#------------------------------------------------------------------------------
#$Date: 2017-01-13 08:13:25 +0200 (Fri, 13 Jan 2017) $
#$Revision: 190462 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/22/74/7227427.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7227427
loop_
_publ_author_name
'Zhao, Meng'
'Yao, Zhao-Quan'
'Xu, Yue-Ling'
'Chang, Ze'
'Bu, Xian-He'
_publ_section_title
;
 Guest dependent structure and acetone sensing properties of a 2D Eu3+
 coordination polymer
;
_journal_issue                   4
_journal_name_full               'RSC Adv.'
_journal_page_first              2258
_journal_paper_doi               10.1039/C6RA25681C
_journal_volume                  7
_journal_year                    2017
_chemical_formula_sum            'C30 H22 Eu N O9'
_chemical_formula_weight         692.45
_chemical_name_systematic
;
 ?
;
_chemical_properties_physical    ', Light-sensitive'
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_audit_block_doi                 10.5517/ccdc.csd.cc1lmnrm
_audit_creation_method           SHELXL-2014
_audit_update_record
;
2016-08-25 deposited with the CCDC.
2016-12-01 downloaded from the CCDC.
;
_cell_angle_alpha                104.260(4)
_cell_angle_beta                 96.594(2)
_cell_angle_gamma                97.594(3)
_cell_formula_units_Z            2
_cell_length_a                   9.5960(15)
_cell_length_b                   13.277(2)
_cell_length_c                   15.277(3)
_cell_measurement_reflns_used    6283
_cell_measurement_temperature    113
_cell_measurement_theta_max      27.5
_cell_measurement_theta_min      3.1
_cell_volume                     1847.7(5)
_computing_structure_refinement  'SHELXL-2014 (Sheldrick, 2014)'
_diffrn_ambient_temperature      113
_diffrn_measured_fraction_theta_full 0.988
_diffrn_measured_fraction_theta_max 0.969
_diffrn_measurement_device_type  Rigaku
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0243
_diffrn_reflns_av_unetI/netI     0.0248
_diffrn_reflns_Laue_measured_fraction_full 0.988
_diffrn_reflns_Laue_measured_fraction_max 0.969
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            23534
_diffrn_reflns_point_group_measured_fraction_full 0.988
_diffrn_reflns_point_group_measured_fraction_max 0.969
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.633
_diffrn_reflns_theta_min         3.142
_exptl_absorpt_coefficient_mu    1.740
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.245
_exptl_crystal_description       prism
_exptl_crystal_F_000             688
_exptl_crystal_preparation       ', Luminescent'
_refine_diff_density_max         3.279
_refine_diff_density_min         -1.491
_refine_diff_density_rms         0.126
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.057
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     372
_refine_ls_number_reflns         8351
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.057
_refine_ls_R_factor_all          0.0381
_refine_ls_R_factor_gt           0.0359
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0600P)²+4.2960P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0988
_refine_ls_wR_factor_ref         0.0999
_reflns_Friedel_coverage         0.000
_reflns_number_gt                7766
_reflns_number_total             8351
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c6ra25681c2.cif
_cod_data_source_block           1_sqd
_cod_database_code               7227427
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelxl_version_number           2014-3
_platon_squeeze_void_probe_radius 1.20
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
C14 C 1.1742(4) 0.4048(3) 0.3758(2) 0.0197(6) Uani 1 1 d . .
C15 C 0.9891(4) 0.5221(3) 0.3714(2) 0.0218(7) Uani 1 1 d . .
H15 H 0.9865 0.5285 0.4332 0.026 Uiso 1 1 calc R U
C16 C 0.9024(4) 0.5735(3) 0.3242(2) 0.0219(7) Uani 1 1 d . .
H16 H 0.8400 0.6124 0.3544 0.026 Uiso 1 1 calc R U
C17 C 1.0798(4) 0.4607(3) 0.3262(2) 0.0203(6) Uani 1 1 d . .
