#------------------------------------------------------------------------------
#$Date: 2016-02-16 03:10:39 +0200 (Tue, 16 Feb 2016) $
#$Revision: 176453 $
#$URL: svn://www.crystallography.net/cod/cif/7/21/96/7219692.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7219692
loop_
_publ_author_name
'Zhang, Lina'
'Zhang, Chao'
'Zhang, Bin'
'Du, Chenxia'
'Hou, Hongwei'
_publ_section_title
;
 Two series of pH-dependent lanthanide complexes showing solvent-induced
 single crystal to single crystal transformation, sorption and
 luminescence properties
;
_journal_issue                   14
_journal_name_full               CrystEngComm
_journal_page_first              2837
_journal_paper_doi               10.1039/C5CE00263J
_journal_volume                  17
_journal_year                    2015
_chemical_formula_moiety
'C73.5 H53 Eu2 N1.5 O22, C3 H7 N O, C3 H6 N O'
_chemical_formula_sum            'C79.5 H71.5 Eu2 N3.5 O24'
_chemical_formula_weight         1763.79
_chemical_name_systematic
;
 ? 
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_date             2014-12-13
_audit_creation_method
;
Olex2 1.2
(compiled 2012.05.09 svn.r2324, GUI svn.r4862)
;
_audit_update_record
;
2015-01-16 deposited with the CCDC.
2015-03-02 downloaded from the CCDC.
;
_cell_angle_alpha                90.00
_cell_angle_beta                 107.0296(13)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   14.13790(15)
_cell_length_b                   29.5535(3)
_cell_length_c                   18.3735(3)
_cell_measurement_reflns_used    16822
_cell_measurement_temperature    291(2)
_cell_measurement_theta_max      29.1926
_cell_measurement_theta_min      2.8890
_cell_volume                     7340.29(17)
_computing_cell_refinement
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.20 (release 27-06-2012 CrysAlis171 .NET)
(compiled Jul 11 2012,15:38:31)
;
_computing_data_collection
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.20 (release 27-06-2012 CrysAlis171 .NET)
(compiled Jul 11 2012,15:38:31)
;
_computing_data_reduction
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.20 (release 27-06-2012 CrysAlis171 .NET)
(compiled Jul 11 2012,15:38:31)
;
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement
;
XL, G.M. Sheldrick, Acta Cryst.
(2008). A64, 112-122
;
_computing_structure_solution
;
SHELXS, G.M. Sheldrick, Acta Cryst.
(2008). A64, 112-122
;
_diffrn_ambient_temperature      291.15
_diffrn_detector_area_resol_mean 16.2312
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_details
;
  1 omega  -57.00   -8.00   0.5000   10.0000
omega____ theta____ kappa____ phi______ frames
    -      -17.1323  106.0000  -38.0000 98

  2 omega  -18.00   63.00   0.5000   10.0000
omega____ theta____ kappa____ phi______ frames
    -       19.7104 -106.0000 -137.0000 162

  3 omega    2.00   27.00   0.5000   10.0000
omega____ theta____ kappa____ phi______ frames
    -      -17.1323 -106.0000 -141.0000 50

  4 omega  -86.00  -26.00   0.5000   10.0000
omega____ theta____ kappa____ phi______ frames
    -      -17.1323  -77.0000    0.0000 120

  5 omega  -49.00   40.00   0.5000   10.0000
omega____ theta____ kappa____ phi______ frames
    -       19.7104  -57.0000  -60.0000 178
;
_diffrn_measurement_device_type  'Xcalibur, Eos, Gemini'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_UB_11      0.0505035000
_diffrn_orient_matrix_UB_12      -0.0010444000
_diffrn_orient_matrix_UB_13      0.0010453000
_diffrn_orient_matrix_UB_21      0.0052824000
_diffrn_orient_matrix_UB_22      0.0233631000
_diffrn_orient_matrix_UB_23      0.0091409000
_diffrn_orient_matrix_UB_31      0.0131756000
_diffrn_orient_matrix_UB_32      -0.0054154000
_diffrn_orient_matrix_UB_33      0.0393044000
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_av_R_equivalents  0.0324
_diffrn_reflns_av_unetI/netI     0.0397
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_k_max       33
_diffrn_reflns_limit_k_min       -36
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_number            41239
_diffrn_reflns_theta_full        26.37
_diffrn_reflns_theta_max         26.37
_diffrn_reflns_theta_min         2.98
_diffrn_source                   'Enhance (Mo) X-ray Source'
_exptl_absorpt_coefficient_mu    1.777
_exptl_absorpt_correction_T_max  0.843000
_exptl_absorpt_correction_T_min  0.814206
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.20 (release 27-06-2012 CrysAlis171 .NET)
(compiled Jul 11 2012,15:38:31)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            'PALE YELLOW'
_exptl_crystal_density_diffrn    1.591
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       PRISMATIC
_exptl_crystal_F_000             3542
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.10
_refine_diff_density_max         1.059
_refine_diff_density_min         -0.671
_refine_diff_density_rms         0.088
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.040
_refine_ls_hydrogen_treatment    noref
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1015
_refine_ls_number_reflns         14949
_refine_ls_number_restraints     81
_refine_ls_restrained_S_all      1.053
_refine_ls_R_factor_all          0.0475
_refine_ls_R_factor_gt           0.0356
_refine_ls_shift/su_max          0.023
_refine_ls_shift/su_mean         0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0303P)²+10.3409P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0762
_refine_ls_wR_factor_ref         0.0810
_reflns_number_gt                12455
_reflns_number_total             14949
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c5ce00263j2.cif
_cod_data_source_block           Eu-p21c
_cod_depositor_comments
'Adding full bibliography for 7219688--7219700.cif.'
_cod_original_cell_volume        7340.32(15)
_cod_original_formula_sum        'C79.50 H71.5 Eu2 N3.50 O24'
_cod_database_code               7219692
#BEGIN Tags that were not found in dictionaries:
_chemical_oxdiff_formula         C20H20N4O4Eu
_reflns_odcompleteness_completeness 99.71
_reflns_odcompleteness_iscentric 1
_reflns_odcompleteness_theta     26.32
_olex2_submission_special_instructions 'No special instructions were received'
#END Tags that were not found in dictionaries
loop_
_space_group_symop_id
_space_group_symop_operation_xyz
1 'x, y, z'
2 '-x, y+1/2, -z+1/2'
3 '-x, -y, -z'
4 'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.813062(12) 0.243712(6) 0.677846(10) 0.02094(5) Uani 1 1 d . . .
Eu2 Eu 0.673137(12) 0.170180(6) 0.825988(11) 0.02275(5) Uani 1 1 d . . .
O1 O 0.90680(19) 0.22284(10) 0.80139(16) 0.0408(7) Uani 1 1 d . . .
O2 O 0.84613(19) 0.18144(10) 0.87827(18) 0.0434(7) Uani 1 1 d . . .
O3 O 1.0905(2) 0.24148(12) 0.83597(17) 0.0523(9) Uani 1 1 d . . .
H3 H 1.0320 0.2412 0.8108 0.078 Uiso 1 1 calc R . .
O4 O 1.48601(18) 0.22728(9) 1.00913(17) 0.0386(7) Uani 1 1 d . . .
H4 H 1.5437 0.2277 1.0360 0.058 Uiso 1 1 calc R . .
O5 O 1.6187(2) 0.30346(10) 1.20062(17) 0.0513(9) Uani 1 1 d . . .
O6 O 1.6391(2) 0.25670(11) 1.11346(18) 0.0471(8) Uani 1 1 d . . .
O7 O 0.9131(2) 0.31400(8) 0.72168(15) 0.0342(6) Uani 1 1 d . . .
O8 O 0.7997(2) 0.31709(9) 0.61096(15) 0.0367(7) Uani 1 1 d . . .
O9 O 1.0418(2) 0.37666(9) 0.76409(17) 0.0398(7) Uani 1 1 d . . .
H9 H 1.0120 0.3532 0.7667 0.060 Uiso 1 1 calc R . .
O10 O 1.2259(2) 0.53811(10) 0.7362(2) 0.0560(10) Uani 1 1 d . . .
H10 H 1.2492 0.5628 0.7307 0.084 Uiso 1 1 calc R . .
O11 O 1.2473(2) 0.62398(9) 0.74446(17) 0.0400(7) Uani 1 1 d . . .
O12 O 1.1874(2) 0.66404(8) 0.82361(17) 0.0399(7) Uani 1 1 d . . .
O13 O 0.7410(2) 0.28600(9) 0.75866(17) 0.0374(7) Uani 1 1 d . . .
O14 O 0.6730(2) 0.24890(8) 0.83616(17) 0.0383(7) Uani 1 1 d . . .
O15 O 0.7452(2) 0.37402(9) 0.7734(2) 0.0443(8) Uani 1 1 d . . .
H15 H 0.7639 0.3491 0.7636 0.066 Uiso 1 1 calc R . .
O16 O 0.5500(2) 0.53747(9) 0.78517(16) 0.0382(7) Uani 1 1 d . . .
H16 H 0.5219 0.5620 0.7823 0.057 Uiso 1 1 calc R . .
O17 O 0.4390(2) 0.60408(9) 0.72521(16) 0.0382(7) Uani 1 1 d . . .
O18 O 0.3385(2) 0.59969(9) 0.60902(16) 0.0385(7) Uani 1 1 d . . .
O19 O 0.6952(2) 0.19304(9) 0.96008(15) 0.0380(7) Uani 1 1 d . . .
H19A H 0.7036 0.2225 0.9654 0.057 Uiso 1 1 d R . .
H19B H 0.6429 0.1857 0.9744 0.057 Uiso 1 1 d R . .
O20 O 0.5092(2) 0.18675(11) 0.8417(2) 0.0540(9) Uani 1 1 d . . .
H20A H 0.4739 0.1624 0.8344 0.081 Uiso 1 1 d R . .
H20B H 0.5157 0.1966 0.8870 0.081 Uiso 1 1 d R . .
O21 O 0.9709(2) 0.23339(11) 0.6579(2) 0.0507(8) Uani 1 1 d . . .
O22 O 0.7848(2) 0.22390(10) 0.54090(17) 0.0459(8) Uani 1 1 d D . .
O23 O 0.3317(3) 0.35419(15) 0.3034(3) 0.0815(13) Uani 1 1 d . . .
