#------------------------------------------------------------------------------
#$Date: 2022-05-12 01:55:35 +0300 (Thu, 12 May 2022) $
#$Revision: 275350 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/71/02/7710245.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7710245
loop_
_publ_author_name
'Schoening, Juliane'
'Ganesamoorthy, Chelladurai'
'Wölper, Christoph'
'Solel, Ephrath'
'Schreiner, Peter R.'
'Schulz, Stephan'
_publ_section_title
;
 Synthesis, electronic nature, and reactivity of selected silylene
 carbonyl complexes
;
_journal_name_full               'Dalton Transactions'
_journal_paper_doi               10.1039/D2DT01335E
_journal_year                    2022
_chemical_formula_sum            'C58 H85 Br2 Ga2 N5 Si'
_chemical_formula_weight         1179.65
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_Hall           '-C 2yc'
_space_group_name_H-M_alt        'C 1 2/c 1'
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-2017/1
_audit_update_record
;
2022-01-25 deposited with the CCDC.	2022-05-11 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 99.872(3)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   23.796(3)
_cell_length_b                   10.9213(12)
_cell_length_c                   23.597(3)
_cell_measurement_reflns_used    9984
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      80.27
_cell_measurement_theta_min      3.80
_cell_volume                     6041.7(13)
_computing_cell_refinement       'Bruker APEX3(v2017.3-0)'
_computing_data_collection       'Bruker APEX3(v2017.3-0)'
_computing_data_reduction        'Bruker APEX3(v2017.3-0)'
_computing_molecular_graphics    'ORTEP/PLATON (Spek)'
_computing_publication_material  'BRUKER AXS SHELXTL (c) 2008 / Vers. 2008/4'
_computing_structure_refinement  'SHELXL-2017/1 (Sheldrick, 2017)'
_computing_structure_solution    'Bruker APEX3(v2017.3-0)'
_diffrn_ambient_temperature      100(2)
_diffrn_detector_area_resol_mean 7.3910
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device_type  'Bruker D8 Venture (Photon II detector)'
_diffrn_measurement_method       'Data collection strategy APEX 3/Queen'
_diffrn_radiation_monochromator  'multilayer mirror'
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54178
_diffrn_reflns_av_R_equivalents  0.0540
_diffrn_reflns_av_unetI/netI     0.0228
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.995
_diffrn_reflns_limit_h_max       30
_diffrn_reflns_limit_h_min       -26
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       30
_diffrn_reflns_limit_l_min       -30
_diffrn_reflns_number            89420
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.995
_diffrn_reflns_theta_full        67.679
_diffrn_reflns_theta_max         80.635
_diffrn_reflns_theta_min         3.771
_diffrn_source                   'micro-focus sealed tube'
_diffrn_source_type              'INCOATEC I\mS 3.0'
_exptl_absorpt_coefficient_mu    3.117
_exptl_absorpt_correction_T_max  0.75
_exptl_absorpt_correction_T_min  0.61
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
; 
 SADABS
 R.H. Blessing, Acta Cryst. (1995) A51 33-38 
;
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.297
_exptl_crystal_description       block
_exptl_crystal_F_000             2456
_exptl_crystal_size_max          0.309
_exptl_crystal_size_mid          0.148
_exptl_crystal_size_min          0.111
_refine_diff_density_max         0.334
_refine_diff_density_min         -0.526
_refine_diff_density_rms         0.076
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.370
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     450
_refine_ls_number_reflns         6604
_refine_ls_number_restraints     140
_refine_ls_restrained_S_all      1.357
_refine_ls_R_factor_all          0.0395
_refine_ls_R_factor_gt           0.0393
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+25.8204P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0977
_refine_ls_wR_factor_ref         0.0978
_reflns_Friedel_coverage         0.000
_reflns_number_gt                6567
_reflns_number_total             6604
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d2dt01335e2.cif
_cod_data_source_block           jus_165m
_cod_depositor_comments
;
The following automatic conversions were performed:

data item '_atom_sites_solution_secondary' value 'diffmap' was
changed to 'difmap'.

