#------------------------------------------------------------------------------
#$Date: 2016-03-26 19:34:25 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180440 $
#$URL: svn://www.crystallography.net/cod/cif/7/21/09/7210998.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7210998
loop_
_publ_author_name
'Yu, Wen-Jing'
'Chen, Xi'
'Li, Jia'
'Li, Bao'
'Zhang, Tian-le'
'Tao, Jun'
_publ_section_title
;
 Lanthanide coordination polymers with hexa-carboxylate ligands derived
 from cyclotriphosphazene as bridging linkers: synthesis, thermal and
 luminescent properties
;
_journal_issue                   38
_journal_name_full               CrystEngComm
_journal_page_first              7732
_journal_paper_doi               10.1039/c3ce41060a
_journal_volume                  15
_journal_year                    2013
_chemical_formula_sum            'C47 H38 Eu2 N5 O24 P3'
_chemical_formula_weight         1453.65
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                96.869(3)
_cell_angle_beta                 92.323(2)
_cell_angle_gamma                92.071(2)
_cell_formula_units_Z            2
_cell_length_a                   9.2371(3)
_cell_length_b                   9.8604(3)
_cell_length_c                   30.4599(10)
_cell_measurement_temperature    293(2)
_cell_volume                     2749.81(15)
_computing_cell_refinement       SMART
_computing_data_collection       SMART
_computing_data_reduction        SAINT-Plus
_computing_molecular_graphics    DIAMOND
_computing_publication_material  PUBLCIF
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.973
_diffrn_measured_fraction_theta_max 0.973
_diffrn_measurement_device_type  'Brucker SMART APEX'
_diffrn_measurement_method       'ω scan'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0481
_diffrn_reflns_av_sigmaI/netI    0.0682
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       36
_diffrn_reflns_limit_l_min       -36
_diffrn_reflns_number            25951
_diffrn_reflns_theta_full        26.00
_diffrn_reflns_theta_max         26.00
_diffrn_reflns_theta_min         3.06
_exptl_absorpt_coefficient_mu    2.435
_exptl_absorpt_correction_T_max  0.7928
_exptl_absorpt_correction_T_min  0.6417
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            white
_exptl_crystal_density_diffrn    1.756
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1436
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.10
_platon_squeeze_details
;
;
_refine_diff_density_max         3.156
_refine_diff_density_min         -3.640
_refine_diff_density_rms         0.159
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.052
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     724
_refine_ls_number_reflns         10521
_refine_ls_number_restraints     13
_refine_ls_restrained_S_all      1.052
_refine_ls_R_factor_all          0.0737
_refine_ls_R_factor_gt           0.0594
_refine_ls_shift/su_max          0.011
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0427P)²+21.1965P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1270
_refine_ls_wR_factor_ref         0.1343
_reflns_number_gt                8846
_reflns_number_total             10521
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c3ce41060a.txt
_cod_data_source_block           compound3
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7210998
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Eu1 Eu 0.18795(3) 0.50347(3) 0.470884(10) 0.01451(10) Uani 1 1 d .
Eu2 Eu 0.02599(6) 0.16442(5) -0.034497(13) 0.05001(16) Uani 1 1 d .
P3 P 0.25395(19) 0.07681(19) 0.24155(6) 0.0220(4) Uani 1 1 d .
P1 P 0.04911(19) -0.03370(18) 0.29240(6) 0.0202(4) Uani 1 1 d .
P2 P 0.00729(19) 0.21460(19) 0.26244(6) 0.0210(4) Uani 1 1 d .
O3 O 0.0837(5) 0.2838(5) 0.47403(15) 0.0220(10) Uani 1 1 d .
O9 O -0.2963(5) 0.5296(5) 0.45593(15) 0.0208(10) Uani 1 1 d .
O1 O 0.0956(5) -0.0624(5) 0.34062(15) 0.0224(10) Uani 1 1 d .
O8 O -0.0616(5) 0.5069(5) 0.45191(14) 0.0176(10) Uani 1 1 d .
O7 O 0.0051(5) 0.3617(5) 0.28944(15) 0.0224(10) Uani 1 1 d .
O1W O 0.4288(5) 0.6257(5) 0.47496(16) 0.0238(11) Uani 1 1 d .
O2 O -0.1511(5) 0.2744(5) 0.49013(16) 0.0241(11) Uani 1 1 d .
O15 O 0.2348(5) 0.3792(5) 0.39833(15) 0.0268(11) Uani 1 1 d .
O14 O 0.3884(5) 0.3384(5) 0.45170(16) 0.0266(11) Uani 1 1 d .
O4 O -0.0566(6) -0.1646(5) 0.27846(16) 0.0292(12) Uani 1 1 d .
O13 O 0.4163(5) 0.1199(5) 0.25845(16) 0.0294(12) Uani 1 1 d .
C21 C -0.1862(7) 0.5120(6) 0.4332(2) 0.0163(13) Uani 1 1 d .
O19 O 0.1768(6) 0.6578(5) 0.41604(17) 0.0303(12) Uani 1 1 d .
O16 O 0.2827(5) 0.0114(5) 0.19305(15) 0.0284(12) Uani 1 1 d .
O10 O -0.1181(5) 0.2129(5) 0.22497(14) 0.0254(11) Uani 1 1 d .
C17 C -0.2030(7) 0.4899(6) 0.3843(2) 0.0158(13) Uani 1 1 d .
C30 C 0.6033(7) 0.1189(7) 0.3132(2) 0.0260(16) Uani 1 1 d .
H30A H 0.6607 0.0790 0.2912 0.031 Uiso 1 1 calc R
C14 C -0.1459(11) -0.2010(9) 0.1180(3) 0.043(2) Uani 1 1 d .
C35 C 0.3480(7) 0.3246(7) 0.4118(2) 0.0210(14) Uani 1 1 d .
C3 C -0.0604(7) 0.0942(7) 0.4417(2) 0.0197(14) Uani 1 1 d .
C7 C -0.0409(7) 0.2271(7) 0.4713(2) 0.0209(14) Uani 1 1 d .
N3 N 0.1607(7) 0.2091(6) 0.24194(19) 0.0257(13) Uani 1 1 d .
C33 C 0.4351(7) 0.2452(7) 0.3777(2) 0.0204(14) Uani 1 1 d .
C1 C 0.0032(7) -0.0442(7) 0.3769(2) 0.0177(14) Uani 1 1 d .
C16 C -0.0902(7) 0.4387(6) 0.3594(2) 0.0162(13) Uani 1 1 d .
H16A H -0.0015 0.4229 0.3729 0.019 Uiso 1 1 calc R
C2 C 0.0223(7) 0.0750(7) 0.4050(2) 0.0195(14) Uani 1 1 d .
H2A H 0.0902 0.1420 0.3994 0.023 Uiso 1 1 calc R
C6 C -0.0925(8) -0.1476(7) 0.3844(2) 0.0244(15) Uani 1 1 d .
H6A H -0.1012 -0.2287 0.3653 0.029 Uiso 1 1 calc R
C32 C 0.5726(8) 0.2068(7) 0.3885(2) 0.0256(16) Uani 1 1 d .
H32A H 0.6087 0.2224 0.4177 0.031 Uiso 1 1 calc R
C34 C 0.3787(7) 0.2180(7) 0.3348(2) 0.0240(15) Uani 1 1 d .