O24 O 0.2875(9) 0.6351(3) 1.0033(7) 0.171(4) Uiso 0.676(10) 1 d PD A 1
O24A O 0.3697(18) 0.6530(4) 0.9688(13) 0.171(4) Uiso 0.324(10) 1 d PD A 2
N1 N 1.1328(3) 0.22846(14) 0.6661(2) 0.0470(9) Uani 1 1 d . . .
N2 N 0.2317(3) 0.41329(15) 0.3080(3) 0.0609(12) Uani 1 1 d . . .
N3 N 0.3589(5) 0.5739(3) 0.9748(4) 0.111(2) Uiso 1 1 d D A .
N4 N 0.8723(10) 0.1814(5) 0.4753(7) 0.102(4) Uani 0.50 1 d PU . .
C1 C 1.0197(3) 0.19472(13) 0.9146(2) 0.0295(8) Uani 1 1 d . . .
C2 C 1.1031(3) 0.21559(13) 0.8996(2) 0.0319(9) Uani 1 1 d . . .
C3 C 1.1975(3) 0.21048(13) 0.9481(2) 0.0266(8) Uani 1 1 d . . .
C4 C 1.2139(3) 0.18172(12) 1.0123(2) 0.0259(8) Uani 1 1 d . . .
C5 C 1.1302(3) 0.16129(13) 1.0290(2) 0.0285(8) Uani 1 1 d . . .
C6 C 1.0348(3) 0.16860(13) 0.9795(2) 0.0306(9) Uani 1 1 d . . .
H6 H 0.9806 0.1556 0.9905 0.037 Uiso 1 1 calc R . .
C7 C 1.3087(3) 0.17063(13) 1.0606(2) 0.0328(9) Uani 1 1 d . . .
H7 H 1.3642 0.1828 1.0506 0.039 Uiso 1 1 calc R . .
C8 C 1.3208(3) 0.14234(15) 1.1217(2) 0.0432(11) Uani 1 1 d . . .
H8 H 1.3843 0.1355 1.1521 0.052 Uiso 1 1 calc R . .
C9 C 1.2392(3) 0.12362(16) 1.1388(3) 0.0470(11) Uani 1 1 d . . .
H9A H 1.2482 0.1050 1.1811 0.056 Uiso 1 1 calc R . .
C10 C 1.1464(3) 0.13282(15) 1.0931(2) 0.0411(10) Uani 1 1 d . . .
H10A H 1.0923 0.1200 1.1045 0.049 Uiso 1 1 calc R . .
C11 C 1.2843(3) 0.23382(13) 0.9290(2) 0.0294(8) Uani 1 1 d . . .
H11A H 1.3313 0.2109 0.9244 0.035 Uiso 1 1 calc R . .
H11B H 1.2596 0.2486 0.8799 0.035 Uiso 1 1 calc R . .
C12 C 1.3381(3) 0.26871(12) 0.9873(2) 0.0257(8) Uani 1 1 d . . .
C13 C 1.4362(3) 0.26278(12) 1.0280(2) 0.0261(8) Uani 1 1 d . . .
C14 C 1.4836(3) 0.29213(13) 1.0904(2) 0.0287(8) Uani 1 1 d . . .
C15 C 1.4346(3) 0.32943(13) 1.1035(2) 0.0362(9) Uani 1 1 d . . .
H15A H 1.4644 0.3480 1.1447 0.043 Uiso 1 1 calc R . .
C16 C 1.3399(3) 0.34047(14) 1.0562(3) 0.0365(9) Uani 1 1 d . . .
C17 C 1.2900(3) 0.30973(13) 0.9987(2) 0.0322(9) Uani 1 1 d . . .
C18 C 1.1953(3) 0.32194(15) 0.9503(3) 0.0434(11) Uani 1 1 d U . .
H18 H 1.1599 0.3017 0.9137 0.052 Uiso 1 1 calc R . .
C19 C 1.1559(4) 0.36333(18) 0.9575(3) 0.0598(14) Uani 1 1 d U . .
H19 H 1.0948 0.3713 0.9244 0.072 Uiso 1 1 calc R . .
C20 C 1.2050(4) 0.39342(19) 1.0126(3) 0.0637(15) Uani 1 1 d U . .
H20 H 1.1766 0.4214 1.0162 0.076 Uiso 1 1 calc R . .
C21 C 1.2952(4) 0.38285(17) 1.0623(3) 0.0559(13) Uani 1 1 d U . .
H21 H 1.3271 0.4033 1.0999 0.067 Uiso 1 1 calc R . .
C22 C 0.9170(3) 0.19970(13) 0.8616(2) 0.0335(9) Uani 1 1 d . . .
C23 C 1.5863(3) 0.28330(14) 1.1384(2) 0.0346(9) Uani 1 1 d . . .
C24 C 0.9059(3) 0.38142(12) 0.6486(2) 0.0267(8) Uani 1 1 d . . .
C25 C 0.9907(3) 0.40060(12) 0.7021(2) 0.0284(8) Uani 1 1 d . . .
C26 C 1.0240(3) 0.44356(12) 0.6914(2) 0.0294(8) Uani 1 1 d . . .
C27 C 0.9711(3) 0.46886(12) 0.6262(2) 0.0332(9) Uani 1 1 d . . .
C28 C 0.8870(3) 0.44953(13) 0.5727(2) 0.0336(9) Uani 1 1 d . . .
C29 C 0.8569(3) 0.40561(13) 0.5854(2) 0.0342(9) Uani 1 1 d . . .
H29 H 0.8025 0.3928 0.5500 0.041 Uiso 1 1 calc R . .
C30 C 0.9981(3) 0.51332(13) 0.6101(3) 0.0402(10) Uani 1 1 d . . .
H30 H 1.0540 0.5267 0.6429 0.048 Uiso 1 1 calc R . .
C31 C 0.9445(4) 0.53657(15) 0.5484(3) 0.0502(12) Uani 1 1 d . . .
H31 H 0.9631 0.5659 0.5403 0.060 Uiso 1 1 calc R . .
C32 C 0.8614(4) 0.51722(16) 0.4964(3) 0.0528(13) Uani 1 1 d . . .
H32 H 0.8243 0.5338 0.4549 0.063 Uiso 1 1 calc R . .
C33 C 0.8354(3) 0.47407(15) 0.5070(3) 0.0460(11) Uani 1 1 d . . .
H33 H 0.7830 0.4605 0.4707 0.055 Uiso 1 1 calc R . .
C34 C 1.1183(3) 0.46133(12) 0.7476(2) 0.0331(9) Uani 1 1 d . B .
H34A H 1.1435 0.4383 0.7859 0.040 Uiso 1 1 calc R . .
H34B H 1.1672 0.4656 0.7206 0.040 Uiso 1 1 calc R . .
C35 C 1.1091(3) 0.50519(12) 0.7877(2) 0.0302(8) Uani 1 1 d . . .
C36 C 1.1625(3) 0.54292(13) 0.7783(2) 0.0325(9) Uani 1 1 d . B .
C37 C 1.1479(3) 0.58573(12) 0.8088(2) 0.0286(8) Uani 1 1 d . . .
C38 C 1.0715(17) 0.5897(10) 0.8408(11) 0.029(3) Uani 0.512(6) 1 d P B 1
H38 H 1.0553 0.6184 0.8543 0.035 Uiso 0.512(6) 1 calc PR B 1
C38A C 1.0958(18) 0.5883(10) 0.8615(13) 0.029(3) Uani 0.488(6) 1 d P B 2
H38A H 1.0937 0.6153 0.8871 0.035 Uiso 0.488(6) 1 calc PR B 2
C39 C 1.0164(8) 0.5521(5) 0.8541(6) 0.0326(19) Uani 0.512(6) 1 d PU B 1
C39A C 1.0469(8) 0.5505(5) 0.8760(7) 0.0326(19) Uani 0.488(6) 1 d P B 2
C40 C 1.0343(16) 0.5092(10) 0.8263(14) 0.027(3) Uani 0.512(6) 1 d PU B 1
C40A C 1.0549(17) 0.5080(11) 0.8403(14) 0.027(3) Uani 0.488(6) 1 d PU B 2
C41 C 0.9782(10) 0.4717(7) 0.8398(9) 0.034(2) Uani 0.512(6) 1 d PU B 1
H41 H 0.9916 0.4429 0.8250 0.041 Uiso 0.512(6) 1 calc PR B 1
C41A C 1.0032(11) 0.4700(7) 0.8563(10) 0.034(2) Uani 0.488(6) 1 d P B 2
H41A H 1.0072 0.4424 0.8331 0.041 Uiso 0.488(6) 1 calc PR B 2
C42 C 0.9059(8) 0.4772(4) 0.8736(6) 0.0462(18) Uani 0.512(6) 1 d PU B 1
H42 H 0.8697 0.4523 0.8812 0.055 Uiso 0.512(6) 1 calc PR B 1
C42A C 0.9475(8) 0.4735(4) 0.9055(6) 0.0462(18) Uani 0.488(6) 1 d PU B 2
H42A H 0.9127 0.4484 0.9145 0.055 Uiso 0.488(6) 1 calc PR B 2
C43 C 0.8853(8) 0.5200(3) 0.8972(6) 0.0535(18) Uani 0.512(6) 1 d PU B 1
H43 H 0.8337 0.5236 0.9186 0.064 Uiso 0.512(6) 1 calc PR B 1
C43A C 0.9423(8) 0.5143(4) 0.9425(7) 0.0535(18) Uani 0.488(6) 1 d PU B 2
H43A H 0.9063 0.5159 0.9774 0.064 Uiso 0.488(6) 1 calc PR B 2
C44 C 0.9395(8) 0.5561(3) 0.8894(6) 0.0486(18) Uani 0.512(6) 1 d PU B 1
H44 H 0.9265 0.5841 0.9073 0.058 Uiso 0.512(6) 1 calc PR B 1
C44A C 0.9899(8) 0.5519(4) 0.9276(6) 0.0486(18) Uani 0.488(6) 1 d PU B 2
H44A H 0.9846 0.5790 0.9519 0.058 Uiso 0.488(6) 1 calc PR B 2
C45 C 0.8706(3) 0.33553(12) 0.6606(2) 0.0282(8) Uani 1 1 d . . .
