#------------------------------------------------------------------------------
#$Date: 2022-11-11 02:01:51 +0200 (Fri, 11 Nov 2022) $
#$Revision: 279221 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/71/17/7711747.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7711747
loop_
_publ_author_name
'Roy, Soumalya'
'Shukla, Pooja'
'Ahmed, Naushad'
'Du, Ming-Hao'
'Tarannum, Ibtesham'
'Kong, Xiang-Jian'
'Gupta, Tulika'
'Singh, Saurabh Kumar Kumar'
'Das, Sourav'
_publ_section_title
;
 Interplay between anisotropy and magnetic exchange to modulate magnetic
 relaxation behaviors of phenoxo bridged Dy2 dimers with axial
 β-diketonate co-ligands
;
_journal_name_full               'Dalton Transactions'
_journal_paper_doi               10.1039/D2DT03117E
_journal_year                    2022
_chemical_formula_moiety         'C44 H28 Dy2 F12 N4 O10'
_chemical_formula_sum            'C44 H28 Dy2 F12 N4 O10'
_chemical_formula_weight         1325.70
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2yn'
_space_group_name_H-M_alt        'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     iterative
_audit_creation_date             2022-10-18
_audit_creation_method
;
Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_audit_update_record
;
2022-11-06 deposited with the CCDC.	2022-11-10 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 91.215(14)
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   10.559(3)
_cell_length_b                   17.123(3)
_cell_length_c                   12.969(2)
_cell_measurement_reflns_used    9600
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      25.30
_cell_measurement_theta_min      2.85
_cell_volume                     2344.3(9)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'olex2.solve (Bourhis et al., 2015)'
_diffrn_ambient_temperature      150.0
_diffrn_measured_fraction_theta_full 0.983
_diffrn_measured_fraction_theta_max 0.983
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0212
_diffrn_reflns_av_unetI/netI     0.0158
_diffrn_reflns_Laue_measured_fraction_full 0.983
_diffrn_reflns_Laue_measured_fraction_max 0.983
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_k_min       -20
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_number            21676
_diffrn_reflns_point_group_measured_fraction_full 0.983
_diffrn_reflns_point_group_measured_fraction_max 0.983
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         25.368
_diffrn_reflns_theta_min         2.514
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    3.271
_exptl_absorpt_correction_T_max  1
_exptl_absorpt_correction_T_min  0.77864
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
'SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.'
_exptl_crystal_colour            'clear yellow'
_exptl_crystal_colour_lustre     clear
_exptl_crystal_colour_primary    yellow
_exptl_crystal_density_diffrn    1.878
_exptl_crystal_description       block
_exptl_crystal_F_000             1280
_exptl_crystal_size_max          0.317
_exptl_crystal_size_mid          0.31
_exptl_crystal_size_min          0.3
_refine_diff_density_max         0.882
_refine_diff_density_min         -0.611
_refine_diff_density_rms         0.081
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.228
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     354
_refine_ls_number_reflns         4227
_refine_ls_number_restraints     6
_refine_ls_restrained_S_all      1.235
_refine_ls_R_factor_all          0.0243
_refine_ls_R_factor_gt           0.0242
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+7.9550P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0580
_refine_ls_wR_factor_ref         0.0580
_reflns_Friedel_coverage         0.000
_reflns_number_gt                4201
_reflns_number_total             4227
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d2dt03117e2.cif
_cod_data_source_block           Compound_02
_cod_database_code               7711747
_shelx_shelxl_version_number     2018/1
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_max   0.440
_shelx_estimated_absorpt_t_min   0.424
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2. Uiso/Uaniso restraints and constraints
Uanis(F4) \\sim Ueq: with sigma of 0.01 and sigma for terminal atoms of 0.02
3. Rigid body (RIGU) restrains
 F4, F5, F6
 with sigma for 1-2 distances of 0.004 and sigma for 1-3 distances of 0.004
4. Others
 Sof(F5A)=Sof(F6A)=Sof(F4A)=1-FVAR(1)
 Sof(F5)=Sof(F4)=Sof(F6)=FVAR(1)
5.a Aromatic/amide H refined with riding coordinates:
 C12(H12), C5(H5), C7(H7), C11(H11), C2(H2), C20(H20), C3(H3), C4(H4),
 C10(H10), C9(H9), C15(H15)
5.b Idealised Me refined as rotating group:
 C17(H17A,H17B,H17C)
;
_olex2_submission_special_instructions 'No special instructions were received'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Dy1 Dy 0.42967(2) 0.48515(2) 0.36654(2) 0.01689(7) Uani 1 1 d . . . . .
