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#$Date: 2022-08-31 01:57:24 +0300 (Wed, 31 Aug 2022) $
#$Revision: 277472 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/71/10/7711093.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7711093
loop_
_publ_author_name
'Ilmi, Rashid'
'Yin, Jiaxuan'
'Dutra, Jose D. L.'
'Al Rasbi, Nawal K.'
'Oliveira, Willyan F.'
'Zhou, Liang'
'Wong, Wai-Yeung Raymond'
'Raithby, Paul R.'
'Khan, Muhammad S.'
_publ_section_title
;
 Single component white-OLEDs derived from tris(β-diketonato)
 europium(III) complexes bearing the large bite angle N^N
 2-(4-thiazolyl)benzimidazole ligand
;
_journal_name_full               'Dalton Transactions'
_journal_paper_doi               10.1039/D2DT01873J
_journal_year                    2022
_chemical_formula_sum            'C25 H10 Eu F18 N3 O6 S'
_chemical_formula_weight         974.38
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2018/3
_audit_update_record
;
2022-06-13 deposited with the CCDC.	2022-08-22 downloaded from the CCDC.
;
_cell_angle_alpha                82.80(3)
_cell_angle_beta                 76.70(3)
_cell_angle_gamma                83.90(3)
_cell_formula_units_Z            2
_cell_length_a                   9.7200(19)
_cell_length_b                   12.770(3)
_cell_length_c                   14.300(3)
_cell_measurement_reflns_used    9917
_cell_measurement_temperature    297(2)
_cell_measurement_theta_max      60
_cell_measurement_theta_min      3
_cell_volume                     1708.2(7)
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018)'
_diffrn_ambient_temperature      297(2)
_diffrn_detector_area_resol_mean 6.67
_diffrn_measured_fraction_theta_full 0.994
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device_type  'stoe ipds ii'
_diffrn_measurement_method       'w scan'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0384
_diffrn_reflns_av_unetI/netI     0.0379
_diffrn_reflns_Laue_measured_fraction_full 0.994
_diffrn_reflns_Laue_measured_fraction_max 0.995
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            19762
_diffrn_reflns_point_group_measured_fraction_full 0.994
_diffrn_reflns_point_group_measured_fraction_max 0.995
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         29.999
_diffrn_reflns_theta_min         2.590
_diffrn_source                   'sealed x-ray tube'
_exptl_absorpt_coefficient_mu    2.038
_exptl_absorpt_correction_T_max  0.6
_exptl_absorpt_correction_T_min  0.6
_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.894
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             940
_exptl_crystal_recrystallization_method
'Re-crystallisation from solvent: Water/ethanol'
_exptl_crystal_size_max          0.200
_exptl_crystal_size_mid          0.200
_exptl_crystal_size_min          0.200
_refine_diff_density_max         1.097
_refine_diff_density_min         -0.795
_refine_diff_density_rms         0.114
_refine_ls_extinction_coef       0.0048(7)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     'SHELXL-2018/3 (Sheldrick 2018)'
_refine_ls_goodness_of_fit_ref   1.034
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     488
_refine_ls_number_reflns         9917
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.034
_refine_ls_R_factor_all          0.0628
_refine_ls_R_factor_gt           0.0484
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0779P)²+1.5500P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1256
_refine_ls_wR_factor_ref         0.1379
_reflns_Friedel_coverage         0.000
_reflns_number_gt                8086
_reflns_number_total             9917
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d2dt01873j2.cif
_cod_data_source_block           Eu2
_cod_original_cell_volume        1708.2(6)
_cod_database_code               7711093
_shelx_shelxl_version_number     2018/3
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.686
_shelx_estimated_absorpt_t_max   0.686
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.51245(2) 0.26326(2) 0.69869(2) 0.04770(9) Uani 1 1 d . . . . .
S1 S 0.48830(17) 0.26999(12) 0.34386(10) 0.0717(3) Uani 1 1 d . . . . .
