#------------------------------------------------------------------------------
#$Date: 2023-05-05 05:28:06 +0300 (Fri, 05 May 2023) $
#$Revision: 283325 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/71/21/7712103.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7712103
loop_
_publ_author_name
'Hruzd, Mariia'
'Kahlal, Samia'
'le Poul, Nicolas'
'Wojcik, Laurianne'
'Cordier, Marie'
'Saillard, Jean-Yves'
'Rodríguez-López, Julián'
'Robin-le Guen, Françoise'
'Gauthier, Sébastien'
'Achelle, Sylvain'
_publ_section_title
;
 Phosphorescent cyclometalated platinum(II) complexes with phenyldiazine
 N^C ligands.
;
_journal_issue                   7
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              1927
_journal_page_last               1938
_journal_paper_doi               10.1039/d2dt03690h
_journal_volume                  52
_journal_year                    2023
_chemical_compound_source        'synthesis as described'
_chemical_formula_moiety         'C29 H23 Cl N4 O Pt'
_chemical_formula_sum            'C29 H23 Cl N4 O Pt'
_chemical_formula_weight         674.05
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2yn'
_space_group_name_H-M_alt        'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_audit_update_record
;
2022-10-06 deposited with the CCDC.	2023-01-12 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 94.2180(10)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   12.4061(3)
_cell_length_b                   7.9544(2)
_cell_length_c                   25.2752(5)
_cell_measurement_reflns_used    9909
_cell_measurement_temperature    150
_cell_measurement_theta_max      27.4767
_cell_measurement_theta_min      3.0283
_cell_measurement_wavelength     0.710730
_cell_volume                     2487.48(10)
_computing_cell_refinement       'APEX3 (Bruker, 2015)'
_computing_data_collection       'SAINT (Bruker, 2014)'
_computing_data_reduction        'SAINT (Bruker, 2014)'
_computing_molecular_graphics    'SXGRAPH (Farrugia, 1999), Mercury (CSD, 2016)'
_computing_publication_material  'CRYSCALC (T. Roisnel, local program, 2018)'
_computing_structure_refinement  'SHELXL-2018_3 (Sheldrick, 2018)'
_computing_structure_solution    'SHELXT (G. Sheldrick, 2015)'
_diffrn_ambient_temperature      150
_diffrn_detector                 CMOS-PHOTON70
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'D8 VENTURE Bruker AXS'
_diffrn_measurement_method       'rotation images'
_diffrn_radiation_monochromator  'multilayer monochromator'
_diffrn_radiation_probe          x-ray
_diffrn_radiation_source         'Incoatec microfocus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0421
_diffrn_reflns_av_unetI/netI     0.0413
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       10
_diffrn_reflns_limit_k_min       -9
_diffrn_reflns_limit_l_max       32
_diffrn_reflns_limit_l_min       -32
_diffrn_reflns_number            19769
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.477
_diffrn_reflns_theta_min         2.685
_exptl_absorpt_coefficient_mu    5.779
_exptl_absorpt_correction_T_max  0.315
_exptl_absorpt_correction_T_min  0.191
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
  [Sheldrick, G.M. (2014). SADABS Bruker AXS Inc., Madison, Wisconsin, USA]
;
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.800
_exptl_crystal_description       stick
_exptl_crystal_F_000             1312
_exptl_crystal_size_max          0.340
_exptl_crystal_size_mid          0.220
_exptl_crystal_size_min          0.200
_refine_diff_density_max         1.808
_refine_diff_density_min         -1.323
_refine_diff_density_rms         0.209
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.061
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     322
_refine_ls_number_reflns         5683
_refine_ls_number_restraints     15
_refine_ls_restrained_S_all      1.127
_refine_ls_R_factor_all          0.0344
_refine_ls_R_factor_gt           0.0281
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0267P)²+3.4663P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0644
_refine_ls_wR_factor_ref         0.0660
_reflns_Friedel_coverage         0.000
_reflns_number_gt                4968
_reflns_number_total             5683
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            d2dt03690h2.cif
_cod_data_source_block           HM269D8
_cod_depositor_comments
'Adding full bibliography for 7712102--7712104.cif.'
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               7712103
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.17547(2) 0.64759(2) 0.14724(2) 0.01596(5) Uani 1 1 d . . . . .