H34A H 0.2856 0.2432 0.3274 0.029 Uiso 1 1 calc R
O18 O 0.1192(9) 0.0392(8) 0.0341(2) 0.0655(15) Uani 1 1 d .
C29 C 0.4632(7) 0.1523(7) 0.3030(2) 0.0238(15) Uani 1 1 d .
N2 N 0.1923(6) -0.0437(6) 0.26544(19) 0.0240(13) Uani 1 1 d .
O6 O -0.0138(7) -0.1722(7) 0.11389(18) 0.0477(16) Uani 1 1 d .
O12 O -0.1561(9) 0.0319(7) 0.06461(19) 0.0573(19) Uani 1 1 d .
C9 C -0.1034(9) -0.1739(8) 0.1994(2) 0.0309(17) Uani 1 1 d .
H9A H -0.0052 -0.1592 0.1951 0.037 Uiso 1 1 calc R
C5 C -0.1754(8) -0.1278(7) 0.4211(2) 0.0283(16) Uani 1 1 d .
H5A H -0.2418 -0.1961 0.4267 0.034 Uiso 1 1 calc R
O5 O -0.2308(8) -0.2332(7) 0.08430(19) 0.0583(19) Uani 1 1 d .
C4 C -0.1609(7) -0.0076(7) 0.4496(2) 0.0246(15) Uani 1 1 d .
H4A H -0.2182 0.0052 0.4741 0.030 Uiso 1 1 calc R
C15 C -0.1120(7) 0.4118(7) 0.3141(2) 0.0192(14) Uani 1 1 d .
O3W O -0.2209(9) 0.2182(8) -0.0588(2) 0.071(2) Uani 1 1 d .
N1 N -0.0383(6) 0.1013(6) 0.29201(18) 0.0204(12) Uani 1 1 d .
C20 C -0.2419(8) 0.4381(8) 0.2927(2) 0.0298(17) Uani 1 1 d .
H20A H -0.2545 0.4194 0.2621 0.036 Uiso 1 1 calc R
C22 C -0.0981(8) 0.2733(8) 0.1859(2) 0.0288(17) Uani 1 1 d .
C31 C 0.6570(8) 0.1451(8) 0.3560(2) 0.0276(16) Uani 1 1 d .
H31A H 0.7507 0.1212 0.3633 0.033 Uiso 1 1 calc R
C8 C -0.1522(8) -0.1756(8) 0.2415(2) 0.0273(16) Uani 1 1 d .
C42 C 0.2158(12) 0.1314(11) 0.0433(3) 0.051(3) Uani 1 1 d .
O11 O -0.1118(9) 0.2138(7) 0.02966(19) 0.066(2) Uani 1 1 d .
C10 C -0.2025(9) -0.1944(9) 0.1633(3) 0.0360(19) Uani 1 1 d .
C23 C -0.1165(9) 0.1900(8) 0.1465(2) 0.0325(18) Uani 1 1 d .
H23A H -0.1367 0.0968 0.1463 0.039 Uiso 1 1 calc R
C36 C 0.3369(8) 0.0814(9) 0.1595(2) 0.0342(19) Uani 1 1 d .
C28 C -0.1282(12) 0.1554(11) 0.0636(3) 0.050(2) Uani 1 1 d .
C24 C -0.1047(10) 0.2458(9) 0.1069(2) 0.037(2) Uani 1 1 d .
C13 C -0.2984(10) -0.1918(11) 0.2490(3) 0.050(3) Uani 1 1 d .
H13A H -0.3301 -0.1925 0.2776 0.060 Uiso 1 1 calc R
O2W O 0.0335(13) 0.4074(9) -0.0213(3) 0.102(4) Uani 1 1 d .
C27 C -0.0673(11) 0.4101(10) 0.1872(3) 0.047(2) Uani 1 1 d .
H27A H -0.0569 0.4653 0.2142 0.057 Uiso 1 1 calc R
C12 C -0.3972(10) -0.2072(14) 0.2125(3) 0.068(3) Uani 1 1 d .
H12A H -0.4961 -0.2170 0.2167 0.082 Uiso 1 1 calc R
C11 C -0.3482(11) -0.2078(11) 0.1705(3) 0.054(3) Uani 1 1 d .
H11A H -0.4148 -0.2175 0.1464 0.065 Uiso 1 1 calc R
C18 C -0.3339(7) 0.5182(7) 0.3632(2) 0.0231(15) Uani 1 1 d .
H18A H -0.4088 0.5545 0.3797 0.028 Uiso 1 1 calc R
C19 C -0.3516(8) 0.4923(8) 0.3177(2) 0.0328(18) Uani 1 1 d .
H19A H -0.4385 0.5116 0.3037 0.039 Uiso 1 1 calc R
O17 O 0.2394(9) 0.2185(8) 0.0174(2) 0.0655(15) Uani 1 1 d .
C37 C 0.2514(9) 0.0747(9) 0.1205(2) 0.0349(19) Uani 1 1 d .
H37A H 0.1617 0.0278 0.1177 0.042 Uiso 1 1 calc R
C38 C 0.3026(10) 0.1390(10) 0.0858(3) 0.044(2) Uani 1 1 d .
C25 C -0.0733(12) 0.3820(10) 0.1073(3) 0.053(3) Uani 1 1 d .
H25A H -0.0664 0.4193 0.0808 0.064 Uiso 1 1 calc R
C26 C -0.0513(13) 0.4665(10) 0.1479(3) 0.060(3) Uani 1 1 d .
H26A H -0.0264 0.5590 0.1484 0.072 Uiso 1 1 calc R
C45 C 0.2585(12) 0.6952(13) 0.3891(4) 0.067(3) Uani 1 1 d .
H45A H 0.2583 0.6354 0.3631 0.081 Uiso 1 1 calc R
C43 C 0.4318(12) 0.8358(13) 0.3548(4) 0.074(4) Uani 1 1 d .
H43A H 0.4197 0.7671 0.3297 0.111 Uiso 1 1 calc R
H43B H 0.5317 0.8432 0.3651 0.111 Uiso 1 1 calc R
H43C H 0.4032 0.9221 0.3465 0.111 Uiso 1 1 calc R
C39 C 0.4367(13) 0.2031(15) 0.0899(3) 0.078(4) Uani 1 1 d .
H39A H 0.4709 0.2450 0.0664 0.093 Uiso 1 1 calc R
C44 C 0.3530(14) 0.8972(12) 0.4299(5) 0.080(4) Uani 1 1 d .
H44A H 0.2905 0.8655 0.4513 0.120 Uiso 1 1 calc R
H44B H 0.3233 0.9847 0.4230 0.120 Uiso 1 1 calc R
H44C H 0.4511 0.9053 0.4418 0.120 Uiso 1 1 calc R
N4 N 0.3438(9) 0.7988(10) 0.3893(3) 0.059(2) Uani 1 1 d .
C41 C 0.4715(10) 0.1429(14) 0.1635(3) 0.069(4) Uani 1 1 d .
H41A H 0.5293 0.1429 0.1892 0.083 Uiso 1 1 calc R
C40 C 0.5213(12) 0.2070(17) 0.1274(4) 0.092(5) Uani 1 1 d .
H40A H 0.6121 0.2518 0.1295 0.111 Uiso 1 1 calc R
O5W O -0.2936(11) 0.3436(10) -0.1362(6) 0.165(7) Uani 1 1 d .
