#------------------------------------------------------------------------------
#$Date: 2022-09-01 01:55:39 +0300 (Thu, 01 Sep 2022) $
#$Revision: 277512 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/71/10/7711099.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7711099
loop_
_publ_author_name
'Thangavel, Muthu Kumar'
'Harrowfield, Jack'
'Bailly, Corinne'
'Karmazin, Lydia'
'Stadler, Adrian-Mihail'
_publ_section_title
;
 Modulation of the structural information in shape-defined heterocyclic
 strands: the case of a (pyridine-hydrazone)2pyrazine ligand
;
_journal_name_full               'Dalton Transactions'
_journal_paper_doi               10.1039/D2DT01684B
_journal_year                    2022
_chemical_formula_moiety
'C60 H56 Eu2 F18 N24 O18 S6, 2(F6 P), 6(C2 H3 N)'
_chemical_formula_sum            'C72 H74 Eu2 F30 N30 O18 P2 S6'
_chemical_formula_weight         2775.83
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2022-05-11 deposited with the CCDC.	2022-08-22 downloaded from the CCDC.
;
_cell_angle_alpha                100.556(2)
_cell_angle_beta                 96.448(2)
_cell_angle_gamma                91.114(2)
_cell_formula_units_Z            1
_cell_length_a                   12.5676(7)
_cell_length_b                   14.0097(6)
_cell_length_c                   15.1758(9)
_cell_measurement_reflns_used    9320
_cell_measurement_temperature    120(2)
_cell_measurement_theta_max      31.84
_cell_measurement_theta_min      2.25
_cell_volume                     2608.0(2)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX3'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_structure_solution    'SHELXT 2014/5 (Sheldrick, 2014)'
_diffrn_ambient_temperature      120(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Bruker PHOTON-III CPAD'
_diffrn_measurement_method       'φ and ω shuterless scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0498
_diffrn_reflns_av_unetI/netI     0.0239
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.999
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_k_min       -20
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_number            204125
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.999
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         32.012
_diffrn_reflns_theta_min         2.200
_diffrn_source                   'Mo-ImuS 3.0 microfocus tube'
_exptl_absorpt_coefficient_mu    1.473
_exptl_absorpt_correction_T_max  0.7463
_exptl_absorpt_correction_T_min  0.6657
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    1.767
_exptl_crystal_description       plate
_exptl_crystal_F_000             1382
_exptl_crystal_size_max          0.160
_exptl_crystal_size_mid          0.080
_exptl_crystal_size_min          0.060
_refine_diff_density_max         2.415
_refine_diff_density_min         -1.820
_refine_diff_density_rms         0.130
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.075
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     767
_refine_ls_number_reflns         18098
_refine_ls_number_restraints     9
_refine_ls_restrained_S_all      1.107
_refine_ls_R_factor_all          0.0494
_refine_ls_R_factor_gt           0.0429
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0387P)²+9.0241P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1017
_refine_ls_wR_factor_ref         0.1059
_reflns_Friedel_coverage         0.000
_reflns_number_gt                16377
_reflns_number_total             18098
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d2dt01684b1.cif
_cod_data_source_block           Eucplx
_cod_original_cell_volume        2607.9(2)
_cod_database_code               7711099
_shelx_shelxl_version_number     2014/7
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.799
_shelx_estimated_absorpt_t_max   0.917
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.8874(3) 0.9301(4) 0.7449(2) 0.0428(9) Uani 1 1 d . . . . .
H1 H 0.8432 0.8785 0.7554 0.051 Uiso 1 1 calc R U . . .
C2 C 0.9688(4) 0.9726(4) 0.8100(3) 0.0478(11) Uani 1 1 d . . . . .
H2 H 0.9814 0.9506 0.8657 0.057 Uiso 1 1 calc R U . . .
C3 C 1.0315(3) 1.0477(3) 0.7928(3) 0.0457(10) Uani 1 1 d . . . . .
H3 H 1.0885 1.0767 0.8366 0.055 Uiso 1 1 calc R U . . .
C4 C 1.0119(3) 1.0805(3) 0.7127(3) 0.0391(8) Uani 1 1 d . . . . .
H4 H 1.0542 1.1331 0.7018 0.047 Uiso 1 1 calc R U . . .
C5 C 0.9298(3) 1.0365(2) 0.6475(2) 0.0293(6) Uani 1 1 d . . . . .
C6 C 0.9060(3) 1.0673(2) 0.5616(2) 0.0276(6) Uani 1 1 d . . . . .
H6 H 0.9408 1.1232 0.5491 0.033 Uiso 1 1 calc R U . . .
C7 C 0.8567(3) 1.1324(2) 0.4035(2) 0.0280(6) Uani 1 1 d . . . . .
H7A H 0.8382 1.1880 0.4477 0.042 Uiso 1 1 calc R U . . .
H7B H 0.8278 1.1404 0.3427 0.042 Uiso 1 1 calc R U . . .
H7C H 0.9348 1.1288 0.4071 0.042 Uiso 1 1 calc R U . . .
C8 C 0.7388(2) 0.98182(19) 0.36047(19) 0.0197(5) Uani 1 1 d . . . . .
C9 C 0.7021(2) 0.8922(2) 0.37650(18) 0.0188(5) Uani 1 1 d . . . . .
H9 H 0.7255 0.8727 0.4320 0.023 Uiso 1 1 calc R U . . .
C10 C 0.6007(2) 0.86477(19) 0.23763(18) 0.0188(5) Uani 1 1 d . . . . .
C11 C 0.6413(3) 0.9528(2) 0.2217(2) 0.0250(6) Uani 1 1 d . . . . .
H11 H 0.6192 0.9721 0.1659 0.030 Uiso 1 1 calc R U . . .
C12 C 0.4681(3) 0.8402(3) 0.0998(2) 0.0373(9) Uani 1 1 d . . . . .
H12A H 0.5015 0.8214 0.0442 0.056 Uiso 1 1 calc R U . . .
H12B H 0.4660 0.9112 0.1147 0.056 Uiso 1 1 calc R U . . .
H12C H 0.3949 0.8119 0.0910 0.056 Uiso 1 1 calc R U . . .
C13 C 0.4647(2) 0.6489(2) 0.11984(19) 0.0221(5) Uani 1 1 d . . . . .
