#------------------------------------------------------------------------------
#$Date: 2023-10-21 02:03:38 +0300 (Sat, 21 Oct 2023) $
#$Revision: 287065 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/71/42/7714261.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7714261
loop_
_publ_author_name
'Shen, Quanli'
'Cong, Xuzi'
'Chen, Leyi'
'Wang, Lei'
'Liu, Yonggang'
'Wang, Likai'
'Tang, Zhenghua'
_publ_section_title
;
 Synthesis, structure anatomy, and catalytic properties of Ag14Cu2
 nanoclusters co-protected by alkynyl and phosphine ligands
;
_journal_name_full               'Dalton Transactions'
_journal_paper_doi               10.1039/D3DT02838K
_journal_year                    2023
_chemical_formula_moiety         'C212 H102 Ag14 Cu2 F84 P4'
_chemical_formula_sum            'C212 H102 Ag14 Cu2 F84 P4'
_chemical_formula_weight         6006.07
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_audit_creation_date             2022-04-29
_audit_creation_method
;
Olex2 1.5
(compiled 2022.04.07 svn.rca3783a0 for OlexSys, GUI svn.r6498)
;
_audit_update_record
;
2023-05-17 deposited with the CCDC.	2023-10-16 downloaded from the CCDC.
;
_cell_angle_alpha                105.4210(10)
_cell_angle_beta                 105.0070(10)
_cell_angle_gamma                116.9920(10)
_cell_formula_units_Z            1
_cell_length_a                   18.68860(10)
_cell_length_b                   19.6047(2)
_cell_length_c                   19.8873(2)
_cell_measurement_reflns_used    145426
_cell_measurement_temperature    100.00(10)
_cell_measurement_theta_max      31.2000
_cell_measurement_theta_min      2.2910
_cell_volume                     5614.54(14)
_computing_cell_refinement       'CrysAlisPro 1.171.41.122a (Rigaku OD, 2021)'
_computing_data_collection       'CrysAlisPro 1.171.41.122a (Rigaku OD, 2021)'
_computing_data_reduction        'CrysAlisPro 1.171.41.122a (Rigaku OD, 2021)'
_computing_molecular_graphics    'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT  (Sheldrick, 2015)'
_diffrn_ambient_environment      N~2~
_diffrn_ambient_temperature      100.00(10)
_diffrn_detector                 'Hybrid Pixel Array Detector'
_diffrn_detector_area_resol_mean 10.0000
_diffrn_detector_type            HyPix
_diffrn_measured_fraction_theta_full 0.995
_diffrn_measured_fraction_theta_max 0.855
_diffrn_measurement_details
;
List of Runs (angles in degrees, time in seconds):

  # Type    Start    End  Width  tₑₓₚ   ω     θ     κ     φ   Frames
#--------------------------------------------------------------------------
  1  ω     -9.00  38.00   0.50    1.20    --    4.52 -99.00 141.00   94
  2  ω     -6.00  75.00   0.50    1.20    --    4.52  57.00 -60.00  162
  3  ω    -20.00  23.00   0.50    1.20    --   -6.00  33.00  56.40   86
  4  ω    -19.00  69.00   0.50    1.20    --   -6.24  30.00 148.80  176
  5  ω    -20.00  52.00   0.50    1.20    --   -6.00  33.00   0.14  144
  6  ω    -19.00  59.00   0.50    1.20    --   -6.24  19.00  90.00  156
  7  ω    -19.00  68.00   0.50    1.20    --   -6.24  31.00 -61.48  174
  8  ω    -19.00  55.00   0.50    1.20    --   -6.24  30.00-129.72  148
  9  ω    -19.00  68.00   0.50    1.20    --   -6.24  28.00-166.20  174
 10  ω    -29.00  21.00   0.50    1.20    --    4.52  99.00-112.00  100
 11  ω     -9.00  22.00   0.50    1.20    --   -6.24  99.00-112.00   62
 12  ω    -40.00 -12.00   0.50    1.20    --   -6.24  99.00-112.00   56
 13  ω    -79.00  15.00   0.50    1.20    --   -6.24 -77.00  90.00  188
;
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'XtaLAB Synergy R, DW system, HyPix'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_type
'CrysAlisPro convention (1999,Acta A55,543-557)'
_diffrn_orient_matrix_UB_11      0.0055255000
_diffrn_orient_matrix_UB_12      0.0208483000
_diffrn_orient_matrix_UB_13      0.0378920000
_diffrn_orient_matrix_UB_21      0.0037664000
_diffrn_orient_matrix_UB_22      -0.0309722000
_diffrn_orient_matrix_UB_23      0.0095640000
_diffrn_orient_matrix_UB_31      0.0470106000
_diffrn_orient_matrix_UB_32      0.0257501000
_diffrn_orient_matrix_UB_33      0.0131950000
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0255
_diffrn_reflns_av_unetI/netI     0.0188
_diffrn_reflns_Laue_measured_fraction_full 0.995
_diffrn_reflns_Laue_measured_fraction_max 0.855
_diffrn_reflns_limit_h_max       27
_diffrn_reflns_limit_h_min       -25
_diffrn_reflns_limit_k_max       28
_diffrn_reflns_limit_k_min       -27
_diffrn_reflns_limit_l_max       28
_diffrn_reflns_limit_l_min       -27
_diffrn_reflns_number            170364
_diffrn_reflns_point_group_measured_fraction_full 0.995
_diffrn_reflns_point_group_measured_fraction_max 0.855
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         31.012
_diffrn_reflns_theta_min         2.251
_diffrn_source                   'Rotating-anode X-ray tube'
_diffrn_source_type              'Rigaku (Mo) X-ray Source'
_exptl_absorpt_coefficient_mu    1.522
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.77284
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlisPro 1.171.41.122a (Rigaku Oxford Diffraction, 2021)
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            'clear dark red'
_exptl_crystal_density_diffrn    1.776
_exptl_crystal_description       block
_exptl_crystal_F_000             2906
_exptl_crystal_size_max          0.3
_exptl_crystal_size_mid          0.2
_exptl_crystal_size_min          0.2
_refine_diff_density_max         1.247
_refine_diff_density_min         -3.782
_refine_diff_density_rms         0.119
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.037
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1547
_refine_ls_number_reflns         30605
_refine_ls_number_restraints     301
_refine_ls_restrained_S_all      1.066
_refine_ls_R_factor_all          0.0450
_refine_ls_R_factor_gt           0.0358
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0487P)²+15.8362P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0931
_refine_ls_wR_factor_ref         0.1007
_reflns_Friedel_coverage         0.000
_reflns_number_gt                26169
_reflns_number_total             30605
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d3dt02838k2.cif
_cod_data_source_block           exp_1924_mgy3_auto
_cod_original_cell_volume        5614.53(10)
_cod_database_code               7714261
_shelx_shelxl_version_number     2018/3
_chemical_oxdiff_formula         'Ag Cu CHFPCl'
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
2. Restrained distances
 C13-F37
 1.36 with sigma of 0.02
 C51-F15
 1.29 with sigma of 0.02
 C51-F31
 1.36 with sigma of 0.02
 C13-F19
 1.27 with sigma of 0.02
 C51-F2
 1.27 with sigma of 0.02
 C103-F33
 1.29 with sigma of 0.02
 C103-F17
 1.36 with sigma of 0.02
 C103-F35
 1.27 with sigma of 0.02
 C13-F9
 1.29 with sigma of 0.02
 C53-F25
 1.27 with sigma of 0.02
 C53-F3
 1.29 with sigma of 0.02
 C53-F49
 1.36 with sigma of 0.02
 C103-F33 \\sim C103-F17 \\sim C103-F35
 with sigma of 0.02
 C51-F15 \\sim C51-F31 \\sim C51-F2
 with sigma of 0.02
 C13-F9 \\sim C13-F37 \\sim C13-F19
 with sigma of 0.02
 F15-F31 \\sim F31-F2 \\sim F2-F15
 with sigma of 0.03
 F33-F17 \\sim F17-F35 \\sim F35-F33
 with sigma of 0.03
 F9-F37 \\sim F37-F19 \\sim F19-F9
 with sigma of 0.03
