#------------------------------------------------------------------------------
#$Date: 2023-09-26 01:50:13 +0300 (Tue, 26 Sep 2023) $
#$Revision: 286514 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/71/40/7714019.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7714019
loop_
_publ_author_name
'Ali, Asgar'
'Ahmed, Zubair'
'Rahisuddin, ?'
'Iftikhar, K.'
_publ_section_title
;
 Pure red-light emitting europium based complexes as efficient UV light
 converters: synthesis, crystal structure and photoluminescence
 properties.
;
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_paper_doi               10.1039/d3dt01536j
_journal_year                    2023
_chemical_formula_moiety         'C37 H36 Eu F21 N2 O6'
_chemical_formula_sum            'C37 H36 Eu F21 N2 O6'
_chemical_formula_weight         1155.64
_chemical_name_systematic        '[Eu(fod)3(bzi)]'
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_atom_sites_solution_hydrogens   mixed
_audit_creation_method           SHELXL-2018/3
_audit_update_record
;
2023-03-24 deposited with the CCDC.	2023-08-23 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 111.345(6)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   15.521(2)
_cell_length_b                   17.684(3)
_cell_length_c                   18.449(3)
_cell_measurement_reflns_used    9731
_cell_measurement_temperature    200(2)
_cell_measurement_theta_max      70.56
_cell_measurement_theta_min      2.57
_cell_volume                     4716.4(13)
_computing_cell_refinement       'APEX3/SAINT (Bruker, 2016)'
_computing_data_collection       'APEX3 (Bruker, 2016)'
_computing_data_reduction        'SAINT/XPREP (Bruker, 2016)'
_computing_molecular_graphics
'ORTEP3 (Farrugia, 1997) and Mercury (Bruno et al., 2002)'
_computing_publication_material  'SHELXL-2018/3 (Sheldrick, 2018)'
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018)'
_computing_structure_solution    'SHELXT-2018/2 (Sheldrick, 2018)'
_diffrn_ambient_temperature      200(2)
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.990
_diffrn_measurement_device_type
'Bruker D8 VENTURE diffractometer with PHOTON II detector'
_diffrn_measurement_method       'ω and φ scan'
_diffrn_radiation_source         'micro-focus sealed tube'
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54178
_diffrn_reflns_av_R_equivalents  0.0919
_diffrn_reflns_av_unetI/netI     0.0452
_diffrn_reflns_Laue_measured_fraction_full 0.996
_diffrn_reflns_Laue_measured_fraction_max 0.990
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_k_max       21
_diffrn_reflns_limit_k_min       -21
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_number            95947
_diffrn_reflns_point_group_measured_fraction_full 0.996
_diffrn_reflns_point_group_measured_fraction_max 0.990
_diffrn_reflns_theta_full        67.679
_diffrn_reflns_theta_max         70.831
_diffrn_reflns_theta_min         3.950
_exptl_absorpt_coefficient_mu    10.685
_exptl_absorpt_correction_T_max  0.7536
_exptl_absorpt_correction_T_min  0.3866
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS (Bruker, 2016)'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.628
_exptl_crystal_description       block
_exptl_crystal_F_000             2288
_exptl_crystal_recrystallization_method 'Re-crystallisation from solvent'
_exptl_crystal_size_max          0.150
_exptl_crystal_size_mid          0.120
_exptl_crystal_size_min          0.080
_refine_diff_density_max         1.167
_refine_diff_density_min         -0.901
_refine_diff_density_rms         0.098
_refine_ls_extinction_coef       0.0049(3)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     'SHELXL-2018/3 (Sheldrick 2018)'
_refine_ls_goodness_of_fit_ref   1.119
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     679
_refine_ls_number_reflns         9001
_refine_ls_number_restraints     271
_refine_ls_restrained_S_all      1.121
_refine_ls_R_factor_all          0.0714
_refine_ls_R_factor_gt           0.0620
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.1220P)²+2.0012P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1751
_refine_ls_wR_factor_ref         0.1855
_reflns_Friedel_coverage         0.000
_reflns_number_gt                7524
_reflns_number_total             9001
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d3dt01536j2.cif
_cod_data_source_block           shelx
_cod_original_cell_volume        4716.3(12)
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               7714019
_shelx_shelxl_version_number     2018/3
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.297
_shelx_estimated_absorpt_t_max   0.482
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.33045(2) 0.35698(2) 0.34226(2) 0.04788(17) Uani 1 1 d . . . . .
C1 C 0.3668(4) 0.4554(3) 0.5189(3) 0.0535(11) Uani 1 1 d . . . . .
C2 C 0.2761(4) 0.4808(3) 0.5006(3) 0.0636(13) Uani 1 1 d . . . . .
H2 H 0.227811 0.465555 0.454060 0.076 Uiso 1 1 calc R U . . .
C3 C 0.2596(5) 0.5291(4) 0.5530(4) 0.0756(16) Uani 1 1 d . . . . .
H3 H 0.198527 0.547248 0.542121 0.091 Uiso 1 1 calc R U . . .
C4 C 0.3300(5) 0.5519(4) 0.6214(4) 0.0769(17) Uani 1 1 d . . . . .
H4 H 0.315764 0.585394 0.655807 0.092 Uiso 1 1 calc R U . . .
C5 C 0.4194(5) 0.5271(4) 0.6402(4) 0.0694(15) Uani 1 1 d . . . . .
H5 H 0.467282 0.542307 0.686953 0.083 Uiso 1 1 calc R U . . .
C6 C 0.4365(4) 0.4788(3) 0.5876(3) 0.0550(12) Uani 1 1 d . . . . .
C7 C 0.4942(4) 0.4061(3) 0.5197(3) 0.0525(11) Uani 1 1 d . . . . .
H7 H 0.538026 0.378859 0.505019 0.063 Uiso 1 1 calc R U . . .
C8 C 0.1369(7) 0.6352(5) 0.3243(7) 0.101(3) Uani 1 1 d . . . . .