H13 H 0.4373 0.6675 0.0648 0.027 Uiso 1 1 calc R U . . .
C14 C 0.4456(2) 0.5499(2) 0.13380(19) 0.0216(5) Uani 1 1 d . . . . .
C15 C 0.3852(3) 0.4836(2) 0.0656(2) 0.0325(7) Uani 1 1 d . . . . .
H15 H 0.3618 0.5011 0.0092 0.039 Uiso 1 1 calc R U . . .
C16 C 0.3599(3) 0.3923(3) 0.0813(2) 0.0378(8) Uani 1 1 d . . . . .
H16 H 0.3188 0.3462 0.0359 0.045 Uiso 1 1 calc R U . . .
C17 C 0.3953(3) 0.3690(2) 0.1643(2) 0.0309(7) Uani 1 1 d . . . . .
H17 H 0.3784 0.3070 0.1772 0.037 Uiso 1 1 calc R U . . .
C18 C 0.4561(2) 0.4382(2) 0.2279(2) 0.0230(5) Uani 1 1 d . . . . .
H18 H 0.4806 0.4218 0.2846 0.028 Uiso 1 1 calc R U . . .
C19 C 0.7587(3) 0.6734(2) 0.1644(2) 0.0239(5) Uani 1 1 d . . . . .
H19 H 0.7262 0.7341 0.1650 0.029 Uiso 1 1 calc R U . . .
C20 C 0.8378(3) 0.6500(3) 0.1084(2) 0.0284(6) Uani 1 1 d . . . . .
H20 H 0.8599 0.6943 0.0729 0.034 Uiso 1 1 calc R U . . .
C21 C 0.8839(3) 0.5610(3) 0.1051(2) 0.0325(7) Uani 1 1 d . . . . .
H21 H 0.9372 0.5422 0.0664 0.039 Uiso 1 1 calc R U . . .
C22 C 0.8507(3) 0.4998(2) 0.1596(2) 0.0296(6) Uani 1 1 d . . . . .
H22 H 0.8807 0.4379 0.1586 0.035 Uiso 1 1 calc R U . . .
C23 C 0.7730(2) 0.5299(2) 0.21584(19) 0.0204(5) Uani 1 1 d . . . . .
C24 C 0.7464(2) 0.4688(2) 0.27909(19) 0.0195(5) Uani 1 1 d . . . . .
H24 H 0.7782 0.4077 0.2785 0.023 Uiso 1 1 calc R U . . .
C25 C 0.7312(3) 0.3654(3) 0.4140(3) 0.0367(8) Uani 1 1 d . . . . .
H25A H 0.7121 0.3100 0.3646 0.055 Uiso 1 1 calc R U . . .
H25B H 0.7205 0.3465 0.4715 0.055 Uiso 1 1 calc R U . . .
H25C H 0.8065 0.3855 0.4149 0.055 Uiso 1 1 calc R U . . .
C26 C 0.5827(2) 0.47385(18) 0.45235(17) 0.0150(4) Uani 1 1 d . . . . .
C27 C 0.4430(2) 0.57445(19) 0.47967(18) 0.0174(4) Uani 1 1 d . . . . .
H27 H 0.4012 0.6269 0.4663 0.021 Uiso 1 1 calc R U . . .
C28 C 0.9645(6) 0.6372(5) 0.4121(6) 0.0382(13) Uani 0.55 1 d . . P A 1
C28B C 0.9474(7) 0.6133(7) 0.4518(8) 0.0382(13) Uani 0.45 1 d . . P B 2
C29 C 0.5240(8) 0.8993(7) 0.5981(6) 0.0451(15) Uani 0.55 1 d . . P C 1
C29B C 0.5070(10) 0.8615(8) 0.6213(7) 0.0451(15) Uani 0.45 1 d . . P C 2
C30 C 0.2147(4) 0.6847(5) 0.2550(4) 0.0693(18) Uani 1 1 d D . . . .
C31 C 0.3538(5) 0.7313(3) 0.8749(3) 0.0517(12) Uani 1 1 d . . . . .
C32 C 0.3756(8) 0.8043(4) 0.8211(4) 0.095(3) Uani 1 1 d . . . . .
H32A H 0.4261 0.8546 0.8570 0.143 Uiso 1 1 calc R U . . .
H32B H 0.3086 0.8339 0.8029 0.143 Uiso 1 1 calc R U . . .
H32C H 0.4068 0.7733 0.7671 0.143 Uiso 1 1 calc R U . . .
C33 C 0.0580(5) 0.7311(4) 0.9842(4) 0.0640(16) Uani 1 1 d . . . . .
C34 C 0.1188(7) 0.8208(5) 1.0108(8) 0.114(4) Uani 1 1 d . . . . .
H34A H 0.1559 0.8336 0.9605 0.171 Uiso 1 1 calc R U . . .
H34B H 0.1716 0.8169 1.0626 0.171 Uiso 1 1 calc R U . . .
H34C H 0.0707 0.8736 1.0277 0.171 Uiso 1 1 calc R U . . .
C35 C -0.0092(5) 0.6902(4) 0.7355(4) 0.0556(12) Uani 1 1 d . . . . .
C36 C -0.1209(6) 0.6542(6) 0.7361(5) 0.085(2) Uani 1 1 d . . . . .
H36A H -0.1262 0.5836 0.7154 0.128 Uiso 1 1 calc R U . . .
H36B H -0.1696 0.6852 0.6958 0.128 Uiso 1 1 calc R U . . .
H36C H -0.1408 0.6699 0.7976 0.128 Uiso 1 1 calc R U . . .
N1 N 0.8715(2) 0.9627(2) 0.6668(2) 0.0326(6) Uani 1 1 d . . . . .
N2 N 0.8353(2) 1.01559(18) 0.50278(18) 0.0237(5) Uani 1 1 d . . . . .
N3 N 0.8109(2) 1.04328(17) 0.42304(18) 0.0229(5) Uani 1 1 d . . . . .
N4 N 0.63437(19) 0.83389(17) 0.31445(16) 0.0183(4) Uani 1 1 d . . . . .
N5 N 0.7097(2) 1.01016(18) 0.28226(18) 0.0253(5) Uani 1 1 d . . . . .