C46 C 1.1978(3) 0.62774(12) 0.7916(2) 0.0305(9) Uani 1 1 d . B .
C47 C 0.6303(3) 0.32545(12) 0.8108(2) 0.0297(8) Uani 1 1 d . . .
C48 C 0.6601(3) 0.36928(12) 0.7938(2) 0.0315(9) Uani 1 1 d . . .
C49 C 0.6052(3) 0.40739(12) 0.7975(2) 0.0295(8) Uani 1 1 d . . .
C50 C 0.5179(3) 0.40251(13) 0.8204(2) 0.0346(9) Uani 1 1 d . . .
C51 C 0.4867(3) 0.35855(14) 0.8366(2) 0.0372(10) Uani 1 1 d . . .
C52 C 0.5454(3) 0.32113(14) 0.8320(2) 0.0370(10) Uani 1 1 d . . .
H52 H 0.5263 0.2926 0.8436 0.044 Uiso 1 1 calc R . .
C53 C 0.3986(4) 0.35427(16) 0.8580(3) 0.0552(14) Uani 1 1 d . . .
H53 H 0.3785 0.3257 0.8689 0.066 Uiso 1 1 calc R . .
C54 C 0.3429(4) 0.39078(18) 0.8629(3) 0.0626(15) Uani 1 1 d . . .
H54 H 0.2843 0.3872 0.8755 0.075 Uiso 1 1 calc R . .
C55 C 0.3741(4) 0.43378(17) 0.8487(3) 0.0530(13) Uani 1 1 d . . .
H55 H 0.3367 0.4589 0.8534 0.064 Uiso 1 1 calc R . .
C56 C 0.4582(3) 0.43967(15) 0.8281(3) 0.0411(10) Uani 1 1 d . . .
H56 H 0.4770 0.4688 0.8188 0.049 Uiso 1 1 calc R . .
C57 C 0.6370(3) 0.45319(12) 0.7754(2) 0.0333(9) Uani 1 1 d . . .
H57A H 0.6992 0.4496 0.7637 0.040 Uiso 1 1 calc R . .
H57B H 0.6487 0.4733 0.8188 0.040 Uiso 1 1 calc R . .
C58 C 0.5625(3) 0.47521(12) 0.7077(2) 0.0291(8) Uani 1 1 d . . .
C59 C 0.5211(3) 0.51652(12) 0.7157(2) 0.0291(8) Uani 1 1 d . . .
C60 C 0.4480(3) 0.53725(12) 0.6542(2) 0.0307(9) Uani 1 1 d . . .
C61 C 0.4175(3) 0.51493(14) 0.5861(2) 0.0374(10) Uani 1 1 d . . .
H61 H 0.3697 0.5282 0.5459 0.045 Uiso 1 1 calc R . .
C62 C 0.4562(3) 0.47243(13) 0.5749(2) 0.0363(9) Uani 1 1 d . . .
C63 C 0.5325(3) 0.45341(12) 0.6356(2) 0.0335(9) Uani 1 1 d . . .
C64 C 0.5778(3) 0.41293(13) 0.6197(3) 0.0416(10) Uani 1 1 d . . .
H64 H 0.6314 0.4007 0.6566 0.050 Uiso 1 1 calc R . .
C65 C 0.5434(4) 0.39204(15) 0.5508(3) 0.0519(13) Uani 1 1 d . . .
H65 H 0.5739 0.3656 0.5419 0.062 Uiso 1 1 calc R . .
C66 C 0.4636(4) 0.40926(16) 0.4934(3) 0.0572(14) Uani 1 1 d . . .
H66 H 0.4386 0.3934 0.4481 0.069 Uiso 1 1 calc R . .
C67 C 0.4225(4) 0.44940(16) 0.5042(3) 0.0513(12) Uani 1 1 d . . .
H67 H 0.3719 0.4618 0.4650 0.062 Uiso 1 1 calc R . .
C68 C 0.6854(3) 0.28386(12) 0.8014(2) 0.0287(8) Uani 1 1 d . . .
C69 C 0.4055(3) 0.58238(12) 0.6627(2) 0.0314(9) Uani 1 1 d . . .
C70 C 1.0544(3) 0.25001(16) 0.6701(3) 0.0468(11) Uani 1 1 d . . .
H70 H 1.0617 0.2805 0.6833 0.056 Uiso 1 1 calc R . .
C71 C 1.2297(4) 0.2494(2) 0.6848(4) 0.0762(18) Uani 1 1 d . . .
H71A H 1.2244 0.2807 0.6965 0.114 Uiso 1 1 calc R . .
H71B H 1.2556 0.2468 0.6421 0.114 Uiso 1 1 calc R . .
H71C H 1.2734 0.2344 0.7280 0.114 Uiso 1 1 calc R . .
C72 C 1.1258(5) 0.1812(2) 0.6452(5) 0.103(3) Uani 1 1 d . . .
H72A H 1.0597 0.1707 0.6390 0.155 Uiso 1 1 calc R . .
H72B H 1.1715 0.1640 0.6844 0.155 Uiso 1 1 calc R . .
H72C H 1.1417 0.1776 0.5981 0.155 Uiso 1 1 calc R . .
C73 C 0.8095(13) 0.1894(4) 0.5168(9) 0.107(5) Uani 0.50 1 d PDU . .
C74 C 0.8826(11) 0.1376(5) 0.4454(9) 0.101(5) Uani 0.50 1 d PU . .
C75 C 0.9280(10) 0.2141(5) 0.4640(8) 0.081(4) Uani 0.50 1 d PU . .
C76 C 0.3081(4) 0.3940(2) 0.2932(3) 0.0671(16) Uani 1 1 d . . .
H76 H 0.3477 0.4124 0.2732 0.080 Uiso 1 1 calc R . .
C77 C 0.1670(6) 0.3879(3) 0.3389(5) 0.120(3) Uani 1 1 d U . .
H77A H 0.1808 0.3562 0.3366 0.179 Uiso 1 1 calc R . .
H77B H 0.0997 0.3938 0.3100 0.179 Uiso 1 1 calc R . .
H77C H 0.1768 0.3966 0.3909 0.179 Uiso 1 1 calc R . .
C78 C 0.2103(5) 0.4611(2) 0.2990(5) 0.102(2) Uani 1 1 d . . .
H78A H 0.2530 0.4773 0.3413 0.153 Uiso 1 1 calc R . .
H78B H 0.1426 0.4663 0.2971 0.153 Uiso 1 1 calc R . .
H78C H 0.2211 0.4715 0.2526 0.153 Uiso 1 1 calc R . .
C79 C 0.3536(12) 0.6174(4) 0.9875(9) 0.212(6) Uiso 1 1 d D . .
C80 C 0.4296(8) 0.5671(4) 0.9361(7) 0.185(5) Uiso 1 1 d D . .
H80A H 0.3968 0.5600 0.8837 0.278 Uiso 1 1 calc R A .
H80B H 0.4721 0.5424 0.9591 0.278 Uiso 1 1 calc R . .
H80C H 0.4682 0.5940 0.9388 0.278 Uiso 1 1 calc R . .
C81 C 0.3024(7) 0.5408(3) 0.9988(5) 0.136(3) Uiso 1 1 d D . .
H81A H 0.2647 0.5550 1.0283 0.204 Uiso 1 1 calc R A .
H81B H 0.3458 0.5186 1.0293 0.204 Uiso 1 1 calc R . .
H81C H 0.2583 0.5265 0.9550 0.204 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O1 Eu1 Eu2 59.97(7) . .
O1 Eu1 O6 133.00(10) . 4_465
O1 Eu1 O7 78.58(9) . .
O1 Eu1 O8 130.51(9) . .
O1 Eu1 O12 75.38(10) . 2_746
O1 Eu1 O13 76.07(10) . .
O1 Eu1 O21 80.00(11) . .
O1 Eu1 O22 142.12(10) . .
O1 Eu1 C23 113.61(10) . 4_465
O1 Eu1 C45 104.85(11) . .
O6 Eu1 Eu2 73.70(8) 4_465 .
O6 Eu1 O7 124.27(10) 4_465 .
O6 Eu1 O8 80.85(10) 4_465 .
O6 Eu1 O22 70.35(11) 4_465 .
O6 Eu1 C23 20.67(10) 4_465 4_465
O6 Eu1 C45 103.47(11) 4_465 .
O7 Eu1 Eu2 121.72(6) . .
O7 Eu1 C23 135.89(9) . 4_465
O7 Eu1 C45 26.31(10) . .
O8 Eu1 Eu2 139.56(7) . .
O8 Eu1 O7 52.22(8) . .
O8 Eu1 O22 74.85(9) . .
O8 Eu1 C23 100.48(10) . 4_465
O8 Eu1 C45 25.95(10) . .
O12 Eu1 Eu2 60.71(7) 2_746 .
O12 Eu1 O6 89.44(11) 2_746 4_465
O12 Eu1 O7 146.19(10) 2_746 .
O12 Eu1 O8 150.68(9) 2_746 .
O12 Eu1 O13 122.04(10) 2_746 .
O12 Eu1 O21 82.53(11) 2_746 .
O12 Eu1 O22 75.83(10) 2_746 .
O12 Eu1 C23 75.32(10) 2_746 4_465
O12 Eu1 C45 160.36(10) 2_746 .
O13 Eu1 Eu2 61.33(6) . .
O13 Eu1 O6 75.29(10) . 4_465
O13 Eu1 O7 70.74(9) . .
O13 Eu1 O8 82.27(9) . .
O13 Eu1 O22 141.08(10) . .
O13 Eu1 C23 71.75(10) . 4_465
O13 Eu1 C45 76.17(10) . .
O21 Eu1 Eu2 130.17(8) . .
O21 Eu1 O6 142.64(11) . 4_465
O21 Eu1 O7 71.95(10) . .
O21 Eu1 O8 88.55(11) . .
O21 Eu1 O13 138.78(11) . .
O21 Eu1 O22 72.31(11) . .
O21 Eu1 C23 149.39(11) . 4_465
O21 Eu1 C45 78.23(11) . .
O22 Eu1 Eu2 122.77(7) . .
O22 Eu1 O7 115.21(10) . .
O22 Eu1 C23 81.86(11) . 4_465
O22 Eu1 C45 94.41(10) . .
C23 Eu1 Eu2 53.68(8) 4_465 .
