#------------------------------------------------------------------------------
#$Date: 2022-10-12 02:02:55 +0300 (Wed, 12 Oct 2022) $
#$Revision: 278535 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/71/14/7711456.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7711456
loop_
_publ_author_name
'Molčanov, Lidija'
'Šenjug, Pavla'
'Barišić, Dario'
'Pajić, Damir'
'Molčanov, Krešimir'
'Jurić, Marijana'
_publ_section_title
;
 Oxalate-based [CuIICrIII] coordination compounds affected by the
 tridentate ligand, simple anion, and reactant ratio: structural and
 magnetic features
;
_journal_name_full               'Dalton Transactions'
_journal_paper_doi               10.1039/D2DT01949C
_journal_year                    2022
_chemical_formula_sum            'C38 H30 Cr Cu2 N7 O21'
_chemical_formula_weight         1099.79
_space_group_IT_number           13
_space_group_name_Hall           '-P 2yc'
_space_group_name_H-M_alt        'P 1 2/c 1'
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yc'
_symmetry_space_group_name_H-M   'P 1 2/c 1'
_atom_sites_solution_hydrogens   mixed
_audit_creation_date             2021-11-02T14:46:49-00:00
_audit_creation_method           'WinGX routine CIF_UPDATE'
_audit_update_record
;
2022-09-06 deposited with the CCDC.	2022-10-05 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 96.663(4)
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   10.8670(5)
_cell_length_b                   8.6697(3)
_cell_length_c                   23.7339(9)
_cell_measurement_reflns_used    4805
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      75.773
_cell_measurement_theta_min      3.727
_cell_volume                     2220.95(15)
_computing_cell_refinement       'CrysAlisPro 1.171.39.46 (Rigaku OD, 2018)'
_computing_data_collection       'CrysAlisPro 1.171.39.46 (Rigaku OD, 2018)'
_computing_data_reduction        'CrysAlisPro 1.171.39.46 (Rigaku OD, 2018)'
_computing_structure_refinement  'SHELXL-2017/1 (Sheldrick, 2017)'
_computing_structure_solution    'SHELXT 2018/2 (Sheldrick, 2018)'
_diffrn_ambient_temperature      293(2)
_diffrn_detector_area_resol_mean 10.4323
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.983
_diffrn_measurement_device_type  'Xcalibur, Ruby, Nova'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54184
_diffrn_reflns_av_R_equivalents  0.0432
_diffrn_reflns_av_unetI/netI     0.0533
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.983
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       7
_diffrn_reflns_limit_k_min       -10
_diffrn_reflns_limit_l_max       27
_diffrn_reflns_limit_l_min       -29
_diffrn_reflns_number            11112
_diffrn_reflns_point_group_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.983
_diffrn_reflns_theta_full        67.684
_diffrn_reflns_theta_max         75.976
_diffrn_reflns_theta_min         3.75
_diffrn_source                   'micro-focus sealed X-ray tube'