N6 N 0.5301(2) 0.80480(18) 0.17321(16) 0.0222(5) Uani 1 1 d . . . . .
N7 N 0.51950(19) 0.71094(17) 0.18325(15) 0.0182(4) Uani 1 1 d . . . . .
N8 N 0.4824(2) 0.52717(17) 0.21416(16) 0.0195(4) Uani 1 1 d . . . . .
N9 N 0.72523(19) 0.61527(18) 0.21788(16) 0.0193(4) Uani 1 1 d . . . . .
N10 N 0.67964(18) 0.49782(16) 0.33562(15) 0.0162(4) Uani 1 1 d . . . . .
N11 N 0.66403(19) 0.44514(17) 0.40058(16) 0.0182(4) Uani 1 1 d . . . . .
N12 N 0.52484(18) 0.54855(16) 0.43311(15) 0.0161(4) Uani 1 1 d . . . . .
N13 N 0.3417(4) 0.6751(3) 0.9164(3) 0.0558(11) Uani 1 1 d . . . . .
N14 N 0.0088(5) 0.6605(4) 0.9611(4) 0.0745(16) Uani 1 1 d . . . . .
N15 N 0.0787(4) 0.7170(3) 0.7376(4) 0.0627(13) Uani 1 1 d . . . . .
O1 O 0.76548(18) 0.68486(17) 0.41271(18) 0.0309(5) Uani 1 1 d . . . . .
O2 O 0.8970(8) 0.7788(7) 0.5264(6) 0.0419(7) Uani 0.55 1 d . . P A 1
O3 O 0.8429(4) 0.6155(4) 0.5318(4) 0.0419(7) Uani 0.55 1 d . . P A 1
O2B O 0.9017(10) 0.7896(9) 0.5081(7) 0.0419(7) Uani 0.45 1 d . . P B 2
O3B O 0.9101(5) 0.7487(5) 0.3605(5) 0.0419(7) Uani 0.45 1 d . . P B 2
O4 O 0.57413(18) 0.75901(16) 0.48076(14) 0.0237(4) Uani 1 1 d . . . . .
O5 O 0.5389(6) 0.7244(4) 0.6278(4) 0.0449(12) Uani 0.55 1 d . . P C 1
O5B O 0.6034(7) 0.7021(5) 0.6206(4) 0.0449(12) Uani 0.45 1 d . . P C 2
O6 O 0.7030(3) 0.8264(3) 0.6082(2) 0.0724(13) Uani 1 1 d . . . . .
O7 O 0.40655(17) 0.69865(17) 0.33126(14) 0.0243(4) Uani 1 1 d . . . . .
O8 O 0.3212(4) 0.8434(3) 0.2988(3) 0.0758(13) Uani 1 1 d . . . . .
O9 O 0.2693(2) 0.7656(3) 0.4191(2) 0.0468(7) Uani 1 1 d . . . . .
P1 P 0.73455(11) 0.91643(9) -0.03281(9) 0.0297(2) Uani 0.7 1 d . . P D 1
P1B P 0.7793(3) 0.8805(2) -0.0264(2) 0.0297(2) Uani 0.3 1 d D . P E 2
F1 F 0.9375(14) 0.546(2) 0.374(3) 0.0448(19) Uani 0.55 1 d . . P A 1
F2 F 0.9712(4) 0.6825(4) 0.3414(4) 0.0565(9) Uani 0.55 1 d . . P A 1
F3 F 1.0595(5) 0.6501(5) 0.4571(5) 0.0565(9) Uani 0.55 1 d . . P A 1
F1B F 0.9581(19) 0.544(3) 0.381(3) 0.0448(19) Uani 0.45 1 d . . P B 2
F2B F 0.9102(5) 0.5700(5) 0.5119(5) 0.0565(9) Uani 0.45 1 d . . P B 2
F3B F 1.0473(7) 0.6359(7) 0.4859(6) 0.0565(9) Uani 0.45 1 d . . P B 2
F4 F 0.5332(6) 0.9381(5) 0.6852(4) 0.0609(14) Uani 0.55 1 d . . P C 1
F5 F 0.4237(5) 0.8864(6) 0.5662(5) 0.0795(18) Uani 0.55 1 d . . P C 1
F6 F 0.5738(7) 0.9639(4) 0.5573(5) 0.0781(18) Uani 0.55 1 d . . P C 1
F4B F 0.5317(7) 0.8903(6) 0.7103(5) 0.0609(14) Uani 0.45 1 d . . P C 2
F5B F 0.4114(6) 0.8137(7) 0.6077(6) 0.0795(18) Uani 0.45 1 d . . P C 2
F6B F 0.4955(10) 0.9393(6) 0.5830(6) 0.0781(18) Uani 0.45 1 d . . P C 2
F7 F 0.2343(6) 0.6468(6) 0.1762(7) 0.0710(13) Uani 0.5 1 d . . P F 1
F8 F 0.2074(5) 0.5942(7) 0.2988(5) 0.0710(13) Uani 0.5 1 d . . P F 1
F9 F 0.1133(6) 0.7048(6) 0.2557(7) 0.0710(13) Uani 0.5 1 d . . P F 1
F7B F 0.2521(6) 0.6894(6) 0.1683(7) 0.0710(13) Uani 0.5 1 d . . P F 2
F8B F 0.1955(6) 0.5997(7) 0.2576(5) 0.0710(13) Uani 0.5 1 d D . P F 2
F9B F 0.1274(6) 0.7428(6) 0.2466(7) 0.0710(13) Uani 0.5 1 d . . P F 2
F10 F 0.8550(4) 0.9428(6) -0.0002(7) 0.0663(14) Uani 0.7 1 d . . P D 1
F11 F 0.7330(7) 0.8490(5) 0.0384(5) 0.0470(9) Uani 0.7 1 d . . P D 1
F12 F 0.6010(4) 0.8942(8) -0.0740(6) 0.115(3) Uani 0.7 1 d . . P D 1
F13 F 0.7282(6) 0.9937(5) -0.1121(5) 0.0639(13) Uani 0.7 1 d . . P D 1
F14 F 0.7699(7) 0.8259(5) -0.1003(5) 0.0820(12) Uani 0.7 1 d . . P D 1
F15 F 0.6791(5) 1.0120(4) 0.0253(4) 0.0820(12) Uani 0.7 1 d . . P D 1
F10B F 0.8873(9) 0.9407(16) -0.0020(17) 0.0663(14) Uani 0.3 1 d D . P E 2
F11B F 0.7374(19) 0.8352(15) 0.0537(13) 0.0470(9) Uani 0.3 1 d D . P E 2
F12B F 0.6476(7) 0.879(2) -0.0640(14) 0.115(3) Uani 0.3 1 d D . P E 2
F13B F 0.7441(17) 0.9666(13) -0.0989(12) 0.0639(13) Uani 0.3 1 d D . P E 2
F14B F 0.7872(19) 0.8149(12) -0.1179(9) 0.0820(12) Uani 0.3 1 d D . P E 2
F15B F 0.7402(13) 0.9882(7) 0.0397(9) 0.0820(12) Uani 0.3 1 d D . P E 2
S1 S 0.85780(11) 0.68639(10) 0.47562(11) 0.0265(2) Uani 0.55 1 d . . P A 1
S1B S 0.87381(14) 0.72039(13) 0.43672(13) 0.0265(2) Uani 0.45 1 d . . P B 2
S2 S 0.60014(7) 0.78504(6) 0.57813(5) 0.02747(15) Uani 1 1 d . . . . .
