#------------------------------------------------------------------------------
#$Date: 2023-05-05 05:18:10 +0300 (Fri, 05 May 2023) $
#$Revision: 283302 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/71/21/7712160.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7712160
loop_
_publ_author_name
'Sheokand, Sonu'
'Mondal, Dipanjan'
'Kote, Basvaraj S.'
'Radhakrishna, Latchupatula'
'Balakrishna, Maravanji S.'
_publ_section_title
;
 Novel 1,2,3-triazolyl phosphine with a pyridyl functionality: synthesis,
 coinage metal complexes, photophysical studies and Cu(I) catalyzed C-O
 coupling of phenols with aryl bromides.
;
_journal_issue                   6
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              1785
_journal_page_last               1796
_journal_paper_doi               10.1039/d2dt03791b
_journal_volume                  52
_journal_year                    2023
_chemical_formula_moiety         'C50 H38 Ag2 I2 N8 P2, 2(C2 H3 N)'
_chemical_formula_sum            'C54 H44 Ag2 I2 N10 P2'
_chemical_formula_weight         1364.47
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   geom
_audit_creation_date             2022-09-30
_audit_creation_method
;
Olex2 1.5
(compiled 2022.04.07 svn.rca3783a0 for OlexSys, GUI svn.r6498)
;
_audit_update_record
;
2022-11-24 deposited with the CCDC.	2022-12-30 downloaded from the CCDC.
;
_cell_angle_alpha                99.4390(10)
_cell_angle_beta                 112.0120(10)
_cell_angle_gamma                101.4420(10)
_cell_formula_units_Z            1
_cell_length_a                   10.22310(10)
_cell_length_b                   10.86800(10)
_cell_length_c                   13.3111(2)
_cell_measurement_reflns_used    26826
_cell_measurement_temperature    150.00(10)
_cell_measurement_theta_max      30.6250
_cell_measurement_theta_min      1.9830
_cell_volume                     1296.82(3)
_computing_cell_refinement       'CrysAlisPro 1.171.41.93a (Rigaku OD, 2020)'
_computing_data_collection       'CrysAlisPro 1.171.41.93a (Rigaku OD, 2020)'
_computing_data_reduction        'CrysAlisPro 1.171.41.93a (Rigaku OD, 2020)'
_computing_molecular_graphics    'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'ShelXT (Sheldrick, 2015)'
_diffrn_ambient_temperature      150.15
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.811
_diffrn_measurement_details
;
List of Runs (angles in degrees, time in seconds):

  # Type    Start    End  Width  tₑₓₚ   ω     θ     κ     φ   Frames
#--------------------------------------------------------------------------
  1  φ    154.25 334.25   1.00    1.00 -25.75   0.00  73.76    --   180
  2  φ    -10.27 348.73   0.50    2.00  81.02  -9.84  31.50    --   718
  3  ω    -65.46   0.04   0.50    2.00    --  -19.34  94.56 145.16  131
  4  ω    -60.89   0.11   0.50    2.00    --  -14.77  94.56 -34.84  122
  5  ω   -100.81  15.69   0.50    2.00    --   -9.84 -59.25 -51.92  233
  6  ω    -65.46   0.04   0.50    2.00    --  -19.34  94.56  73.16  131
  7  φ   -349.73   9.27   0.50    2.00   6.61  -9.84 -31.50    --   718
  8  ω    -65.46   0.04   0.50    2.00    --  -19.34  94.56   1.16  131
  9  ω   -100.81  15.69   0.50    2.00    --   -9.84 -59.25 164.08  233
 10  ω   -100.81  15.69   0.50    2.00    --   -9.84 -59.25  20.08  233
 11  φ   -339.92  19.08   0.50    2.00  15.81  -9.84 -59.25    --   718
;
_diffrn_measurement_device       'abstract diffractometer'
_diffrn_measurement_device_type
'Saxi-CrysAlisPro-abstract goniometer imported SAXI images'
_diffrn_measurement_method       'ω and φ scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0406
_diffrn_reflns_av_unetI/netI     0.0357
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.811
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_number            89799
_diffrn_reflns_point_group_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.811
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         36.818
_diffrn_reflns_theta_min         2.172
_exptl_absorpt_coefficient_mu    2.055
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.81315
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlisPro 1.171.41.93a (Rigaku Oxford Diffraction, 2020)
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            colourless
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.747
_exptl_crystal_description       block
_exptl_crystal_F_000             668
_exptl_crystal_size_max          0.095
_exptl_crystal_size_mid          0.067
_exptl_crystal_size_min          0.065
_refine_diff_density_max         1.221
_refine_diff_density_min         -0.724
_refine_diff_density_rms         0.104
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.052
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     317
_refine_ls_number_reflns         10573
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.052
_refine_ls_R_factor_all          0.0507
_refine_ls_R_factor_gt           0.0297
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0237P)²+0.5214P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0571
_refine_ls_wR_factor_ref         0.0629
_reflns_Friedel_coverage         0.000
_reflns_number_gt                8251
_reflns_number_total             10573
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d2dt03791b2.cif
_cod_data_source_block           comp_8
_cod_depositor_comments
'Adding full bibliography for 7712157--7712163.cif.'