_exptl_absorpt_coefficient_mu    3.897
_exptl_absorpt_correction_T_max  1
_exptl_absorpt_correction_T_min  0.33453
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
        CrysAlisPro 1.171.39.46 (Rigaku Oxford Diffraction, 2018)
        Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            black
_exptl_crystal_density_diffrn    1.645
_exptl_crystal_description       prism
_exptl_crystal_F_000             1114
_exptl_crystal_size_max          0.34
_exptl_crystal_size_mid          0.12
_exptl_crystal_size_min          0.06
_refine_diff_density_max         1.402
_refine_diff_density_min         -0.646
_refine_diff_density_rms         0.151
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.14
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     378
_refine_ls_number_reflns         4567
_refine_ls_number_restraints     20
_refine_ls_restrained_S_all      1.151
_refine_ls_R_factor_all          0.0916
_refine_ls_R_factor_gt           0.0844
_refine_ls_shift/su_max          0.025
_refine_ls_shift/su_mean         0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.2000P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.2689
_reflns_number_gt                3888
_reflns_number_total             4567
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d2dt01949c2.cif
_cod_data_source_block           lidija_p100
_cod_original_sg_symbol_H-M      'P 2/c'
_cod_database_code               7711456
loop_
_space_group_symop_id
_space_group_symop_operation_xyz
1 x,y,z
2 -x,y,1/2-z
3 -x,-y,-z
4 x,-y,1/2+z
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
_atom_site_type_symbol
Cu1 0.24801(6) 0.25332(6) 0.58859(3) 0.0563(3) Uani d 1 . . Cu
Cr1 0 0.50304(9) 0.75 0.0514(3) Uani d 1 . . Cr
O1 0.2268(3) 0.2483(3) 0.66979(14) 0.0616(8) Uani d 1 . . O
O2 0.0554(3) 0.3948(3) 0.59300(12) 0.0595(7) Uani d 1 . . O
O3 -0.0297(3) 0.4940(3) 0.66649(12) 0.0569(7) Uani d 1 . . O
O4 0.1295(3) 0.3478(3) 0.73863(12) 0.0570(7) Uani d 1 . . O
O5A 0.5398(14) 0.1023(11) 0.5633(4) 0.087(3) Uani d 0.374(7) A 1 O
O6A 0.6204(11) 0.2459(13) 0.6333(6) 0.086(3) Uani d 0.374(7) A 1 O
O7A 0.4403(8) 0.1360(12) 0.6314(4) 0.0553(18) Uani d 0.374(7) A 1 O
O5B 0.491(4) 0.164(4) 0.5761(11) 0.087(3) Uani d 0.126(7) A 2 O
O6B 0.641(3) 0.167(4) 0.6406(16) 0.086(3) Uani d 0.126(7) A 2 O
O7B 0.439(3) 0.118(4) 0.6484(11) 0.0553(18) Uani d 0.126(7) A 2 O
O7 0.1191(4) 0.6716(4) 0.74564(14) 0.0698(8) Uani d 1 . . O
O8 0.1246(7) 0.9282(5) 0.7430(2) 0.1104(18) Uani d 1 . . O
O9 0.3834(3) 0.0494(5) 0.74247(14) 0.0698(8) Uani d 1 . . O
H9A 0.437117 0.114541 0.74861 0.105 Uiso d 1 . . H
O10 0.377(2) 0.557(3) 0.7765(8) 0.178(8) Uani d 0.5 . . O
H10 0.414881 0.473484 0.778491 0.22(4) Uiso d 1 . . H
O11 0.0896(5) 1.1356(4) 0.83777(18) 0.0902(12) Uani d 1 . . O
H11A 0.048542 1.179767 0.803566 0.135 Uiso d 1 . . H
H11B 0.128254 1.047163 0.822994 0.135 Uiso d 1 . . H