N5 N -0.7125(12) -0.4211(12) 0.1946(4) 0.087(3) Uani 1 1 d U
H5B H -0.7281 -0.3625 0.1763 0.105 Uiso 1 1 calc R
O4W O -0.5023(12) 0.1113(15) -0.0355(4) 0.134(4) Uani 1 1 d .
C46 C -0.7529(18) -0.399(2) 0.2405(5) 0.122(7) Uani 1 1 d .
H46A H -0.7960 -0.3120 0.2461 0.183 Uiso 1 1 calc R
H46B H -0.6680 -0.4007 0.2597 0.183 Uiso 1 1 calc R
H46C H -0.8212 -0.4701 0.2460 0.183 Uiso 1 1 calc R
C47 C -0.642(2) -0.5522(16) 0.1815(6) 0.130(7) Uani 1 1 d U
H47A H -0.6217 -0.5591 0.1507 0.195 Uiso 1 1 calc R
H47B H -0.7065 -0.6271 0.1865 0.195 Uiso 1 1 calc R
H47C H -0.5538 -0.5552 0.1989 0.195 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O3 Eu1 O8 71.63(15) . .
O3 Eu1 O19 132.86(17) . .
O8 Eu1 O19 76.30(17) . .
O3 Eu1 O2 133.88(16) . 2_566
O8 Eu1 O2 83.87(16) . 2_566
O19 Eu1 O2 73.70(18) . 2_566
O3 Eu1 O15 76.29(17) . .
O8 Eu1 O15 91.36(15) . .
O19 Eu1 O15 70.83(18) . .
O2 Eu1 O15 144.33(17) 2_566 .
O3 Eu1 O9 83.20(16) . 2_566
O8 Eu1 O9 126.20(15) . 2_566
O19 Eu1 O9 143.92(17) . 2_566
O2 Eu1 O9 80.75(16) 2_566 2_566
O15 Eu1 O9 128.21(15) . 2_566
O3 Eu1 O1W 140.54(15) . .
O8 Eu1 O1W 147.15(15) . .
O19 Eu1 O1W 73.88(16) . .
O2 Eu1 O1W 74.86(16) 2_566 .
O15 Eu1 O1W 91.64(17) . .
O9 Eu1 O1W 75.15(15) 2_566 .
O3 Eu1 O14 74.41(16) . .
O8 Eu1 O14 134.99(15) . .
O19 Eu1 O14 108.10(17) . .
O2 Eu1 O14 141.03(16) 2_566 .
O15 Eu1 O14 52.02(15) . .
O9 Eu1 O14 76.87(15) 2_566 .
O1W Eu1 O14 68.81(16) . .
O3 Eu1 O8 69.72(15) . 2_566
O8 Eu1 O8 76.28(15) . 2_566
O19 Eu1 O8 133.60(16) . 2_566
O2 Eu1 O8 66.76(15) 2_566 2_566
O15 Eu1 O8 145.94(16) . 2_566
O9 Eu1 O8 50.27(14) 2_566 2_566
O1W Eu1 O8 115.98(14) . 2_566
O14 Eu1 O8 117.79(15) . 2_566
O3 Eu1 C35 74.88(18) . .
O8 Eu1 C35 114.78(17) . .
O19 Eu1 C35 88.73(19) . .
O2 Eu1 C35 150.96(18) 2_566 .
O15 Eu1 C35 26.22(17) . .
O9 Eu1 C35 102.58(17) 2_566 .
O1W Eu1 C35 78.15(17) . .
O14 Eu1 C35 25.85(17) . .
O8 Eu1 C35 136.95(17) 2_566 .
O3 Eu1 C21 77.56(17) . 2_566
O8 Eu1 C21 101.81(16) . 2_566
O19 Eu1 C21 143.50(18) . 2_566
O2 Eu1 C21 69.87(17) 2_566 2_566
O15 Eu1 C21 145.15(17) . 2_566
O9 Eu1 C21 24.96(15) 2_566 2_566
O1W Eu1 C21 94.12(17) . 2_566
O14 Eu1 C21 98.74(16) . 2_566
O8 Eu1 C21 25.53(15) 2_566 2_566
C35 Eu1 C21 123.10(18) . 2_566
O3 Eu1 Eu1 65.07(11) . 2_566
O8 Eu1 Eu1 41.02(11) . 2_566
O19 Eu1 Eu1 108.97(13) . 2_566
O2 Eu1 Eu1 70.73(11) 2_566 2_566
O15 Eu1 Eu1 125.02(12) . 2_566
O9 Eu1 Eu1 85.36(10) 2_566 2_566
O1W Eu1 Eu1 142.67(11) . 2_566
O14 Eu1 Eu1 137.32(12) . 2_566
O8 Eu1 Eu1 35.26(9) 2_566 2_566
C35 Eu1 Eu1 137.97(14) . 2_566
C21 Eu1 Eu1 60.79(12) 2_566 2_566
O2W Eu2 O18 145.6(3) . 2
O2W Eu2 O11 75.7(3) . .
O18 Eu2 O11 77.1(3) 2 .
O2W Eu2 O12 144.4(3) . 2
O18 Eu2 O12 69.8(3) 2 2
O11 Eu2 O12 133.9(2) . 2
O2W Eu2 O6 90.9(2) . 2
O18 Eu2 O6 97.5(2) 2 2
O11 Eu2 O6 141.5(2) . 2
O12 Eu2 O6 75.4(2) 2 2
O2W Eu2 O3W 77.8(3) . .
O18 Eu2 O3W 73.9(3) 2 .
O11 Eu2 O3W 71.8(2) . .
O12 Eu2 O3W 125.1(3) 2 .
O6 Eu2 O3W 70.2(2) 2 .
O2W Eu2 O17 76.7(3) . .
O18 Eu2 O17 121.3(2) 2 .
O11 Eu2 O17 84.8(3) . .
O12 Eu2 O17 85.9(3) 2 .
O6 Eu2 O17 127.6(2) 2 .
O3W Eu2 O17 148.8(3) . .
O2W Eu2 O5 77.3(3) . 2
O18 Eu2 O5 132.9(2) 2 2
O11 Eu2 O5 149.7(2) . 2
O12 Eu2 O5 68.3(2) 2 2
O6 Eu2 O5 51.8(2) 2 2
O3W Eu2 O5 115.4(2) . 2
O17 Eu2 O5 75.8(2) . 2
O2W Eu2 O18 115.0(3) . .
O18 Eu2 O18 72.0(3) 2 .
O11 Eu2 O18 66.8(2) . .
O12 Eu2 O18 73.0(2) 2 .
O6 Eu2 O18 148.3(2) 2 .
O3W Eu2 O18 130.7(3) . .
O17 Eu2 O18 49.8(2) . .
O5 Eu2 O18 113.9(2) 2 .
O2W Eu2 C14 85.6(3) . 2
O18 Eu2 C14 115.1(2) 2 2
O11 Eu2 C14 158.2(2) . 2
O12 Eu2 C14 67.7(2) 2 2
O6 Eu2 C14 25.8(2) 2 2
O3W Eu2 C14 93.7(3) . 2
O17 Eu2 C14 101.9(3) . 2
O5 Eu2 C14 26.2(2) 2 2
O18 Eu2 C14 132.9(3) . 2
O2W Eu2 C42 94.6(3) . .