 C3-F2 \\sim C3-F47
 with sigma of 0.04
 C3-C51 \\sim C3-C105
 with sigma of 0.02
 F15-F2 \\sim F45-F47
 with sigma of 0.04
 C51-F31 \\sim C105-F23
 with sigma of 0.02
 F31-F2 \\sim F23-F47
 with sigma of 0.04
 C3-F15 \\sim C3-F45
 with sigma of 0.04
 C13-F19 \\sim C13-F11
 with sigma of 0.02
 C103-F17 \\sim C103-F5
 with sigma of 0.02
 C51-F15 \\sim C105-F45
 with sigma of 0.02
 C103-F35 \\sim C103-F41
 with sigma of 0.02
 C51-F2 \\sim C105-F47
 with sigma of 0.02
 C3-F31 \\sim C3-F23
 with sigma of 0.04
 C13-F9 \\sim C13-F21
 with sigma of 0.02
 C13-F37 \\sim C13-F43
 with sigma of 0.02
 F15-F31 \\sim F45-F23
 with sigma of 0.04
 C103-F33 \\sim C103-F39
 with sigma of 0.02
 F3-F49 \\sim F49-F25 \\sim F25-F3
 with sigma of 0.03
 C53-F3 \\sim C53-F49 \\sim C53-F25
 with sigma of 0.02
 F49-F25 \\sim F13-F53
 with sigma of 0.04
 C53-F49 \\sim C107-F13
 with sigma of 0.02
 C53-F3 \\sim C107-F51
 with sigma of 0.02
 C95-C53 \\sim C95-C107
 with sigma of 0.02
 F3-F25 \\sim F51-F53
 with sigma of 0.04
 C53-F25 \\sim C107-F53
 with sigma of 0.02
 C95-F49 \\sim C95-F13
 with sigma of 0.04
 C95-F3 \\sim C95-F51
 with sigma of 0.04
 C95-F25 \\sim C95-F53
 with sigma of 0.04
 F3-F49 \\sim F51-F13
 with sigma of 0.04
 C105-C3 \\sim C51-C3
 with sigma of 0.01
3. Rigid bond restraints
 C3, C51, F15, F31, F2
 with sigma for 1-2 distances of 0.005 and sigma for 1-3 distances of 0.01
4. Uiso/Uaniso restraints and constraints
C51 \\sim F15 \\sim F31 \\sim F2 \\sim C3: within 1.7A with sigma of 0.01 and
sigma for terminal atoms of 0.02 within 1.7A
Uanis(C51) = Uanis(C105)
5. Rigid body (RIGU) restrains
 C51, F15, F31, F2, C105, F45, F23, F47
 with sigma for 1-2 distances of 0.0005 and sigma for 1-3 distances of 0.0005
 C103, F33, F17, F35, F39, F5, F41
 with sigma for 1-2 distances of 0.0005 and sigma for 1-3 distances of 0.0005
 C13, F9, F37, F19, F21, F43, F11
 with sigma for 1-2 distances of 0.0005 and sigma for 1-3 distances of 0.0005
 C53, F3, F49, F25, C107, F51, F13, F53, C95
 with sigma for 1-2 distances of 0.0005 and sigma for 1-3 distances of 0.0005
6. Others
 Sof(F39)=Sof(F5)=Sof(F41)=1-FVAR(1)
 Sof(F33)=Sof(F17)=Sof(F35)=FVAR(1)
 Sof(F21)=Sof(F43)=Sof(F11)=1-FVAR(2)
 Sof(F9)=Sof(F37)=Sof(F19)=FVAR(2)
 Sof(C105)=Sof(F45)=Sof(F23)=Sof(F47)=1-FVAR(3)
 Sof(C51)=Sof(F15)=Sof(F31)=Sof(F2)=FVAR(3)
 Sof(C107)=Sof(F51)=Sof(F13)=Sof(F53)=1-FVAR(4)
 Sof(C53)=Sof(F3)=Sof(F49)=Sof(F25)=FVAR(4)
7.a Aromatic/amide H refined with riding coordinates:
 C24(H24), C28(H28), C30(H30), C32(H32), C38(H38), C42(H42), C48(H48),
 C52(H52), C62(H62), C64(H64), C70(H70), C72(H72), C84(H84), C86(H86), C88(H88),
  C100(H100), C102(H102), C104(H104), C106(H106), C108(H108), C27(H27),
 C55(H55), C7(H7), C57(H57), C29(H29), C61(H61), C31(H31), C63(H63), C2(H2),
 C65(H65), C67(H67), C69(H69), C35(H35), C71(H71), C9(H9), C73(H73), C37(H37),
 C75(H75), C77(H77), C39(H39), C5(H5), C83(H83), C85(H85), C43(H43), C45(H45),
 C91(H91), C97(H97), C49(H49), C99(H99), C25(H25), C101(H101)
;
_smtbx_masks_void_probe_radius   1.2
_smtbx_masks_void_truncation_radius 1.2
_olex2_submission_special_instructions 'No special instructions were received'
_oxdiff_exptl_absorpt_empirical_details
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
;
_oxdiff_exptl_absorpt_empirical_full_max 1.296
_oxdiff_exptl_absorpt_empirical_full_min 0.821
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag4 Ag 0.41908(2) 0.36729(2) 0.51128(2) 0.01806(5) Uani 1 1 d . . . . .
Ag6 Ag 0.57354(2) 0.52922(2) 0.56736(2) 0.01769(4) Uani 1 1 d . . . . .
Ag8 Ag 0.42744(2) 0.54272(2) 0.57507(2) 0.01825(5) Uani 1 1 d . . . . .
Ag2 Ag 0.24878(2) 0.34761(2) 0.46313(2) 0.02017(5) Uani 1 1 d . . . . .
Ag5 Ag 0.21951(2) 0.24815(2) 0.31353(2) 0.02108(5) Uani 1 1 d . . . . .
Ag3 Ag 0.50564(2) 0.73173(2) 0.61270(2) 0.02580(5) Uani 1 1 d . . . . .
Ag7 Ag 0.59519(2) 0.39499(2) 0.55137(2) 0.02657(5) Uani 1 1 d . . . . .
Cu1 Cu 0.60811(2) 0.68071(2) 0.65983(2) 0.01685(7) Uani 1 1 d . . . . .
P1 P 0.47409(5) 0.83811(5) 0.62008(5) 0.02005(14) Uani 1 1 d . . . . .
P2 P 0.12826(5) 0.13376(5) 0.18014(4) 0.02016(14) Uani 1 1 d . . . . .
F1 F 0.99337(16) 0.39862(16) 0.40402(15) 0.0422(5) Uani 1 1 d . . . . .
F4 F 0.21133(15) 0.50551(14) 0.78259(14) 0.0409(5) Uani 1 1 d . . . . .
F6 F 0.64227(15) 0.69469(16) 0.97694(13) 0.0474(6) Uani 1 1 d . . . . .
F8 F 0.88347(16) 0.64920(16) 0.36054(16) 0.0441(5) Uani 1 1 d . . . . .
F10 F 0.88324(18) 0.47853(18) 0.63535(15) 0.0487(6) Uani 1 1 d . . . . .
F12 F 0.5157(2) 0.8752(2) 0.40021(18) 0.0589(7) Uani 1 1 d . . . . .
F14 F 0.67931(16) 0.61123(18) 0.93308(15) 0.0521(6) Uani 1 1 d . . . . .
F16 F 0.23179(17) 0.58967(19) 0.89077(15) 0.0573(7) Uani 1 1 d . . . . .
F18 F 0.8863(2) 0.31405(19) 0.4215(2) 0.0603(8) Uani 1 1 d . . . . .
F20 F 0.36178(19) 0.4129(2) 0.93136(16) 0.0551(7) Uani 1 1 d . . . . .
F22 F 0.99198(16) 0.58664(16) 0.74306(16) 0.0485(6) Uani 1 1 d . . . . .
F24 F 0.31411(17) 0.49184(19) 0.92033(14) 0.0494(6) Uani 1 1 d . . . . .
F26 F 0.52044(18) 0.84710(18) 1.06396(14) 0.0570(7) Uani 1 1 d . . . . .
F28 F 0.9395(2) 0.45919(19) 0.73098(17) 0.0541(7) Uani 1 1 d . . . . .
F30 F 0.24647(17) 0.36675(19) 0.82857(15) 0.0635(9) Uani 1 1 d . . . . .
F32 F 0.66555(16) 0.68646(19) 0.87635(14) 0.0637(9) Uani 1 1 d . . . . .
F34 F 0.19083(16) 0.60522(17) 0.78773(17) 0.0516(6) Uani 1 1 d . . . . .
F36 F 0.99114(19) 0.63690(18) 0.35943(19) 0.0554(7) Uani 1 1 d . . . . .
F38 F 0.6153(2) 0.99551(18) 0.41250(19) 0.0606(8) Uani 1 1 d . . . . .
F40 F 0.62945(17) 0.8632(2) 1.03924(15) 0.0634(8) Uani 1 1 d . . . . .
F42 F 0.4355(2) 0.2866(3) 0.91948(18) 0.0699(9) Uani 1 1 d . . . . .
F44 F 0.86251(19) 0.31251(17) 0.30910(15) 0.0568(7) Uani 1 1 d . . . . .
F46 F 0.5444(2) 0.2999(2) 0.89368(17) 0.0672(9) Uani 1 1 d . . . . .
F48 F 0.99879(19) 0.70735(15) 0.46682(16) 0.0562(7) Uani 1 1 d . . . . .
F50 F 0.5900(2) 0.8813(2) 0.33227(16) 0.0616(8) Uani 1 1 d . . . . .
F52 F -0.16185(18) 0.1915(2) 0.07439(16) 0.0604(8) Uani 1 1 d . . . . .
C1 C 0.6727(2) 0.4318(2) 0.50182(19) 0.0257(6) Uani 1 1 d . . . . .
C4 C 0.51582(19) 0.66943(18) 0.69634(16) 0.0201(5) Uani 1 1 d . . . . .
F54 F -0.2914(2) 0.0937(2) 0.05151(16) 0.0668(9) Uani 1 1 d . . . . .
F27 F -0.2372(3) 0.2207(2) 0.12677(17) 0.0730(10) Uani 1 1 d . . . . .
F7 F 0.5622(3) 0.91978(17) 1.00339(17) 0.0836(12) Uani 1 1 d . . . . .
F29 F 0.5323(2) 0.4065(2) 0.92882(15) 0.0666(8) Uani 1 1 d . . . . .
C6 C 0.66764(19) 0.62732(17) 0.69472(16) 0.0197(5) Uani 1 1 d . . . . .
C8 C 0.4864(2) 0.67769(18) 0.74388(17) 0.0216(5) Uani 1 1 d . . . . .
C10 C 0.1318(2) 0.2749(2) 0.36095(17) 0.0241(6) Uani 1 1 d . . . . .
C12 C 0.67853(19) 0.80569(19) 0.58299(17) 0.0212(5) Uani 1 1 d . . . . .
C14 C 0.52150(19) 0.35743(18) 0.60472(17) 0.0210(5) Uani 1 1 d . . . . .
C16 C 0.34299(19) 0.40796(18) 0.57752(16) 0.0192(5) Uani 1 1 d . . . . .
C18 C -0.04414(19) 0.19214(19) 0.28179(17) 0.0230(6) Uani 1 1 d . . . . .
C20 C 0.7059(2) 0.8656(2) 0.55068(18) 0.0259(6) Uani 1 1 d . . . . .
C22 C 0.4779(2) 0.33269(19) 0.63976(17) 0.0224(5) Uani 1 1 d . . . . .
C24 C 0.6406(2) 0.86511(19) 0.49614(18) 0.0239(6) Uani 1 1 d . . . . .
H24 H 0.579016 0.825750 0.480966 0.029 Uiso 1 1 calc R U . . .
C26 C 0.65227(19) 0.75726(18) 0.61219(16) 0.0202(5) Uani 1 1 d . . . . .