C18 C 1.0845(4) 0.4530(3) 0.2338(2) 0.0234(7) Uani 1 1 d . .
H18 H 1.1434 0.4113 0.2028 0.028 Uiso 1 1 calc R U
C19 C 1.0015(4) 0.5076(3) 0.1884(2) 0.0238(7) Uani 1 1 d . .
H19 H 1.0081 0.5043 0.1275 0.029 Uiso 1 1 calc R U
Eu1 Eu 0.58983(2) 0.66352(2) -0.46056(2) 0.01738(7) Uani 1 1 d . .
O1 O 0.4991(3) 0.51603(19) -0.40438(15) 0.0206(5) Uani 1 1 d . .
O6 O 0.7886(3) 0.56032(19) -0.46248(16) 0.0214(5) Uani 1 1 d . .
O2 O 0.4445(3) 0.36191(19) -0.37629(16) 0.0238(5) Uani 1 1 d . .
O3 O 0.4843(3) 1.1602(2) 0.45984(17) 0.0294(6) Uani 1 1 d . .
O7 O 0.3316(3) 0.6425(2) -0.48685(19) 0.0294(6) Uani 1 1 d . .
O4 O 0.4568(3) 1.2075(2) 0.33154(17) 0.0274(6) Uani 1 1 d . .
O5 O 0.7781(3) 0.6731(2) -0.33127(17) 0.0240(5) Uani 1 1 d . .
O8 O 0.7906(3) 0.7773(2) -0.4853(2) 0.0372(7) Uani 1 1 d . .
C2 C 0.5636(4) 0.4410(3) -0.1920(2) 0.0207(7) Uani 1 1 d . .
H2 H 0.5473 0.3684 -0.2168 0.025 Uiso 1 1 calc R U
C8 C 0.6851(4) 0.6358(3) 0.0393(2) 0.0192(6) Uani 1 1 d . .
C3 C 0.6354(4) 0.5914(3) -0.0604(2) 0.0192(6) Uani 1 1 d . .
C1 C 0.4911(4) 0.4590(3) -0.3482(2) 0.0191(6) Uani 1 1 d . .
C4 C 0.6124(4) 0.4827(3) -0.0995(2) 0.0202(7) Uani 1 1 d . .
H4 H 0.6299 0.4377 -0.0630 0.024 Uiso 1 1 calc R U
C9 C 0.6421(4) 0.7276(3) 0.0869(2) 0.0198(6) Uani 1 1 d . .
H9 H 0.5851 0.7626 0.0553 0.024 Uiso 1 1 calc R U
C5 C 0.5388(4) 0.5070(3) -0.2482(2) 0.0185(6) Uani 1 1 d . .
C21 C 0.5364(4) 1.0439(3) 0.3258(2) 0.0213(7) Uani 1 1 d . .
C22 C 0.5560(4) 0.9638(3) 0.3678(2) 0.0237(7) Uani 1 1 d . .
H22 H 0.5383 0.9706 0.4273 0.028 Uiso 1 1 calc R U
C23 C 0.5624(4) 1.0325(3) 0.2362(2) 0.0245(7) Uani 1 1 d . .
H23 H 0.5475 1.0853 0.2076 0.029 Uiso 1 1 calc R U
C24 C 0.4898(4) 1.1427(3) 0.3759(2) 0.0219(7) Uani 1 1 d . .
C6 C 0.5623(4) 0.6157(3) -0.2102(2) 0.0244(7) Uani 1 1 d . .
H6 H 0.5463 0.6605 -0.2471 0.029 Uiso 1 1 calc R U
C7 C 0.6099(4) 0.6570(3) -0.1170(2) 0.0254(7) Uani 1 1 d . .
H7 H 0.6249 0.7296 -0.0921 0.031 Uiso 1 1 calc R U
C25 C 0.6100(4) 0.9437(3) 0.1893(2) 0.0238(7) Uani 1 1 d . .
