#------------------------------------------------------------------------------
#$Date: 2022-09-02 01:51:42 +0300 (Fri, 02 Sep 2022) $
#$Revision: 277566 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/71/11/7711110.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7711110
loop_
_publ_author_name
'Rain Talosig, A.'
'Cosio, Mario N.'
'Morse, Benjamin'
'Nguyen, Vinh T.'
'Kosanovich, Alex J.'
'Pell, Christopher J.'
'Li, Chun'
'Bhuvanesh, Nattamai'
'Zhou, Jia'
'Larsen, Anna S.'
'Ozerov, Oleg. V.'
_publ_section_title
;
 Distinct modes of Si--H binding to Rh in complexes of a
 phosphine-diarylamido-silane (SiNP) pincer ligand
;
_journal_name_full               'Dalton Transactions'
_journal_paper_doi               10.1039/D2DT02175G
_journal_year                    2022
_chemical_formula_moiety         'C29 H50 N O3 P2 Rh Si'
_chemical_formula_sum            'C29 H50 N O3 P2 Rh Si'
_chemical_formula_weight         653.64
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     dual
_audit_creation_date             2019-06-17
_audit_creation_method
;
Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_audit_update_record
;
2020-09-24 deposited with the CCDC.	2022-08-31 downloaded from the CCDC.
;
_cell_angle_alpha                103.562(7)
_cell_angle_beta                 105.146(8)
_cell_angle_gamma                100.236(8)
_cell_formula_units_Z            4
_cell_length_a                   12.957(4)
_cell_length_b                   14.254(4)
_cell_length_c                   19.296(5)
_cell_measurement_reflns_used    9023
_cell_measurement_temperature    110.0
_cell_measurement_theta_max      27.396
_cell_measurement_theta_min      2.156
_cell_volume                     3233.8(16)
_computing_cell_refinement
'SAINT V8.38 Bruker AXS Inc., Madison, WI, USA.'
_computing_data_reduction
'SAINT V8.38 Bruker AXS Inc., Madison, WI, USA.'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'ShelXT (Sheldrick, 2015)'
_diffrn_ambient_temperature      110.0
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Bruker PHOTON'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0566
_diffrn_reflns_av_unetI/netI     0.0738
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.999
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_number            34328
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.999
_diffrn_reflns_theta_full        25.000
_diffrn_reflns_theta_max         25.000
_diffrn_reflns_theta_min         1.610
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    0.693
_exptl_absorpt_correction_T_max  0.4305
_exptl_absorpt_correction_T_min  0.3939
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
'SADABS-2016/2 (Bruker,2016/2) was used for absorption correction. wR2(int) was 0.0739 before and 0.0567 after correction. The Ratio of minimum to maximum transmission is 0.9150. The λ/2 correction factor is Not present.'
_exptl_crystal_colour            brown
_exptl_crystal_colour_primary    brown
_exptl_crystal_density_diffrn    1.343
_exptl_crystal_description       block
_exptl_crystal_F_000             1376
_exptl_crystal_size_max          0.249
_exptl_crystal_size_mid          0.214
_exptl_crystal_size_min          0.182
_refine_diff_density_max         0.496
_refine_diff_density_min         -0.504
_refine_diff_density_rms         0.090
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.029
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     755
_refine_ls_number_reflns         11373
_refine_ls_number_restraints     244
_refine_ls_restrained_S_all      1.018
_refine_ls_R_factor_all          0.0721
_refine_ls_R_factor_gt           0.0445
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0283P)²+1.6050P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0756
_refine_ls_wR_factor_ref         0.0830
_reflns_Friedel_coverage         0.000
_reflns_number_gt                8389
_reflns_number_total             11373
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d2dt02175g3.cif
_cod_data_source_block           mc328
_cod_original_cell_volume        3233.8(15)
_cod_database_code               7711110
_shelx_shelxl_version_number     2018/3
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_max   0.884
_shelx_estimated_absorpt_t_min   0.846
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2. Restrained distances
 C25-C24 \\sim C26A-C24A \\sim C26-C24 \\sim C25A-C24A
 with sigma of 0.02
 Si1-C24A \\sim Si1-C24
 with sigma of 0.02
 Si1-C21 \\sim Si1-C21A
 with sigma of 0.02
 C22A-C21A \\sim C23-C21 \\sim C23A-C21A \\sim C22-C21
 with sigma of 0.02
 P2-O3 \\sim P2-O3A
 with sigma of 0.02
 O3A-C29A \\sim O3-C29
 with sigma of 0.02
 Si1B-H1B \\sim Si1-H1
 with sigma of 0.02
 Rh1-H1 \\sim Rh1B-H1B
 with sigma of 0.02
3. Uiso/Uaniso restraints and constraints
C24 \\sim C25 \\sim C26 \\sim C24A \\sim C25A \\sim C26A: within 2A with sigma
of 0.02 and sigma for terminal atoms of 0.04
C21 \\sim C22 \\sim C23 \\sim C21A \\sim C22A \\sim C23A: within 2A with sigma
of 0.02 and sigma for terminal atoms of 0.04
O3 \\sim C29 \\sim O3A \\sim C29A \\sim P2: within 2A with sigma of 0.02 and
sigma for terminal atoms of 0.04
Uanis(C24) = Uanis(C24A)
Uanis(C21) = Uanis(C21A)
Uanis(C22A) = Uanis(C23A) = Uanis(C22)
4. Rigid body (RIGU) restrains
 C24, C25, C26, C24A, C25A, C26A
 with sigma for 1-2 distances of 0.02 and sigma for 1-3 distances of 0.02
 C21, C22, C23, C21A, C22A, C23A
 with sigma for 1-2 distances of 0.02 and sigma for 1-3 distances of 0.02
 P2, O3, C29, O3A, C29A
 with sigma for 1-2 distances of 0.02 and sigma for 1-3 distances of 0.02
5. Others
 Sof(C21A)=Sof(H21A)=Sof(C22A)=Sof(H22D)=Sof(H22E)=Sof(H22F)=Sof(C23A)=
 Sof(H23D)=Sof(H23E)=Sof(H23F)=Sof(C24A)=Sof(H24A)=Sof(C25A)=Sof(H25D)=
 Sof(H25E)=Sof(H25F)=Sof(C26A)=Sof(H26D)=Sof(H26E)=Sof(H26F)=Sof(O3A)=Sof(C29A)=
 Sof(H29D)=Sof(H29E)=Sof(H29F)=1-FVAR(1)
 Sof(C21)=Sof(H21)=Sof(C22)=Sof(H22A)=Sof(H22B)=Sof(H22C)=Sof(C23)=Sof(H23A)=
 Sof(H23B)=Sof(H23C)=Sof(C24)=Sof(H24)=Sof(C25)=Sof(H25A)=Sof(H25B)=Sof(H25C)=
 Sof(C26)=Sof(H26A)=Sof(H26B)=Sof(H26C)=Sof(O3)=Sof(C29)=Sof(H29A)=Sof(H29B)=
 Sof(H29C)=FVAR(1)
6.a Ternary CH refined with riding coordinates:
 C15(H15), C18(H18), C21(H21), C21A(H21A), C24(H24), C24A(H24A), C15B(H15B),
 C18B(H18B), C21B(H21B), C24B(H24B)
6.b Aromatic/amide H refined with riding coordinates:
 C3(H3), C5(H5), C6(H6), C9(H9), C10(H10), C12(H12), C3B(H3B), C5B(H5B),
 C6B(H6B), C9B(H9B), C10B(H10B), C12B(H12B)
6.c Idealised Me refined as rotating group:
 C7(H7A,H7B,H7C), C14(H14A,H14B,H14C), C16(H16A,H16B,H16C), C17(H17A,H17B,
 H17C), C19(H19A,H19B,H19C), C20(H20A,H20B,H20C), C22(H22A,H22B,H22C), C23(H23A,
 H23B,H23C), C22A(H22D,H22E,H22F), C23A(H23D,H23E,H23F), C25(H25A,H25B,H25C),
 C26(H26A,H26B,H26C), C25A(H25D,H25E,H25F), C26A(H26D,H26E,H26F), C27(H27A,H27B,
 H27C), C28(H28A,H28B,H28C), C29(H29A,H29B,H29C), C29A(H29D,H29E,H29F),
 C7B(H7BA,H7BB,H7BC), C14B(H14D,H14E,H14F), C16B(H16D,H16E,H16F), C17B(H17D,
 H17E,H17F), C19B(H19D,H19E,H19F), C20B(H20D,H20E,H20F), C22B(H22G,H22H,H22I),
 C23B(H23G,H23H,H23I), C25B(H25G,H25H,H25I), C26B(H26G,H26H,H26I), C27B(H27D,
 H27E,H27F), C28B(H28D,H28E,H28F), C29B(H29G,H29H,H29I)
;
_olex2_submission_special_instructions 'No special instructions were received'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Rh1 Rh 0.70866(2) 0.17788(2) 0.04193(2) 0.01828(9) Uani 1 1 d D . . . .
