#------------------------------------------------------------------------------
#$Date: 2016-03-26 23:11:40 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180531 $
#$URL: svn://www.crystallography.net/cod/cif/7/22/00/7220034.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7220034
loop_
_publ_author_name
'Xu, Guohai'
'Xie, Min'
'Li, Xiaokang'
'Shi, Wenjie'
'Yu, Hui'
'Hu, Yinhui'
'Xun, Xiaochen'
'Xie, Yongrong'
_publ_section_title
;
 Four binuclear coordination polymers with a 63net and self-assembly of 2D
 63topology into different supramolecular networks using unit--unit
 H-bonds
;
_journal_issue                   19
_journal_name_full               CrystEngComm
_journal_page_first              3677
_journal_paper_doi               10.1039/C5CE00264H
_journal_volume                  17
_journal_year                    2015
_chemical_formula_moiety         'C25 H27 Co2 N O10'
_chemical_formula_sum            'C25 H27 Co2 N O10'
_chemical_formula_weight         619.34
_chemical_melting_point          ?
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_audit_update_record
;
2015-02-04 deposited with the CCDC.
2015-03-30 downloaded from the CCDC.
;
_cell_angle_alpha                108.4540(10)
_cell_angle_beta                 96.560(2)
_cell_angle_gamma                92.829(2)
_cell_formula_units_Z            2
_cell_length_a                   10.1815(11)
_cell_length_b                   11.5501(12)
_cell_length_c                   11.6759(12)
_cell_measurement_temperature    298(2)
_cell_measurement_theta_max      26.1
_cell_measurement_theta_min      1.9
_cell_volume                     1288.6(2)
_computing_cell_refinement       'SAINT (Bruker, 1999)'
_computing_data_collection       'SMART (Bruker, 1997)'
_computing_data_reduction        'SAINT (Bruker, 1999)'
_computing_molecular_graphics    'SHELXTL-PLUS (Sheldrick, 1990)'
_computing_publication_material  SHELXL-97
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97(Sheldrick, 1997)'
_diffrn_ambient_temperature      298(2)
_diffrn_measured_fraction_theta_full 0.993
_diffrn_measured_fraction_theta_max 0.986
_diffrn_measurement_device_type  'Bruker SMART APEX CCD'
_diffrn_measurement_method       'ω scan'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0137
_diffrn_reflns_av_sigmaI/netI    0.0288
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_l_max       14
_diffrn_reflns_limit_l_min       -14
_diffrn_reflns_number            7237
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         26.08
_diffrn_reflns_theta_min         1.86
_exptl_absorpt_coefficient_mu    1.346
_exptl_absorpt_correction_T_max  0.8135
_exptl_absorpt_correction_T_min  0.7384
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS (Sheldrick, 1996)'
_exptl_crystal_colour            pink
_exptl_crystal_density_diffrn    1.596
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             636
_exptl_crystal_recrystallization_method Solvothermal
_exptl_crystal_size_max          0.24
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.16
_refine_diff_density_max         1.182
_refine_diff_density_min         -0.573
_refine_diff_density_rms         0.072
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.036
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     349
_refine_ls_number_reflns         5045
_refine_ls_number_restraints     3
_refine_ls_restrained_S_all      1.042
_refine_ls_R_factor_all          0.0497
_refine_ls_R_factor_gt           0.0406
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0556P)²+1.4422P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1043
_refine_ls_wR_factor_ref         0.1105
_reflns_number_gt                4224
_reflns_number_total             5045
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c5ce00264h2.cif
_cod_data_source_block           compound2
_cod_depositor_comments
;
The following automatic conversions were performed:

'_chemical_melting_point' value 'not measured' was changed to '?' -
the value is undefined or not given.

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 3143 2015-03-26 13:38:13Z robertas 

 Adding full bibliography for 7220033--7220036.cif.
;
_cod_original_sg_symbol_H-M      p-1
_cod_database_code               7220034
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
C1 C 0.1381(4) 0.5409(4) 0.8603(3) 0.0502(9) Uani 1 1 d .
H1A H 0.1844 0.6116 0.9241 0.060 Uiso 1 1 calc R
H1B H 0.0500 0.5276 0.8803 0.060 Uiso 1 1 calc R
C2 C 0.1280(6) 0.5639(6) 0.7428(5) 0.093(2) Uani 1 1 d .