O18 Eu2 C42 97.0(3) 2 .
O11 Eu2 C42 72.5(3) . .
O12 Eu2 C42 80.6(2) 2 .
O6 Eu2 C42 145.5(3) 2 .
O3W Eu2 C42 144.2(3) . .
O17 Eu2 C42 24.8(3) . .
O5 Eu2 C42 96.3(3) 2 .
O18 Eu2 C42 25.1(2) . .
C14 Eu2 C42 120.8(3) 2 .
O2W Eu2 Eu2 139.01(18) . 2
O18 Eu2 Eu2 38.47(15) 2 2
O11 Eu2 Eu2 67.23(16) . 2
O12 Eu2 Eu2 66.91(16) 2 2
O6 Eu2 Eu2 129.22(16) 2 2
O3W Eu2 Eu2 105.40(19) . 2
O17 Eu2 Eu2 83.05(16) . 2
O5 Eu2 Eu2 131.32(17) 2 2
O18 Eu2 Eu2 33.48(17) . 2
C14 Eu2 Eu2 133.76(19) 2 2
C42 Eu2 Eu2 58.6(2) . 2
N2 P3 O16 105.4(3) . .
N2 P3 N3 117.5(3) . .
O16 P3 N3 112.0(3) . .
N2 P3 O13 111.3(3) . .
O16 P3 O13 99.3(3) . .
N3 P3 O13 109.7(3) . .
O1 P1 N1 112.6(3) . .
O1 P1 N2 105.6(3) . .
N1 P1 N2 117.3(3) . .
O1 P1 O4 98.9(3) . .
N1 P1 O4 110.0(3) . .
N2 P1 O4 110.8(3) . .
N3 P2 N1 118.6(3) . .
N3 P2 O7 104.7(3) . .
N1 P2 O7 110.8(3) . .
N3 P2 O10 111.2(3) . .
N1 P2 O10 106.2(3) . .
O7 P2 O10 104.8(3) . .
C7 O3 Eu1 137.8(4) . .
C21 O9 Eu1 99.1(4) . 2_566
C1 O1 P1 123.3(4) . .
C21 O8 Eu1 167.3(4) . .
C21 O8 Eu1 89.0(4) . 2_566
Eu1 O8 Eu1 103.72(15) . 2_566
C15 O7 P2 124.7(4) . .
C7 O2 Eu1 130.5(4) . 2_566
C35 O15 Eu1 94.9(4) . .
C35 O14 Eu1 91.2(4) . .
C8 O4 P1 122.6(5) . .
C29 O13 P3 125.0(4) . .
O9 C21 O8 120.6(6) . .
O9 C21 C17 119.8(5) . .
O8 C21 C17 119.6(6) . .
O9 C21 Eu1 55.9(3) . 2_566
O8 C21 Eu1 65.5(3) . 2_566
C17 C21 Eu1 167.2(4) . 2_566
C45 O19 Eu1 135.7(6) . .
C36 O16 P3 125.7(5) . .
C22 O10 P2 122.1(5) . .
C16 C17 C18 119.7(6) . .
C16 C17 C21 120.3(5) . .
C18 C17 C21 120.0(6) . .
C31 C30 C29 119.3(6) . .
C31 C30 H30A 120.3 . .
C29 C30 H30A 120.3 . .
O6 C14 O5 121.0(8) . .
O6 C14 C10 118.9(7) . .
O5 C14 C10 120.1(9) . .
O6 C14 Eu2 57.0(4) . 2
O5 C14 Eu2 64.6(5) . 2
C10 C14 Eu2 170.2(6) . 2
O14 C35 O15 121.7(6) . .
O14 C35 C33 120.6(6) . .
O15 C35 C33 117.7(6) . .
O14 C35 Eu1 63.0(3) . .
O15 C35 Eu1 58.9(3) . .
C33 C35 Eu1 173.1(5) . .
C2 C3 C4 119.6(6) . .
C2 C3 C7 118.3(6) . .
C4 C3 C7 122.1(6) . .
O3 C7 O2 125.8(6) . .
O3 C7 C3 116.4(6) . .
O2 C7 C3 117.8(6) . .
P2 N3 P3 121.2(4) . .
C32 C33 C34 120.4(6) . .
C32 C33 C35 120.5(6) . .
C34 C33 C35 119.0(6) . .
C2 C1 C6 122.6(6) . .
C2 C1 O1 117.1(6) . .
C6 C1 O1 120.1(6) . .
C15 C16 C17 118.9(6) . .
C15 C16 H16A 120.5 . .
C17 C16 H16A 120.5 . .
C1 C2 C3 119.1(6) . .
C1 C2 H2A 120.5 . .
C3 C2 H2A 120.5 . .
C1 C6 C5 118.1(6) . .
C1 C6 H6A 120.9 . .
C5 C6 H6A 120.9 . .
C33 C32 C31 120.0(6) . .
C33 C32 H32A 120.0 . .
C31 C32 H32A 120.0 . .
C33 C34 C29 118.8(6) . .
C33 C34 H34A 120.6 . .
C29 C34 H34A 120.6 . .
C42 O18 Eu2 162.4(6) . 2
C42 O18 Eu2 89.5(5) . .
Eu2 O18 Eu2 108.0(3) 2 .
C30 C29 C34 121.1(7) . .
C30 C29 O13 115.5(6) . .
C34 C29 O13 123.3(6) . .
P3 N2 P1 122.8(4) . .
C14 O6 Eu2 97.3(5) . 2
C28 O12 Eu2 129.6(7) . 2
C8 C9 C10 119.5(8) . .
C8 C9 H9A 120.3 . .
C10 C9 H9A 120.3 . .
C6 C5 C4 120.8(7) . .
C6 C5 H5A 119.6 . .
C4 C5 H5A 119.6 . .
C14 O5 Eu2 89.2(6) . 2
C5 C4 C3 119.8(7) . .
C5 C4 H4A 120.1 . .
C3 C4 H4A 120.1 . .
C16 C15 C20 121.8(6) . .
C16 C15 O7 117.7(6) . .
C20 C15 O7 120.4(6) . .
P2 N1 P1 121.1(4) . .
C19 C20 C15 118.8(6) . .
C19 C20 H20A 120.6 . .
C15 C20 H20A 120.6 . .
C27 C22 C23 121.5(7) . .
C27 C22 O10 121.2(7) . .
C23 C22 O10 117.3(7) . .
C30 C31 C32 120.3(6) . .
C30 C31 H31A 119.9 . .
C32 C31 H31A 119.9 . .
C9 C8 C13 121.5(7) . .
C9 C8 O4 121.6(7) . .
C13 C8 O4 116.9(7) . .
O17 C42 O18 120.9(8) . .
O17 C42 C38 119.6(10) . .
O18 C42 C38 119.6(9) . .
O17 C42 Eu2 56.2(5) . .
O18 C42 Eu2 65.4(5) . .
C38 C42 Eu2 169.8(7) . .
C28 O11 Eu2 133.2(6) . .
C11 C10 C9 119.3(8) . .
C11 C10 C14 122.4(8) . .
C9 C10 C14 118.3(8) . .
C22 C23 C24 119.5(8) . .
C22 C23 H23A 120.2 . .
C24 C23 H23A 120.2 . .