C28 C 0.5019(2) 0.53712(19) 0.77941(16) 0.0201(5) Uani 1 1 d . . . . .
H28 H 0.541642 0.558536 0.757363 0.024 Uiso 1 1 calc R U . . .
C30 C 0.8064(2) 0.54751(19) 0.71351(18) 0.0234(6) Uani 1 1 d . . . . .
H30 H 0.816191 0.566425 0.675478 0.028 Uiso 1 1 calc R U . . .
C32 C 0.8350(2) 0.5426(2) 0.43588(19) 0.0267(6) Uani 1 1 d . . . . .
H32 H 0.817796 0.581655 0.445501 0.032 Uiso 1 1 calc R U . . .
C34 C 0.4590(2) 0.8713(2) 0.70693(19) 0.0248(6) Uani 1 1 d . . . . .
C36 C 0.7285(2) 0.4536(2) 0.47660(18) 0.0256(6) Uani 1 1 d . . . . .
C38 C 0.3537(2) 0.43974(19) 0.76437(17) 0.0219(5) Uani 1 1 d . . . . .
H38 H 0.292072 0.396072 0.731988 0.026 Uiso 1 1 calc R U . . .
C40 C 0.7023(2) 0.59144(18) 0.71384(17) 0.0222(5) Uani 1 1 d . . . . .
C42 C -0.2308(2) 0.0961(2) 0.19572(18) 0.0252(6) Uani 1 1 d . . . . .
H42 H -0.293910 0.063203 0.166211 0.030 Uiso 1 1 calc R U . . .
C44 C -0.1926(2) 0.0876(2) 0.26002(19) 0.0278(6) Uani 1 1 d . . . . .
C46 C 0.4564(2) 0.68954(19) 0.80300(16) 0.0207(5) Uani 1 1 d . . . . .
C48 C -0.0999(2) 0.1346(2) 0.30279(19) 0.0276(6) Uani 1 1 d . . . . .
H48 H -0.074706 0.127361 0.346227 0.033 Uiso 1 1 calc R U . . .
C50 C 0.37590(19) 0.44018(18) 0.64837(16) 0.0184(5) Uani 1 1 d . . . . .
C52 C -0.0825(2) 0.2020(2) 0.21779(18) 0.0239(6) Uani 1 1 d . . . . .
H52 H -0.045358 0.241853 0.203403 0.029 Uiso 1 1 calc R U . . .
C54 C 0.7472(2) 0.55414(19) 0.74131(18) 0.0226(6) Uani 1 1 d . . . . .
C56 C 0.41104(19) 0.47239(18) 0.73135(16) 0.0187(5) Uani 1 1 d . . . . .
C58 C 0.5332(2) 0.5695(2) 0.85953(17) 0.0231(6) Uani 1 1 d . . . . .
C60 C 0.11219(19) 0.17755(19) 0.11199(17) 0.0228(6) Uani 1 1 d . . . . .
C62 C 0.5158(2) 0.75860(19) 0.87695(17) 0.0231(6) Uani 1 1 d . . . . .
H62 H 0.576640 0.796559 0.888626 0.028 Uiso 1 1 calc R U . . .
C64 C 0.3676(2) 0.63326(19) 0.78777(17) 0.0220(5) Uani 1 1 d . . . . .
H64 H 0.326447 0.585991 0.737934 0.026 Uiso 1 1 calc R U . . .
C66 C -0.1748(2) 0.15369(19) 0.17539(17) 0.0222(5) Uani 1 1 d . . . . .
C68 C 0.7950(2) 0.4707(2) 0.44853(18) 0.0241(6) Uani 1 1 d . . . . .
C70 C 0.3368(2) 0.25518(19) 0.64905(19) 0.0256(6) Uani 1 1 d . . . . .
H70 H 0.303823 0.241005 0.596595 0.031 Uiso 1 1 calc R U . . .
C72 C 0.2644(2) 0.1171(2) 0.16905(18) 0.0255(6) Uani 1 1 d . . . . .
H72 H 0.300939 0.177544 0.198700 0.031 Uiso 1 1 calc R U . . .
C74 C 0.4861(2) 0.7717(2) 0.93334(17) 0.0256(6) Uani 1 1 d . . . . .
C76 C 0.1723(2) 0.07263(19) 0.14679(16) 0.0215(5) Uani 1 1 d . . . . .
C78 C 0.5665(2) 0.93529(19) 0.62967(18) 0.0232(6) Uani 1 1 d . . . . .
C80 C 0.3740(2) 0.80484(18) 0.53895(19) 0.0231(6) Uani 1 1 d . . . . .
C82 C 0.3396(2) 0.6464(2) 0.84544(18) 0.0244(6) Uani 1 1 d . . . . .
C84 C 0.4018(2) 0.8076(2) 0.7221(2) 0.0300(7) Uani 1 1 d . . . . .
H84 H 0.371087 0.749105 0.686893 0.036 Uiso 1 1 calc R U . . .
C86 C 0.3983(2) 0.7160(2) 0.91838(18) 0.0260(6) Uani 1 1 d . . . . .
H86 H 0.378547 0.725234 0.957315 0.031 Uiso 1 1 calc R U . . .
C88 C 0.3614(2) 0.7639(2) 0.4638(2) 0.0293(6) Uani 1 1 d . . . . .
H88 H 0.406208 0.756941 0.456078 0.035 Uiso 1 1 calc R U . . .
C90 C 0.4307(2) 0.30371(19) 0.68322(18) 0.0237(6) Uani 1 1 d . . . . .
C92 C 0.9002(2) 0.5577(2) 0.40916(19) 0.0264(6) Uani 1 1 d . . . . .
C94 C 0.0518(2) 0.2389(2) 0.32510(18) 0.0251(6) Uani 1 1 d . . . . .
C96 C 0.3872(2) 0.4713(2) 0.84467(18) 0.0251(6) Uani 1 1 d . . . . .
C98 C 0.0155(2) 0.05559(19) 0.16262(18) 0.0248(6) Uani 1 1 d . . . . .
C100 C -0.0621(2) 0.0351(2) 0.10492(19) 0.0268(6) Uani 1 1 d . . . . .
H100 H -0.057716 0.059784 0.069811 0.032 Uiso 1 1 calc R U . . .
C102 C 0.4766(2) 0.5371(2) 0.89292(17) 0.0267(6) Uani 1 1 d . . . . .
H102 H 0.498739 0.559557 0.947837 0.032 Uiso 1 1 calc R U . . .
C104 C 0.7961(3) 0.9244(3) 0.5726(2) 0.0418(9) Uani 1 1 d . . . . .
H104 H 0.841290 0.925097 0.608874 0.050 Uiso 1 1 calc R U . . .
C106 C 0.3031(2) 0.0742(2) 0.14842(19) 0.0279(6) Uani 1 1 d . . . . .
H106 H 0.365755 0.105049 0.163894 0.033 Uiso 1 1 calc R U . . .
C108 C 0.8204(2) 0.4132(2) 0.43337(18) 0.0267(6) Uani 1 1 d . . . . .
H108 H 0.793529 0.363781 0.441640 0.032 Uiso 1 1 calc R U . . .
C27 C 0.7340(3) 0.5264(3) 0.7976(2) 0.0363(8) Uani 1 1 d . . . . .
H27 H 0.693341 0.529967 0.816407 0.044 Uiso 1 1 calc R U . . .
C55 C 0.6525(2) 0.9625(2) 0.67778(19) 0.0261(6) Uani 1 1 d . . . . .
H55 H 0.660651 0.930190 0.703336 0.031 Uiso 1 1 calc R U . . .
C7 C 0.7152(3) 1.0831(2) 0.6505(2) 0.0389(8) Uani 1 1 d . . . . .
H7 H 0.765832 1.133786 0.657824 0.047 Uiso 1 1 calc R U . . .
C57 C -0.1452(2) -0.0209(2) 0.0984(2) 0.0340(7) Uani 1 1 d . . . . .
H57 H -0.197511 -0.034069 0.059019 0.041 Uiso 1 1 calc R U . . .
C29 C 0.4780(2) 0.3245(2) 0.76055(19) 0.0283(6) Uani 1 1 d . . . . .
H29 H 0.541618 0.357869 0.784431 0.034 Uiso 1 1 calc R U . . .
C59 C 0.8508(2) 0.5130(2) 0.74193(19) 0.0266(6) Uani 1 1 d . . . . .
C15 C 0.6302(2) 0.6408(2) 0.91131(19) 0.0306(7) Uani 1 1 d . . . . .
C61 C 0.1275(2) 0.1599(2) 0.04647(18) 0.0267(6) Uani 1 1 d . . . . .
H61 H 0.146025 0.122204 0.035000 0.032 Uiso 1 1 calc R U . . .
C31 C 0.6299(3) 1.0559(2) 0.6016(3) 0.0417(9) Uani 1 1 d . . . . .
H31 H 0.622439 1.087546 0.574802 0.050 Uiso 1 1 calc R U . . .
C63 C 0.1159(2) 0.1971(2) -0.0019(2) 0.0340(7) Uani 1 1 d . . . . .
H63 H 0.126840 0.185159 -0.046307 0.041 Uiso 1 1 calc R U . . .
C2 C 0.1197(2) -0.0158(2) 0.10309(19) 0.0285(6) Uani 1 1 d . . . . .
H2 H 0.056985 -0.046865 0.087260 0.034 Uiso 1 1 calc R U . . .
C65 C 0.7267(2) 1.0372(2) 0.6886(2) 0.0324(7) Uani 1 1 d . . . . .
H65 H 0.785271 1.056257 0.722341 0.039 Uiso 1 1 calc R U . . .
C33 C 0.5500(3) 0.8504(2) 1.0098(2) 0.0359(8) Uani 1 1 d . . . . .
C67 C 0.9255(2) 0.5008(2) 0.3943(2) 0.0283(6) Uani 1 1 d . . . . .
H67 H 0.970070 0.511142 0.376300 0.034 Uiso 1 1 calc R U . . .
C17 C 0.2921(2) 0.2279(2) 0.6924(2) 0.0327(7) Uani 1 1 d . . . . .
