#------------------------------------------------------------------------------
#$Date: 2023-07-20 01:57:53 +0300 (Thu, 20 Jul 2023) $
#$Revision: 285280 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/71/35/7713508.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7713508
loop_
_publ_author_name
'Kikuchi, Kazuma'
'Imoto, Hiroaki'
'Naka, Kensuke'
_publ_section_title
;
 Robust and highly emissive copper(I) halide 1D-coordination polymers with
 triphenylarsine and a series of bridging N-heteroaromatic co-ligands
;
_journal_name_full               'Dalton Transactions'
_journal_paper_doi               10.1039/D3DT00784G
_journal_year                    2023
_chemical_formula_moiety         'C20.5 H18 As Cu I N, C2 H4 N'
_chemical_formula_sum            'C22.5 H22 As Cu I N2'
_chemical_formula_weight         585.78
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2yn'
_space_group_name_H-M_alt        'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_audit_creation_date             2023-04-26
_audit_creation_method
;
Olex2 1.5-ac5-024
(compiled 2022.04.12 svn.rca3783a0 for Rigaku Oxford Diffraction, GUI svn.r6498)
;
_audit_update_record
;
2023-05-31 deposited with the CCDC.	2023-07-18 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 94.323(5)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   8.9916(5)
_cell_length_b                   18.7540(8)
_cell_length_c                   13.3544(7)
_cell_measurement_reflns_used    2406
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      25.1910
_cell_measurement_theta_min      3.0710
_cell_volume                     2245.5(2)
_computing_cell_refinement       'CrysAlisPro 1.171.42.84a (Rigaku OD, 2023)'
_computing_data_collection       'CrysAlisPro 1.171.42.84a (Rigaku OD, 2023)'
_computing_data_reduction        'CrysAlisPro 1.171.42.84a (Rigaku OD, 2023)'
_computing_molecular_graphics    'Olex2 1.5-ac5-024 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5-ac5-024 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT  (Sheldrick, 2015)'
_diffrn_ambient_temperature      293(2)
_diffrn_detector                 'CCD plate'
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_details
;
List of Runs (angles in degrees, time in seconds):

  # Type    Start    End  Width  tₑₓₚ   ω     θ     κ     φ   Frames
#--------------------------------------------------------------------------
  1  ω    -35.00  10.00   0.20    2.00    --   30.00  54.00  30.00  225
  2  ω    -65.00 119.00   0.20    2.00    --   30.00  54.00 -60.00  920
;
_diffrn_measurement_device       'two-circle diffractometer'
_diffrn_measurement_device_type  'XtaLAB Mini (JP)'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_type
'CrysAlisPro convention (1999,Acta A55,543-557)'
_diffrn_orient_matrix_UB_11      0.0150507000
_diffrn_orient_matrix_UB_12      -0.0361727000
_diffrn_orient_matrix_UB_13      0.0123506000
_diffrn_orient_matrix_UB_21      -0.0770262000
_diffrn_orient_matrix_UB_22      -0.0080452000
_diffrn_orient_matrix_UB_23      -0.0078544000
_diffrn_orient_matrix_UB_31      0.0093560000
_diffrn_orient_matrix_UB_32      -0.0075118000
_diffrn_orient_matrix_UB_33      -0.0512756000
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0264
_diffrn_reflns_av_unetI/netI     0.0394
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.998
_diffrn_reflns_limit_h_max       4
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       22
_diffrn_reflns_limit_k_min       -20
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            8400
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.998
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         25.344
_diffrn_reflns_theta_min         2.518
_diffrn_source                   'fine-focus sealed X-ray tube'
_diffrn_source_type              'Rigaku (Mo) X-ray Source'
_exptl_absorpt_coefficient_mu    3.819
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.61865