C45 Eu1 Eu2 136.89(7) . .
C45 Eu1 C23 120.75(10) . 4_465
O2 Eu2 Eu1 65.35(7) . .
O2 Eu2 O11 72.86(11) . 2_746
O2 Eu2 O17 136.13(10) . 2_646
O2 Eu2 O18 97.54(10) . 2_646
O2 Eu2 O19 75.27(10) . .
O2 Eu2 O20 144.73(11) . .
O2 Eu2 C69 118.35(11) . 2_646
O5 Eu2 Eu1 45.64(9) 4_465 .
O5 Eu2 O2 110.76(11) 4_465 .
O5 Eu2 O11 74.14(10) 4_465 2_746
O5 Eu2 O17 84.31(10) 4_465 2_646
O5 Eu2 O18 136.01(10) 4_465 2_646
O5 Eu2 O19 142.74(10) 4_465 .
O5 Eu2 O20 90.00(12) 4_465 .
O5 Eu2 C69 110.61(12) 4_465 2_646
O11 Eu2 Eu1 64.85(7) 2_746 .
O11 Eu2 O17 72.40(10) 2_746 2_646
O11 Eu2 O18 83.47(10) 2_746 2_646
O11 Eu2 O19 138.91(10) 2_746 .
O11 Eu2 O20 141.98(11) 2_746 .
O11 Eu2 C69 76.96(10) 2_746 2_646
O14 Eu2 Eu1 64.31(7) . .
O14 Eu2 O2 81.53(10) . .
O14 Eu2 O5 74.88(10) . 4_465
O14 Eu2 O11 128.85(10) . 2_746
O14 Eu2 O17 142.01(10) . 2_646
O14 Eu2 O18 144.41(10) . 2_646
O14 Eu2 O19 69.66(9) . .
O14 Eu2 O20 76.71(10) . .
O14 Eu2 C69 152.97(10) . 2_646
O17 Eu2 Eu1 120.13(7) 2_646 .
O17 Eu2 C69 26.63(10) 2_646 2_646
O18 Eu2 Eu1 146.94(7) 2_646 .
O18 Eu2 O17 52.62(9) 2_646 2_646
O18 Eu2 O19 75.68(9) 2_646 .
O18 Eu2 O20 84.92(10) 2_646 .
O18 Eu2 C69 25.99(10) 2_646 2_646
O19 Eu2 Eu1 122.20(6) . .
O19 Eu2 O17 117.63(9) . 2_646
O19 Eu2 C69 96.49(10) . 2_646
O20 Eu2 Eu1 125.79(8) . .
O20 Eu2 O17 71.79(10) . 2_646
O20 Eu2 O19 71.29(11) . .
O20 Eu2 C69 76.85(11) . 2_646
C69 Eu2 Eu1 138.82(8) 2_646 .
C22 O1 Eu1 150.3(2) . .
C22 O2 Eu2 139.9(3) . .
C2 O3 H3 109.5 . .
C13 O4 H4 109.5 . .
C23 O5 Eu2 170.3(3) . 4_666
C23 O6 Eu1 117.1(2) . 4_666
C45 O7 Eu1 93.1(2) . .
C45 O8 Eu1 95.2(2) . .
C25 O9 H9 109.5 . .
C36 O10 H10 109.5 . .
C46 O11 Eu2 139.9(2) . 2_756
C46 O12 Eu1 148.3(3) . 2_756
C68 O13 Eu1 144.8(2) . .
C68 O14 Eu2 141.0(3) . .
C48 O15 H15 109.5 . .
C59 O16 H16 109.5 . .
C69 O17 Eu2 91.5(2) . 2_656
C69 O18 Eu2 96.2(2) . 2_656
Eu2 O19 H19A 110.6 . .
Eu2 O19 H19B 110.9 . .
H19A O19 H19B 108.0 . .
Eu2 O20 H20A 109.6 . .
Eu2 O20 H20B 110.0 . .
H20A O20 H20B 108.9 . .
C70 O21 Eu1 143.9(3) . .
C73 O22 Eu1 126.2(8) . .
C70 N1 C71 122.7(5) . .
C70 N1 C72 119.8(4) . .
C72 N1 C71 117.4(5) . .
C76 N2 C77 121.1(5) . .
C76 N2 C78 123.8(5) . .
C77 N2 C78 115.1(5) . .
C79 N3 C80 108.5(11) . .
C79 N3 C81 123.8(11) . .
C80 N3 C81 127.7(8) . .
C73 N4 C74 122.2(14) . .
C75 N4 C73 119.3(14) . .
C75 N4 C74 118.4(14) . .
C2 C1 C22 121.9(3) . .
C6 C1 C2 118.7(3) . .
C6 C1 C22 119.3(3) . .
O3 C2 C1 120.0(3) . .
O3 C2 C3 118.3(3) . .
C3 C2 C1 121.7(3) . .
C2 C3 C4 119.6(3) . .
C2 C3 C11 119.4(3) . .
C4 C3 C11 120.9(3) . .
C3 C4 C5 119.1(3) . .
C7 C4 C3 123.8(3) . .
C7 C4 C5 117.2(3) . .
C6 C5 C4 119.3(3) . .
C6 C5 C10 121.5(3) . .
C10 C5 C4 119.1(3) . .
C1 C6 C5 121.3(3) . .
C1 C6 H6 119.3 . .
C5 C6 H6 119.3 . .
C4 C7 H7 119.2 . .
C8 C7 C4 121.7(4) . .
C8 C7 H7 119.2 . .
C7 C8 H8 119.6 . .
C7 C8 C9 120.9(4) . .
C9 C8 H8 119.6 . .
C8 C9 H9A 120.2 . .
C10 C9 C8 119.5(4) . .
C10 C9 H9A 120.2 . .
C5 C10 H10A 119.2 . .
C9 C10 C5 121.7(4) . .
C9 C10 H10A 119.2 . .
C3 C11 H11A 108.7 . .
C3 C11 H11B 108.7 . .
H11A C11 H11B 107.6 . .
C12 C11 C3 114.3(3) . .
C12 C11 H11A 108.7 . .
C12 C11 H11B 108.7 . .
C13 C12 C11 120.7(3) . .
C13 C12 C17 118.2(3) . .
C17 C12 C11 121.0(3) . .
O4 C13 C12 118.2(3) . .
O4 C13 C14 120.8(3) . .
C12 C13 C14 121.0(3) . .
C13 C14 C23 120.9(3) . .
C15 C14 C13 119.2(3) . .
C15 C14 C23 119.8(4) . .
C14 C15 H15A 119.3 . .
C14 C15 C16 121.4(4) . .
C16 C15 H15A 119.3 . .
C15 C16 C17 119.3(4) . .
C15 C16 C21 121.4(4) . .
C17 C16 C21 119.2(4) . .
C16 C17 C12 119.8(3) . .
C16 C17 C18 118.5(4) . .
C18 C17 C12 121.6(4) . .
C17 C18 H18 119.9 . .
C19 C18 C17 120.2(5) . .
C19 C18 H18 119.9 . .
C18 C19 H19 119.4 . .
C18 C19 C20 121.3(5) . .
C20 C19 H19 119.4 . .
C19 C20 H20 119.5 . .
C21 C20 C19 121.0(5) . .
C21 C20 H20 119.5 . .
C16 C21 H21 120.1 . .
C20 C21 C16 119.8(5) . .
C20 C21 H21 120.1 . .
O1 C22 C1 117.3(3) . .
O2 C22 O1 123.3(4) . .
O2 C22 C1 119.4(4) . .
O5 C23 Eu1 80.6(3) . 4_666
O5 C23 O6 122.2(4) . .
O5 C23 C14 119.5(4) . .
O6 C23 C14 118.3(4) . .
C14 C23 Eu1 157.9(3) . 4_666
C25 C24 C45 120.9(3) . .
C29 C24 C25 119.5(3) . .
C29 C24 C45 119.6(3) . .
O9 C25 C24 120.3(3) . .
O9 C25 C26 118.5(3) . .
C26 C25 C24 121.1(4) . .
C25 C26 C27 118.9(4) . .
C25 C26 C34 119.0(4) . .
C27 C26 C34 122.0(3) . .
C28 C27 C26 119.8(3) . .
C28 C27 C30 116.7(4) . .
C30 C27 C26 123.5(4) . .
C29 C28 C27 119.3(4) . .
C29 C28 C33 120.6(4) . .
C33 C28 C27 120.1(4) . .
C24 C29 C28 121.4(4) . .
C24 C29 H29 119.3 . .
C28 C29 H29 119.3 . .
C27 C30 H30 119.2 . .
C31 C30 C27 121.6(4) . .
C31 C30 H30 119.2 . .
C30 C31 H31 119.4 . .
C30 C31 C32 121.1(4) . .
C32 C31 H31 119.4 . .
C31 C32 H32 120.2 . .
C33 C32 C31 119.6(5) . .
C33 C32 H32 120.2 . .
C28 C33 H33 119.6 . .
C32 C33 C28 120.7(5) . .
C32 C33 H33 119.6 . .
C26 C34 H34A 108.2 . .
C26 C34 H34B 108.2 . .
H34A C34 H34B 107.4 . .
C35 C34 C26 116.3(3) . .
C35 C34 H34A 108.2 . .
C35 C34 H34B 108.2 . .
C36 C35 C34 120.0(3) . .
C36 C35 C40 120.1(12) . .
C36 C35 C40A 117.8(13) . .
C40 C35 C34 119.3(12) . .
C40A C35 C34 122.0(13) . .
O10 C36 C35 117.6(3) . .
O10 C36 C37 121.0(3) . .
C35 C36 C37 121.3(4) . .
C36 C37 C46 121.3(3) . .
C38 C37 C36 117.8(12) . .
C38 C37 C46 119.6(12) . .
C38A C37 C36 119.6(13) . .
C38A C37 C46 118.7(13) . .
C37 C38 H38 118.5 . .
C37 C38 C39 123(2) . .
C39 C38 H38 118.5 . .
C37 C38A H38A 120.3 . .
C37 C38A C39A 119(2) . .
C39A C38A H38A 120.3 . .
C38 C39 C44 123.0(16) . .
C40 C39 C38 118.3(19) . .
C40 C39 C44 118.5(15) . .
C38A C39A C40A 121(2) . .