C69 C 0.2836(3) 0.7333(2) 0.4000(2) 0.0362(8) Uani 1 1 d . . . . .
H69 H 0.275547 0.706120 0.348813 0.043 Uiso 1 1 calc R U . . .
C35 C 0.1584(3) -0.0588(2) 0.0826(2) 0.0361(8) Uani 1 1 d . . . . .
H35 H 0.122006 -0.119179 0.052958 0.043 Uiso 1 1 calc R U . . .
C71 C 0.0066(3) 0.0181(3) 0.2134(2) 0.0402(9) Uani 1 1 d . . . . .
H71 H 0.058605 0.031595 0.253393 0.048 Uiso 1 1 calc R U . . .
C9 C 0.0854(2) 0.2336(2) 0.1283(2) 0.0313(7) Uani 1 1 d . . . . .
H9 H 0.075777 0.246868 0.173350 0.038 Uiso 1 1 calc R U . . .
C73 C 0.2497(2) -0.0142(2) 0.1049(2) 0.0322(7) Uani 1 1 d . . . . .
H73 H 0.275747 -0.044030 0.090514 0.039 Uiso 1 1 calc R U . . .
C37 C -0.1532(3) -0.0581(3) 0.1485(2) 0.0411(9) Uani 1 1 d . . . . .
H37 H -0.210656 -0.096840 0.143361 0.049 Uiso 1 1 calc R U . . .
C75 C 0.3390(3) 0.2476(2) 0.7690(2) 0.0375(8) Uani 1 1 d . . . . .
H75 H 0.307947 0.228234 0.798026 0.045 Uiso 1 1 calc R U . . .
C19 C 0.9158(3) 0.5092(2) 0.7128(2) 0.0344(7) Uani 1 1 d . . . . .
C77 C 0.5553(2) 0.9826(2) 0.5914(2) 0.0329(7) Uani 1 1 d . . . . .
H77 H 0.496911 0.964622 0.558492 0.039 Uiso 1 1 calc R U . . .
C39 C 0.3895(3) 0.8296(3) 0.7890(2) 0.0396(9) Uani 1 1 d . . . . .
H39 H 0.348804 0.786335 0.798265 0.047 Uiso 1 1 calc R U . . .
C79 C 0.6658(3) 0.9218(2) 0.4645(2) 0.0346(8) Uani 1 1 d . . . . .
C5 C -0.0771(3) -0.0384(3) 0.2059(3) 0.0490(10) Uani 1 1 d . . . . .
H5 H -0.082223 -0.063742 0.240515 0.059 Uiso 1 1 calc R U . . .
C81 C 0.4317(3) 0.2960(2) 0.8026(2) 0.0344(7) Uani 1 1 d . . . . .
C41 C -0.2151(2) 0.1655(2) 0.10753(19) 0.0300(7) Uani 1 1 d . . . . .
C83 C 0.8382(3) 0.4864(3) 0.7980(2) 0.0358(8) Uani 1 1 d . . . . .
H83 H 0.869105 0.463205 0.817249 0.043 Uiso 1 1 calc R U . . .
C21 C 0.2435(2) 0.5865(2) 0.8272(2) 0.0337(7) Uani 1 1 d . . . . .
C85 C 0.2177(2) 0.7426(2) 0.4113(2) 0.0390(8) Uani 1 1 d . . . . .
H85 H 0.164215 0.721147 0.367687 0.047 Uiso 1 1 calc R U . . .
C43 C 0.3075(2) 0.8148(2) 0.5498(2) 0.0309(7) Uani 1 1 d . . . . .
H43 H 0.315604 0.843211 0.600682 0.037 Uiso 1 1 calc R U . . .
C87 C 0.9066(3) 0.3633(2) 0.3854(2) 0.0340(7) Uani 1 1 d . . . . .
C11 C 0.8848(2) 0.4286(2) 0.40623(19) 0.0269(6) Uani 1 1 d . . . . .
C89 C 0.3273(3) 0.4356(3) 0.8811(2) 0.0360(8) Uani 1 1 d . . . . .
C45 C 0.5044(3) 0.9567(2) 0.7595(3) 0.0432(10) Uani 1 1 d . . . . .
H45 H 0.542816 1.000548 0.749329 0.052 Uiso 1 1 calc R U . . .
C91 C 0.0882(3) 0.2519(3) 0.0143(2) 0.0395(8) Uani 1 1 d . . . . .
H91 H 0.079874 0.277155 -0.019194 0.047 Uiso 1 1 calc R U . . .
C23 C 0.9433(2) 0.6376(2) 0.3989(2) 0.0338(7) Uani 1 1 d . . . . .
C93 C 0.4860(4) 0.3220(4) 0.8861(3) 0.0506(11) Uani 1 1 d . . . . .
C47 C 0.5960(3) 0.9178(3) 0.4023(3) 0.0433(9) Uani 1 1 d . . . . .
C95 C 0.8194(3) 0.9820(3) 0.5407(3) 0.0571(11) Uani 1 1 d D . . . .
C3 C 0.7803(3) 0.4938(3) 0.8259(3) 0.0475(10) Uani 1 1 d D U . . .
C97 C 0.7556(3) 0.9813(3) 0.4872(3) 0.0514(11) Uani 1 1 d . . . . .
H97 H 0.772489 1.020984 0.466039 0.062 Uiso 1 1 calc R U . . .
C49 C 0.4371(3) 0.9152(3) 0.8420(2) 0.0448(10) Uani 1 1 d . . . . .
H49 H 0.430596 0.930269 0.888456 0.054 Uiso 1 1 calc R U . . .
C99 C 0.2294(2) 0.7828(3) 0.4851(3) 0.0387(8) Uani 1 1 d . . . . .
H99 H 0.183840 0.788730 0.492249 0.046 Uiso 1 1 calc R U . . .
C25 C 0.0728(3) 0.2697(3) 0.0794(3) 0.0405(8) Uani 1 1 d . . . . .
H25 H 0.053592 0.306942 0.090361 0.049 Uiso 1 1 calc R U . . .
C101 C 0.4935(3) 0.9780(3) 0.8271(3) 0.0540(12) Uani 1 1 d . . . . .
H101 H 0.525274 1.036349 0.863218 0.065 Uiso 1 1 calc R U . . .
C51 C 0.7540(6) 0.4485(5) 0.8757(5) 0.0567(11) Uani 0.527(6) 1 d D U P A 1
F15 F 0.7084(5) 0.4722(5) 0.9058(5) 0.0677(17) Uani 0.527(6) 1 d D U P A 1
F31 F 0.8328(7) 0.4801(7) 0.9365(6) 0.091(3) Uani 0.527(6) 1 d D U P A 1
F2 F 0.7044(5) 0.3646(4) 0.8395(5) 0.0824(17) Uani 0.527(6) 1 d D U P A 1
C103 C -0.2521(2) 0.0262(3) 0.2836(2) 0.0405(6) Uani 1 1 d D . . . .
F33 F -0.2638(5) 0.0621(4) 0.3396(4) 0.0758(16) Uani 0.604(6) 1 d D . P B 1
F17 F -0.2203(4) -0.0162(4) 0.3070(4) 0.0665(14) Uani 0.604(6) 1 d D . P B 1
F35 F -0.3317(4) -0.0358(4) 0.2254(4) 0.0877(19) Uani 0.604(6) 1 d D . P B 1
C13 C 0.1918(3) 0.1768(3) 0.6555(3) 0.0476(7) Uani 1 1 d D . . . .
F9 F 0.1645(4) 0.2176(5) 0.6300(6) 0.0768(17) Uani 0.507(6) 1 d D . P C 1
F37 F 0.1629(4) 0.1668(5) 0.7094(4) 0.0788(18) Uani 0.507(6) 1 d D . P C 1
F19 F 0.1589(4) 0.1016(4) 0.6040(5) 0.084(2) Uani 0.507(6) 1 d D . P C 1
F39 F -0.2162(6) 0.0575(6) 0.3615(4) 0.072(2) Uani 0.396(6) 1 d D . P B 2
F5 F -0.2813(8) -0.0508(5) 0.2439(6) 0.072(2) Uani 0.396(6) 1 d D . P B 2
F41 F -0.3256(5) 0.0270(6) 0.2736(5) 0.0587(18) Uani 0.396(6) 1 d D . P B 2
F21 F 0.1574(4) 0.2193(5) 0.6790(5) 0.0785(18) Uani 0.493(6) 1 d D . P C 2
F43 F 0.1532(4) 0.1035(5) 0.6575(6) 0.0809(19) Uani 0.493(6) 1 d D . P C 2
F11 F 0.1516(3) 0.1532(5) 0.5782(4) 0.0697(17) Uani 0.493(6) 1 d D . P C 2
C105 C 0.7835(7) 0.4871(7) 0.9015(5) 0.0567(11) Uani 0.473(6) 1 d D . P A 2
F45 F 0.7029(6) 0.4307(7) 0.8896(5) 0.088(2) Uani 0.473(6) 1 d D . P A 2
F23 F 0.8076(7) 0.5543(5) 0.9635(5) 0.100(3) Uani 0.473(6) 1 d D . P A 2
F47 F 0.8238(10) 0.4488(10) 0.9173(8) 0.101(3) Uani 0.473(6) 1 d D . P A 2
C53 C 0.9125(7) 1.0535(6) 0.5630(6) 0.0745(19) Uani 0.480(10) 1 d D . P D 1
F3 F 0.9303(5) 1.1300(4) 0.6017(5) 0.091(3) Uani 0.480(10) 1 d D . P D 1
F49 F 0.9253(7) 1.0529(6) 0.4993(5) 0.086(2) Uani 0.480(10) 1 d D . P D 1
F25 F 0.9694(6) 1.0420(6) 0.6040(6) 0.090(2) Uani 0.480(10) 1 d D . P D 1
C107 C 0.9204(7) 1.0404(8) 0.5718(7) 0.098(2) Uani 0.520(10) 1 d D . P D 2
F51 F 0.9613(5) 1.0977(6) 0.6465(5) 0.123(4) Uani 0.520(10) 1 d D . P D 2
F13 F 0.9438(7) 1.0837(7) 0.5313(7) 0.118(3) Uani 0.520(10) 1 d D . P D 2
F53 F 0.9653(5) 1.0036(8) 0.5733(7) 0.113(3) Uani 0.520(10) 1 d D . P D 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Ag6 Ag4 Ag6 59.093(8) . 2_666 ?