O12 0.4530(14) 0.294(3) 0.7553(7) 0.199(10) Uani d 0.5 . . O
N1 0.3271(4) 0.4645(5) 0.58350(18) 0.0642(9) Uani d 1 . . N
N2 0.2564(3) 0.2626(4) 0.50809(16) 0.0538(7) Uani d 1 . . N
N3 0.1792(3) 0.0437(4) 0.56589(14) 0.0544(7) Uani d 1 . . N
N4A 0.5389(8) 0.1565(10) 0.6124(4) 0.0398(19) Uani d 0.374(7) A 1 N
N4B 0.531(2) 0.148(3) 0.6263(13) 0.0398(19) Uani d 0.126(7) A 2 N
C1 0.3644(5) 0.5623(7) 0.6264(3) 0.0786(13) Uani d 1 . . C
H1 0.358787 0.531418 0.663545 0.094 Uiso calc 1 . . H
C2 0.4108(5) 0.7072(7) 0.6165(3) 0.0881(18) Uani d 1 . . C
H2 0.43597 0.77291 0.646585 0.106 Uiso calc 1 . . H
C3 0.4192(5) 0.7530(5) 0.5613(4) 0.0835(18) Uani d 1 . . C
H3 0.449013 0.850619 0.553879 0.1 Uiso calc 1 . . H
C4 0.3829(5) 0.6521(6) 0.5172(3) 0.0765(13) Uani d 1 . . C
H4 0.389602 0.680275 0.479846 0.092 Uiso calc 1 . . H
C5 0.3368(4) 0.5099(5) 0.5293(2) 0.0646(11) Uani d 1 . . C
C6 0.2940(4) 0.3954(5) 0.4858(2) 0.0589(9) Uani d 1 . . C
C7 0.2936(5) 0.4086(7) 0.4278(2) 0.0723(12) Uani d 1 . . C
H7 0.318374 0.499659 0.411744 0.087 Uiso calc 1 . . H
C8 0.2552(5) 0.2830(8) 0.3940(2) 0.0762(12) Uani d 1 . . C
H8 0.254514 0.290169 0.354912 0.091 Uiso calc 1 . . H
C9 0.2180(5) 0.1472(6) 0.41756(19) 0.0673(11) Uani d 1 . . C
H9 0.193623 0.062425 0.39498 0.081 Uiso calc 1 . . H
C10 0.2184(4) 0.1418(5) 0.47602(17) 0.0552(8) Uani d 1 . . C
C11 0.1743(4) 0.0138(5) 0.51000(18) 0.0551(9) Uani d 1 . . C
C12 0.1291(4) -0.1254(5) 0.4865(2) 0.0623(10) Uani d 1 . . C
H12 0.127649 -0.144771 0.447893 0.075 Uiso calc 1 . . H
C13 0.0863(5) -0.2342(5) 0.5225(2) 0.0659(11) Uani d 1 . . C
H13 0.05517 -0.327899 0.508048 0.079 Uiso calc 1 . . H
C14 0.0900(5) -0.2036(5) 0.5788(2) 0.0698(11) Uani d 1 . . C
H14 0.060936 -0.27563 0.603104 0.084 Uiso calc 1 . . H
C15 0.1385(4) -0.0615(5) 0.5999(2) 0.0618(9) Uani d 1 . . C
H15 0.142092 -0.040967 0.63856 0.074 Uiso calc 1 . . H
C16 0.0477(4) 0.4099(4) 0.64343(16) 0.0508(8) Uani d 1 . . C
C17 0.1423(4) 0.3278(4) 0.68694(16) 0.0528(8) Uani d 1 . . C
C18 0.0714(7) 0.8055(5) 0.7471(2) 0.0771(14) Uani d 1 . . C
C19 0.387(2) -0.112(2) 0.7601(11) 0.204(17) Uani d 0.5 . . C
C20 0.372(3) 0.717(3) 0.7547(10) 0.138(7) Uani d 0.5 . . C
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0 0 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.018 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cr Cr -0.1635 2.4439 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu -1.9646 0.5888 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N2 Cu1 O1 175.87(14) . . ?
N2 Cu1 N3 80.27(14) . . ?
O1 Cu1 N3 99.20(14) . . ?
N2 Cu1 N1 80.46(16) . . ?
O1 Cu1 N1 100.17(15) . . ?
N3 Cu1 N1 160.61(16) . . ?
N2 Cu1 O7A 107.1(2) . . ?
O1 Cu1 O7A 77.0(2) . . ?
N3 Cu1 O7A 90.5(3) . . ?
N1 Cu1 O7A 93.0(3) . . ?
N2 Cu1 O2 99.28(12) . . ?
O1 Cu1 O2 76.73(12) . . ?
N3 Cu1 O2 99.86(12) . . ?
N1 Cu1 O2 85.46(14) . . ?
O7A Cu1 O2 153.0(2) . . ?
O7 Cr1 O7 83.8(2) . 2_556 ?