H25 H 0.6281 0.9374 0.1298 0.029 Uiso 1 1 calc R U
C10 C 0.6832(4) 0.7679(3) 0.1813(2) 0.0191(6) Uani 1 1 d . .
C26 C 0.6309(4) 0.8633(3) 0.2312(2) 0.0197(6) Uani 1 1 d . .
C11 C 0.7716(4) 0.5849(3) 0.0876(2) 0.0211(7) Uani 1 1 d . .
H11 H 0.8006 0.5237 0.0564 0.025 Uiso 1 1 calc R U
C12 C 0.8160(4) 0.6237(3) 0.1822(2) 0.0199(6) Uani 1 1 d . .
C20 C 0.9078(4) 0.5677(3) 0.2320(2) 0.0203(7) Uani 1 1 d . .
C13 C 0.7707(4) 0.7156(3) 0.2281(2) 0.0211(7) Uani 1 1 d . .
H13 H 0.7992 0.7424 0.2908 0.025 Uiso 1 1 calc R U
C27 C 0.6023(4) 0.8735(3) 0.3206(2) 0.0230(7) Uani 1 1 d . .
H27 H 0.6141 0.8198 0.3485 0.028 Uiso 1 1 calc R U
O9 O 0.1748(8) 0.7411(5) 0.6422(6) 0.126(3) Uani 1 1 d . .
N2 N 0.1967(8) 0.7568(7) 0.8017(6) 0.103(3) Uani 1 1 d . .
C31 C 0.2355(11) 0.7109(9) 0.7254(10) 0.112(4) Uani 1 1 d . .
H31 H 0.2972 0.6621 0.7223 0.135 Uiso 1 1 calc R U
C33 C 0.0949(12) 0.8240(9) 0.8111(10) 0.146(6) Uani 1 1 d . .
H33A H 0.0713 0.8415 0.7545 0.220 Uiso 1 1 calc R U
H33B H 0.1329 0.8873 0.8585 0.220 Uiso 1 1 calc R U
H33C H 0.0109 0.7892 0.8268 0.220 Uiso 1 1 calc R U
C32 C 0.2638(14) 0.7324(16) 0.8833(10) 0.179(7) Uani 1 1 d . .
H32A H 0.3176 0.6767 0.8654 0.268 Uiso 1 1 calc R U
H32B H 0.1917 0.7105 0.9166 0.268 Uiso 1 1 calc R U
H32C H 0.3261 0.7940 0.9214 0.268 Uiso 1 1 calc R U
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O5 C14 O6 120.6(3) 2_765 2_765
O5 C14 C17 119.7(3) 2_765 .
O6 C14 C17 119.6(3) 2_765 .
O5 C14 Eu1 60.87(17) 2_765 2_765
O6 C14 Eu1 61.14(17) 2_765 2_765
C17 C14 Eu1 165.0(2) . 2_765
C16 C15 C17 120.1(3) . .
C16 C15 H15 119.9 . .
C17 C15 H15 119.9 . .
C15 C16 C20 120.9(3) . .
C15 C16 H16 119.5 . .
C20 C16 H16 119.5 . .
C15 C17 C18 119.4(3) . .
C15 C17 C14 121.0(3) . .
C18 C17 C14 119.6(3) . .
C19 C18 C17 119.9(3) . .
C19 C18 H18 120.1 . .
C17 C18 H18 120.1 . .
C18 C19 C20 121.5(3) . .
C18 C19 H19 119.2 . .
C20 C19 H19 119.2 . .
O4 Eu1 O2 135.57(9) 2_675 2_664
O4 Eu1 O8 93.93(10) 2_675 .
O2 Eu1 O8 76.24(10) 2_664 .
O4 Eu1 O1 93.55(9) 2_675 .
O2 Eu1 O1 117.13(8) 2_664 .
O8 Eu1 O1 149.07(9) . .
O4 Eu1 O7 77.85(10) 2_675 .
O2 Eu1 O7 81.57(9) 2_664 .
O8 Eu1 O7 138.24(10) . .