C41 C36 C37 121.7(8) . .
C41 C36 O16 121.4(7) . .
C37 C36 O16 116.7(7) . .
O12 C28 O11 126.5(9) . .
O12 C28 C24 118.1(8) . .
O11 C28 C24 115.4(9) . .
C25 C24 C23 120.1(8) . .
C25 C24 C28 120.1(8) . .
C23 C24 C28 119.8(8) . .
C8 C13 C12 118.4(8) . .
C8 C13 H13A 120.8 . .
C12 C13 H13A 120.8 . .
C22 C27 C26 119.6(8) . .
C22 C27 H27A 120.2 . .
C26 C27 H27A 120.2 . .
C11 C12 C13 120.0(9) . .
C11 C12 H12A 120.0 . .
C13 C12 H12A 120.0 . .
C12 C11 C10 121.2(8) . .
C12 C11 H11A 119.4 . .
C10 C11 H11A 119.4 . .
C19 C18 C17 120.0(6) . .
C19 C18 H18A 120.0 . .
C17 C18 H18A 120.0 . .
C20 C19 C18 120.7(6) . .
C20 C19 H19A 119.7 . .
C18 C19 H19A 119.7 . .
C42 O17 Eu2 99.0(6) . .
C38 C37 C36 118.8(8) . .
C38 C37 H37A 120.6 . .
C36 C37 H37A 120.6 . .
C39 C38 C37 119.7(8) . .
C39 C38 C42 119.9(9) . .
C37 C38 C42 120.3(9) . .
C24 C25 C26 120.1(8) . .
C24 C25 H25A 119.9 . .
C26 C25 H25A 119.9 . .
C27 C26 C25 119.2(9) . .
C27 C26 H26A 120.4 . .
C25 C26 H26A 120.4 . .
O19 C45 N4 133.1(13) . .
O19 C45 H45A 113.4 . .
N4 C45 H45A 113.4 . .
N4 C43 H43A 109.5 . .
N4 C43 H43B 109.5 . .
H43A C43 H43B 109.5 . .
N4 C43 H43C 109.5 . .
H43A C43 H43C 109.5 . .
H43B C43 H43C 109.5 . .
C40 C39 C38 121.6(10) . .
C40 C39 H39A 119.2 . .
C38 C39 H39A 119.2 . .
N4 C44 H44A 109.5 . .
N4 C44 H44B 109.5 . .
H44A C44 H44B 109.5 . .
N4 C44 H44C 109.5 . .
H44A C44 H44C 109.5 . .
H44B C44 H44C 109.5 . .
C45 N4 C43 128.6(12) . .
C45 N4 C44 116.9(11) . .
C43 N4 C44 114.5(10) . .
C36 C41 C40 118.2(9) . .
C36 C41 H41A 120.9 . .
C40 C41 H41A 120.9 . .
C39 C40 C41 120.0(10) . .
C39 C40 H40A 120.0 . .
C41 C40 H40A 120.0 . .
C46 N5 C47 115.1(13) . .
C46 N5 H5B 122.4 . .
C47 N5 H5B 122.4 . .
N5 C46 H46A 109.5 . .
N5 C46 H46B 109.5 . .
H46A C46 H46B 109.5 . .
N5 C46 H46C 109.5 . .
H46A C46 H46C 109.5 . .
H46B C46 H46C 109.5 . .
N5 C47 H47A 109.5 . .
N5 C47 H47B 109.5 . .
H47A C47 H47B 109.5 . .
N5 C47 H47C 109.5 . .
H47A C47 H47C 109.5 . .
H47B C47 H47C 109.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Eu1 O3 2.353(5) .
Eu1 O8 2.356(4) .
Eu1 O19 2.392(5) .
Eu1 O2 2.406(5) 2_566
Eu1 O15 2.458(5) .
Eu1 O9 2.469(4) 2_566
Eu1 O1W 2.483(5) .
Eu1 O14 2.549(5) .
Eu1 O8 2.678(4) 2_566
Eu1 C35 2.860(7) .
Eu1 C21 2.943(6) 2_566
Eu1 Eu1 3.9646(6) 2_566
Eu2 O2W 2.379(8) .
Eu2 O18 2.375(8) 2
Eu2 O11 2.386(7) .
Eu2 O12 2.422(7) 2
Eu2 O6 2.427(5) 2
Eu2 O3W 2.464(8) .
Eu2 O17 2.477(7) .
Eu2 O5 2.593(7) 2
Eu2 O18 2.679(6) .
Eu2 C14 2.871(9) 2
Eu2 C42 2.946(9) .
Eu2 Eu2 4.0940(9) 2
P3 N2 1.567(6) .
P3 O16 1.576(5) .
P3 N3 1.588(6) .
P3 O13 1.592(5) .
P1 O1 1.574(5) .
P1 N1 1.583(6) .
P1 N2 1.585(6) .
P1 O4 1.595(5) .
P2 N3 1.572(6) .
P2 N1 1.573(6) .
P2 O7 1.581(5) .
P2 O10 1.591(5) .
O3 C7 1.257(8) .
O9 C21 1.258(8) .
O9 Eu1 2.469(4) 2_566
O1 C1 1.422(8) .
O8 C21 1.269(7) .
O8 Eu1 2.678(4) 2_566
O7 C15 1.413(8) .
O2 C7 1.265(8) .
O2 Eu1 2.406(5) 2_566
O15 C35 1.268(8) .
O14 C35 1.248(8) .
O4 C8 1.393(8) .
O13 C29 1.402(8) .
C21 C17 1.480(9) .
C21 Eu1 2.943(6) 2_566
O19 C45 1.216(12) .
O16 C36 1.398(9) .
O10 C22 1.409(8) .
C17 C16 1.389(9) .
C17 C18 1.400(9) .
C30 C31 1.368(10) .
C30 C29 1.379(10) .
C30 H30A 0.9300 .
C14 O6 1.257(11) .
C14 O5 1.268(10) .
C14 C10 1.490(12) .
C14 Eu2 2.871(9) 2
C35 C33 1.502(9) .
C3 C2 1.378(9) .
C3 C4 1.392(10) .
C3 C7 1.500(9) .
C33 C32 1.377(9) .
C33 C34 1.379(10) .
C1 C2 1.370(9) .
C1 C6 1.371(10) .
C16 C15 1.377(9) .
C16 H16A 0.9300 .
C2 H2A 0.9300 .
C6 C5 1.377(10) .
C6 H6A 0.9300 .
C32 C31 1.383(10) .
C32 H32A 0.9300 .
C34 C29 1.385(10) .
C34 H34A 0.9300 .
O18 C42 1.250(12) .
O18 Eu2 2.375(8) 2
O6 Eu2 2.427(5) 2
O12 C28 1.241(12) .
O12 Eu2 2.422(7) 2
C9 C8 1.379(10) .
C9 C10 1.394(11) .
C9 H9A 0.9300 .
C5 C4 1.383(10) .
C5 H5A 0.9300 .
O5 Eu2 2.593(7) 2
C4 H4A 0.9300 .
C15 C20 1.389(10) .
C20 C19 1.376(10) .
C20 H20A 0.9300 .
C22 C27 1.365(12) .
C22 C23 1.371(10) .
C31 H31A 0.9300 .
C8 C13 1.386(11) .
C42 O17 1.253(11) .
C42 C38 1.489(12) .