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlisPro 1.171.42.84a (Rigaku Oxford Diffraction, 2023)
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            yellow
_exptl_crystal_colour_primary    yellow
_exptl_crystal_density_diffrn    1.733
_exptl_crystal_description       block
_exptl_crystal_F_000             1144
_exptl_crystal_size_max          0.532
_exptl_crystal_size_mid          0.326
_exptl_crystal_size_min          0.269
_refine_diff_density_max         1.488
_refine_diff_density_min         -1.027
_refine_diff_density_rms         0.133
_refine_ls_extinction_coef       0.0009(2)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     'SHELXL-2018/3 (Sheldrick 2018)'
_refine_ls_goodness_of_fit_ref   1.091
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     248
_refine_ls_number_reflns         4097
_refine_ls_number_restraints     150
_refine_ls_restrained_S_all      1.074
_refine_ls_R_factor_all          0.0720
_refine_ls_R_factor_gt           0.0506
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0528P)²+7.4592P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1289
_refine_ls_wR_factor_ref         0.1421
_reflns_Friedel_coverage         0.000
_reflns_number_gt                3003
_reflns_number_total             4097
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d3dt00784g2.cif
_cod_data_source_block           '[Cu2I2(AsPh3)2(meprz)]n_298K'
_cod_original_formula_sum        'C22.50 H22 As Cu I N2'
_cod_database_code               7713508
_shelx_shelxl_version_number     2018/3
_chemical_oxdiff_formula         CHAsCuIN
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_max   0.426
_shelx_estimated_absorpt_t_min   0.236
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2. Restrained distances
 N2B-C22B \\sim N2A-C22A
 with sigma of 0.02
 C22B-C23B \\sim C22A-C23A
 with sigma of 0.02
 N2B-C23B \\sim N2A-C23A
 with sigma of 0.04
3. Uiso/Uaniso restraints and constraints
N2A \\sim C22B \\sim C23A: within 2A with sigma of 0.04 and sigma for terminal
atoms of 0.08 within 2A
N2B \\sim C22A \\sim C23B: within 2A with sigma of 0.04 and sigma for terminal
atoms of 0.08 within 2A
4. Rigid body (RIGU) restrains
 C14, C13, C18, C17, C16, C15
 with sigma for 1-2 distances of 0.004 and sigma for 1-3 distances of 0.004
 C7, C12, C11, C10, C9, C8
 with sigma for 1-2 distances of 0.004 and sigma for 1-3 distances of 0.004
 C6, C5, C4, C3, C2, C1
 with sigma for 1-2 distances of 0.004 and sigma for 1-3 distances of 0.004
 C23B, C22A, N2B
 with sigma for 1-2 distances of 0.004 and sigma for 1-3 distances of 0.004
 C22B, C23A, N2A
 with sigma for 1-2 distances of 0.004 and sigma for 1-3 distances of 0.004
 C21, C19, N1, C20
 with sigma for 1-2 distances of 0.004 and sigma for 1-3 distances of 0.004
5. Others
 Fixed Sof: H19(0.5) C21(0.5) H21A(0.5) H21B(0.5) H21C(0.5) N2B(0.5) C22B(0.5)
 H22B(0.5) C23B(0.5) H23A(0.5) H23B(0.5) H23C(0.5) C23A(0.5) H23D(0.5)
 H23E(0.5) H23F(0.5) C22A(0.5) H22A(0.5) N2A(0.5)
6.a Aromatic/amide H refined with riding coordinates:
 C12(H12), C11(H11), C10(H10), C9(H9), C8(H8), C19(H19), C20(H20), C18(H18),
 C17(H17), C16(H16), C15(H15), C14(H14), C6(H6), C5(H5), C4(H4), C3(H3), C2(H2),
  C22B(H22B), C22A(H22A)
6.b Fitted hexagon refined as free rotating group:
 C7(C12,C11,C10,C9,C8), C18(C17,C16,C15,C14,C13), C6(C5,C4,C3,C2,C1)
6.c Idealised Me refined as rotating group:
 C21(H21A,H21B,H21C), C23B(H23A,H23B,H23C), C23A(H23D,H23E,H23F)
;
_olex2_submission_special_instructions 'No special instructions were received'
_oxdiff_exptl_absorpt_empirical_details
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
;
_oxdiff_exptl_absorpt_empirical_full_max 1.565
_oxdiff_exptl_absorpt_empirical_full_min 0.801
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
I1 I 0.48638(5) 0.38349(2) 0.50086(4) 0.0506(2) Uani 1 1 d . . . . .
As1 As 0.59647(8) 0.49785(4) 0.74581(5) 0.0386(2) Uani 1 1 d . . . . .
Cu1 Cu 0.63990(10) 0.49592(5) 0.57347(7) 0.0490(3) Uani 1 1 d . . . . .