_cod_original_cell_volume        1296.81(3)
_cod_database_code               7712160
_shelx_shelxl_version_number     2018/3
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_max   0.878
_shelx_estimated_absorpt_t_min   0.829
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2.a Aromatic/amide H refined with riding coordinates:
 C21(H21), C15(H15), C18(H18), C2(H2), C13(H13), C19(H19), C16(H16), C9(H9),
 C25(H25), C22(H22), C4(H4), C3(H3), C12(H12), C17(H17), C10(H10), C11(H11),
 C1(H1), C24(H24), C23(H23)
2.b Idealised Me refined as rotating group:
 C26(H26A,H26B,H26C)
;
_olex2_submission_special_instructions 'No special instructions were received'
_oxdiff_exptl_absorpt_empirical_details
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
- Detector area scaling
;
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
I1 I 0.53631(2) 0.71564(2) 0.96881(2) 0.02813(4) Uani 1 1 d . . . . .
Ag1 Ag 0.50718(2) 0.45652(2) 0.89328(2) 0.02627(4) Uani 1 1 d . . . . .
P1 P 0.61516(4) 0.34433(4) 0.78388(3) 0.01773(8) Uani 1 1 d . . . . .
N4 N 0.49543(15) 0.06646(13) 0.68880(11) 0.0213(3) Uani 1 1 d . . . . .
N3 N 0.36446(16) -0.02556(14) 0.62649(13) 0.0284(3) Uani 1 1 d . . . . .
N2 N 0.26147(16) 0.03366(15) 0.60914(12) 0.0276(3) Uani 1 1 d . . . . .
C20 C 0.63462(16) 0.39447(15) 0.66515(13) 0.0194(3) Uani 1 1 d . . . . .
N1 N 0.27504(15) 0.36589(14) 0.72503(11) 0.0223(3) Uani 1 1 d . . . . .
C21 C 0.6072(2) 0.30805(17) 0.56498(14) 0.0254(3) Uani 1 1 d . . . . .
H21 H 0.573201 0.217091 0.555211 0.031 Uiso 1 1 calc R U . . .
C15 C 0.88883(17) 0.29521(16) 0.81752(14) 0.0226(3) Uani 1 1 d . . . . .
H15 H 0.860687 0.284000 0.739264 0.027 Uiso 1 1 calc R U . . .
N5 N -0.0866(3) 0.2717(2) 0.29213(19) 0.0552(5) Uani 1 1 d . . . . .
C5 C 0.22519(17) 0.24773(16) 0.65189(13) 0.0209(3) Uani 1 1 d . . . . .
C18 C 0.97374(19) 0.33117(19) 1.04714(15) 0.0294(4) Uani 1 1 d . . . . .
H18 H 1.002956 0.343518 1.125609 0.035 Uiso 1 1 calc R U . . .
C6 C 0.32354(17) 0.16342(16) 0.66123(13) 0.0208(3) Uani 1 1 d . . . . .
C8 C 0.62534(18) 0.02227(16) 0.72483(14) 0.0226(3) Uani 1 1 d . . . . .
C2 C 0.03997(19) 0.40255(19) 0.63216(15) 0.0292(4) Uani 1 1 d . . . . .
H2 H -0.021087 0.458887 0.626978 0.035 Uiso 1 1 calc R U . . .
