#------------------------------------------------------------------------------
#$Date: 2016-06-16 09:53:48 +0300 (Thu, 16 Jun 2016) $
#$Revision: 183529 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/22/55/7225558.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7225558
loop_
_publ_author_name
'Mahmoudi, Ghodrat'
'Stilinovic, Vladimir'
'Bauza, Antonio'
'Frontera, Antonio'
'Bartyzel, Agata'
'Ruiz-Perez, Catalina'
'Kirillov, Alexander M.'
_publ_section_title
;
 Inorganic-Organic Hybrid Materials Based on PbBr2 and Pyridine-Hydrazone
 Blocks -- Structural and Theoretical Study
;
_journal_name_full               'RSC Adv.'
_journal_paper_doi               10.1039/C6RA13462A
_journal_year                    2016
_chemical_formula_sum            'C54 H48 Br4 N8 Pb2'
_chemical_formula_weight         1543.00
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_audit_update_record
;
2015-11-04 deposited with the CCDC.
2016-06-15 downloaded from the CCDC.
;
_cell_angle_alpha                94.099(1)
_cell_angle_beta                 103.293(1)
_cell_angle_gamma                105.080(2)
_cell_formula_units_Z            1
_cell_length_a                   10.1876(4)
_cell_length_b                   10.6582(4)
_cell_length_c                   12.8044(5)
_cell_measurement_reflns_used    7853
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      31.15
_cell_measurement_theta_min      2.34
_cell_volume                     1293.66(9)
_computing_cell_refinement       'Apex2 v2009.7-0'
_computing_data_collection       'Apex2 v2009.7-0 (Bruker, 2009)'
_computing_data_reduction        'Apex2 v2009.7-0'
_computing_molecular_graphics    'SHELXTL 6.14'
_computing_publication_material  'SHELXTL 6.14'
_computing_structure_refinement  'SHELXTL 6.14'
_computing_structure_solution
'SHELXTL 6.14 (Bruker, 2000-2003; Sheldrick, 2008)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.991
_diffrn_measured_fraction_theta_max 0.896
_diffrn_measurement_device_type  'Bruker AXS SMART APEX CCD diffractometer'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0268
_diffrn_reflns_av_sigmaI/netI    0.0387
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            15494
_diffrn_reflns_theta_full        28.00
_diffrn_reflns_theta_max         31.37
_diffrn_reflns_theta_min         1.65
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    9.632
_exptl_absorpt_correction_T_max  0.7463
_exptl_absorpt_correction_T_min  0.3595
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'Apex2  v2009.7-0 (Bruker, 2009)'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.981
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             732
_exptl_crystal_size_max          0.513
_exptl_crystal_size_mid          0.388
_exptl_crystal_size_min          0.182
_refine_diff_density_max         1.865
_refine_diff_density_min         -1.744
_refine_diff_density_rms         0.139
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.024
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     307
_refine_ls_number_reflns         7630
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.024
_refine_ls_R_factor_all          0.0301
_refine_ls_R_factor_gt           0.0252
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0276P)²+0.7822P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0597
_refine_ls_wR_factor_ref         0.0614
_reflns_number_gt                6865
_reflns_number_total             8524
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            c6ra13462a1.cif
_cod_data_source_block           1
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 4268 2015-11-12 08:31:59Z antanas 
;
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7225558
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Br1 Br 0.59911(3) 0.92015(3) 0.40638(3) 0.02771(7) Uani 1 1 d .
Br2 Br 0.19959(3) 0.61852(3) 0.24527(3) 0.02843(7) Uani 1 1 d .
C1 C 0.5206(3) 0.6484(3) 0.5760(3) 0.0219(6) Uani 1 1 d .
H1 H 0.5673 0.6747 0.5215 0.026 Uiso 1 1 calc R
C2 C 0.5678(3) 0.5643(3) 0.6426(3) 0.0232(6) Uani 1 1 d .
H2 H 0.6458 0.5347 0.6348 0.028 Uiso 1 1 calc R
C3 C 0.4991(3) 0.5243(3) 0.7206(3) 0.0231(6) Uani 1 1 d .