C9 C 0.2315(6) 0.6489(3) 0.3229(5) 0.081(2) Uani 1 1 d . . . . .
C10 C 0.2540(4) 0.6078(3) 0.2582(4) 0.0668(14) Uani 1 1 d . . . . .
C11 C 0.2431(4) 0.5218(3) 0.2551(3) 0.0563(12) Uani 1 1 d . . . . .
C12 C 0.1698(4) 0.4929(3) 0.1968(3) 0.0667(14) Uani 1 1 d . . . . .
H12 H 0.132142 0.526867 0.158445 0.080 Uiso 1 1 calc R U . . .
C13 C 0.1451(4) 0.4146(3) 0.1888(3) 0.0561(12) Uani 1 1 d . . . . .
C14 C 0.0585(4) 0.3905(4) 0.1203(3) 0.0691(15) Uani 1 1 d . . . . .
C15 C 0.0452(6) 0.3053(4) 0.1222(4) 0.089(2) Uani 1 1 d . . . . .
H15A H 0.101364 0.279535 0.122770 0.134 Uiso 1 1 calc R U . . .
H15B H -0.007268 0.289785 0.075995 0.134 Uiso 1 1 calc R U . . .
H15C H 0.033059 0.291772 0.169104 0.134 Uiso 1 1 calc R U . . .
C16 C -0.0250(5) 0.4325(5) 0.1260(5) 0.094(2) Uani 1 1 d . . . . .
H16A H -0.025736 0.426746 0.178627 0.140 Uiso 1 1 calc R U . . .
H16B H -0.082039 0.411300 0.088182 0.140 Uiso 1 1 calc R U . . .
H16C H -0.020833 0.486249 0.114886 0.140 Uiso 1 1 calc R U . . .
C17 C 0.0730(6) 0.4133(4) 0.0452(4) 0.087(2) Uani 1 1 d . . . . .
H17A H 0.073113 0.468527 0.041248 0.131 Uiso 1 1 calc R U . . .
H17B H 0.022898 0.392443 0.000224 0.131 Uiso 1 1 calc R U . . .
H17C H 0.132430 0.393346 0.046327 0.131 Uiso 1 1 calc R U . . .
C18 C -0.0628(9) 0.3549(7) 0.3952(9) 0.119(4) Uani 1 1 d . . . . .
C19 C 0.0173(5) 0.3394(5) 0.3692(5) 0.0813(19) Uani 1 1 d . . . . .
C20 C 0.0914(5) 0.2834(4) 0.4160(4) 0.0763(17) Uani 1 1 d . . . . .
C21 C 0.1669(4) 0.2700(4) 0.3840(3) 0.0655(14) Uani 1 1 d . . . . .
C22 C 0.1665(5) 0.2031(4) 0.3457(5) 0.0777(17) Uani 1 1 d . . . . .
H22 H 0.118739 0.167462 0.340316 0.093 Uiso 1 1 calc R U . . .
C23 C 0.2343(5) 0.1856(4) 0.3143(4) 0.0760(17) Uani 1 1 d . . . . .
C24 C 0.2315(6) 0.1086(4) 0.2752(6) 0.109(3) Uani 1 1 d D U . . .
C25 C 0.1799(14) 0.0474(8) 0.3089(13) 0.129(6) Uani 0.536(14) 1 d D U P A 1
H25A H 0.113154 0.057279 0.287899 0.194 Uiso 0.536(14) 1 calc R U P A 1
H25B H 0.202949 0.050959 0.365766 0.194 Uiso 0.536(14) 1 calc R U P A 1
H25C H 0.191865 -0.003378 0.293551 0.194 Uiso 0.536(14) 1 calc R U P A 1
C26 C 0.1852(16) 0.1130(11) 0.1931(9) 0.136(7) Uani 0.536(14) 1 d D U P A 1
H26A H 0.212548 0.153481 0.172254 0.204 Uiso 0.536(14) 1 calc R U P A 1
H26B H 0.119445 0.123708 0.181002 0.204 Uiso 0.536(14) 1 calc R U P A 1
H26C H 0.191542 0.064707 0.169394 0.204 Uiso 0.536(14) 1 calc R U P A 1
C27 C 0.3294(10) 0.0793(9) 0.3021(12) 0.125(7) Uani 0.536(14) 1 d D U P A 1
H27A H 0.329646 0.028479 0.280921 0.188 Uiso 0.536(14) 1 calc R U P A 1
H27B H 0.355093 0.077155 0.359069 0.188 Uiso 0.536(14) 1 calc R U P A 1
H27C H 0.367156 0.113141 0.283736 0.188 Uiso 0.536(14) 1 calc R U P A 1
C25' C 0.1310(11) 0.0886(13) 0.2218(14) 0.132(8) Uani 0.464(14) 1 d D U P A 2
H25D H 0.132333 0.055285 0.179732 0.198 Uiso 0.464(14) 1 calc R U P A 2
H25E H 0.097395 0.135075 0.199458 0.198 Uiso 0.464(14) 1 calc R U P A 2
H25F H 0.099774 0.062800 0.252355 0.198 Uiso 0.464(14) 1 calc R U P A 2
C26' C 0.2795(18) 0.1221(12) 0.2145(14) 0.147(9) Uani 0.464(14) 1 d D U P A 2
H26D H 0.344059 0.136955 0.241948 0.221 Uiso 0.464(14) 1 calc R U P A 2
H26E H 0.246930 0.162268 0.178391 0.221 Uiso 0.464(14) 1 calc R U P A 2
H26F H 0.277423 0.075306 0.185399 0.221 Uiso 0.464(14) 1 calc R U P A 2
C27' C 0.2744(19) 0.0496(12) 0.3271(14) 0.159(10) Uani 0.464(14) 1 d D U P A 2
H27D H 0.341700 0.054020 0.343207 0.239 Uiso 0.464(14) 1 calc R U P A 2
H27E H 0.254299 0.000781 0.301269 0.239 Uiso 0.464(14) 1 calc R U P A 2
H27F H 0.256927 0.052800 0.373025 0.239 Uiso 0.464(14) 1 calc R U P A 2
C28 C 0.6843(10) 0.1177(7) 0.4838(7) 0.127(4) Uani 1 1 d . . . . .