N1 N 0.8552(7) 0.4967(3) 0.5306(5) 0.0459(14) Uani 1 1 d . . . . .
C7 C 0.6464(5) 0.5852(2) 0.8190(3) 0.0424(15) Uani 1 1 d G . . . .
C12 C 0.7739(5) 0.6212(3) 0.7948(3) 0.0540(18) Uani 1 1 d G . . . .
H12 H 0.829303 0.604194 0.743786 0.065 Uiso 1 1 calc R U . . .
C11 C 0.8186(5) 0.6827(3) 0.8467(4) 0.070(2) Uani 1 1 d G . . . .
H11 H 0.903928 0.706866 0.830522 0.084 Uiso 1 1 calc R U . . .
C10 C 0.7359(7) 0.7082(2) 0.9230(4) 0.076(2) Uani 1 1 d G . . . .
H10 H 0.765777 0.749356 0.957737 0.092 Uiso 1 1 calc R U . . .
C9 C 0.6084(6) 0.6721(3) 0.9472(3) 0.068(2) Uani 1 1 d G . . . .
H9 H 0.553001 0.689173 0.998217 0.081 Uiso 1 1 calc R U . . .
C8 C 0.5637(5) 0.6106(2) 0.8953(4) 0.0545(18) Uani 1 1 d G . . . .
H8 H 0.478374 0.586501 0.911482 0.065 Uiso 1 1 calc R U . . .
C19 C 0.9451(8) 0.4406(4) 0.5348(6) 0.0494(18) Uani 1 1 d . . . . .
H19 H 0.909525 0.397573 0.558231 0.059 Uiso 0.5 1 calc R U P A 2
C20 C 0.9129(9) 0.5569(4) 0.4937(6) 0.0538(19) Uani 1 1 d . . . . .
H20 H 0.854013 0.597604 0.487562 0.065 Uiso 1 1 calc R U . . .
C18 C 0.2883(5) 0.5344(3) 0.7217(4) 0.0578(19) Uani 1 1 d G . . . .
H18 H 0.321871 0.569141 0.679092 0.069 Uiso 1 1 calc R U . . .
C17 C 0.1372(5) 0.5293(3) 0.7363(4) 0.071(2) Uani 1 1 d G . . . .
H17 H 0.069748 0.560618 0.703497 0.085 Uiso 1 1 calc R U . . .
C16 C 0.0870(4) 0.4775(3) 0.8001(4) 0.072(2) Uani 1 1 d G . . . .
H16 H -0.014023 0.474041 0.809856 0.086 Uiso 1 1 calc R U . . .
C15 C 0.1879(6) 0.4307(3) 0.8492(4) 0.077(3) Uani 1 1 d G . . . .
H15 H 0.154329 0.395987 0.891811 0.092 Uiso 1 1 calc R U . . .
C14 C 0.3390(5) 0.4358(2) 0.8346(4) 0.061(2) Uani 1 1 d G . . . .
H14 H 0.406452 0.404508 0.867409 0.073 Uiso 1 1 calc R U . . .
C13 C 0.3892(4) 0.4877(3) 0.7708(4) 0.0424(15) Uani 1 1 d G . . . .
C6 C 0.7518(6) 0.4439(2) 0.9317(3) 0.0546(18) Uani 1 1 d G . . . .
H6 H 0.745676 0.490376 0.955391 0.065 Uiso 1 1 calc R U . . .
C5 C 0.8226(6) 0.3917(3) 0.9918(3) 0.066(2) Uani 1 1 d G . . . .
H5 H 0.863930 0.403227 1.055725 0.079 Uiso 1 1 calc R U . . .
C4 C 0.8317(7) 0.3222(2) 0.9565(4) 0.072(2) Uani 1 1 d G . . . .
H4 H 0.879118 0.287310 0.996685 0.087 Uiso 1 1 calc R U . . .
C3 C 0.7700(7) 0.30501(19) 0.8610(4) 0.087(3) Uani 1 1 d G . . . .
H3 H 0.776053 0.258542 0.837312 0.105 Uiso 1 1 calc R U . . .
C2 C 0.6991(6) 0.3572(2) 0.8009(3) 0.066(2) Uani 1 1 d G . . . .
H2 H 0.657799 0.345690 0.736977 0.080 Uiso 1 1 calc R U . . .