C38A C39A C44A 121.3(17) . .
C44A C39A C40A 118.1(16) . .
C39 C40 C35 119(2) . .
C39 C40 C41 118(2) . .
C41 C40 C35 123(2) . .
C35 C40A C39A 120(2) . .
C35 C40A C41A 121(2) . .
C41A C40A C39A 119(2) . .
C40 C41 H41 119.3 . .
C42 C41 C40 121.4(19) . .
C42 C41 H41 119.3 . .
C40A C41A H41A 119.6 . .
C42A C41A C40A 121(2) . .
C42A C41A H41A 119.6 . .
C41 C42 H42 119.8 . .
C41 C42 C43 120.4(12) . .
C43 C42 H42 119.8 . .
C41A C42A H42A 119.7 . .
C41A C42A C43A 120.7(12) . .
C43A C42A H42A 119.7 . .
C42 C43 H43 119.7 . .
C44 C43 C42 120.6(9) . .
C44 C43 H43 119.7 . .
C42A C43A H43A 119.8 . .
C44A C43A C42A 120.4(9) . .
C44A C43A H43A 119.8 . .
C39 C44 H44 119.4 . .
C43 C44 C39 121.2(10) . .
C43 C44 H44 119.4 . .
C39A C44A H44A 119.4 . .
C43A C44A C39A 121.3(11) . .
C43A C44A H44A 119.4 . .
O7 C45 Eu1 60.57(18) . .
O7 C45 C24 119.6(3) . .
O8 C45 Eu1 58.84(18) . .
O8 C45 O7 119.2(3) . .
O8 C45 C24 121.2(3) . .
C24 C45 Eu1 175.4(3) . .
O11 C46 C37 117.2(3) . .
O12 C46 O11 124.1(4) . .
O12 C46 C37 118.7(4) . .
C48 C47 C68 121.7(3) . .
C52 C47 C48 119.1(3) . .
C52 C47 C68 119.1(3) . .
O15 C48 C47 119.6(3) . .
O15 C48 C49 118.8(3) . .
C49 C48 C47 121.6(3) . .
C48 C49 C50 118.7(3) . .
C48 C49 C57 120.0(3) . .
C50 C49 C57 121.3(3) . .
C49 C50 C51 120.0(3) . .
C56 C50 C49 123.0(4) . .
C56 C50 C51 117.0(4) . .
C52 C51 C50 118.7(4) . .
C52 C51 C53 122.1(4) . .
C53 C51 C50 119.3(4) . .
C47 C52 C51 121.8(4) . .
C47 C52 H52 119.1 . .
C51 C52 H52 119.1 . .
C51 C53 H53 119.3 . .
C54 C53 C51 121.5(4) . .
C54 C53 H53 119.3 . .
C53 C54 H54 120.2 . .
C53 C54 C55 119.5(4) . .
C55 C54 H54 120.2 . .
C54 C55 H55 119.4 . .
C56 C55 C54 121.2(4) . .
C56 C55 H55 119.4 . .
C50 C56 H56 119.2 . .
C55 C56 C50 121.5(4) . .
C55 C56 H56 119.2 . .
C49 C57 H57A 108.7 . .
C49 C57 H57B 108.7 . .
C49 C57 C58 114.3(3) . .
H57A C57 H57B 107.6 . .
C58 C57 H57A 108.7 . .
C58 C57 H57B 108.7 . .
C59 C58 C57 120.3(4) . .
C59 C58 C63 118.7(4) . .
C63 C58 C57 121.0(3) . .
O16 C59 C58 118.7(3) . .
O16 C59 C60 119.6(3) . .
C58 C59 C60 121.8(4) . .
C59 C60 C69 121.5(4) . .
C61 C60 C59 118.6(3) . .
C61 C60 C69 119.9(4) . .
C60 C61 H61 118.9 . .
C60 C61 C62 122.1(4) . .
C62 C61 H61 118.9 . .
C61 C62 C63 118.4(4) . .
C61 C62 C67 121.4(4) . .
C67 C62 C63 120.2(4) . .
C58 C63 C64 122.8(4) . .
C62 C63 C58 120.1(3) . .
C62 C63 C64 117.0(4) . .
C63 C64 H64 119.7 . .
C65 C64 C63 120.7(4) . .
C65 C64 H64 119.7 . .
C64 C65 H65 119.1 . .
C64 C65 C66 121.7(4) . .
C66 C65 H65 119.1 . .
C65 C66 H66 120.2 . .
C67 C66 C65 119.5(5) . .
C67 C66 H66 120.2 . .
C62 C67 H67 119.7 . .
C66 C67 C62 120.5(5) . .
C66 C67 H67 119.7 . .
O13 C68 C47 118.1(3) . .
O14 C68 O13 124.2(3) . .
O14 C68 C47 117.7(3) . .
O17 C69 Eu2 61.85(19) . 2_656
O17 C69 C60 119.2(3) . .
O18 C69 Eu2 57.84(19) . 2_656
O18 C69 O17 119.7(3) . .
O18 C69 C60 121.1(4) . .
C60 C69 Eu2 177.7(3) . 2_656
O21 C70 N1 125.4(5) . .
O21 C70 H70 117.3 . .
N1 C70 H70 117.3 . .
N1 C71 H71A 109.5 . .
N1 C71 H71B 109.5 . .
N1 C71 H71C 109.5 . .
H71A C71 H71B 109.5 . .
H71A C71 H71C 109.5 . .
H71B C71 H71C 109.5 . .
N1 C72 H72A 109.5 . .
N1 C72 H72B 109.5 . .
N1 C72 H72C 109.5 . .
H72A C72 H72B 109.5 . .
H72A C72 H72C 109.5 . .
H72B C72 H72C 109.5 . .
O22 C73 N4 131.7(17) . .
O23 C76 N2 126.0(5) . .
O23 C76 H76 117.0 . .
N2 C76 H76 117.0 . .
N2 C77 H77A 109.5 . .
N2 C77 H77B 109.5 . .
N2 C77 H77C 109.5 . .
H77A C77 H77B 109.5 . .
H77A C77 H77C 109.5 . .
H77B C77 H77C 109.5 . .
N2 C78 H78A 109.5 . .
N2 C78 H78B 109.5 . .
N2 C78 H78C 109.5 . .
H78A C78 H78B 109.5 . .
H78A C78 H78C 109.5 . .
H78B C78 H78C 109.5 . .
O24 C79 N3 124.6(14) . .
O24A C79 O24 84.9(14) . .
O24A C79 N3 144.7(16) . .
N3 C80 H80A 109.5 . .
N3 C80 H80B 109.5 . .
N3 C80 H80C 109.4 . .
H80A C80 H80B 109.5 . .
H80A C80 H80C 109.5 . .
H80B C80 H80C 109.5 . .
N3 C81 H81A 109.5 . .
N3 C81 H81B 109.5 . .
N3 C81 H81C 109.5 . .
H81A C81 H81B 109.5 . .
H81A C81 H81C 109.5 . .
H81B C81 H81C 109.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Eu1 Eu2 4.3816(3) .
Eu1 O1 2.351(3) .
Eu1 O6 2.397(3) 4_465
Eu1 O7 2.510(2) .
Eu1 O8 2.472(3) .
Eu1 O12 2.355(3) 2_746
Eu1 O13 2.386(3) .
Eu1 O21 2.384(3) .
Eu1 O22 2.499(3) .
Eu1 C23 3.174(4) 4_465
Eu1 C45 2.877(4) .
Eu2 O2 2.375(3) .
Eu2 O5 2.338(3) 4_465
Eu2 O11 2.379(3) 2_746
Eu2 O14 2.334(3) .
Eu2 O17 2.518(3) 2_646
Eu2 O18 2.431(3) 2_646
Eu2 O19 2.485(3) .
Eu2 O20 2.468(3) .
Eu2 C69 2.855(4) 2_646
O1 C22 1.273(5) .
O2 C22 1.252(5) .
O3 H3 0.8200 .
O3 C2 1.365(5) .
O4 H4 0.8200 .
O4 C13 1.363(4) .
O5 Eu2 2.338(3) 4_666
O5 C23 1.251(5) .
O6 Eu1 2.397(3) 4_666
O6 C23 1.259(5) .
O7 C45 1.277(5) .
O8 C45 1.264(4) .
O9 H9 0.8200 .
O9 C25 1.356(5) .
O10 H10 0.8200 .
O10 C36 1.352(5) .
O11 Eu2 2.379(3) 2_756
O11 C46 1.267(5) .
O12 Eu1 2.355(3) 2_756
O12 C46 1.253(4) .
O13 C68 1.265(5) .
O14 C68 1.253(4) .
O15 H15 0.8200 .
O15 C48 1.367(4) .
O16 H16 0.8200 .
O16 C59 1.369(5) .
O17 Eu2 2.518(3) 2_656
O17 C69 1.280(5) .
O18 Eu2 2.431(3) 2_656
O18 C69 1.258(5) .
O19 H19A 0.8799 .
O19 H19B 0.8805 .
O20 H20A 0.8632 .
O20 H20B 0.8604 .
O21 C70 1.237(5) .
O22 C73 1.204(9) .
O23 C76 1.223(7) .
O24 C79 1.180(9) .
O24A C79 1.148(9) .
N1 C70 1.298(5) .
N1 C71 1.450(6) .
N1 C72 1.443(7) .
N2 C76 1.317(7) .
N2 C77 1.424(7) .
N2 C78 1.445(7) .
N3 C79 1.313(9) .
N3 C80 1.401(8) .
N3 C81 1.411(9) .
N4 C73 1.349(18) .
N4 C74 1.431(18) .
N4 C75 1.301(16) .
C1 C2 1.427(5) .
C1 C6 1.383(5) .
C1 C22 1.501(5) .
C2 C3 1.379(5) .
C3 C4 1.417(5) .
C3 C11 1.535(5) .
C4 C5 1.439(5) .
C4 C7 1.412(5) .
C5 C6 1.406(5) .
C5 C10 1.410(5) .
C6 H6 0.9300 .
C7 H7 0.9300 .
C7 C8 1.370(6) .
C8 H8 0.9300 .
C8 C9 1.396(6) .
C9 H9A 0.9300 .
C9 C10 1.362(6) .
C10 H10A 0.9300 .
C11 H11A 0.9700 .