O5 O 0.3189(2) 0.60013(15) 0.4055(2) 0.0257(6) Uani 1 1 d . . . . .
O4 O 0.4855(2) 0.58130(15) 0.24740(19) 0.0243(6) Uani 1 1 d . . . . .
O3 O 0.4170(2) 0.35180(15) 0.4031(2) 0.0269(6) Uani 1 1 d . . . . .
O2 O 0.5643(2) 0.41815(15) 0.2554(2) 0.0257(6) Uani 1 1 d . . . . .
C12 C 0.6662(4) 0.5302(3) 0.8918(3) 0.0322(9) Uani 1 1 d . . . . .
H12 H 0.579876 0.516789 0.901136 0.039 Uiso 1 1 calc R . . . .
C5 C 0.9458(3) 0.5847(2) 0.4645(3) 0.0226(7) Uani 1 1 d . . . . .
H5 H 1.009633 0.597756 0.514289 0.027 Uiso 1 1 calc R . . . .
O1 O 0.6134(2) 0.52139(15) 0.45536(18) 0.0205(5) Uani 1 1 d . . . . .
N2 N 0.7070(3) 0.53849(19) 0.7951(2) 0.0250(7) Uani 1 1 d . . . . .
F3 F 0.6602(3) 0.6819(2) 0.1593(3) 0.0746(10) Uani 1 1 d . . . . .
F1 F 0.5103(5) 0.7649(2) 0.1342(4) 0.114(2) Uani 1 1 d . . . . .
C6 C 0.8262(3) 0.5611(2) 0.4975(3) 0.0188(7) Uani 1 1 d . . . . .
F2 F 0.5051(4) 0.6543(3) 0.0609(3) 0.0883(12) Uani 1 1 d . . . . .
C7 C 0.8723(3) 0.5669(2) 0.6767(3) 0.0211(7) Uani 1 1 d . . . . .
H7 H 0.956850 0.582185 0.663416 0.025 Uiso 1 1 calc R . . . .
C11 C 0.7429(4) 0.5400(3) 0.9785(3) 0.0326(9) Uani 1 1 d . . . . .
H11 H 0.710015 0.533646 1.045630 0.039 Uiso 1 1 calc R . . . .
C1 C 0.7293(3) 0.5418(2) 0.4243(3) 0.0181(7) Uani 1 1 d . . . . .
C2 C 0.7597(3) 0.5459(2) 0.3199(3) 0.0238(8) Uani 1 1 d . . . . .
H2 H 0.697638 0.532023 0.269100 0.029 Uiso 1 1 calc R . . . .
C21 C 0.4519(4) 0.2888(2) 0.3635(3) 0.0261(8) Uani 1 1 d . . . . .
C16 C 0.3233(4) 0.6710(2) 0.3828(3) 0.0284(8) Uani 1 1 d . . . . .
C8 C 0.8299(3) 0.5579(2) 0.7829(3) 0.0233(8) Uani 1 1 d . . . . .
C20 C 0.5377(4) 0.2826(2) 0.2829(3) 0.0334(9) Uani 1 1 d . . . . .
H20 H 0.560104 0.232220 0.258644 0.040 Uiso 1 1 calc R . . . .
C3 C 0.8782(4) 0.5696(2) 0.2893(3) 0.0259(8) Uani 1 1 d . . . . .
H3 H 0.895620 0.572593 0.217809 0.031 Uiso 1 1 calc R . . . .
C4 C 0.9722(3) 0.5892(2) 0.3612(3) 0.0244(8) Uani 1 1 d . . . . .
H4 H 1.053420 0.605434 0.339415 0.029 Uiso 1 1 calc R . . . .
C10 C 0.8682(4) 0.5592(3) 0.9654(3) 0.0335(9) Uani 1 1 d . . . . .