Automatic conversion script
Id: cif_fix_values 7556 2019-12-06 15:28:31Z antanas 
;
_cod_original_cell_volume        6041.8(11)
_cod_original_sg_symbol_H-M      'C 2/c'
_cod_database_code               7710245
_shelx_shelxl_version_number     2017/1
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.446
_shelx_estimated_absorpt_t_max   0.724
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Br1 Br 0.46651(2) 0.56920(3) 0.14175(2) 0.02416(9) Uani 1 1 d . . . . .
Ga1 Ga 0.49823(2) 0.36248(3) 0.15815(2) 0.01863(9) Uani 1 1 d . . . . .
Si1 Si 0.48533(6) 0.26712(14) 0.24888(8) 0.0200(4) Uani 0.5 1 d . . P A -3
H1 H 0.527(3) 0.168(6) 0.253(3) 0.024(17) Uiso 0.5 1 d . . P B -3
N3 N 0.4197(3) 0.1984(7) 0.2427(3) 0.0382(15) Uani 0.5 1 d . . P A -3
H4 H 0.397(5) 0.255(10) 0.249(5) 0.07(3) Uiso 0.5 1 d . . P C -3
H3 H 0.412(5) 0.150(11) 0.216(5) 0.08(4) Uiso 0.5 1 d . . P D -3
N1 N 0.56706(10) 0.3610(2) 0.12333(11) 0.0243(5) Uani 1 1 d . . . . .
N2 N 0.45017(10) 0.2761(2) 0.09420(10) 0.0201(5) Uani 1 1 d . . . . .
C1 C 0.56094(13) 0.3716(3) 0.06616(14) 0.0281(6) Uani 1 1 d . . . . .
C2 C 0.50956(14) 0.3497(3) 0.02910(13) 0.0282(6) Uani 1 1 d . . . . .
H2 H 0.508024 0.376322 -0.009456 0.034 Uiso 1 1 calc R U . . .
C3 C 0.46032(13) 0.2941(3) 0.04110(12) 0.0237(6) Uani 1 1 d . . . . .
C4 C 0.61186(18) 0.4064(4) 0.0393(2) 0.0509(11) Uani 1 1 d . . . . .
H4A H 0.601049 0.406259 -0.002660 0.076 Uiso 1 1 calc R U . . .
H4B H 0.642649 0.347191 0.050834 0.076 Uiso 1 1 calc R U . . .
H4C H 0.624953 0.488365 0.052378 0.076 Uiso 1 1 calc R U . . .
C5 C 0.41748(16) 0.2501(4) -0.00960(14) 0.0367(8) Uani 1 1 d . . . . .
H5A H 0.430626 0.272051 -0.045419 0.055 Uiso 1 1 calc R U . . .
H5B H 0.380472 0.288778 -0.008740 0.055 Uiso 1 1 calc R U . . .
H5C H 0.413554 0.160971 -0.007521 0.055 Uiso 1 1 calc R U . . .
