#------------------------------------------------------------------------------
#$Date: 2023-09-13 01:59:44 +0300 (Wed, 13 Sep 2023) $
#$Revision: 286311 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/71/39/7713941.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7713941
loop_
_publ_author_name
'Sahoo, Amiya Kumar'
'Sahoo, Ashish Kumar'
'Das, Bhagyashree Ms'
'Panda, Subhra Jyoti'
'Purohit, Chandra Shekhar'
'Doddi, Adinarayana'
_publ_section_title
;
 New Cationic Coinage Metal Complexes Featuring Silyl Group Functionalized
 Phosphine; Syntheses, Structures and Catalytic Studies in Alkyne-Azide
 Cycloaddition Reactions
;
_journal_name_full               'Dalton Transactions'
_journal_paper_doi               10.1039/D3DT01692G
_journal_year                    2023
_chemical_formula_moiety         'F6 Sb, C42 H46 Ag P2 Si2'
_chemical_formula_sum            'C42 H46 Ag F6 P2 Sb Si2'
_chemical_formula_weight         1012.53
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_audit_creation_date             2023-01-28
_audit_creation_method
;
Olex2 1.3
(compiled 2020.11.12 svn.r5f609507 for OlexSys, GUI svn.r6408)
;
_audit_update_record
;
2023-05-23 deposited with the CCDC.	2023-09-12 downloaded from the CCDC.
;
_cell_angle_alpha                98.729(2)
_cell_angle_beta                 91.481(2)
_cell_angle_gamma                101.102(2)
_cell_formula_units_Z            1
_cell_length_a                   8.2983(2)
_cell_length_b                   10.5547(3)
_cell_length_c                   12.5094(3)
_cell_measurement_reflns_used    12765
_cell_measurement_temperature    100.00(10)
_cell_measurement_theta_max      77.3310
_cell_measurement_theta_min      3.6330
_cell_volume                     1060.98(5)
_computing_cell_refinement       'CrysAlisPro 1.171.42.52a (Rigaku OD, 2022)'
_computing_data_collection       'CrysAlisPro 1.171.42.52a (Rigaku OD, 2022)'
_computing_data_reduction        'CrysAlisPro 1.171.42.52a (Rigaku OD, 2022)'
_computing_molecular_graphics    'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2019/2 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT 2014/5 (Sheldrick, 2014)'
_diffrn_ambient_environment      N~2~
_diffrn_ambient_temperature      100.00(10)
_diffrn_detector                 'Hybrid Pixel Array Detector'
_diffrn_detector_area_resol_mean 5.8140
_diffrn_detector_type            'Pilatus 200K'
_diffrn_measured_fraction_theta_full 0.9990
_diffrn_measured_fraction_theta_max 0.7116
_diffrn_measurement_details
;
List of Runs (angles in degrees, time in seconds):

  # Type    Start    End  Width  tₑₓₚ   ω     θ     κ     φ   Frames
#--------------------------------------------------------------------------
  1  ω    -74.00  16.00   0.50    0.10    --  -38.50  98.00  57.00  180
  2  ω      5.00  84.00   0.50    0.10    --   49.06 -98.00 -49.00  158
  3  ω    104.00 176.00   0.50    0.30    --  107.46  98.00  57.00  144
  4  ω     39.00 107.00   0.50    0.30    --  107.46 -98.00 -49.00  136
  5  ω    -42.00  28.00   0.50    0.10    --  -38.50  37.00 -90.00  140
  6  ω   -101.00 -26.00   0.50    0.10    --  -38.50 -59.00-178.15  150
  7  ω   -105.00 -35.00   0.50    0.10    --  -38.50 -37.00  90.00  140
  8  ω   -101.00 -27.00   0.50    0.10    --  -38.50 -57.00 -90.00  148
  9  ω    -86.00  -6.00   0.50    0.10    --  -38.50 125.00 -90.00  160
