#------------------------------------------------------------------------------
#$Date: 2023-05-05 05:15:28 +0300 (Fri, 05 May 2023) $
#$Revision: 283297 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/71/20/7712081.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7712081
loop_
_publ_author_name
'Bykowski, Janelle'
'Sinclair, Jocelyn'
'Trach, Jonathan'
'Ferguson, Michael J.'
'Rivard, Eric'
_publ_section_title
;
 Molecular Sn(II) precursors for room temperature deposition of
 crystalline elemental tin.
;
_journal_issue                   6
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              1602
_journal_page_last               1607
_journal_paper_doi               10.1039/d2dt04028j
_journal_volume                  52
_journal_year                    2023
_chemical_formula_moiety         'C32 H70 K2 O8 Sn2'
_chemical_formula_sum            'C32 H70 K2 O8 Sn2'
_chemical_formula_weight         898.46
_chemical_properties_physical    Air-sensitive
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_audit_creation_method           SHELXL-2018/3
_audit_update_record
;
2022-12-13 deposited with the CCDC.	2023-01-10 downloaded from the CCDC.
;
_cell_angle_alpha                99.693(3)
_cell_angle_beta                 113.801(3)
_cell_angle_gamma                96.897(3)
_cell_formula_units_Z            1
_cell_length_a                   10.193(2)
_cell_length_b                   10.823(2)
_cell_length_c                   11.118(2)
_cell_measurement_reflns_used    7673
_cell_measurement_temperature    193(2)
_cell_measurement_theta_max      30.02
_cell_measurement_theta_min      2.23
_cell_volume                     1081.9(4)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018)'
_computing_structure_solution    'SHELXT-2014/5 (Sheldrick, 2015)'
_diffrn_ambient_temperature      193(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.986
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0478
_diffrn_reflns_av_unetI/netI     0.0538
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.986
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_number            19027
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.986
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         30.579
_diffrn_reflns_theta_min         1.952
_diffrn_source                   'Short anode X-ray tube fine focus 2kW'
_exptl_absorpt_coefficient_mu    1.386
_exptl_absorpt_correction_T_max  0.9566
_exptl_absorpt_correction_T_min  0.6724
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details
; 
 SADABS 2016/2: Krause, L., Herbst-Irmer, R., Sheldrick G.M. & Stalke D., 
 J. Appl. Cryst. 48 (2015) 3-10 
;
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.379
_exptl_crystal_description       block
_exptl_crystal_F_000             464
_exptl_crystal_recrystallization_method
'Re-crystallisation from solvent: Tetrahydrofuran'
_exptl_crystal_size_max          0.282
_exptl_crystal_size_mid          0.273
_exptl_crystal_size_min          0.209
_refine_diff_density_max         1.247
_refine_diff_density_min         -0.953
_refine_diff_density_rms         0.097
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.032
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     208
_refine_ls_number_reflns         6558
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.032
_refine_ls_R_factor_all          0.0458
_refine_ls_R_factor_gt           0.0371
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0460P)²+0.2119P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0929
_refine_ls_wR_factor_ref         0.0990
_reflns_Friedel_coverage         0.000
_reflns_number_gt                5550
_reflns_number_total             6558
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d2dt04028j2.cif
_cod_data_source_block           riv2274
_cod_depositor_comments
'Adding full bibliography for 7712080--7712083.cif.'
_cod_database_code               7712081
_shelx_shelxl_version_number     2018/3
_shelx_space_group_comment
; 
The symmetry employed for this shelxl refinement is uniquely defined 
by the following loop, which should always be used as a source of 
symmetry information in preference to the above space-group names. 
They are only intended as comments. 
;
_shelx_estimated_absorpt_t_min   0.696
_shelx_estimated_absorpt_t_max   0.761
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Sn1 Sn 0.30925(2) 0.37915(2) 0.16024(2) 0.03385(7) Uani 1 1 d . . . . .
K1 K 0.36659(6) 0.59659(5) 0.49702(5) 0.03453(12) Uani 1 1 d . . . . .
O1 O 0.46626(19) 0.53390(16) 0.30754(16) 0.0321(3) Uani 1 1 d . . . . .
O2 O 0.19732(19) 0.40957(17) 0.27774(17) 0.0351(4) Uani 1 1 d . . . . .
O3 O 0.4221(2) 0.25748(17) 0.26877(19) 0.0433(4) Uani 1 1 d . . . . .
O4 O 0.1674(3) 0.7526(2) 0.4131(2) 0.0620(6) Uani 1 1 d . . . . .