O1 Eu1 O7 72.68(9) . .
O4 Eu1 O5 73.44(9) 2_675 .
O2 Eu1 O5 140.81(9) 2_664 .
O8 Eu1 O5 75.97(10) . .
O1 Eu1 O5 77.53(8) . .
O7 Eu1 O5 136.77(9) . .
O4 Eu1 O6 126.15(8) 2_675 .
O2 Eu1 O6 93.49(8) 2_664 .
O8 Eu1 O6 74.96(10) . .
O1 Eu1 O6 76.41(8) . .
O7 Eu1 O6 141.96(9) . .
O5 Eu1 O6 52.71(8) . .
O4 Eu1 O3 52.89(8) 2_675 2_675
O2 Eu1 O3 83.21(8) 2_664 2_675
O8 Eu1 O3 72.01(10) . 2_675
O1 Eu1 O3 134.30(9) . 2_675
O7 Eu1 O3 70.58(10) . 2_675
O5 Eu1 O3 113.33(9) . 2_675
O6 Eu1 O3 146.64(9) . 2_675
O4 Eu1 O1 149.69(9) 2_675 2_664
O2 Eu1 O1 50.63(8) 2_664 2_664
O8 Eu1 O1 114.71(9) . 2_664
O1 Eu1 O1 67.26(9) . 2_664
O7 Eu1 O1 74.16(8) . 2_664
O5 Eu1 O1 121.32(8) . 2_664
O6 Eu1 O1 73.78(8) . 2_664
O3 Eu1 O1 125.01(8) 2_675 2_664
O4 Eu1 C24 26.55(9) 2_675 2_675
O2 Eu1 C24 109.26(9) 2_664 2_675
O8 Eu1 C24 82.73(11) . 2_675
O1 Eu1 C24 114.88(10) . 2_675
O7 Eu1 C24 71.80(10) . 2_675
O5 Eu1 C24 93.97(9) . 2_675
O6 Eu1 C24 143.26(9) . 2_675
O3 Eu1 C24 26.35(9) 2_675 2_675
O1 Eu1 C24 142.86(9) 2_664 2_675
O4 Eu1 C14 99.54(9) 2_675 2_765
O2 Eu1 C14 119.38(9) 2_664 2_765
O8 Eu1 C14 77.12(10) . 2_765
O1 Eu1 C14 72.05(9) . 2_765
O7 Eu1 C14 144.39(10) . 2_765
O5 Eu1 C14 26.32(9) . 2_765
O6 Eu1 C14 26.79(9) . 2_765
O3 Eu1 C14 135.66(10) 2_675 2_765
O1 Eu1 C14 96.50(8) 2_664 2_765
C24 Eu1 C14 119.92(10) 2_675 2_765
O4 Eu1 C1 149.66(9) 2_675 2_664
O2 Eu1 C1 24.83(9) 2_664 2_664
O8 Eu1 C1 95.95(10) . 2_664
O1 Eu1 C1 92.54(9) . 2_664
O7 Eu1 C1 75.70(9) . 2_664
O5 Eu1 C1 136.84(9) . 2_664
O6 Eu1 C1 84.15(8) . 2_664
O3 Eu1 C1 103.64(9) 2_675 2_664
O1 Eu1 C1 25.84(8) 2_664 2_664
C24 Eu1 C1 127.52(10) 2_675 2_664
C14 Eu1 C1 110.60(9) 2_765 2_664
C1 O1 Eu1 156.6(2) . .
C1 O1 Eu1 87.13(19) . 2_664
Eu1 O1 Eu1 112.73(9) . 2_664
C14 O6 Eu1 92.1(2) 2_765 .
C1 O2 Eu1 101.6(2) . 2_664
C24 O3 Eu1 90.0(2) . 2_675
C24 O4 Eu1 95.8(2) . 2_675
C14 O5 Eu1 92.80(19) 2_765 .
C4 C2 C5 120.6(3) . .