F1 F 0.9917(9) 0.3585(10) 0.6842(8) 0.252(6) Uani 1 1 d . . . . .
F2 F 1.0048(7) 0.3882(6) 0.5456(8) 0.215(5) Uani 1 1 d . . . . .
F3 F 1.1137(5) 0.2603(5) 0.6038(8) 0.194(4) Uani 1 1 d . . . . .
F4 F 0.9460(5) -0.0693(4) 0.6106(6) 0.159(3) Uani 1 1 d . . . . .
F5 F 0.7497(10) -0.0897(4) 0.7047(5) 0.180(3) Uani 1 1 d . . . . .
F6 F 0.7634(7) -0.0727(4) 0.5598(5) 0.141(2) Uani 1 1 d . . . . .
F7 F 0.3212(6) -0.0875(3) 0.7537(5) 0.1273(19) Uani 1 1 d . . . . .
F8 F 0.2156(6) -0.0059(4) 0.6532(3) 0.1079(14) Uani 1 1 d . . . . .
F9 F 0.1039(6) -0.0426(4) 0.7965(4) 0.140(2) Uani 1 1 d . . . . .
F10 F 0.2309(12) 0.2770(11) 1.0303(5) 0.256(7) Uani 1 1 d . . . . .
F11 F 0.0811(13) 0.3431(7) 0.9659(6) 0.245(6) Uani 1 1 d . . . . .
F12 F 0.0661(8) 0.1928(5) 1.0333(4) 0.166(3) Uani 1 1 d . . . . .
F13 F 0.7821(17) 0.1285(9) 1.0097(10) 0.299(8) Uani 1 1 d . . . . .
F14 F 0.6195(11) 0.0606(11) 1.0017(11) 0.319(10) Uani 1 1 d . . . . .
F15 F 0.794(2) 0.0467(12) 0.9133(10) 0.324(10) Uani 1 1 d . . . . .
F16 F 0.7123(13) 0.4965(6) 0.9489(6) 0.221(5) Uani 1 1 d . . . . .
F17 F 0.5679(10) 0.5692(6) 0.8709(7) 0.194(4) Uani 1 1 d . . . . .
F18 F 0.7692(12) 0.5399(7) 0.7991(7) 0.208(4) Uani 1 1 d . . . . .
O1 O 0.7527(3) 0.3086(3) 0.6196(3) 0.0600(8) Uani 1 1 d . . . . .
O2 O 0.6522(3) 0.1112(3) 0.6324(3) 0.0646(8) Uani 1 1 d . . . . .
O3 O 0.3605(3) 0.1325(3) 0.7067(2) 0.0571(7) Uani 1 1 d . . . . .
O4 O 0.3267(4) 0.2750(3) 0.8392(3) 0.0654(9) Uani 1 1 d . . . . .
O5 O 0.5834(4) 0.3955(3) 0.7787(3) 0.0682(9) Uani 1 1 d . . . . .
O6 O 0.6172(4) 0.1744(3) 0.8218(3) 0.0727(9) Uani 1 1 d . . . . .
N1 N 0.3633(4) 0.4245(3) 0.6503(3) 0.0486(7) Uani 1 1 d . . . . .
N2 N 0.4866(4) 0.2827(3) 0.5202(3) 0.0533(8) Uani 1 1 d . . . . .
N3 N 0.2651(4) 0.5339(3) 0.5443(3) 0.0542(8) Uani 1 1 d . . . . .
H3 H 0.243596 0.559107 0.490353 0.065 Uiso 1 1 calc R U . . .
C1 C 0.2841(4) 0.5091(3) 0.6975(3) 0.0526(9) Uani 1 1 d . . . . .
C2 C 0.2613(6) 0.5294(4) 0.7934(4) 0.0677(13) Uani 1 1 d . . . . .
H2 H 0.300716 0.484339 0.838321 0.081 Uiso 1 1 calc R U . . .
C3 C 0.1771(7) 0.6202(5) 0.8182(5) 0.0818(17) Uani 1 1 d . . . . .