C6 C 0.6223(6) 0.3593(14) 0.1647(4) 0.021(2) Uani 0.5 1 d . U P E 1
C7 C 0.6490(3) 0.2470(7) 0.1778(3) 0.0291(14) Uani 0.5 1 d . . P E 1
C8 C 0.7055(4) 0.2477(9) 0.2075(4) 0.040(2) Uani 0.5 1 d . . P E 1
H8 H 0.724558 0.172055 0.216603 0.048 Uiso 0.5 1 calc R U P E 1
C9 C 0.7340(7) 0.3562(16) 0.2238(7) 0.035(3) Uani 0.5 1 d . . P E 1
H9 H 0.772656 0.354679 0.242548 0.042 Uiso 0.5 1 calc R U P E 1
C10 C 0.7059(12) 0.466(2) 0.2126(12) 0.028(3) Uani 0.5 1 d . . P E 1
H10 H 0.722300 0.542282 0.226096 0.034 Uiso 0.5 1 calc R U P E 1
C11 C 0.6495(12) 0.456(2) 0.1787(13) 0.027(4) Uani 0.5 1 d . . P E 1
C12 C 0.6186(3) 0.1261(6) 0.1630(4) 0.0368(15) Uani 0.5 1 d . . P E 1
H12 H 0.576752 0.142294 0.158621 0.044 Uiso 0.5 1 calc R U P E 1
C13 C 0.6300(6) 0.0779(11) 0.1062(5) 0.060(3) Uani 0.5 1 d . . P E 1
H13A H 0.615159 0.135807 0.075586 0.090 Uiso 0.5 1 calc R U P E 1
H13B H 0.611033 -0.001462 0.098248 0.090 Uiso 0.5 1 calc R U P E 1
H13C H 0.671173 0.067843 0.107920 0.090 Uiso 0.5 1 calc R U P E 1
C14 C 0.6334(4) 0.0309(7) 0.2104(4) 0.049(2) Uani 0.5 1 d . . P E 1
H14A H 0.605144 -0.035119 0.204586 0.073 Uiso 0.5 1 calc R U P E 1
H14B H 0.633260 0.069460 0.247871 0.073 Uiso 0.5 1 calc R U P E 1
H14C H 0.671365 -0.002771 0.209198 0.073 Uiso 0.5 1 calc R U P E 1
C6' C 0.6262(6) 0.3555(13) 0.1486(4) 0.0177(19) Uani 0.5 1 d . U P E 2
C7' C 0.6555(3) 0.2423(7) 0.1498(3) 0.0313(14) Uani 0.5 1 d . . P E 2
C8' C 0.7106(4) 0.2363(9) 0.1807(4) 0.0378(19) Uani 0.5 1 d . . P E 2
H8' H 0.731096 0.161556 0.181471 0.045 Uiso 0.5 1 calc R U P E 2
C9' C 0.7355(8) 0.3331(17) 0.2094(7) 0.038(3) Uani 0.5 1 d . . P E 2
H9' H 0.772737 0.324950 0.231282 0.045 Uiso 0.5 1 calc R U P E 2
C10' C 0.7078(14) 0.445(2) 0.2077(14) 0.035(4) Uani 0.5 1 d . . P E 2
H10' H 0.728951 0.510733 0.227242 0.042 Uiso 0.5 1 calc R U P E 2
C11' C 0.6517(12) 0.472(2) 0.1802(11) 0.024(3) Uani 0.5 1 d . . P E 2
C12' C 0.6298(4) 0.1283(9) 0.1198(6) 0.051(2) Uani 0.5 1 d . . P E 2
H12' H 0.588609 0.145001 0.104802 0.061 Uiso 0.5 1 calc R U P E 2
C13' C 0.6594(5) 0.0996(10) 0.0677(5) 0.070(3) Uani 0.5 1 d . . P E 2
H13D H 0.642871 0.025192 0.048494 0.105 Uiso 0.5 1 calc R U P E 2
H13E H 0.700324 0.087253 0.081148 0.105 Uiso 0.5 1 calc R U P E 2
H13F H 0.653799 0.168282 0.040601 0.105 Uiso 0.5 1 calc R U P E 2
C14' C 0.6333(6) 0.0179(8) 0.1572(6) 0.078(4) Uani 0.5 1 d . . P E 2
H14D H 0.611851 -0.049313 0.136059 0.118 Uiso 0.5 1 calc R U P E 2
H14E H 0.617033 0.036623 0.191644 0.118 Uiso 0.5 1 calc R U P E 2
H14F H 0.673298 -0.006338 0.168520 0.118 Uiso 0.5 1 calc R U P E 2
C15 C 0.62264(13) 0.5895(3) 0.17157(13) 0.0269(6) Uani 1 1 d . . . . .
