#------------------------------------------------------------------------------
#$Date: 2023-10-04 01:52:32 +0300 (Wed, 04 Oct 2023) $
#$Revision: 286642 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/71/40/7714098.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7714098
loop_
_publ_author_name
'Siewert, Jan-Erik'
'Schumann, André'
'Wellnitz, Tim'
'Dankert, Fabian'
'Hering-Junghans, Christian'
_publ_section_title
;
 Triphosphiranes as Phosphinidene-Transfer Agents -- Synthesis of Regular
 and Chelating NHC Phosphinidene Adducts
;
_journal_name_full               'Dalton Transactions'
_journal_paper_doi               10.1039/D3DT02690F
_journal_year                    2023
_chemical_formula_moiety         'C23 H37 N2 P'
_chemical_formula_sum            'C23 H37 N2 P'
_chemical_formula_weight         372.51
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2023-08-17 deposited with the CCDC.	2023-09-26 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 106.127(2)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   10.4539(9)
_cell_length_b                   15.7979(13)
_cell_length_c                   14.8454(12)
_cell_measurement_reflns_used    9755
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      30.45
_cell_measurement_theta_min      2.40
_cell_volume                     2355.2(3)
_computing_cell_refinement       'SAINT (Bruker, 2013)'
_computing_data_collection       'APEX2 (Bruker, 2014)'
_computing_data_reduction        SAINT
_computing_molecular_graphics    'ORTEP-3v2.01 (Farrugia, 1997)'
_computing_publication_material  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_structure_solution    'SHELXT (Sheldrick, 2015)'
_diffrn_ambient_temperature      150(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0364
_diffrn_reflns_av_unetI/netI     0.0222
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 1.000
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       22
_diffrn_reflns_limit_k_min       -22
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            59977
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 1.000
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         29.999
_diffrn_reflns_theta_min         1.924
_exptl_absorpt_coefficient_mu    0.125
_exptl_absorpt_correction_T_max  0.979
_exptl_absorpt_correction_T_min  0.966
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Sheldrick, 2014)'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.051
_exptl_crystal_description       block
_exptl_crystal_F_000             816
_exptl_crystal_size_max          0.280
_exptl_crystal_size_mid          0.260
_exptl_crystal_size_min          0.170
_refine_diff_density_max         0.360
_refine_diff_density_min         -0.247
_refine_diff_density_rms         0.042
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.066
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     245
_refine_ls_number_reflns         6873
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.066
_refine_ls_R_factor_all          0.0475
_refine_ls_R_factor_gt           0.0369
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0616P)²+0.2408P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1040
_refine_ls_wR_factor_ref         0.1094
_reflns_Friedel_coverage         0.000
_reflns_number_gt                5553
_reflns_number_total             6873
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d3dt02690f2.cif
_cod_data_source_block           ax1959_DipPIiPr2Me2_cmpd4b
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               7714098
_shelx_shelxl_version_number     2014/7
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.966
_shelx_estimated_absorpt_t_max   0.979
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.25449(9) 0.25720(6) 0.70176(6) 0.01942(18) Uani 1 1 d . . . . .
C2 C 0.12182(10) 0.23168(6) 0.65744(7) 0.02284(19) Uani 1 1 d . . . . .
C3 C 0.04574(11) 0.19420(7) 0.71051(8) 0.0320(2) Uani 1 1 d . . . . .
H3 H -0.0428 0.1767 0.6804 0.038 Uiso 1 1 calc R U . . .
C4 C 0.09690(12) 0.18203(8) 0.80601(8) 0.0362(3) Uani 1 1 d . . . . .
H4 H 0.0428 0.1582 0.8414 0.043 Uiso 1 1 calc R U . . .
C5 C 0.22713(12) 0.20475(7) 0.84988(7) 0.0307(2) Uani 1 1 d . . . . .
H5 H 0.2620 0.1958 0.9154 0.037 Uiso 1 1 calc R U . . .
C6 C 0.30839(10) 0.24060(6) 0.79951(7) 0.02295(19) Uani 1 1 d . . . . .
C7 C 0.06040(10) 0.24207(7) 0.55220(7) 0.0264(2) Uani 1 1 d . . . . .
H7 H 0.1107 0.2884 0.5311 0.032 Uiso 1 1 calc R U . . .
C8 C 0.07873(15) 0.16269(9) 0.49958(9) 0.0457(3) Uani 1 1 d . . . . .