C13 C 0.6793(2) 0.0025(2) 0.83115(16) 0.0321(4) Uani 1 1 d . . . . .
H13 H 0.634057 0.021293 0.880242 0.038 Uiso 1 1 calc R U . . .
C19 C 0.83552(18) 0.33834(18) 0.97940(14) 0.0250(3) Uani 1 1 d . . . . .
H19 H 0.770650 0.356595 1.011728 0.030 Uiso 1 1 calc R U . . .
C16 C 1.02691(18) 0.28813(18) 0.88571(15) 0.0273(3) Uani 1 1 d . . . . .
H16 H 1.092649 0.271011 0.853908 0.033 Uiso 1 1 calc R U . . .
C7 C 0.47625(16) 0.18680(15) 0.71340(12) 0.0186(3) Uani 1 1 d . . . . .
C9 C 0.6885(2) -0.00447(18) 0.65174(16) 0.0312(4) Uani 1 1 d . . . . .
H9 H 0.650124 0.009899 0.579112 0.037 Uiso 1 1 calc R U . . .
C25 C 0.68314(19) 0.52770(17) 0.67728(15) 0.0270(3) Uani 1 1 d . . . . .
H25 H 0.699886 0.587980 0.744235 0.032 Uiso 1 1 calc R U . . .
C14 C 0.79159(16) 0.31872(15) 0.86366(13) 0.0194(3) Uani 1 1 d . . . . .
C22 C 0.6290(2) 0.3537(2) 0.47935(15) 0.0315(4) Uani 1 1 d . . . . .
H22 H 0.609246 0.294338 0.411047 0.038 Uiso 1 1 calc R U . . .
C4 C 0.08148(18) 0.20254(19) 0.56767(15) 0.0290(4) Uani 1 1 d . . . . .
H4 H 0.047938 0.118729 0.517080 0.035 Uiso 1 1 calc R U . . .
C3 C -0.01150(19) 0.2811(2) 0.55870(15) 0.0321(4) Uani 1 1 d . . . . .
H3 H -0.109758 0.251477 0.502414 0.039 Uiso 1 1 calc R U . . .
C12 C 0.8006(2) -0.0452(2) 0.8647(2) 0.0422(5) Uani 1 1 d . . . . .
H12 H 0.839727 -0.058487 0.937636 0.051 Uiso 1 1 calc R U . . .
C17 C 1.06899(18) 0.30602(18) 1.00027(15) 0.0280(4) Uani 1 1 d . . . . .
H17 H 1.163476 0.300994 1.046697 0.034 Uiso 1 1 calc R U . . .
C10 C 0.8097(2) -0.0530(2) 0.68670(19) 0.0415(5) Uani 1 1 d . . . . .
H10 H 0.854906 -0.072164 0.637667 0.050 Uiso 1 1 calc R U . . .
C27 C -0.1738(3) 0.1800(2) 0.23032(19) 0.0410(5) Uani 1 1 d . . . . .
C11 C 0.8645(2) -0.0733(2) 0.7928(2) 0.0438(5) Uani 1 1 d . . . . .
H11 H 0.946880 -0.106867 0.816159 0.053 Uiso 1 1 calc R U . . .
C1 C 0.18321(18) 0.44050(18) 0.71392(14) 0.0266(3) Uani 1 1 d . . . . .
H1 H 0.218417 0.524140 0.765040 0.032 Uiso 1 1 calc R U . . .
C24 C 0.7070(2) 0.5725(2) 0.59243(18) 0.0358(4) Uani 1 1 d . . . . .
H24 H 0.742447 0.663267 0.602084 0.043 Uiso 1 1 calc R U . . .
C23 C 0.6795(2) 0.4859(2) 0.49391(17) 0.0345(4) Uani 1 1 d . . . . .
H23 H 0.695350 0.517229 0.435676 0.041 Uiso 1 1 calc R U . . .
C26 C -0.2803(3) 0.0581(2) 0.14966(19) 0.0487(6) Uani 1 1 d . . . . .
H26A H -0.281991 0.055175 0.075186 0.073 Uiso 1 1 calc R U . . .
H26B H -0.378504 0.054575 0.146068 0.073 Uiso 1 1 calc R U . . .