H2A H 0.0524 0.5130 0.6894 0.111 Uiso 1 1 calc R
H2B H 0.1110 0.6487 0.7563 0.111 Uiso 1 1 calc R
C3 C 0.1771(5) 0.3577(4) 0.5042(3) 0.0604(11) Uani 1 1 d .
H3A H 0.0842 0.3413 0.5104 0.072 Uiso 1 1 calc R
H3B H 0.1889 0.3253 0.4189 0.072 Uiso 1 1 calc R
C4 C 0.2127(6) 0.4912(5) 0.5489(4) 0.0775(14) Uani 1 1 d .
H4A H 0.2884 0.5096 0.5120 0.093 Uiso 1 1 calc R
H4B H 0.1390 0.5317 0.5235 0.093 Uiso 1 1 calc R
C5 C 0.3423(4) 0.6468(4) 0.7186(6) 0.0772(15) Uani 1 1 d .
H5A H 0.3336 0.6964 0.8012 0.093 Uiso 1 1 calc R
H5B H 0.3216 0.6957 0.6661 0.093 Uiso 1 1 calc R
C6 C 0.4802(4) 0.6173(3) 0.7138(4) 0.0531(10) Uani 1 1 d .
H6A H 0.5009 0.6046 0.6318 0.064 Uiso 1 1 calc R
H6B H 0.5383 0.6865 0.7685 0.064 Uiso 1 1 calc R
C7 C 0.8161(3) 0.6606(3) 0.8703(3) 0.0283(6) Uani 1 1 d .
C8 C 0.8910(3) 0.7840(3) 0.9377(3) 0.0296(6) Uani 1 1 d .
C9 C 0.9122(3) 0.8641(3) 0.8760(3) 0.0324(7) Uani 1 1 d .
H9 H 0.8833 0.8404 0.7927 0.039 Uiso 1 1 calc R
C10 C 0.9777(3) 0.9833(3) 0.9364(3) 0.0287(6) Uani 1 1 d .
C11 C 0.9374(3) 0.8181(3) 1.0639(3) 0.0373(7) Uani 1 1 d .
H11 H 0.9243 0.7630 1.1056 0.045 Uiso 1 1 calc R
C12 C 1.0014(3) 0.9316(3) 1.1247(3) 0.0378(7) Uani 1 1 d .
H12 H 1.0314 0.9528 1.2076 0.045 Uiso 1 1 calc R
C13 C 0.7707(4) 0.2749(3) 0.6172(3) 0.0432(8) Uani 1 1 d .
C14 C 0.8427(3) 0.1658(3) 0.5549(3) 0.0379(7) Uani 1 1 d .
C15 C 0.7777(4) 0.0719(3) 0.4511(3) 0.0472(9) Uani 1 1 d .
H15 H 0.6928 0.0806 0.4178 0.057 Uiso 1 1 calc R
C16 C 0.9679(4) 0.1532(3) 0.6025(3) 0.0378(7) Uani 1 1 d .
H16 H 1.0111 0.2156 0.6701 0.045 Uiso 1 1 calc R
C17 C 1.0336(3) 0.0473(3) 0.5514(3) 0.0341(7) Uani 1 1 d .
C18 C 1.1620(4) 0.0314(3) 0.6012(3) 0.0449(8) Uani 1 1 d .
H18 H 1.2059 0.0917 0.6701 0.054 Uiso 1 1 calc R
C19 C 0.5287(3) 0.2667(3) 0.8508(3) 0.0303(6) Uani 1 1 d .
C20 C 0.5399(3) 0.1680(3) 0.9097(3) 0.0280(6) Uani 1 1 d .
C21 C 0.6659(3) 0.1426(3) 0.9548(3) 0.0344(7) Uani 1 1 d .
H21 H 0.7419 0.1849 0.9456 0.041 Uiso 1 1 calc R
C22 C 0.4284(3) 0.1035(3) 0.9198(3) 0.0308(6) Uani 1 1 d .
H22 H 0.3456 0.1199 0.8891 0.037 Uiso 1 1 calc R
C23 C 0.4370(3) 0.0121(3) 0.9765(3) 0.0278(6) Uani 1 1 d .
C24 C 0.3231(3) -0.0565(3) 0.9884(3) 0.0352(7) Uani 1 1 d .
H24 H 0.2396 -0.0426 0.9569 0.042 Uiso 1 1 calc R
C25 C 0.4042(6) 0.0643(5) 0.3534(5) 0.0912(18) Uani 1 1 d .