H3 H 0.5258 0.4631 0.7654 0.028 Uiso 1 1 calc R
C4 C 0.3900(3) 0.5749(3) 0.7327(2) 0.0201(6) Uani 1 1 d .
H4 H 0.3435 0.5514 0.7878 0.024 Uiso 1 1 calc R
C5 C 0.3500(3) 0.6601(3) 0.6634(2) 0.0162(5) Uani 1 1 d .
C6 C 0.2354(3) 0.7204(3) 0.6740(2) 0.0161(5) Uani 1 1 d .
C7 C 0.2219(3) 0.7465(3) 0.7869(2) 0.0169(5) Uani 1 1 d .
C8 C 0.3099(3) 0.8601(3) 0.8528(3) 0.0224(6) Uani 1 1 d .
H8 H 0.3748 0.9209 0.8250 0.027 Uiso 1 1 calc R
C9 C 0.3037(4) 0.8855(4) 0.9588(3) 0.0297(7) Uani 1 1 d .
H9 H 0.3627 0.9644 1.0031 0.036 Uiso 1 1 calc R
C10 C 0.2115(4) 0.7956(4) 1.0000(3) 0.0316(8) Uani 1 1 d .
H10 H 0.2091 0.8112 1.0735 0.038 Uiso 1 1 calc R
C11 C 0.1232(4) 0.6838(3) 0.9346(3) 0.0342(8) Uani 1 1 d .
H11 H 0.0592 0.6228 0.9630 0.041 Uiso 1 1 calc R
C12 C 0.1263(4) 0.6587(3) 0.8278(3) 0.0300(7) Uani 1 1 d .
H12 H 0.0633 0.5820 0.7827 0.036 Uiso 1 1 calc R
C13 C 0.0576(3) 0.8182(4) 0.5944(3) 0.0247(7) Uani 1 1 d .
H13A H 0.0892 0.9090 0.5782 0.030 Uiso 1 1 calc R
H13B H 0.0439 0.8229 0.6685 0.030 Uiso 1 1 calc R
C14 C -0.0818(3) 0.7446(4) 0.5129(3) 0.0287(7) Uani 1 1 d .
H14A H -0.1258 0.6647 0.5415 0.034 Uiso 1 1 calc R
H14B H -0.1459 0.8009 0.5067 0.034 Uiso 1 1 calc R
C15 C -0.0680(3) 0.7045(4) 0.4005(2) 0.0259(7) Uani 1 1 d .
H15A H -0.0279 0.6292 0.4020 0.031 Uiso 1 1 calc R
H15B H -0.1624 0.6760 0.3490 0.031 Uiso 1 1 calc R
C16 C -0.0157(3) 0.8436(3) 0.2689(2) 0.0176(5) Uani 1 1 d .
C17 C -0.1528(3) 0.7783(3) 0.1868(2) 0.0173(5) Uani 1 1 d .
C18 C -0.1573(3) 0.6824(3) 0.1065(3) 0.0235(6) Uani 1 1 d .
H18 H -0.0752 0.6566 0.1049 0.028 Uiso 1 1 calc R
C19 C -0.2825(4) 0.6238(3) 0.0279(3) 0.0299(7) Uani 1 1 d .
H19 H -0.2861 0.5578 -0.0275 0.036 Uiso 1 1 calc R
C20 C -0.4015(4) 0.6615(4) 0.0305(3) 0.0316(8) Uani 1 1 d .
H20 H -0.4865 0.6227 -0.0241 0.038 Uiso 1 1 calc R
C21 C -0.3978(4) 0.7551(4) 0.1117(3) 0.0330(8) Uani 1 1 d .
H21 H -0.4806 0.7795 0.1140 0.040 Uiso 1 1 calc R
C22 C -0.2731(3) 0.8140(4) 0.1903(3) 0.0280(7) Uani 1 1 d .
H22 H -0.2704 0.8787 0.2464 0.034 Uiso 1 1 calc R
C23 C 0.0848(3) 0.9500(3) 0.2329(2) 0.0167(5) Uani 1 1 d .