 10  ω    -20.00  55.00   0.50    0.10    --   49.06 -19.00 120.00  150
 11  ω     28.00 100.00   0.50    0.10    --   49.06-125.00 -90.00  144
 12  ω    -17.00  52.00   0.50    0.10    --   49.06 -37.00  60.00  138
 13  ω     45.00 121.00   0.50    0.30    --  107.46 -61.00 150.00  152
 14  ω    103.00 172.00   0.50    0.30    --  107.46  45.00 -60.00  138
 15  ω     39.00 107.00   0.50    0.30    --  107.46 -94.00-180.00  136
 16  ω     39.00 107.00   0.50    0.30    --  107.46 -94.00-150.00  136
 17  ω     39.00 107.00   0.50    0.30    --  107.46 -94.00 120.00  136
 18  ω    103.00 172.00   0.50    0.30    --  107.46  45.00  30.00  138
 19  ω    104.00 176.00   0.50    0.30    --  107.46  30.00   0.00  144
 20  ω     43.00 112.00   0.50    0.30    --  107.46 -45.00 -90.00  138
 21  ω     39.00 116.00   0.50    0.30    --  107.46 -15.00-180.00  154
 22  ω     43.00 113.00   0.50    0.30    --  107.46-125.00  90.00  140
 23  ω     45.00 121.00   0.50    0.30    --  107.46 -61.00  60.00  152
 24  ω     43.00 113.00   0.50    0.30    --  107.46-125.00 -90.00  140
 25  ω     43.00 112.00   0.50    0.30    --  107.46 -45.00-180.00  138
 26  ω     43.00 112.00   0.50    0.30    --  107.46 -45.00   0.00  138
 27  ω     43.00 112.00   0.50    0.30    --  107.46 -45.00  60.00  138
 28  ω     43.00 131.00   0.50    0.30    --  107.46 -77.00 -60.00  176
 29  ω     43.00 131.00   0.50    0.30    --  107.46 -77.00 -90.00  176
 30  ω     39.00 111.00   0.50    0.30    --  107.46 -30.00  30.00  144
 31  ω     96.00 170.00   0.50    0.30    --  107.46  57.00-153.77  148
 32  ω     99.00 171.00   0.50    0.30    --  107.46  54.00 -35.61  144
 33  ω   -101.00 -21.00   0.50    0.10    --  -38.50 -68.00  -2.46  160
 34  ω     31.00  96.00   0.50    0.10    --   49.06  69.00  73.91  130
 35  ω     38.00 112.00   0.50    0.10    --   49.06  57.00-180.00  148
;
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type
'SuperNova, Dual, Cu at home/near, Pilatus 200K'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_type
'CrysAlisPro convention (1999,Acta A55,543-557)'
_diffrn_orient_matrix_UB_11      -0.0253971000
_diffrn_orient_matrix_UB_12      0.0591380000
_diffrn_orient_matrix_UB_13      0.1172286000
_diffrn_orient_matrix_UB_21      0.1738849000
_diffrn_orient_matrix_UB_22      0.0857002000
_diffrn_orient_matrix_UB_23      0.0076763000
_diffrn_orient_matrix_UB_31      -0.0709016000
_diffrn_orient_matrix_UB_32      0.1089157000
_diffrn_orient_matrix_UB_33      -0.0421051000
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           'Cu K\a'
_diffrn_radiation_wavelength     1.54184
_diffrn_reflns_av_R_equivalents  0.0815
_diffrn_reflns_av_unetI/netI     0.0544
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.971
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -10
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_number            16610
_diffrn_reflns_point_group_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.971
_diffrn_reflns_theta_full        67.684
_diffrn_reflns_theta_max         77.824
_diffrn_reflns_theta_min         3.580
_diffrn_source                   'micro-focus sealed X-ray tube'
_diffrn_source_type              'SuperNova (Cu) X-ray Source'
_exptl_absorpt_coefficient_mu    10.480
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.26182
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlisPro 1.171.42.52a (Rigaku Oxford Diffraction, 2022)