C1 C 0.6900(5) 0.4267(2) 0.8362(3) 0.0416(15) Uani 1 1 d G . . . .
C21 C 0.9038(18) 0.3735(8) 0.5848(16) 0.072(5) Uani 0.5 1 d . . P B 1
H21A H 0.895828 0.382334 0.654971 0.108 Uiso 0.5 1 calc R U P B 1
H21B H 0.979054 0.338123 0.576712 0.108 Uiso 0.5 1 calc R U P B 1
H21C H 0.809754 0.356780 0.554931 0.108 Uiso 0.5 1 calc R U P B 1
N2B N 0.104(5) 0.700(3) 0.645(4) 0.114(13) Uani 0.5 1 d D U P C 2
C22B C 0.195(7) 0.722(5) 0.697(7) 0.13(2) Uani 0.5 1 d D U P C 2
H22B H 0.274244 0.706956 0.661113 0.157 Uiso 0.5 1 calc R U P C 2
C23B C 0.288(5) 0.757(3) 0.782(3) 0.156(17) Uani 0.5 1 d D U P C 2
H23A H 0.375055 0.778122 0.756071 0.234 Uiso 0.5 1 calc R U P C 2
H23B H 0.318108 0.722215 0.831630 0.234 Uiso 0.5 1 calc R U P C 2
H23C H 0.230447 0.793621 0.811025 0.234 Uiso 0.5 1 calc R U P C 2
C23A C 0.354(4) 0.740(2) 0.734(3) 0.148(15) Uani 0.5 1 d D U P D 3
H23D H 0.389583 0.777465 0.692267 0.222 Uiso 0.5 1 calc R U P D 3
H23E H 0.408488 0.697186 0.723385 0.222 Uiso 0.5 1 calc R U P D 3
H23F H 0.368161 0.754085 0.802963 0.222 Uiso 0.5 1 calc R U P D 3
C22A C 0.191(7) 0.728(5) 0.706(6) 0.14(2) Uani 0.5 1 d D U P D 3
H22A H 0.159719 0.732834 0.770626 0.166 Uiso 0.5 1 calc R U P D 3
N2A N 0.079(5) 0.717(3) 0.668(5) 0.14(2) Uani 0.5 1 d D U P D 3
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
As As 0.0499 2.0058 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
I I -0.4742 1.8119 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_exptl_crystal_face_index_h
_exptl_crystal_face_index_k
_exptl_crystal_face_index_l
_exptl_crystal_face_perp_dist
0 -1 0 0.1028
0 1 0 0.1660
1 2 -2 0.1893
-1 -2 2 0.1985
0 -1 -2 0.2440
-1 0 2 0.2274
-1 -1 0 0.1759
1 0 -1 0.1476
-1 0 1 0.2077
-2 -1 -1 0.1572
-2 1 -1 0.1547
2 -1 1 0.1317
-1 2 -1 0.1635
0 -2 1 0.1167
1 -2 0 0.1169
-1 2 0 0.1801
1 2 0 0.1858
2 5 18 0.3099
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Cu1 I1 Cu1 70.18(4) . 3_666 ?
C7 As1 Cu1 117.01(14) . . ?
C7 As1 C1 101.1(2) . . ?
C13 As1 Cu1 113.59(15) . . ?
C13 As1 C7 100.7(2) . . ?
C13 As1 C1 101.7(2) . . ?
C1 As1 Cu1 119.86(14) . . ?
I1 Cu1 I1 109.82(4) . 3_666 ?
As1 Cu1 I1 104.33(4) . . ?
As1 Cu1 I1 104.51(4) . 3_666 ?
N1 Cu1 I1 105.71(16) . 3_666 ?
N1 Cu1 I1 112.15(16) . . ?
N1 Cu1 As1 119.89(18) . . ?
C19 N1 Cu1 124.4(5) . . ?
C19 N1 C20 115.4(6) . . ?
C20 N1 Cu1 120.2(5) . . ?
C12 C7 As1 117.2(3) . . ?
C12 C7 C8 120.0 . . ?
C8 C7 As1 122.8(3) . . ?
C7 C12 C11 120.0 . . ?
C10 C11 C12 120.0 . . ?
C9 C10 C11 120.0 . . ?
C10 C9 C8 120.0 . . ?