C24 C 0.0391(3) 1.0222(3) 0.1536(3) 0.0219(6) Uani 1 1 d .
H24 H -0.0584 1.0056 0.1205 0.026 Uiso 1 1 calc R
C25 C 0.1373(4) 1.1185(3) 0.1232(3) 0.0267(7) Uani 1 1 d .
H25 H 0.1080 1.1700 0.0698 0.032 Uiso 1 1 calc R
C26 C 0.2791(4) 1.1393(3) 0.1716(3) 0.0264(7) Uani 1 1 d .
H26 H 0.3487 1.2040 0.1513 0.032 Uiso 1 1 calc R
C27 C 0.3168(3) 1.0631(3) 0.2504(3) 0.0215(6) Uani 1 1 d .
H27 H 0.4139 1.0767 0.2834 0.026 Uiso 1 1 calc R
N1 N 0.4129(3) 0.6948(2) 0.5840(2) 0.0180(5) Uani 1 1 d .
N2 N 0.1653(3) 0.7516(3) 0.5893(2) 0.0197(5) Uani 1 1 d .
N3 N 0.0226(3) 0.8132(3) 0.3629(2) 0.0207(5) Uani 1 1 d .
N4 N 0.2228(3) 0.9717(2) 0.2818(2) 0.0178(5) Uani 1 1 d .
Pb1 Pb 0.298495(10) 0.827785(11) 0.429549(8) 0.01677(4) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Br Br -0.2901 2.4595 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pb Pb -3.3944 10.1111 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_3
Pb1 Br1 Pb1 98.018(9) 2_676
N1 C1 C2 123.6(3) .
N1 C1 H1 118.2 .
C2 C1 H1 118.2 .
C3 C2 C1 118.4(3) .
C3 C2 H2 120.8 .
C1 C2 H2 120.8 .
C2 C3 C4 118.9(3) .
C2 C3 H3 120.5 .
C4 C3 H3 120.5 .
C5 C4 C3 119.2(3) .
C5 C4 H4 120.4 .
C3 C4 H4 120.4 .
N1 C5 C4 122.0(3) .
N1 C5 C6 116.2(2) .
C4 C5 C6 121.7(3) .
N2 C6 C5 118.2(3) .
N2 C6 C7 126.2(3) .
C5 C6 C7 115.5(2) .
C8 C7 C12 119.5(3) .
C8 C7 C6 118.8(3) .
C12 C7 C6 121.8(3) .
C9 C8 C7 120.5(3) .
C9 C8 H8 119.8 .
C7 C8 H8 119.8 .
C10 C9 C8 119.7(3) .
C10 C9 H9 120.1 .
C8 C9 H9 120.1 .
C11 C10 C9 119.9(3) .
C11 C10 H10 120.1 .
C9 C10 H10 120.1 .
C10 C11 C12 120.9(3) .
C10 C11 H11 119.6 .
C12 C11 H11 119.6 .
C11 C12 C7 119.5(3) .
C11 C12 H12 120.2 .
C7 C12 H12 120.2 .
N2 C13 C14 110.5(3) .
N2 C13 H13A 109.5 .
C14 C13 H13A 109.5 .
N2 C13 H13B 109.5 .
C14 C13 H13B 109.5 .
H13A C13 H13B 108.1 .
C15 C14 C13 114.4(3) .
C15 C14 H14A 108.7 .
C13 C14 H14A 108.7 .
C15 C14 H14B 108.7 .
C13 C14 H14B 108.7 .
H14A C14 H14B 107.6 .
N3 C15 C14 111.4(3) .
N3 C15 H15A 109.4 .
C14 C15 H15A 109.4 .
N3 C15 H15B 109.4 .
C14 C15 H15B 109.4 .
H15A C15 H15B 108.0 .
N3 C16 C23 118.4(3) .
N3 C16 C17 125.9(3) .
C23 C16 C17 115.7(2) .
C22 C17 C18 120.1(3) .
C22 C17 C16 120.9(3) .
C18 C17 C16 119.0(3) .