C1 C 0.5568(3) 0.6222(2) 0.2772(2) 0.0327(5) Uani 1 1 d . . . . .
C2 C 0.6698(4) 0.5575(3) 0.2466(3) 0.0507(7) Uani 1 1 d . . . . .
H2A H 0.732577 0.529989 0.326307 0.076 Uiso 1 1 calc R U . . .
H2B H 0.730280 0.618529 0.224089 0.076 Uiso 1 1 calc R U . . .
H2C H 0.618736 0.482816 0.169909 0.076 Uiso 1 1 calc R U . . .
C3 C 0.4661(4) 0.6731(3) 0.1561(3) 0.0498(7) Uani 1 1 d . . . . .
H3A H 0.419665 0.602674 0.074684 0.075 Uiso 1 1 calc R U . . .
H3B H 0.530183 0.739209 0.142943 0.075 Uiso 1 1 calc R U . . .
H3C H 0.390285 0.710097 0.173217 0.075 Uiso 1 1 calc R U . . .
C4 C 0.6351(3) 0.7336(3) 0.4019(3) 0.0433(6) Uani 1 1 d . . . . .
H4A H 0.563284 0.779780 0.415378 0.065 Uiso 1 1 calc R U . . .
H4B H 0.706941 0.791963 0.388982 0.065 Uiso 1 1 calc R U . . .
H4C H 0.685547 0.700465 0.481590 0.065 Uiso 1 1 calc R U . . .
C5 C 0.0479(3) 0.3511(2) 0.2366(3) 0.0354(5) Uani 1 1 d . . . . .
C6 C -0.0542(4) 0.3874(4) 0.1089(3) 0.0607(9) Uani 1 1 d . . . . .
H6A H -0.047003 0.480377 0.127704 0.091 Uiso 1 1 calc R U . . .
H6B H -0.155466 0.343906 0.081374 0.091 Uiso 1 1 calc R U . . .
H6C H -0.025493 0.361192 0.035796 0.091 Uiso 1 1 calc R U . . .
C7 C 0.0100(3) 0.4018(3) 0.3524(3) 0.0489(7) Uani 1 1 d . . . . .
H7A H 0.074381 0.378389 0.434382 0.073 Uiso 1 1 calc R U . . .
H7B H -0.092333 0.364273 0.328323 0.073 Uiso 1 1 calc R U . . .
H7C H 0.023539 0.495305 0.369015 0.073 Uiso 1 1 calc R U . . .
C8 C 0.0291(4) 0.2060(3) 0.2119(4) 0.0570(8) Uani 1 1 d . . . . .
H8A H 0.054482 0.173681 0.138070 0.086 Uiso 1 1 calc R U . . .
H8B H -0.072990 0.167354 0.187441 0.086 Uiso 1 1 calc R U . . .
H8C H 0.093754 0.183597 0.294483 0.086 Uiso 1 1 calc R U . . .
C9 C 0.4426(3) 0.1372(2) 0.2152(3) 0.0443(6) Uani 1 1 d . . . . .
C10 C 0.5740(4) 0.1566(4) 0.1835(4) 0.0632(9) Uani 1 1 d . . . . .
H10A H 0.551818 0.198864 0.108359 0.095 Uiso 1 1 calc R U . . .
H10B H 0.596290 0.073187 0.158148 0.095 Uiso 1 1 calc R U . . .
H10C H 0.658841 0.210094 0.263576 0.095 Uiso 1 1 calc R U . . .
C11 C 0.3090(4) 0.0619(4) 0.0882(4) 0.0754(12) Uani 1 1 d . . . . .
H11A H 0.223263 0.051520 0.107724 0.113 Uiso 1 1 calc R U . . .
H11B H 0.326193 -0.022584 0.058504 0.113 Uiso 1 1 calc R U . . .
H11C H 0.291251 0.108302 0.016514 0.113 Uiso 1 1 calc R U . . .
C12 C 0.4725(5) 0.0624(3) 0.3242(4) 0.0693(11) Uani 1 1 d . . . . .
H12A H 0.560500 0.109237 0.405517 0.104 Uiso 1 1 calc R U . . .
H12B H 0.487708 -0.022017 0.291236 0.104 Uiso 1 1 calc R U . . .
H12C H 0.388559 0.051710 0.346285 0.104 Uiso 1 1 calc R U . . .
C13 C 0.0849(6) 0.8332(5) 0.4527(5) 0.0866(15) Uani 1 1 d . . . . .
H13A H 0.149088 0.894951 0.539922 0.104 Uiso 1 1 calc R U . . .