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            'clear light colourless'
_exptl_crystal_colour_lustre     clear
_exptl_crystal_colour_modifier   light
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.585
_exptl_crystal_description       plate
_exptl_crystal_F_000             508
_exptl_crystal_preparation       'As per the reaction scheme'
_exptl_crystal_recrystallization_method 'Slow vapour diffusion'
_exptl_crystal_size_max          0.33
_exptl_crystal_size_mid          0.29
_exptl_crystal_size_min          0.2
_refine_diff_density_max         1.383
_refine_diff_density_min         -1.738
_refine_diff_density_rms         0.148
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.108
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     250
_refine_ls_number_reflns         4411
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.108
_refine_ls_R_factor_all          0.0436
_refine_ls_R_factor_gt           0.0424
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0825P)²+0.1803P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1198
_refine_ls_wR_factor_ref         0.1216
_reflns_Friedel_coverage         0.000
_reflns_number_gt                4122
_reflns_number_total             4411
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d3dt01692g2.cif
_cod_data_source_block           sjp-as-211_auto
_cod_database_code               7713941
_shelx_shelxl_version_number     2019/2
_chemical_oxdiff_formula         'C H N P Si Ag Sb F'
_chemical_oxdiff_usercomment     'COLOURLESS PLATES'
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_max   0.228
_shelx_estimated_absorpt_t_min   0.129
_diffrn_oxdiff_digest_frames
;
015b6754dd3a80a8fd90ca86d19342d8d800041b2b0
;
_diffrn_oxdiff_digest_hkl
;
0137af9fc2d240470341d5795d7b4016ad0d47
;
_reflns_odcompleteness_completeness 99.90
_reflns_odcompleteness_iscentric 1
_reflns_odcompleteness_theta     68.13
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2.a Aromatic/amide H refined with riding coordinates:
 C2(H2), C3(H3), C4(H4), C5(H5), C6(H6), C8(H8), C9(H9), C10(H10), C11(H11),
 C12(H12), C14(H14), C15(H15), C16(H16), C17(H17)
2.b Idealised Me refined as rotating group:
 C19(H19a,H19b,H19c), C20(H20a,H20b,H20c), C21(H21a,H21b,H21c)
;
_olex2_exptl_crystal_mounting_method 'Mounted on the loop'
_olex2_submission_special_instructions 'No special instructions were received'
_oxdiff_exptl_absorpt_empirical_details
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
;
_oxdiff_exptl_absorpt_empirical_full_max 2.647
_oxdiff_exptl_absorpt_empirical_full_min 0.503
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Sb1 Sb 1.000000 1.000000 0.500000 0.02194(12) Uani 1 2 d S . P . .
F1 F 0.8147(2) 1.00737(18) 0.41263(13) 0.0306(4) Uani 1 1 d . . . . .
F2 F 0.9959(2) 0.82789(17) 0.43163(14) 0.0316(4) Uani 1 1 d . . . . .
F3 F 0.8626(2) 0.93542(19) 0.60461(14) 0.0347(4) Uani 1 1 d . . . . .
Ag1 Ag 0.500000 0.500000 0.000000 0.01997(12) Uani 1 2 d S . P . .
P1 P 0.66106(8) 0.56634(6) 0.16776(5) 0.01906(16) Uani 1 1 d . . . . .
Si04 Si 0.50669(9) 0.22756(8) 0.18308(6) 0.02218(18) Uani 1 1 d . . . . .
C1 C 0.8203(3) 0.6949(3) 0.1306(2) 0.0221(5) Uani 1 1 d . . . . .
C2 C 0.9062(3) 0.6612(3) 0.0388(2) 0.0277(6) Uani 1 1 d . . . . .
H2 H 0.881436 0.574485 0.000007 0.033 Uiso 1 1 calc R U . . .