H26C H -0.250981 -0.016337 0.174169 0.073 Uiso 1 1 calc R U . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
I I -0.4742 1.8119 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Ag1 I1 Ag1 61.844(5) . 2_667 ?
I1 Ag1 I1 118.156(6) . 2_667 ?
I1 Ag1 Ag1 61.862(5) . 2_667 ?
Ag1 Ag1 I1 56.295(5) 2_667 2_667 ?
P1 Ag1 I1 103.504(11) . 2_667 ?
P1 Ag1 I1 131.977(11) . . ?
P1 Ag1 Ag1 149.840(12) . 2_667 ?
N1 Ag1 I1 107.38(3) . . ?
N1 Ag1 I1 100.62(3) . 2_667 ?
N1 Ag1 Ag1 117.79(3) . 2_667 ?
N1 Ag1 P1 85.86(3) . . ?
C20 P1 Ag1 122.06(5) . . ?
C20 P1 C7 101.15(7) . . ?
C20 P1 C14 104.56(7) . . ?
C7 P1 Ag1 102.06(5) . . ?
C14 P1 Ag1 116.27(5) . . ?
C14 P1 C7 109.16(7) . . ?
N3 N4 C8 117.15(13) . . ?
N3 N4 C7 111.29(13) . . ?
C7 N4 C8 131.33(13) . . ?
N2 N3 N4 107.22(13) . . ?
N3 N2 C6 109.68(13) . . ?
C21 C20 P1 123.94(13) . . ?
C21 C20 C25 118.74(16) . . ?
C25 C20 P1 117.30(13) . . ?
C5 N1 Ag1 127.98(11) . . ?
C1 N1 Ag1 113.60(11) . . ?
C1 N1 C5 118.01(14) . . ?
C20 C21 H21 119.7 . . ?
C22 C21 C20 120.58(17) . . ?
C22 C21 H21 119.7 . . ?
C16 C15 H15 120.0 . . ?
C16 C15 C14 120.10(15) . . ?
C14 C15 H15 120.0 . . ?
N1 C5 C6 119.46(13) . . ?
N1 C5 C4 121.43(15) . . ?
C4 C5 C6 119.11(15) . . ?
C19 C18 H18 120.0 . . ?
C17 C18 H18 120.0 . . ?
C17 C18 C19 119.97(16) . . ?
N2 C6 C5 118.11(14) . . ?
N2 C6 C7 108.34(14) . . ?
C7 C6 C5 133.54(15) . . ?
C13 C8 N4 118.40(15) . . ?
C9 C8 N4 119.66(15) . . ?
C9 C8 C13 121.88(16) . . ?
C3 C2 H2 120.9 . . ?
C3 C2 C1 118.20(16) . . ?
C1 C2 H2 120.9 . . ?
C8 C13 H13 120.6 . . ?
C8 C13 C12 118.72(19) . . ?
C12 C13 H13 120.6 . . ?
C18 C19 H19 119.9 . . ?
C18 C19 C14 120.13(16) . . ?
C14 C19 H19 119.9 . . ?
C15 C16 H16 120.0 . . ?
C17 C16 C15 120.07(16) . . ?
C17 C16 H16 120.0 . . ?
N4 C7 P1 128.92(11) . . ?
N4 C7 C6 103.46(13) . . ?
C6 C7 P1 127.32(12) . . ?
C8 C9 H9 120.7 . . ?
C8 C9 C10 118.55(18) . . ?
C10 C9 H9 120.7 . . ?
C20 C25 H25 119.8 . . ?
C24 C25 C20 120.40(17) . . ?
C24 C25 H25 119.8 . . ?
C15 C14 P1 123.35(12) . . ?
C15 C14 C19 119.48(14) . . ?
C19 C14 P1 116.79(12) . . ?
C21 C22 H22 120.1 . . ?
C23 C22 C21 119.71(18) . . ?
C23 C22 H22 120.1 . . ?
C5 C4 H4 120.3 . . ?
C3 C4 C5 119.36(17) . . ?
C3 C4 H4 120.3 . . ?
C2 C3 C4 119.27(16) . . ?
C2 C3 H3 120.4 . . ?
C4 C3 H3 120.4 . . ?
C13 C12 H12 119.8 . . ?
C11 C12 C13 120.3(2) . . ?
C11 C12 H12 119.8 . . ?