O7 Cr1 O3 90.50(14) . . ?
O7 Cr1 O3 92.91(13) 2_556 . ?
O7 Cr1 O3 92.91(13) . 2_556 ?
O7 Cr1 O3 90.50(14) 2_556 2_556 ?
O3 Cr1 O3 175.42(15) . 2_556 ?
O7 Cr1 O4 90.88(15) . . ?
O7 Cr1 O4 173.03(14) 2_556 . ?
O3 Cr1 O4 82.67(11) . . ?
O3 Cr1 O4 94.22(12) 2_556 . ?
O7 Cr1 O4 173.03(14) . 2_556 ?
O7 Cr1 O4 90.88(15) 2_556 2_556 ?
O3 Cr1 O4 94.22(12) . 2_556 ?
O3 Cr1 O4 82.67(12) 2_556 2_556 ?
O4 Cr1 O4 94.80(19) . 2_556 ?
C17 O1 Cu1 118.6(3) . . ?
C16 O2 Cu1 104.7(3) . . ?
C16 O3 Cr1 114.4(2) . . ?
C17 O4 Cr1 112.6(2) . . ?
N4A O7A Cu1 122.1(6) . . ?
C18 O7 Cr1 113.9(4) . . ?
C19 O9 H9A 128.4 . . ?
C20 O10 H10 146(10) . . ?
H11A O11 H11B 101 . . ?
C1 N1 C5 118.8(5) . . ?
C1 N1 Cu1 127.8(4) . . ?
C5 N1 Cu1 113.3(3) . . ?
C10 N2 C6 122.3(4) . . ?
C10 N2 Cu1 119.2(3) . . ?
C6 N2 Cu1 118.4(3) . . ?
C15 N3 C11 119.3(4) . . ?
C15 N3 Cu1 126.6(3) . . ?
C11 N3 Cu1 114.1(3) . . ?
O7A N4A O6A 124.1(11) . . ?
O7A N4A O5A 112.9(10) . . ?
O6A N4A O5A 121.5(11) . . ?
O7B N4B O6B 138(3) . . ?
O7B N4B O5B 103(2) . . ?
O6B N4B O5B 119(3) . . ?
N1 C1 C2 121.6(6) . . ?
N1 C1 H1 119.2 . . ?
C2 C1 H1 119.2 . . ?
C1 C2 C3 119.2(6) . . ?
C1 C2 H2 120.4 . . ?
C3 C2 H2 120.4 . . ?
C2 C3 C4 119.3(5) . . ?
C2 C3 H3 120.3 . . ?
C4 C3 H3 120.3 . . ?
C5 C4 C3 119.1(6) . . ?
C5 C4 H4 120.5 . . ?
C3 C4 H4 120.5 . . ?
N1 C5 C4 121.9(5) . . ?
N1 C5 C6 114.6(4) . . ?
C4 C5 C6 123.5(5) . . ?
N2 C6 C7 119.7(4) . . ?
N2 C6 C5 112.7(4) . . ?
C7 C6 C5 127.5(4) . . ?
C6 C7 C8 118.5(5) . . ?
C6 C7 H7 120.8 . . ?
C8 C7 H7 120.8 . . ?
C9 C8 C7 121.2(5) . . ?
C9 C8 H8 119.4 . . ?
C7 C8 H8 119.4 . . ?
C8 C9 C10 117.7(5) . . ?
C8 C9 H9 121.1 . . ?
C10 C9 H9 121.1 . . ?
N2 C10 C9 120.6(4) . . ?
N2 C10 C11 112.1(4) . . ?
C9 C10 C11 127.2(4) . . ?
N3 C11 C12 122.1(4) . . ?
N3 C11 C10 114.4(3) . . ?
C12 C11 C10 123.4(4) . . ?
C13 C12 C11 118.0(4) . . ?
C13 C12 H12 121 . . ?
C11 C12 H12 121 . . ?