S3 S 0.31225(6) 0.75772(6) 0.33539(6) 0.02661(15) Uani 1 1 d . . . . .
Eu1 Eu 0.58934(2) 0.66062(2) 0.33300(2) 0.01386(4) Uani 1 1 d . . . . .
H1N H 0.820(4) 0.937(3) 0.628(3) 0.036(12) Uiso 1 1 d . . . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 C1 C2 119.1(4) . . ?
N1 C1 H1 120.4 . . ?
C2 C1 H1 120.4 . . ?
C3 C2 C1 119.1(4) . . ?
C3 C2 H2 120.5 . . ?
C1 C2 H2 120.5 . . ?
C4 C3 C2 120.3(4) . . ?
C4 C3 H3 119.8 . . ?
C2 C3 H3 119.8 . . ?
C3 C4 C5 119.9(4) . . ?
C3 C4 H4 120.0 . . ?
C5 C4 H4 120.0 . . ?
N1 C5 C4 117.6(4) . . ?
N1 C5 C6 119.9(3) . . ?
C4 C5 C6 122.5(4) . . ?
N2 C6 C5 117.3(3) . . ?
N2 C6 H6 121.4 . . ?
C5 C6 H6 121.4 . . ?
N3 C7 H7A 109.5 . . ?
N3 C7 H7B 109.5 . . ?
H7A C7 H7B 109.5 . . ?
N3 C7 H7C 109.5 . . ?
H7A C7 H7C 109.5 . . ?
H7B C7 H7C 109.5 . . ?
N5 C8 N3 116.8(2) . . ?
N5 C8 C9 121.1(3) . . ?
N3 C8 C9 122.0(3) . . ?
N4 C9 C8 120.7(2) . . ?
N4 C9 H9 119.7 . . ?
C8 C9 H9 119.7 . . ?
N4 C10 N6 118.4(2) . . ?
N4 C10 C11 120.1(3) . . ?
N6 C10 C11 121.4(3) . . ?
N5 C11 C10 121.9(3) . . ?
N5 C11 H11 119.0 . . ?
C10 C11 H11 119.0 . . ?
N6 C12 H12A 109.5 . . ?
N6 C12 H12B 109.5 . . ?
H12A C12 H12B 109.5 . . ?
N6 C12 H12C 109.5 . . ?
H12A C12 H12C 109.5 . . ?
H12B C12 H12C 109.5 . . ?
N7 C13 C14 119.3(3) . . ?
N7 C13 H13 120.4 . . ?
C14 C13 H13 120.4 . . ?
N8 C14 C15 122.2(3) . . ?
N8 C14 C13 118.6(2) . . ?
C15 C14 C13 119.1(3) . . ?
C16 C15 C14 119.2(3) . . ?
C16 C15 H15 120.4 . . ?
C14 C15 H15 120.4 . . ?
C15 C16 C17 118.9(3) . . ?
C15 C16 H16 120.5 . . ?
C17 C16 H16 120.5 . . ?
C18 C17 C16 118.4(3) . . ?
C18 C17 H17 120.8 . . ?
C16 C17 H17 120.8 . . ?
N8 C18 C17 123.8(3) . . ?
N8 C18 H18 118.1 . . ?
C17 C18 H18 118.1 . . ?
N9 C19 C20 123.9(3) . . ?
N9 C19 H19 118.1 . . ?
C20 C19 H19 118.1 . . ?
C21 C20 C19 118.7(3) . . ?
C21 C20 H20 120.6 . . ?
C19 C20 H20 120.6 . . ?
C20 C21 C22 118.5(3) . . ?
C20 C21 H21 120.7 . . ?
C22 C21 H21 120.7 . . ?
C21 C22 C23 119.2(3) . . ?
C21 C22 H22 120.4 . . ?
C23 C22 H22 120.4 . . ?
N9 C23 C22 123.0(3) . . ?
N9 C23 C24 118.4(2) . . ?
C22 C23 C24 118.5(3) . . ?
N10 C24 C23 119.7(3) . . ?
N10 C24 H24 120.1 . . ?
C23 C24 H24 120.1 . . ?
N11 C25 H25A 109.5 . . ?
N11 C25 H25B 109.5 . . ?
H25A C25 H25B 109.5 . . ?
N11 C25 H25C 109.5 . . ?
H25A C25 H25C 109.5 . . ?
H25B C25 H25C 109.5 . . ?
N12 C26 N11 117.8(2) . . ?
N12 C26 C27 120.0(2) . 2_666 ?
N11 C26 C27 122.2(2) . 2_666 ?
N12 C27 C26 121.4(2) . 2_666 ?
N12 C27 H27 119.3 . . ?
C26 C27 H27 119.3 2_666 . ?
F3 C28 F1 114.6(9) . . ?
F3 C28 F2 104.5(7) . . ?
F1 C28 F2 104.2(19) . . ?
F3 C28 S1 114.4(6) . . ?
F1 C28 S1 108.4(14) . . ?
F2 C28 S1 110.1(5) . . ?