C11 H11B 0.9700 .
C11 C12 1.521(5) .
C12 C13 1.381(5) .
C12 C17 1.435(5) .
C13 C14 1.437(5) .
C14 C15 1.360(5) .
C14 C23 1.485(5) .
C15 H15A 0.9300 .
C15 C16 1.404(6) .
C16 C17 1.415(6) .
C16 C21 1.422(6) .
C17 C18 1.419(5) .
C18 H18 0.9300 .
C18 C19 1.366(6) .
C19 H19 0.9300 .
C19 C20 1.373(8) .
C20 H20 0.9300 .
C20 C21 1.369(7) .
C21 H21 0.9300 .
C23 Eu1 3.174(4) 4_666
C24 C25 1.426(5) .
C24 C29 1.368(5) .
C24 C45 1.483(5) .
C25 C26 1.388(5) .
C26 C27 1.424(6) .
C26 C34 1.521(5) .
C27 C28 1.421(6) .
C27 C30 1.423(5) .
C28 C29 1.406(5) .
C28 C33 1.413(6) .
C29 H29 0.9300 .
C30 H30 0.9300 .
C30 C31 1.353(6) .
C31 H31 0.9300 .
C31 C32 1.400(7) .
C32 H32 0.9300 .
C32 C33 1.357(6) .
C33 H33 0.9300 .
C34 H34A 0.9700 .
C34 H34B 0.9700 .
C34 C35 1.516(5) .
C35 C36 1.386(5) .
C35 C40 1.44(3) .
C35 C40A 1.40(3) .
C36 C37 1.423(5) .
C37 C38 1.38(3) .
C37 C38A 1.38(3) .
C37 C46 1.507(5) .
C38 H38 0.9300 .
C38 C39 1.42(3) .
C38A H38A 0.9300 .
C38A C39A 1.38(3) .
C39 C40 1.42(3) .
C39 C44 1.425(16) .
C39A C40A 1.44(3) .
C39A C44A 1.414(17) .
C40 C41 1.42(3) .
C40A C41A 1.42(4) .
C41 H41 0.9300 .
C41 C42 1.35(2) .
C41A H41A 0.9300 .
C41A C42A 1.36(2) .
C42 H42 0.9300 .
C42 C43 1.396(14) .
C42A H42A 0.9300 .
C42A C43A 1.398(15) .
C43 H43 0.9300 .
C43 C44 1.346(13) .
C43A H43A 0.9300 .
C43A C44A 1.368(14) .
C44 H44 0.9300 .
C44A H44A 0.9300 .
C47 C48 1.425(5) .
C47 C52 1.372(5) .
C47 C68 1.491(5) .
C48 C49 1.381(5) .
C49 C50 1.424(5) .
C49 C57 1.518(5) .
C50 C51 1.431(5) .
C50 C56 1.417(5) .
C51 C52 1.400(5) .
C51 C53 1.417(6) .
C52 H52 0.9300 .
C53 H53 0.9300 .
C53 C54 1.354(6) .
C54 H54 0.9300 .
C54 C55 1.394(7) .
C55 H55 0.9300 .
C55 C56 1.361(6) .
C56 H56 0.9300 .
C57 H57A 0.9700 .
C57 H57B 0.9700 .
C57 C58 1.522(5) .
C58 C59 1.380(5) .
C58 C63 1.422(6) .
C59 C60 1.427(5) .
C60 C61 1.367(6) .
C60 C69 1.490(5) .
C61 H61 0.9300 .
C61 C62 1.409(5) .
C62 C63 1.420(6) .
C62 C67 1.419(6) .
C63 C64 1.427(5) .
C64 H64 0.9300 .
C64 C65 1.363(7) .
C65 H65 0.9300 .
C65 C66 1.395(7) .
C66 H66 0.9300 .
C66 C67 1.361(6) .
C67 H67 0.9300 .
C69 Eu2 2.855(4) 2_656
C70 H70 0.9300 .
C71 H71A 0.9600 .
C71 H71B 0.9600 .
C71 H71C 0.9600 .
C72 H72A 0.9600 .
C72 H72B 0.9600 .
C72 H72C 0.9600 .
C76 H76 0.9300 .
C77 H77A 0.9600 .
C77 H77B 0.9600 .
C77 H77C 0.9600 .
C78 H78A 0.9600 .
C78 H78B 0.9600 .
C78 H78C 0.9600 .
C80 H80A 0.9600 .
C80 H80B 0.9600 .
C80 H80C 0.9600 .
C81 H81A 0.9600 .
C81 H81B 0.9600 .
C81 H81C 0.9600 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
Eu1 Eu2 O2 C22 1.4(4) . .
Eu1 Eu2 O14 C68 16.4(4) . .
Eu1 O1 C22 O2 -18.2(8) . .
Eu1 O1 C22 C1 162.1(4) . .
Eu1 O6 C23 O5 -11.1(5) 4_666 .
Eu1 O6 C23 C14 166.4(3) 4_666 .
Eu1 O7 C45 O8 4.6(4) . .
Eu1 O7 C45 C24 -174.8(3) . .
Eu1 O8 C45 O7 -4.6(4) . .
Eu1 O8 C45 C24 174.7(3) . .
Eu1 O12 C46 O11 24.1(8) 2_756 .
Eu1 O12 C46 C37 -155.1(4) 2_756 .
Eu1 O13 C68 O14 27.0(7) . .
Eu1 O13 C68 C47 -152.5(3) . .
Eu1 O21 C70 N1 161.5(4) . .
Eu1 O22 C73 N4 -117.6(16) . .
Eu2 Eu1 O1 C22 14.5(5) . .
Eu2 Eu1 O7 C45 -133.3(2) . .
Eu2 Eu1 O8 C45 99.3(2) . .
Eu2 Eu1 O13 C68 -12.5(4) . .
Eu2 Eu1 O21 C70 -108.6(6) . .
Eu2 Eu1 O22 C73 -65.7(12) . .
Eu2 Eu1 C45 O7 64.9(3) . .
Eu2 Eu1 C45 O8 -110.5(2) . .
Eu2 O2 C22 O1 4.5(7) . .
Eu2 O2 C22 C1 -175.8(3) . .
Eu2 O11 C46 O12 -10.0(7) 2_756 .
Eu2 O11 C46 C37 169.2(3) 2_756 .
Eu2 O14 C68 O13 -29.6(7) . .
Eu2 O14 C68 C47 149.9(3) . .
Eu2 O17 C69 O18 -1.3(4) 2_656 .
Eu2 O17 C69 C60 177.6(3) 2_656 .
Eu2 O18 C69 O17 1.3(4) 2_656 .
Eu2 O18 C69 C60 -177.6(3) 2_656 .
O1 Eu1 Eu2 O2 -3.77(12) . .
O1 Eu1 Eu2 O5 -177.67(13) . 4_465
O1 Eu1 Eu2 O11 -85.56(12) . 2_746
O1 Eu1 Eu2 O14 88.58(12) . .
O1 Eu1 Eu2 O17 -134.37(11) . 2_646
O1 Eu1 Eu2 O18 -67.64(15) . 2_646
O1 Eu1 Eu2 O19 47.93(12) . .
O1 Eu1 Eu2 O20 137.17(13) . .
O1 Eu1 Eu2 C69 -109.37(15) . 2_646
O1 Eu1 O7 C45 -176.8(2) . .
O1 Eu1 O8 C45 10.0(3) . .
O1 Eu1 O13 C68 -75.6(4) . .
O1 Eu1 O21 C70 -73.1(6) . .
O1 Eu1 O22 C73 16.1(12) . .
O1 Eu1 C45 O7 3.2(2) . .
O1 Eu1 C45 O8 -172.2(2) . .
O2 Eu2 O14 C68 83.0(4) . .
O3 C2 C3 C4 -176.3(4) . .
O3 C2 C3 C11 0.0(6) . .
O4 C13 C14 C15 174.4(4) . .
O4 C13 C14 C23 -3.0(6) . .
O5 Eu2 O2 C22 6.1(5) 4_465 .
O5 Eu2 O14 C68 -31.3(4) 4_465 .
O6 Eu1 Eu2 O2 -175.59(11) 4_465 .
O6 Eu1 Eu2 O5 10.51(13) 4_465 4_465
O6 Eu1 Eu2 O11 102.62(12) 4_465 2_746
O6 Eu1 Eu2 O14 -83.24(11) 4_465 .
O6 Eu1 Eu2 O17 53.81(11) 4_465 2_646
O6 Eu1 Eu2 O18 120.54(14) 4_465 2_646
O6 Eu1 Eu2 O19 -123.89(11) 4_465 .
O6 Eu1 Eu2 O20 -34.65(13) 4_465 .
O6 Eu1 Eu2 C69 78.81(14) 4_465 2_646
O6 Eu1 O1 C22 25.2(6) 4_465 .
O6 Eu1 O7 C45 -42.1(3) 4_465 .
O6 Eu1 O8 C45 150.4(2) 4_465 .
O6 Eu1 O13 C68 66.7(4) 4_465 .
O6 Eu1 O21 C70 131.4(5) 4_465 .
O6 Eu1 O22 C73 -119.9(12) 4_465 .
O6 Eu1 C45 O7 145.3(2) 4_465 .
O6 Eu1 C45 O8 -30.1(2) 4_465 .
O7 Eu1 Eu2 O2 -54.99(11) . .
O7 Eu1 Eu2 O5 131.11(13) . 4_465
O7 Eu1 Eu2 O11 -136.79(11) . 2_746
O7 Eu1 Eu2 O14 37.35(11) . .
O7 Eu1 Eu2 O17 174.41(10) . 2_646
O7 Eu1 Eu2 O18 -118.87(14) . 2_646
O7 Eu1 Eu2 O19 -3.29(11) . .
O7 Eu1 Eu2 O20 85.95(12) . .
O7 Eu1 Eu2 C69 -160.59(14) . 2_646
O7 Eu1 O1 C22 151.9(6) . .
O7 Eu1 O8 C45 2.6(2) . .
O7 Eu1 O13 C68 -158.2(5) . .
O7 Eu1 O21 C70 8.1(5) . .
O7 Eu1 O22 C73 120.5(12) . .
O7 Eu1 C45 O8 -175.4(4) . .
O8 Eu1 Eu2 O2 -122.35(12) . .