Cl1 Cl 0.12875(8) 0.53468(12) 0.23003(3) 0.0246(2) Uani 1 1 d . . . . .
N1 N 0.2697(2) 0.4538(4) 0.12778(11) 0.0183(6) Uani 1 1 d . . . . .
N2 N 0.3699(3) 0.3454(4) 0.05875(13) 0.0278(8) Uani 1 1 d . . . . .
N3 N 0.3178(3) 0.8415(4) -0.07535(12) 0.0225(7) Uani 1 1 d . . . . .
N4 N 0.0802(2) 0.8442(4) 0.16160(12) 0.0186(6) Uani 1 1 d . . . . .
C1 C 0.2914(3) 0.3141(5) 0.15649(16) 0.0246(8) Uani 1 1 d . . . . .
H1 H 0.264470 0.303584 0.190572 0.030 Uiso 1 1 calc R U . . .
C2 C 0.3515(3) 0.1872(6) 0.13741(17) 0.0309(10) Uani 1 1 d . . . . .
H2 H 0.366920 0.088157 0.157571 0.037 Uiso 1 1 calc R U . . .
C3 C 0.3887(3) 0.2076(6) 0.08816(16) 0.0304(10) Uani 1 1 d . . . . .
H3 H 0.429803 0.119489 0.074233 0.036 Uiso 1 1 calc R U . . .
C4 C 0.3104(3) 0.4659(5) 0.07916(14) 0.0208(8) Uani 1 1 d . . . . .
C5 C 0.2821(3) 0.6200(5) 0.05077(14) 0.0194(8) Uani 1 1 d . . . . .
C6 C 0.3183(3) 0.6561(5) 0.00114(15) 0.0223(8) Uani 1 1 d . . . . .
H6 H 0.364071 0.579964 -0.015533 0.027 Uiso 1 1 calc R U . . .
C7 C 0.2860(3) 0.8056(5) -0.02340(14) 0.0220(8) Uani 1 1 d . . . . .
C8 C 0.2214(3) 0.9190(5) 0.00180(15) 0.0254(8) Uani 1 1 d . . . . .
H8 H 0.200056 1.021548 -0.015186 0.031 Uiso 1 1 calc R U . . .
C9 C 0.1880(3) 0.8822(5) 0.05188(15) 0.0237(8) Uani 1 1 d . . . . .
H9 H 0.145298 0.961486 0.069133 0.028 Uiso 1 1 calc R U . . .
C10 C 0.2162(3) 0.7305(5) 0.07725(14) 0.0181(7) Uani 1 1 d . . . . .
C11 C 0.3048(3) 0.7321(5) -0.11869(14) 0.0221(8) Uani 1 1 d . . . . .
C12 C 0.2545(3) 0.5762(5) -0.12263(15) 0.0267(8) Uani 1 1 d . . . . .
H12 H 0.224970 0.525712 -0.092860 0.032 Uiso 1 1 calc R U . . .
C13 C 0.2490(4) 0.4973(5) -0.17141(16) 0.0316(9) Uani 1 1 d . . . . .
H13 H 0.214452 0.390978 -0.175271 0.038 Uiso 1 1 calc R U . . .
C14 C 0.2931(4) 0.5706(6) -0.21531(16) 0.0327(10) Uani 1 1 d . . . . .
H14 H 0.288224 0.513412 -0.248401 0.039 Uiso 1 1 calc R U . . .
C15 C 0.3435(3) 0.7247(6) -0.21103(15) 0.0281(9) Uani 1 1 d . . . . .
H15 H 0.375275 0.772189 -0.240666 0.034 Uiso 1 1 calc R U . . .
C16 C 0.3476(3) 0.8104(5) -0.16278(14) 0.0207(8) Uani 1 1 d . . . . .
C17 C 0.3874(3) 0.9735(5) -0.14564(14) 0.0214(8) Uani 1 1 d . . . . .
C18 C 0.4391(3) 1.1037(5) -0.17064(16) 0.0269(9) Uani 1 1 d . . . . .
H18 H 0.452916 1.095578 -0.207020 0.032 Uiso 1 1 calc R U . . .
C19 C 0.4698(3) 1.2450(6) -0.14147(17) 0.0315(9) Uani 1 1 d . . . . .
H19 H 0.505521 1.334254 -0.158018 0.038 Uiso 1 1 calc R U . . .