H25A H 0.4801 0.0607 0.3110 0.137 Uiso 1 1 calc R
H25B H 0.3258 0.0664 0.3003 0.137 Uiso 1 1 calc R
H25C H 0.3954 -0.0068 0.3788 0.137 Uiso 1 1 calc R
N1 N 0.2453(3) 0.5399(2) 0.6817(2) 0.0356(6) Uani 1 1 d .
O1 O 0.2562(3) 0.2975(2) 0.5720(2) 0.0482(6) Uani 1 1 d D
O2 O 0.2084(3) 0.4359(2) 0.8529(2) 0.0478(6) Uani 1 1 d D
O3 O 0.5055(2) 0.51160(19) 0.7463(2) 0.0388(5) Uani 1 1 d .
O4 O 0.4173(2) 0.2722(2) 0.7958(2) 0.0414(5) Uani 1 1 d .
O5 O 0.6316(2) 0.3356(2) 0.8620(2) 0.0429(6) Uani 1 1 d .
O6 O 0.6515(3) 0.2785(3) 0.5840(3) 0.0588(7) Uani 1 1 d .
O7 O 0.8344(3) 0.3597(2) 0.7042(3) 0.0525(7) Uani 1 1 d .
O8 O 0.7881(2) 0.62664(19) 0.75809(19) 0.0374(5) Uani 1 1 d .
O9 O 0.7816(2) 0.59251(19) 0.93047(19) 0.0366(5) Uani 1 1 d .
O10 O 0.4203(4) 0.1667(4) 0.4527(4) 0.1241(19) Uani 1 1 d D
H03 H 0.4985 0.1939 0.4682 0.186 Uiso 1 1 calc RD
Co1 Co 0.68125(4) 0.45546(3) 0.77578(4) 0.02884(13) Uani 1 1 d .
Co2 Co 0.34865(4) 0.40454(3) 0.73821(4) 0.02827(12) Uani 1 1 d .
H01 H 0.323(3) 0.261(3) 0.535(3) 0.042 Uiso 1 1 d D
H02 H 0.210(4) 0.423(3) 0.9244(18) 0.042 Uiso 1 1 d D
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Co Co 0.3494 0.9721 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O2 C1 C2 109.6(3) . .
O2 C1 H1A 109.8 . .
C2 C1 H1A 109.8 . .
O2 C1 H1B 109.8 . .
C2 C1 H1B 109.8 . .
H1A C1 H1B 108.2 . .
N1 C2 C1 114.4(4) . .
N1 C2 H2A 108.7 . .
C1 C2 H2A 108.7 . .
N1 C2 H2B 108.7 . .
C1 C2 H2B 108.7 . .
H2A C2 H2B 107.6 . .
O1 C3 C4 111.5(3) . .
O1 C3 H3A 109.3 . .
C4 C3 H3A 109.3 . .
O1 C3 H3B 109.3 . .
C4 C3 H3B 109.3 . .
H3A C3 H3B 108.0 . .
N1 C4 C3 112.6(3) . .
N1 C4 H4A 109.1 . .
C3 C4 H4A 109.1 . .
N1 C4 H4B 109.1 . .
C3 C4 H4B 109.1 . .
H4A C4 H4B 107.8 . .
N1 C5 C6 114.3(4) . .
N1 C5 H5A 108.7 . .
C6 C5 H5A 108.7 . .
N1 C5 H5B 108.7 . .
C6 C5 H5B 108.7 . .
H5A C5 H5B 107.6 . .
O3 C6 C5 112.9(3) . .
O3 C6 H6A 109.0 . .
C5 C6 H6A 109.0 . .
O3 C6 H6B 109.0 . .
C5 C6 H6B 109.0 . .
H6A C6 H6B 107.8 . .
O8 C7 O9 120.5(3) . .
O8 C7 C8 120.4(3) . .
O9 C7 C8 119.1(3) . .
C9 C8 C11 119.8(3) . .
C9 C8 C7 119.2(3) . .
C11 C8 C7 121.0(3) . .
C8 C9 C10 121.3(3) . .
C8 C9 H9 119.3 . .
C10 C9 H9 119.3 . .
C12 C10 C9 122.4(3) 2_777 .
C12 C10 C10 119.4(3) 2_777 2_777
C9 C10 C10 118.2(3) . 2_777
C12 C11 C8 120.4(3) . .
C12 C11 H11 119.8 . .
C8 C11 H11 119.8 . .
C11 C12 C10 120.8(3) . 2_777
C11 C12 H12 119.6 . .
C10 C12 H12 119.6 2_777 .
O6 C13 O7 121.3(3) . .
O6 C13 C14 120.5(3) . .