H10 H 0.923317 0.566059 1.023566 0.040 Uiso 1 1 calc R . . . .
C14 C 0.4681(4) 0.6541(2) 0.2401(3) 0.0295(9) Uani 1 1 d . . . . .
C22 C 0.3955(5) 0.2152(3) 0.4095(4) 0.0408(11) Uani 1 1 d . . . . .
C17 C 0.2450(5) 0.7266(3) 0.4455(4) 0.0440(12) Uani 1 1 d . . . . .
H17A H 0.183098 0.752934 0.400167 0.066 Uiso 1 1 calc GR . . . .
H17B H 0.300662 0.765564 0.478294 0.066 Uiso 1 1 calc GR . . . .
H17C H 0.200570 0.697405 0.498704 0.066 Uiso 1 1 calc GR . . . .
C19 C 0.5909(4) 0.3477(2) 0.2377(3) 0.0288(8) Uani 1 1 d . . . . .
C9 C 0.9129(4) 0.5685(2) 0.8665(3) 0.0309(9) Uani 1 1 d . . . . .
H9 H 0.998899 0.581905 0.855869 0.037 Uiso 1 1 calc R . . . .
C13 C 0.5381(5) 0.6915(3) 0.1510(4) 0.0447(12) Uani 1 1 d . . . . .
C15 C 0.3958(5) 0.7009(2) 0.3009(4) 0.0392(11) Uani 1 1 d . . . . .
H15 H 0.394123 0.755436 0.287796 0.047 Uiso 1 1 calc R . . . .
C18 C 0.6946(5) 0.3352(3) 0.1599(5) 0.0531(14) Uani 1 1 d . . . . .
N1 N 0.7937(3) 0.55384(17) 0.6021(2) 0.0189(6) Uani 1 1 d . . . . .
F5 F 0.8095(6) 0.3540(5) 0.2099(7) 0.114(3) Uani 0.655(5) 1 d . U P A 1
F4 F 0.6898(8) 0.3828(3) 0.0877(5) 0.112(3) Uani 0.655(5) 1 d . U P A 1
F6 F 0.7094(6) 0.2654(3) 0.1293(4) 0.077(2) Uani 0.655(5) 1 d . U P A 1
F5A F 0.4335(7) 0.2078(4) 0.5020(6) 0.041(2) Uani 0.345(5) 1 d . . P A 2
F6A F 0.2655(7) 0.2286(4) 0.4141(6) 0.039(2) Uani 0.345(5) 1 d . . P A 2
F4A F 0.4084(8) 0.1545(4) 0.3569(6) 0.049(2) Uani 0.345(5) 1 d . . P A 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O5 Dy1 Dy1 82.97(7) . 3_666 ?
O5 Dy1 O1 73.90(9) . 3_666 ?
O5 Dy1 N2 91.97(10) . 3_666 ?
O5 Dy1 N1 73.28(9) . 3_666 ?
O4 Dy1 Dy1 114.26(7) . 3_666 ?
O4 Dy1 O5 71.73(9) . . ?
O4 Dy1 O2 76.94(9) . . ?
O4 Dy1 O1 137.19(9) . 3_666 ?
O4 Dy1 N2 73.48(10) . 3_666 ?
O4 Dy1 N1 123.25(9) . 3_666 ?
O3 Dy1 Dy1 88.21(7) . 3_666 ?
O3 Dy1 O5 138.09(9) . . ?
O3 Dy1 O4 146.83(9) . . ?
O3 Dy1 O2 71.60(9) . . ?
O3 Dy1 O1 75.10(9) . 3_666 ?
O3 Dy1 N2 88.73(10) . 3_666 ?
O3 Dy1 N1 69.33(9) . 3_666 ?
O2 Dy1 Dy1 113.45(7) . 3_666 ?
O2 Dy1 O5 148.52(9) . . ?
O2 Dy1 O1 135.10(9) . 3_666 ?
O2 Dy1 N2 75.95(10) . 3_666 ?
O2 Dy1 N1 123.85(9) . 3_666 ?
O1 Dy1 Dy1 35.98(6) 3_666 3_666 ?