H3A H 0.161438 0.637394 0.881246 0.098 Uiso 1 1 calc R U . . .
C4 C 0.1142(7) 0.6874(5) 0.7516(5) 0.0821(17) Uani 1 1 d . . . . .
H4 H 0.056483 0.746678 0.772159 0.099 Uiso 1 1 calc R U . . .
C5 C 0.1356(6) 0.6679(4) 0.6570(5) 0.0741(14) Uani 1 1 d . . . . .
H5 H 0.094390 0.712424 0.612606 0.089 Uiso 1 1 calc R U . . .
C6 C 0.2228(5) 0.5773(3) 0.6312(4) 0.0568(10) Uani 1 1 d . . . . .
C7 C 0.3471(4) 0.4440(3) 0.5606(3) 0.0464(8) Uani 1 1 d . . . . .
C8 C 0.4098(4) 0.3715(3) 0.4881(3) 0.0465(8) Uani 1 1 d . . . . .
C9 C 0.3996(5) 0.3781(4) 0.3946(4) 0.0591(10) Uani 1 1 d . . . . .
H9 H 0.351584 0.433271 0.363105 0.071 Uiso 1 1 calc R U . . .
C10 C 0.5316(6) 0.2228(4) 0.4505(4) 0.0655(12) Uani 1 1 d . . . . .
H10 H 0.584086 0.158321 0.458621 0.079 Uiso 1 1 calc R U . . .
C11 C 0.8119(7) -0.0398(5) 0.6280(7) 0.0865(19) Uani 1 1 d . . . . .
C12 C 0.7787(5) 0.0803(4) 0.6289(4) 0.0642(12) Uani 1 1 d . . . . .
C13 C 0.8886(5) 0.1436(4) 0.6264(5) 0.0724(14) Uani 1 1 d . . . . .
H13 H 0.978252 0.111434 0.629058 0.087 Uiso 1 1 calc R U . . .
C14 C 0.8675(5) 0.2516(4) 0.6202(4) 0.0607(11) Uani 1 1 d . . . . .
C15 C 0.9957(6) 0.3128(5) 0.6095(6) 0.0847(18) Uani 1 1 d . . . . .
C16 C 0.2242(6) -0.0127(4) 0.7443(4) 0.0695(13) Uani 1 1 d . . . . .
C17 C 0.2634(4) 0.0912(3) 0.7694(3) 0.0496(8) Uani 1 1 d . . . . .
C18 C 0.1947(6) 0.1275(4) 0.8563(4) 0.0649(12) Uani 1 1 d . . . . .
H18 H 0.122435 0.090571 0.896748 0.078 Uiso 1 1 calc R U . . .
C19 C 0.2327(5) 0.2184(4) 0.8835(3) 0.0612(11) Uani 1 1 d . . . . .
C20 C 0.1499(12) 0.2547(7) 0.9795(6) 0.120(4) Uani 1 1 d . . . . .
C21 C 0.6747(14) 0.4984(8) 0.8696(8) 0.123(3) Uani 1 1 d . . . . .
C22 C 0.6411(8) 0.3919(6) 0.8481(5) 0.0836(17) Uani 1 1 d . . . . .
C23 C 0.6794(11) 0.3022(7) 0.9057(6) 0.109(3) Uani 1 1 d . . . . .
H23 H 0.717641 0.310899 0.957931 0.131 Uiso 1 1 calc R U . . .
C24 C 0.6627(7) 0.2008(6) 0.8879(5) 0.0848(17) Uani 1 1 d . . . . .
C25 C 0.7083(12) 0.1101(10) 0.9555(8) 0.125(3) Uani 1 1 d . . . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O3 Eu1 O6 93.87(14) . . ?
O3 Eu1 O4 71.04(11) . . ?
O6 Eu1 O4 77.08(15) . . ?
O3 Eu1 O5 147.45(12) . . ?
O6 Eu1 O5 72.85(14) . . ?