H13B H 0.006064 0.781279 0.464429 0.104 Uiso 1 1 calc R U . . .
C14 C 0.0222(6) 0.9011(5) 0.3492(5) 0.0876(14) Uani 1 1 d . . . . .
H14A H 0.075809 0.991416 0.379123 0.105 Uiso 1 1 calc R U . . .
H14B H -0.082111 0.899714 0.328318 0.105 Uiso 1 1 calc R U . . .
C15 C 0.0361(5) 0.8332(4) 0.2283(4) 0.0741(11) Uani 1 1 d . . . . .
H15A H -0.055479 0.770657 0.165529 0.089 Uiso 1 1 calc R U . . .
H15B H 0.059164 0.894619 0.179419 0.089 Uiso 1 1 calc R U . . .
C16 C 0.1590(5) 0.7672(4) 0.2852(4) 0.0656(9) Uani 1 1 d . . . . .
H16A H 0.139974 0.682410 0.224292 0.079 Uiso 1 1 calc R U . . .
H16B H 0.251985 0.818919 0.296649 0.079 Uiso 1 1 calc R U . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
K K 0.2009 0.2494 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sn Sn -0.6537 1.4246 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O2 Sn1 O3 92.98(8) . . ?
O2 Sn1 O1 83.58(7) . . ?
O3 Sn1 O1 88.46(7) . . ?
O2 Sn1 K1 83.17(5) . 2_666 ?
O3 Sn1 K1 41.68(5) . 2_666 ?
O1 Sn1 K1 47.20(5) . 2_666 ?
O2 Sn1 K1 41.15(5) . . ?
O3 Sn1 K1 88.64(5) . . ?
O1 Sn1 K1 42.54(5) . . ?
K1 Sn1 K1 55.940(17) 2_666 . ?
O2 K1 O3 166.05(6) . 2_666 ?
O2 K1 O1 61.96(5) . . ?
O3 K1 O1 112.37(6) 2_666 . ?
O2 K1 O4 90.43(7) . . ?
O3 K1 O4 103.52(7) 2_666 . ?
O1 K1 O4 109.19(7) . . ?
O2 K1 O1 104.41(6) . 2_666 ?
O3 K1 O1 62.93(6) 2_666 2_666 ?
O1 K1 O1 99.42(5) . 2_666 ?
O4 K1 O1 151.37(6) . 2_666 ?
O2 K1 K1 81.09(4) . 2_666 ?
O3 K1 K1 85.63(4) 2_666 2_666 ?
O1 K1 K1 51.66(4) . 2_666 ?
O4 K1 K1 160.82(6) . 2_666 ?
O1 K1 K1 47.76(4) 2_666 2_666 ?
O2 K1 Sn1 135.75(4) . 2_666 ?
O3 K1 Sn1 30.92(4) 2_666 2_666 ?
O1 K1 Sn1 105.79(4) . 2_666 ?
O4 K1 Sn1 131.80(5) . 2_666 ?
O1 K1 Sn1 32.27(3) 2_666 2_666 ?
K1 K1 Sn1 62.096(18) 2_666 2_666 ?
O2 K1 Sn1 30.61(4) . . ?
O3 K1 Sn1 141.76(5) 2_666 . ?
O1 K1 Sn1 31.42(4) . . ?
O4 K1 Sn1 102.69(5) . . ?
O1 K1 Sn1 102.37(4) 2_666 . ?
K1 K1 Sn1 61.964(15) 2_666 . ?
Sn1 K1 Sn1 124.059(18) 2_666 . ?
C1 O1 Sn1 122.42(14) . . ?
C1 O1 K1 124.45(13) . . ?
Sn1 O1 K1 106.04(7) . . ?
C1 O1 K1 112.39(13) . 2_666 ?
Sn1 O1 K1 100.53(6) . 2_666 ?
K1 O1 K1 80.58(5) . 2_666 ?
C5 O2 Sn1 124.30(14) . . ?
C5 O2 K1 126.95(14) . . ?
Sn1 O2 K1 108.24(7) . . ?
C9 O3 Sn1 126.85(18) . . ?
C9 O3 K1 118.91(16) . 2_666 ?
Sn1 O3 K1 107.40(7) . 2_666 ?
C13 O4 C16 109.0(3) . . ?
C13 O4 K1 144.9(2) . . ?
C16 O4 K1 105.49(19) . . ?
O1 C1 C4 106.94(19) . . ?
O1 C1 C3 111.4(2) . . ?
C4 C1 C3 109.1(2) . . ?
O1 C1 C2 110.1(2) . . ?
C4 C1 C2 109.9(2) . . ?