O1 Dy1 Dy1 36.81(6) . 3_666 ?
O1 Dy1 O5 94.81(9) . . ?
O1 Dy1 O4 85.40(9) . . ?
O1 Dy1 O3 102.20(9) . . ?
O1 Dy1 O2 85.67(9) . . ?
O1 Dy1 O1 72.79(9) . 3_666 ?
O1 Dy1 N2 132.61(9) 3_666 3_666 ?
O1 Dy1 N2 154.53(9) . 3_666 ?
O1 Dy1 N1 140.79(9) . 3_666 ?
O1 Dy1 N1 68.03(9) 3_666 3_666 ?
N2 Dy1 Dy1 168.51(7) 3_666 3_666 ?
N1 Dy1 Dy1 104.00(7) 3_666 3_666 ?
N1 Dy1 N2 64.59(10) 3_666 3_666 ?
C16 O5 Dy1 137.9(2) . . ?
C14 O4 Dy1 134.8(2) . . ?
C21 O3 Dy1 137.7(2) . . ?
C19 O2 Dy1 136.1(2) . . ?
N2 C12 H12 118.2 . . ?
N2 C12 C11 123.6(4) . . ?
C11 C12 H12 118.2 . . ?
C6 C5 H5 119.5 . . ?
C4 C5 H5 119.5 . . ?
C4 C5 C6 121.0(3) . . ?
Dy1 O1 Dy1 107.21(9) . 3_666 ?
C1 O1 Dy1 132.7(2) . . ?
C1 O1 Dy1 120.1(2) . 3_666 ?
C12 N2 Dy1 124.3(3) . 3_666 ?
C12 N2 C8 117.6(3) . . ?
C8 N2 Dy1 118.0(2) . 3_666 ?
C5 C6 C1 120.3(3) . . ?
C5 C6 N1 123.8(3) . . ?
N1 C6 C1 115.9(3) . . ?
C8 C7 H7 120.5 . . ?
N1 C7 H7 120.5 . . ?
N1 C7 C8 119.1(3) . . ?
C12 C11 H11 120.8 . . ?
C10 C11 C12 118.5(4) . . ?
C10 C11 H11 120.8 . . ?
O1 C1 C6 120.5(3) . . ?
O1 C1 C2 122.2(3) . . ?
C2 C1 C6 117.3(3) . . ?
C1 C2 H2 119.3 . . ?
C3 C2 C1 121.4(3) . . ?
C3 C2 H2 119.3 . . ?
O3 C21 C20 124.8(4) . . ?
O3 C21 C22 115.6(3) . . ?
C20 C21 C22 119.7(4) . . ?
O5 C16 C17 117.5(4) . . ?
O5 C16 C15 123.4(4) . . ?
C15 C16 C17 119.1(4) . . ?
N2 C8 C7 116.7(3) . . ?
N2 C8 C9 122.1(4) . . ?
C9 C8 C7 121.2(3) . . ?
C21 C20 H20 119.0 . . ?
C19 C20 C21 122.0(4) . . ?
C19 C20 H20 119.0 . . ?
C2 C3 H3 119.5 . . ?
C2 C3 C4 121.1(3) . . ?
C4 C3 H3 119.5 . . ?
C5 C4 C3 118.9(3) . . ?
C5 C4 H4 120.5 . . ?
C3 C4 H4 120.5 . . ?
C11 C10 H10 120.4 . . ?
C11 C10 C9 119.2(4) . . ?
C9 C10 H10 120.4 . . ?
O4 C14 C13 113.5(3) . . ?
O4 C14 C15 128.1(4) . . ?
C15 C14 C13 118.4(4) . . ?
F5A C22 C21 109.7(5) . . ?
F5A C22 F6A 105.6(6) . . ?
F6A C22 C21 106.0(4) . . ?
F4A C22 C21 115.2(5) . . ?
F4A C22 F5A 113.5(7) . . ?
F4A C22 F6A 106.2(6) . . ?
C16 C17 H17A 109.5 . . ?
C16 C17 H17B 109.5 . . ?
C16 C17 H17C 109.5 . . ?
H17A C17 H17B 109.5 . . ?