H8A H 0.1740 0.1515 0.5104 0.069 Uiso 1 1 calc R U . . .
H8B H 0.0371 0.1707 0.4323 0.069 Uiso 1 1 calc R U . . .
H8C H 0.0369 0.1146 0.5220 0.069 Uiso 1 1 calc R U . . .
C9 C -0.08512(13) 0.26840(11) 0.52491(10) 0.0506(4) Uani 1 1 d . . . . .
H9A H -0.1390 0.2226 0.5399 0.076 Uiso 1 1 calc R U . . .
H9B H -0.1148 0.2801 0.4575 0.076 Uiso 1 1 calc R U . . .
H9C H -0.0954 0.3195 0.5597 0.076 Uiso 1 1 calc R U . . .
C10 C 0.45323(11) 0.25699(7) 0.85273(7) 0.0271(2) Uani 1 1 d . . . . .
H10 H 0.5015 0.2737 0.8060 0.033 Uiso 1 1 calc R U . . .
C11 C 0.52060(12) 0.17734(8) 0.90344(8) 0.0367(3) Uani 1 1 d . . . . .
H11A H 0.4794 0.1620 0.9529 0.055 Uiso 1 1 calc R U . . .
H11B H 0.6156 0.1885 0.9313 0.055 Uiso 1 1 calc R U . . .
H11C H 0.5099 0.1306 0.8585 0.055 Uiso 1 1 calc R U . . .
C12 C 0.46791(13) 0.32935(8) 0.92352(8) 0.0361(3) Uani 1 1 d . . . . .
H12A H 0.4250 0.3803 0.8913 0.054 Uiso 1 1 calc R U . . .
H12B H 0.5626 0.3407 0.9524 0.054 Uiso 1 1 calc R U . . .
H12C H 0.4256 0.3133 0.9722 0.054 Uiso 1 1 calc R U . . .
C13 C 0.40957(9) 0.39802(6) 0.69575(6) 0.01987(18) Uani 1 1 d . . . . .
C14 C 0.41173(11) 0.51983(6) 0.77644(7) 0.0275(2) Uani 1 1 d . . . . .
C15 C 0.53877(11) 0.50308(7) 0.77680(7) 0.0275(2) Uani 1 1 d . . . . .
C16 C 0.36212(15) 0.59092(8) 0.82442(10) 0.0444(3) Uani 1 1 d . . . . .
H16A H 0.3342 0.5686 0.8776 0.067 Uiso 1 1 calc R U . . .
H16B H 0.2862 0.6183 0.7800 0.067 Uiso 1 1 calc R U . . .
H16C H 0.4335 0.6324 0.8470 0.067 Uiso 1 1 calc R U . . .
C17 C 0.66218(13) 0.55029(8) 0.82639(9) 0.0393(3) Uani 1 1 d . . . . .
H17A H 0.6377 0.6046 0.8488 0.059 Uiso 1 1 calc R U . . .
H17B H 0.7162 0.5603 0.7830 0.059 Uiso 1 1 calc R U . . .
H17C H 0.7135 0.5168 0.8798 0.059 Uiso 1 1 calc R U . . .
C18 C 0.18552(10) 0.45544(7) 0.68858(8) 0.0284(2) Uani 1 1 d . . . . .
H18 H 0.1610 0.4017 0.6522 0.034 Uiso 1 1 calc R U . . .
C19 C 0.11466(14) 0.45345(10) 0.76517(11) 0.0461(3) Uani 1 1 d . . . . .
H19A H 0.1508 0.4073 0.8089 0.069 Uiso 1 1 calc R U . . .
H19B H 0.0192 0.4444 0.7369 0.069 Uiso 1 1 calc R U . . .
H19C H 0.1284 0.5074 0.7990 0.069 Uiso 1 1 calc R U . . .
C20 C 0.14177(13) 0.52740(8) 0.61853(10) 0.0418(3) Uani 1 1 d . . . . .
H20A H 0.1638 0.5817 0.6510 0.063 Uiso 1 1 calc R U . . .
H20B H 0.0454 0.5240 0.5899 0.063 Uiso 1 1 calc R U . . .
H20C H 0.1879 0.5227 0.5696 0.063 Uiso 1 1 calc R U . . .
C21 C 0.64793(10) 0.38831(7) 0.69890(8) 0.0313(2) Uani 1 1 d . . . . .