C17 C18 C19 119.7(3) .
C17 C18 H18 120.1 .
C19 C18 H18 120.1 .
C20 C19 C18 120.0(3) .
C20 C19 H19 120.0 .
C18 C19 H19 120.0 .
C21 C20 C19 120.3(3) .
C21 C20 H20 119.8 .
C19 C20 H20 119.8 .
C20 C21 C22 120.0(3) .
C20 C21 H21 120.0 .
C22 C21 H21 120.0 .
C17 C22 C21 119.9(3) .
C17 C22 H22 120.0 .
C21 C22 H22 120.0 .
N4 C23 C24 121.8(3) .
N4 C23 C16 116.3(3) .
C24 C23 C16 121.9(3) .
C25 C24 C23 119.1(3) .
C25 C24 H24 120.4 .
C23 C24 H24 120.4 .
C24 C25 C26 119.2(3) .
C24 C25 H25 120.4 .
C26 C25 H25 120.4 .
C25 C26 C27 118.4(3) .
C25 C26 H26 120.8 .
C27 C26 H26 120.8 .
N4 C27 C26 122.9(3) .
N4 C27 H27 118.6 .
C26 C27 H27 118.6 .
C1 N1 C5 117.8(3) .
C1 N1 Pb1 121.7(2) .
C5 N1 Pb1 119.98(18) .
C6 N2 C13 121.3(3) .
C6 N2 Pb1 118.34(19) .
C13 N2 Pb1 111.81(18) .
C16 N3 C15 120.9(3) .
C16 N3 Pb1 114.95(19) .
C15 N3 Pb1 112.91(19) .
C27 N4 C23 118.6(3) .
C27 N4 Pb1 121.9(2) .
C23 N4 Pb1 119.44(19) .
N4 Pb1 N3 61.97(8) .
N4 Pb1 N1 172.49(7) .
N3 Pb1 N1 125.49(8) .
N4 Pb1 N2 125.93(8) .
N3 Pb1 N2 69.83(7) .
N1 Pb1 N2 60.20(7) .
N4 Pb1 Br2 83.45(5) .
N3 Pb1 Br2 78.05(6) .
N1 Pb1 Br2 98.70(5) .
N2 Pb1 Br2 109.71(6) .
N4 Pb1 Br1 89.07(6) .
N3 Pb1 Br1 150.71(5) .
N1 Pb1 Br1 83.57(5) .
N2 Pb1 Br1 137.93(5) .
Br2 Pb1 Br1 95.366(10) .
N4 Pb1 Br1 86.98(5) 2_676
N3 Pb1 Br1 99.60(6) 2_676
N1 Pb1 Br1 90.49(5) 2_676
N2 Pb1 Br1 78.01(6) 2_676
Br2 Pb1 Br1 170.122(10) 2_676
Br1 Pb1 Br1 81.981(10) 2_676
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Br1 Pb1 3.0541(3) .
Br1 Pb1 3.0735(4) 2_676
Br2 Pb1 2.9228(4) .
C1 N1 1.337(4) .
C1 C2 1.381(4) .
C1 H1 0.9500 .
C2 C3 1.377(5) .
C2 H2 0.9500 .
C3 C4 1.388(4) .
C3 H3 0.9500 .
C4 C5 1.385(4) .
C4 H4 0.9500 .
C5 N1 1.346(4) .
C5 C6 1.498(4) .
C6 N2 1.271(4) .
C6 C7 1.498(4) .
C7 C8 1.386(4) .
C7 C12 1.389(4) .
C8 C9 1.384(4) .
C8 H8 0.9500 .
C9 C10 1.383(5) .
C9 H9 0.9500 .
C10 C11 1.373(5) .
C10 H10 0.9500 .
C11 C12 1.383(5) .
C11 H11 0.9500 .
C12 H12 0.9500 .
C13 N2 1.464(4) .
C13 C14 1.531(5) .
C13 H13A 0.9900 .
C13 H13B 0.9900 .
C14 C15 1.521(5) .
C14 H14A 0.9900 .
