C5 119.5(9) . .
C3 C4 C7 105.9(8) . .
C5 C4 C7 103.3(8) . .
C3 C4 H4 109.2 . .
C5 C4 H4 109.2 . .
C7 C4 H4 109.2 . .
O2 C5 C4 103.7(8) . .
O2 C5 H5A 111.0 . .
C4 C5 H5A 111.0 . .
O2 C5 H5B 111.0 . .
C4 C5 H5B 111.0 . .
H5A C5 H5B 109.0 . .
O2 C6 C10 111.3(9) . .
O2 C6 C7 108.3(8) . .
C10 C6 C7 111.9(7) . .
O2 C6 H6 108.4 . .
C10 C6 H6 108.4 . .
C7 C6 H6 108.4 . .
C8 C7 C4 107.4(7) . .
C8 C7 C6 115.1(8) . .
C4 C7 C6 101.6(7) . .
C8 C7 H7 110.8 . .
C4 C7 H7 110.8 . .
C6 C7 H7 110.8 . .
C7 C8 C9 105.8(7) . .
C7 C8 H8A 110.6 . .
C9 C8 H8A 110.6 . .
C7 C8 H8B 110.6 . .
C9 C8 H8B 110.6 . .
H8A C8 H8B 108.7 . .
C3 C9 C8 105.9(8) . .
C3 C9 C1 105.0(9) . .
C8 C9 C1 113.0(8) . .
C3 C9 H9 110.9 . .
C8 C9 H9 110.9 . .
C1 C9 H9 110.9 . .
N1 C10 C6 177.9(12) . .
N2 C11 C12 176.1(9) . .
O4 C12 C11 109.2(6) . .
O4 C12 C13 105.7(5) . .
C11 C12 C13 112.5(6) . .
O4 C12 H12 109.8 . .
C11 C12 H12 109.8 . .
C13 C12 H12 109.8 . .
C19 C13 C12 103.5(5) . .
C19 C13 C14 106.5(5) . .
C12 C13 C14 113.7(6) . .
C19 C13 H13 110.9 . .
C12 C13 H13 110.9 . .
C14 C13 H13 110.9 . .
C15 C14 C13 104.8(5) . .
C15 C14 H14A 110.8 . .
C13 C14 H14A 110.8 . .
C15 C14 H14B 110.8 . .
C13 C14 H14B 110.8 . .
H14A C14 H14B 108.9 . .
C16 C15 C14 111.9(6) . .
C16 C15 C18 102.3(5) . .
C14 C15 C18 103.4(5) . .
C16 C15 H15 112.8 . .
C14 C15 H15 112.8 . .
C18 C15 H15 112.8 . .
O3 C16 C22 109.5(6) . 4_676
O3 C16 C15 105.4(6) . .
C22 C16 C15 112.3(6) 4_676 .
O3 C16 H16 109.8 . .
C22 C16 H16 109.8 4_676 .
C15 C16 H16 109.8 . .
O3 C17 C18 108.5(6) . .
O3 C17 H17A 110.0 . .
C18 C17 H17A 110.0 . .
O3 C17 H17B 110.0 . .
C18 C17 H17B 110.0 . .
H17A C17 H17B 108.4 . .
C19 C18 C17 117.6(6) . .
C19 C18 C15 105.2(5) . .
C17 C18 C15 102.3(6) . .
C19 C18 H18 110.4 . .
C17 C18 H18 110.4 . .
C15 C18 H18 110.4 . .
C18 C19 C20 116.2(6) . .
C18 C19 C13 106.2(5) . .
C20 C19 C13 104.3(6) . .
C18 C19 H19 110.0 . .
C20 C19 H19 110.0 . .
C13 C19 H19 110.0 . .
O4 C20 C19 104.4(6) . .
O4 C20 H20A 110.9 . .
C19 C20 H20A 110.9 . .
O4 C20 H20B 110.9 . .
C19 C20 H20B 110.9 . .
H20A C20 H20B 108.9 . .
N3 C21 C1 177.3(11) . 2_656
N4 C22 C16 176.3(8) . 4_475
C10 N1 Ag1 177.9(8) . .