O4 Eu1 O5 76.98(13) . . ?
O3 Eu1 O2 72.11(11) . . ?
O6 Eu1 O2 73.80(15) . . ?
O4 Eu1 O2 130.60(13) . . ?
O5 Eu1 O2 128.52(13) . . ?
O3 Eu1 O1 140.25(11) . . ?
O6 Eu1 O1 85.19(13) . . ?
O4 Eu1 O1 145.61(13) . . ?
O5 Eu1 O1 69.66(13) . . ?
O2 Eu1 O1 69.50(11) . . ?
O3 Eu1 N1 100.59(12) . . ?
O6 Eu1 N1 145.19(13) . . ?
O4 Eu1 N1 78.00(13) . . ?
O5 Eu1 N1 78.13(13) . . ?
O2 Eu1 N1 140.83(13) . . ?
O1 Eu1 N1 102.49(11) . . ?
O3 Eu1 N2 79.79(12) . . ?
O6 Eu1 N2 149.48(13) . . ?
O4 Eu1 N2 127.06(13) . . ?
O5 Eu1 N2 126.19(13) . . ?
O2 Eu1 N2 75.86(13) . . ?
O1 Eu1 N2 81.27(12) . . ?
N1 Eu1 N2 64.98(11) . . ?
C10 S1 C9 89.9(2) . . ?
C14 O1 Eu1 127.4(3) . . ?
C12 O2 Eu1 130.5(3) . . ?
C17 O3 Eu1 136.3(3) . . ?
C19 O4 Eu1 135.2(3) . . ?
C22 O5 Eu1 133.6(4) . . ?
C24 O6 Eu1 135.6(4) . . ?
C7 N1 C1 104.5(4) . . ?
C7 N1 Eu1 120.1(3) . . ?
C1 N1 Eu1 135.5(3) . . ?
C10 N2 C8 109.5(4) . . ?
C10 N2 Eu1 132.6(4) . . ?
C8 N2 Eu1 117.9(3) . . ?
C7 N3 C6 106.6(4) . . ?
C7 N3 H3 126.7 . . ?
C6 N3 H3 126.7 . . ?
C2 C1 C6 120.9(4) . . ?
C2 C1 N1 130.0(5) . . ?
C6 C1 N1 109.0(4) . . ?
C3 C2 C1 116.3(6) . . ?
C3 C2 H2 121.8 . . ?
C1 C2 H2 121.8 . . ?
C2 C3 C4 122.3(6) . . ?
C2 C3 H3A 118.8 . . ?
C4 C3 H3A 118.8 . . ?
C5 C4 C3 121.8(5) . . ?
C5 C4 H4 119.1 . . ?
C3 C4 H4 119.1 . . ?
C4 C5 C6 116.1(6) . . ?
C4 C5 H5 122.0 . . ?
C6 C5 H5 122.0 . . ?
N3 C6 C5 131.4(5) . . ?
N3 C6 C1 106.1(4) . . ?
C5 C6 C1 122.5(5) . . ?
N1 C7 N3 113.9(4) . . ?
N1 C7 C8 121.6(4) . . ?
N3 C7 C8 124.5(4) . . ?
C9 C8 N2 115.6(4) . . ?
C9 C8 C7 129.0(4) . . ?
N2 C8 C7 115.4(4) . . ?
C8 C9 S1 109.5(4) . . ?
C8 C9 H9 125.3 . . ?
S1 C9 H9 125.3 . . ?
N2 C10 S1 115.5(4) . . ?
N2 C10 H10 122.2 . . ?
S1 C10 H10 122.2 . . ?
F5 C11 F4 110.0(8) . . ?
F5 C11 F6 104.9(7) . . ?
F4 C11 F6 105.8(7) . . ?
F5 C11 C12 111.9(6) . . ?
F4 C11 C12 113.8(5) . . ?
F6 C11 C12 110.0(6) . . ?
O2 C12 C13 126.5(5) . . ?
O2 C12 C11 114.5(5) . . ?