C18 C17 C16 120.23(15) . . ?
C18 C17 H17 119.9 . . ?
C16 C17 H17 119.9 . . ?
C9 C10 H10 120.0 . . ?
C11 C10 C9 120.1(2) . . ?
C11 C10 H10 120.0 . . ?
N5 C27 C26 176.7(3) . . ?
C12 C11 C10 120.49(19) . . ?
C12 C11 H11 119.8 . . ?
C10 C11 H11 119.8 . . ?
N1 C1 C2 123.71(17) . . ?
N1 C1 H1 118.1 . . ?
C2 C1 H1 118.1 . . ?
C25 C24 H24 119.9 . . ?
C23 C24 C25 120.17(18) . . ?
C23 C24 H24 119.9 . . ?
C22 C23 H23 119.8 . . ?
C24 C23 C22 120.38(18) . . ?
C24 C23 H23 119.8 . . ?
C27 C26 H26A 109.5 . . ?
C27 C26 H26B 109.5 . . ?
C27 C26 H26C 109.5 . . ?
H26A C26 H26B 109.5 . . ?
H26A C26 H26C 109.5 . . ?
H26B C26 H26C 109.5 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
I1 Ag1 2.74672(18) . ?
I1 Ag1 2.91151(19) 2_667 ?
Ag1 Ag1 2.9110(3) 2_667 ?
Ag1 P1 2.4459(4) . ?
Ag1 N1 2.4459(13) . ?
P1 C20 1.8192(16) . ?
P1 C7 1.8269(16) . ?
P1 C14 1.8217(15) . ?
N4 N3 1.3583(19) . ?
N4 C8 1.441(2) . ?
N4 C7 1.366(2) . ?
N3 N2 1.308(2) . ?
N2 C6 1.366(2) . ?
C20 C21 1.394(2) . ?
C20 C25 1.395(2) . ?
N1 C5 1.347(2) . ?
N1 C1 1.341(2) . ?
C21 H21 0.9500 . ?
C21 C22 1.388(2) . ?
C15 H15 0.9500 . ?
C15 C16 1.388(2) . ?
C15 C14 1.392(2) . ?
N5 C27 1.137(3) . ?
C5 C6 1.475(2) . ?
C5 C4 1.398(2) . ?
C18 H18 0.9500 . ?
C18 C19 1.388(2) . ?
C18 C17 1.385(3) . ?
C6 C7 1.399(2) . ?
C8 C13 1.384(2) . ?
C8 C9 1.379(2) . ?
C2 H2 0.9500 . ?
C2 C3 1.375(3) . ?
C2 C1 1.385(2) . ?
C13 H13 0.9500 . ?
C13 C12 1.387(3) . ?
C19 H19 0.9500 . ?
C19 C14 1.399(2) . ?
C16 H16 0.9500 . ?
C16 C17 1.388(3) . ?
C9 H9 0.9500 . ?
C9 C10 1.392(3) . ?
C25 H25 0.9500 . ?
C25 C24 1.383(3) . ?
C22 H22 0.9500 . ?
C22 C23 1.380(3) . ?
C4 H4 0.9500 . ?
C4 C3 1.385(3) . ?
C3 H3 0.9500 . ?
C12 H12 0.9500 . ?
C12 C11 1.373(3) . ?
C17 H17 0.9500 . ?
C10 H10 0.9500 . ?
C10 C11 1.384(3) . ?
C27 C26 1.476(3) . ?
C11 H11 0.9500 . ?
C1 H1 0.9500 . ?
C24 H24 0.9500 . ?
C24 C23 1.378(3) . ?
C23 H23 0.9500 . ?
C26 H26A 0.9800 . ?
C26 H26B 0.9800 . ?
C26 H26C 0.9800 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Ag1 P1 C20 C21 -139.10(12) . . . . ?
Ag1 P1 C20 C25 42.36(14) . . . . ?
Ag1 P1 C7 N4 -143.66(13) . . . . ?
Ag1 P1 C7 C6 43.74(15) . . . . ?
Ag1 P1 C14 C15 -159.20(12) . . . . ?
Ag1 P1 C14 C19 13.64(15) . . . . ?
Ag1 N1 C5 C6 -8.2(2) . . . . ?
Ag1 N1 C5 C4 171.26(13) . . . . ?