O11 C28 1.252(11) .
C10 C11 1.377(13) .
C23 C24 1.391(11) .
C23 H23A 0.9300 .
C36 C41 1.358(13) .
C36 C37 1.394(11) .
C28 C24 1.505(12) .
C24 C25 1.362(13) .
C13 C12 1.400(13) .
C13 H13A 0.9300 .
C27 C26 1.390(12) .
C27 H27A 0.9300 .
C12 C11 1.375(14) .
C12 H12A 0.9300 .
C11 H11A 0.9300 .
C18 C19 1.380(10) .
C18 H18A 0.9300 .
C19 H19A 0.9300 .
C37 C38 1.386(12) .
C37 H37A 0.9300 .
C38 C39 1.365(14) .
C25 C26 1.408(14) .
C25 H25A 0.9300 .
C26 H26A 0.9300 .
C45 N4 1.267(14) .
C45 H45A 0.9300 .
C43 N4 1.428(13) .
C43 H43A 0.9600 .
C43 H43B 0.9600 .
C43 H43C 0.9600 .
C39 C40 1.354(15) .
C39 H39A 0.9300 .
C44 N4 1.474(15) .
C44 H44A 0.9600 .
C44 H44B 0.9600 .
C44 H44C 0.9600 .
C41 C40 1.416(14) .
C41 H41A 0.9300 .
C40 H40A 0.9300 .
N5 C46 1.455(17) .
N5 C47 1.485(17) .
N5 H5B 0.8600 .
C46 H46A 0.9600 .
C46 H46B 0.9600 .
C46 H46C 0.9600 .
C47 H47A 0.9600 .
C47 H47B 0.9600 .
C47 H47C 0.9600 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O8 Eu1 O3 C7 -7.6(6) . .
O19 Eu1 O3 C7 -57.1(7) . .
O2 Eu1 O3 C7 54.1(7) 2_566 .
O15 Eu1 O3 C7 -103.7(7) . .
O9 Eu1 O3 C7 124.2(7) 2_566 .
O1W Eu1 O3 C7 -179.2(6) . .
O14 Eu1 O3 C7 -157.6(7) . .
O8 Eu1 O3 C7 74.2(6) 2_566 .
C35 Eu1 O3 C7 -130.7(7) . .
C21 Eu1 O3 C7 99.5(7) 2_566 .
Eu1 Eu1 O3 C7 36.2(6) 2_566 .
N1 P1 O1 C1 41.7(6) . .
N2 P1 O1 C1 170.9(5) . .
O4 P1 O1 C1 -74.5(5) . .
O3 Eu1 O8 C21 -111.2(19) . .
O19 Eu1 O8 C21 33.8(19) . .
O2 Eu1 O8 C21 108.4(19) 2_566 .
O15 Eu1 O8 C21 -36.1(19) . .
O9 Eu1 O8 C21 -177.8(19) 2_566 .
O1W Eu1 O8 C21 59(2) . .
O14 Eu1 O8 C21 -68(2) . .
O8 Eu1 O8 C21 176(2) 2_566 .
C35 Eu1 O8 C21 -48(2) . .
C21 Eu1 O8 C21 176.4(18) 2_566 .
Eu1 Eu1 O8 C21 176(2) 2_566 .
O3 Eu1 O8 Eu1 72.85(17) . 2_566
O19 Eu1 O8 Eu1 -142.2(2) . 2_566
O2 Eu1 O8 Eu1 -67.52(17) 2_566 2_566
O15 Eu1 O8 Eu1 147.92(17) . 2_566
O9 Eu1 O8 Eu1 6.3(2) 2_566 2_566
O1W Eu1 O8 Eu1 -116.9(3) . 2_566
O14 Eu1 O8 Eu1 115.8(2) . 2_566
O8 Eu1 O8 Eu1 0.0 2_566 2_566
C35 Eu1 O8 Eu1 135.71(18) . 2_566
C21 Eu1 O8 Eu1 0.39(19) 2_566 2_566
N3 P2 O7 C15 -179.2(5) . .
N1 P2 O7 C15 -50.3(6) . .
O10 P2 O7 C15 63.8(5) . .
O3 Eu1 O15 C35 -83.5(4) . .
O8 Eu1 O15 C35 -154.3(4) . .
O19 Eu1 O15 C35 130.8(4) . .
O2 Eu1 O15 C35 124.4(4) 2_566 .
O9 Eu1 O15 C35 -13.9(5) 2_566 .
O1W Eu1 O15 C35 58.5(4) . .
O14 Eu1 O15 C35 -2.8(4) . .
O8 Eu1 O15 C35 -87.1(5) 2_566 .
C21 Eu1 O15 C35 -41.2(6) 2_566 .
Eu1 Eu1 O15 C35 -129.1(4) 2_566 .
O3 Eu1 O14 C35 87.4(4) . .
O8 Eu1 O14 C35 45.3(5) . .
O19 Eu1 O14 C35 -43.3(4) . .
O2 Eu1 O14 C35 -129.5(4) 2_566 .
O15 Eu1 O14 C35 2.8(4) . .
O9 Eu1 O14 C35 173.9(4) 2_566 .
O1W Eu1 O14 C35 -107.2(4) . .
O8 Eu1 O14 C35 143.8(4) 2_566 .
C21 Eu1 O14 C35 161.8(4) 2_566 .
Eu1 Eu1 O14 C35 105.9(4) 2_566 .
O1 P1 O4 C8 166.0(5) . .
N1 P1 O4 C8 47.9(6) . .
N2 P1 O4 C8 -83.5(6) . .
N2 P3 O13 C29 -52.3(6) . .
O16 P3 O13 C29 -163.0(5) . .
N3 P3 O13 C29 79.4(6) . .
Eu1 O9 C21 O8 -11.0(7) 2_566 .
Eu1 O9 C21 C17 165.8(5) 2_566 .
Eu1 O8 C21 O9 -166.1(15) . .
Eu1 O8 C21 O9 10.0(6) 2_566 .
Eu1 O8 C21 C17 17(2) . .
Eu1 O8 C21 C17 -166.8(5) 2_566 .
Eu1 O8 C21 Eu1 -176(2) . 2_566
O3 Eu1 O19 C45 -105.4(11) . .
O8 Eu1 O19 C45 -153.4(11) . .
O2 Eu1 O19 C45 119.0(11) 2_566 .
O15 Eu1 O19 C45 -57.1(11) . .
O9 Eu1 O19 C45 72.3(11) 2_566 .
O1W Eu1 O19 C45 40.5(11) . .
O14 Eu1 O19 C45 -20.1(11) . .
O8 Eu1 O19 C45 151.2(10) 2_566 .
C35 Eu1 O19 C45 -37.5(11) . .
C21 Eu1 O19 C45 115.1(11) 2_566 .
Eu1 Eu1 O19 C45 -178.6(11) 2_566 .
N2 P3 O16 C36 179.4(5) . .
N3 P3 O16 C36 50.5(6) . .
O13 P3 O16 C36 -65.3(6) . .
N3 P2 O10 C22 -32.4(6) . .
N1 P2 O10 C22 -162.7(5) . .
O7 P2 O10 C22 80.1(5) . .
O9 C21 C17 C16 -164.7(6) . .
O8 C21 C17 C16 12.2(9) . .