H17A C17 H17C 109.5 . . ?
H17B C17 H17C 109.5 . . ?
O2 C19 C20 126.8(4) . . ?
O2 C19 C18 115.0(4) . . ?
C20 C19 C18 118.2(4) . . ?
C8 C9 H9 120.5 . . ?
C10 C9 C8 119.0(4) . . ?
C10 C9 H9 120.5 . . ?
F3 C13 F1 110.7(5) . . ?
F3 C13 F2 104.2(4) . . ?
F3 C13 C14 112.2(4) . . ?
F1 C13 F2 104.7(5) . . ?
F1 C13 C14 114.7(4) . . ?
F2 C13 C14 109.4(4) . . ?
C16 C15 H15 118.7 . . ?
C14 C15 C16 122.5(4) . . ?
C14 C15 H15 118.7 . . ?
F5 C18 C19 106.8(5) . . ?
F4 C18 C19 112.9(5) . . ?
F4 C18 F5 102.7(7) . . ?
F4 C18 F6 112.7(6) . . ?
F6 C18 C19 115.8(4) . . ?
F6 C18 F5 104.5(6) . . ?
C6 N1 Dy1 115.5(2) . 3_666 ?
C7 N1 Dy1 121.5(2) . 3_666 ?
C7 N1 C6 123.0(3) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Dy1 Dy1 3.7723(8) 3_666 ?
Dy1 O5 2.350(3) . ?
Dy1 O4 2.342(2) . ?
Dy1 O3 2.336(3) . ?
Dy1 O2 2.345(3) . ?
Dy1 O1 2.366(2) 3_666 ?
Dy1 O1 2.320(2) . ?
Dy1 N2 2.552(3) 3_666 ?
Dy1 N1 2.493(3) 3_666 ?
O5 C16 1.250(5) . ?
O4 C14 1.263(5) . ?
O3 C21 1.253(5) . ?
O2 C19 1.261(5) . ?
C12 H12 0.9500 . ?
C12 N2 1.342(5) . ?
C12 C11 1.383(6) . ?
C5 H5 0.9500 . ?
C5 C6 1.401(5) . ?
C5 C4 1.377(5) . ?
O1 C1 1.343(4) . ?
N2 C8 1.351(5) . ?
F3 C13 1.302(6) . ?
F1 C13 1.307(6) . ?
C6 C1 1.420(5) . ?
C6 N1 1.412(4) . ?
F2 C13 1.370(7) . ?
C7 H7 0.9500 . ?
C7 C8 1.465(5) . ?
C7 N1 1.281(5) . ?
C11 H11 0.9500 . ?
C11 C10 1.377(6) . ?
C1 C2 1.399(5) . ?
C2 H2 0.9500 . ?
C2 C3 1.382(5) . ?
C21 C20 1.402(5) . ?
C21 C22 1.520(6) . ?
C16 C17 1.509(6) . ?
C16 C15 1.418(6) . ?
C8 C9 1.392(5) . ?
C20 H20 0.9500 . ?
C20 C19 1.383(6) . ?
C3 H3 0.9500 . ?
C3 C4 1.388(6) . ?
C4 H4 0.9500 . ?
C10 H10 0.9500 . ?
C10 C9 1.386(6) . ?
C14 C13 1.526(6) . ?
C14 C15 1.368(6) . ?
C22 F5A 1.263(9) . ?
C22 F6A 1.395(8) . ?
C22 F4A 1.252(9) . ?
C17 H17A 0.9800 . ?
C17 H17B 0.9800 . ?
C17 H17C 0.9800 . ?
C19 C18 1.520(6) . ?
C9 H9 0.9500 . ?
C15 H15 0.9500 . ?
C18 F5 1.401(9) . ?
C18 F4 1.241(8) . ?
C18 F6 1.270(6) . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Dy1 O5 C16 C17 -168.0(3) . . . . ?
Dy1 O5 C16 C15 13.0(7) . . . . ?
Dy1 O4 C14 C13 173.6(3) . . . . ?
Dy1 O4 C14 C15 -6.6(7) . . . . ?
Dy1 O3 C21 C20 12.4(6) . . . . ?
Dy1 O3 C21 C22 -168.3(3) . . . . ?