O7 C13 C14 118.1(3) . .
C16 C14 C15 119.3(3) . .
C16 C14 C13 120.5(3) . .
C15 C14 C13 120.1(3) . .
C18 C15 C14 120.9(3) 2_756 .
C18 C15 H15 119.5 2_756 .
C14 C15 H15 119.5 . .
C14 C16 C17 121.6(3) . .
C14 C16 H16 119.2 . .
C17 C16 H16 119.2 . .
C18 C17 C16 122.4(3) . .
C18 C17 C17 119.0(4) . 2_756
C16 C17 C17 118.6(4) . 2_756
C15 C18 C17 120.6(3) 2_756 .
C15 C18 H18 119.7 2_756 .
C17 C18 H18 119.7 . .
O5 C19 O4 126.2(3) . .
O5 C19 C20 116.9(3) . .
O4 C19 C20 116.9(3) . .
C22 C20 C21 119.8(3) . .
C22 C20 C19 120.2(3) . .
C21 C20 C19 120.0(3) . .
C24 C21 C20 120.5(3) 2_657 .
C24 C21 H21 119.8 2_657 .
C20 C21 H21 119.8 . .
C20 C22 C23 120.9(3) . .
C20 C22 H22 119.6 . .
C23 C22 H22 119.6 . .
C22 C23 C23 119.3(3) . 2_657
C22 C23 C24 122.3(3) . .
C23 C23 C24 118.4(3) 2_657 .
C21 C24 C23 121.1(3) 2_657 .
C21 C24 H24 119.5 2_657 .
C23 C24 H24 119.5 . .
O10 C25 H25A 109.5 . .
O10 C25 H25B 109.5 . .
H25A C25 H25B 109.5 . .
O10 C25 H25C 109.5 . .
H25A C25 H25C 109.5 . .
H25B C25 H25C 109.5 . .
C2 N1 C5 112.4(4) . .
C2 N1 C4 112.6(4) . .
C5 N1 C4 111.1(4) . .
C2 N1 Co2 109.1(2) . .
C5 N1 Co2 104.1(2) . .
C4 N1 Co2 107.1(2) . .
C3 O1 Co2 116.1(2) . .
C3 O1 H01 115(2) . .
Co2 O1 H01 103(2) . .
C1 O2 Co2 116.1(2) . .
C1 O2 H02 108(2) . .
Co2 O2 H02 128(2) . .
C6 O3 Co2 115.0(2) . .
C6 O3 Co1 125.7(2) . .
Co2 O3 Co1 118.67(10) . .
C19 O4 Co2 130.0(2) . .
C19 O5 Co1 132.5(2) . .
C13 O7 Co1 100.4(2) . .
C7 O8 Co1 86.29(17) . .
C7 O9 Co1 93.85(17) . .
C25 O10 H03 109.5 . .
O3 Co1 O5 98.92(10) . .
O3 Co1 O7 147.95(11) . .
O5 Co1 O7 93.57(11) . .
O3 Co1 O9 105.52(10) . .
O5 Co1 O9 96.83(9) . .
O7 Co1 O9 102.11(10) . .
O3 Co1 O8 92.49(9) . .
O5 Co1 O8 155.70(9) . .
O7 Co1 O8 87.81(9) . .
O9 Co1 O8 59.29(8) . .
O3 Co2 O4 104.71(9) . .
O3 Co2 O1 118.70(11) . .
O4 Co2 O1 97.87(10) . .
O3 Co2 O2 127.50(11) . .
O4 Co2 O2 92.81(10) . .
O1 Co2 O2 106.86(11) . .
O3 Co2 N1 83.49(10) . .
O4 Co2 N1 171.34(10) . .
O1 Co2 N1 80.21(11) . .
O2 Co2 N1 79.78(10) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C1 O2 1.423(4) .
C1 C2 1.470(6) .
C1 H1A 0.9700 .
C1 H1B 0.9700 .
C2 N1 1.455(5) .
C2 H2A 0.9700 .
C2 H2B 0.9700 .
C3 O1 1.421(5) .
C3 C4 1.474(6) .
C3 H3A 0.9700 .
C3 H3B 0.9700 .
C4 N1 1.464(5) .
C4 H4A 0.9700 .
C4 H4B 0.9700 .
C5 N1 1.459(5) .
C5 C6 1.464(6) .
C5 H5A 0.9700 .
C5 H5B 0.9700 .
C6 O3 1.416(4) .
C6 H6A 0.9700 .