P1 P 0.79472(8) 0.22949(7) -0.03835(5) 0.0188(2) Uani 1 1 d . . . . .
P2 P 0.56394(8) 0.23161(8) 0.00365(6) 0.0242(2) Uani 1 1 d D U . . .
Si1 Si 0.72704(8) 0.18326(8) 0.17278(6) 0.0195(2) Uani 1 1 d D . . . .
O1 O 0.51714(19) 0.19932(19) -0.08594(13) 0.0264(6) Uani 1 1 d . . . . .
O2 O 0.4557(2) 0.2025(2) 0.02789(15) 0.0316(7) Uani 1 1 d . . . . .
N1 N 0.8508(2) 0.1270(2) 0.07244(15) 0.0183(7) Uani 1 1 d . . . . .
C1 C 0.9438(3) 0.1625(2) 0.05303(18) 0.0166(8) Uani 1 1 d . . . . .
C2 C 0.9328(3) 0.2174(2) 0.00071(19) 0.0163(8) Uani 1 1 d . . . . .
C3 C 1.0236(3) 0.2587(3) -0.01804(19) 0.0196(9) Uani 1 1 d . . . . .
H3 H 1.012638 0.294591 -0.053959 0.024 Uiso 1 1 calc R . . . .
C4 C 1.1288(3) 0.2499(3) 0.01317(19) 0.0199(9) Uani 1 1 d . . . . .
C5 C 1.1394(3) 0.1958(3) 0.06485(19) 0.0204(9) Uani 1 1 d . . . . .
H5 H 1.210470 0.187753 0.087571 0.025 Uiso 1 1 calc R . . . .
C6 C 1.0517(3) 0.1534(3) 0.08449(19) 0.0198(9) Uani 1 1 d . . . . .
H6 H 1.063904 0.117131 0.120073 0.024 Uiso 1 1 calc R . . . .
C7 C 1.2259(3) 0.2973(3) -0.0068(2) 0.0268(10) Uani 1 1 d . . . . .
H7A H 1.207736 0.279178 -0.061551 0.040 Uiso 1 1 calc GR . . . .
H7B H 1.290073 0.273575 0.014414 0.040 Uiso 1 1 calc GR . . . .
H7C H 1.243053 0.369991 0.013872 0.040 Uiso 1 1 calc GR . . . .
C8 C 0.8610(3) 0.0696(3) 0.12363(19) 0.0179(8) Uani 1 1 d . . . . .
C9 C 0.9098(3) -0.0101(3) 0.11751(19) 0.0204(9) Uani 1 1 d . . . . .
H9 H 0.937276 -0.028863 0.076606 0.024 Uiso 1 1 calc R . . . .
C10 C 0.9193(3) -0.0626(3) 0.1700(2) 0.0232(9) Uani 1 1 d . . . . .
H10 H 0.952840 -0.116789 0.164326 0.028 Uiso 1 1 calc R . . . .
C11 C 0.8802(3) -0.0371(3) 0.2309(2) 0.0225(9) Uani 1 1 d . . . . .
C12 C 0.8260(3) 0.0390(3) 0.23432(19) 0.0225(9) Uani 1 1 d . . . . .
H12 H 0.795980 0.055721 0.274189 0.027 Uiso 1 1 calc R . . . .
C13 C 0.8139(3) 0.0919(3) 0.18110(19) 0.0189(9) Uani 1 1 d . . . . .
C14 C 0.8934(3) -0.0919(3) 0.2896(2) 0.0316(10) Uani 1 1 d . . . . .
H14A H 0.830270 -0.150060 0.273849 0.047 Uiso 1 1 calc GR . . . .
H14B H 0.896729 -0.047123 0.337697 0.047 Uiso 1 1 calc GR . . . .
H14C H 0.961848 -0.113889 0.295514 0.047 Uiso 1 1 calc GR . . . .
C15 C 0.8149(3) 0.3548(3) -0.0517(2) 0.0261(10) Uani 1 1 d . . . . .
H15 H 0.868884 0.359685 -0.080253 0.031 Uiso 1 1 calc R . . . .
C16 C 0.8667(3) 0.4355(3) 0.0237(2) 0.0374(11) Uani 1 1 d . . . . .
H16A H 0.815348 0.433895 0.053037 0.056 Uiso 1 1 calc GR . . . .
H16B H 0.882424 0.500997 0.015328 0.056 Uiso 1 1 calc GR . . . .
H16C H 0.935709 0.423499 0.051369 0.056 Uiso 1 1 calc GR . . . .
C17 C 0.7093(3) 0.3734(3) -0.0977(2) 0.0367(11) Uani 1 1 d . . . . .
H17A H 0.675644 0.318985 -0.144833 0.055 Uiso 1 1 calc GR . . . .
H17B H 0.727288 0.436802 -0.108876 0.055 Uiso 1 1 calc GR . . . .
H17C H 0.657207 0.376324 -0.068928 0.055 Uiso 1 1 calc GR . . . .
C18 C 0.7423(3) 0.1396(3) -0.13400(19) 0.0230(9) Uani 1 1 d . . . . .
H18 H 0.662123 0.135998 -0.155419 0.028 Uiso 1 1 calc R . . . .
C19 C 0.8008(3) 0.1677(3) -0.1884(2) 0.0337(11) Uani 1 1 d . . . . .
H19A H 0.786376 0.229819 -0.197113 0.051 Uiso 1 1 calc GR . . . .
H19B H 0.772934 0.114203 -0.236157 0.051 Uiso 1 1 calc GR . . . .
H19C H 0.880592 0.177014 -0.166664 0.051 Uiso 1 1 calc GR . . . .
C20 C 0.7521(3) 0.0364(3) -0.1281(2) 0.0297(10) Uani 1 1 d . . . . .
H20A H 0.830370 0.036871 -0.110361 0.045 Uiso 1 1 calc GR . . . .
H20B H 0.716545 -0.013003 -0.177684 0.045 Uiso 1 1 calc GR . . . .
H20C H 0.715697 0.018987 -0.092643 0.045 Uiso 1 1 calc GR . . . .
C21 C 0.6069(13) 0.1499(11) 0.2091(10) 0.0230(17) Uani 0.553(4) 1 d D U P A 1
H21 H 0.549653 0.181589 0.185523 0.028 Uiso 0.553(4) 1 calc R . P A 1
C22 C 0.5507(17) 0.0378(10) 0.1838(14) 0.0270(15) Uani 0.553(4) 1 d D U P A 1
H22A H 0.535316 0.010961 0.129432 0.041 Uiso 0.553(4) 1 calc GR . P A 1
H22B H 0.481241 0.027402 0.195593 0.041 Uiso 0.553(4) 1 calc GR . P A 1
H22C H 0.599763 0.003380 0.210052 0.041 Uiso 0.553(4) 1 calc GR . P A 1
C23 C 0.6317(6) 0.1922(5) 0.2929(4) 0.031(2) Uani 0.553(4) 1 d D U P A 1
H23A H 0.685599 0.161855 0.319355 0.046 Uiso 0.553(4) 1 calc GR . P A 1
H23B H 0.563432 0.177582 0.305706 0.046 Uiso 0.553(4) 1 calc GR . P A 1
H23C H 0.662197 0.264623 0.307918 0.046 Uiso 0.553(4) 1 calc GR . P A 1
C21A C 0.6160(17) 0.1609(13) 0.2193(14) 0.0230(17) Uani 0.447(4) 1 d D U P A 2
H21A H 0.656551 0.170728 0.273249 0.028 Uiso 0.447(4) 1 calc R . P A 2
C22A C 0.5391(7) 0.2298(6) 0.2197(5) 0.0270(15) Uani 0.447(4) 1 d D U P A 2
H22D H 0.582961 0.299310 0.241428 0.041 Uiso 0.447(4) 1 calc GR . P A 2
H22E H 0.491653 0.214841 0.249828 0.041 Uiso 0.447(4) 1 calc GR . P A 2
H22F H 0.493084 0.219809 0.168076 0.041 Uiso 0.447(4) 1 calc GR . P A 2
C23A C 0.545(2) 0.0530(13) 0.1890(17) 0.0270(15) Uani 0.447(4) 1 d D U P A 2
H23D H 0.502083 0.039196 0.136039 0.041 Uiso 0.447(4) 1 calc GR . P A 2
H23E H 0.494374 0.043507 0.218113 0.041 Uiso 0.447(4) 1 calc GR . P A 2
H23F H 0.592843 0.007209 0.193346 0.041 Uiso 0.447(4) 1 calc GR . P A 2
C24 C 0.8172(12) 0.3121(8) 0.2290(9) 0.0196(19) Uani 0.553(4) 1 d D U P A 1
H24 H 0.835308 0.313015 0.282889 0.024 Uiso 0.553(4) 1 calc R . P A 1
C25 C 0.9284(11) 0.3402(14) 0.2158(9) 0.021(3) Uani 0.553(4) 1 d D U P A 1
H25A H 0.969800 0.290717 0.224839 0.031 Uiso 0.553(4) 1 calc GR . P A 1
H25B H 0.970761 0.406193 0.250257 0.031 Uiso 0.553(4) 1 calc GR . P A 1
H25C H 0.915781 0.341838 0.163801 0.031 Uiso 0.553(4) 1 calc GR . P A 1
C26 C 0.7499(6) 0.3876(5) 0.2209(4) 0.030(2) Uani 0.553(4) 1 d D U P A 1
H26A H 0.733312 0.392802 0.169606 0.045 Uiso 0.553(4) 1 calc GR . P A 1
H26B H 0.792168 0.452789 0.256689 0.045 Uiso 0.553(4) 1 calc GR . P A 1
H26C H 0.680716 0.366197 0.231156 0.045 Uiso 0.553(4) 1 calc GR . P A 1
C24A C 0.8021(17) 0.3193(10) 0.2246(10) 0.0196(19) Uani 0.447(4) 1 d D U P A 2
H24A H 0.748997 0.361220 0.214356 0.024 Uiso 0.447(4) 1 calc R . P A 2
C25A C 0.8438(8) 0.3351(7) 0.3092(5) 0.041(3) Uani 0.447(4) 1 d D U P A 2
H25D H 0.780828 0.318976 0.327256 0.061 Uiso 0.447(4) 1 calc GR . P A 2
H25E H 0.884702 0.404945 0.334848 0.061 Uiso 0.447(4) 1 calc GR . P A 2
H25F H 0.892803 0.291619 0.319823 0.061 Uiso 0.447(4) 1 calc GR . P A 2
C26A C 0.9018(15) 0.3558(17) 0.2004(12) 0.031(4) Uani 0.447(4) 1 d D U P A 2
H26D H 0.951925 0.312091 0.206470 0.047 Uiso 0.447(4) 1 calc GR . P A 2
H26E H 0.940959 0.424160 0.231675 0.047 Uiso 0.447(4) 1 calc GR . P A 2
H26F H 0.876408 0.354341 0.147572 0.047 Uiso 0.447(4) 1 calc GR . P A 2
C27 C 0.4220(3) 0.2264(3) -0.1264(2) 0.0419(12) Uani 1 1 d . . . . .