Ag1 N1 C1 C2 -172.80(15) . . . . ?
P1 C20 C21 C22 -177.95(13) . . . . ?
P1 C20 C25 C24 176.97(13) . . . . ?
N4 N3 N2 C6 -1.08(19) . . . . ?
N4 C8 C13 C12 177.34(18) . . . . ?
N4 C8 C9 C10 -176.95(17) . . . . ?
N3 N4 C8 C13 -95.96(19) . . . . ?
N3 N4 C8 C9 81.3(2) . . . . ?
N3 N4 C7 P1 -174.31(12) . . . . ?
N3 N4 C7 C6 -0.36(18) . . . . ?
N3 N2 C6 C5 -179.86(14) . . . . ?
N3 N2 C6 C7 0.9(2) . . . . ?
N2 C6 C7 P1 173.79(12) . . . . ?
N2 C6 C7 N4 -0.30(17) . . . . ?
C20 P1 C7 N4 89.80(15) . . . . ?
C20 P1 C7 C6 -82.80(15) . . . . ?
C20 P1 C14 C15 -21.49(16) . . . . ?
C20 P1 C14 C19 151.35(13) . . . . ?
C20 C21 C22 C23 0.5(3) . . . . ?
C20 C25 C24 C23 1.6(3) . . . . ?
N1 C5 C6 N2 161.88(15) . . . . ?
N1 C5 C6 C7 -19.1(3) . . . . ?
N1 C5 C4 C3 0.4(3) . . . . ?
C21 C20 C25 C24 -1.7(2) . . . . ?
C21 C22 C23 C24 -0.6(3) . . . . ?
C15 C16 C17 C18 -0.1(3) . . . . ?
C5 N1 C1 C2 0.5(3) . . . . ?
C5 C6 C7 P1 -5.3(3) . . . . ?
C5 C6 C7 N4 -179.40(17) . . . . ?
C5 C4 C3 C2 0.6(3) . . . . ?
C18 C19 C14 P1 -174.71(14) . . . . ?
C18 C19 C14 C15 -1.6(3) . . . . ?
C6 C5 C4 C3 179.81(17) . . . . ?
C8 N4 N3 N2 175.99(14) . . . . ?
C8 N4 C7 P1 11.5(3) . . . . ?
C8 N4 C7 C6 -174.53(16) . . . . ?
C8 C13 C12 C11 -0.6(3) . . . . ?
C8 C9 C10 C11 -0.1(3) . . . . ?
C13 C8 C9 C10 0.2(3) . . . . ?
C13 C12 C11 C10 0.7(4) . . . . ?
C19 C18 C17 C16 0.1(3) . . . . ?
C16 C15 C14 P1 174.25(13) . . . . ?
C16 C15 C14 C19 1.6(3) . . . . ?
C7 P1 C20 C21 -27.08(15) . . . . ?
C7 P1 C20 C25 154.37(13) . . . . ?
C7 P1 C14 C15 86.08(15) . . . . ?
C7 P1 C14 C19 -101.08(14) . . . . ?
C7 N4 N3 N2 0.91(19) . . . . ?
C7 N4 C8 C13 77.9(2) . . . . ?
C7 N4 C8 C9 -104.8(2) . . . . ?
C9 C8 C13 C12 0.2(3) . . . . ?
C9 C10 C11 C12 -0.4(3) . . . . ?
C25 C20 C21 C22 0.6(2) . . . . ?
C25 C24 C23 C22 -0.5(3) . . . . ?
C14 P1 C20 C21 86.30(15) . . . . ?
C14 P1 C20 C25 -92.25(13) . . . . ?
C14 P1 C7 N4 -20.06(16) . . . . ?
C14 P1 C7 C6 167.33(14) . . . . ?
C14 C15 C16 C17 -0.8(3) . . . . ?
C4 C5 C6 N2 -17.6(2) . . . . ?
C4 C5 C6 C7 161.48(18) . . . . ?
C3 C2 C1 N1 0.5(3) . . . . ?
C17 C18 C19 C14 0.7(3) . . . . ?
C1 N1 C5 C6 179.63(15) . . . . ?
C1 N1 C5 C4 -0.9(2) . . . . ?
C1 C2 C3 C4 -1.1(3) . . . . ?