Ag6 Ag4 Ag8 54.177(6) 2_666 . ?
Ag6 Ag4 Ag8 56.756(7) . . ?
Ag6 Ag4 Ag2 118.449(9) . . ?
Ag6 Ag4 Ag2 73.508(8) 2_666 . ?
Ag6 Ag4 Ag7 58.366(7) . . ?
Ag6 Ag4 Ag7 101.454(9) 2_666 . ?
Ag6 Ag4 Cu1 53.893(8) 2_666 2_666 ?
Ag6 Ag4 Cu1 92.921(10) . 2_666 ?
Ag2 Ag4 Ag8 64.388(7) . . ?
Ag2 Ag4 Ag7 174.875(10) . . ?
Ag2 Ag4 Cu1 88.268(9) . 2_666 ?
Ag7 Ag4 Ag8 113.636(9) . . ?
Ag7 Ag4 Cu1 87.919(9) . 2_666 ?
Cu1 Ag4 Ag8 107.492(9) 2_666 . ?
C14 Ag4 Ag6 81.25(7) . . ?
C14 Ag4 Ag6 138.50(7) . 2_666 ?
C14 Ag4 Ag8 115.03(7) . . ?
C14 Ag4 Ag2 143.44(7) . . ?
C14 Ag4 Ag7 41.56(7) . . ?
C14 Ag4 Cu1 123.21(7) . 2_666 ?
C14 Ag4 C26 106.79(10) . 2_666 ?
C16 Ag4 Ag6 93.17(7) . 2_666 ?
C16 Ag4 Ag6 98.73(7) . . ?
C16 Ag4 Ag8 47.56(7) . . ?
C16 Ag4 Ag2 44.90(7) . . ?
C16 Ag4 Ag7 137.72(7) . . ?
C16 Ag4 Cu1 131.30(7) . 2_666 ?
C16 Ag4 C14 105.31(10) . . ?
C16 Ag4 C26 125.94(10) . 2_666 ?
C26 Ag4 Ag6 128.19(7) 2_666 . ?
C26 Ag4 Ag6 90.49(7) 2_666 2_666 ?
C26 Ag4 Ag8 137.80(7) 2_666 . ?
C26 Ag4 Ag2 85.52(7) 2_666 . ?
C26 Ag4 Ag7 93.67(7) 2_666 . ?
C26 Ag4 Cu1 39.17(7) 2_666 2_666 ?
Ag4 Ag6 Ag4 120.907(8) . 2_666 ?
Ag4 Ag6 Ag8 69.614(8) . . ?
Ag4 Ag6 Ag8 80.705(8) 2_666 . ?
Ag4 Ag6 Ag8 83.511(8) . 2_666 ?
Ag6 Ag6 Ag4 59.370(8) 2_666 2_666 ?
Ag6 Ag6 Ag4 61.536(9) 2_666 . ?
Ag6 Ag6 Ag8 59.017(8) 2_666 . ?
Ag6 Ag6 Ag8 62.557(8) 2_666 2_666 ?
Ag6 Ag6 Ag7 106.742(12) 2_666 . ?
Ag8 Ag6 Ag4 70.176(8) 2_666 2_666 ?
Ag8 Ag6 Ag8 121.574(8) 2_666 . ?
Ag7 Ag6 Ag4 63.221(8) . . ?
Ag7 Ag6 Ag4 136.233(10) . 2_666 ?
Ag7 Ag6 Ag8 130.703(10) . . ?
Ag7 Ag6 Ag8 67.120(8) . 2_666 ?
Cu1 Ag6 Ag4 67.995(9) . 2_666 ?
Cu1 Ag6 Ag4 126.746(11) . . ?
Cu1 Ag6 Ag6 102.481(12) . 2_666 ?
Cu1 Ag6 Ag8 137.082(12) . 2_666 ?
Cu1 Ag6 Ag8 60.000(9) . . ?
Cu1 Ag6 Ag7 149.439(12) . . ?
C6 Ag6 Ag4 127.00(7) . . ?
C6 Ag6 Ag4 103.30(7) . 2_666 ?
C6 Ag6 Ag6 147.07(7) . 2_666 ?
C6 Ag6 Ag8 92.32(7) . . ?
C6 Ag6 Ag8 142.39(7) . 2_666 ?
C6 Ag6 Ag7 104.45(7) . . ?
C6 Ag6 Cu1 45.27(7) . . ?
Ag4 Ag8 Ag2 52.384(6) . . ?
Ag6 Ag8 Ag4 53.629(6) . . ?
Ag6 Ag8 Ag4 55.648(7) 2_666 . ?
Ag6 Ag8 Ag6 58.426(8) 2_666 . ?
Ag6 Ag8 Ag2 103.965(8) . . ?
Ag6 Ag8 Ag2 68.160(7) 2_666 . ?
Ag6 Ag8 Ag3 101.569(9) . . ?
Ag6 Ag8 Ag3 105.201(9) 2_666 . ?
Ag6 Ag8 Ag7 56.274(7) 2_666 2_666 ?
Ag6 Ag8 Ag7 96.558(9) . 2_666 ?
Ag6 Ag8 Cu1 99.609(10) 2_666 . ?
Ag3 Ag8 Ag4 153.336(9) . . ?
Ag3 Ag8 Ag2 143.565(9) . . ?
Ag3 Ag8 Ag7 56.880(8) . 2_666 ?
Ag7 Ag8 Ag4 111.301(8) 2_666 . ?
Ag7 Ag8 Ag2 94.509(8) 2_666 . ?
Cu1 Ag8 Ag4 108.368(10) . . ?
Cu1 Ag8 Ag6 56.720(9) . . ?
Cu1 Ag8 Ag2 160.547(11) . . ?
Cu1 Ag8 Ag3 52.565(9) . . ?
Cu1 Ag8 Ag7 90.463(10) . 2_666 ?
C1 Ag8 Ag4 122.95(8) 2_666 . ?
C1 Ag8 Ag6 134.63(8) 2_666 . ?
C1 Ag8 Ag6 82.44(8) 2_666 2_666 ?
C1 Ag8 Ag2 78.47(8) 2_666 . ?
C1 Ag8 Ag3 65.10(8) 2_666 . ?
C1 Ag8 Ag7 38.85(8) 2_666 2_666 ?
C1 Ag8 Cu1 115.98(8) 2_666 . ?
C4 Ag8 Ag4 134.17(7) . . ?
C4 Ag8 Ag6 96.33(7) . . ?
C4 Ag8 Ag6 142.03(7) . 2_666 ?
C4 Ag8 Ag2 149.78(7) . . ?
C4 Ag8 Ag3 48.41(7) . . ?
C4 Ag8 Ag7 105.27(7) . 2_666 ?
C4 Ag8 Cu1 43.92(7) . . ?
C4 Ag8 C1 102.84(10) . 2_666 ?
C4 Ag8 C16 117.53(10) . . ?
C16 Ag8 Ag4 47.76(7) . . ?
C16 Ag8 Ag6 96.04(7) . . ?
C16 Ag8 Ag6 94.63(7) . 2_666 ?
C16 Ag8 Ag2 38.97(7) . . ?
C16 Ag8 Ag3 158.39(7) . . ?
C16 Ag8 Ag7 133.48(7) . 2_666 ?
C16 Ag8 Cu1 132.98(7) . . ?
C16 Ag8 C1 110.17(11) . 2_666 ?
Ag4 Ag2 Ag8 63.229(7) . . ?
Ag5 Ag2 Ag4 83.263(8) . . ?
Ag5 Ag2 Ag8 122.008(9) . . ?
C10 Ag2 Ag4 135.15(8) . . ?
C10 Ag2 Ag8 142.71(9) . . ?
C10 Ag2 Ag5 52.39(8) . . ?
C10 Ag2 C16 165.03(12) . . ?
C16 Ag2 Ag4 55.52(8) . . ?
C16 Ag2 Ag8 47.06(8) . . ?
C16 Ag2 Ag5 138.43(8) . . ?
Cu1 Ag5 Ag2 98.081(11) 2_666 . ?
P2 Ag5 Ag2 154.87(2) . . ?
P2 Ag5 Cu1 106.95(2) . 2_666 ?
P2 Ag5 C6 105.27(7) . 2_666 ?
P2 Ag5 C26 111.82(6) . 2_666 ?
C6 Ag5 Ag2 94.02(6) 2_666 . ?
C6 Ag5 Cu1 44.40(7) 2_666 2_666 ?
C6 Ag5 C26 86.99(9) 2_666 2_666 ?
C10 Ag5 Ag2 46.07(8) . . ?
C10 Ag5 Cu1 141.12(8) . 2_666 ?
C10 Ag5 P2 110.19(8) . . ?
C10 Ag5 C6 112.87(11) . 2_666 ?
C10 Ag5 C26 125.90(10) . 2_666 ?
C26 Ag5 Ag2 84.68(6) 2_666 . ?
C26 Ag5 Cu1 44.08(7) 2_666 2_666 ?
Ag7 Ag3 Ag8 61.769(8) 2_666 . ?
Cu1 Ag3 Ag8 58.467(10) . . ?
Cu1 Ag3 Ag7 97.862(11) . 2_666 ?
P1 Ag3 Ag8 145.77(2) . . ?
P1 Ag3 Ag7 106.12(2) . 2_666 ?
P1 Ag3 Cu1 152.82(2) . . ?
P1 Ag3 C26 121.06(7) . . ?
C4 Ag3 Ag8 50.32(7) . . ?
C4 Ag3 Ag7 112.08(7) . 2_666 ?
C4 Ag3 Cu1 46.86(7) . . ?
C4 Ag3 P1 129.62(7) . . ?
C4 Ag3 C26 90.34(10) . . ?
C26 Ag3 Ag8 92.15(7) . . ?