H27A H 0.398519 0.188425 -0.179746 0.063 Uiso 1 1 calc GR . . . .
H27B H 0.441416 0.297981 -0.121152 0.063 Uiso 1 1 calc GR . . . .
H27C H 0.361476 0.211281 -0.105919 0.063 Uiso 1 1 calc GR . . . .
C28 C 0.3960(3) 0.0992(3) 0.0044(2) 0.0405(12) Uani 1 1 d . . . . .
H28A H 0.366997 0.075120 -0.050605 0.061 Uiso 1 1 calc GR . . . .
H28B H 0.334539 0.092407 0.025109 0.061 Uiso 1 1 calc GR . . . .
H28C H 0.445838 0.059790 0.022695 0.061 Uiso 1 1 calc GR . . . .
O3 O 0.5972(6) 0.3536(5) 0.0367(5) 0.0253(19) Uani 0.553(4) 1 d D U P A 1
C29 C 0.5251(7) 0.4142(6) 0.0546(6) 0.036(2) Uani 0.553(4) 1 d D U P A 1
H29A H 0.464169 0.405189 0.009034 0.054 Uiso 0.553(4) 1 calc GR . P A 1
H29B H 0.566578 0.484469 0.074736 0.054 Uiso 0.553(4) 1 calc GR . P A 1
H29C H 0.495216 0.394379 0.092192 0.054 Uiso 0.553(4) 1 calc GR . P A 1
O3A O 0.5546(8) 0.3437(6) 0.0119(5) 0.021(2) Uani 0.447(4) 1 d D U P A 2
C29A C 0.5785(10) 0.4052(8) 0.0863(5) 0.035(3) Uani 0.447(4) 1 d D U P A 2
H29D H 0.586136 0.474888 0.086407 0.052 Uiso 0.447(4) 1 calc GR . P A 2
H29E H 0.647666 0.398566 0.118196 0.052 Uiso 0.447(4) 1 calc GR . P A 2
H29F H 0.518170 0.384707 0.105733 0.052 Uiso 0.447(4) 1 calc GR . P A 2
Rh1B Rh 0.67437(2) 0.70534(2) 0.46920(2) 0.01927(9) Uani 1 1 d D . . . .
P1A P 0.84580(8) 0.68401(8) 0.46755(6) 0.0256(3) Uani 1 1 d . . . . .
P2B P 0.70977(8) 0.77696(9) 0.58785(6) 0.0296(3) Uani 1 1 d . . . . .
Si1B Si 0.50181(9) 0.74846(7) 0.41067(6) 0.0201(2) Uani 1 1 d D . . . .
O1B O 0.6282(2) 0.7349(3) 0.62924(15) 0.0476(9) Uani 1 1 d . . . . .
O2B O 0.8302(2) 0.7820(2) 0.64010(13) 0.0353(7) Uani 1 1 d . . . . .
O3B O 0.6982(2) 0.8893(2) 0.61545(14) 0.0411(8) Uani 1 1 d . . . . .
N1B N 0.6376(2) 0.6358(2) 0.35421(16) 0.0195(7) Uani 1 1 d . . . . .
C1B C 0.5274(3) 0.5905(3) 0.30948(19) 0.0176(8) Uani 1 1 d . . . . .
C2B C 0.4458(3) 0.6363(3) 0.32709(19) 0.0176(8) Uani 1 1 d . . . . .
C3B C 0.3350(3) 0.5891(3) 0.2883(2) 0.0206(9) Uani 1 1 d . . . . .
H3B H 0.280617 0.620382 0.300749 0.025 Uiso 1 1 calc R . . . .
C4B C 0.3002(3) 0.4984(3) 0.2321(2) 0.0212(9) Uani 1 1 d . . . . .
C5B C 0.3821(3) 0.4553(3) 0.2151(2) 0.0230(9) Uani 1 1 d . . . . .
H5B H 0.361223 0.393408 0.176769 0.028 Uiso 1 1 calc R . . . .
C6B C 0.4926(3) 0.4996(3) 0.2522(2) 0.0216(9) Uani 1 1 d . . . . .
H6B H 0.546251 0.468020 0.238830 0.026 Uiso 1 1 calc R . . . .
C7B C 0.1790(3) 0.4490(3) 0.1923(2) 0.0327(10) Uani 1 1 d . . . . .
H7BA H 0.140845 0.444350 0.229448 0.049 Uiso 1 1 calc GR . . . .
H7BB H 0.170476 0.381809 0.160148 0.049 Uiso 1 1 calc GR . . . .
H7BC H 0.147043 0.488576 0.161264 0.049 Uiso 1 1 calc GR . . . .
C8B C 0.7217(3) 0.6378(2) 0.3220(2) 0.0205(9) Uani 1 1 d . . . . .
C9B C 0.7046(3) 0.6223(3) 0.2447(2) 0.0283(10) Uani 1 1 d . . . . .
H9B H 0.631522 0.608612 0.211597 0.034 Uiso 1 1 calc R . . . .
C10B C 0.7918(4) 0.6267(3) 0.2158(2) 0.0343(11) Uani 1 1 d . . . . .
H10B H 0.777279 0.617163 0.163414 0.041 Uiso 1 1 calc R . . . .
C11B C 0.9001(4) 0.6445(3) 0.2612(2) 0.0334(11) Uani 1 1 d . . . . .
C12B C 0.9183(3) 0.6616(3) 0.3374(2) 0.0311(10) Uani 1 1 d . . . . .
H12B H 0.991742 0.674389 0.369718 0.037 Uiso 1 1 calc R . . . .
C13B C 0.8316(3) 0.6607(3) 0.3686(2) 0.0215(9) Uani 1 1 d . . . . .
C14B C 0.9944(4) 0.6490(3) 0.2286(3) 0.0524(14) Uani 1 1 d . . . . .
H14D H 0.984896 0.583877 0.193241 0.079 Uiso 1 1 calc GR . . . .
H14E H 1.064607 0.665909 0.269281 0.079 Uiso 1 1 calc GR . . . .
H14F H 0.994938 0.699951 0.202296 0.079 Uiso 1 1 calc GR . . . .
C15B C 0.5543(3) 0.8668(3) 0.3884(2) 0.0209(9) Uani 1 1 d . . . . .
H15B H 0.579671 0.922743 0.436346 0.025 Uiso 1 1 calc R . . . .
C16B C 0.6508(3) 0.8681(3) 0.3570(2) 0.0297(10) Uani 1 1 d . . . . .
H16D H 0.714940 0.861821 0.394355 0.045 Uiso 1 1 calc GR . . . .
H16E H 0.669740 0.931009 0.345401 0.045 Uiso 1 1 calc GR . . . .