C3 C 1.0272(4) 0.7540(4) 0.0046(3) 0.0322(7) Uani 1 1 d . . . . .
H3 H 1.085892 0.731019 -0.057192 0.039 Uiso 1 1 calc R U . . .
C4 C 1.0623(4) 0.8811(3) 0.0613(3) 0.0327(7) Uani 1 1 d . . . . .
H4 H 1.146162 0.944591 0.038609 0.039 Uiso 1 1 calc R U . . .
C5 C 0.9756(4) 0.9155(3) 0.1506(3) 0.0301(6) Uani 1 1 d . . . . .
H5 H 0.998414 1.002798 0.188132 0.036 Uiso 1 1 calc R U . . .
C6 C 0.8542(3) 0.8215(3) 0.1857(2) 0.0244(5) Uani 1 1 d . . . . .
H6 H 0.795347 0.844875 0.247407 0.029 Uiso 1 1 calc R U . . .
C7 C 0.5530(3) 0.6445(3) 0.2742(2) 0.0214(5) Uani 1 1 d . . . . .
C8 C 0.4190(4) 0.6972(3) 0.2466(2) 0.0276(6) Uani 1 1 d . . . . .
H8 H 0.383580 0.688356 0.172522 0.033 Uiso 1 1 calc R U . . .
C9 C 0.3363(4) 0.7624(3) 0.3252(3) 0.0301(6) Uani 1 1 d . . . . .
H9 H 0.245799 0.798611 0.305153 0.036 Uiso 1 1 calc R U . . .
C10 C 0.3863(4) 0.7741(4) 0.4326(3) 0.0364(7) Uani 1 1 d . . . . .
H10 H 0.329501 0.817635 0.487054 0.044 Uiso 1 1 calc R U . . .
C11 C 0.5192(6) 0.7227(5) 0.4612(3) 0.0527(11) Uani 1 1 d . . . . .
H11 H 0.554049 0.732179 0.535400 0.063 Uiso 1 1 calc R U . . .
C12 C 0.6018(4) 0.6579(4) 0.3837(3) 0.0393(8) Uani 1 1 d . . . . .
H12 H 0.692163 0.622225 0.404624 0.047 Uiso 1 1 calc R U . . .
C13 C 0.7748(3) 0.4639(3) 0.2336(2) 0.0211(5) Uani 1 1 d . . . . .
C14 C 0.9291(3) 0.5278(3) 0.2832(2) 0.0250(5) Uani 1 1 d . . . . .
H14 H 0.970895 0.616152 0.275600 0.030 Uiso 1 1 calc R U . . .
C15 C 1.0213(3) 0.4634(3) 0.3431(2) 0.0285(6) Uani 1 1 d . . . . .
H15 H 1.124052 0.507742 0.378067 0.034 Uiso 1 1 calc R U . . .
C16 C 0.9609(4) 0.3338(3) 0.3511(3) 0.0296(6) Uani 1 1 d . . . . .
H16 H 1.023437 0.288080 0.390672 0.035 Uiso 1 1 calc R U . . .
C17 C 0.8094(3) 0.2703(3) 0.3015(2) 0.0258(6) Uani 1 1 d . . . . .
H17 H 0.770667 0.181256 0.308066 0.031 Uiso 1 1 calc R U . . .
C18 C 0.7111(3) 0.3323(3) 0.2421(2) 0.0211(5) Uani 1 1 d . . . . .
C19 C 0.5109(4) 0.1879(3) 0.0318(2) 0.0302(6) Uani 1 1 d . . . . .
H19A H 0.556611 0.267493 0.002674 0.045 Uiso 1 1 calc R U . . .
H19B H 0.398797 0.152708 0.000581 0.045 Uiso 1 1 calc R U . . .
H19C H 0.579551 0.122719 0.013285 0.045 Uiso 1 1 calc R U . . .
C20 C 0.3314(3) 0.3094(3) 0.2209(3) 0.0302(6) Uani 1 1 d . . . . .