C9 C8 C7 120.0 . . ?
N1 C19 C20 122.8(7) . 3_766 ?
N1 C19 C21 121.3(9) . . ?
C20 C19 C21 115.4(9) 3_766 . ?
N1 C20 C19 121.8(7) . 3_766 ?
C17 C18 C13 120.0 . . ?
C18 C17 C16 120.0 . . ?
C15 C16 C17 120.0 . . ?
C16 C15 C14 120.0 . . ?
C15 C14 C13 120.0 . . ?
C18 C13 As1 117.4(3) . . ?
C14 C13 As1 122.6(3) . . ?
C14 C13 C18 120.0 . . ?
C5 C6 C1 120.0 . . ?
C6 C5 C4 120.0 . . ?
C5 C4 C3 120.0 . . ?
C2 C3 C4 120.0 . . ?
C1 C2 C3 120.0 . . ?
C6 C1 As1 122.2(3) . . ?
C2 C1 As1 117.7(3) . . ?
C2 C1 C6 120.0 . . ?
N2B C22B C23B 166(9) . . ?
N2A C22A C23A 167(10) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
I1 Cu1 2.6626(10) . ?
I1 Cu1 2.6870(10) 3_666 ?
As1 Cu1 2.3635(11) . ?
As1 C7 1.943(3) . ?
As1 C13 1.928(3) . ?
As1 C1 1.948(3) . ?
Cu1 N1 2.060(6) . ?
N1 C19 1.326(9) . ?
N1 C20 1.350(9) . ?
C7 C12 1.3900 . ?
C7 C8 1.3900 . ?
C12 C11 1.3900 . ?
C11 C10 1.3900 . ?
C10 C9 1.3900 . ?
C9 C8 1.3900 . ?
C19 C20 1.360(10) 3_766 ?
C19 C21 1.483(16) . ?
C18 C17 1.3900 . ?
C18 C13 1.3900 . ?
C17 C16 1.3900 . ?
C16 C15 1.3900 . ?
C15 C14 1.3900 . ?
C14 C13 1.3900 . ?
C6 C5 1.3900 . ?
C6 C1 1.3900 . ?
C5 C4 1.3900 . ?
C4 C3 1.3900 . ?
C3 C2 1.3900 . ?
C2 C1 1.3900 . ?
N2B C22B 1.11(3) . ?
C22B C23B 1.50(4) . ?
C23A C22A 1.50(4) . ?
C22A N2A 1.11(3) . ?
loop_
_exptl_oxdiff_crystal_face_indexfrac_h
_exptl_oxdiff_crystal_face_indexfrac_k
_exptl_oxdiff_crystal_face_indexfrac_l
_exptl_oxdiff_crystal_face_x
_exptl_oxdiff_crystal_face_y
_exptl_oxdiff_crystal_face_z
-0.0007 -0.9972 0.0002 0.0361 0.0081 0.0075
0.0007 0.9972 -0.0002 -0.0361 -0.0081 -0.0075
0.9998 1.9922 -1.9935 -0.0816 -0.0774 0.0966
-0.9998 -1.9922 1.9935 0.0816 0.0774 -0.0966
0.0009 -0.9984 -1.9950 0.0115 0.0236 0.1098
-0.9984 0.0022 1.9930 0.0095 0.0612 -0.1116
-0.9976 -0.9962 -0.0020 0.0210 0.0849 -0.0018
0.9977 -0.0016 -0.9954 0.0028 -0.0690 0.0604
-0.9977 0.0016 0.9954 -0.0028 0.0690 -0.0604
-1.9937 -0.9958 -1.0017 -0.0064 0.1694 0.0402
-1.9924 0.9986 -1.0022 -0.0785 0.1533 0.0252
1.9924 -0.9986 1.0022 0.0785 -0.1533 -0.0252
-0.9948 1.9948 -1.0002 -0.0995 0.0684 0.0270
-0.0021 -1.9938 0.9980 0.0844 0.0084 -0.0362
0.9956 -1.9954 0.0026 0.0872 -0.0607 0.0242
-0.9956 1.9954 -0.0026 -0.0872 0.0607 -0.0242
0.9982 1.9934 0.0017 -0.0571 -0.0929 -0.0057
1.7729 5.0209 18.0272 0.0677 -0.3186 -0.9455