C26 Ag3 Ag7 90.91(6) . 2_666 ?
C26 Ag3 Cu1 44.66(7) . . ?
Ag4 Ag7 Ag8 76.437(8) . 2_666 ?
Ag4 Ag7 Ag3 77.836(9) . 2_666 ?
Ag6 Ag7 Ag4 58.413(8) . . ?
Ag6 Ag7 Ag8 56.609(7) . 2_666 ?
Ag6 Ag7 Ag3 109.332(10) . 2_666 ?
Ag3 Ag7 Ag8 61.349(8) 2_666 2_666 ?
C1 Ag7 Ag4 127.71(9) . . ?
C1 Ag7 Ag6 92.04(9) . . ?
C1 Ag7 Ag8 51.59(9) . 2_666 ?
C1 Ag7 Ag3 73.02(10) . 2_666 ?
C1 Ag7 C14 177.13(12) . . ?
C14 Ag7 Ag4 55.15(8) . . ?
C14 Ag7 Ag6 89.89(8) . . ?
C14 Ag7 Ag8 131.27(8) . 2_666 ?
C14 Ag7 Ag3 108.33(9) . 2_666 ?
Ag6 Cu1 Ag4 58.111(9) . 2_666 ?
Ag6 Cu1 Ag8 63.279(10) . . ?
Ag8 Cu1 Ag4 77.694(10) . 2_666 ?
Ag5 Cu1 Ag4 81.437(11) 2_666 2_666 ?
Ag5 Cu1 Ag6 87.827(12) 2_666 . ?
Ag5 Cu1 Ag8 150.350(14) 2_666 . ?
Ag3 Cu1 Ag4 79.440(11) . 2_666 ?
Ag3 Cu1 Ag6 120.626(14) . . ?
Ag3 Cu1 Ag8 68.968(11) . . ?
Ag3 Cu1 Ag5 127.291(15) . 2_666 ?
C4 Cu1 Ag4 125.83(8) . 2_666 ?
C4 Cu1 Ag6 113.98(8) . . ?
C4 Cu1 Ag8 56.89(8) . . ?
C4 Cu1 Ag5 150.98(8) . 2_666 ?
C4 Cu1 Ag3 58.88(8) . . ?
C6 Cu1 Ag4 103.33(8) . 2_666 ?
C6 Cu1 Ag6 55.88(8) . . ?
C6 Cu1 Ag8 102.66(8) . . ?
C6 Cu1 Ag5 62.07(8) . 2_666 ?
C6 Cu1 Ag3 170.64(8) . . ?
C6 Cu1 C4 113.39(12) . . ?
C6 Cu1 C26 122.78(12) . . ?
C26 Cu1 Ag4 51.46(8) . 2_666 ?
C26 Cu1 Ag6 106.06(8) . . ?
C26 Cu1 Ag8 115.90(9) . . ?
C26 Cu1 Ag5 63.65(8) . 2_666 ?
C26 Cu1 Ag3 66.00(8) . . ?
C26 Cu1 C4 122.72(12) . . ?
C34 P1 Ag3 110.30(10) . . ?
C78 P1 Ag3 112.23(10) . . ?
C78 P1 C34 104.90(15) . . ?
C78 P1 C80 107.43(14) . . ?
C80 P1 Ag3 115.18(10) . . ?
C80 P1 C34 106.13(14) . . ?
C60 P2 Ag5 110.15(10) . . ?
C60 P2 C76 105.86(14) . . ?
C60 P2 C98 104.65(14) . . ?
C76 P2 Ag5 116.47(10) . . ?
C76 P2 C98 105.95(14) . . ?
C98 P2 Ag5 112.88(10) . . ?
Ag7 C1 Ag8 89.56(12) . 2_666 ?
C36 C1 Ag8 98.4(2) . 2_666 ?
C36 C1 Ag7 172.0(3) . . ?
Ag3 C4 Ag8 81.27(9) . . ?
Cu1 C4 Ag8 79.19(9) . . ?
Cu1 C4 Ag3 74.26(9) . . ?
C8 C4 Ag8 120.5(2) . . ?
C8 C4 Ag3 119.0(2) . . ?
C8 C4 Cu1 156.4(3) . . ?
Ag6 C6 Ag5 103.55(11) . 2_666 ?
Cu1 C6 Ag6 78.85(10) . . ?
Cu1 C6 Ag5 73.53(9) . 2_666 ?
C40 C6 Ag6 98.8(2) . . ?
C40 C6 Ag5 107.6(2) . 2_666 ?
C40 C6 Cu1 177.6(3) . . ?
C4 C8 C46 177.0(3) . . ?
Ag2 C10 Ag5 81.54(10) . . ?
C94 C10 Ag2 152.3(3) . . ?
C94 C10 Ag5 125.0(2) . . ?
C26 C12 C20 175.5(3) . . ?
Ag7 C14 Ag4 83.28(10) . . ?
C22 C14 Ag4 99.8(2) . . ?
C22 C14 Ag7 176.8(3) . . ?
Ag8 C16 Ag4 84.68(9) . . ?
Ag2 C16 Ag4 79.59(9) . . ?
Ag2 C16 Ag8 93.97(11) . . ?
C50 C16 Ag4 119.7(2) . . ?
C50 C16 Ag8 93.3(2) . . ?
C50 C16 Ag2 160.0(2) . . ?
C48 C18 C52 119.1(3) . . ?
C48 C18 C94 119.6(3) . . ?
C52 C18 C94 121.2(3) . . ?
C24 C20 C12 119.4(3) . . ?
C104 C20 C12 121.6(3) . . ?
C104 C20 C24 119.0(3) . . ?
C14 C22 C90 177.0(3) . . ?
C20 C24 H24 120.0 . . ?
C79 C24 C20 120.1(3) . . ?
C79 C24 H24 120.0 . . ?
Ag4 C26 Ag5 99.79(10) 2_666 2_666 ?
Ag4 C26 Ag3 95.04(10) 2_666 . ?
Ag5 C26 Ag3 138.48(12) 2_666 . ?
Cu1 C26 Ag4 89.36(11) . 2_666 ?
Cu1 C26 Ag5 72.27(9) . 2_666 ?
Cu1 C26 Ag3 69.34(9) . . ?
C12 C26 Ag4 91.4(2) . 2_666 ?
C12 C26 Ag5 109.0(2) . 2_666 ?
C12 C26 Ag3 109.2(2) . . ?
C12 C26 Cu1 178.4(3) . . ?
C56 C28 H28 120.4 . . ?
C58 C28 H28 120.4 . . ?
C58 C28 C56 119.3(3) . . ?
C54 C30 H30 120.2 . . ?
C59 C30 H30 120.2 . . ?
C59 C30 C54 119.5(3) . . ?
C68 C32 H32 119.8 . . ?
C68 C32 C92 120.3(3) . . ?
C92 C32 H32 119.8 . . ?
C84 C34 P1 117.9(2) . . ?
C45 C34 P1 122.7(3) . . ?
C45 C34 C84 119.3(3) . . ?
C1 C36 C68 172.6(3) . . ?
C56 C38 H38 120.1 . . ?
C96 C38 H38 120.1 . . ?
C96 C38 C56 119.8(3) . . ?
C6 C40 C54 176.2(3) . . ?
C44 C42 H42 120.7 . . ?
C44 C42 C66 118.6(3) . . ?
C66 C42 H42 120.7 . . ?
C42 C44 C48 121.0(3) . . ?
C42 C44 C103 119.5(3) . . ?
C48 C44 C103 119.5(3) . . ?
C62 C46 C8 120.1(3) . . ?
C62 C46 C64 118.9(3) . . ?
C64 C46 C8 121.0(3) . . ?
C18 C48 C44 120.0(3) . . ?
C18 C48 H48 120.0 . . ?
C44 C48 H48 120.0 . . ?
C16 C50 C56 176.1(3) . . ?
C18 C52 H52 120.1 . . ?
C66 C52 C18 119.9(3) . . ?
C66 C52 H52 120.1 . . ?
C30 C54 C40 120.2(3) . . ?
C30 C54 C27 119.4(3) . . ?
C27 C54 C40 120.3(3) . . ?
C28 C56 C50 120.5(3) . . ?
C38 C56 C28 119.9(3) . . ?
C38 C56 C50 119.6(3) . . ?
C28 C58 C102 121.2(3) . . ?
C28 C58 C15 119.4(3) . . ?
C102 C58 C15 119.4(3) . . ?
C61 C60 P2 123.5(2) . . ?
C61 C60 C9 119.2(3) . . ?
C9 C60 P2 117.4(2) . . ?
C46 C62 H62 119.9 . . ?
C74 C62 C46 120.1(3) . . ?
C74 C62 H62 119.9 . . ?
C46 C64 H64 119.9 . . ?
C82 C64 C46 120.1(3) . . ?
C82 C64 H64 119.9 . . ?
C42 C66 C52 121.4(3) . . ?
C42 C66 C41 119.1(3) . . ?
C52 C66 C41 119.5(3) . . ?
C32 C68 C36 121.8(3) . . ?
C32 C68 C108 119.3(3) . . ?
C108 C68 C36 118.9(3) . . ?
C90 C70 H70 120.2 . . ?
C17 C70 H70 120.2 . . ?
C17 C70 C90 119.7(3) . . ?
C76 C72 H72 119.6 . . ?
C106 C72 H72 119.6 . . ?
C106 C72 C76 120.9(3) . . ?
C62 C74 C33 118.5(3) . . ?
C86 C74 C62 121.0(3) . . ?
C86 C74 C33 120.4(3) . . ?
C72 C76 P2 117.7(2) . . ?
C2 C76 P2 123.3(2) . . ?
C2 C76 C72 118.9(3) . . ?
C55 C78 P1 117.0(2) . . ?
C55 C78 C77 119.4(3) . . ?
C77 C78 P1 123.6(3) . . ?
C88 C80 P1 118.3(2) . . ?
C88 C80 C43 119.5(3) . . ?
C43 C80 P1 122.2(3) . . ?
C64 C82 C86 120.9(3) . . ?