Dy1 O2 C19 C20 2.5(7) . . . . ?
Dy1 O2 C19 C18 -176.0(3) . . . . ?
Dy1 O1 C1 C6 -179.6(2) . . . . ?
Dy1 O1 C1 C6 -1.3(4) 3_666 . . . ?
Dy1 O1 C1 C2 179.5(3) 3_666 . . . ?
Dy1 O1 C1 C2 1.1(5) . . . . ?
Dy1 N2 C8 C7 2.6(4) 3_666 . . . ?
Dy1 N2 C8 C9 -177.1(3) 3_666 . . . ?
O5 C16 C15 C14 -0.4(7) . . . . ?
O4 C14 C13 F3 -60.0(6) . . . . ?
O4 C14 C13 F1 172.5(5) . . . . ?
O4 C14 C13 F2 55.2(5) . . . . ?
O4 C14 C15 C16 -2.4(8) . . . . ?
O3 C21 C20 C19 -1.4(7) . . . . ?
O3 C21 C22 F5A -65.1(6) . . . . ?
O3 C21 C22 F6A 48.5(6) . . . . ?
O3 C21 C22 F4A 165.5(6) . . . . ?
O2 C19 C18 F5 74.5(6) . . . . ?
O2 C19 C18 F4 -37.6(8) . . . . ?
O2 C19 C18 F6 -169.6(6) . . . . ?
C12 N2 C8 C7 -179.8(3) . . . . ?
C12 N2 C8 C9 0.5(6) . . . . ?
C12 C11 C10 C9 0.4(6) . . . . ?
C5 C6 C1 O1 -178.0(3) . . . . ?
C5 C6 C1 C2 1.3(5) . . . . ?
C5 C6 N1 Dy1 178.0(3) . . . 3_666 ?
C5 C6 N1 C7 -1.4(5) . . . . ?
O1 C1 C2 C3 177.7(3) . . . . ?
N2 C12 C11 C10 -0.1(7) . . . . ?
N2 C8 C9 C10 -0.3(6) . . . . ?
C6 C5 C4 C3 -0.3(6) . . . . ?
C6 C1 C2 C3 -1.6(5) . . . . ?
C7 C8 C9 C10 -179.9(4) . . . . ?
C11 C12 N2 Dy1 177.2(3) . . . 3_666 ?
C11 C12 N2 C8 -0.3(6) . . . . ?
C11 C10 C9 C8 -0.2(6) . . . . ?
C1 C6 N1 Dy1 -2.8(4) . . . 3_666 ?
C1 C6 N1 C7 177.8(3) . . . . ?
C1 C2 C3 C4 1.0(6) . . . . ?
C2 C3 C4 C5 0.0(6) . . . . ?
C21 C20 C19 O2 -5.7(7) . . . . ?
C21 C20 C19 C18 172.8(5) . . . . ?
C8 C7 N1 Dy1 0.6(4) . . . 3_666 ?
C8 C7 N1 C6 180.0(3) . . . . ?
C20 C21 C22 F5A 114.2(6) . . . . ?
C20 C21 C22 F6A -132.2(5) . . . . ?
C20 C21 C22 F4A -15.2(8) . . . . ?
C20 C19 C18 F5 -104.2(6) . . . . ?
C20 C19 C18 F4 143.6(6) . . . . ?
C20 C19 C18 F6 11.7(8) . . . . ?
C4 C5 C6 C1 -0.4(5) . . . . ?
C4 C5 C6 N1 178.8(3) . . . . ?
C22 C21 C20 C19 179.4(4) . . . . ?
C17 C16 C15 C14 -179.4(5) . . . . ?
C13 C14 C15 C16 177.4(4) . . . . ?
C15 C14 C13 F3 120.2(5) . . . . ?
C15 C14 C13 F1 -7.4(7) . . . . ?
C15 C14 C13 F2 -124.6(5) . . . . ?
N1 C6 C1 O1 2.8(5) . . . . ?
N1 C6 C1 C2 -177.9(3) . . . . ?
N1 C7 C8 N2 -2.1(5) . . . . ?
N1 C7 C8 C9 177.5(4) . . . . ?