C14 H14B 0.9900 .
C15 N3 1.468(4) .
C15 H15A 0.9900 .
C15 H15B 0.9900 .
C16 N3 1.270(4) .
C16 C23 1.495(4) .
C16 C17 1.502(4) .
C17 C22 1.384(4) .
C17 C18 1.381(4) .
C18 C19 1.391(4) .
C18 H18 0.9500 .
C19 C20 1.380(5) .
C19 H19 0.9500 .
C20 C21 1.376(6) .
C20 H20 0.9500 .
C21 C22 1.388(5) .
C21 H21 0.9500 .
C22 H22 0.9500 .
C23 N4 1.352(4) .
C23 C24 1.386(4) .
C24 C25 1.381(5) .
C24 H24 0.9500 .
C25 C26 1.386(5) .
C25 H25 0.9500 .
C26 C27 1.388(4) .
C26 H26 0.9500 .
C27 N4 1.332(4) .
C27 H27 0.9500 .
N1 Pb1 2.734(2) .
N2 Pb1 2.761(2) .
N3 Pb1 2.702(2) .
N4 Pb1 2.624(2) .
Pb1 Br1 3.0735(4) 2_676
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
N1 C1 C2 C3 1.0(5) . .
C1 C2 C3 C4 -3.1(5) . .
C2 C3 C4 C5 2.4(4) . .
C3 C4 C5 N1 0.5(4) . .
C3 C4 C5 C6 -178.6(3) . .
N1 C5 C6 N2 28.9(4) . .
C4 C5 C6 N2 -152.0(3) . .
N1 C5 C6 C7 -147.1(3) . .
C4 C5 C6 C7 32.1(4) . .
N2 C6 C7 C8 -93.2(4) . .
C5 C6 C7 C8 82.4(3) . .
N2 C6 C7 C12 88.4(4) . .
C5 C6 C7 C12 -96.1(4) . .
C12 C7 C8 C9 0.7(5) . .
C6 C7 C8 C9 -177.9(3) . .
C7 C8 C9 C10 1.4(5) . .
C8 C9 C10 C11 -2.1(5) . .
C9 C10 C11 C12 0.7(6) . .
C10 C11 C12 C7 1.4(6) . .
C8 C7 C12 C11 -2.1(5) . .
C6 C7 C12 C11 176.4(3) . .
N2 C13 C14 C15 -46.3(4) . .
C13 C14 C15 N3 -46.3(4) . .
N3 C16 C17 C22 83.3(4) . .
C23 C16 C17 C22 -99.2(3) . .
N3 C16 C17 C18 -97.3(4) . .
C23 C16 C17 C18 80.2(4) . .
C22 C17 C18 C19 1.3(5) . .
C16 C17 C18 C19 -178.1(3) . .
C17 C18 C19 C20 0.0(5) . .
C18 C19 C20 C21 -1.3(5) . .
C19 C20 C21 C22 1.3(5) . .
C18 C17 C22 C21 -1.3(5) . .
C16 C17 C22 C21 178.1(3) . .
C20 C21 C22 C17 0.0(5) . .
N3 C16 C23 N4 24.4(4) . .
C17 C16 C23 N4 -153.3(3) . .
N3 C16 C23 C24 -155.8(3) . .
C17 C16 C23 C24 26.5(4) . .
N4 C23 C24 C25 0.4(5) . .
C16 C23 C24 C25 -179.5(3) . .
C23 C24 C25 C26 1.0(5) . .
C24 C25 C26 C27 -1.0(5) . .
C25 C26 C27 N4 -0.4(5) . .
C2 C1 N1 C5 1.9(5) . .
C2 C1 N1 Pb1 -169.9(2) . .
C4 C5 N1 C1 -2.7(4) . .
C6 C5 N1 C1 176.5(3) . .
C4 C5 N1 Pb1 169.3(2) . .
C6 C5 N1 Pb1 -11.6(3) . .
C5 C6 N2 C13 -176.2(3) . .
C7 C6 N2 C13 -0.8(5) . .
C5 C6 N2 Pb1 -31.0(3) . .