C64 C82 C21 119.2(3) . . ?
C86 C82 C21 119.9(3) . . ?
C34 C84 H84 119.9 . . ?
C39 C84 C34 120.2(3) . . ?
C39 C84 H84 119.9 . . ?
C74 C86 C82 118.9(3) . . ?
C74 C86 H86 120.5 . . ?
C82 C86 H86 120.5 . . ?
C80 C88 H88 119.9 . . ?
C69 C88 C80 120.3(3) . . ?
C69 C88 H88 119.9 . . ?
C70 C90 C22 120.6(3) . . ?
C29 C90 C22 120.0(3) . . ?
C29 C90 C70 119.4(3) . . ?
C32 C92 C23 118.2(3) . . ?
C67 C92 C32 120.4(3) . . ?
C67 C92 C23 121.3(3) . . ?
C10 C94 C18 177.2(3) . . ?
C38 C96 C89 120.6(3) . . ?
C102 C96 C38 120.8(3) . . ?
C102 C96 C89 118.6(3) . . ?
C100 C98 P2 123.9(3) . . ?
C100 C98 C71 118.2(3) . . ?
C71 C98 P2 117.7(3) . . ?
C98 C100 H100 119.7 . . ?
C57 C100 C98 120.5(3) . . ?
C57 C100 H100 119.7 . . ?
C58 C102 H102 120.5 . . ?
C96 C102 C58 119.0(3) . . ?
C96 C102 H102 120.5 . . ?
C20 C104 H104 120.2 . . ?
C95 C104 C20 119.5(4) . . ?
C95 C104 H104 120.2 . . ?
C72 C106 H106 120.2 . . ?
C72 C106 C73 119.6(3) . . ?
C73 C106 H106 120.2 . . ?
C68 C108 H108 120.1 . . ?
C11 C108 C68 119.7(3) . . ?
C11 C108 H108 120.1 . . ?
C54 C27 H27 120.1 . . ?
C3 C27 C54 119.8(3) . . ?
C3 C27 H27 120.1 . . ?
C78 C55 H55 119.9 . . ?
C78 C55 C65 120.2(3) . . ?
C65 C55 H55 119.9 . . ?
C31 C7 H7 119.9 . . ?
C65 C7 H7 119.9 . . ?
C65 C7 C31 120.3(3) . . ?
C100 C57 H57 119.6 . . ?
C37 C57 C100 120.8(3) . . ?
C37 C57 H57 119.6 . . ?
C90 C29 H29 120.1 . . ?
C81 C29 C90 119.8(3) . . ?
C81 C29 H29 120.1 . . ?
C30 C59 C19 118.3(3) . . ?
C83 C59 C30 120.9(3) . . ?
C83 C59 C19 120.8(3) . . ?
F6 C15 F14 105.6(3) . . ?
F6 C15 C58 112.6(3) . . ?
F14 C15 C58 111.8(3) . . ?
F32 C15 F6 107.2(3) . . ?
F32 C15 F14 107.5(3) . . ?
F32 C15 C58 111.8(3) . . ?
C60 C61 H61 119.8 . . ?
C63 C61 C60 120.3(3) . . ?
C63 C61 H61 119.8 . . ?
C7 C31 H31 119.9 . . ?
C7 C31 C77 120.3(3) . . ?
C77 C31 H31 119.9 . . ?
C61 C63 H63 119.9 . . ?
C61 C63 C91 120.1(3) . . ?
C91 C63 H63 119.9 . . ?
C76 C2 H2 119.8 . . ?
C35 C2 C76 120.3(3) . . ?
C35 C2 H2 119.8 . . ?
C55 C65 H65 120.0 . . ?
C7 C65 C55 120.0(3) . . ?
C7 C65 H65 120.0 . . ?
F26 C33 C74 112.5(3) . . ?
F40 C33 F26 106.1(3) . . ?
F40 C33 C74 112.8(3) . . ?
F7 C33 F26 105.7(3) . . ?
F7 C33 F40 107.6(4) . . ?
F7 C33 C74 111.7(3) . . ?
C92 C67 H67 120.5 . . ?
C92 C67 C11 119.1(3) . . ?
C11 C67 H67 120.5 . . ?
C70 C17 C13 119.2(4) . . ?
C75 C17 C70 121.1(3) . . ?
C75 C17 C13 119.7(3) . . ?
C88 C69 H69 120.1 . . ?
C85 C69 C88 119.8(4) . . ?
C85 C69 H69 120.1 . . ?
C2 C35 H35 119.8 . . ?
C2 C35 C73 120.5(3) . . ?
C73 C35 H35 119.8 . . ?
C98 C71 H71 119.6 . . ?
C5 C71 C98 120.7(4) . . ?
C5 C71 H71 119.6 . . ?
C60 C9 H9 119.8 . . ?
C25 C9 C60 120.3(3) . . ?
C25 C9 H9 119.8 . . ?
C106 C73 H73 120.1 . . ?
C35 C73 C106 119.9(3) . . ?
C35 C73 H73 120.1 . . ?
C57 C37 H37 120.3 . . ?
C5 C37 C57 119.5(3) . . ?
C5 C37 H37 120.3 . . ?
C17 C75 H75 120.5 . . ?
C81 C75 C17 119.0(3) . . ?
C81 C75 H75 120.5 . . ?
F10 C19 F22 106.8(3) . . ?
F10 C19 C59 112.8(3) . . ?
F22 C19 C59 111.8(3) . . ?
F28 C19 F10 106.2(3) . . ?
F28 C19 F22 106.4(3) . . ?
F28 C19 C59 112.5(3) . . ?
C78 C77 H77 120.1 . . ?
C31 C77 C78 119.8(3) . . ?
C31 C77 H77 120.1 . . ?
C84 C39 H39 120.1 . . ?
C49 C39 C84 119.7(4) . . ?
C49 C39 H39 120.1 . . ?
C24 C79 C47 120.2(3) . . ?
C24 C79 C97 120.9(4) . . ?
C97 C79 C47 118.9(3) . . ?
C71 C5 H5 119.9 . . ?
C37 C5 C71 120.3(4) . . ?
C37 C5 H5 119.9 . . ?
C29 C81 C93 117.6(4) . . ?
C75 C81 C29 121.0(3) . . ?
C75 C81 C93 121.3(3) . . ?
F52 C41 F54 106.1(3) . . ?
F52 C41 F27 107.8(3) . . ?
F52 C41 C66 112.9(3) . . ?
F54 C41 C66 112.7(3) . . ?
F27 C41 F54 104.4(3) . . ?
F27 C41 C66 112.4(3) . . ?
C59 C83 H83 120.3 . . ?
C59 C83 C3 119.4(3) . . ?
C3 C83 H83 120.3 . . ?
F4 C21 F34 106.2(3) . . ?
F4 C21 C82 112.0(3) . . ?
F16 C21 F4 107.5(3) . . ?
F16 C21 F34 107.1(3) . . ?
F16 C21 C82 112.4(3) . . ?
F34 C21 C82 111.3(3) . . ?
C69 C85 H85 119.8 . . ?
C99 C85 C69 120.3(3) . . ?
C99 C85 H85 119.8 . . ?
C80 C43 H43 120.3 . . ?
C99 C43 C80 119.4(3) . . ?
C99 C43 H43 120.3 . . ?
F1 C87 C11 112.7(3) . . ?
F18 C87 F1 106.0(3) . . ?
F18 C87 F44 107.8(3) . . ?
F18 C87 C11 112.5(3) . . ?
F44 C87 F1 106.3(3) . . ?
F44 C87 C11 111.1(3) . . ?
C108 C11 C67 121.1(3) . . ?
C108 C11 C87 118.8(3) . . ?
C67 C11 C87 120.0(3) . . ?
F20 C89 C96 111.5(3) . . ?
F24 C89 F20 106.7(3) . . ?
F24 C89 F30 106.4(3) . . ?
F24 C89 C96 112.2(3) . . ?
F30 C89 F20 107.3(3) . . ?
F30 C89 C96 112.3(3) . . ?
C34 C45 H45 120.0 . . ?
C34 C45 C101 120.0(4) . . ?
C101 C45 H45 120.0 . . ?
C63 C91 H91 120.1 . . ?
C25 C91 C63 119.8(4) . . ?
C25 C91 H91 120.1 . . ?
F8 C23 F36 106.7(3) . . ?
F8 C23 F48 106.4(3) . . ?
F8 C23 C92 112.2(3) . . ?
F36 C23 C92 112.5(3) . . ?
F48 C23 F36 106.7(3) . . ?
F48 C23 C92 112.0(3) . . ?
F42 C93 C81 112.8(4) . . ?
F46 C93 F42 107.0(4) . . ?
F46 C93 F29 107.5(4) . . ?
F46 C93 C81 111.8(4) . . ?
F29 C93 F42 106.2(4) . . ?
F29 C93 C81 111.2(4) . . ?
F12 C47 F38 106.6(3) . . ?
F12 C47 F50 108.6(4) . . ?
F12 C47 C79 112.2(3) . . ?
F38 C47 C79 112.3(4) . . ?
F50 C47 F38 105.6(3) . . ?
F50 C47 C79 111.1(3) . . ?
C104 C95 C53 126.0(6) . . ?
C104 C95 C107 111.5(6) . . ?
C97 C95 C104 121.4(4) . . ?
C97 C95 C53 112.4(6) . . ?
C97 C95 C107 127.1(6) . . ?
C27 C3 C51 120.0(4) . . ?
C27 C3 C105 117.5(5) . . ?
C83 C3 C27 120.9(3) . . ?
C83 C3 C51 117.9(4) . . ?
C83 C3 C105 119.9(5) . . ?
C79 C97 H97 120.5 . . ?
C95 C97 C79 119.0(4) . . ?
C95 C97 H97 120.5 . . ?
C39 C49 H49 119.9 . . ?
C101 C49 C39 120.1(4) . . ?
C101 C49 H49 119.9 . . ?
C85 C99 C43 120.6(4) . . ?
C85 C99 H99 119.7 . . ?
C43 C99 H99 119.7 . . ?