C6 H6B 0.9700 .
C7 O8 1.236(4) .
C7 O9 1.271(3) .
C7 C8 1.509(4) .
C8 C9 1.364(4) .
C8 C11 1.416(4) .
C9 C10 1.422(4) .
C9 H9 0.9300 .
C10 C12 1.408(4) 2_777
C10 C10 1.423(6) 2_777
C11 C12 1.366(4) .
C11 H11 0.9300 .
C12 C10 1.408(4) 2_777
C12 H12 0.9300 .
C13 O6 1.238(5) .
C13 O7 1.252(4) .
C13 C14 1.512(4) .
C14 C16 1.364(5) .
C14 C15 1.413(5) .
C15 C18 1.368(5) 2_756
C15 H15 0.9300 .
C16 C17 1.418(4) .
C16 H16 0.9300 .
C17 C18 1.413(5) .
C17 C17 1.418(6) 2_756
C18 C15 1.368(5) 2_756
C18 H18 0.9300 .
C19 O5 1.252(4) .
C19 O4 1.253(4) .
C19 C20 1.508(4) .
C20 C22 1.365(4) .
C20 C21 1.410(4) .
C21 C24 1.360(4) 2_657
C21 H21 0.9300 .
C22 C23 1.413(4) .
C22 H22 0.9300 .
C23 C23 1.414(6) 2_657
C23 C24 1.417(4) .
C24 C21 1.360(4) 2_657
C24 H24 0.9300 .
C25 O10 1.356(6) .
C25 H25A 0.9600 .
C25 H25B 0.9600 .
C25 H25C 0.9600 .
N1 Co2 2.155(3) .
O1 Co2 2.032(2) .
O1 H01 0.892(10) .
O2 Co2 2.035(2) .
O2 H02 0.893(10) .
O3 Co2 1.945(2) .
O3 Co1 1.964(2) .
O4 Co2 1.981(2) .
O5 Co1 2.029(2) .
O7 Co1 2.058(2) .
O8 Co1 2.287(2) .
O9 Co1 2.102(2) .
O10 H03 0.8200 .
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
O1 H01 O10 0.892(10) 1.666(14) 2.542(4) 167(4) .
O10 H03 O6 0.82 1.93 2.680(5) 150.8 .
O2 H02 O9 0.893(10) 1.751(11) 2.643(3) 176(4) 2_667
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O2 C1 C2 N1 -37.5(7) . .
O1 C3 C4 N1 -37.8(6) . .
N1 C5 C6 O3 -35.5(6) . .
O8 C7 C8 C9 8.6(4) . .
O9 C7 C8 C9 -171.1(3) . .
O8 C7 C8 C11 -172.4(3) . .
O9 C7 C8 C11 7.9(4) . .
C11 C8 C9 C10 -1.5(5) . .
C7 C8 C9 C10 177.5(3) . .
C8 C9 C10 C12 -178.8(3) . 2_777
C8 C9 C10 C10 0.7(5) . 2_777
C9 C8 C11 C12 1.1(5) . .
C7 C8 C11 C12 -177.9(3) . .
C8 C11 C12 C10 0.1(5) . 2_777
O6 C13 C14 C16 -170.3(3) . .
O7 C13 C14 C16 8.4(5) . .
O6 C13 C14 C15 5.8(5) . .
O7 C13 C14 C15 -175.6(3) . .
C16 C14 C15 C18 0.7(5) . 2_756
C13 C14 C15 C18 -175.4(3) . 2_756
C15 C14 C16 C17 -1.0(5) . .
C13 C14 C16 C17 175.1(3) . .
C14 C16 C17 C18 -178.5(3) . .
C14 C16 C17 C17 -0.1(5) . 2_756
C16 C17 C18 C15 -179.7(3) . 2_756
C17 C17 C18 C15 1.9(6) 2_756 2_756
O5 C19 C20 C22 168.6(3) . .
O4 C19 C20 C22 -11.0(4) . .
O5 C19 C20 C21 -11.1(4) . .
O4 C19 C20 C21 169.2(3) . .
C22 C20 C21 C24 -1.9(5) . 2_657
C19 C20 C21 C24 177.9(3) . 2_657
C21 C20 C22 C23 0.8(5) . .
C19 C20 C22 C23 -179.0(3) . .
C20 C22 C23 C23 0.2(5) . 2_657
C20 C22 C23 C24 -180.0(3) . .
C22 C23 C24 C21 -178.9(3) . 2_657
C23 C23 C24 C21 0.9(5) 2_657 2_657
C1 C2 N1 C5 -88.4(5) . .