C7 C6 N2 Pb1 144.4(2) . .
C14 C13 N2 C6 -127.4(3) . .
C14 C13 N2 Pb1 85.3(3) . .
C23 C16 N3 C15 -176.4(3) . .
C17 C16 N3 C15 1.0(5) . .
C23 C16 N3 Pb1 -35.2(3) . .
C17 C16 N3 Pb1 142.2(2) . .
C14 C15 N3 C16 -131.9(3) . .
C14 C15 N3 Pb1 86.2(3) . .
C26 C27 N4 C23 1.7(5) . .
C26 C27 N4 Pb1 179.3(2) . .
C24 C23 N4 C27 -1.7(4) . .
C16 C23 N4 C27 178.2(3) . .
C24 C23 N4 Pb1 -179.3(2) . .
C16 C23 N4 Pb1 0.5(3) . .
C27 N4 Pb1 N3 170.8(3) . .
C23 N4 Pb1 N3 -11.66(19) . .
C27 N4 Pb1 N2 141.0(2) . .
C23 N4 Pb1 N2 -41.4(2) . .
C27 N4 Pb1 Br2 -109.3(2) . .
C23 N4 Pb1 Br2 68.3(2) . .
C27 N4 Pb1 Br1 -13.8(2) . .
C23 N4 Pb1 Br1 163.8(2) . .
C27 N4 Pb1 Br1 68.2(2) . 2_676
C23 N4 Pb1 Br1 -114.2(2) . 2_676
C16 N3 Pb1 N4 24.4(2) . .
C15 N3 Pb1 N4 168.7(2) . .
C16 N3 Pb1 N1 -156.7(2) . .
C15 N3 Pb1 N1 -12.5(2) . .
C16 N3 Pb1 N2 179.1(2) . .
C15 N3 Pb1 N2 -36.7(2) . .
C16 N3 Pb1 Br2 -64.5(2) . .
C15 N3 Pb1 Br2 79.8(2) . .
C16 N3 Pb1 Br1 15.0(3) . .
C15 N3 Pb1 Br1 159.28(16) . .
C16 N3 Pb1 Br1 105.8(2) . 2_676
C15 N3 Pb1 Br1 -110.0(2) . 2_676
C1 N1 Pb1 N3 143.8(2) . .
C5 N1 Pb1 N3 -27.8(2) . .
C1 N1 Pb1 N2 170.1(3) . .
C5 N1 Pb1 N2 -1.51(19) . .
C1 N1 Pb1 Br2 62.3(2) . .
C5 N1 Pb1 Br2 -109.3(2) . .
C1 N1 Pb1 Br1 -32.2(2) . .
C5 N1 Pb1 Br1 156.2(2) . .
C1 N1 Pb1 Br1 -114.1(2) . 2_676
C5 N1 Pb1 Br1 74.3(2) . 2_676
C6 N2 Pb1 N4 -157.5(2) . .
C13 N2 Pb1 N4 -9.1(2) . .
C6 N2 Pb1 N3 174.7(2) . .
C13 N2 Pb1 N3 -36.92(19) . .
C6 N2 Pb1 N1 17.4(2) . .
C13 N2 Pb1 N1 165.7(2) . .
C6 N2 Pb1 Br2 106.2(2) . .
C13 N2 Pb1 Br2 -105.45(19) . .
C6 N2 Pb1 Br1 -16.8(3) . .
C13 N2 Pb1 Br1 131.50(17) . .
C6 N2 Pb1 Br1 -80.2(2) . 2_676
C13 N2 Pb1 Br1 68.13(19) . 2_676
Pb1 Br1 Pb1 N4 87.08(5) 2_676 .
Pb1 Br1 Pb1 N3 95.35(12) 2_676 .
Pb1 Br1 Pb1 N1 -91.41(5) 2_676 .
Pb1 Br1 Pb1 N2 -62.01(8) 2_676 .
Pb1 Br1 Pb1 Br2 170.418(10) 2_676 .
Pb1 Br1 Pb1 Br1 0.0 2_676 2_676