C20 C 0.4493(3) 1.2584(6) -0.08822(17) 0.0300(9) Uani 1 1 d . . . . .
H20 H 0.471300 1.357173 -0.069214 0.036 Uiso 1 1 calc R U . . .
C21 C 0.3980(3) 1.1325(5) -0.06233(16) 0.0260(9) Uani 1 1 d . . . . .
H21 H 0.384211 1.142782 -0.025997 0.031 Uiso 1 1 calc R U . . .
C22 C 0.3671(3) 0.9892(5) -0.09146(14) 0.0207(8) Uani 1 1 d . . . . .
C23 C 0.1144(3) 0.9637(5) 0.19653(15) 0.0246(8) Uani 1 1 d . . . . .
H23 H 0.185435 0.956061 0.213132 0.029 Uiso 1 1 calc R U . . .
C24 C 0.0496(4) 1.0977(5) 0.20918(18) 0.0331(10) Uani 1 1 d . . . . .
H24 H 0.075564 1.179789 0.234285 0.040 Uiso 1 1 calc R U . . .
C25 C -0.0530(4) 1.1097(6) 0.1847(2) 0.0371(11) Uani 1 1 d . . . . .
H25 H -0.098798 1.201288 0.192040 0.045 Uiso 1 1 calc R U . . .
C26 C -0.0879(4) 0.9852(6) 0.1492(2) 0.0388(11) Uani 1 1 d . . . . .
H26 H -0.158879 0.989309 0.132299 0.047 Uiso 1 1 calc R U . . .
C27 C -0.0203(3) 0.8571(5) 0.13847(17) 0.0285(9) Uani 1 1 d . . . . .
H27 H -0.045194 0.773449 0.113670 0.034 Uiso 1 1 calc R U . . .
O1 O -0.0122(4) 1.5090(5) 0.01333(18) 0.0489(10) Uani 0.5 1 d D . P A -1
O2 O 0.0977(5) 1.3119(6) -0.0102(2) 0.0489(10) Uani 0.5 1 d D . P A -1
C28 C 0.0415(4) 1.3591(5) 0.02329(18) 0.0489(10) Uani 0.5 1 d D . P A -1
C29 C 0.0127(7) 1.2942(9) 0.0762(2) 0.0489(10) Uani 0.5 1 d D . P A -1
H29A H 0.013156 1.170990 0.075777 0.073 Uiso 0.5 1 calc R U P A -1
H29B H -0.059502 1.334269 0.083324 0.073 Uiso 0.5 1 calc R U P A -1
H29C H 0.065599 1.334887 0.103927 0.073 Uiso 0.5 1 calc R U P A -1
C30 C 0.0108(5) 1.5858(6) -0.03885(19) 0.0489(10) Uani 0.5 1 d D . P A -1
H30A H -0.012338 1.510637 -0.068784 0.059 Uiso 0.5 1 calc R U P A -1
H30B H 0.088666 1.611522 -0.040164 0.059 Uiso 0.5 1 calc R U P A -1
C31 C -0.0557(6) 1.7434(6) -0.0399(3) 0.0489(10) Uani 0.5 1 d D . P A -1
H31A H -0.114799 1.729955 -0.016586 0.073 Uiso 0.5 1 calc R U P A -1
H31B H -0.085590 1.765064 -0.076214 0.073 Uiso 0.5 1 calc R U P A -1
H31C H -0.010003 1.838179 -0.027546 0.073 Uiso 0.5 1 calc R U P A -1
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C10 Pt1 N4 95.38(13) . . ?
C10 Pt1 N1 81.19(13) . . ?
N4 Pt1 N1 176.29(12) . . ?
C10 Pt1 Cl1 177.26(11) . . ?
N4 Pt1 Cl1 87.17(9) . . ?
N1 Pt1 Cl1 96.24(9) . . ?
C1 N1 C4 118.1(3) . . ?
C1 N1 Pt1 126.6(2) . . ?
C4 N1 Pt1 115.2(2) . . ?
C3 N2 C4 116.9(3) . . ?
C22 N3 C11 108.8(3) . . ?
C22 N3 C7 126.3(3) . . ?
C11 N3 C7 124.9(3) . . ?
C27 N4 C23 118.1(3) . . ?