C4 C2 H2 119.7 . .
C5 C2 H2 119.7 . .
C11 C8 C9 118.7(3) . .
C11 C8 C3 120.7(3) . .
C9 C8 C3 120.5(3) . .
C7 C3 C4 118.4(3) . .
C7 C3 C8 121.0(3) . .
C4 C3 C8 120.6(3) . .
O2 C1 O1 120.5(3) . .
O2 C1 C5 119.1(3) . .
O1 C1 C5 120.4(3) . .
O2 C1 Eu1 53.62(16) . 2_664
O1 C1 Eu1 67.04(17) . 2_664
C5 C1 Eu1 171.5(2) . 2_664
C2 C4 C3 120.7(3) . .
C2 C4 H4 119.6 . .
C3 C4 H4 119.6 . .
C8 C9 C10 121.2(3) . .
C8 C9 H9 119.4 . .
C10 C9 H9 119.4 . .
C2 C5 C6 119.3(3) . .
C2 C5 C1 118.9(3) . .
C6 C5 C1 121.8(3) . .
C22 C21 C23 119.4(3) . .
C22 C21 C24 121.0(3) . .
C23 C21 C24 119.6(3) . .
C21 C22 C27 120.1(3) . .
C21 C22 H22 120.0 . .
C27 C22 H22 120.0 . .
C25 C23 C21 120.9(3) . .
C25 C23 H23 119.6 . .
C21 C23 H23 119.6 . .
O3 C24 O4 121.3(3) . .
O3 C24 C21 120.2(3) . .
O4 C24 C21 118.5(3) . .
O3 C24 Eu1 63.65(18) . 2_675
O4 C24 Eu1 57.65(17) . 2_675
C21 C24 Eu1 175.6(3) . 2_675
C7 C6 C5 119.9(3) . .
C7 C6 H6 120.1 . .
C5 C6 H6 120.1 . .
C6 C7 C3 121.1(3) . .
C6 C7 H7 119.4 . .
C3 C7 H7 119.4 . .
C23 C25 C26 120.0(3) . .
C23 C25 H25 120.0 . .
C26 C25 H25 120.0 . .
C9 C10 C13 119.0(3) . .
C9 C10 C26 120.2(3) . .
C13 C10 C26 120.8(3) . .
C25 C26 C27 119.3(3) . .
C25 C26 C10 120.2(3) . .
C27 C26 C10 120.5(3) . .
C8 C11 C12 121.6(3) . .
C8 C11 H11 119.2 . .
C12 C11 H11 119.2 . .
C13 C12 C11 118.4(3) . .
C13 C12 C20 121.1(3) . .
C11 C12 C20 120.5(3) . .
C19 C20 C16 118.1(3) . .
C19 C20 C12 121.2(3) . .
C16 C20 C12 120.7(3) . .
C10 C13 C12 121.1(3) . .
C10 C13 H13 119.4 . .
C12 C13 H13 119.4 . .
C22 C27 C26 120.3(3) . .
C22 C27 H27 119.8 . .
C26 C27 H27 119.8 . .
C31 N2 C33 125.5(12) . .
C31 N2 C32 115.6(12) . .
C33 N2 C32 118.8(11) . .
N2 C31 O9 116.1(10) . .
N2 C31 H31 122.0 . .
O9 C31 H31 122.0 . .
N2 C33 H33A 109.5 . .
N2 C33 H33B 109.5 . .
H33A C33 H33B 109.5 . .
N2 C33 H33C 109.5 . .
H33A C33 H33C 109.5 . .
H33B C33 H33C 109.5 . .
N2 C32 H32A 109.5 . .
N2 C32 H32B 109.5 . .
H32A C32 H32B 109.5 . .
N2 C32 H32C 109.5 . .
H32A C32 H32C 109.5 . .
H32B C32 H32C 109.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C14 O5 1.262(4) 2_765
C14 O6 1.281(4) 2_765
C14 C17 1.497(4) .