H20A H 0.340640 0.341655 0.298961 0.045 Uiso 1 1 calc R U . . .
H20B H 0.227420 0.246632 0.202298 0.045 Uiso 1 1 calc R U . . .
H20C H 0.334006 0.383053 0.181288 0.045 Uiso 1 1 calc R U . . .
C21 C 0.4748(4) 0.0690(3) 0.2367(2) 0.0296(6) Uani 1 1 d . . . . .
H21A H 0.563649 0.023126 0.214912 0.044 Uiso 1 1 calc R U . . .
H21B H 0.368964 0.014675 0.207260 0.044 Uiso 1 1 calc R U . . .
H21C H 0.474973 0.086140 0.315893 0.044 Uiso 1 1 calc R U . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag 0.1306 4.2820 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0727 0.0534 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.2955 0.4335 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sb Sb -0.0562 5.8946 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.2541 0.3302 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
F1 Sb1 F1 180.00(8) . 2_776 ?
F2 Sb1 F1 90.29(8) . . ?
F2 Sb1 F1 89.71(8) 2_776 . ?
F2 Sb1 F1 89.72(8) . 2_776 ?
F2 Sb1 F1 90.29(8) 2_776 2_776 ?
F2 Sb1 F2 180.00(11) . 2_776 ?
F3 Sb1 F1 89.61(8) 2_776 . ?
F3 Sb1 F1 90.39(8) 2_776 2_776 ?
F3 Sb1 F1 89.61(8) . 2_776 ?
F3 Sb1 F1 90.39(8) . . ?
F3 Sb1 F2 89.95(8) 2_776 2_776 ?
F3 Sb1 F2 90.05(8) 2_776 . ?
F3 Sb1 F2 90.05(8) . 2_776 ?
F3 Sb1 F2 89.95(8) . . ?
F3 Sb1 F3 180.0 2_776 . ?
P1 Ag1 P1 180.0 . 2_665 ?
C1 P1 Ag1 100.20(8) . . ?
C1 P1 C13 104.50(12) . . ?
C7 P1 Ag1 112.85(9) . . ?
C7 P1 C1 106.37(13) . . ?
C7 P1 C13 105.33(12) . . ?
C13 P1 Ag1 125.69(9) . . ?
C19 Si04 C18 110.07(12) . . ?
C20 Si04 C18 111.58(13) . . ?
C20 Si04 C19 110.45(14) . . ?
C20 Si04 C21 108.51(14) . . ?
C21 Si04 C18 108.91(13) . . ?
C21 Si04 C19 107.20(14) . . ?
C2 C1 P1 116.8(2) . . ?
C6 C1 P1 123.3(2) . . ?
C6 C1 C2 119.9(3) . . ?
C1 C2 H2 119.9 . . ?
C3 C2 C1 120.1(3) . . ?
C3 C2 H2 119.9 . . ?
C2 C3 H3 120.1 . . ?
C2 C3 C4 119.7(3) . . ?
C4 C3 H3 120.1 . . ?
C3 C4 H4 119.8 . . ?
C5 C4 C3 120.3(3) . . ?
C5 C4 H4 119.8 . . ?
C4 C5 H5 120.0 . . ?
C4 C5 C6 120.0(3) . . ?
C6 C5 H5 120.0 . . ?
C1 C6 C5 119.9(3) . . ?
C1 C6 H6 120.1 . . ?
C5 C6 H6 120.1 . . ?
C8 C7 P1 119.2(2) . . ?
C8 C7 C12 118.3(3) . . ?
C12 C7 P1 122.5(2) . . ?
C7 C8 H8 119.4 . . ?
C9 C8 C7 121.2(3) . . ?
C9 C8 H8 119.4 . . ?
C8 C9 H9 120.3 . . ?
C10 C9 C8 119.4(3) . . ?
C10 C9 H9 120.3 . . ?