C27 N4 Pt1 121.4(3) . . ?
C23 N4 Pt1 120.5(3) . . ?
N1 C1 C2 120.9(4) . . ?
N1 C1 H1 119.5 . . ?
C2 C1 H1 119.5 . . ?
C1 C2 C3 117.6(4) . . ?
C1 C2 H2 121.2 . . ?
C3 C2 H2 121.2 . . ?
N2 C3 C2 123.2(4) . . ?
N2 C3 H3 118.4 . . ?
C2 C3 H3 118.4 . . ?
N2 C4 N1 123.3(3) . . ?
N2 C4 C5 122.4(3) . . ?
N1 C4 C5 114.3(3) . . ?
C6 C5 C10 122.5(3) . . ?
C6 C5 C4 122.5(3) . . ?
C10 C5 C4 114.9(3) . . ?
C7 C6 C5 118.6(3) . . ?
C7 C6 H6 120.7 . . ?
C5 C6 H6 120.7 . . ?
C6 C7 C8 120.5(3) . . ?
C6 C7 N3 119.6(3) . . ?
C8 C7 N3 119.9(3) . . ?
C9 C8 C7 120.0(4) . . ?
C9 C8 H8 120.0 . . ?
C7 C8 H8 120.0 . . ?
C8 C9 C10 121.2(3) . . ?
C8 C9 H9 119.4 . . ?
C10 C9 H9 119.4 . . ?
C9 C10 C5 117.2(3) . . ?
C9 C10 Pt1 128.5(3) . . ?
C5 C10 Pt1 114.3(3) . . ?
C12 C11 N3 129.6(3) . . ?
C12 C11 C16 122.0(3) . . ?
N3 C11 C16 108.4(4) . . ?
C13 C12 C11 117.5(4) . . ?
C13 C12 H12 121.2 . . ?
C11 C12 H12 121.2 . . ?
C12 C13 C14 121.5(4) . . ?
C12 C13 H13 119.3 . . ?
C14 C13 H13 119.3 . . ?
C15 C14 C13 120.7(4) . . ?
C15 C14 H14 119.7 . . ?
C13 C14 H14 119.7 . . ?
C14 C15 C16 119.4(4) . . ?
C14 C15 H15 120.3 . . ?
C16 C15 H15 120.3 . . ?
C15 C16 C11 118.9(4) . . ?
C15 C16 C17 133.7(4) . . ?
C11 C16 C17 107.4(3) . . ?
C18 C17 C22 119.6(4) . . ?
C18 C17 C16 133.7(3) . . ?
C22 C17 C16 106.7(3) . . ?
C19 C18 C17 118.7(4) . . ?
C19 C18 H18 120.6 . . ?
C17 C18 H18 120.6 . . ?
C18 C19 C20 121.0(4) . . ?
C18 C19 H19 119.5 . . ?
C20 C19 H19 119.5 . . ?
C21 C20 C19 121.8(4) . . ?
C21 C20 H20 119.1 . . ?
C19 C20 H20 119.1 . . ?
C20 C21 C22 117.5(4) . . ?
C20 C21 H21 121.2 . . ?
C22 C21 H21 121.2 . . ?
C21 C22 N3 129.9(3) . . ?
C21 C22 C17 121.4(4) . . ?
N3 C22 C17 108.7(3) . . ?
N4 C23 C24 122.3(4) . . ?
N4 C23 H23 118.8 . . ?
C24 C23 H23 118.8 . . ?
C25 C24 C23 118.8(4) . . ?
C25 C24 H24 120.6 . . ?
C23 C24 H24 120.6 . . ?
C24 C25 C26 118.4(4) . . ?
C24 C25 H25 120.8 . . ?
C26 C25 H25 120.8 . . ?
C27 C26 C25 119.8(4) . . ?
C27 C26 H26 120.1 . . ?
C25 C26 H26 120.1 . . ?
N4 C27 C26 122.5(4) . . ?
N4 C27 H27 118.7 . . ?
C26 C27 H27 118.7 . . ?
C28 O1 C30 113.1(2) . . ?
O2 C28 O1 116.2(2) . . ?
O2 C28 C29 135.4(3) . . ?
O1 C28 C29 108.5(3) . . ?
C28 C29 H29A 109.5 . . ?
C28 C29 H29B 109.5 . . ?