C3 C1 C2 109.3(2) . . ?
O2 C5 C8 110.3(2) . . ?
O2 C5 C7 106.6(2) . . ?
C8 C5 C7 109.6(3) . . ?
O2 C5 C6 111.3(2) . . ?
C8 C5 C6 110.0(3) . . ?
C7 C5 C6 109.0(2) . . ?
O3 C9 C10 109.6(3) . . ?
O3 C9 C11 112.6(2) . . ?
C10 C9 C11 109.3(3) . . ?
O3 C9 C12 106.8(2) . . ?
C10 C9 C12 109.5(3) . . ?
C11 C9 C12 109.1(3) . . ?
O4 C13 C14 108.6(3) . . ?
C13 C14 C15 106.0(3) . . ?
C16 C15 C14 104.0(3) . . ?
O4 C16 C15 106.4(3) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Sn1 O2 2.0652(17) . ?
Sn1 O3 2.0715(19) . ?
Sn1 O1 2.0894(17) . ?
Sn1 K1 3.8471(8) 2_666 ?
Sn1 K1 3.8518(8) . ?
K1 O2 2.6687(18) . ?
K1 O3 2.681(2) 2_666 ?
K1 O1 2.7096(17) . ?
K1 O4 2.769(2) . ?
K1 O1 2.8708(18) 2_666 ?
K1 K1 3.6108(11) 2_666 ?
O1 C1 1.424(3) . ?
O2 C5 1.428(3) . ?
O3 C9 1.413(3) . ?
O4 C13 1.417(4) . ?
O4 C16 1.426(4) . ?
C1 C4 1.525(4) . ?
C1 C3 1.529(4) . ?
C1 C2 1.537(4) . ?
C5 C8 1.522(4) . ?
C5 C7 1.524(4) . ?
C5 C6 1.532(4) . ?
C9 C10 1.517(5) . ?
C9 C11 1.519(4) . ?
C9 C12 1.520(5) . ?
C13 C14 1.440(6) . ?
C14 C15 1.488(6) . ?
C15 C16 1.486(6) . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O2 Sn1 O1 C1 -148.13(17) . . . . ?
O3 Sn1 O1 C1 118.70(17) . . . . ?
K1 Sn1 O1 C1 125.25(18) 2_666 . . . ?
K1 Sn1 O1 C1 -151.6(2) . . . . ?
O2 Sn1 O1 K1 3.50(7) . . . . ?
O3 Sn1 O1 K1 -89.67(8) . . . . ?
K1 Sn1 O1 K1 -83.12(6) 2_666 . . . ?
O2 Sn1 O1 K1 86.63(7) . . . 2_666 ?
O3 Sn1 O1 K1 -6.55(7) . . . 2_666 ?
K1 Sn1 O1 K1 83.12(6) . . . 2_666 ?
O2 K1 O1 C1 147.85(18) . . . . ?
O3 K1 O1 C1 -46.26(18) 2_666 . . . ?
O4 K1 O1 C1 68.00(18) . . . . ?
O1 K1 O1 C1 -110.76(17) 2_666 . . . ?
K1 K1 O1 C1 -110.76(17) 2_666 . . . ?
Sn1 K1 O1 C1 -78.30(17) 2_666 . . . ?
Sn1 K1 O1 C1 150.9(2) . . . . ?
O2 K1 O1 Sn1 -3.05(6) . . . . ?
O3 K1 O1 Sn1 162.84(7) 2_666 . . . ?
O4 K1 O1 Sn1 -82.90(9) . . . . ?
O1 K1 O1 Sn1 98.34(7) 2_666 . . . ?
K1 K1 O1 Sn1 98.34(7) 2_666 . . . ?
Sn1 K1 O1 Sn1 130.80(6) 2_666 . . . ?
O2 K1 O1 K1 -101.39(6) . . . 2_666 ?
O3 K1 O1 K1 64.50(6) 2_666 . . 2_666 ?
O4 K1 O1 K1 178.76(7) . . . 2_666 ?
O1 K1 O1 K1 0.0 2_666 . . 2_666 ?
Sn1 K1 O1 K1 32.46(4) 2_666 . . 2_666 ?
Sn1 K1 O1 K1 -98.34(7) . . . 2_666 ?
O3 Sn1 O2 C5 -103.17(19) . . . . ?
O1 Sn1 O2 C5 168.72(19) . . . . ?
K1 Sn1 O2 C5 -143.75(18) 2_666 . . . ?
K1 Sn1 O2 C5 172.3(2) . . . . ?