H21 H 0.6128 0.3342 0.6664 0.038 Uiso 1 1 calc R U . . .
C22 C 0.69005(13) 0.44292(8) 0.62743(9) 0.0396(3) Uani 1 1 d . . . . .
H22A H 0.6121 0.4556 0.5748 0.059 Uiso 1 1 calc R U . . .
H22B H 0.7563 0.4124 0.6044 0.059 Uiso 1 1 calc R U . . .
H22C H 0.7288 0.4959 0.6572 0.059 Uiso 1 1 calc R U . . .
C23 C 0.76349(12) 0.36446(10) 0.78335(11) 0.0500(4) Uani 1 1 d . . . . .
H23A H 0.8110 0.4158 0.8111 0.075 Uiso 1 1 calc R U . . .
H23B H 0.8247 0.3268 0.7631 0.075 Uiso 1 1 calc R U . . .
H23C H 0.7289 0.3354 0.8301 0.075 Uiso 1 1 calc R U . . .
N1 N 0.33222(8) 0.45519(5) 0.72552(6) 0.02295(17) Uani 1 1 d . . . . .
N2 N 0.53658(8) 0.42833(5) 0.72611(6) 0.02348(17) Uani 1 1 d . . . . .
P1 P 0.35818(2) 0.30206(2) 0.62993(2) 0.02080(7) Uani 1 1 d . . . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C2 C1 C6 118.58(8) . . ?
C2 C1 P1 119.54(7) . . ?
C6 C1 P1 121.64(7) . . ?
C3 C2 C1 119.69(9) . . ?
C3 C2 C7 118.69(9) . . ?
C1 C2 C7 121.61(9) . . ?
C4 C3 C2 121.23(10) . . ?
C4 C3 H3 119.4 . . ?
C2 C3 H3 119.4 . . ?
C3 C4 C5 119.77(10) . . ?
C3 C4 H4 120.1 . . ?
C5 C4 H4 120.1 . . ?
C4 C5 C6 121.20(10) . . ?
C4 C5 H5 119.4 . . ?
C6 C5 H5 119.4 . . ?
C5 C6 C1 119.42(9) . . ?
C5 C6 C10 117.10(9) . . ?
C1 C6 C10 123.44(8) . . ?
C8 C7 C9 110.44(11) . . ?
C8 C7 C2 111.18(9) . . ?
C9 C7 C2 114.10(10) . . ?
C8 C7 H7 106.9 . . ?
C9 C7 H7 106.9 . . ?
C2 C7 H7 106.9 . . ?
C7 C8 H8A 109.5 . . ?
C7 C8 H8B 109.5 . . ?
H8A C8 H8B 109.5 . . ?
C7 C8 H8C 109.5 . . ?
H8A C8 H8C 109.5 . . ?
H8B C8 H8C 109.5 . . ?
C7 C9 H9A 109.5 . . ?
C7 C9 H9B 109.5 . . ?
H9A C9 H9B 109.5 . . ?
C7 C9 H9C 109.5 . . ?
H9A C9 H9C 109.5 . . ?
H9B C9 H9C 109.5 . . ?
C6 C10 C12 112.25(9) . . ?
C6 C10 C11 111.72(9) . . ?
C12 C10 C11 109.32(9) . . ?
C6 C10 H10 107.8 . . ?
C12 C10 H10 107.8 . . ?
C11 C10 H10 107.8 . . ?
C10 C11 H11A 109.5 . . ?
C10 C11 H11B 109.5 . . ?
H11A C11 H11B 109.5 . . ?
C10 C11 H11C 109.5 . . ?
H11A C11 H11C 109.5 . . ?
H11B C11 H11C 109.5 . . ?
C10 C12 H12A 109.5 . . ?
C10 C12 H12B 109.5 . . ?
H12A C12 H12B 109.5 . . ?
C10 C12 H12C 109.5 . . ?
H12A C12 H12C 109.5 . . ?
H12B C12 H12C 109.5 . . ?
N2 C13 N1 105.69(8) . . ?
N2 C13 P1 126.16(7) . . ?
N1 C13 P1 128.15(7) . . ?
C15 C14 N1 107.15(9) . . ?
C15 C14 C16 127.88(10) . . ?
N1 C14 C16 124.91(10) . . ?
C14 C15 N2 107.09(9) . . ?