C13 C12 C11 119.0(5) . . ?
C14 C13 C12 121.6(5) . . ?
C14 C13 H13 119.2 . . ?
C12 C13 H13 119.2 . . ?
O1 C14 C13 128.0(5) . . ?
O1 C14 C15 114.6(5) . . ?
C13 C14 C15 117.4(5) . . ?
F2 C15 F3 110.1(8) . . ?
F2 C15 F1 101.9(9) . . ?
F3 C15 F1 99.5(8) . . ?
F2 C15 C14 114.2(6) . . ?
F3 C15 C14 117.2(6) . . ?
F1 C15 C14 112.0(7) . . ?
F7 C16 F9 108.4(6) . . ?
F7 C16 F8 105.3(6) . . ?
F9 C16 F8 107.2(6) . . ?
F7 C16 C17 110.8(5) . . ?
F9 C16 C17 113.5(5) . . ?
F8 C16 C17 111.2(5) . . ?
O3 C17 C18 127.6(4) . . ?
O3 C17 C16 113.6(4) . . ?
C18 C17 C16 118.8(4) . . ?
C17 C18 C19 120.3(4) . . ?
C17 C18 H18 119.9 . . ?
C19 C18 H18 119.9 . . ?
O4 C19 C18 127.8(4) . . ?
O4 C19 C20 115.0(5) . . ?
C18 C19 C20 117.2(5) . . ?
F12 C20 F10 106.2(10) . . ?
F12 C20 F11 108.0(10) . . ?
F10 C20 F11 101.7(9) . . ?
F12 C20 C19 117.5(6) . . ?
F10 C20 C19 111.8(9) . . ?
F11 C20 C19 110.4(9) . . ?
F16 C21 F18 110.3(10) . . ?
F16 C21 F17 107.1(11) . . ?
F18 C21 F17 101.3(11) . . ?
F16 C21 C22 114.3(9) . . ?
F18 C21 C22 110.8(9) . . ?
F17 C21 C22 112.2(9) . . ?
O5 C22 C23 127.5(6) . . ?
O5 C22 C21 114.7(7) . . ?
C23 C22 C21 117.8(7) . . ?
C24 C23 C22 122.3(7) . . ?
C24 C23 H23 118.8 . . ?
C22 C23 H23 118.8 . . ?
O6 C24 C23 127.7(6) . . ?
O6 C24 C25 114.9(8) . . ?
C23 C24 C25 117.3(8) . . ?
F14 C25 F15 104.8(16) . . ?
F14 C25 F13 106.9(13) . . ?
F15 C25 F13 96.0(13) . . ?
F14 C25 C24 116.2(9) . . ?
F15 C25 C24 112.3(10) . . ?
F13 C25 C24 118.1(11) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O3 2.320(3) . ?
Eu1 O6 2.345(4) . ?
Eu1 O4 2.381(3) . ?
Eu1 O5 2.394(4) . ?
Eu1 O2 2.413(3) . ?
Eu1 O1 2.444(3) . ?
Eu1 N1 2.508(4) . ?
Eu1 N2 2.601(4) . ?
S1 C10 1.697(6) . ?
S1 C9 1.699(5) . ?
F1 C15 1.271(11) . ?
F2 C15 1.237(9) . ?
F3 C15 1.256(8) . ?
F4 C11 1.294(8) . ?
F5 C11 1.255(9) . ?
F6 C11 1.305(10) . ?
F7 C16 1.286(8) . ?
F8 C16 1.317(8) . ?
F9 C16 1.300(7) . ?
F10 C20 1.261(15) . ?
F11 C20 1.267(13) . ?
F12 C20 1.255(9) . ?
F13 C25 1.228(13) . ?
F14 C25 1.153(13) . ?
F15 C25 1.207(16) . ?
F16 C21 1.265(11) . ?
F17 C21 1.300(14) . ?
F18 C21 1.298(13) . ?
O1 C14 1.267(6) . ?
O2 C12 1.242(6) . ?