C14 C13 C12 119.9(4) . . ?
C14 C13 H13 120 . . ?
C12 C13 H13 120 . . ?
C13 C14 C15 119.2(5) . . ?
C13 C14 H14 120.4 . . ?
C15 C14 H14 120.4 . . ?
N3 C15 C14 121.4(4) . . ?
N3 C15 H15 119.3 . . ?
C14 C15 H15 119.3 . . ?
O2 C16 O3 127.2(4) . . ?
O2 C16 C17 119.5(4) . . ?
O3 C16 C17 113.3(3) . . ?
O1 C17 O4 123.9(4) . . ?
O1 C17 C16 119.5(4) . . ?
O4 C17 C16 116.6(3) . . ?
O8 C18 O7 126.6(7) . . ?
O8 C18 C18 119.2(5) . 2_556 ?
O7 C18 C18 114.2(3) . 2_556 ?
O9 C19 C20 158(2) . 1_545 ?
C19 C20 O10 154(2) 1_565 . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
_geom_bond_publ_flag
Cu1 N2 . 1.925(4) ?
Cu1 O1 . 1.968(3) ?
Cu1 N3 . 2.015(4) ?
Cu1 N1 . 2.033(4) ?
Cu1 O7A . 2.438(8) ?
Cu1 O2 . 2.439(3) ?
Cr1 O7 . 1.963(3) ?
Cr1 O7 2_556 1.963(3) ?
Cr1 O3 . 1.972(3) ?
Cr1 O3 2_556 1.972(3) ?
Cr1 O4 . 1.988(3) ?
Cr1 O4 2_556 1.988(3) ?
O1 C17 . 1.254(5) ?
O2 C16 . 1.217(5) ?
O3 C16 . 1.282(5) ?
O4 C17 . 1.263(5) ?
O5A N4A . 1.259(12) ?
O6A N4A . 1.237(12) ?
O7A N4A . 1.222(10) ?
O5B N4B . 1.228(19) ?
O6B N4B . 1.213(18) ?
O7B N4B . 1.211(18) ?
O7 C18 . 1.273(7) ?
O8 C18 . 1.219(7) ?
O9 C19 . 1.46(2) ?
O9 H9A . 0.8129 ?
O10 C20 . 1.483(18) ?
O10 H10 . 0.83(2) ?
O11 H11A . 0.960(10) ?
O11 H11B . 0.9598 ?
O12 O12 2_656 1.08(3) ?
N1 C1 . 1.350(7) ?
N1 C5 . 1.360(7) ?
N2 C10 . 1.332(5) ?
N2 C6 . 1.350(6) ?
N3 C15 . 1.328(6) ?
N3 C11 . 1.346(6) ?
C1 C2 . 1.384(9) ?
C1 H1 . 0.93 ?
C2 C3 . 1.381(11) ?
C2 H2 . 0.93 ?
C3 C4 . 1.387(9) ?
C3 H3 . 0.93 ?
C4 C5 . 1.374(7) ?
C4 H4 . 0.93 ?
C5 C6 . 1.469(7) ?
C6 C7 . 1.381(7) ?
C7 C8 . 1.387(9) ?
C7 H7 . 0.93 ?
C8 C9 . 1.383(8) ?
C8 H8 . 0.93 ?
C9 C10 . 1.388(6) ?
C9 H9 . 0.93 ?
C10 C11 . 1.483(6) ?
C11 C12 . 1.395(6) ?
C12 C13 . 1.388(7) ?
C12 H12 . 0.93 ?
C13 C14 . 1.359(8) ?
C13 H13 . 0.93 ?
C14 C15 . 1.409(7) ?
C14 H14 . 0.93 ?
C15 H15 . 0.93 ?
C16 C17 . 1.543(5) ?
C18 C18 2_556 1.575(14) ?
C19 C20 1_545 1.50(3) ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Cu1 O7A N4A O6A 102.0(11) . . . . ?