C29 C 0.5994(6) 0.1567(4) 0.4239(5) 0.086(2) Uani 1 1 d . . . . .
C30 C 0.6173(5) 0.2400(4) 0.4076(4) 0.0742(17) Uani 1 1 d . . . . .
C31 C 0.5297(4) 0.2792(3) 0.3517(3) 0.0635(13) Uani 1 1 d . . . . .
C32 C 0.5143(5) 0.2792(4) 0.2742(4) 0.0714(15) Uani 1 1 d . . . . .
H32 H 0.555309 0.251699 0.256338 0.086 Uiso 1 1 calc R U . . .
C33 C 0.4392(4) 0.3190(3) 0.2188(3) 0.0626(13) Uani 1 1 d . . . . .
C34 C 0.4306(5) 0.3230(4) 0.1330(4) 0.0817(19) Uani 1 1 d D U . . .
C35 C 0.3472(17) 0.2685(17) 0.0947(15) 0.122(9) Uani 0.288(13) 1 d D U P B 3
H35A H 0.299160 0.278418 0.116303 0.183 Uiso 0.288(13) 1 calc R U P B 3
H35B H 0.368148 0.215984 0.105476 0.183 Uiso 0.288(13) 1 calc R U P B 3
H35C H 0.321794 0.276833 0.038336 0.183 Uiso 0.288(13) 1 calc R U P B 3
C36 C 0.5133(16) 0.2861(17) 0.1216(18) 0.109(8) Uani 0.288(13) 1 d D U P B 3
H36A H 0.506564 0.289957 0.066804 0.164 Uiso 0.288(13) 1 calc R U P B 3
H36B H 0.516542 0.232691 0.136570 0.164 Uiso 0.288(13) 1 calc R U P B 3
H36C H 0.570197 0.311840 0.154100 0.164 Uiso 0.288(13) 1 calc R U P B 3
C37 C 0.410(2) 0.3983(10) 0.1022(16) 0.108(8) Uani 0.288(13) 1 d D U P B 3
H37A H 0.462609 0.431568 0.129005 0.162 Uiso 0.288(13) 1 calc R U P B 3
H37B H 0.354835 0.417030 0.110105 0.162 Uiso 0.288(13) 1 calc R U P B 3
H37C H 0.399140 0.397621 0.046386 0.162 Uiso 0.288(13) 1 calc R U P B 3
C35' C 0.3343(9) 0.3489(8) 0.0825(7) 0.113(5) Uani 0.712(13) 1 d D U P B 4
H35D H 0.330343 0.353317 0.028383 0.169 Uiso 0.712(13) 1 calc R U P B 4
H35E H 0.321656 0.398160 0.100759 0.169 Uiso 0.712(13) 1 calc R U P B 4
H35F H 0.288786 0.311910 0.085578 0.169 Uiso 0.712(13) 1 calc R U P B 4
C36' C 0.4608(11) 0.2546(7) 0.1040(7) 0.114(5) Uani 0.712(13) 1 d D U P B 4
H36D H 0.424528 0.211267 0.109852 0.171 Uiso 0.712(13) 1 calc R U P B 4
H36E H 0.526504 0.245688 0.133925 0.171 Uiso 0.712(13) 1 calc R U P B 4
H36F H 0.451464 0.261262 0.048945 0.171 Uiso 0.712(13) 1 calc R U P B 4
C37' C 0.4960(11) 0.3910(8) 0.1298(8) 0.119(5) Uani 0.712(13) 1 d D U P B 4
H37D H 0.560401 0.378168 0.160725 0.178 Uiso 0.712(13) 1 calc R U P B 4
H37E H 0.478277 0.436706 0.150918 0.178 Uiso 0.712(13) 1 calc R U P B 4
H37F H 0.489760 0.399986 0.075665 0.178 Uiso 0.712(13) 1 calc R U P B 4
N1 N 0.4049(3) 0.4092(2) 0.4764(2) 0.0518(9) Uani 1 1 d . . . . .
O1 O 0.3046(2) 0.48745(18) 0.3124(2) 0.0515(7) Uani 1 1 d . . . . .
O2 O 0.1898(3) 0.36605(19) 0.2359(2) 0.0578(9) Uani 1 1 d . . . . .
O3 O 0.2244(3) 0.3242(2) 0.3973(2) 0.0617(9) Uani 1 1 d . . . . .
O4 O 0.2985(3) 0.2296(2) 0.3173(3) 0.0688(10) Uani 1 1 d . . . . .
O5 O 0.3812(3) 0.3549(2) 0.2374(2) 0.0616(10) Uani 1 1 d . . . . .
O6 O 0.4793(3) 0.3072(2) 0.3863(2) 0.0606(9) Uani 1 1 d . . . . .
F1 F 0.1247(3) 0.5646(3) 0.3409(3) 0.1034(13) Uani 1 1 d . . . . .
F2 F 0.1250(5) 0.6777(4) 0.3805(5) 0.169(3) Uani 1 1 d . . . . .
F3 F 0.0712(4) 0.6517(4) 0.2571(5) 0.146(3) Uani 1 1 d . . . . .
F4 F 0.2425(4) 0.7236(2) 0.3156(3) 0.1200(17) Uani 1 1 d . . . . .
F5 F 0.2932(3) 0.6273(2) 0.3925(3) 0.0859(11) Uani 1 1 d . . . . .
F6 F 0.2037(4) 0.64067(19) 0.1898(3) 0.0924(14) Uani 1 1 d . . . . .
F7 F 0.3440(3) 0.6256(2) 0.2712(3) 0.0790(10) Uani 1 1 d . . . . .