C14 Eu1 2.842(3) 2_765
C15 C16 1.390(5) .
C15 C17 1.396(5) .
C15 H15 0.9300 .
C16 C20 1.399(5) .
C16 H16 0.9300 .
C17 C18 1.397(5) .
C18 C19 1.384(5) .
C18 H18 0.9300 .
C19 C20 1.397(5) .
C19 H19 0.9300 .
Eu1 O4 2.400(2) 2_675
Eu1 O2 2.409(2) 2_664
Eu1 O8 2.411(3) .
Eu1 O1 2.424(2) .
Eu1 O7 2.432(3) .
Eu1 O5 2.485(2) .
Eu1 O6 2.490(2) .
Eu1 O3 2.532(3) 2_675
Eu1 O1 2.702(2) 2_664
Eu1 C24 2.826(3) 2_675
Eu1 C14 2.842(3) 2_765
Eu1 C1 2.931(3) 2_664
O1 C1 1.279(4) .
O1 Eu1 2.703(2) 2_664
O6 C14 1.281(4) 2_765
O2 C1 1.256(4) .
O2 Eu1 2.409(2) 2_664
O3 C24 1.254(4) .
O3 Eu1 2.532(3) 2_675
O4 C24 1.270(4) .
O4 Eu1 2.400(2) 2_675
O5 C14 1.262(4) 2_765
C2 C4 1.385(4) .
C2 C5 1.392(5) .
C2 H2 0.9300 .
C8 C11 1.395(5) .
C8 C9 1.396(4) .
C8 C3 1.488(4) .
C3 C7 1.395(5) .
C3 C4 1.396(5) .
C1 C5 1.493(4) .
C1 Eu1 2.931(3) 2_664
C4 H4 0.9300 .
C9 C10 1.398(4) .
C9 H9 0.9300 .
C5 C6 1.394(5) .
C21 C22 1.393(5) .
C21 C23 1.395(5) .
C21 C24 1.498(4) .
C22 C27 1.394(5) .
C22 H22 0.9300 .
C23 C25 1.384(5) .
C23 H23 0.9300 .
C24 Eu1 2.826(3) 2_675
C6 C7 1.391(5) .
C6 H6 0.9300 .
C7 H7 0.9300 .
C25 C26 1.399(5) .
C25 H25 0.9300 .
C10 C13 1.399(5) .
C10 C26 1.488(4) .
C26 C27 1.400(5) .
C11 C12 1.402(4) .
C11 H11 0.9300 .
C12 C13 1.400(4) .
C12 C20 1.485(5) .
C13 H13 0.9300 .
C27 H27 0.9300 .
O9 C31 1.503(15) .
N2 C31 1.296(13) .
N2 C33 1.404(14) .
N2 C32 1.464(15) .
C31 H31 0.9300 .
C33 H33A 0.9600 .
C33 H33B 0.9600 .
C33 H33C 0.9600 .
C32 H32A 0.9600 .
C32 H32B 0.9600 .
C32 H32C 0.9600 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
C17 C15 C16 C20 -2.1(6) . .
C16 C15 C17 C18 1.1(6) . .
C16 C15 C17 C14 179.9(3) . .
O5 C14 C17 C15 158.7(4) 2_765 .
O6 C14 C17 C15 -24.6(5) 2_765 .
Eu1 C14 C17 C15 -113.3(9) 2_765 .
O5 C14 C17 C18 -22.5(5) 2_765 .
O6 C14 C17 C18 154.2(3) 2_765 .
Eu1 C14 C17 C18 65.5(10) 2_765 .
C15 C17 C18 C19 1.2(6) . .
C14 C17 C18 C19 -177.6(3) . .
C17 C18 C19 C20 -2.6(6) . .
C11 C8 C3 C7 -149.5(4) . .
C9 C8 C3 C7 32.5(5) . .
C11 C8 C3 C4 30.9(5) . .
C9 C8 C3 C4 -147.0(4) . .
Eu1 O2 C1 O1 4.4(4) 2_664 .