H29A C29 H29B 109.5 . . ?
C28 C29 H29C 109.5 . . ?
H29A C29 H29C 109.5 . . ?
H29B C29 H29C 109.5 . . ?
O1 C30 C31 102.46(19) . . ?
O1 C30 H30A 111.3 . . ?
C31 C30 H30A 111.3 . . ?
O1 C30 H30B 111.3 . . ?
C31 C30 H30B 111.3 . . ?
H30A C30 H30B 109.2 . . ?
C30 C31 H31A 109.5 . . ?
C30 C31 H31B 109.5 . . ?
H31A C31 H31B 109.5 . . ?
C30 C31 H31C 109.5 . . ?
H31A C31 H31C 109.5 . . ?
H31B C31 H31C 109.5 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 C10 1.988(3) . ?
Pt1 N4 2.010(3) . ?
Pt1 N1 2.017(3) . ?
Pt1 Cl1 2.3874(9) . ?
N1 C1 1.343(5) . ?
N1 C4 1.366(4) . ?
N2 C3 1.335(5) . ?
N2 C4 1.336(5) . ?
N3 C22 1.398(5) . ?
N3 C11 1.399(5) . ?
N3 C7 1.427(4) . ?
N4 C27 1.341(5) . ?
N4 C23 1.345(5) . ?
C1 C2 1.364(5) . ?
C1 H1 0.9500 . ?
C2 C3 1.369(6) . ?
C2 H2 0.9500 . ?
C3 H3 0.9500 . ?
C4 C5 1.451(5) . ?
C5 C6 1.393(5) . ?
C5 C10 1.404(5) . ?
C6 C7 1.386(5) . ?
C6 H6 0.9500 . ?
C7 C8 1.393(5) . ?
C8 C9 1.391(5) . ?
C8 H8 0.9500 . ?
C9 C10 1.399(5) . ?
C9 H9 0.9500 . ?
C11 C12 1.389(6) . ?
C11 C16 1.413(5) . ?
C12 C13 1.381(6) . ?
C12 H12 0.9500 . ?
C13 C14 1.400(6) . ?
C13 H13 0.9500 . ?
C14 C15 1.377(6) . ?
C14 H14 0.9500 . ?
C15 C16 1.395(5) . ?
C15 H15 0.9500 . ?
C16 C17 1.443(6) . ?
C17 C18 1.394(6) . ?
C17 C22 1.416(5) . ?
C18 C19 1.382(6) . ?
C18 H18 0.9500 . ?
C19 C20 1.392(6) . ?
C19 H19 0.9500 . ?
C20 C21 1.378(6) . ?
C20 H20 0.9500 . ?
C21 C22 1.395(6) . ?
C21 H21 0.9500 . ?
C23 C24 1.386(6) . ?
C23 H23 0.9500 . ?
C24 C25 1.377(7) . ?
C24 H24 0.9500 . ?
C25 C26 1.385(7) . ?
C25 H25 0.9500 . ?
C26 C27 1.360(6) . ?
C26 H26 0.9500 . ?
C27 H27 0.9500 . ?
O1 C28 1.380(3) . ?
O1 C30 1.4999(4) . ?
O2 C28 1.196(3) . ?
C28 C29 1.5000(4) . ?
C29 H29A 0.9800 . ?
C29 H29B 0.9800 . ?
C29 H29C 0.9800 . ?
C30 C31 1.5000(4) . ?
C30 H30A 0.9900 . ?
C30 H30B 0.9900 . ?
C31 H31A 0.9800 . ?
C31 H31B 0.9800 . ?
C31 H31C 0.9800 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C4 N1 C1 C2 -0.7(6) . . . . ?
Pt1 N1 C1 C2 176.1(3) . . . . ?
N1 C1 C2 C3 0.1(7) . . . . ?
C4 N2 C3 C2 -1.0(7) . . . . ?
C1 C2 C3 N2 0.8(7) . . . . ?
C3 N2 C4 N1 0.3(6) . . . . ?
C3 N2 C4 C5 -178.5(4) . . . . ?
C1 N1 C4 N2 0.5(6) . . . . ?
Pt1 N1 C4 N2 -176.6(3) . . . . ?
C1 N1 C4 C5 179.4(3) . . . . ?
Pt1 N1 C4 C5 2.3(4) . . . . ?