F8 F -0.0356(8) 0.3784(9) 0.4640(7) 0.254(7) Uani 1 1 d . . . . .
F9 F -0.1079(6) 0.2952(6) 0.3955(9) 0.230(5) Uani 1 1 d . . . . .
F10 F -0.1202(5) 0.4037(5) 0.3526(5) 0.165(3) Uani 1 1 d . . . . .
F11 F -0.0203(4) 0.3130(4) 0.2972(3) 0.1276(19) Uani 1 1 d . . . . .
F12 F 0.0551(4) 0.4050(3) 0.3645(5) 0.148(3) Uani 1 1 d . . . . .
F13 F 0.0455(3) 0.2193(3) 0.4192(3) 0.1134(16) Uani 1 1 d . . . . .
F14 F 0.1292(3) 0.3090(4) 0.4902(3) 0.1187(18) Uani 1 1 d . . . . .
F15 F 0.6857(3) 0.2401(3) 0.3790(3) 0.0937(12) Uani 1 1 d . . . . .
F16 F 0.6485(3) 0.2756(3) 0.4760(2) 0.0939(13) Uani 1 1 d . . . . .
F17 F 0.5740(4) 0.1189(3) 0.3569(3) 0.1089(15) Uani 1 1 d . . . . .
F18 F 0.5290(4) 0.1534(3) 0.4490(3) 0.1103(16) Uani 1 1 d . . . . .
F19 F 0.7082(8) 0.1445(4) 0.5503(4) 0.193(5) Uani 1 1 d . . . . .
F20 F 0.6588(7) 0.0457(4) 0.4908(5) 0.187(4) Uani 1 1 d . . . . .
F21 F 0.7497(7) 0.1114(7) 0.4591(6) 0.215(5) Uani 1 1 d . . . . .
N2 N 0.5165(3) 0.4452(3) 0.5865(3) 0.0568(10) Uani 1 1 d D . . . .
H2A H 0.5746(18) 0.447(4) 0.617(3) 0.068 Uiso 1 1 d D U . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0727 0.0534 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -8.9294 11.1857 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O3 Eu1 O4 72.94(14) . . ?
O3 Eu1 O6 122.01(14) . . ?
O4 Eu1 O6 79.34(15) . . ?
O3 Eu1 O5 150.59(15) . . ?
O4 Eu1 O5 86.14(14) . . ?
O6 Eu1 O5 72.08(14) . . ?
O3 Eu1 O2 77.82(14) . . ?
O4 Eu1 O2 80.42(15) . . ?
O6 Eu1 O2 145.12(13) . . ?
O5 Eu1 O2 78.50(15) . . ?
O3 Eu1 O1 105.07(13) . . ?
O4 Eu1 O1 153.36(16) . . ?
O6 Eu1 O1 120.78(13) . . ?
O5 Eu1 O1 84.39(12) . . ?
O2 Eu1 O1 73.31(12) . . ?
O3 Eu1 N1 78.64(14) . . ?
O4 Eu1 N1 123.04(15) . . ?
O6 Eu1 N1 75.61(13) . . ?
O5 Eu1 N1 130.70(15) . . ?
O2 Eu1 N1 139.16(13) . . ?
O1 Eu1 N1 81.28(13) . . ?
C6 C1 C2 120.2(5) . . ?
C6 C1 N1 109.6(5) . . ?
C2 C1 N1 130.1(5) . . ?
C3 C2 C1 117.2(5) . . ?
C3 C2 H2 121.4 . . ?
C1 C2 H2 121.4 . . ?
C2 C3 C4 121.9(6) . . ?
C2 C3 H3 119.0 . . ?
C4 C3 H3 119.0 . . ?
C5 C4 C3 121.4(6) . . ?
C5 C4 H4 119.3 . . ?
C3 C4 H4 119.3 . . ?
C4 C5 C6 116.9(6) . . ?
C4 C5 H5 121.5 . . ?
C6 C5 H5 121.5 . . ?
N2 C6 C5 132.5(5) . . ?
N2 C6 C1 105.1(4) . . ?
C5 C6 C1 122.4(5) . . ?
N1 C7 N2 113.3(5) . . ?
N1 C7 H7 123.4 . . ?
N2 C7 H7 123.4 . . ?
F1 C8 F3 107.5(8) . . ?
F1 C8 F2 106.1(10) . . ?
F3 C8 F2 108.9(7) . . ?
F1 C8 C9 112.5(6) . . ?
F3 C8 C9 112.1(10) . . ?
F2 C8 C9 109.5(8) . . ?
F4 C9 F5 107.6(6) . . ?
F4 C9 C8 108.7(6) . . ?
F5 C9 C8 107.4(8) . . ?
F4 C9 C10 108.2(7) . . ?
F5 C9 C10 108.7(5) . . ?
C8 C9 C10 115.9(7) . . ?
F6 C10 F7 105.7(5) . . ?
F6 C10 C11 111.9(5) . . ?
F7 C10 C11 109.1(5) . . ?
F6 C10 C9 107.7(5) . . ?
F7 C10 C9 105.1(5) . . ?
C11 C10 C9 116.5(5) . . ?
O1 C11 C12 129.3(5) . . ?
O1 C11 C10 113.4(5) . . ?
C12 C11 C10 117.2(5) . . ?
C11 C12 C13 124.4(5) . . ?
C11 C12 H12 117.8 . . ?
C13 C12 H12 117.8 . . ?
O2 C13 C12 122.5(5) . . ?
O2 C13 C14 119.0(5) . . ?
C12 C13 C14 118.5(5) . . ?
C15 C14 C16 110.7(6) . . ?
C15 C14 C13 110.0(5) . . ?
C16 C14 C13 108.6(5) . . ?
C15 C14 C17 110.2(6) . . ?
C16 C14 C17 110.0(6) . . ?
C13 C14 C17 107.3(6) . . ?
C14 C15 H15A 109.5 . . ?
C14 C15 H15B 109.5 . . ?
H15A C15 H15B 109.5 . . ?