Cu1 O7A N4A O5A -64.3(11) . . . . ?
C5 N1 C1 C2 0.6(8) . . . . ?
Cu1 N1 C1 C2 -176.3(4) . . . . ?
N1 C1 C2 C3 0.0(9) . . . . ?
C1 C2 C3 C4 -1.0(9) . . . . ?
C2 C3 C4 C5 1.4(8) . . . . ?
C1 N1 C5 C4 -0.2(7) . . . . ?
Cu1 N1 C5 C4 177.1(4) . . . . ?
C1 N1 C5 C6 179.9(4) . . . . ?
Cu1 N1 C5 C6 -2.8(5) . . . . ?
C3 C4 C5 N1 -0.8(7) . . . . ?
C3 C4 C5 C6 179.1(4) . . . . ?
C10 N2 C6 C7 0.1(6) . . . . ?
Cu1 N2 C6 C7 -176.0(3) . . . . ?
C10 N2 C6 C5 -177.5(4) . . . . ?
Cu1 N2 C6 C5 6.4(5) . . . . ?
N1 C5 C6 N2 -2.1(5) . . . . ?
C4 C5 C6 N2 178.0(4) . . . . ?
N1 C5 C6 C7 -179.5(4) . . . . ?
C4 C5 C6 C7 0.7(7) . . . . ?
N2 C6 C7 C8 -0.7(7) . . . . ?
C5 C6 C7 C8 176.5(5) . . . . ?
C6 C7 C8 C9 0.1(8) . . . . ?
C7 C8 C9 C10 1.1(8) . . . . ?
C6 N2 C10 C9 1.1(6) . . . . ?
Cu1 N2 C10 C9 177.1(3) . . . . ?
C6 N2 C10 C11 -176.3(4) . . . . ?
Cu1 N2 C10 C11 -0.3(5) . . . . ?
C8 C9 C10 N2 -1.7(7) . . . . ?
C8 C9 C10 C11 175.4(5) . . . . ?
C15 N3 C11 C12 -0.8(6) . . . . ?
Cu1 N3 C11 C12 -179.9(3) . . . . ?
C15 N3 C11 C10 178.1(4) . . . . ?
Cu1 N3 C11 C10 -1.0(4) . . . . ?
N2 C10 C11 N3 0.9(5) . . . . ?
C9 C10 C11 N3 -176.3(4) . . . . ?
N2 C10 C11 C12 179.7(4) . . . . ?
C9 C10 C11 C12 2.5(7) . . . . ?
N3 C11 C12 C13 1.0(6) . . . . ?
C10 C11 C12 C13 -177.7(4) . . . . ?
C11 C12 C13 C14 -0.4(7) . . . . ?
C12 C13 C14 C15 -0.5(7) . . . . ?
C11 N3 C15 C14 -0.2(6) . . . . ?
Cu1 N3 C15 C14 178.8(3) . . . . ?
C13 C14 C15 N3 0.8(7) . . . . ?
Cu1 O2 C16 O3 170.2(3) . . . . ?
Cu1 O2 C16 C17 -6.8(4) . . . . ?
Cr1 O3 C16 O2 -174.0(3) . . . . ?
Cr1 O3 C16 C17 3.2(4) . . . . ?
Cu1 O1 C17 O4 -171.2(3) . . . . ?
Cu1 O1 C17 C16 7.8(5) . . . . ?
Cr1 O4 C17 O1 172.1(3) . . . . ?
Cr1 O4 C17 C16 -6.9(4) . . . . ?
O2 C16 C17 O1 1.0(6) . . . . ?
O3 C16 C17 O1 -176.4(4) . . . . ?
O2 C16 C17 O4 -180.0(4) . . . . ?
O3 C16 C17 O4 2.6(5) . . . . ?
Cr1 O7 C18 O8 -177.3(5) . . . . ?
Cr1 O7 C18 C18 0.9(6) . . . 2_556 ?