H16F H 0.629852 0.812119 0.311105 0.045 Uiso 1 1 calc GR . . . .
C17B C 0.4581(3) 0.8884(3) 0.3339(2) 0.0357(11) Uani 1 1 d . . . . .
H17D H 0.429721 0.833814 0.286733 0.054 Uiso 1 1 calc GR . . . .
H17E H 0.484160 0.951106 0.323849 0.054 Uiso 1 1 calc GR . . . .
H17F H 0.398950 0.893897 0.356401 0.054 Uiso 1 1 calc GR . . . .
C18B C 0.3865(3) 0.7681(3) 0.4507(2) 0.0237(9) Uani 1 1 d . . . . .
H18B H 0.323328 0.770475 0.408868 0.028 Uiso 1 1 calc R . . . .
C19B C 0.4160(3) 0.8664(3) 0.5138(2) 0.0344(11) Uani 1 1 d . . . . .
H19D H 0.479523 0.867840 0.555259 0.052 Uiso 1 1 calc GR . . . .
H19E H 0.352678 0.871475 0.531849 0.052 Uiso 1 1 calc GR . . . .
H19F H 0.434832 0.922649 0.494387 0.052 Uiso 1 1 calc GR . . . .
C20B C 0.3447(3) 0.6810(3) 0.4787(2) 0.0356(11) Uani 1 1 d . . . . .
H20D H 0.324763 0.618181 0.438291 0.053 Uiso 1 1 calc GR . . . .
H20E H 0.279564 0.690218 0.493557 0.053 Uiso 1 1 calc GR . . . .
H20F H 0.403037 0.678879 0.521960 0.053 Uiso 1 1 calc GR . . . .
C21B C 0.8697(4) 0.5675(4) 0.4865(3) 0.0529(15) Uani 1 1 d . . . . .
H21B H 0.937176 0.556132 0.473446 0.063 Uiso 1 1 calc R . . . .
C22B C 0.7720(5) 0.4805(4) 0.4353(4) 0.089(2) Uani 1 1 d . . . . .
H22G H 0.705794 0.487306 0.449551 0.134 Uiso 1 1 calc GR . . . .
H22H H 0.788396 0.417503 0.440444 0.134 Uiso 1 1 calc GR . . . .
H22I H 0.758971 0.480891 0.383014 0.134 Uiso 1 1 calc GR . . . .
C23B C 0.8904(5) 0.5733(4) 0.5692(3) 0.078(2) Uani 1 1 d . . . . .
H23G H 0.950353 0.632247 0.600546 0.117 Uiso 1 1 calc GR . . . .
H23H H 0.911156 0.513136 0.577855 0.117 Uiso 1 1 calc GR . . . .
H23I H 0.822921 0.578083 0.582224 0.117 Uiso 1 1 calc GR . . . .
C24B C 0.9725(3) 0.7829(3) 0.5235(2) 0.0374(11) Uani 1 1 d . . . . .
H24B H 0.968283 0.802840 0.575731 0.045 Uiso 1 1 calc R . . . .
C25B C 0.9722(4) 0.8752(3) 0.4964(2) 0.0443(12) Uani 1 1 d . . . . .
H25G H 0.977331 0.860021 0.445422 0.066 Uiso 1 1 calc GR . . . .
H25H H 1.035488 0.929885 0.530207 0.066 Uiso 1 1 calc GR . . . .
H25I H 0.903476 0.895010 0.496344 0.066 Uiso 1 1 calc GR . . . .
C26B C 1.0838(3) 0.7558(4) 0.5304(3) 0.0663(17) Uani 1 1 d . . . . .
H26G H 1.081934 0.695027 0.545998 0.100 Uiso 1 1 calc GR . . . .
H26H H 1.143396 0.810683 0.567957 0.100 Uiso 1 1 calc GR . . . .
H26I H 1.096879 0.744482 0.481699 0.100 Uiso 1 1 calc GR . . . .
C27B C 0.5987(4) 0.6298(4) 0.6188(3) 0.0675(17) Uani 1 1 d . . . . .
H27D H 0.578954 0.593829 0.565330 0.101 Uiso 1 1 calc GR . . . .
H27E H 0.535407 0.613034 0.636471 0.101 Uiso 1 1 calc GR . . . .
H27F H 0.661550 0.610475 0.647477 0.101 Uiso 1 1 calc GR . . . .
C28B C 0.8625(4) 0.8211(4) 0.7211(2) 0.0512(14) Uani 1 1 d . . . . .
H28D H 0.838433 0.882406 0.734521 0.077 Uiso 1 1 calc GR . . . .
H28E H 0.943104 0.835901 0.742257 0.077 Uiso 1 1 calc GR . . . .
H28F H 0.827866 0.771562 0.741270 0.077 Uiso 1 1 calc GR . . . .
C29B C 0.7652(4) 0.9645(3) 0.5966(3) 0.0494(13) Uani 1 1 d . . . . .
H29G H 0.752282 0.944487 0.542202 0.074 Uiso 1 1 calc GR . . . .
H29H H 0.843368 0.972623 0.622992 0.074 Uiso 1 1 calc GR . . . .
H29I H 0.745704 1.027909 0.611546 0.074 Uiso 1 1 calc GR . . . .
H1 H 0.641(2) 0.127(2) 0.0848(15) 0.031(10) Uiso 1 1 d D . . . .
H1B H 0.554(2) 0.692(3) 0.4732(19) 0.063(13) Uiso 1 1 d D . . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P1 Rh1 Si1 145.71(4) . . ?
P1 Rh1 H1 170.3(10) . . ?
P2 Rh1 P1 94.90(4) . . ?
P2 Rh1 Si1 105.45(4) . . ?
P2 Rh1 H1 84.9(11) . . ?
Si1 Rh1 H1 42.6(10) . . ?
N1 Rh1 P1 81.42(8) . . ?
N1 Rh1 P2 176.18(8) . . ?
N1 Rh1 Si1 78.28(8) . . ?
N1 Rh1 H1 98.6(11) . . ?
C2 P1 Rh1 101.24(12) . . ?
C2 P1 C15 104.75(16) . . ?
C2 P1 C18 104.71(16) . . ?
C15 P1 Rh1 125.74(13) . . ?
C15 P1 C18 105.95(17) . . ?
C18 P1 Rh1 112.22(12) . . ?
O1 P2 Rh1 111.31(10) . . ?
O1 P2 O2 103.61(14) . . ?
O1 P2 O3 109.5(3) . . ?
O1 P2 O3A 93.2(3) . . ?
O2 P2 Rh1 121.52(10) . . ?
O2 P2 O3 101.1(3) . . ?
O3 P2 Rh1 109.0(2) . . ?
O3A P2 Rh1 129.1(3) . . ?
O3A P2 O2 92.6(4) . . ?
Rh1 Si1 H1 38.8(9) . . ?
C13 Si1 Rh1 97.87(11) . . ?
C13 Si1 C21 109.6(6) . . ?
C13 Si1 C21A 110.4(7) . . ?
C13 Si1 C24 108.2(5) . . ?
C13 Si1 C24A 115.5(7) . . ?
C13 Si1 H1 99.3(11) . . ?
C21 Si1 Rh1 124.8(6) . . ?
C21 Si1 H1 88.9(11) . . ?
C21A Si1 Rh1 129.9(8) . . ?
C21A Si1 H1 94.8(12) . . ?
C24 Si1 Rh1 104.0(5) . . ?
C24 Si1 C21 110.9(7) . . ?
C24 Si1 H1 137.3(11) . . ?
C24A Si1 Rh1 101.6(6) . . ?
C24A Si1 C21A 102.1(9) . . ?
C24A Si1 H1 132.1(12) . . ?
C27 O1 P2 122.9(2) . . ?
C28 O2 P2 118.5(2) . . ?
C1 N1 Rh1 120.4(2) . . ?
C1 N1 C8 118.6(3) . . ?
C8 N1 Rh1 120.1(2) . . ?
N1 C1 C2 118.5(3) . . ?
N1 C1 C6 125.8(3) . . ?
C2 C1 C6 115.6(3) . . ?
C1 C2 P1 115.1(3) . . ?
C3 C2 P1 123.8(3) . . ?
C3 C2 C1 121.1(3) . . ?
C2 C3 H3 118.5 . . ?
C4 C3 C2 123.0(3) . . ?
C4 C3 H3 118.5 . . ?
C3 C4 C5 115.9(3) . . ?
C3 C4 C7 121.9(3) . . ?
C5 C4 C7 122.3(3) . . ?
C4 C5 H5 118.6 . . ?
C6 C5 C4 122.9(3) . . ?
C6 C5 H5 118.6 . . ?
C1 C6 H6 119.2 . . ?
C5 C6 C1 121.6(3) . . ?
C5 C6 H6 119.2 . . ?
C4 C7 H7A 109.5 . . ?
C4 C7 H7B 109.5 . . ?
C4 C7 H7C 109.5 . . ?