C14 C15 H15C 109.5 . . ?
H15A C15 H15C 109.5 . . ?
H15B C15 H15C 109.5 . . ?
C14 C16 H16A 109.5 . . ?
C14 C16 H16B 109.5 . . ?
H16A C16 H16B 109.5 . . ?
C14 C16 H16C 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
C14 C17 H17A 109.5 . . ?
C14 C17 H17B 109.5 . . ?
H17A C17 H17B 109.5 . . ?
C14 C17 H17C 109.5 . . ?
H17A C17 H17C 109.5 . . ?
H17B C17 H17C 109.5 . . ?
F8 C18 F9 104.8(13) . . ?
F8 C18 F10 107.5(11) . . ?
F9 C18 F10 107.5(12) . . ?
F8 C18 C19 111.6(11) . . ?
F9 C18 C19 111.7(10) . . ?
F10 C18 C19 113.3(10) . . ?
F12 C19 F11 106.8(8) . . ?
F12 C19 C18 107.3(8) . . ?
F11 C19 C18 105.5(8) . . ?
F12 C19 C20 110.4(6) . . ?
F11 C19 C20 107.8(6) . . ?
C18 C19 C20 118.4(8) . . ?
F13 C20 F14 106.1(6) . . ?
F13 C20 C21 112.5(6) . . ?
F14 C20 C21 109.6(6) . . ?
F13 C20 C19 105.6(6) . . ?
F14 C20 C19 108.3(6) . . ?
C21 C20 C19 114.3(6) . . ?
O3 C21 C22 128.3(6) . . ?
O3 C21 C20 113.4(5) . . ?
C22 C21 C20 118.4(6) . . ?
C21 C22 C23 122.3(6) . . ?
C21 C22 H22 118.8 . . ?
C23 C22 H22 118.8 . . ?
O4 C23 C22 123.3(6) . . ?
O4 C23 C24 117.3(6) . . ?
C22 C23 C24 119.4(6) . . ?
C26 C24 C27 115.3(11) . . ?
C27' C24 C23 114.3(13) . . ?
C26 C24 C23 111.7(10) . . ?
C27 C24 C23 107.3(8) . . ?
C27' C24 C25' 112.3(11) . . ?
C23 C24 C25' 110.5(9) . . ?
C27' C24 C26' 111.6(11) . . ?
C23 C24 C26' 105.1(9) . . ?
C25' C24 C26' 102.1(10) . . ?
C26 C24 C25 108.6(10) . . ?
C27 C24 C25 103.1(9) . . ?
C23 C24 C25 110.5(9) . . ?
C24 C25 H25A 109.5 . . ?
C24 C25 H25B 109.5 . . ?
H25A C25 H25B 109.5 . . ?
C24 C25 H25C 109.5 . . ?
H25A C25 H25C 109.5 . . ?
H25B C25 H25C 109.5 . . ?
C24 C26 H26A 109.5 . . ?
C24 C26 H26B 109.5 . . ?
H26A C26 H26B 109.5 . . ?
C24 C26 H26C 109.5 . . ?
H26A C26 H26C 109.5 . . ?
H26B C26 H26C 109.5 . . ?
C24 C27 H27A 109.5 . . ?
C24 C27 H27B 109.5 . . ?
H27A C27 H27B 109.5 . . ?
C24 C27 H27C 109.5 . . ?
H27A C27 H27C 109.5 . . ?
H27B C27 H27C 109.5 . . ?
C24 C25' H25D 109.5 . . ?
C24 C25' H25E 109.5 . . ?
H25D C25' H25E 109.5 . . ?
C24 C25' H25F 109.5 . . ?
H25D C25' H25F 109.5 . . ?
H25E C25' H25F 109.5 . . ?
C24 C26' H26D 109.5 . . ?
C24 C26' H26E 109.5 . . ?
H26D C26' H26E 109.5 . . ?
C24 C26' H26F 109.5 . . ?
H26D C26' H26F 109.5 . . ?
H26E C26' H26F 109.5 . . ?
C24 C27' H27D 109.5 . . ?
C24 C27' H27E 109.5 . . ?
H27D C27' H27E 109.5 . . ?
C24 C27' H27F 109.5 . . ?
H27D C27' H27F 109.5 . . ?
H27E C27' H27F 109.5 . . ?
F19 C28 F21 113.7(15) . . ?
F19 C28 F20 104.9(11) . . ?
F21 C28 F20 104.6(10) . . ?
F19 C28 C29 114.1(9) . . ?
F21 C28 C29 111.8(10) . . ?
F20 C28 C29 106.7(11) . . ?
F17 C29 F18 107.3(8) . . ?
F17 C29 C28 109.2(7) . . ?
F18 C29 C28 109.1(8) . . ?
F17 C29 C30 108.1(6) . . ?
F18 C29 C30 109.6(6) . . ?
C28 C29 C30 113.5(9) . . ?
F16 C30 F15 107.7(6) . . ?
F16 C30 C31 110.4(5) . . ?
F15 C30 C31 111.5(6) . . ?
F16 C30 C29 107.1(6) . . ?
F15 C30 C29 107.4(5) . . ?
C31 C30 C29 112.5(6) . . ?
O6 C31 C32 128.4(6) . . ?
O6 C31 C30 113.1(5) . . ?
C32 C31 C30 118.5(5) . . ?
C31 C32 C33 122.5(5) . . ?
C31 C32 H32 118.7 . . ?
C33 C32 H32 118.7 . . ?
O5 C33 C32 122.6(5) . . ?
O5 C33 C34 117.2(5) . . ?
C32 C33 C34 120.1(5) . . ?
C36' C34 C35' 113.5(8) . . ?
C37 C34 C36 114.8(12) . . ?
C37 C34 C33 111.9(12) . . ?
C36' C34 C33 114.6(7) . . ?
C35' C34 C33 110.1(7) . . ?
C36 C34 C33 111.1(12) . . ?