O3 C17 1.253(5) . ?
O4 C19 1.232(6) . ?
O5 C22 1.242(7) . ?
O6 C24 1.228(8) . ?
N1 C7 1.318(6) . ?
N1 C1 1.408(5) . ?
N2 C10 1.299(6) . ?
N2 C8 1.379(6) . ?
N3 C7 1.353(5) . ?
N3 C6 1.383(6) . ?
N3 H3 0.8600 . ?
C1 C2 1.390(7) . ?
C1 C6 1.397(7) . ?
C2 C3 1.382(7) . ?
C2 H2 0.9300 . ?
C3 C4 1.402(10) . ?
C3 H3A 0.9300 . ?
C4 C5 1.370(9) . ?
C4 H4 0.9300 . ?
C5 C6 1.396(6) . ?
C5 H5 0.9300 . ?
C7 C8 1.460(5) . ?
C8 C9 1.355(6) . ?
C9 H9 0.9300 . ?
C10 H10 0.9300 . ?
C11 C12 1.536(8) . ?
C12 C13 1.398(7) . ?
C13 C14 1.367(7) . ?
C13 H13 0.9300 . ?
C14 C15 1.509(7) . ?
C16 C17 1.524(7) . ?
C17 C18 1.379(6) . ?
C18 C19 1.381(7) . ?
C18 H18 0.9300 . ?
C19 C20 1.523(7) . ?
C21 C22 1.516(11) . ?
C22 C23 1.393(11) . ?
C23 C24 1.384(11) . ?
C23 H23 0.9300 . ?
C24 C25 1.509(11) . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C7 N1 C1 C2 179.1(5) . . . . ?
Eu1 N1 C1 C2 -1.1(7) . . . . ?
C7 N1 C1 C6 -0.2(5) . . . . ?
Eu1 N1 C1 C6 179.6(3) . . . . ?
C6 C1 C2 C3 -0.6(8) . . . . ?
N1 C1 C2 C3 -179.8(5) . . . . ?
C1 C2 C3 C4 1.6(9) . . . . ?
C2 C3 C4 C5 -1.5(11) . . . . ?
C3 C4 C5 C6 0.3(9) . . . . ?
C7 N3 C6 C5 -178.5(5) . . . . ?
C7 N3 C6 C1 0.2(5) . . . . ?
C4 C5 C6 N3 179.3(5) . . . . ?
C4 C5 C6 C1 0.7(8) . . . . ?
C2 C1 C6 N3 -179.4(4) . . . . ?
N1 C1 C6 N3 0.0(5) . . . . ?
C2 C1 C6 C5 -0.6(7) . . . . ?
N1 C1 C6 C5 178.8(5) . . . . ?
C1 N1 C7 N3 0.3(5) . . . . ?
Eu1 N1 C7 N3 -179.4(2) . . . . ?
C1 N1 C7 C8 -177.8(3) . . . . ?
Eu1 N1 C7 C8 2.4(5) . . . . ?
C6 N3 C7 N1 -0.4(5) . . . . ?
C6 N3 C7 C8 177.8(4) . . . . ?
C10 N2 C8 C9 -0.9(5) . . . . ?
Eu1 N2 C8 C9 179.9(3) . . . . ?
C10 N2 C8 C7 177.4(4) . . . . ?
Eu1 N2 C8 C7 -1.9(4) . . . . ?
N1 C7 C8 C9 177.7(4) . . . . ?
N3 C7 C8 C9 -0.3(7) . . . . ?
N1 C7 C8 N2 -0.3(5) . . . . ?
N3 C7 C8 N2 -178.3(4) . . . . ?
N2 C8 C9 S1 0.2(5) . . . . ?
C7 C8 C9 S1 -177.8(3) . . . . ?
C10 S1 C9 C8 0.5(4) . . . . ?
C8 N2 C10 S1 1.3(5) . . . . ?
Eu1 N2 C10 S1 -179.6(2) . . . . ?