O8 Eu1 Eu2 O5 63.76(14) . 4_465
O8 Eu1 Eu2 O11 155.86(13) . 2_746
O8 Eu1 Eu2 O14 -30.00(12) . .
O8 Eu1 Eu2 O17 107.06(12) . 2_646
O8 Eu1 Eu2 O18 173.78(15) . 2_646
O8 Eu1 Eu2 O19 -70.64(12) . .
O8 Eu1 Eu2 O20 18.60(14) . .
O8 Eu1 Eu2 C69 132.05(15) . 2_646
O8 Eu1 O1 C22 145.9(5) . .
O8 Eu1 O7 C45 -2.6(2) . .
O8 Eu1 O13 C68 149.2(4) . .
O8 Eu1 O21 C70 58.5(6) . .
O8 Eu1 O22 C73 154.5(12) . .
O8 Eu1 C45 O7 175.4(4) . .
O9 C25 C26 C27 179.7(3) . .
O9 C25 C26 C34 2.4(5) . .
O10 C36 C37 C38 170.1(8) . .
O10 C36 C37 C38A -169.4(8) . .
O10 C36 C37 C46 3.5(6) . .
O11 Eu2 O2 C22 71.0(4) 2_746 .
O11 Eu2 O14 C68 23.2(5) 2_746 .
O12 Eu1 Eu2 O2 85.65(12) 2_746 .
O12 Eu1 Eu2 O5 -88.25(13) 2_746 4_465
O12 Eu1 Eu2 O11 3.86(12) 2_746 2_746
O12 Eu1 Eu2 O14 178.00(12) 2_746 .
O12 Eu1 Eu2 O17 -44.95(11) 2_746 2_646
O12 Eu1 Eu2 O18 21.78(14) 2_746 2_646
O12 Eu1 Eu2 O19 137.35(12) 2_746 .
O12 Eu1 Eu2 O20 -133.41(13) 2_746 .
O12 Eu1 Eu2 C69 -19.95(15) 2_746 2_646
O12 Eu1 O1 C22 -49.9(6) 2_746 .
O12 Eu1 O7 C45 143.0(2) 2_746 .
O12 Eu1 O8 C45 -137.4(2) 2_746 .
O12 Eu1 O13 C68 -13.1(5) 2_746 .
O12 Eu1 O21 C70 -149.5(6) 2_746 .
O12 Eu1 O22 C73 -25.4(12) 2_746 .
O12 Eu1 C45 O7 -84.8(4) 2_746 .
O12 Eu1 C45 O8 99.8(4) 2_746 .
O13 Eu1 Eu2 O2 -93.73(12) . .
O13 Eu1 Eu2 O5 92.37(13) . 4_465
O13 Eu1 Eu2 O11 -175.52(11) . 2_746
O13 Eu1 Eu2 O14 -1.38(11) . .
O13 Eu1 Eu2 O17 135.67(11) . 2_646
O13 Eu1 Eu2 O18 -157.60(14) . 2_646
O13 Eu1 Eu2 O19 -42.03(11) . .
O13 Eu1 Eu2 O20 47.21(13) . .
O13 Eu1 Eu2 C69 160.67(14) . 2_646
O13 Eu1 O1 C22 79.1(6) . .
O13 Eu1 O7 C45 -97.8(2) . .
O13 Eu1 O8 C45 74.2(2) . .
O13 Eu1 O21 C70 -18.0(6) . .
O13 Eu1 O22 C73 -149.3(12) . .
O13 Eu1 C45 O7 74.4(2) . .
O13 Eu1 C45 O8 -100.9(2) . .
O14 Eu2 O2 C22 -64.2(4) . .
O15 C48 C49 C50 -178.6(4) . .
O15 C48 C49 C57 3.0(6) . .
O16 C59 C60 C61 -177.5(4) . .
O16 C59 C60 C69 2.9(5) . .
O17 Eu2 O2 C22 110.0(4) 2_646 .
O17 Eu2 O14 C68 -90.4(4) 2_646 .
O18 Eu2 O2 C22 151.8(4) 2_646 .
O18 Eu2 O14 C68 174.2(4) 2_646 .
O19 Eu2 O2 C22 -135.2(4) . .
O19 Eu2 O14 C68 160.4(4) . .
O20 Eu2 O2 C22 -116.3(4) . .
O20 Eu2 O14 C68 -124.9(4) . .
O21 Eu1 Eu2 O2 37.60(13) . .
O21 Eu1 Eu2 O5 -136.30(14) . 4_465
O21 Eu1 Eu2 O11 -44.19(13) . 2_746
O21 Eu1 Eu2 O14 129.95(13) . .
O21 Eu1 Eu2 O17 -93.00(13) . 2_646
O21 Eu1 Eu2 O18 -26.28(16) . 2_646
O21 Eu1 Eu2 O19 89.30(13) . .
O21 Eu1 Eu2 O20 178.54(14) . .
O21 Eu1 Eu2 C69 -68.00(16) . 2_646
O21 Eu1 O1 C22 -134.7(6) . .
O21 Eu1 O7 C45 100.1(2) . .
O21 Eu1 O8 C45 -65.5(2) . .
O21 Eu1 O13 C68 -131.9(4) . .
O21 Eu1 O22 C73 61.2(12) . .
O21 Eu1 C45 O7 -73.0(2) . .
O21 Eu1 C45 O8 111.7(2) . .
O22 Eu1 Eu2 O2 131.63(12) . .
O22 Eu1 Eu2 O5 -42.26(13) . 4_465
O22 Eu1 Eu2 O11 49.84(12) . 2_746
O22 Eu1 Eu2 O14 -136.02(12) . .
O22 Eu1 Eu2 O17 1.04(11) . 2_646
O22 Eu1 Eu2 O18 67.76(15) . 2_646
O22 Eu1 Eu2 O19 -176.66(11) . .
O22 Eu1 Eu2 O20 -87.42(13) . .
O22 Eu1 Eu2 C69 26.03(15) . 2_646
O22 Eu1 O1 C22 -91.5(6) . .
O22 Eu1 O7 C45 40.5(2) . .
O22 Eu1 O8 C45 -137.6(2) . .
O22 Eu1 O13 C68 95.2(5) . .
O22 Eu1 O21 C70 133.1(6) . .
O22 Eu1 C45 O7 -143.9(2) . .
O22 Eu1 C45 O8 40.8(2) . .
C1 C2 C3 C4 3.8(6) . .
C1 C2 C3 C11 -179.9(4) . .
C2 C1 C6 C5 -1.9(6) . .
C2 C1 C22 O1 1.1(6) . .
C2 C1 C22 O2 -178.6(4) . .
C2 C3 C4 C5 -5.1(6) . .
C2 C3 C4 C7 173.1(4) . .
C2 C3 C11 C12 117.7(4) . .
C3 C4 C5 C6 3.0(5) . .
C3 C4 C5 C10 -179.7(4) . .
C3 C4 C7 C8 -179.4(4) . .
C3 C11 C12 C13 116.7(4) . .
C3 C11 C12 C17 -66.6(5) . .
C4 C3 C11 C12 -66.1(5) . .
C4 C5 C6 C1 0.5(6) . .
C4 C5 C10 C9 -1.1(6) . .
C4 C7 C8 C9 -0.5(7) . .
C5 C4 C7 C8 -1.2(6) . .
C6 C1 C2 O3 179.9(4) . .
C6 C1 C2 C3 -0.3(6) . .
C6 C1 C22 O1 -177.8(4) . .
C6 C1 C22 O2 2.5(6) . .
C6 C5 C10 C9 176.2(4) . .
C7 C4 C5 C6 -175.4(4) . .
C7 C4 C5 C10 2.0(5) . .
C7 C8 C9 C10 1.5(7) . .
C8 C9 C10 C5 -0.7(7) . .
C10 C5 C6 C1 -176.7(4) . .
C11 C3 C4 C5 178.7(3) . .
C11 C3 C4 C7 -3.1(6) . .
C11 C12 C13 O4 6.4(5) . .
C11 C12 C13 C14 -171.2(3) . .
C11 C12 C17 C16 176.6(3) . .
C11 C12 C17 C18 -7.6(6) . .
C12 C13 C14 C15 -8.1(6) . .
C12 C13 C14 C23 174.5(3) . .
C12 C17 C18 C19 -173.0(4) . .
C13 C12 C17 C16 -6.6(5) . .
C13 C12 C17 C18 169.1(4) . .
C13 C14 C15 C16 -1.7(6) . .
C13 C14 C23 Eu1 41.4(9) . 4_666
C13 C14 C23 O5 -165.8(4) . .
C13 C14 C23 O6 16.6(6) . .
C14 C15 C16 C17 6.9(6) . .
C14 C15 C16 C21 -169.9(4) . .
C15 C14 C23 Eu1 -136.0(6) . 4_666
C15 C14 C23 O5 16.8(6) . .
C15 C14 C23 O6 -160.8(4) . .
C15 C16 C17 C12 -2.7(6) . .
C15 C16 C17 C18 -178.6(4) . .
C15 C16 C21 C20 176.6(4) . .
C16 C17 C18 C19 2.8(6) . .
C17 C12 C13 O4 -170.4(3) . .
C17 C12 C13 C14 12.0(5) . .
C17 C16 C21 C20 -0.3(7) . .
C17 C18 C19 C20 -2.0(7) . .
C18 C19 C20 C21 0.0(8) . .
C19 C20 C21 C16 1.1(8) . .
C21 C16 C17 C12 174.2(4) . .
C21 C16 C17 C18 -1.7(6) . .
C22 C1 C2 O3 0.9(6) . .
C22 C1 C2 C3 -179.2(4) . .
C22 C1 C6 C5 177.1(4) . .
C23 Eu1 Eu2 O2 178.62(12) 4_465 .
C23 Eu1 Eu2 O5 4.72(13) 4_465 4_465
C23 Eu1 Eu2 O11 96.83(12) 4_465 2_746
C23 Eu1 Eu2 O14 -89.03(12) 4_465 .
C23 Eu1 Eu2 O17 48.02(11) 4_465 2_646
C23 Eu1 Eu2 O18 114.75(15) 4_465 2_646
C23 Eu1 Eu2 O19 -129.68(12) 4_465 .
C23 Eu1 Eu2 O20 -40.44(13) 4_465 .