C37 C34 C35 111.5(12) . . ?
C36 C34 C35 106.0(11) . . ?
C33 C34 C35 100.6(11) . . ?
C36' C34 C37' 108.5(8) . . ?
C35' C34 C37' 104.4(8) . . ?
C33 C34 C37' 104.8(6) . . ?
C34 C35 H35A 109.5 . . ?
C34 C35 H35B 109.5 . . ?
H35A C35 H35B 109.5 . . ?
C34 C35 H35C 109.5 . . ?
H35A C35 H35C 109.5 . . ?
H35B C35 H35C 109.5 . . ?
C34 C36 H36A 109.5 . . ?
C34 C36 H36B 109.5 . . ?
H36A C36 H36B 109.5 . . ?
C34 C36 H36C 109.5 . . ?
H36A C36 H36C 109.5 . . ?
H36B C36 H36C 109.5 . . ?
C34 C37 H37A 109.5 . . ?
C34 C37 H37B 109.5 . . ?
H37A C37 H37B 109.5 . . ?
C34 C37 H37C 109.5 . . ?
H37A C37 H37C 109.5 . . ?
H37B C37 H37C 109.5 . . ?
C34 C35' H35D 109.5 . . ?
C34 C35' H35E 109.5 . . ?
H35D C35' H35E 109.5 . . ?
C34 C35' H35F 109.5 . . ?
H35D C35' H35F 109.5 . . ?
H35E C35' H35F 109.5 . . ?
C34 C36' H36D 109.5 . . ?
C34 C36' H36E 109.5 . . ?
H36D C36' H36E 109.5 . . ?
C34 C36' H36F 109.5 . . ?
H36D C36' H36F 109.5 . . ?
H36E C36' H36F 109.5 . . ?
C34 C37' H37D 109.5 . . ?
C34 C37' H37E 109.5 . . ?
H37D C37' H37E 109.5 . . ?
C34 C37' H37F 109.5 . . ?
H37D C37' H37F 109.5 . . ?
H37E C37' H37F 109.5 . . ?
C7 N1 C1 104.4(4) . . ?
C7 N1 Eu1 125.9(3) . . ?
C1 N1 Eu1 129.2(3) . . ?
C11 O1 Eu1 131.3(3) . . ?
C13 O2 Eu1 138.2(3) . . ?
C21 O3 Eu1 132.0(4) . . ?
C23 O4 Eu1 136.4(4) . . ?
C33 O5 Eu1 136.7(4) . . ?
C31 O6 Eu1 133.2(4) . . ?
C7 N2 C6 107.5(4) . . ?
C7 N2 H2A 118(4) . . ?
C6 N2 H2A 134(4) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O3 2.300(4) . ?
Eu1 O4 2.317(4) . ?
Eu1 O6 2.325(4) . ?
Eu1 O5 2.340(4) . ?
Eu1 O2 2.350(4) . ?
Eu1 O1 2.372(3) . ?
Eu1 N1 2.497(4) . ?
C1 C6 1.396(8) . ?
C1 C2 1.398(8) . ?
C1 N1 1.402(6) . ?
C2 C3 1.382(8) . ?
C2 H2 0.9500 . ?
C3 C4 1.395(10) . ?
C3 H3 0.9500 . ?
C4 C5 1.374(10) . ?
C4 H4 0.9500 . ?
C5 C6 1.388(8) . ?
C5 H5 0.9500 . ?
C6 N2 1.384(7) . ?
C7 N1 1.325(6) . ?
C7 N2 1.343(7) . ?
C7 H7 0.9500 . ?
C8 F1 1.317(10) . ?
C8 F3 1.319(12) . ?
C8 F2 1.347(12) . ?
C8 C9 1.496(13) . ?
C9 F4 1.344(7) . ?
C9 F5 1.348(9) . ?
C9 C10 1.542(11) . ?
C10 F6 1.351(7) . ?
C10 F7 1.366(7) . ?
C10 C11 1.530(8) . ?
C11 O1 1.290(6) . ?
C11 C12 1.349(8) . ?
C12 C13 1.429(8) . ?
C12 H12 0.9500 . ?
C13 O2 1.240(6) . ?
C13 C14 1.533(8) . ?
C14 C15 1.523(10) . ?
C14 C16 1.530(10) . ?
C14 C17 1.536(10) . ?
C15 H15A 0.9800 . ?
C15 H15B 0.9800 . ?
C15 H15C 0.9800 . ?
C16 H16A 0.9800 . ?
C16 H16B 0.9800 . ?
C16 H16C 0.9800 . ?
C17 H17A 0.9800 . ?
C17 H17B 0.9800 . ?
C17 H17C 0.9800 . ?
C18 F8 1.253(16) . ?
C18 F9 1.268(13) . ?
C18 F10 1.283(14) . ?
C18 C19 1.513(13) . ?
C19 F12 1.317(9) . ?
C19 F11 1.326(10) . ?
C19 C20 1.525(11) . ?
C20 F13 1.351(8) . ?
C20 F14 1.356(8) . ?
C20 C21 1.512(9) . ?
C21 O3 1.271(7) . ?
C21 C22 1.376(9) . ?
C22 C23 1.408(10) . ?
C22 H22 0.9500 . ?
C23 O4 1.249(8) . ?
C23 C24 1.534(10) . ?
C24 C27' 1.410(15) . ?
C24 C26 1.423(14) . ?
C24 C27 1.509(13) . ?
C24 C25' 1.553(14) . ?
C24 C26' 1.572(16) . ?
C24 C25 1.600(14) . ?
C25 H25A 0.9800 . ?
C25 H25B 0.9800 . ?
C25 H25C 0.9800 . ?
C26 H26A 0.9800 . ?
C26 H26B 0.9800 . ?
C26 H26C 0.9800 . ?
C27 H27A 0.9800 . ?
C27 H27B 0.9800 . ?
C27 H27C 0.9800 . ?
C25' H25D 0.9800 . ?