C9 S1 C10 N2 -1.1(4) . . . . ?
Eu1 O2 C12 C13 -28.0(9) . . . . ?
Eu1 O2 C12 C11 151.7(5) . . . . ?
F5 C11 C12 O2 -63.9(9) . . . . ?
F4 C11 C12 O2 170.7(7) . . . . ?
F6 C11 C12 O2 52.2(8) . . . . ?
F5 C11 C12 C13 115.8(8) . . . . ?
F4 C11 C12 C13 -9.6(11) . . . . ?
F6 C11 C12 C13 -128.1(7) . . . . ?
O2 C12 C13 C14 -5.1(11) . . . . ?
C11 C12 C13 C14 175.3(7) . . . . ?
Eu1 O1 C14 C13 30.3(9) . . . . ?
Eu1 O1 C14 C15 -151.7(4) . . . . ?
C12 C13 C14 O1 2.9(11) . . . . ?
C12 C13 C14 C15 -175.0(6) . . . . ?
O1 C14 C15 F2 -45.0(11) . . . . ?
C13 C14 C15 F2 133.2(9) . . . . ?
O1 C14 C15 F3 -175.9(8) . . . . ?
C13 C14 C15 F3 2.4(12) . . . . ?
O1 C14 C15 F1 70.2(10) . . . . ?
C13 C14 C15 F1 -111.6(10) . . . . ?
Eu1 O3 C17 C18 13.6(8) . . . . ?
Eu1 O3 C17 C16 -164.4(4) . . . . ?
F7 C16 C17 O3 73.0(7) . . . . ?
F9 C16 C17 O3 -164.8(6) . . . . ?
F8 C16 C17 O3 -43.7(7) . . . . ?
F7 C16 C17 C18 -105.2(6) . . . . ?
F9 C16 C17 C18 17.0(8) . . . . ?
F8 C16 C17 C18 138.1(6) . . . . ?
O3 C17 C18 C19 -1.3(9) . . . . ?
C16 C17 C18 C19 176.6(5) . . . . ?
Eu1 O4 C19 C18 -8.1(10) . . . . ?
Eu1 O4 C19 C20 172.0(6) . . . . ?
C17 C18 C19 O4 -1.1(10) . . . . ?
C17 C18 C19 C20 178.8(7) . . . . ?
O4 C19 C20 F12 -170.9(10) . . . . ?
C18 C19 C20 F12 9.2(15) . . . . ?
O4 C19 C20 F10 -47.7(13) . . . . ?
C18 C19 C20 F10 132.3(9) . . . . ?
O4 C19 C20 F11 64.7(13) . . . . ?
C18 C19 C20 F11 -115.2(10) . . . . ?
Eu1 O5 C22 C23 -2.6(12) . . . . ?
Eu1 O5 C22 C21 176.2(6) . . . . ?
F16 C21 C22 O5 169.3(10) . . . . ?
F18 C21 C22 O5 -65.3(13) . . . . ?
F17 C21 C22 O5 47.1(13) . . . . ?
F16 C21 C22 C23 -11.8(16) . . . . ?
F18 C21 C22 C23 113.6(11) . . . . ?
F17 C21 C22 C23 -134.0(10) . . . . ?
O5 C22 C23 C24 3.4(15) . . . . ?
C21 C22 C23 C24 -175.3(9) . . . . ?
Eu1 O6 C24 C23 -7.4(13) . . . . ?
Eu1 O6 C24 C25 174.1(6) . . . . ?
C22 C23 C24 O6 1.6(15) . . . . ?
C22 C23 C24 C25 180.0(9) . . . . ?
O6 C24 C25 F14 -66.4(18) . . . . ?
C23 C24 C25 F14 115.0(16) . . . . ?
O6 C24 C25 F15 54.3(17) . . . . ?
C23 C24 C25 F15 -124.3(16) . . . . ?
O6 C24 C25 F13 164.5(14) . . . . ?
C23 C24 C25 F13 -14.1(19) . . . . ?