H7A C7 H7B 109.5 . . ?
H7A C7 H7C 109.5 . . ?
H7B C7 H7C 109.5 . . ?
C9 C8 N1 123.7(3) . . ?
C9 C8 C13 118.7(3) . . ?
C13 C8 N1 117.5(3) . . ?
C8 C9 H9 119.4 . . ?
C10 C9 C8 121.3(3) . . ?
C10 C9 H9 119.4 . . ?
C9 C10 H10 119.5 . . ?
C9 C10 C11 121.0(4) . . ?
C11 C10 H10 119.5 . . ?
C10 C11 C14 121.4(3) . . ?
C12 C11 C10 117.3(3) . . ?
C12 C11 C14 121.3(3) . . ?
C11 C12 H12 118.8 . . ?
C11 C12 C13 122.5(3) . . ?
C13 C12 H12 118.8 . . ?
C8 C13 Si1 114.8(3) . . ?
C8 C13 C12 118.9(3) . . ?
C12 C13 Si1 126.0(3) . . ?
C11 C14 H14A 109.5 . . ?
C11 C14 H14B 109.5 . . ?
C11 C14 H14C 109.5 . . ?
H14A C14 H14B 109.5 . . ?
H14A C14 H14C 109.5 . . ?
H14B C14 H14C 109.5 . . ?
P1 C15 H15 107.1 . . ?
C16 C15 P1 110.7(3) . . ?
C16 C15 H15 107.1 . . ?
C16 C15 C17 110.9(3) . . ?
C17 C15 P1 113.4(3) . . ?
C17 C15 H15 107.1 . . ?
C15 C16 H16A 109.5 . . ?
C15 C16 H16B 109.5 . . ?
C15 C16 H16C 109.5 . . ?
H16A C16 H16B 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
C15 C17 H17A 109.5 . . ?
C15 C17 H17B 109.5 . . ?
C15 C17 H17C 109.5 . . ?
H17A C17 H17B 109.5 . . ?
H17A C17 H17C 109.5 . . ?
H17B C17 H17C 109.5 . . ?
P1 C18 H18 107.9 . . ?
C19 C18 P1 114.3(3) . . ?
C19 C18 H18 107.9 . . ?
C20 C18 P1 109.0(2) . . ?
C20 C18 H18 107.9 . . ?
C20 C18 C19 109.6(3) . . ?
C18 C19 H19A 109.5 . . ?
C18 C19 H19B 109.5 . . ?
C18 C19 H19C 109.5 . . ?
H19A C19 H19B 109.5 . . ?
H19A C19 H19C 109.5 . . ?
H19B C19 H19C 109.5 . . ?
C18 C20 H20A 109.5 . . ?
C18 C20 H20B 109.5 . . ?
C18 C20 H20C 109.5 . . ?
H20A C20 H20B 109.5 . . ?
H20A C20 H20C 109.5 . . ?
H20B C20 H20C 109.5 . . ?
Si1 C21 H21 105.5 . . ?
C22 C21 Si1 114.0(11) . . ?
C22 C21 H21 105.5 . . ?
C23 C21 Si1 115.2(10) . . ?
C23 C21 H21 105.5 . . ?
C23 C21 C22 110.1(13) . . ?
C21 C22 H22A 109.5 . . ?
C21 C22 H22B 109.5 . . ?
C21 C22 H22C 109.5 . . ?
H22A C22 H22B 109.5 . . ?
H22A C22 H22C 109.5 . . ?
H22B C22 H22C 109.5 . . ?
C21 C23 H23A 109.5 . . ?
C21 C23 H23B 109.5 . . ?
C21 C23 H23C 109.5 . . ?
H23A C23 H23B 109.5 . . ?
H23A C23 H23C 109.5 . . ?
H23B C23 H23C 109.5 . . ?
Si1 C21A H21A 105.8 . . ?
C22A C21A Si1 117.9(12) . . ?
C22A C21A H21A 105.8 . . ?
C22A C21A C23A 108.1(15) . . ?
C23A C21A Si1 112.6(14) . . ?
C23A C21A H21A 105.8 . . ?
C21A C22A H22D 109.5 . . ?
C21A C22A H22E 109.5 . . ?
C21A C22A H22F 109.5 . . ?
H22D C22A H22E 109.5 . . ?
H22D C22A H22F 109.5 . . ?
H22E C22A H22F 109.5 . . ?
C21A C23A H23D 109.5 . . ?
C21A C23A H23E 109.5 . . ?
C21A C23A H23F 109.5 . . ?
H23D C23A H23E 109.5 . . ?
H23D C23A H23F 109.5 . . ?
H23E C23A H23F 109.5 . . ?
Si1 C24 H24 105.8 . . ?
C25 C24 Si1 116.1(11) . . ?
C25 C24 H24 105.8 . . ?
C26 C24 Si1 109.2(8) . . ?
C26 C24 H24 105.8 . . ?
C26 C24 C25 113.4(10) . . ?
C24 C25 H25A 109.5 . . ?
C24 C25 H25B 109.5 . . ?
C24 C25 H25C 109.5 . . ?
H25A C25 H25B 109.5 . . ?
H25A C25 H25C 109.5 . . ?
H25B C25 H25C 109.5 . . ?
C24 C26 H26A 109.5 . . ?
C24 C26 H26B 109.5 . . ?
C24 C26 H26C 109.5 . . ?
H26A C26 H26B 109.5 . . ?
H26A C26 H26C 109.5 . . ?
H26B C26 H26C 109.5 . . ?
Si1 C24A H24A 108.6 . . ?
C25A C24A Si1 110.5(10) . . ?
C25A C24A H24A 108.6 . . ?
C25A C24A C26A 107.6(14) . . ?
C26A C24A Si1 112.9(14) . . ?
C26A C24A H24A 108.6 . . ?
C24A C25A H25D 109.5 . . ?
C24A C25A H25E 109.5 . . ?
C24A C25A H25F 109.5 . . ?
H25D C25A H25E 109.5 . . ?
H25D C25A H25F 109.5 . . ?
H25E C25A H25F 109.5 . . ?
C24A C26A H26D 109.5 . . ?
C24A C26A H26E 109.5 . . ?
C24A C26A H26F 109.5 . . ?
H26D C26A H26E 109.5 . . ?
H26D C26A H26F 109.5 . . ?
H26E C26A H26F 109.5 . . ?
O1 C27 H27A 109.5 . . ?
O1 C27 H27B 109.5 . . ?
O1 C27 H27C 109.5 . . ?
H27A C27 H27B 109.5 . . ?
H27A C27 H27C 109.5 . . ?
H27B C27 H27C 109.5 . . ?
O2 C28 H28A 109.5 . . ?
O2 C28 H28B 109.5 . . ?
O2 C28 H28C 109.5 . . ?
H28A C28 H28B 109.5 . . ?
H28A C28 H28C 109.5 . . ?
H28B C28 H28C 109.5 . . ?
C29 O3 P2 126.3(7) . . ?
O3 C29 H29A 109.5 . . ?
O3 C29 H29B 109.5 . . ?
O3 C29 H29C 109.5 . . ?
H29A C29 H29B 109.5 . . ?
H29A C29 H29C 109.5 . . ?
H29B C29 H29C 109.5 . . ?
C29A O3A P2 115.8(8) . . ?
O3A C29A H29D 109.5 . . ?
O3A C29A H29E 109.5 . . ?
O3A C29A H29F 109.5 . . ?
H29D C29A H29E 109.5 . . ?
H29D C29A H29F 109.5 . . ?
H29E C29A H29F 109.5 . . ?
P1A Rh1B Si1B 149.54(4) . . ?
P1A Rh1B H1B 165.1(12) . . ?
P2B Rh1B P1A 100.37(4) . . ?
P2B Rh1B Si1B 103.09(4) . . ?
P2B Rh1B H1B 80.2(13) . . ?
Si1B Rh1B H1B 41.3(10) . . ?
N1B Rh1B P1A 80.49(8) . . ?
N1B Rh1B P2B 179.13(8) . . ?
N1B Rh1B Si1B 76.16(8) . . ?
N1B Rh1B H1B 98.9(13) . . ?
C13B P1A Rh1B 101.63(12) . . ?
C13B P1A C21B 103.56(19) . . ?
C13B P1A C24B 109.31(18) . . ?
C21B P1A Rh1B 113.00(17) . . ?
C24B P1A Rh1B 121.13(14) . . ?
C24B P1A C21B 106.7(2) . . ?
O1B P2B Rh1B 118.29(12) . . ?
O1B P2B O2B 104.17(15) . . ?
O1B P2B O3B 93.11(17) . . ?
O2B P2B Rh1B 115.21(11) . . ?
O2B P2B O3B 103.18(15) . . ?
O3B P2B Rh1B 119.56(11) . . ?
Rh1B Si1B H1B 38.4(10) . . ?
C2B Si1B Rh1B 96.96(11) . . ?
C2B Si1B C15B 113.59(16) . . ?