C25' H25E 0.9800 . ?
C25' H25F 0.9800 . ?
C26' H26D 0.9800 . ?
C26' H26E 0.9800 . ?
C26' H26F 0.9800 . ?
C27' H27D 0.9800 . ?
C27' H27E 0.9800 . ?
C27' H27F 0.9800 . ?
C28 F19 1.240(13) . ?
C28 F21 1.260(15) . ?
C28 F20 1.353(15) . ?
C28 C29 1.539(13) . ?
C29 F17 1.333(9) . ?
C29 F18 1.334(10) . ?
C29 C30 1.549(11) . ?
C30 F16 1.333(7) . ?
C30 F15 1.347(8) . ?
C30 C31 1.540(9) . ?
C31 O6 1.275(6) . ?
C31 C32 1.361(8) . ?
C32 C33 1.424(9) . ?
C32 H32 0.9500 . ?
C33 O5 1.248(7) . ?
C33 C34 1.542(8) . ?
C34 C37 1.437(15) . ?
C34 C36' 1.466(11) . ?
C34 C35' 1.515(12) . ?
C34 C36 1.522(16) . ?
C34 C35 1.562(16) . ?
C34 C37' 1.588(12) . ?
C35 H35A 0.9800 . ?
C35 H35B 0.9800 . ?
C35 H35C 0.9800 . ?
C36 H36A 0.9800 . ?
C36 H36B 0.9800 . ?
C36 H36C 0.9800 . ?
C37 H37A 0.9800 . ?
C37 H37B 0.9800 . ?
C37 H37C 0.9800 . ?
C35' H35D 0.9800 . ?
C35' H35E 0.9800 . ?
C35' H35F 0.9800 . ?
C36' H36D 0.9800 . ?
C36' H36E 0.9800 . ?
C36' H36F 0.9800 . ?
C37' H37D 0.9800 . ?
C37' H37E 0.9800 . ?
C37' H37F 0.9800 . ?
N2 H2A 0.87(2) . ?
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
_geom_hbond_publ_flag
C7 H7 O6 0.95 2.40 2.959(6) 117.0 . yes
C7 H7 F5 0.95 2.62 3.158(7) 116.6 3_666 yes
N2 H2A O1 0.87(2) 2.19(4) 2.972(6) 149(6) 3_666 yes
N2 H2A F5 0.87(2) 2.49(5) 3.112(6) 128(5) 3_666 yes
N2 H2A F7 0.87(2) 2.36(5) 3.001(6) 130(5) 3_666 yes
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C6 C1 C2 C3 0.0(8) . . . . ?
N1 C1 C2 C3 -177.2(6) . . . . ?
C1 C2 C3 C4 0.1(10) . . . . ?
C2 C3 C4 C5 -0.3(11) . . . . ?
C3 C4 C5 C6 0.5(10) . . . . ?
C4 C5 C6 N2 177.9(6) . . . . ?
C4 C5 C6 C1 -0.5(9) . . . . ?
C2 C1 C6 N2 -178.5(5) . . . . ?
N1 C1 C6 N2 -0.8(6) . . . . ?
C2 C1 C6 C5 0.2(8) . . . . ?
N1 C1 C6 C5 178.0(5) . . . . ?
F1 C8 C9 F4 -172.1(8) . . . . ?
F3 C8 C9 F4 66.5(9) . . . . ?
F2 C8 C9 F4 -54.4(11) . . . . ?
F1 C8 C9 F5 -56.0(10) . . . . ?
F3 C8 C9 F5 -177.3(6) . . . . ?
F2 C8 C9 F5 61.7(9) . . . . ?
F1 C8 C9 C10 65.8(11) . . . . ?
F3 C8 C9 C10 -55.6(9) . . . . ?
F2 C8 C9 C10 -176.5(7) . . . . ?
F4 C9 C10 F6 -51.7(7) . . . . ?
F5 C9 C10 F6 -168.3(5) . . . . ?
C8 C9 C10 F6 70.6(8) . . . . ?
F4 C9 C10 F7 60.7(7) . . . . ?
F5 C9 C10 F7 -55.9(6) . . . . ?
C8 C9 C10 F7 -176.9(6) . . . . ?
F4 C9 C10 C11 -178.4(6) . . . . ?
F5 C9 C10 C11 65.0(7) . . . . ?
C8 C9 C10 C11 -56.0(8) . . . . ?
F6 C10 C11 O1 165.5(5) . . . . ?
F7 C10 C11 O1 48.8(7) . . . . ?
C9 C10 C11 O1 -70.0(7) . . . . ?
F6 C10 C11 C12 -17.8(8) . . . . ?
F7 C10 C11 C12 -134.5(6) . . . . ?
C9 C10 C11 C12 106.7(7) . . . . ?
O1 C11 C12 C13 1.4(11) . . . . ?
C10 C11 C12 C13 -174.7(6) . . . . ?
C11 C12 C13 O2 0.2(10) . . . . ?
C11 C12 C13 C14 178.6(6) . . . . ?
O2 C13 C14 C15 -2.0(8) . . . . ?
C12 C13 C14 C15 179.5(6) . . . . ?
O2 C13 C14 C16 119.2(6) . . . . ?
C12 C13 C14 C16 -59.2(8) . . . . ?
O2 C13 C14 C17 -121.9(6) . . . . ?
C12 C13 C14 C17 59.6(7) . . . . ?
F8 C18 C19 F12 -68.2(14) . . . . ?
F9 C18 C19 F12 174.9(12) . . . . ?
F10 C18 C19 F12 53.3(13) . . . . ?
F8 C18 C19 F11 178.1(12) . . . . ?
F9 C18 C19 F11 61.2(14) . . . . ?
F10 C18 C19 F11 -60.4(12) . . . . ?
F8 C18 C19 C20 57.4(15) . . . . ?
F9 C18 C19 C20 -59.5(15) . . . . ?
F10 C18 C19 C20 179.0(9) . . . . ?