C1 C2 N1 C4 145.3(5) . .
C1 C2 N1 Co2 26.5(6) . .
C6 C5 N1 C2 150.2(4) . .
C6 C5 N1 C4 -82.7(5) . .
C6 C5 N1 Co2 32.3(5) . .
C3 C4 N1 C2 -83.2(5) . .
C3 C4 N1 C5 149.8(4) . .
C3 C4 N1 Co2 36.7(5) . .
C4 C3 O1 Co2 19.3(5) . .
C2 C1 O2 Co2 30.7(5) . .
C5 C6 O3 Co2 18.7(5) . .
C5 C6 O3 Co1 -170.1(3) . .
O5 C19 O4 Co2 -14.5(5) . .
C20 C19 O4 Co2 165.2(2) . .
O4 C19 O5 Co1 -14.7(5) . .
C20 C19 O5 Co1 165.6(2) . .
O6 C13 O7 Co1 11.9(4) . .
C14 C13 O7 Co1 -166.7(2) . .
O9 C7 O8 Co1 2.3(3) . .
C8 C7 O8 Co1 -177.3(3) . .
O8 C7 O9 Co1 -2.5(3) . .
C8 C7 O9 Co1 177.1(2) . .
C6 O3 Co1 O5 164.4(3) . .
Co2 O3 Co1 O5 -24.68(15) . .
C6 O3 Co1 O7 -83.9(3) . .
Co2 O3 Co1 O7 87.0(2) . .
C6 O3 Co1 O9 64.7(3) . .
Co2 O3 Co1 O9 -124.38(13) . .
C6 O3 Co1 O8 5.9(3) . .
Co2 O3 Co1 O8 176.84(13) . .
C19 O5 Co1 O3 33.3(3) . .
C19 O5 Co1 O7 -117.1(3) . .
C19 O5 Co1 O9 140.2(3) . .
C19 O5 Co1 O8 150.3(3) . .
C13 O7 Co1 O3 -34.8(3) . .
C13 O7 Co1 O5 78.3(2) . .
C13 O7 Co1 O9 176.1(2) . .
C13 O7 Co1 O8 -125.9(2) . .
C7 O9 Co1 O3 -82.17(19) . .
C7 O9 Co1 O5 176.56(18) . .
C7 O9 Co1 O7 81.41(19) . .
C7 O9 Co1 O8 1.37(17) . .
C7 O8 Co1 O3 105.19(19) . .
C7 O8 Co1 O5 -13.1(3) . .
C7 O8 Co1 O7 -106.88(19) . .
C7 O8 Co1 O9 -1.41(17) . .
C6 O3 Co2 O4 -177.5(3) . .
Co1 O3 Co2 O4 10.64(16) . .
C6 O3 Co2 O1 74.8(3) . .
Co1 O3 Co2 O1 -97.13(15) . .
C6 O3 Co2 O2 -72.1(3) . .
Co1 O3 Co2 O2 116.03(14) . .
C6 O3 Co2 N1 -0.3(3) . .
Co1 O3 Co2 N1 -172.20(15) . .
C19 O4 Co2 O3 14.4(3) . .
C19 O4 Co2 O1 136.9(3) . .
C19 O4 Co2 O2 -115.6(3) . .
C19 O4 Co2 N1 -146.5(6) . .
C3 O1 Co2 O3 -76.2(3) . .
C3 O1 Co2 O4 172.2(3) . .
C3 O1 Co2 O2 76.8(3) . .
C3 O1 Co2 N1 0.7(3) . .
C1 O2 Co2 O3 60.3(3) . .
C1 O2 Co2 O4 171.3(3) . .
C1 O2 Co2 O1 -89.6(3) . .
C1 O2 Co2 N1 -13.2(3) . .
C2 N1 Co2 O3 -137.4(4) . .
C5 N1 Co2 O3 -17.2(3) . .
C4 N1 Co2 O3 100.5(3) . .
C2 N1 Co2 O4 24.0(9) . .
C5 N1 Co2 O4 144.2(7) . .
C4 N1 Co2 O4 -98.1(7) . .
C2 N1 Co2 O1 101.9(4) . .
C5 N1 Co2 O1 -137.9(3) . .
C4 N1 Co2 O1 -20.2(3) . .
C2 N1 Co2 O2 -7.4(3) . .
C5 N1 Co2 O2 112.8(3) . .
C4 N1 Co2 O2 -129.5(3) . .