H15 H 0.586422 0.583204 0.143121 0.032 Uiso 0.5 1 calc R U P E 1
H15' H 0.586829 0.578548 0.142929 0.032 Uiso 0.5 1 calc R U P E 2
C16 C 0.66082(14) 0.6824(3) 0.14744(15) 0.0344(7) Uani 1 1 d . . . . .
H16A H 0.671533 0.649860 0.112076 0.052 Uiso 1 1 calc R U . . .
H16B H 0.695292 0.697084 0.175887 0.052 Uiso 1 1 calc R U . . .
H16C H 0.640020 0.759490 0.138950 0.052 Uiso 1 1 calc R U . . .
C17 C 0.60680(16) 0.6368(4) 0.22784(15) 0.0384(8) Uani 1 1 d . . . . .
H17A H 0.586252 0.714601 0.220705 0.058 Uiso 1 1 calc R U . . .
H17B H 0.641582 0.649460 0.256130 0.058 Uiso 1 1 calc R U . . .
H17C H 0.582407 0.576740 0.242705 0.058 Uiso 1 1 calc R U . . .
C18 C 0.40135(13) 0.2028(3) 0.10191(13) 0.0273(6) Uani 1 1 d . . . . .
C19 C 0.40871(17) 0.0769(3) 0.11366(19) 0.0441(9) Uani 1 1 d . . . . .
C20 C 0.3610(2) 0.0077(4) 0.1203(2) 0.0527(11) Uani 1 1 d . . . . .
H20 H 0.365285 -0.077660 0.127495 0.063 Uiso 1 1 calc R U . . .
C21 C 0.30841(18) 0.0596(4) 0.11657(19) 0.0519(11) Uani 1 1 d . . . . .
H21 H 0.276435 0.010857 0.121176 0.062 Uiso 1 1 calc R U . . .
C22 C 0.30203(15) 0.1835(4) 0.10608(17) 0.0406(8) Uani 1 1 d . . . . .
H22 H 0.265391 0.219369 0.104288 0.049 Uiso 1 1 calc R U . . .
C23 C 0.34734(13) 0.2574(3) 0.09808(14) 0.0297(7) Uani 1 1 d . . . . .
C24 C 0.4635(4) 0.0098(8) 0.1053(5) 0.032(2) Uani 0.5 1 d . . P F 2
H24 H 0.493068 0.072698 0.101228 0.038 Uiso 0.5 1 calc R U P F 2
C25 C 0.4587(5) -0.0783(9) 0.0540(5) 0.052(2) Uani 0.5 1 d . . P F 2
H25A H 0.447051 -0.032665 0.018196 0.078 Uiso 0.5 1 calc R U P F 2
H25B H 0.430316 -0.141511 0.057554 0.078 Uiso 0.5 1 calc R U P F 2
H25C H 0.495836 -0.116946 0.053624 0.078 Uiso 0.5 1 calc R U P F 2
C26 C 0.4832(7) -0.0605(12) 0.1606(6) 0.044(3) Uani 0.5 1 d . . P F 2
H26A H 0.518875 -0.103409 0.158058 0.066 Uiso 0.5 1 calc R U P F 2
H26B H 0.453963 -0.120258 0.166319 0.066 Uiso 0.5 1 calc R U P F 2
H26C H 0.489540 -0.003396 0.193078 0.066 Uiso 0.5 1 calc R U P F 2
C24' C 0.4695(5) 0.0189(10) 0.1303(4) 0.035(2) Uani 0.5 1 d . . P F 1
H24' H 0.497025 0.085943 0.144509 0.042 Uiso 0.5 1 calc R U P F 1
C25' C 0.4836(6) -0.0281(12) 0.0731(5) 0.070(3) Uani 0.5 1 d . . P F 1
H25D H 0.452935 -0.082238 0.054765 0.105 Uiso 0.5 1 calc R U P F 1
H25E H 0.519599 -0.073630 0.080326 0.105 Uiso 0.5 1 calc R U P F 1
H25F H 0.487184 0.041389 0.047733 0.105 Uiso 0.5 1 calc R U P F 1
C26' C 0.4765(11) -0.0840(17) 0.1761(7) 0.056(4) Uani 0.5 1 d . . P F 1
H26D H 0.516302 -0.111633 0.183548 0.084 Uiso 0.5 1 calc R U P F 1
H26E H 0.451639 -0.152875 0.161978 0.084 Uiso 0.5 1 calc R U P F 1
H26F H 0.466089 -0.052625 0.211811 0.084 Uiso 0.5 1 calc R U P F 1
C27 C 0.33666(13) 0.3929(3) 0.08683(14) 0.0293(7) Uani 1 1 d . . . . .