Eu1 C21 C17 C16 -98.0(19) 2_566 .
O9 C21 C17 C18 14.2(9) . .
O8 C21 C17 C18 -169.0(6) . .
Eu1 C21 C17 C18 81(2) 2_566 .
Eu1 O14 C35 O15 -5.0(7) . .
Eu1 O14 C35 C33 173.3(6) . .
Eu1 O15 C35 O14 5.3(7) . .
Eu1 O15 C35 C33 -173.1(5) . .
O3 Eu1 C35 O14 -85.4(4) . .
O8 Eu1 C35 O14 -146.4(4) . .
O19 Eu1 C35 O14 139.3(4) . .
O2 Eu1 C35 O14 87.5(5) 2_566 .
O15 Eu1 C35 O14 -175.0(7) . .
O9 Eu1 C35 O14 -6.1(4) 2_566 .
O1W Eu1 C35 O14 65.5(4) . .
O8 Eu1 C35 O14 -50.0(5) 2_566 .
C21 Eu1 C35 O14 -21.7(5) 2_566 .
Eu1 Eu1 C35 O14 -103.2(4) 2_566 .
O3 Eu1 C35 O15 89.6(4) . .
O8 Eu1 C35 O15 28.6(5) . .
O19 Eu1 C35 O15 -45.7(4) . .
O2 Eu1 C35 O15 -97.5(5) 2_566 .
O9 Eu1 C35 O15 168.9(4) 2_566 .
O1W Eu1 C35 O15 -119.5(4) . .
O14 Eu1 C35 O15 175.0(7) . .
O8 Eu1 C35 O15 125.0(4) 2_566 .
C21 Eu1 C35 O15 153.3(4) 2_566 .
Eu1 Eu1 C35 O15 71.8(5) 2_566 .
O3 Eu1 C35 C33 151(4) . .
O8 Eu1 C35 C33 90(4) . .
O19 Eu1 C35 C33 16(4) . .
O2 Eu1 C35 C33 -36(4) 2_566 .
O15 Eu1 C35 C33 62(4) . .
O9 Eu1 C35 C33 -129(4) 2_566 .
O1W Eu1 C35 C33 -58(4) . .
O14 Eu1 C35 C33 -123(4) . .
O8 Eu1 C35 C33 -173(4) 2_566 .
C21 Eu1 C35 C33 -145(4) 2_566 .
Eu1 Eu1 C35 C33 134(4) 2_566 .
Eu1 O3 C7 O2 -44.5(11) . .
Eu1 O3 C7 C3 133.0(5) . .
Eu1 O2 C7 O3 9.8(10) 2_566 .
Eu1 O2 C7 C3 -167.6(4) 2_566 .
C2 C3 C7 O3 -31.4(9) . .
C4 C3 C7 O3 150.2(6) . .
C2 C3 C7 O2 146.3(6) . .
C4 C3 C7 O2 -32.2(9) . .
N1 P2 N3 P3 13.6(6) . .
O7 P2 N3 P3 137.6(4) . .
O10 P2 N3 P3 -109.8(4) . .
N2 P3 N3 P2 -4.4(6) . .
O16 P3 N3 P2 117.9(4) . .
O13 P3 N3 P2 -132.8(4) . .
O14 C35 C33 C32 -11.3(10) . .
O15 C35 C33 C32 167.0(7) . .
Eu1 C35 C33 C32 109(4) . .
O14 C35 C33 C34 172.2(7) . .
O15 C35 C33 C34 -9.4(10) . .
Eu1 C35 C33 C34 -68(4) . .
P1 O1 C1 C2 -98.6(6) . .
P1 O1 C1 C6 86.1(7) . .
C18 C17 C16 C15 -2.5(10) . .
C21 C17 C16 C15 176.3(6) . .
C6 C1 C2 C3 -1.9(10) . .
O1 C1 C2 C3 -177.0(5) . .
C4 C3 C2 C1 0.3(9) . .
C7 C3 C2 C1 -178.2(6) . .
C2 C1 C6 C5 2.1(10) . .
O1 C1 C6 C5 177.1(6) . .
C34 C33 C32 C31 2.4(11) . .
C35 C33 C32 C31 -174.0(7) . .
C32 C33 C34 C29 -0.5(11) . .
C35 C33 C34 C29 176.0(6) . .
O2W Eu2 O18 C42 -38.0(7) . .
O18 Eu2 O18 C42 178.3(8) 2 .
O11 Eu2 O18 C42 -98.3(6) . .
O12 Eu2 O18 C42 104.6(6) 2 .
O6 Eu2 O18 C42 103.8(7) 2 .
O3W Eu2 O18 C42 -133.4(6) . .
O17 Eu2 O18 C42 5.3(6) . .
O5 Eu2 O18 C42 48.6(7) 2 .
C14 Eu2 O18 C42 70.5(7) 2 .
Eu2 Eu2 O18 C42 178.3(8) 2 .
O2W Eu2 O18 Eu2 143.6(4) . 2
O18 Eu2 O18 Eu2 0.0 2 2
O11 Eu2 O18 Eu2 83.4(4) . 2
O12 Eu2 O18 Eu2 -73.7(3) 2 2
O6 Eu2 O18 Eu2 -74.5(5) 2 2
O3W Eu2 O18 Eu2 48.3(4) . 2
O17 Eu2 O18 Eu2 -173.1(5) . 2
O5 Eu2 O18 Eu2 -129.7(3) 2 2
C14 Eu2 O18 Eu2 -107.8(4) 2 2
C42 Eu2 O18 Eu2 -178.3(8) . 2
C31 C30 C29 C34 3.2(11) . .
C31 C30 C29 O13 -179.0(7) . .
C33 C34 C29 C30 -2.4(11) . .
C33 C34 C29 O13 -180.0(6) . .
P3 O13 C29 C30 147.9(6) . .
P3 O13 C29 C34 -34.4(10) . .
O16 P3 N2 P1 -130.2(4) . .
N3 P3 N2 P1 -4.6(6) . .
O13 P3 N2 P1 123.1(4) . .
O1 P1 N2 P3 -122.3(4) . .
N1 P1 N2 P3 4.0(6) . .
O4 P1 N2 P3 131.5(4) . .
O5 C14 O6 Eu2 9.3(10) . 2
C10 C14 O6 Eu2 -169.6(7) . 2
C1 C6 C5 C4 -0.8(11) . .
O6 C14 O5 Eu2 -8.7(9) . 2
C10 C14 O5 Eu2 170.2(8) . 2
C6 C5 C4 C3 -0.8(11) . .
C2 C3 C4 C5 1.0(10) . .
C7 C3 C4 C5 179.5(6) . .
C17 C16 C15 C20 1.9(10) . .
C17 C16 C15 O7 179.1(6) . .
P2 O7 C15 C16 114.5(6) . .
P2 O7 C15 C20 -68.2(8) . .
N3 P2 N1 P1 -14.2(6) . .
O7 P2 N1 P1 -135.2(4) . .
O10 P2 N1 P1 111.6(4) . .
O1 P1 N1 P2 128.4(4) . .
N2 P1 N1 P2 5.6(5) . .
O4 P1 N1 P2 -122.3(4) . .
C16 C15 C20 C19 -0.1(11) . .
O7 C15 C20 C19 -177.3(7) . .
P2 O10 C22 C27 -61.9(9) . .