C11 N2 Ag1 142.4(7) . .
C21 N3 Ag1 159.3(9) . .
C22 N4 Ag1 172.0(6) . .
C1 O1 C2 107.6(11) . .
C6 O2 C5 106.8(7) . .
C16 O3 C17 108.5(5) . .
C12 O4 C20 106.1(5) . .
F5 P1 F6 85.6(11) . .
F5 P1 F3 89.3(10) . .
F6 P1 F3 174.9(11) . .
F5 P1 F1 97.0(11) . .
F6 P1 F1 86.6(8) . .
F3 P1 F1 93.3(9) . .
F5 P1 F4 92.0(11) . .
F6 P1 F4 90.1(8) . .
F3 P1 F4 90.8(9) . .
F1 P1 F4 170.1(9) . .
F5 P1 F2 175.1(9) . .
F6 P1 F2 98.1(11) . .
F3 P1 F2 87.0(8) . .
F1 P1 F2 86.4(7) . .
F4 P1 F2 84.8(7) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 N4 2.233(6) .
Ag1 N1 2.267(8) .
Ag1 N3 2.355(8) .
Ag1 N2 2.414(8) .
C1 O1 1.419(2) .
C1 C21 1.460(14) 2_646
C1 C9 1.543(13) .
C1 H1 0.9800 .
C2 O1 1.419(2) .
C2 C3 1.47(2) .
C2 H2A 0.9700 .
C2 H2B 0.9700 .
C3 C9 1.485(15) .
C3 C4 1.500(16) .
C4 C5 1.511(14) .
C4 C7 1.520(13) .
C4 H4 0.9800 .
C5 O2 1.402(15) .
C5 H5A 0.9700 .
C5 H5B 0.9700 .
C6 O2 1.362(14) .
C6 C10 1.485(12) .
C6 C7 1.540(12) .
C6 H6 0.9800 .
C7 C8 1.490(11) .
C7 H7 0.9800 .
C8 C9 1.512(12) .
C8 H8A 0.9700 .
C8 H8B 0.9700 .
C9 H9 0.9800 .
C10 N1 1.110(10) .
C11 N2 1.123(10) .
C11 C12 1.472(10) .
C12 O4 1.417(9) .
C12 C13 1.542(9) .
C12 H12 0.9800 .
C13 C19 1.540(9) .
C13 C14 1.542(9) .
C13 H13 0.9800 .
C14 C15 1.527(9) .
C14 H14A 0.9700 .
C14 H14B 0.9700 .
C15 C16 1.525(9) .
C15 C18 1.536(9) .
C15 H15 0.9800 .
C16 O3 1.414(9) .
C16 C22 1.489(9) 4_676
C16 H16 0.9800 .
C17 O3 1.439(10) .
C17 C18 1.526(10) .
C17 H17A 0.9700 .
C17 H17B 0.9700 .
C18 C19 1.521(10) .
C18 H18 0.9800 .
C19 C20 1.521(10) .
C19 H19 0.9800 .
C20 O4 1.433(9) .
C20 H20A 0.9700 .
C20 H20B 0.9700 .
C21 N3 1.127(11) .
C21 C1 1.460(14) 2_656
C22 N4 1.125(8) .
C22 C16 1.489(9) 4_475
F1 P1 1.494(11) .
F2 P1 1.534(10) .
F3 P1 1.459(10) .
F4 P1 1.498(10) .
F5 P1 1.421(10) .
F6 P1 1.436(10) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O1 C2 C3 C9 41.6(16) . .
O1 C2 C3 C4 -78.4(18) . .
C2 C3 C4 C5 6.0(16) . .
C9 C3 C4 C5 -110.4(11) . .
C2 C3 C4 C7 122.0(12) . .
C9 C3 C4 C7 5.5(12) . .
C3 C4 C5 O2 82.5(11) . .
C7 C4 C5 O2 -34.7(9) . .
C3 C4 C7 C8 10.7(10) . .
C5 C4 C7 C8 137.2(7) . .
C3 C4 C7 C6 -110.5(9) . .
C5 C4 C7 C6 16.0(8) . .
O2 C6 C7 C8 -107.6(9) . .