F12 C19 C20 F13 178.3(7) . . . . ?
F11 C19 C20 F13 -65.4(8) . . . . ?
C18 C19 C20 F13 54.1(10) . . . . ?
F12 C19 C20 F14 64.9(8) . . . . ?
F11 C19 C20 F14 -178.8(6) . . . . ?
C18 C19 C20 F14 -59.3(10) . . . . ?
F12 C19 C20 C21 -57.6(9) . . . . ?
F11 C19 C20 C21 58.7(8) . . . . ?
C18 C19 C20 C21 178.2(8) . . . . ?
F13 C20 C21 O3 -164.3(6) . . . . ?
F14 C20 C21 O3 -46.5(7) . . . . ?
C19 C20 C21 O3 75.3(8) . . . . ?
F13 C20 C21 C22 15.2(9) . . . . ?
F14 C20 C21 C22 133.0(7) . . . . ?
C19 C20 C21 C22 -105.2(7) . . . . ?
O3 C21 C22 C23 -0.2(12) . . . . ?
C20 C21 C22 C23 -179.7(6) . . . . ?
C21 C22 C23 O4 -1.5(12) . . . . ?
C21 C22 C23 C24 177.7(7) . . . . ?
O4 C23 C24 C27' 95.0(15) . . . . ?
C22 C23 C24 C27' -84.1(15) . . . . ?
O4 C23 C24 C26 -85.1(13) . . . . ?
C22 C23 C24 C26 95.7(14) . . . . ?
O4 C23 C24 C27 42.2(13) . . . . ?
C22 C23 C24 C27 -137.0(11) . . . . ?
O4 C23 C24 C25' -137.1(12) . . . . ?
C22 C23 C24 C25' 43.7(14) . . . . ?
O4 C23 C24 C26' -27.7(13) . . . . ?
C22 C23 C24 C26' 153.2(12) . . . . ?
O4 C23 C24 C25 153.9(10) . . . . ?
C22 C23 C24 C25 -25.3(12) . . . . ?
F19 C28 C29 F17 -173.7(12) . . . . ?
F21 C28 C29 F17 55.5(15) . . . . ?
F20 C28 C29 F17 -58.3(11) . . . . ?
F19 C28 C29 F18 -56.8(15) . . . . ?
F21 C28 C29 F18 172.4(11) . . . . ?
F20 C28 C29 F18 58.6(11) . . . . ?
F19 C28 C29 C30 65.7(15) . . . . ?
F21 C28 C29 C30 -65.1(13) . . . . ?
F20 C28 C29 C30 -178.9(8) . . . . ?
F17 C29 C30 F16 -175.9(6) . . . . ?
F18 C29 C30 F16 67.5(8) . . . . ?
C28 C29 C30 F16 -54.7(9) . . . . ?
F17 C29 C30 F15 -60.5(8) . . . . ?
F18 C29 C30 F15 -177.1(6) . . . . ?
C28 C29 C30 F15 60.7(8) . . . . ?
F17 C29 C30 C31 62.5(8) . . . . ?
F18 C29 C30 C31 -54.0(8) . . . . ?
C28 C29 C30 C31 -176.2(7) . . . . ?
F16 C30 C31 O6 -33.9(8) . . . . ?
F15 C30 C31 O6 -153.6(5) . . . . ?
C29 C30 C31 O6 85.7(6) . . . . ?
F16 C30 C31 C32 147.1(6) . . . . ?
F15 C30 C31 C32 27.4(9) . . . . ?
C29 C30 C31 C32 -93.3(7) . . . . ?
O6 C31 C32 C33 6.1(11) . . . . ?
C30 C31 C32 C33 -175.0(6) . . . . ?
C31 C32 C33 O5 -1.8(10) . . . . ?
C31 C32 C33 C34 174.3(6) . . . . ?
O5 C33 C34 C37 42.2(16) . . . . ?
C32 C33 C34 C37 -134.1(16) . . . . ?
O5 C33 C34 C36' -148.3(9) . . . . ?
C32 C33 C34 C36' 35.4(11) . . . . ?
O5 C33 C34 C35' -18.9(10) . . . . ?
C32 C33 C34 C35' 164.8(8) . . . . ?
O5 C33 C34 C36 171.9(14) . . . . ?
C32 C33 C34 C36 -4.4(15) . . . . ?
O5 C33 C34 C35 -76.2(14) . . . . ?
C32 C33 C34 C35 107.4(14) . . . . ?
O5 C33 C34 C37' 92.9(8) . . . . ?
C32 C33 C34 C37' -83.4(9) . . . . ?
N2 C7 N1 C1 0.8(6) . . . . ?
N2 C7 N1 Eu1 173.8(3) . . . . ?
C6 C1 N1 C7 0.0(5) . . . . ?
C2 C1 N1 C7 177.5(5) . . . . ?
C6 C1 N1 Eu1 -172.6(3) . . . . ?
C2 C1 N1 Eu1 4.8(8) . . . . ?
C12 C11 O1 Eu1 5.2(9) . . . . ?
C10 C11 O1 Eu1 -178.6(4) . . . . ?
C12 C13 O2 Eu1 -9.4(9) . . . . ?
C14 C13 O2 Eu1 172.2(4) . . . . ?
C22 C21 O3 Eu1 18.4(10) . . . . ?
C20 C21 O3 Eu1 -162.2(4) . . . . ?
C22 C23 O4 Eu1 -16.0(11) . . . . ?
C24 C23 O4 Eu1 164.9(5) . . . . ?
C32 C33 O5 Eu1 -19.5(9) . . . . ?
C34 C33 O5 Eu1 164.3(4) . . . . ?
C32 C31 O6 Eu1 9.8(10) . . . . ?
C30 C31 O6 Eu1 -169.1(4) . . . . ?
N1 C7 N2 C6 -1.4(6) . . . . ?
C5 C6 N2 C7 -177.3(6) . . . . ?
C1 C6 N2 C7 1.3(6) . . . . ?