C14 C15 C17 128.06(10) . . ?
N2 C15 C17 124.73(10) . . ?
C14 C16 H16A 109.5 . . ?
C14 C16 H16B 109.5 . . ?
H16A C16 H16B 109.5 . . ?
C14 C16 H16C 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
C15 C17 H17A 109.5 . . ?
C15 C17 H17B 109.5 . . ?
H17A C17 H17B 109.5 . . ?
C15 C17 H17C 109.5 . . ?
H17A C17 H17C 109.5 . . ?
H17B C17 H17C 109.5 . . ?
N1 C18 C19 113.17(10) . . ?
N1 C18 C20 109.83(9) . . ?
C19 C18 C20 114.20(10) . . ?
N1 C18 H18 106.3 . . ?
C19 C18 H18 106.3 . . ?
C20 C18 H18 106.3 . . ?
C18 C19 H19A 109.5 . . ?
C18 C19 H19B 109.5 . . ?
H19A C19 H19B 109.5 . . ?
C18 C19 H19C 109.5 . . ?
H19A C19 H19C 109.5 . . ?
H19B C19 H19C 109.5 . . ?
C18 C20 H20A 109.5 . . ?
C18 C20 H20B 109.5 . . ?
H20A C20 H20B 109.5 . . ?
C18 C20 H20C 109.5 . . ?
H20A C20 H20C 109.5 . . ?
H20B C20 H20C 109.5 . . ?
N2 C21 C22 110.51(9) . . ?
N2 C21 C23 112.65(11) . . ?
C22 C21 C23 113.30(10) . . ?
N2 C21 H21 106.6 . . ?
C22 C21 H21 106.6 . . ?
C23 C21 H21 106.6 . . ?
C21 C22 H22A 109.5 . . ?
C21 C22 H22B 109.5 . . ?
H22A C22 H22B 109.5 . . ?
C21 C22 H22C 109.5 . . ?
H22A C22 H22C 109.5 . . ?
H22B C22 H22C 109.5 . . ?
C21 C23 H23A 109.5 . . ?
C21 C23 H23B 109.5 . . ?
H23A C23 H23B 109.5 . . ?
C21 C23 H23C 109.5 . . ?
H23A C23 H23C 109.5 . . ?
H23B C23 H23C 109.5 . . ?
C13 N1 C14 109.96(8) . . ?
C13 N1 C18 121.90(8) . . ?
C14 N1 C18 126.73(9) . . ?
C13 N2 C15 110.08(8) . . ?
C13 N2 C21 121.88(9) . . ?
C15 N2 C21 127.82(9) . . ?
C13 P1 C1 98.22(4) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 C2 1.4184(13) . ?
C1 C6 1.4275(13) . ?
C1 P1 1.8592(9) . ?
C2 C3 1.3972(14) . ?
C2 C7 1.5240(14) . ?
C3 C4 1.3827(17) . ?
C3 H3 0.9500 . ?
C4 C5 1.3834(16) . ?
C4 H4 0.9500 . ?
C5 C6 1.3980(14) . ?
C5 H5 0.9500 . ?
C6 C10 1.5229(14) . ?
C7 C8 1.5175(16) . ?
C7 C9 1.5196(16) . ?
C7 H7 1.0000 . ?
C8 H8A 0.9800 . ?
C8 H8B 0.9800 . ?
C8 H8C 0.9800 . ?
C9 H9A 0.9800 . ?
C9 H9B 0.9800 . ?
C9 H9C 0.9800 . ?
C10 C12 1.5314(16) . ?
C10 C11 1.5335(16) . ?
C10 H10 1.0000 . ?
C11 H11A 0.9800 . ?
C11 H11B 0.9800 . ?
C11 H11C 0.9800 . ?
C12 H12A 0.9800 . ?
C12 H12B 0.9800 . ?
C12 H12C 0.9800 . ?
C13 N2 1.3648(12) . ?
C13 N1 1.3651(12) . ?
C13 P1 1.8028(10) . ?
C14 C15 1.3527(16) . ?
C14 N1 1.3986(13) . ?
C14 C16 1.4977(16) . ?
C15 N2 1.3971(13) . ?
C15 C17 1.4949(15) . ?
C16 H16A 0.9800 . ?
C16 H16B 0.9800 . ?
C16 H16C 0.9800 . ?
C17 H17A 0.9800 . ?