F2B C28B F3B 103.1(9) . . ?
F2B C28B F1B 106(2) . . ?
F3B C28B F1B 102.3(12) . . ?
F2B C28B S1B 111.7(7) . . ?
F3B C28B S1B 111.6(7) . . ?
F1B C28B S1B 120.1(18) . . ?
F5 C29 F4 109.9(8) . . ?
F5 C29 F6 110.6(10) . . ?
F4 C29 F6 106.2(8) . . ?
F5 C29 S2 113.0(7) . . ?
F4 C29 S2 111.0(7) . . ?
F6 C29 S2 105.9(6) . . ?
F6B C29B F4B 109.1(9) . . ?
F6B C29B F5B 107.2(11) . . ?
F4B C29B F5B 107.5(10) . . ?
F6B C29B S2 113.3(9) . . ?
F4B C29B S2 110.5(9) . . ?
F5B C29B S2 109.0(7) . . ?
F7 C30 F9 111.1(7) . . ?
F8B C30 F9B 116.9(6) . . ?
F8B C30 F7B 108.2(6) . . ?
F9B C30 F7B 97.3(7) . . ?
F7 C30 F8 101.2(7) . . ?
F9 C30 F8 95.7(7) . . ?
F8B C30 S3 121.8(6) . . ?
F7 C30 S3 122.5(5) . . ?
F9 C30 S3 119.0(5) . . ?
F9B C30 S3 105.4(5) . . ?
F7B C30 S3 103.8(5) . . ?
F8 C30 S3 100.2(4) . . ?
N13 C31 C32 177.1(7) . . ?
C31 C32 H32A 109.5 . . ?
C31 C32 H32B 109.5 . . ?
H32A C32 H32B 109.5 . . ?
C31 C32 H32C 109.5 . . ?
H32A C32 H32C 109.5 . . ?
H32B C32 H32C 109.5 . . ?
N14 C33 C34 178.3(9) . . ?
C33 C34 H34A 109.5 . . ?
C33 C34 H34B 109.5 . . ?
H34A C34 H34B 109.5 . . ?
C33 C34 H34C 109.5 . . ?
H34A C34 H34C 109.5 . . ?
H34B C34 H34C 109.5 . . ?
N15 C35 C36 177.7(7) . . ?
C35 C36 H36A 109.5 . . ?
C35 C36 H36B 109.5 . . ?
H36A C36 H36B 109.5 . . ?
C35 C36 H36C 109.5 . . ?
H36A C36 H36C 109.5 . . ?
H36B C36 H36C 109.5 . . ?
C1 N1 C5 123.9(3) . . ?
C1 N1 H1N 118(3) . . ?
C5 N1 H1N 118(3) . . ?
C6 N2 N3 118.4(3) . . ?
N2 N3 C8 115.9(2) . . ?
N2 N3 C7 121.9(3) . . ?
C8 N3 C7 122.2(3) . . ?
C9 N4 C10 118.2(2) . . ?
C9 N4 Eu1 120.65(17) . . ?
C10 N4 Eu1 120.74(17) . . ?
C11 N5 C8 117.9(3) . . ?
N7 N6 C10 116.4(2) . . ?
N7 N6 C12 121.2(2) . . ?
C10 N6 C12 122.4(2) . . ?
C13 N7 N6 119.3(2) . . ?
C13 N7 Eu1 120.02(18) . . ?
N6 N7 Eu1 120.39(17) . . ?
C18 N8 C14 117.4(2) . . ?
C18 N8 Eu1 124.77(19) . . ?
C14 N8 Eu1 117.77(18) . . ?
C19 N9 C23 116.7(2) . . ?
C19 N9 Eu1 125.2(2) . . ?
C23 N9 Eu1 117.85(17) . . ?
C24 N10 N11 119.1(2) . . ?
C24 N10 Eu1 119.79(18) . . ?
N11 N10 Eu1 120.88(16) . . ?
N10 N11 C26 116.1(2) . . ?
N10 N11 C25 120.8(2) . . ?
C26 N11 C25 123.0(2) . . ?
C27 N12 C26 118.6(2) . . ?
C27 N12 Eu1 119.08(17) . . ?
C26 N12 Eu1 121.24(16) . . ?
S1 O1 Eu1 165.09(19) . . ?
S1B O1 Eu1 159.46(19) . . ?
S2 O4 Eu1 153.60(15) . . ?
S3 O7 Eu1 158.89(15) . . ?
F10 P1 F11 89.7(5) . . ?
F10 P1 F14 88.5(5) . . ?
F11 P1 F14 87.5(4) . . ?
F10 P1 F15 100.0(4) . . ?
F11 P1 F15 97.4(4) . . ?
F14 P1 F15 170.2(4) . . ?
F10 P1 F12 175.5(5) . . ?
F11 P1 F12 94.8(4) . . ?
F14 P1 F12 92.4(5) . . ?
F15 P1 F12 78.8(4) . . ?
F10 P1 F13 93.2(5) . . ?
F11 P1 F13 176.6(4) . . ?
F14 P1 F13 94.4(4) . . ?
F15 P1 F13 80.3(3) . . ?
F12 P1 F13 82.3(4) . . ?
F14B P1B F10B 105.7(12) . . ?
F14B P1B F11B 119.7(11) . . ?
F10B P1B F11B 115.7(14) . . ?
F14B P1B F12B 84.2(13) . . ?
F10B P1B F12B 147.0(13) . . ?
F11B P1B F12B 83.7(11) . . ?
F14B P1B F15B 151.5(10) . . ?
F10B P1B F15B 78.3(8) . . ?
F11B P1B F15B 81.1(9) . . ?
F12B P1B F15B 78.9(11) . . ?
F14B P1B F13B 81.0(11) . . ?
F10B P1B F13B 84.6(13) . . ?
F11B P1B F13B 141.5(9) . . ?
F12B P1B F13B 65.5(10) . . ?
F15B P1B F13B 71.1(8) . . ?
O1 S1 O2 117.2(4) . . ?
O1 S1 O3 109.3(3) . . ?
O2 S1 O3 112.8(4) . . ?
O1 S1 C28 106.8(3) . . ?
O2 S1 C28 106.6(5) . . ?
O3 S1 C28 102.9(4) . . ?