C10 C6 C7 C8 129.4(9) . .
O2 C6 C7 C4 8.1(9) . .
C10 C6 C7 C4 -115.0(9) . .
C4 C7 C8 C9 -22.5(9) . .
C6 C7 C8 C9 89.8(9) . .
C2 C3 C9 C8 -147.6(10) . .
C4 C3 C9 C8 -19.3(12) . .
C2 C3 C9 C1 -27.7(11) . .
C4 C3 C9 C1 100.5(11) . .
C7 C8 C9 C3 25.8(10) . .
C7 C8 C9 C1 -88.7(9) . .
O1 C1 C9 C3 4.5(10) . .
C21 C1 C9 C3 124.0(10) 2_646 .
O1 C1 C9 C8 119.5(9) . .
C21 C1 C9 C8 -121.0(10) 2_646 .
O2 C6 C10 N1 -171(29) . .
C7 C6 C10 N1 -50(30) . .
N2 C11 C12 O4 -30(13) . .
N2 C11 C12 C13 87(13) . .
O4 C12 C13 C19 18.7(7) . .
C11 C12 C13 C19 -100.3(7) . .
O4 C12 C13 C14 -96.4(6) . .
C11 C12 C13 C14 144.5(6) . .
C19 C13 C14 C15 20.5(7) . .
C12 C13 C14 C15 133.8(6) . .
C13 C14 C15 C16 -144.4(6) . .
C13 C14 C15 C18 -35.1(7) . .
C14 C15 C16 O3 73.5(7) . .
C18 C15 C16 O3 -36.6(6) . .
C14 C15 C16 C22 -167.3(6) . 4_676
C18 C15 C16 C22 82.6(7) . 4_676
O3 C17 C18 C19 -128.7(6) . .
O3 C17 C18 C15 -14.2(7) . .
C16 C15 C18 C19 153.2(5) . .
C14 C15 C18 C19 36.8(7) . .
C16 C15 C18 C17 29.8(6) . .
C14 C15 C18 C17 -86.6(6) . .
C17 C18 C19 C20 -26.4(9) . .
C15 C18 C19 C20 -139.4(6) . .
C17 C18 C19 C13 89.0(7) . .
C15 C18 C19 C13 -24.0(7) . .
C12 C13 C19 C18 -117.9(6) . .
C14 C13 C19 C18 2.2(7) . .
C12 C13 C19 C20 5.3(7) . .
C14 C13 C19 C20 125.4(6) . .
C18 C19 C20 O4 89.1(7) . .
C13 C19 C20 O4 -27.4(7) . .
C6 C10 N1 Ag1 36(50) . .
N4 Ag1 N1 C10 -146(24) . .
N3 Ag1 N1 C10 -4(25) . .
N2 Ag1 N1 C10 103(25) . .
C12 C11 N2 Ag1 -80(13) . .
N4 Ag1 N2 C11 166.3(12) . .
N1 Ag1 N2 C11 -43.4(12) . .
N3 Ag1 N2 C11 51.3(12) . .
C1 C21 N3 Ag1 -44(25) 2_656 .
N4 Ag1 N3 C21 53(2) . .
N1 Ag1 N3 C21 -108(2) . .
N2 Ag1 N3 C21 162(2) . .
C16 C22 N4 Ag1 6(16) 4_475 .
N1 Ag1 N4 C22 -50(5) . .
N3 Ag1 N4 C22 170(5) . .
N2 Ag1 N4 C22 58(5) . .
C21 C1 O1 C2 -99.3(14) 2_646 .
C9 C1 O1 C2 21.9(14) . .
C3 C2 O1 C1 -40.8(18) . .
C10 C6 O2 C5 92.1(9) . .
C7 C6 O2 C5 -31.3(10) . .
C4 C5 O2 C6 41.5(10) . .
C22 C16 O3 C17 -92.4(7) 4_676 .
C15 C16 O3 C17 28.6(7) . .
C18 C17 O3 C16 -8.8(8) . .
C11 C12 O4 C20 83.7(6) . .
C13 C12 O4 C20 -37.5(7) . .
C19 C20 O4 C12 40.9(7) . .