C9 C10 H10 120.0 . . ?
C9 C10 C11 120.0(3) . . ?
C11 C10 H10 120.0 . . ?
C10 C11 H11 119.6 . . ?
C12 C11 C10 120.9(3) . . ?
C12 C11 H11 119.6 . . ?
C7 C12 H12 119.9 . . ?
C11 C12 C7 120.2(3) . . ?
C11 C12 H12 119.9 . . ?
C14 C13 P1 115.4(2) . . ?
C14 C13 C18 120.7(2) . . ?
C18 C13 P1 123.7(2) . . ?
C13 C14 H14 119.6 . . ?
C15 C14 C13 120.9(3) . . ?
C15 C14 H14 119.6 . . ?
C14 C15 H15 120.5 . . ?
C16 C15 C14 119.0(3) . . ?
C16 C15 H15 120.5 . . ?
C15 C16 H16 119.9 . . ?
C15 C16 C17 120.2(3) . . ?
C17 C16 H16 119.9 . . ?
C16 C17 H17 118.7 . . ?
C16 C17 C18 122.7(3) . . ?
C18 C17 H17 118.7 . . ?
C13 C18 Si04 127.9(2) . . ?
C17 C18 Si04 115.5(2) . . ?
C17 C18 C13 116.5(2) . . ?
Si04 C19 H19A 109.5 . . ?
Si04 C19 H19B 109.5 . . ?
Si04 C19 H19C 109.5 . . ?
H19A C19 H19B 109.5 . . ?
H19A C19 H19C 109.5 . . ?
H19B C19 H19C 109.5 . . ?
Si04 C20 H20A 109.5 . . ?
Si04 C20 H20B 109.5 . . ?
Si04 C20 H20C 109.5 . . ?
H20A C20 H20B 109.5 . . ?
H20A C20 H20C 109.5 . . ?
H20B C20 H20C 109.5 . . ?
Si04 C21 H21A 109.5 . . ?
Si04 C21 H21B 109.5 . . ?
Si04 C21 H21C 109.5 . . ?
H21A C21 H21B 109.5 . . ?
H21A C21 H21C 109.5 . . ?
H21B C21 H21C 109.5 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Sb1 F1 1.8839(16) . ?
Sb1 F1 1.8839(16) 2_776 ?
Sb1 F2 1.8804(18) . ?
Sb1 F2 1.8804(18) 2_776 ?
Sb1 F3 1.8775(16) . ?
Sb1 F3 1.8775(16) 2_776 ?
Ag1 P1 2.3936(6) . ?
Ag1 P1 2.3936(6) 2_665 ?
P1 C1 1.827(3) . ?
P1 C7 1.809(3) . ?
P1 C13 1.833(3) . ?
Si04 C18 1.900(3) . ?
Si04 C19 1.878(3) . ?
Si04 C20 1.866(3) . ?
Si04 C21 1.871(3) . ?
C1 C2 1.404(4) . ?
C1 C6 1.381(4) . ?
C2 H2 0.9500 . ?
C2 C3 1.386(4) . ?
C3 H3 0.9500 . ?
C3 C4 1.392(5) . ?
C4 H4 0.9500 . ?
C4 C5 1.385(5) . ?
C5 H5 0.9500 . ?
C5 C6 1.400(4) . ?
C6 H6 0.9500 . ?
C7 C8 1.394(4) . ?
C7 C12 1.396(4) . ?
C8 H8 0.9500 . ?
C8 C9 1.387(4) . ?
C9 H9 0.9500 . ?
C9 C10 1.375(4) . ?
C10 H10 0.9500 . ?
C10 C11 1.381(5) . ?
C11 H11 0.9500 . ?
C11 C12 1.375(5) . ?
C12 H12 0.9500 . ?
C13 C14 1.407(4) . ?
C13 C18 1.408(4) . ?
C14 H14 0.9500 . ?
C14 C15 1.391(4) . ?