O2B S1B O3B 108.9(5) . . ?
O2B S1B O1 121.4(6) . . ?
O3B S1B O1 108.0(3) . . ?
O2B S1B C28B 108.3(6) . . ?
O3B S1B C28B 105.0(5) . . ?
O1 S1B C28B 104.2(3) . . ?
O6 S2 O5B 100.5(4) . . ?
O6 S2 O4 115.57(19) . . ?
O5B S2 O4 112.4(3) . . ?
O6 S2 O5 124.9(3) . . ?
O4 S2 O5 112.9(2) . . ?
O6 S2 C29B 109.6(4) . . ?
O5B S2 C29B 109.2(5) . . ?
O4 S2 C29B 109.2(4) . . ?
O6 S2 C29 97.9(4) . . ?
O4 S2 C29 98.7(3) . . ?
O5 S2 C29 99.3(4) . . ?
O8 S3 O9 117.7(2) . . ?
O8 S3 O7 114.1(2) . . ?
O9 S3 O7 112.71(15) . . ?
O8 S3 C30 102.6(3) . . ?
O9 S3 C30 104.7(3) . . ?
O7 S3 C30 102.6(2) . . ?
O7 Eu1 O1 147.08(8) . . ?
O7 Eu1 O4 74.48(8) . . ?
O1 Eu1 O4 72.77(8) . . ?
O7 Eu1 N4 89.32(8) . . ?
O1 Eu1 N4 79.60(8) . . ?
O4 Eu1 N4 75.81(7) . . ?
O7 Eu1 N12 78.97(7) . . ?
O1 Eu1 N12 94.05(8) . . ?
O4 Eu1 N12 72.13(7) . . ?
N4 Eu1 N12 147.75(7) . . ?
O7 Eu1 N7 69.49(7) . . ?
O1 Eu1 N7 128.40(9) . . ?
O4 Eu1 N7 123.72(8) . . ?
N4 Eu1 N7 62.28(7) . . ?
N12 Eu1 N7 136.62(7) . . ?
O7 Eu1 N10 130.32(8) . . ?
O1 Eu1 N10 68.85(8) . . ?
O4 Eu1 N10 115.20(7) . . ?
N4 Eu1 N10 140.04(7) . . ?
N12 Eu1 N10 61.11(7) . . ?
N7 Eu1 N10 121.08(7) . . ?
O7 Eu1 N8 73.21(8) . . ?
O1 Eu1 N8 137.46(8) . . ?
O4 Eu1 N8 139.84(8) . . ?
N4 Eu1 N8 126.54(7) . . ?
N12 Eu1 N8 78.82(7) . . ?
N7 Eu1 N8 64.27(7) . . ?
N10 Eu1 N8 71.17(7) . . ?
O7 Eu1 N9 137.93(8) . . ?
O1 Eu1 N9 71.87(9) . . ?
O4 Eu1 N9 141.57(8) . . ?
N4 Eu1 N9 83.46(8) . . ?
N12 Eu1 N9 124.87(7) . . ?
N7 Eu1 N9 70.51(8) . . ?
N10 Eu1 N9 64.16(7) . . ?
N8 Eu1 N9 78.22(8) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 N1 1.343(5) . ?
C1 C2 1.382(6) . ?
C1 H1 0.9500 . ?
C2 C3 1.381(7) . ?
C2 H2 0.9500 . ?
C3 C4 1.376(6) . ?
C3 H3 0.9500 . ?
C4 C5 1.395(5) . ?
C4 H4 0.9500 . ?
C5 N1 1.349(5) . ?
C5 C6 1.448(5) . ?
C6 N2 1.293(4) . ?
C6 H6 0.9500 . ?
C7 N3 1.457(4) . ?
C7 H7A 0.9800 . ?
C7 H7B 0.9800 . ?
C7 H7C 0.9800 . ?
C8 N5 1.335(4) . ?
C8 N3 1.393(4) . ?
C8 C9 1.401(4) . ?
C9 N4 1.338(3) . ?
C9 H9 0.9500 . ?
C10 N4 1.344(3) . ?
C10 N6 1.387(4) . ?
C10 C11 1.397(4) . ?
C11 N5 1.324(4) . ?
C11 H11 0.9500 . ?
C12 N6 1.455(4) . ?
C12 H12A 0.9800 . ?
C12 H12B 0.9800 . ?
C12 H12C 0.9800 . ?
C13 N7 1.295(4) . ?
C13 C14 1.459(4) . ?
C13 H13 0.9500 . ?
C14 N8 1.351(4) . ?
C14 C15 1.398(4) . ?
C15 C16 1.380(5) . ?
C15 H15 0.9500 . ?
C16 C17 1.387(5) . ?
C16 H16 0.9500 . ?
C17 C18 1.385(4) . ?
C17 H17 0.9500 . ?
C18 N8 1.342(4) . ?
C18 H18 0.9500 . ?
C19 N9 1.344(3) . ?
C19 C20 1.385(4) . ?
C19 H19 0.9500 . ?
C20 C21 1.380(5) . ?
C20 H20 0.9500 . ?
C21 C22 1.385(4) . ?
C21 H21 0.9500 . ?
C22 C23 1.389(4) . ?
C22 H22 0.9500 . ?
C23 N9 1.346(4) . ?
C23 C24 1.460(4) . ?
C24 N10 1.285(3) . ?
C24 H24 0.9500 . ?
C25 N11 1.443(4) . ?
C25 H25A 0.9800 . ?
C25 H25B 0.9800 . ?
C25 H25C 0.9800 . ?
C26 N12 1.343(3) . ?
C26 N11 1.380(3) . ?
C26 C27 1.396(3) 2_666 ?
C27 N12 1.332(3) . ?
C27 C26 1.396(3) 2_666 ?
C27 H27 0.9500 . ?
C28 F3 1.298(10) . ?
C28 F1 1.32(3) . ?
C28 F2 1.352(10) . ?
C28 S1 1.813(8) . ?
C28B F2B 1.305(13) . ?
C28B F3B 1.313(12) . ?
C28B F1B 1.34(4) . ?
C28B S1B 1.814(9) . ?
C29 F5 1.296(12) . ?
C29 F4 1.325(10) . ?
C29 F6 1.365(13) . ?
C29 S2 1.875(10) . ?