C17 H17B 0.9800 . ?
C17 H17C 0.9800 . ?
C18 N1 1.4783(13) . ?
C18 C19 1.5199(16) . ?
C18 C20 1.5227(16) . ?
C18 H18 1.0000 . ?
C19 H19A 0.9800 . ?
C19 H19B 0.9800 . ?
C19 H19C 0.9800 . ?
C20 H20A 0.9800 . ?
C20 H20B 0.9800 . ?
C20 H20C 0.9800 . ?
C21 N2 1.4762(13) . ?
C21 C22 1.5243(17) . ?
C21 C23 1.5270(17) . ?
C21 H21 1.0000 . ?
C22 H22A 0.9800 . ?
C22 H22B 0.9800 . ?
C22 H22C 0.9800 . ?
C23 H23A 0.9800 . ?
C23 H23B 0.9800 . ?
C23 H23C 0.9800 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C6 C1 C2 C3 2.44(14) . . . . ?
P1 C1 C2 C3 176.93(8) . . . . ?
C6 C1 C2 C7 -176.01(9) . . . . ?
P1 C1 C2 C7 -1.52(13) . . . . ?
C1 C2 C3 C4 0.57(17) . . . . ?
C7 C2 C3 C4 179.06(11) . . . . ?
C2 C3 C4 C5 -2.09(19) . . . . ?
C3 C4 C5 C6 0.51(19) . . . . ?
C4 C5 C6 C1 2.53(17) . . . . ?
C4 C5 C6 C10 -175.34(11) . . . . ?
C2 C1 C6 C5 -3.95(14) . . . . ?
P1 C1 C6 C5 -178.31(8) . . . . ?
C2 C1 C6 C10 173.77(9) . . . . ?
P1 C1 C6 C10 -0.59(14) . . . . ?
C3 C2 C7 C8 -85.77(13) . . . . ?
C1 C2 C7 C8 92.69(12) . . . . ?
C3 C2 C7 C9 39.92(14) . . . . ?
C1 C2 C7 C9 -141.61(11) . . . . ?
C5 C6 C10 C12 -70.35(12) . . . . ?
C1 C6 C10 C12 111.88(11) . . . . ?
C5 C6 C10 C11 52.87(13) . . . . ?
C1 C6 C10 C11 -124.91(10) . . . . ?
N1 C14 C15 N2 0.02(11) . . . . ?
C16 C14 C15 N2 177.27(11) . . . . ?
N1 C14 C15 C17 -176.12(10) . . . . ?
C16 C14 C15 C17 1.1(2) . . . . ?
N2 C13 N1 C14 -1.52(11) . . . . ?
P1 C13 N1 C14 178.54(7) . . . . ?
N2 C13 N1 C18 165.82(8) . . . . ?
P1 C13 N1 C18 -14.12(13) . . . . ?
C15 C14 N1 C13 0.95(11) . . . . ?
C16 C14 N1 C13 -176.41(11) . . . . ?
C15 C14 N1 C18 -165.63(10) . . . . ?
C16 C14 N1 C18 17.01(17) . . . . ?
C19 C18 N1 C13 127.60(11) . . . . ?
C20 C18 N1 C13 -103.47(11) . . . . ?
C19 C18 N1 C14 -67.29(14) . . . . ?
C20 C18 N1 C14 61.64(13) . . . . ?
N1 C13 N2 C15 1.53(10) . . . . ?
P1 C13 N2 C15 -178.52(7) . . . . ?
N1 C13 N2 C21 -173.45(9) . . . . ?
P1 C13 N2 C21 6.49(13) . . . . ?
C14 C15 N2 C13 -0.98(11) . . . . ?
C17 C15 N2 C13 175.32(10) . . . . ?
C14 C15 N2 C21 173.63(10) . . . . ?
C17 C15 N2 C21 -10.07(17) . . . . ?
C22 C21 N2 C13 106.53(11) . . . . ?
C23 C21 N2 C13 -125.62(11) . . . . ?
C22 C21 N2 C15 -67.51(14) . . . . ?
C23 C21 N2 C15 60.35(14) . . . . ?
N2 C13 P1 C1 131.41(8) . . . . ?
N1 C13 P1 C1 -48.66(9) . . . . ?
C2 C1 P1 C13 127.62(8) . . . . ?
C6 C1 P1 C13 -58.07(9) . . . . ?