H27 H 0.372592 0.430118 0.078052 0.035 Uiso 1 1 calc R U . . .
C28 C 0.32247(15) 0.4555(4) 0.14080(16) 0.0412(9) Uani 1 1 d . . . . .
H28A H 0.320341 0.544290 0.134751 0.062 Uiso 1 1 calc R U . . .
H28B H 0.352308 0.436883 0.173739 0.062 Uiso 1 1 calc R U . . .
H28C H 0.285690 0.425398 0.148416 0.062 Uiso 1 1 calc R U . . .
C29 C 0.28895(14) 0.4165(4) 0.03517(16) 0.0400(8) Uani 1 1 d . . . . .
H29A H 0.297680 0.373108 0.001379 0.060 Uiso 1 1 calc R U . . .
H29B H 0.286199 0.504529 0.027136 0.060 Uiso 1 1 calc R U . . .
H29C H 0.252585 0.386866 0.044096 0.060 Uiso 1 1 calc R U . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Br Br -0.6763 1.2805 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ga Ga -1.2846 0.7763 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.2541 0.3302 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 Ga1 N2 95.30(10) . . ?
N1 Ga1 Br1 101.76(7) . . ?
N2 Ga1 Br1 101.69(7) . . ?
N1 Ga1 Si1 127.17(8) . . ?
N2 Ga1 Si1 108.83(8) . . ?
Br1 Ga1 Si1 117.39(4) . . ?
N3 Si1 Ga1 111.1(2) . . ?
C1 N1 C6' 110.7(4) . . ?
C1 N1 C6 126.2(4) . . ?
C1 N1 Ga1 118.0(2) . . ?
C6' N1 Ga1 131.3(4) . . ?
C6 N1 Ga1 115.6(4) . . ?
C3 N2 C18 118.6(2) . . ?
C3 N2 Ga1 118.3(2) . . ?
C18 N2 Ga1 122.78(18) . . ?
N1 C1 C2 123.3(3) . . ?
N1 C1 C4 119.3(3) . . ?
C2 C1 C4 117.4(3) . . ?
C3 C2 C1 128.7(3) . . ?
N2 C3 C2 123.5(3) . . ?
N2 C3 C5 119.4(3) . . ?
C2 C3 C5 117.1(3) . . ?
C11 C6 C7 119.3(17) . . ?
C11 C6 N1 121.1(17) . . ?
C7 C6 N1 118.1(11) . . ?
C6 C7 C8 117.8(9) . . ?
C6 C7 C12 122.4(8) . . ?
C8 C7 C12 119.8(7) . . ?
C9 C8 C7 121.6(11) . . ?
C10 C9 C8 119.5(17) . . ?
C9 C10 C11 115(2) . . ?
C6 C11 C10 127(2) . . ?
C6 C11 C15 124(2) . . ?
C10 C11 C15 108.0(18) . . ?
C13 C12 C7 111.0(8) . . ?
C13 C12 C14 111.1(7) . . ?
C7 C12 C14 112.6(6) . . ?
C7' C6' N1 119.3(10) . . ?
C7' C6' C11' 124.0(15) . . ?
N1 C6' C11' 116.2(15) . . ?
C8' C7' C6' 117.9(9) . . ?
C8' C7' C12' 118.6(7) . . ?
C6' C7' C12' 123.5(8) . . ?
C9' C8' C7' 121.7(11) . . ?