C29B F6B 1.329(13) . ?
C29B F4B 1.336(12) . ?
C29B F5B 1.340(15) . ?
C29B S2 1.707(11) . ?
C30 F8B 1.219(11) . ?
C30 F7 1.269(11) . ?
C30 F9 1.311(9) . ?
C30 F9B 1.387(10) . ?
C30 F7B 1.458(12) . ?
C30 F8 1.542(13) . ?
C30 S3 1.787(5) . ?
C31 N13 1.112(6) . ?
C31 C32 1.461(8) . ?
C32 H32A 0.9800 . ?
C32 H32B 0.9800 . ?
C32 H32C 0.9800 . ?
C33 N14 1.133(8) . ?
C33 C34 1.427(9) . ?
C34 H34A 0.9800 . ?
C34 H34B 0.9800 . ?
C34 H34C 0.9800 . ?
C35 N15 1.155(7) . ?
C35 C36 1.485(9) . ?
C36 H36A 0.9800 . ?
C36 H36B 0.9800 . ?
C36 H36C 0.9800 . ?
N1 H1N 0.85(5) . ?
N2 N3 1.342(4) . ?
N4 Eu1 2.554(2) . ?
N6 N7 1.357(3) . ?
N7 Eu1 2.568(2) . ?
N8 Eu1 2.584(2) . ?
N9 Eu1 2.584(2) . ?
N10 N11 1.364(3) . ?
N10 Eu1 2.572(2) . ?
N12 Eu1 2.556(2) . ?
O1 S1 1.414(3) . ?
O1 S1B 1.425(3) . ?
O1 Eu1 2.387(2) . ?
O2 S1 1.427(10) . ?
O3 S1 1.444(6) . ?
O2B S1B 1.324(13) . ?
O3B S1B 1.408(7) . ?
O4 S2 1.454(2) . ?
O4 Eu1 2.437(2) . ?
O5 S2 1.490(5) . ?
O5B S2 1.427(7) . ?
O6 S2 1.399(3) . ?
O7 S3 1.459(2) . ?
O7 Eu1 2.367(2) . ?
O8 S3 1.420(3) . ?
O9 S3 1.423(3) . ?
P1 F10 1.555(5) . ?
P1 F11 1.562(3) . ?
P1 F14 1.582(5) . ?
P1 F15 1.673(5) . ?
P1 F12 1.725(6) . ?
P1 F13 1.756(4) . ?
P1B F14B 1.533(8) . ?
P1B F10B 1.556(9) . ?
P1B F11B 1.602(8) . ?
P1B F12B 1.687(8) . ?
P1B F15B 1.763(8) . ?
P1B F13B 1.805(7) . ?
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
N1 H1N O6 0.85(5) 2.06(5) 2.779(5) 141(4) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N1 C1 C2 C3 0.1(7) . . . . ?
C1 C2 C3 C4 1.1(7) . . . . ?
C2 C3 C4 C5 -1.5(6) . . . . ?
C3 C4 C5 N1 0.6(5) . . . . ?
C3 C4 C5 C6 -179.5(3) . . . . ?
N1 C5 C6 N2 -6.7(5) . . . . ?
C4 C5 C6 N2 173.5(3) . . . . ?
N5 C8 C9 N4 -1.8(4) . . . . ?
N3 C8 C9 N4 -178.8(3) . . . . ?
N4 C10 C11 N5 -2.9(5) . . . . ?
N6 C10 C11 N5 -179.2(3) . . . . ?
N7 C13 C14 N8 2.4(4) . . . . ?
N7 C13 C14 C15 179.1(3) . . . . ?
N8 C14 C15 C16 1.6(6) . . . . ?
C13 C14 C15 C16 -175.0(4) . . . . ?
C14 C15 C16 C17 -0.1(6) . . . . ?
C15 C16 C17 C18 -0.8(6) . . . . ?
C16 C17 C18 N8 0.4(6) . . . . ?
N9 C19 C20 C21 1.6(5) . . . . ?
C19 C20 C21 C22 -1.5(6) . . . . ?
C20 C21 C22 C23 -0.3(6) . . . . ?
C21 C22 C23 N9 2.3(5) . . . . ?
C21 C22 C23 C24 -174.2(3) . . . . ?
N9 C23 C24 N10 -0.9(4) . . . . ?
C22 C23 C24 N10 175.7(3) . . . . ?
C2 C1 N1 C5 -1.0(6) . . . . ?
C4 C5 N1 C1 0.6(5) . . . . ?
C6 C5 N1 C1 -179.3(3) . . . . ?
C5 C6 N2 N3 179.3(3) . . . . ?
C6 N2 N3 C8 176.5(3) . . . . ?
C6 N2 N3 C7 -3.8(4) . . . . ?
N5 C8 N3 N2 177.1(3) . . . . ?
C9 C8 N3 N2 -5.8(4) . . . . ?
N5 C8 N3 C7 -2.6(4) . . . . ?
C9 C8 N3 C7 174.4(3) . . . . ?
C8 C9 N4 C10 -1.7(4) . . . . ?
C8 C9 N4 Eu1 170.8(2) . . . . ?
N6 C10 N4 C9 -179.7(3) . . . . ?
C11 C10 N4 C9 3.9(4) . . . . ?
N6 C10 N4 Eu1 7.8(4) . . . . ?
C11 C10 N4 Eu1 -168.5(2) . . . . ?
C10 C11 N5 C8 -0.5(5) . . . . ?
N3 C8 N5 C11 180.0(3) . . . . ?
C9 C8 N5 C11 2.9(5) . . . . ?
N4 C10 N6 N7 -14.6(4) . . . . ?
C11 C10 N6 N7 161.7(3) . . . . ?
N4 C10 N6 C12 163.8(3) . . . . ?
C11 C10 N6 C12 -20.0(5) . . . . ?
C14 C13 N7 N6 -174.8(3) . . . . ?
C14 C13 N7 Eu1 -1.4(4) . . . . ?
C10 N6 N7 C13 -172.0(3) . . . . ?
C12 N6 N7 C13 9.6(4) . . . . ?
C10 N6 N7 Eu1 14.6(3) . . . . ?
C12 N6 N7 Eu1 -163.8(3) . . . . ?
C17 C18 N8 C14 1.0(5) . . . . ?