C23 Eu1 Eu2 C69 73.02(15) 4_465 2_646
C23 Eu1 O1 C22 16.6(6) 4_465 .
C23 Eu1 O7 C45 -64.6(3) 4_465 .
C23 Eu1 O8 C45 143.9(2) 4_465 .
C23 Eu1 O13 C68 45.5(4) 4_465 .
C23 Eu1 O21 C70 166.9(5) 4_465 .
C23 Eu1 O22 C73 -102.2(12) 4_465 .
C23 Eu1 C45 O7 133.0(2) 4_465 .
C23 Eu1 C45 O8 -42.4(3) 4_465 .
C23 C14 C15 C16 175.7(4) . .
C24 C25 C26 C27 0.9(5) . .
C24 C25 C26 C34 -176.4(3) . .
C25 C24 C29 C28 -1.5(6) . .
C25 C24 C45 O7 4.2(5) . .
C25 C24 C45 O8 -175.1(3) . .
C25 C26 C27 C28 -1.3(6) . .
C25 C26 C27 C30 179.4(4) . .
C25 C26 C34 C35 -122.2(4) . .
C26 C27 C28 C29 0.4(6) . .
C26 C27 C28 C33 -178.6(4) . .
C26 C27 C30 C31 -178.5(4) . .
C26 C34 C35 C36 -118.8(4) . .
C26 C34 C35 C40 52.3(11) . .
C26 C34 C35 C40A 67.3(11) . .
C27 C26 C34 C35 60.6(5) . .
C27 C28 C29 C24 1.0(6) . .
C27 C28 C33 C32 -4.0(7) . .
C27 C30 C31 C32 -1.9(7) . .
C28 C27 C30 C31 2.2(6) . .
C29 C24 C25 O9 -178.3(4) . .
C29 C24 C25 C26 0.5(6) . .
C29 C24 C45 O7 -176.1(4) . .
C29 C24 C45 O8 4.5(6) . .
C29 C28 C33 C32 176.9(4) . .
C30 C27 C28 C29 179.8(4) . .
C30 C27 C28 C33 0.7(6) . .
C30 C31 C32 C33 -1.5(7) . .
C31 C32 C33 C28 4.4(7) . .
C33 C28 C29 C24 -179.9(4) . .
C34 C26 C27 C28 175.8(3) . .
C34 C26 C27 C30 -3.5(6) . .
C34 C35 C36 O10 -3.6(6) . .
C34 C35 C36 C37 173.4(4) . .
C34 C35 C40 C39 -170.8(10) . .
C34 C35 C40 C41 11(2) . .
C34 C35 C40A C39A -179.0(10) . .
C34 C35 C40A C41A -2(2) . .
C35 C36 C37 C38 -6.8(9) . .
C35 C36 C37 C38A 13.7(9) . .
C35 C36 C37 C46 -173.4(4) . .
C35 C40 C41 C42 -177.4(13) . .
C35 C40A C41A C42A -177.5(13) . .
C36 C35 C40 C39 0.2(19) . .
C36 C35 C40 C41 -178.4(12) . .
C36 C35 C40A C39A 7(2) . .
C36 C35 C40A C41A -176.3(12) . .
C36 C37 C38 C39 8.9(15) . .
C36 C37 C38A C39A -9.1(16) . .
C36 C37 C46 O11 5.2(6) . .
C36 C37 C46 O12 -175.6(4) . .
C37 C38 C39 C40 -6.4(18) . .
C37 C38 C39 C44 178.0(10) . .
C37 C38A C39A C40A 4(2) . .
C37 C38A C39A C44A -177.8(10) . .
C38 C37 C38A C39A 80(7) . .
C38 C37 C46 O11 -161.2(7) . .
C38 C37 C46 O12 18.1(8) . .
C38 C39 C40 C35 2(2) . .
C38 C39 C40 C41 -179.8(13) . .
C38 C39 C44 C43 176.3(11) . .
C38A C37 C38 C39 -92(8) . .
C38A C37 C46 O11 178.1(8) . .
C38A C37 C46 O12 -2.6(9) . .
C38A C39A C40A C35 -3(2) . .
C38A C39A C40A C41A -179.7(14) . .
C38A C39A C44A C43A -179.3(12) . .
C39 C40 C41 C42 4(2) . .
C39A C40A C41A C42A -1(2) . .
C40 C35 C36 O10 -174.6(10) . .
C40 C35 C36 C37 2.4(11) . .
C40 C35 C40A C39A -97(11) . .
C40 C35 C40A C41A 80(11) . .
C40 C39 C44 C43 0.7(17) . .
C40 C41 C42 C43 -1(2) . .
C40A C35 C36 O10 170.6(10) . .
C40A C35 C36 C37 -12.4(11) . .
C40A C35 C40 C39 84(11) . .
C40A C35 C40 C41 -95(11) . .
C40A C39A C44A C43A -1.0(18) . .
C40A C41A C42A C43A -2(2) . .
C41 C42 C43 C44 -2.6(17) . .
C41A C42A C43A C44A 2.6(18) . .
C42 C43 C44 C39 2.6(17) . .
C42A C43A C44A C39A -1.3(17) . .
C44 C39 C40 C35 177.4(11) . .
C44 C39 C40 C41 -4(2) . .
C44A C39A C40A C35 178.8(12) . .
C44A C39A C40A C41A 2(2) . .
C45 Eu1 Eu2 O2 -83.15(14) . .
C45 Eu1 Eu2 O5 102.96(15) . 4_465
C45 Eu1 Eu2 O11 -164.94(14) . 2_746
C45 Eu1 Eu2 O14 9.20(14) . .
C45 Eu1 Eu2 O17 146.25(14) . 2_646
C45 Eu1 Eu2 O18 -147.02(17) . 2_646
C45 Eu1 Eu2 O19 -31.44(14) . .
C45 Eu1 Eu2 O20 57.79(15) . .
C45 Eu1 Eu2 C69 171.25(16) . 2_646
C45 Eu1 O1 C22 150.4(5) . .
C45 Eu1 O13 C68 174.9(5) . .
C45 Eu1 O21 C70 34.5(6) . .
C45 Eu1 O22 C73 137.3(12) . .
C45 C24 C25 O9 1.4(5) . .
C45 C24 C25 C26 -179.8(3) . .
C45 C24 C29 C28 178.8(4) . .
C46 C37 C38 C39 175.7(9) . .
C46 C37 C38A C39A 177.9(9) . .
C47 C48 C49 C50 1.2(6) . .
C47 C48 C49 C57 -177.3(4) . .
C48 C47 C52 C51 0.6(6) . .
C48 C47 C68 O13 -19.6(6) . .
C48 C47 C68 O14 160.8(4) . .
C48 C49 C50 C51 -2.0(6) . .
C48 C49 C50 C56 178.1(4) . .
C48 C49 C57 C58 117.8(4) . .
C49 C50 C51 C52 2.1(6) . .
C49 C50 C51 C53 -178.9(4) . .
C49 C50 C56 C55 178.7(5) . .
C49 C57 C58 C59 119.3(4) . .
C49 C57 C58 C63 -59.5(5) . .
C50 C49 C57 C58 -60.7(5) . .
C50 C51 C52 C47 -1.4(7) . .
C50 C51 C53 C54 0.5(8) . .
C51 C50 C56 C55 -1.2(7) . .
C51 C53 C54 C55 -1.9(9) . .
C52 C47 C48 O15 179.3(4) . .
C52 C47 C48 C49 -0.5(6) . .
C52 C47 C68 O13 156.3(4) . .
C52 C47 C68 O14 -23.2(6) . .
C52 C51 C53 C54 179.4(5) . .
C53 C51 C52 C47 179.6(5) . .
C53 C54 C55 C56 1.7(9) . .
C54 C55 C56 C50 -0.2(8) . .
C56 C50 C51 C52 -178.0(4) . .
C56 C50 C51 C53 1.0(6) . .
C57 C49 C50 C51 176.4(4) . .
C57 C49 C50 C56 -3.4(6) . .
C57 C58 C59 O16 1.2(5) . .
C57 C58 C59 C60 -177.4(3) . .
C57 C58 C63 C62 174.2(3) . .
C57 C58 C63 C64 -7.5(6) . .
C58 C59 C60 C61 1.1(6) . .
C58 C59 C60 C69 -178.5(3) . .
C58 C63 C64 C65 176.7(4) . .
C59 C58 C63 C62 -4.6(5) . .
C59 C58 C63 C64 173.7(4) . .
C59 C60 C61 C62 -0.3(6) . .
C59 C60 C69 O17 3.7(6) . .
C59 C60 C69 O18 -177.4(4) . .
C60 C61 C62 C63 -2.9(6) . .
C60 C61 C62 C67 178.9(4) . .
C61 C60 C69 O17 -175.9(4) . .
C61 C60 C69 O18 3.0(6) . .
C61 C62 C63 C58 5.4(6) . .
C61 C62 C63 C64 -173.1(4) . .
C61 C62 C67 C66 177.3(5) . .
C62 C63 C64 C65 -4.8(6) . .
C63 C58 C59 O16 180.0(3) . .
C63 C58 C59 C60 1.4(6) . .
C63 C62 C67 C66 -0.8(7) . .
C63 C64 C65 C66 0.3(7) . .
C64 C65 C66 C67 4.2(8) . .
C65 C66 C67 C62 -3.8(8) . .
C67 C62 C63 C58 -176.5(4) . .
C67 C62 C63 C64 5.1(6) . .
C68 C47 C48 O15 -4.8(6) . .
C68 C47 C48 C49 175.5(4) . .
C68 C47 C52 C51 -175.4(4) . .
C69 Eu2 O2 C22 135.3(4) 2_646 .
C69 Eu2 O14 C68 -137.1(4) 2_646 .
C69 C60 C61 C62 179.3(4) . .
C71 N1 C70 O21 -176.9(5) . .
C72 N1 C70 O21 0.7(8) . .
C74 N4 C73 O22 -172.8(14) . .
C75 N4 C73 O22 9(3) . .
C77 N2 C76 O23 0.1(10) . .
C78 N2 C76 O23 176.3(6) . .
C80 N3 C79 O24 162.4(16) . .
C80 N3 C79 O24A 21(4) . .
C81 N3 C79 O24 -19(2) . .
C81 N3 C79 O24A -160(3) . .