C8' C9' C10' 121.0(19) . . ?
C9' C10' C11' 127(2) . . ?
C10' C11' C15 129.7(19) . . ?
C10' C11' C6' 108(2) . . ?
C15 C11' C6' 121(2) . . ?
C14' C12' C7' 114.4(10) . . ?
C14' C12' C13' 108.7(9) . . ?
C7' C12' C13' 109.6(8) . . ?
C11' C15 C17 111.0(11) . . ?
C11' C15 C16 109.7(10) . . ?
C17 C15 C16 110.4(3) . . ?
C17 C15 C11 111.9(11) . . ?
C16 C15 C11 113.0(11) . . ?
C23 C18 C19 120.6(3) . . ?
C23 C18 N2 120.1(3) . . ?
C19 C18 N2 119.3(3) . . ?
C20 C19 C18 118.4(4) . . ?
C20 C19 C24 118.7(5) . . ?
C18 C19 C24 121.3(5) . . ?
C20 C19 C24' 119.2(5) . . ?
C18 C19 C24' 121.5(5) . . ?
C21 C20 C19 121.6(4) . . ?
C20 C21 C22 119.4(4) . . ?
C21 C22 C23 122.1(4) . . ?
C22 C23 C18 117.9(3) . . ?
C22 C23 C27 118.7(3) . . ?
C18 C23 C27 123.3(3) . . ?
C26 C24 C25 109.3(9) . . ?
C26 C24 C19 106.0(9) . . ?
C25 C24 C19 116.8(7) . . ?
C25' C24' C26' 110.9(11) . . ?
C25' C24' C19 104.2(8) . . ?
C26' C24' C19 116.9(12) . . ?
C23 C27 C28 110.1(3) . . ?
C23 C27 C29 112.4(3) . . ?
C28 C27 C29 110.2(3) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Br1 Ga1 2.3909(5) . ?
Ga1 N1 1.954(2) . ?
Ga1 N2 1.971(2) . ?
Ga1 Si1 2.4471(19) . ?
Si1 N3 1.716(6) . ?
N1 C1 1.337(4) . ?
N1 C6' 1.433(15) . ?
N1 C6 1.497(15) . ?
N2 C3 1.331(4) . ?
N2 C18 1.447(4) . ?
C1 C2 1.396(5) . ?
C1 C4 1.509(4) . ?
C2 C3 1.391(5) . ?
C3 C5 1.511(4) . ?
C6 C11 1.26(3) . ?
C6 C7 1.391(16) . ?
C7 C8 1.405(11) . ?
C7 C12 1.516(10) . ?
C8 C9 1.387(17) . ?
C9 C10 1.38(2) . ?
C10 C11 1.44(4) . ?
C11 C15 1.59(3) . ?
C12 C13 1.507(13) . ?
C12 C14 1.523(11) . ?
C6' C7' 1.417(15) . ?
C6' C11' 1.55(3) . ?
C7' C8' 1.387(12) . ?
C7' C12' 1.509(14) . ?
C8' C9' 1.338(17) . ?
C9' C10' 1.39(2) . ?
C10' C11' 1.41(5) . ?
C11' C15 1.45(3) . ?
C12' C14' 1.489(15) . ?
C12' C13' 1.549(16) . ?
C15 C17 1.531(5) . ?
C15 C16 1.535(4) . ?
C18 C23 1.406(5) . ?
C18 C19 1.408(5) . ?
C19 C20 1.394(5) . ?
C19 C24 1.537(10) . ?
C19 C24' 1.567(12) . ?
C20 C21 1.363(7) . ?
C21 C22 1.380(6) . ?
C22 C23 1.385(5) . ?
C23 C27 1.517(5) . ?
C24 C26 1.517(16) . ?
C24 C25 1.535(13) . ?
C24' C25' 1.533(11) . ?
C24' C26' 1.549(15) . ?
C27 C28 1.533(5) . ?
C27 C29 1.538(5) . ?