C2B Si1B C18B 108.04(16) . . ?
C2B Si1B H1B 97.5(13) . . ?
C15B Si1B Rh1B 103.01(12) . . ?
C15B Si1B H1B 134.7(12) . . ?
C18B Si1B Rh1B 128.13(13) . . ?
C18B Si1B C15B 107.01(16) . . ?
C18B Si1B H1B 92.6(10) . . ?
C27B O1B P2B 118.7(3) . . ?
C28B O2B P2B 121.3(2) . . ?
C29B O3B P2B 116.9(3) . . ?
C1B N1B Rh1B 119.8(2) . . ?
C8B N1B Rh1B 120.0(2) . . ?
C8B N1B C1B 120.2(3) . . ?
N1B C1B C2B 117.4(3) . . ?
C6B C1B N1B 124.4(3) . . ?
C6B C1B C2B 118.0(3) . . ?
C1B C2B Si1B 113.6(3) . . ?
C3B C2B Si1B 126.8(3) . . ?
C3B C2B C1B 119.1(3) . . ?
C2B C3B H3B 118.5 . . ?
C2B C3B C4B 123.0(3) . . ?
C4B C3B H3B 118.5 . . ?
C3B C4B C7B 121.3(3) . . ?
C5B C4B C3B 116.8(3) . . ?
C5B C4B C7B 121.9(3) . . ?
C4B C5B H5B 119.1 . . ?
C6B C5B C4B 121.9(3) . . ?
C6B C5B H5B 119.1 . . ?
C1B C6B H6B 119.4 . . ?
C5B C6B C1B 121.1(3) . . ?
C5B C6B H6B 119.4 . . ?
C4B C7B H7BA 109.5 . . ?
C4B C7B H7BB 109.5 . . ?
C4B C7B H7BC 109.5 . . ?
H7BA C7B H7BB 109.5 . . ?
H7BA C7B H7BC 109.5 . . ?
H7BB C7B H7BC 109.5 . . ?
N1B C8B C9B 123.9(3) . . ?
N1B C8B C13B 119.1(3) . . ?
C13B C8B C9B 116.9(3) . . ?
C8B C9B H9B 119.3 . . ?
C10B C9B C8B 121.5(4) . . ?
C10B C9B H9B 119.3 . . ?
C9B C10B H10B 119.1 . . ?
C9B C10B C11B 121.8(4) . . ?
C11B C10B H10B 119.1 . . ?
C10B C11B C14B 121.1(4) . . ?
C12B C11B C10B 117.3(4) . . ?
C12B C11B C14B 121.5(4) . . ?
C11B C12B H12B 119.0 . . ?
C11B C12B C13B 122.1(4) . . ?
C13B C12B H12B 119.0 . . ?
C8B C13B P1A 113.8(3) . . ?
C8B C13B C12B 120.3(4) . . ?
C12B C13B P1A 125.9(3) . . ?
C11B C14B H14D 109.5 . . ?
C11B C14B H14E 109.5 . . ?
C11B C14B H14F 109.5 . . ?
H14D C14B H14E 109.5 . . ?
H14D C14B H14F 109.5 . . ?
H14E C14B H14F 109.5 . . ?
Si1B C15B H15B 107.3 . . ?
C16B C15B Si1B 115.7(2) . . ?
C16B C15B H15B 107.3 . . ?
C16B C15B C17B 109.6(3) . . ?
C17B C15B Si1B 109.1(3) . . ?
C17B C15B H15B 107.3 . . ?
C15B C16B H16D 109.5 . . ?
C15B C16B H16E 109.5 . . ?
C15B C16B H16F 109.5 . . ?
H16D C16B H16E 109.5 . . ?
H16D C16B H16F 109.5 . . ?
H16E C16B H16F 109.5 . . ?
C15B C17B H17D 109.5 . . ?
C15B C17B H17E 109.5 . . ?
C15B C17B H17F 109.5 . . ?
H17D C17B H17E 109.5 . . ?
H17D C17B H17F 109.5 . . ?
H17E C17B H17F 109.5 . . ?
Si1B C18B H18B 107.1 . . ?
C19B C18B Si1B 114.0(3) . . ?
C19B C18B H18B 107.1 . . ?
C20B C18B Si1B 112.0(2) . . ?
C20B C18B H18B 107.1 . . ?
C20B C18B C19B 109.3(3) . . ?
C18B C19B H19D 109.5 . . ?
C18B C19B H19E 109.5 . . ?
C18B C19B H19F 109.5 . . ?
H19D C19B H19E 109.5 . . ?
H19D C19B H19F 109.5 . . ?
H19E C19B H19F 109.5 . . ?
C18B C20B H20D 109.5 . . ?
C18B C20B H20E 109.5 . . ?
C18B C20B H20F 109.5 . . ?
H20D C20B H20E 109.5 . . ?
H20D C20B H20F 109.5 . . ?
H20E C20B H20F 109.5 . . ?
P1A C21B H21B 107.9 . . ?
C22B C21B P1A 109.1(3) . . ?
C22B C21B H21B 107.9 . . ?
C23B C21B P1A 112.2(3) . . ?
C23B C21B H21B 107.9 . . ?
C23B C21B C22B 111.7(5) . . ?
C21B C22B H22G 109.5 . . ?
C21B C22B H22H 109.5 . . ?
C21B C22B H22I 109.5 . . ?
H22G C22B H22H 109.5 . . ?
H22G C22B H22I 109.5 . . ?
H22H C22B H22I 109.5 . . ?
C21B C23B H23G 109.5 . . ?
C21B C23B H23H 109.5 . . ?
C21B C23B H23I 109.5 . . ?
H23G C23B H23H 109.5 . . ?
H23G C23B H23I 109.5 . . ?
H23H C23B H23I 109.5 . . ?
P1A C24B H24B 106.0 . . ?
C25B C24B P1A 110.2(3) . . ?
C25B C24B H24B 106.0 . . ?
C25B C24B C26B 110.3(4) . . ?
C26B C24B P1A 117.5(3) . . ?
C26B C24B H24B 106.0 . . ?
C24B C25B H25G 109.5 . . ?
C24B C25B H25H 109.5 . . ?
C24B C25B H25I 109.5 . . ?
H25G C25B H25H 109.5 . . ?
H25G C25B H25I 109.5 . . ?
H25H C25B H25I 109.5 . . ?
C24B C26B H26G 109.5 . . ?
C24B C26B H26H 109.5 . . ?
C24B C26B H26I 109.5 . . ?
H26G C26B H26H 109.5 . . ?
H26G C26B H26I 109.5 . . ?
H26H C26B H26I 109.5 . . ?
O1B C27B H27D 109.5 . . ?
O1B C27B H27E 109.5 . . ?
O1B C27B H27F 109.5 . . ?
H27D C27B H27E 109.5 . . ?
H27D C27B H27F 109.5 . . ?
H27E C27B H27F 109.5 . . ?
O2B C28B H28D 109.5 . . ?
O2B C28B H28E 109.5 . . ?
O2B C28B H28F 109.5 . . ?
H28D C28B H28E 109.5 . . ?
H28D C28B H28F 109.5 . . ?
H28E C28B H28F 109.5 . . ?
O3B C29B H29G 109.5 . . ?
O3B C29B H29H 109.5 . . ?
O3B C29B H29I 109.5 . . ?
H29G C29B H29H 109.5 . . ?
H29G C29B H29I 109.5 . . ?
H29H C29B H29I 109.5 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Rh1 P1 2.3088(11) . ?
Rh1 P2 2.1679(11) . ?
Rh1 Si1 2.4547(12) . ?
Rh1 N1 2.092(3) . ?
Rh1 H1 1.55(3) . ?
P1 C2 1.807(3) . ?
P1 C15 1.846(4) . ?
P1 C18 1.854(4) . ?
P2 O1 1.596(3) . ?
P2 O2 1.608(3) . ?
P2 O3 1.639(7) . ?
P2 O3A 1.598(9) . ?
Si1 C13 1.874(4) . ?
Si1 C21 1.899(9) . ?
Si1 C21A 1.903(11) . ?
Si1 C24 1.886(9) . ?
Si1 C24A 1.902(12) . ?
Si1 H1 1.68(3) . ?
O1 C27 1.445(4) . ?
O2 C28 1.439(5) . ?
N1 C1 1.398(4) . ?
N1 C8 1.419(4) . ?
C1 C2 1.410(5) . ?
C1 C6 1.414(5) . ?
C2 C3 1.392(5) . ?
C3 H3 0.9500 . ?
C3 C4 1.380(5) . ?
C4 C5 1.391(5) . ?
C4 C7 1.503(5) . ?
C5 H5 0.9500 . ?
C5 C6 1.374(5) . ?
C6 H6 0.9500 . ?
C7 H7A 0.9800 . ?
C7 H7B 0.9800 . ?
C7 H7C 0.9800 . ?
C8 C9 1.391(5) . ?
C8 C13 1.400(5) . ?