N2 C4 C5 C6 -2.5(6) . . . . ?
N1 C4 C5 C6 178.6(4) . . . . ?
N2 C4 C5 C10 178.0(4) . . . . ?
N1 C4 C5 C10 -1.0(5) . . . . ?
C10 C5 C6 C7 -1.3(6) . . . . ?
C4 C5 C6 C7 179.2(4) . . . . ?
C5 C6 C7 C8 1.8(6) . . . . ?
C5 C6 C7 N3 -177.0(4) . . . . ?
C22 N3 C7 C6 -128.9(4) . . . . ?
C11 N3 C7 C6 50.7(5) . . . . ?
C22 N3 C7 C8 52.3(5) . . . . ?
C11 N3 C7 C8 -128.1(4) . . . . ?
C6 C7 C8 C9 -0.5(6) . . . . ?
N3 C7 C8 C9 178.3(4) . . . . ?
C7 C8 C9 C10 -1.5(6) . . . . ?
C8 C9 C10 C5 1.9(6) . . . . ?
C8 C9 C10 Pt1 -178.3(3) . . . . ?
C6 C5 C10 C9 -0.5(6) . . . . ?
C4 C5 C10 C9 179.0(3) . . . . ?
C6 C5 C10 Pt1 179.6(3) . . . . ?
C4 C5 C10 Pt1 -0.8(4) . . . . ?
C22 N3 C11 C12 -175.8(4) . . . . ?
C7 N3 C11 C12 4.6(6) . . . . ?
C22 N3 C11 C16 0.7(4) . . . . ?
C7 N3 C11 C16 -178.9(3) . . . . ?
N3 C11 C12 C13 177.1(4) . . . . ?
C16 C11 C12 C13 1.1(6) . . . . ?
C11 C12 C13 C14 0.5(6) . . . . ?
C12 C13 C14 C15 -0.1(7) . . . . ?
C13 C14 C15 C16 -1.9(6) . . . . ?
C14 C15 C16 C11 3.4(6) . . . . ?
C14 C15 C16 C17 -176.0(4) . . . . ?
C12 C11 C16 C15 -3.0(6) . . . . ?
N3 C11 C16 C15 -179.9(3) . . . . ?
C12 C11 C16 C17 176.5(3) . . . . ?
N3 C11 C16 C17 -0.3(4) . . . . ?
C15 C16 C17 C18 -2.0(8) . . . . ?
C11 C16 C17 C18 178.5(4) . . . . ?
C15 C16 C17 C22 179.2(4) . . . . ?
C11 C16 C17 C22 -0.2(4) . . . . ?
C22 C17 C18 C19 0.4(6) . . . . ?
C16 C17 C18 C19 -178.2(4) . . . . ?
C17 C18 C19 C20 -0.4(6) . . . . ?
C18 C19 C20 C21 0.1(6) . . . . ?
C19 C20 C21 C22 0.1(6) . . . . ?
C20 C21 C22 N3 177.6(4) . . . . ?
C20 C21 C22 C17 -0.1(6) . . . . ?
C11 N3 C22 C21 -178.7(4) . . . . ?
C7 N3 C22 C21 0.9(6) . . . . ?
C11 N3 C22 C17 -0.9(4) . . . . ?
C7 N3 C22 C17 178.8(3) . . . . ?
C18 C17 C22 C21 -0.2(6) . . . . ?
C16 C17 C22 C21 178.7(3) . . . . ?
C18 C17 C22 N3 -178.3(3) . . . . ?
C16 C17 C22 N3 0.6(4) . . . . ?
C27 N4 C23 C24 0.1(6) . . . . ?
Pt1 N4 C23 C24 -177.3(3) . . . . ?
N4 C23 C24 C25 -0.7(6) . . . . ?
C23 C24 C25 C26 1.2(7) . . . . ?
C24 C25 C26 C27 -1.3(7) . . . . ?
C23 N4 C27 C26 -0.1(6) . . . . ?
Pt1 N4 C27 C26 177.3(3) . . . . ?
C25 C26 C27 N4 0.8(7) . . . . ?
C30 O1 C28 O2 0.01(11) . . . . ?
C30 O1 C28 C29 179.99(16) . . . . ?
C28 O1 C30 C31 -179.98(14) . . . . ?