P2 O10 C22 C23 120.5(7) . .
C29 C30 C31 C32 -1.2(11) . .
C33 C32 C31 C30 -1.5(11) . .
C10 C9 C8 C13 -2.6(12) . .
C10 C9 C8 O4 175.7(7) . .
P1 O4 C8 C9 61.5(9) . .
P1 O4 C8 C13 -120.2(7) . .
Eu2 O18 C42 O17 165.5(18) 2 .
Eu2 O18 C42 O17 -9.3(10) . .
Eu2 O18 C42 C38 -15(3) 2 .
Eu2 O18 C42 C38 169.9(8) . .
Eu2 O18 C42 Eu2 175(3) 2 .
O2W Eu2 C42 O17 -43.7(7) . .
O18 Eu2 C42 O17 168.8(6) 2 .
O11 Eu2 C42 O17 -117.1(7) . .
O12 Eu2 C42 O17 100.7(6) 2 .
O6 Eu2 C42 O17 54.5(8) 2 .
O3W Eu2 C42 O17 -119.1(7) . .
O5 Eu2 C42 O17 34.0(7) 2 .
O18 Eu2 C42 O17 170.4(11) . .
C14 Eu2 C42 O17 43.9(7) 2 .
Eu2 Eu2 C42 O17 169.3(7) 2 .
O2W Eu2 C42 O18 145.9(6) . .
O18 Eu2 C42 O18 -1.6(8) 2 .
O11 Eu2 C42 O18 72.5(6) . .
O12 Eu2 C42 O18 -69.7(6) 2 .
O6 Eu2 C42 O18 -115.9(7) 2 .
O3W Eu2 C42 O18 70.5(8) . .
O17 Eu2 C42 O18 -170.4(11) . .
O5 Eu2 C42 O18 -136.4(6) 2 .
C14 Eu2 C42 O18 -126.5(6) 2 .
Eu2 Eu2 C42 O18 -1.1(5) 2 .
O2W Eu2 C42 C38 25(4) . .
O18 Eu2 C42 C38 -123(4) 2 .
O11 Eu2 C42 C38 -49(4) . .
O12 Eu2 C42 C38 169(4) 2 .
O6 Eu2 C42 C38 123(4) 2 .
O3W Eu2 C42 C38 -51(4) . .
O17 Eu2 C42 C38 68(4) . .
O5 Eu2 C42 C38 102(4) 2 .
O18 Eu2 C42 C38 -121(4) . .
C14 Eu2 C42 C38 112(4) 2 .
Eu2 Eu2 C42 C38 -122(4) 2 .
O2W Eu2 O11 C28 -145.4(11) . .
O18 Eu2 O11 C28 55.9(10) 2 .
O12 Eu2 O11 C28 11.4(12) 2 .
O6 Eu2 O11 C28 141.8(9) 2 .
O3W Eu2 O11 C28 132.9(11) . .
O17 Eu2 O11 C28 -67.9(10) . .
O5 Eu2 O11 C28 -117.8(10) 2 .
O18 Eu2 O11 C28 -19.7(10) . .
C14 Eu2 O11 C28 -177.1(9) 2 .
C42 Eu2 O11 C28 -45.8(10) . .
Eu2 Eu2 O11 C28 16.7(10) 2 .
C8 C9 C10 C11 3.8(13) . .
C8 C9 C10 C14 -176.1(7) . .
O6 C14 C10 C11 171.8(9) . .
O5 C14 C10 C11 -7.1(14) . .
Eu2 C14 C10 C11 109(4) 2 .
O6 C14 C10 C9 -8.2(13) . .
O5 C14 C10 C9 172.8(8) . .
Eu2 C14 C10 C9 -71(4) 2 .
C27 C22 C23 C24 -0.6(13) . .
O10 C22 C23 C24 177.0(7) . .
P3 O16 C36 C41 62.8(11) . .
P3 O16 C36 C37 -122.6(7) . .
Eu2 O12 C28 O11 56.6(15) 2 .
Eu2 O12 C28 C24 -120.5(8) 2 .
Eu2 O11 C28 O12 -48.2(17) . .
Eu2 O11 C28 C24 129.0(8) . .
C22 C23 C24 C25 0.9(13) . .
C22 C23 C24 C28 -178.6(8) . .
O12 C28 C24 C25 179.8(10) . .
O11 C28 C24 C25 2.3(14) . .
O12 C28 C24 C23 -0.8(14) . .
O11 C28 C24 C23 -178.3(9) . .
C9 C8 C13 C12 0.2(15) . .
O4 C8 C13 C12 -178.1(9) . .
C23 C22 C27 C26 -1.2(14) . .
O10 C22 C27 C26 -178.6(9) . .
C8 C13 C12 C11 0.9(18) . .
C13 C12 C11 C10 0.4(19) . .
C9 C10 C11 C12 -2.8(16) . .
C14 C10 C11 C12 177.2(10) . .
C16 C17 C18 C19 1.5(10) . .
C21 C17 C18 C19 -177.3(7) . .
C15 C20 C19 C18 -1.0(12) . .
C17 C18 C19 C20 0.3(12) . .
O18 C42 O17 Eu2 10.2(11) . .
C38 C42 O17 Eu2 -169.0(8) . .
O2W Eu2 O17 C42 135.0(7) . .
O18 Eu2 O17 C42 -13.0(7) 2 .
O11 Eu2 O17 C42 58.5(6) . .
O12 Eu2 O17 C42 -76.4(6) 2 .
O6 Eu2 O17 C42 -144.4(6) 2 .
O3W Eu2 O17 C42 99.2(7) . .
O5 Eu2 O17 C42 -145.0(7) 2 .
O18 Eu2 O17 C42 -5.3(6) . .
C14 Eu2 O17 C42 -142.5(6) 2 .
Eu2 Eu2 O17 C42 -9.2(6) 2 .
C41 C36 C37 C38 -3.6(14) . .
O16 C36 C37 C38 -178.1(7) . .
C36 C37 C38 C39 2.3(14) . .
C36 C37 C38 C42 178.6(8) . .
O17 C42 C38 C39 -24.1(16) . .
O18 C42 C38 C39 156.7(11) . .
Eu2 C42 C38 C39 -87(4) . .
O17 C42 C38 C37 159.6(9) . .
O18 C42 C38 C37 -19.6(14) . .
Eu2 C42 C38 C37 97(4) . .
C23 C24 C25 C26 0.6(15) . .
C28 C24 C25 C26 -180.0(10) . .
C22 C27 C26 C25 2.6(16) . .
C24 C25 C26 C27 -2.3(17) . .
Eu1 O19 C45 N4 -97.4(14) . .
C37 C38 C39 C40 -1(2) . .
C42 C38 C39 C40 -177.2(13) . .
O19 C45 N4 C43 -177.3(10) . .
O19 C45 N4 C44 1.3(16) . .
C37 C36 C41 C40 3.1(18) . .
O16 C36 C41 C40 177.4(11) . .
C38 C39 C40 C41 0(2) . .
C36 C41 C40 C39 -2(2) . .
loop_
_platon_squeeze_void_nr
_platon_squeeze_void_average_x
_platon_squeeze_void_average_y
_platon_squeeze_void_average_z
_platon_squeeze_void_volume
_platon_squeeze_void_count_electrons
1 0.500 0.500 0.000 145.3 -0.1