C9 H9 0.9500 . ?
C9 C10 1.387(5) . ?
C10 H10 0.9500 . ?
C10 C11 1.394(5) . ?
C11 C12 1.392(5) . ?
C11 C14 1.512(5) . ?
C12 H12 0.9500 . ?
C12 C13 1.404(5) . ?
C14 H14A 0.9800 . ?
C14 H14B 0.9800 . ?
C14 H14C 0.9800 . ?
C15 H15 1.0000 . ?
C15 C16 1.523(5) . ?
C15 C17 1.529(5) . ?
C16 H16A 0.9800 . ?
C16 H16B 0.9800 . ?
C16 H16C 0.9800 . ?
C17 H17A 0.9800 . ?
C17 H17B 0.9800 . ?
C17 H17C 0.9800 . ?
C18 H18 1.0000 . ?
C18 C19 1.529(5) . ?
C18 C20 1.527(5) . ?
C19 H19A 0.9800 . ?
C19 H19B 0.9800 . ?
C19 H19C 0.9800 . ?
C20 H20A 0.9800 . ?
C20 H20B 0.9800 . ?
C20 H20C 0.9800 . ?
C21 H21 1.0000 . ?
C21 C22 1.536(10) . ?
C21 C23 1.510(15) . ?
C22 H22A 0.9800 . ?
C22 H22B 0.9800 . ?
C22 H22C 0.9800 . ?
C23 H23A 0.9800 . ?
C23 H23B 0.9800 . ?
C23 H23C 0.9800 . ?
C21A H21A 1.0000 . ?
C21A C22A 1.520(17) . ?
C21A C23A 1.533(12) . ?
C22A H22D 0.9800 . ?
C22A H22E 0.9800 . ?
C22A H22F 0.9800 . ?
C23A H23D 0.9800 . ?
C23A H23E 0.9800 . ?
C23A H23F 0.9800 . ?
C24 H24 1.0000 . ?
C24 C25 1.528(10) . ?
C24 C26 1.512(14) . ?
C25 H25A 0.9800 . ?
C25 H25B 0.9800 . ?
C25 H25C 0.9800 . ?
C26 H26A 0.9800 . ?
C26 H26B 0.9800 . ?
C26 H26C 0.9800 . ?
C24A H24A 1.0000 . ?
C24A C25A 1.527(16) . ?
C24A C26A 1.532(12) . ?
C25A H25D 0.9800 . ?
C25A H25E 0.9800 . ?
C25A H25F 0.9800 . ?
C26A H26D 0.9800 . ?
C26A H26E 0.9800 . ?
C26A H26F 0.9800 . ?
C27 H27A 0.9800 . ?
C27 H27B 0.9800 . ?
C27 H27C 0.9800 . ?
C28 H28A 0.9800 . ?
C28 H28B 0.9800 . ?
C28 H28C 0.9800 . ?
O3 C29 1.433(9) . ?
C29 H29A 0.9800 . ?
C29 H29B 0.9800 . ?
C29 H29C 0.9800 . ?
O3A C29A 1.416(11) . ?
C29A H29D 0.9800 . ?
C29A H29E 0.9800 . ?
C29A H29F 0.9800 . ?
Rh1B P1A 2.3021(12) . ?
Rh1B P2B 2.1641(12) . ?
Rh1B Si1B 2.4792(12) . ?
Rh1B N1B 2.093(3) . ?
Rh1B H1B 1.57(3) . ?
P1A C13B 1.812(4) . ?
P1A C21B 1.844(4) . ?
P1A C24B 1.839(4) . ?
P2B O1B 1.599(3) . ?
P2B O2B 1.600(3) . ?
P2B O3B 1.612(3) . ?
Si1B C2B 1.858(4) . ?
Si1B C15B 1.892(4) . ?
Si1B C18B 1.887(4) . ?
Si1B H1B 1.66(3) . ?
O1B C27B 1.430(6) . ?
O2B C28B 1.447(4) . ?
O3B C29B 1.433(5) . ?
N1B C1B 1.402(4) . ?
N1B C8B 1.389(4) . ?
C1B C2B 1.410(5) . ?
C1B C6B 1.401(5) . ?
C2B C3B 1.390(5) . ?
C3B H3B 0.9500 . ?
C3B C4B 1.390(5) . ?
C4B C5B 1.390(5) . ?
C4B C7B 1.507(5) . ?
C5B H5B 0.9500 . ?
C5B C6B 1.376(5) . ?
C6B H6B 0.9500 . ?
C7B H7BA 0.9800 . ?
C7B H7BB 0.9800 . ?
C7B H7BC 0.9800 . ?
C8B C9B 1.406(5) . ?
C8B C13B 1.404(5) . ?
C9B H9B 0.9500 . ?
C9B C10B 1.383(5) . ?
C10B H10B 0.9500 . ?
C10B C11B 1.388(6) . ?
C11B C12B 1.380(5) . ?
C11B C14B 1.512(5) . ?
C12B H12B 0.9500 . ?
C12B C13B 1.407(5) . ?
C14B H14D 0.9800 . ?
C14B H14E 0.9800 . ?
C14B H14F 0.9800 . ?
C15B H15B 1.0000 . ?
C15B C16B 1.525(5) . ?
C15B C17B 1.535(5) . ?
C16B H16D 0.9800 . ?
C16B H16E 0.9800 . ?
C16B H16F 0.9800 . ?
C17B H17D 0.9800 . ?
C17B H17E 0.9800 . ?
C17B H17F 0.9800 . ?
C18B H18B 1.0000 . ?
C18B C19B 1.535(5) . ?
C18B C20B 1.534(5) . ?
C19B H19D 0.9800 . ?
C19B H19E 0.9800 . ?
C19B H19F 0.9800 . ?
C20B H20D 0.9800 . ?
C20B H20E 0.9800 . ?
C20B H20F 0.9800 . ?
C21B H21B 1.0000 . ?
C21B C22B 1.527(7) . ?
C21B C23B 1.526(6) . ?
C22B H22G 0.9800 . ?
C22B H22H 0.9800 . ?
C22B H22I 0.9800 . ?
C23B H23G 0.9800 . ?
C23B H23H 0.9800 . ?
C23B H23I 0.9800 . ?
C24B H24B 1.0000 . ?
C24B C25B 1.525(6) . ?
C24B C26B 1.539(5) . ?
C25B H25G 0.9800 . ?
C25B H25H 0.9800 . ?
C25B H25I 0.9800 . ?
C26B H26G 0.9800 . ?
C26B H26H 0.9800 . ?
C26B H26I 0.9800 . ?
C27B H27D 0.9800 . ?
C27B H27E 0.9800 . ?
C27B H27F 0.9800 . ?
C28B H28D 0.9800 . ?
C28B H28E 0.9800 . ?
C28B H28F 0.9800 . ?
C29B H29G 0.9800 . ?
C29B H29H 0.9800 . ?
C29B H29I 0.9800 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Rh1 P1 C2 C1 13.6(3) . . . . ?
Rh1 P1 C2 C3 -166.2(3) . . . . ?
Rh1 P1 C15 C16 50.8(3) . . . . ?
Rh1 P1 C15 C17 -74.7(3) . . . . ?
Rh1 P1 C18 C19 -177.0(2) . . . . ?
Rh1 P1 C18 C20 -54.1(3) . . . . ?
Rh1 P2 O1 C27 -179.1(3) . . . . ?
Rh1 P2 O2 C28 -63.2(3) . . . . ?
Rh1 P2 O3 C29 -150.0(8) . . . . ?
Rh1 P2 O3A C29A -65.1(11) . . . . ?
Rh1 Si1 C13 C8 14.1(3) . . . . ?
Rh1 Si1 C13 C12 -159.4(3) . . . . ?
Rh1 Si1 C21 C22 72.2(17) . . . . ?
Rh1 Si1 C21 C23 -159.1(8) . . . . ?
Rh1 Si1 C24 C25 -55.0(11) . . . . ?
Rh1 Si1 C24 C26 74.6(9) . . . . ?
Rh1 N1 C1 C2 -12.1(4) . . . . ?
Rh1 N1 C1 C6 164.0(3) . . . . ?
Rh1 N1 C8 C9 142.4(3) . . . . ?
Rh1 N1 C8 C13 -34.3(4) . . . . ?
P1 C2 C3 C4 179.1(3) . . . . ?
O1 P2 O2 C28 62.7(3) . . . . ?
O1 P2 O3 C29 88.0(10) . . . . ?
O1 P2 O3A C29A 174.0(9) . . . . ?
O2 P2 O1 C27 48.7(3) . . . . ?
O2 P2 O3 C29 -20.9(10) . . . . ?
O2 P2 O3A C29A 70.2(9) . . . . ?
N1 C1 C2 P1 -2.9(4) . . . . ?
N1 C1 C2 C3 176.9(3) . . . . ?
N1 C1 C6 C5 -176.2(3) . . . . ?