Eu1 O2 C1 C5 -174.8(3) 2_664 .
Eu1 O1 C1 O2 -153.1(4) . .
Eu1 O1 C1 O2 -3.8(3) 2_664 .
Eu1 O1 C1 C5 26.0(8) . .
Eu1 O1 C1 C5 175.3(3) 2_664 .
Eu1 O1 C1 Eu1 -149.3(6) . 2_664
C5 C2 C4 C3 1.0(6) . .
C7 C3 C4 C2 -0.8(5) . .
C8 C3 C4 C2 178.8(3) . .
C11 C8 C9 C10 -0.6(5) . .
C3 C8 C9 C10 177.4(3) . .
C4 C2 C5 C6 -0.6(5) . .
C4 C2 C5 C1 177.9(3) . .
O2 C1 C5 C2 15.6(5) . .
O1 C1 C5 C2 -163.6(3) . .
O2 C1 C5 C6 -166.0(3) . .
O1 C1 C5 C6 14.9(5) . .
C23 C21 C22 C27 0.5(6) . .
C24 C21 C22 C27 -178.7(3) . .
C22 C21 C23 C25 -1.3(6) . .
C24 C21 C23 C25 177.9(4) . .
Eu1 O3 C24 O4 -2.1(4) 2_675 .
Eu1 O3 C24 C21 177.6(3) 2_675 .
Eu1 O4 C24 O3 2.3(4) 2_675 .
Eu1 O4 C24 C21 -177.5(3) 2_675 .
C22 C21 C24 O3 8.7(6) . .
C23 C21 C24 O3 -170.5(4) . .
C22 C21 C24 O4 -171.6(4) . .
C23 C21 C24 O4 9.2(5) . .
C2 C5 C6 C7 -0.1(6) . .
C1 C5 C6 C7 -178.5(3) . .
C5 C6 C7 C3 0.3(6) . .
C4 C3 C7 C6 0.1(6) . .
C8 C3 C7 C6 -179.5(4) . .
C21 C23 C25 C26 0.8(6) . .
C8 C9 C10 C13 0.9(5) . .
C8 C9 C10 C26 -177.3(3) . .
C23 C25 C26 C27 0.4(6) . .
C23 C25 C26 C10 -179.5(3) . .
C9 C10 C26 C25 -34.6(5) . .
C13 C10 C26 C25 147.1(4) . .
C9 C10 C26 C27 145.4(4) . .
C13 C10 C26 C27 -32.8(5) . .
C9 C8 C11 C12 0.0(5) . .
C3 C8 C11 C12 -178.0(3) . .
C8 C11 C12 C13 0.3(6) . .
C8 C11 C12 C20 179.8(3) . .
C18 C19 C20 C16 1.5(6) . .
C18 C19 C20 C12 -178.3(3) . .
C15 C16 C20 C19 0.8(5) . .
C15 C16 C20 C12 -179.4(3) . .
C13 C12 C20 C19 -152.2(4) . .
C11 C12 C20 C19 28.4(5) . .
C13 C12 C20 C16 28.0(5) . .
C11 C12 C20 C16 -151.4(4) . .
C9 C10 C13 C12 -0.6(6) . .
C26 C10 C13 C12 177.6(3) . .
C11 C12 C13 C10 0.0(6) . .
C20 C12 C13 C10 -179.4(3) . .
C21 C22 C27 C26 0.8(6) . .
C25 C26 C27 C22 -1.2(6) . .
C10 C26 C27 C22 178.7(3) . .
C33 N2 C31 O9 5.9(14) . .
C32 N2 C31 O9 -176.0(10) . .
loop_
_platon_squeeze_void_nr
_platon_squeeze_void_average_x
_platon_squeeze_void_average_y
_platon_squeeze_void_average_z
_platon_squeeze_void_volume
_platon_squeeze_void_count_electrons
_platon_squeeze_void_content
1 -0.002 0.000 -0.004 626 136 ' '