C17 C18 N8 Eu1 177.5(3) . . . . ?
C15 C14 N8 C18 -2.0(5) . . . . ?
C13 C14 N8 C18 174.6(3) . . . . ?
C15 C14 N8 Eu1 -178.8(3) . . . . ?
C13 C14 N8 Eu1 -2.2(4) . . . . ?
C20 C19 N9 C23 0.3(5) . . . . ?
C20 C19 N9 Eu1 174.8(2) . . . . ?
C22 C23 N9 C19 -2.2(4) . . . . ?
C24 C23 N9 C19 174.3(3) . . . . ?
C22 C23 N9 Eu1 -177.1(3) . . . . ?
C24 C23 N9 Eu1 -0.7(3) . . . . ?
C23 C24 N10 N11 -173.1(2) . . . . ?
C23 C24 N10 Eu1 2.0(4) . . . . ?
C24 N10 N11 C26 -172.8(2) . . . . ?
Eu1 N10 N11 C26 12.2(3) . . . . ?
C24 N10 N11 C25 8.3(4) . . . . ?
Eu1 N10 N11 C25 -166.8(3) . . . . ?
N12 C26 N11 N10 1.7(4) . . . . ?
C27 C26 N11 N10 179.1(2) 2_666 . . . ?
N12 C26 N11 C25 -179.4(3) . . . . ?
C27 C26 N11 C25 -2.0(4) 2_666 . . . ?
C26 C27 N12 C26 0.4(4) 2_666 . . . ?
C26 C27 N12 Eu1 -167.86(19) 2_666 . . . ?
N11 C26 N12 C27 177.0(2) . . . . ?
C27 C26 N12 C27 -0.4(4) 2_666 . . . ?
N11 C26 N12 Eu1 -15.0(3) . . . . ?
C27 C26 N12 Eu1 167.60(19) 2_666 . . . ?
Eu1 O1 S1 O2 -113.0(7) . . . . ?
Eu1 O1 S1 O3 16.9(7) . . . . ?
Eu1 O1 S1 C28 127.6(7) . . . . ?
F3 C28 S1 O1 167.8(6) . . . . ?
F1 C28 S1 O1 -63.0(16) . . . . ?
F2 C28 S1 O1 50.5(5) . . . . ?
F3 C28 S1 O2 41.7(7) . . . . ?
F1 C28 S1 O2 171.0(16) . . . . ?
F2 C28 S1 O2 -75.6(6) . . . . ?
F3 C28 S1 O3 -77.1(7) . . . . ?
F1 C28 S1 O3 52.1(16) . . . . ?
F2 C28 S1 O3 165.6(5) . . . . ?
Eu1 O1 S1B O2B 104.2(7) . . . . ?
Eu1 O1 S1B O3B -22.4(6) . . . . ?
Eu1 O1 S1B C28B -133.6(6) . . . . ?
F2B C28B S1B O2B 73.6(8) . . . . ?
F3B C28B S1B O2B -41.2(10) . . . . ?
F1B C28B S1B O2B -161(2) . . . . ?
F2B C28B S1B O3B -170.2(6) . . . . ?
F3B C28B S1B O3B 75.0(9) . . . . ?
F1B C28B S1B O3B -45(2) . . . . ?
F2B C28B S1B O1 -56.8(7) . . . . ?
F3B C28B S1B O1 -171.6(7) . . . . ?
F1B C28B S1B O1 69(2) . . . . ?
Eu1 O4 S2 O6 71.1(4) . . . . ?
Eu1 O4 S2 O5B -43.5(5) . . . . ?
Eu1 O4 S2 O5 -81.8(4) . . . . ?
Eu1 O4 S2 C29B -164.8(5) . . . . ?
Eu1 O4 S2 C29 174.2(4) . . . . ?
F6B C29B S2 O6 73.3(10) . . . . ?
F4B C29B S2 O6 -49.5(9) . . . . ?
F5B C29B S2 O6 -167.5(7) . . . . ?
F6B C29B S2 O5B -177.5(9) . . . . ?
F4B C29B S2 O5B 59.7(9) . . . . ?
F5B C29B S2 O5B -58.3(9) . . . . ?
F6B C29B S2 O4 -54.3(10) . . . . ?
F4B C29B S2 O4 -177.1(7) . . . . ?
F5B C29B S2 O4 65.0(9) . . . . ?
F5 C29 S2 O6 172.4(7) . . . . ?
F4 C29 S2 O6 -63.7(8) . . . . ?
F6 C29 S2 O6 51.2(6) . . . . ?
F5 C29 S2 O4 54.9(8) . . . . ?
F4 C29 S2 O4 178.8(7) . . . . ?
F6 C29 S2 O4 -66.3(6) . . . . ?
F5 C29 S2 O5 -60.2(8) . . . . ?
F4 C29 S2 O5 63.8(8) . . . . ?
F6 C29 S2 O5 178.6(6) . . . . ?
Eu1 O7 S3 O8 33.9(5) . . . . ?
Eu1 O7 S3 O9 -103.8(4) . . . . ?
Eu1 O7 S3 C30 144.2(4) . . . . ?
F8B C30 S3 O8 170.6(6) . . . . ?
F7 C30 S3 O8 70.3(8) . . . . ?
F9 C30 S3 O8 -76.8(8) . . . . ?
F9B C30 S3 O8 -53.3(6) . . . . ?
F7B C30 S3 O8 48.5(5) . . . . ?
F8 C30 S3 O8 -179.3(4) . . . . ?
F8B C30 S3 O9 -66.0(6) . . . . ?
F7 C30 S3 O9 -166.2(7) . . . . ?
F9 C30 S3 O9 46.6(8) . . . . ?
F9B C30 S3 O9 70.2(6) . . . . ?
F7B C30 S3 O9 171.9(5) . . . . ?
F8 C30 S3 O9 -55.8(4) . . . . ?
F8B C30 S3 O7 51.9(6) . . . . ?
F7 C30 S3 O7 -48.3(8) . . . . ?
F9 C30 S3 O7 164.5(8) . . . . ?
F9B C30 S3 O7 -171.9(6) . . . . ?
F7B C30 S3 O7 -70.2(5) . . . . ?
F8 C30 S3 O7 62.1(4) . . . . ?