C15 H15 0.9500 . ?
C15 C16 1.383(4) . ?
C16 H16 0.9500 . ?
C16 C17 1.387(4) . ?
C17 H17 0.9500 . ?
C17 C18 1.403(4) . ?
C19 H19A 0.9800 . ?
C19 H19B 0.9800 . ?
C19 H19C 0.9800 . ?
C20 H20A 0.9800 . ?
C20 H20B 0.9800 . ?
C20 H20C 0.9800 . ?
C21 H21A 0.9800 . ?
C21 H21B 0.9800 . ?
C21 H21C 0.9800 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Ag1 P1 C1 C2 -53.8(2) . . . . ?
Ag1 P1 C1 C6 124.0(2) . . . . ?
Ag1 P1 C7 C8 -20.4(3) . . . . ?
Ag1 P1 C7 C12 161.6(3) . . . . ?
Ag1 P1 C13 C14 141.17(17) . . . . ?
Ag1 P1 C13 C18 -43.2(3) . . . . ?
P1 C1 C2 C3 179.1(2) . . . . ?
P1 C1 C6 C5 -178.4(2) . . . . ?
P1 C7 C8 C9 -177.6(2) . . . . ?
P1 C7 C12 C11 177.5(4) . . . . ?
P1 C13 C14 C15 174.8(2) . . . . ?
P1 C13 C18 Si04 4.1(4) . . . . ?
P1 C13 C18 C17 -175.7(2) . . . . ?
C1 P1 C7 C8 88.5(2) . . . . ?
C1 P1 C7 C12 -89.5(3) . . . . ?
C1 P1 C13 C14 26.9(2) . . . . ?
C1 P1 C13 C18 -157.4(2) . . . . ?
C1 C2 C3 C4 -0.4(5) . . . . ?
C2 C1 C6 C5 -0.7(4) . . . . ?
C2 C3 C4 C5 -0.8(5) . . . . ?
C3 C4 C5 C6 1.3(5) . . . . ?
C4 C5 C6 C1 -0.5(4) . . . . ?
C6 C1 C2 C3 1.2(4) . . . . ?
C7 P1 C1 C2 -171.5(2) . . . . ?
C7 P1 C1 C6 6.3(3) . . . . ?
C7 P1 C13 C14 -85.0(2) . . . . ?
C7 P1 C13 C18 90.7(2) . . . . ?
C7 C8 C9 C10 -0.7(5) . . . . ?
C8 C7 C12 C11 -0.5(6) . . . . ?
C8 C9 C10 C11 0.8(5) . . . . ?
C9 C10 C11 C12 -0.8(7) . . . . ?
C10 C11 C12 C7 0.7(7) . . . . ?
C12 C7 C8 C9 0.5(5) . . . . ?
C13 P1 C1 C2 77.4(2) . . . . ?
C13 P1 C1 C6 -104.8(2) . . . . ?
C13 P1 C7 C8 -160.9(2) . . . . ?
C13 P1 C7 C12 21.1(3) . . . . ?
C13 C14 C15 C16 1.7(5) . . . . ?
C14 C13 C18 Si04 179.6(2) . . . . ?
C14 C13 C18 C17 -0.2(4) . . . . ?
C14 C15 C16 C17 -1.2(5) . . . . ?
C15 C16 C17 C18 -0.1(5) . . . . ?
C16 C17 C18 Si04 -179.0(2) . . . . ?
C16 C17 C18 C13 0.8(4) . . . . ?
C18 C13 C14 C15 -1.0(4) . . . . ?
C19 Si04 C18 C13 70.7(3) . . . . ?
C19 Si04 C18 C17 -109.5(2) . . . . ?
C20 Si04 C18 C13 -52.3(3) . . . . ?
C20 Si04 C18 C17 127.5(2) . . . . ?
C21 Si04 C18 C13 -172.0(2) . . . . ?
C21 Si04 C18 C17 7.7(2) . . . . ?