N1 C8 C9 C10 178.9(3) . . . . ?
N1 C8 C13 Si1 8.3(4) . . . . ?
N1 C8 C13 C12 -177.7(3) . . . . ?
C1 N1 C8 C9 -48.1(5) . . . . ?
C1 N1 C8 C13 135.2(3) . . . . ?
C1 C2 C3 C4 -0.7(5) . . . . ?
C2 P1 C15 C16 -65.2(3) . . . . ?
C2 P1 C15 C17 169.3(3) . . . . ?
C2 P1 C18 C19 -68.1(3) . . . . ?
C2 P1 C18 C20 54.9(3) . . . . ?
C2 C1 C6 C5 0.0(5) . . . . ?
C2 C3 C4 C5 0.6(5) . . . . ?
C2 C3 C4 C7 -178.5(3) . . . . ?
C3 C4 C5 C6 -0.2(5) . . . . ?
C4 C5 C6 C1 -0.1(5) . . . . ?
C6 C1 C2 P1 -179.4(2) . . . . ?
C6 C1 C2 C3 0.4(5) . . . . ?
C7 C4 C5 C6 178.9(3) . . . . ?
C8 N1 C1 C2 178.5(3) . . . . ?
C8 N1 C1 C6 -5.4(5) . . . . ?
C8 C9 C10 C11 -0.2(6) . . . . ?
C9 C8 C13 Si1 -168.6(3) . . . . ?
C9 C8 C13 C12 5.4(5) . . . . ?
C9 C10 C11 C12 3.6(5) . . . . ?
C9 C10 C11 C14 -178.0(3) . . . . ?
C10 C11 C12 C13 -2.6(5) . . . . ?
C11 C12 C13 Si1 171.3(3) . . . . ?
C11 C12 C13 C8 -2.0(5) . . . . ?
C13 Si1 C21 C22 -42.9(16) . . . . ?
C13 Si1 C21 C23 85.8(10) . . . . ?
C13 Si1 C24 C25 48.3(11) . . . . ?
C13 Si1 C24 C26 178.0(7) . . . . ?
C13 C8 C9 C10 -4.5(5) . . . . ?
C14 C11 C12 C13 179.1(3) . . . . ?
C15 P1 C2 C1 145.5(3) . . . . ?
C15 P1 C2 C3 -34.3(3) . . . . ?
C15 P1 C18 C19 42.3(3) . . . . ?
C15 P1 C18 C20 165.3(3) . . . . ?
C18 P1 C2 C1 -103.2(3) . . . . ?
C18 P1 C2 C3 77.0(3) . . . . ?
C18 P1 C15 C16 -175.6(3) . . . . ?
C18 P1 C15 C17 59.0(3) . . . . ?
C21 Si1 C13 C8 145.5(6) . . . . ?
C21 Si1 C13 C12 -28.1(7) . . . . ?
C21 Si1 C24 C25 168.6(11) . . . . ?
C21 Si1 C24 C26 -61.8(12) . . . . ?
C21A Si1 C13 C8 152.1(8) . . . . ?
C21A Si1 C13 C12 -21.5(9) . . . . ?
C24 Si1 C13 C8 -93.5(6) . . . . ?
C24 Si1 C13 C12 93.0(6) . . . . ?
C24 Si1 C21 C22 -162.3(14) . . . . ?
C24 Si1 C21 C23 -33.6(14) . . . . ?
C24A Si1 C13 C8 -92.8(7) . . . . ?
C24A Si1 C13 C12 93.7(7) . . . . ?
O3 P2 O1 C27 -58.6(4) . . . . ?
O3 P2 O2 C28 176.1(4) . . . . ?
O3A P2 O1 C27 -44.8(5) . . . . ?
O3A P2 O2 C28 156.6(4) . . . . ?
Rh1B P1A C13B C8B -14.9(3) . . . . ?
Rh1B P1A C13B C12B 166.8(3) . . . . ?
Rh1B P1A C21B C22B 50.4(4) . . . . ?
Rh1B P1A C21B C23B -73.9(4) . . . . ?
Rh1B P1A C24B C25B -63.4(3) . . . . ?
Rh1B P1A C24B C26B 169.2(3) . . . . ?
Rh1B P2B O1B C27B 48.9(3) . . . . ?
Rh1B P2B O2B C28B -175.4(3) . . . . ?
Rh1B P2B O3B C29B -58.9(3) . . . . ?
Rh1B Si1B C2B C1B -22.6(3) . . . . ?
Rh1B Si1B C2B C3B 149.1(3) . . . . ?
Rh1B Si1B C15B C16B 41.3(3) . . . . ?
Rh1B Si1B C15B C17B 165.5(2) . . . . ?
Rh1B Si1B C18B C19B 73.2(3) . . . . ?
Rh1B Si1B C18B C20B -51.5(3) . . . . ?
Rh1B N1B C1B C2B 35.3(4) . . . . ?
Rh1B N1B C1B C6B -140.0(3) . . . . ?
Rh1B N1B C8B C9B -159.3(3) . . . . ?
Rh1B N1B C8B C13B 17.8(4) . . . . ?
Si1B C2B C3B C4B -171.7(3) . . . . ?
O1B P2B O2B C28B -44.2(4) . . . . ?
O1B P2B O3B C29B 175.9(3) . . . . ?
O2B P2B O1B C27B -80.5(3) . . . . ?
O2B P2B O3B C29B 70.5(3) . . . . ?
O3B P2B O1B C27B 175.1(3) . . . . ?
O3B P2B O2B C28B 52.5(3) . . . . ?
N1B C1B C2B Si1B -2.1(4) . . . . ?
N1B C1B C2B C3B -174.5(3) . . . . ?
N1B C1B C6B C5B 174.2(3) . . . . ?
N1B C8B C9B C10B 179.0(3) . . . . ?
N1B C8B C13B P1A 0.5(4) . . . . ?
N1B C8B C13B C12B 179.0(3) . . . . ?
C1B N1B C8B C9B 18.4(5) . . . . ?
C1B N1B C8B C13B -164.5(3) . . . . ?
C1B C2B C3B C4B -0.4(5) . . . . ?
C2B Si1B C15B C16B -62.4(3) . . . . ?
C2B Si1B C15B C17B 61.8(3) . . . . ?
C2B Si1B C18B C19B -172.1(3) . . . . ?
C2B Si1B C18B C20B 63.2(3) . . . . ?
C2B C1B C6B C5B -1.1(5) . . . . ?
C2B C3B C4B C5B -0.4(5) . . . . ?
C2B C3B C4B C7B 179.0(3) . . . . ?
C3B C4B C5B C6B 0.4(5) . . . . ?
C4B C5B C6B C1B 0.4(6) . . . . ?
C6B C1B C2B Si1B 173.5(3) . . . . ?
C6B C1B C2B C3B 1.1(5) . . . . ?
C7B C4B C5B C6B -179.0(4) . . . . ?
C8B N1B C1B C2B -142.3(3) . . . . ?
C8B N1B C1B C6B 42.3(5) . . . . ?
C8B C9B C10B C11B 1.3(6) . . . . ?
C9B C8B C13B P1A 177.7(3) . . . . ?
C9B C8B C13B C12B -3.8(5) . . . . ?
C9B C10B C11B C12B -2.4(6) . . . . ?
C9B C10B C11B C14B 180.0(4) . . . . ?
C10B C11B C12B C13B 0.4(6) . . . . ?
C11B C12B C13B P1A -178.9(3) . . . . ?
C11B C12B C13B C8B 2.8(6) . . . . ?
C13B P1A C21B C22B -58.8(4) . . . . ?
C13B P1A C21B C23B 176.9(4) . . . . ?
C13B P1A C24B C25B 54.0(3) . . . . ?
C13B P1A C24B C26B -73.3(3) . . . . ?
C13B C8B C9B C10B 1.8(5) . . . . ?
C14B C11B C12B C13B 178.0(4) . . . . ?
C15B Si1B C2B C1B 84.9(3) . . . . ?
C15B Si1B C2B C3B -103.4(3) . . . . ?
C15B Si1B C18B C19B -49.4(3) . . . . ?
C15B Si1B C18B C20B -174.1(3) . . . . ?
C18B Si1B C2B C1B -156.6(3) . . . . ?
C18B Si1B C2B C3B 15.2(4) . . . . ?
C18B Si1B C15B C16B 178.5(3) . . . . ?
C18B Si1B C15B C17B -57.4(3) . . . . ?
C21B P1A C13B C8B 102.5(3) . . . . ?
C21B P1A C13B C12B -75.9(4) . . . . ?
C21B P1A C24B C25B 165.4(3) . . . . ?
C21B P1A C24B C26B 38.0(4) . . . . ?
C24B P1A C13B C8B -144.0(3) . . . . ?
C24B P1A C13B C12B 37.6(4) . . . . ?
C24B P1A C21B C22B -174.1(4) . . . . ?
C24B P1A C21B C23B 61.6(4) . . . . ?