O3 Sn1 O2 K1 84.51(8) . . . . ?
O1 Sn1 O2 K1 -3.60(7) . . . . ?
K1 Sn1 O2 K1 43.93(6) 2_666 . . . ?
O3 K1 O2 C5 121.9(3) 2_666 . . . ?
O1 K1 O2 C5 -168.9(2) . . . . ?
O4 K1 O2 C5 -57.32(19) . . . . ?
O1 K1 O2 C5 97.94(18) 2_666 . . . ?
K1 K1 O2 C5 139.96(19) 2_666 . . . ?
Sn1 K1 O2 C5 107.09(18) 2_666 . . . ?
Sn1 K1 O2 C5 -172.1(2) . . . . ?
O3 K1 O2 Sn1 -66.1(3) 2_666 . . . ?
O1 K1 O2 Sn1 3.12(6) . . . . ?
O4 K1 O2 Sn1 114.74(9) . . . . ?
O1 K1 O2 Sn1 -90.00(8) 2_666 . . . ?
K1 K1 O2 Sn1 -47.98(7) 2_666 . . . ?
Sn1 K1 O2 Sn1 -80.86(9) 2_666 . . . ?
O2 Sn1 O3 C9 133.5(2) . . . . ?
O1 Sn1 O3 C9 -143.0(2) . . . . ?
K1 Sn1 O3 C9 -150.2(3) 2_666 . . . ?
K1 Sn1 O3 C9 174.4(2) . . . . ?
O2 Sn1 O3 K1 -76.26(8) . . . 2_666 ?
O1 Sn1 O3 K1 7.23(8) . . . 2_666 ?
K1 Sn1 O3 K1 -35.32(7) . . . 2_666 ?
O2 K1 O4 C13 130.1(5) . . . . ?
O3 K1 O4 C13 -49.7(5) 2_666 . . . ?
O1 K1 O4 C13 -169.6(5) . . . . ?
O1 K1 O4 C13 7.9(6) 2_666 . . . ?
K1 K1 O4 C13 -166.6(5) 2_666 . . . ?
Sn1 K1 O4 C13 -35.3(6) 2_666 . . . ?
Sn1 K1 O4 C13 158.4(5) . . . . ?
O2 K1 O4 C16 -60.2(2) . . . . ?
O3 K1 O4 C16 120.0(2) 2_666 . . . ?
O1 K1 O4 C16 0.1(2) . . . . ?
O1 K1 O4 C16 177.5(2) 2_666 . . . ?
K1 K1 O4 C16 3.1(4) 2_666 . . . ?
Sn1 K1 O4 C16 134.3(2) 2_666 . . . ?
Sn1 K1 O4 C16 -31.9(2) . . . . ?
Sn1 O1 C1 C4 169.61(16) . . . . ?
K1 O1 C1 C4 23.2(3) . . . . ?
K1 O1 C1 C4 -70.7(2) 2_666 . . . ?
Sn1 O1 C1 C3 50.4(2) . . . . ?
K1 O1 C1 C3 -96.0(2) . . . . ?
K1 O1 C1 C3 170.14(16) 2_666 . . . ?
Sn1 O1 C1 C2 -71.0(2) . . . . ?
K1 O1 C1 C2 142.61(18) . . . . ?
K1 O1 C1 C2 48.7(2) 2_666 . . . ?
Sn1 O2 C5 C8 62.0(3) . . . . ?
K1 O2 C5 C8 -127.2(2) . . . . ?
Sn1 O2 C5 C7 -179.09(17) . . . . ?
K1 O2 C5 C7 -8.2(3) . . . . ?
Sn1 O2 C5 C6 -60.4(3) . . . . ?
K1 O2 C5 C6 110.5(2) . . . . ?
Sn1 O3 C9 C10 84.7(3) . . . . ?
K1 O3 C9 C10 -62.5(3) 2_666 . . . ?
Sn1 O3 C9 C11 -37.1(4) . . . . ?
K1 O3 C9 C11 175.7(3) 2_666 . . . ?
Sn1 O3 C9 C12 -156.8(2) . . . . ?
K1 O3 C9 C12 56.0(3) 2_666 . . . ?
C16 O4 C13 C14 0.0(6) . . . . ?
K1 O4 C13 C14 169.4(4) . . . . ?
O4 C13 C14 C15 15.0(6) . . . . ?
C13 C14 C15 C16 -23.3(6) . . . . ?
C13 O4 C16 C15 -14.9(5) . . . . ?
K1 O4 C16 C15 171.3(3) . . . . ?
C14 C15 C16 O4 23.4(5) . . . . ?