C9 C25 C91 120.2(4) . . ?
C9 C25 H25 119.9 . . ?
C91 C25 H25 119.9 . . ?
C45 C101 H101 119.7 . . ?
C49 C101 C45 120.5(4) . . ?
C49 C101 H101 119.7 . . ?
F15 C51 C3 109.3(5) . . ?
F15 C51 F31 106.7(8) . . ?
F31 C51 C3 105.4(8) . . ?
F2 C51 C3 115.8(7) . . ?
F2 C51 F15 107.0(7) . . ?
F2 C51 F31 112.4(8) . . ?
F33 C103 C44 113.6(4) . . ?
F33 C103 F17 105.5(5) . . ?
F33 C103 F35 108.1(5) . . ?
F17 C103 C44 112.9(3) . . ?
F35 C103 C44 113.0(4) . . ?
F35 C103 F17 102.9(5) . . ?
F39 C103 C44 110.3(4) . . ?
F5 C103 C44 114.0(4) . . ?
F5 C103 F39 117.9(7) . . ?
F5 C103 F41 105.0(7) . . ?
F41 C103 C44 110.8(4) . . ?
F41 C103 F39 97.3(6) . . ?
F9 C13 C17 110.1(4) . . ?
F9 C13 F37 105.6(6) . . ?
F9 C13 F19 114.0(7) . . ?
F37 C13 C17 109.6(4) . . ?
F19 C13 C17 110.5(5) . . ?
F19 C13 F37 106.9(6) . . ?
F21 C13 C17 114.8(4) . . ?
F21 C13 F11 97.6(6) . . ?
F43 C13 C17 115.0(5) . . ?
F43 C13 F21 110.2(6) . . ?
F43 C13 F11 101.6(6) . . ?
F11 C13 C17 115.4(4) . . ?
F45 C105 C3 109.3(7) . . ?
F45 C105 F23 101.6(9) . . ?
F45 C105 F47 99.9(11) . . ?
F23 C105 C3 120.1(7) . . ?
F47 C105 C3 110.1(8) . . ?
F47 C105 F23 113.5(10) . . ?
F3 C53 C95 113.2(8) . . ?
F3 C53 F49 106.4(9) . . ?
F49 C53 C95 110.7(8) . . ?
F25 C53 C95 108.7(8) . . ?
F25 C53 F3 110.5(10) . . ?
F25 C53 F49 107.2(10) . . ?
F51 C107 C95 113.2(9) . . ?
F13 C107 C95 112.5(9) . . ?
F13 C107 F51 107.2(10) . . ?
F13 C107 F53 104.3(11) . . ?
F53 C107 C95 117.0(9) . . ?
F53 C107 F51 101.4(12) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag4 Ag6 2.7903(3) . ?
Ag4 Ag6 2.8507(3) 2_666 ?
Ag4 Ag8 3.2483(3) . ?
Ag4 Ag2 2.8820(3) . ?
Ag4 Ag7 2.9243(3) . ?
Ag4 Cu1 3.1130(4) 2_666 ?
Ag4 C14 2.416(3) . ?
Ag4 C16 2.415(3) . ?
Ag4 C26 2.435(3) 2_666 ?
Ag6 Ag6 2.7823(4) 2_666 ?
Ag6 Ag8 2.8982(3) . ?
Ag6 Ag8 2.7998(3) 2_666 ?
Ag6 Ag7 2.7889(3) . ?
Ag6 Cu1 2.7126(4) . ?
Ag6 C6 2.289(3) . ?
Ag8 Ag2 3.2808(3) . ?
Ag8 Ag3 3.0772(3) . ?
Ag8 Ag7 3.0894(3) 2_666 ?
Ag8 Cu1 2.8101(4) . ?
Ag8 C1 2.421(3) 2_666 ?
Ag8 C4 2.396(3) . ?
Ag8 C16 2.408(3) . ?
Ag2 Ag5 2.8384(3) . ?
Ag2 C10 2.067(3) . ?
Ag2 C16 2.068(3) . ?
Ag5 Cu1 2.6924(4) 2_666 ?
Ag5 P2 2.4488(7) . ?
Ag5 C6 2.481(3) 2_666 ?
Ag5 C10 2.273(3) . ?
Ag5 C26 2.533(3) 2_666 ?
Ag3 Ag7 2.9368(4) 2_666 ?
Ag3 Cu1 2.6178(4) . ?
Ag3 P1 2.3909(7) . ?
Ag3 C4 2.328(3) . ?
Ag3 C26 2.556(3) . ?
Ag7 C1 1.938(3) . ?
Ag7 C14 1.954(3) . ?
Cu1 C4 1.984(3) . ?
Cu1 C6 1.964(3) . ?
Cu1 C26 1.966(3) . ?
P1 C34 1.818(3) . ?
P1 C78 1.816(3) . ?
P1 C80 1.816(3) . ?
P2 C60 1.818(3) . ?
P2 C76 1.819(3) . ?
P2 C98 1.821(3) . ?
F1 C87 1.335(4) . ?
F4 C21 1.334(4) . ?
F6 C15 1.330(4) . ?
F8 C23 1.329(4) . ?
F10 C19 1.339(5) . ?
F12 C47 1.327(5) . ?
F14 C15 1.333(4) . ?
F16 C21 1.329(4) . ?
F18 C87 1.330(5) . ?
F20 C89 1.333(5) . ?
F22 C19 1.343(4) . ?
F24 C89 1.332(5) . ?
F26 C33 1.336(4) . ?
F28 C19 1.335(4) . ?
F30 C89 1.333(5) . ?
F32 C15 1.324(4) . ?
F34 C21 1.340(5) . ?
F36 C23 1.336(4) . ?
F38 C47 1.337(4) . ?
F40 C33 1.321(5) . ?
F42 C93 1.336(5) . ?
F44 C87 1.333(4) . ?
F46 C93 1.334(5) . ?
F48 C23 1.333(5) . ?
F50 C47 1.335(5) . ?
F52 C41 1.321(4) . ?
C1 C36 1.226(5) . ?
C4 C8 1.221(4) . ?
F54 C41 1.333(4) . ?
F27 C41 1.325(4) . ?
F7 C33 1.320(5) . ?
F29 C93 1.336(6) . ?
C6 C40 1.219(4) . ?
C8 C46 1.437(4) . ?
C10 C94 1.211(4) . ?
C12 C20 1.442(4) . ?
C12 C26 1.224(4) . ?
C14 C22 1.225(4) . ?
C16 C50 1.220(4) . ?
C18 C48 1.393(4) . ?
C18 C52 1.399(4) . ?
C18 C94 1.444(4) . ?
C20 C24 1.401(5) . ?
C20 C104 1.396(5) . ?
C22 C90 1.432(4) . ?
C24 H24 0.9500 . ?
C24 C79 1.380(4) . ?
C28 H28 0.9500 . ?
C28 C56 1.402(4) . ?
C28 C58 1.388(4) . ?
C30 H30 0.9500 . ?
C30 C54 1.398(4) . ?
C30 C59 1.391(4) . ?
C32 H32 0.9500 . ?
C32 C68 1.393(5) . ?
C32 C92 1.395(4) . ?
C34 C84 1.398(5) . ?
C34 C45 1.392(5) . ?
C36 C68 1.432(4) . ?
C38 H38 0.9500 . ?
C38 C56 1.398(4) . ?
C38 C96 1.389(4) . ?
C40 C54 1.438(4) . ?
C42 H42 0.9500 . ?
C42 C44 1.386(5) . ?
C42 C66 1.386(4) . ?
C44 C48 1.395(4) . ?
C44 C103 1.502(5) . ?
C46 C62 1.400(4) . ?
C46 C64 1.401(4) . ?
C48 H48 0.9500 . ?
C50 C56 1.436(4) . ?
C52 H52 0.9500 . ?
C52 C66 1.386(4) . ?
C54 C27 1.398(5) . ?
C58 C102 1.395(4) . ?
C58 C15 1.505(4) . ?
C60 C61 1.394(4) . ?
C60 C9 1.400(4) . ?
C62 H62 0.9500 . ?
C62 C74 1.390(4) . ?
C64 H64 0.9500 . ?
C64 C82 1.390(4) . ?
C66 C41 1.497(4) . ?
C68 C108 1.401(4) . ?
C70 H70 0.9500 . ?
C70 C90 1.404(4) . ?
C70 C17 1.392(4) . ?
C72 H72 0.9500 . ?
C72 C76 1.399(4) . ?
C72 C106 1.386(4) . ?
C74 C86 1.386(5) . ?
C74 C33 1.502(4) . ?
C76 C2 1.392(4) . ?
C78 C55 1.391(4) . ?
C78 C77 1.397(4) . ?
C80 C88 1.394(5) . ?
C80 C43 1.402(4) . ?
C82 C86 1.391(4) . ?
C82 C21 1.503(5) . ?
C84 H84 0.9500 . ?
C84 C39 1.396(5) . ?
C86 H86 0.9500 . ?
C88 H88 0.9500 . ?
C88 C69 1.390(5) . ?
C90 C29 1.396(4) . ?
C92 C67 1.390(4) . ?
C92 C23 1.500(5) . ?
C96 C102 1.389(5) . ?
C96 C89 1.500(4) . ?
C98 C100 1.394(5) . ?
C98 C71 1.399(5) . ?
C100 H100 0.9500 . ?
C100 C57 1.381(5) . ?
C102 H102 0.9500 . ?
C104 H104 0.9500 . ?
C104 C95 1.394(6) . ?
C106 H106 0.9500 . ?
C106 C73 1.391(5) . ?
C108 H108 0.9500 . ?
C108 C11 1.388(5) . ?
C27 H27 0.9500 . ?
C27 C3 1.385(5) . ?
C55 H55 0.9500 . ?
C55 C65 1.396(5) . ?
C7 H7 0.9500 . ?
C7 C31 1.386(6) . ?
C7 C65 1.373(6) . ?
C57 H57 0.9500 . ?
C57 C37 1.381(6) . ?
C29 H29 0.9500 . ?
C29 C81 1.395(5) . ?
C59 C19 1.498(5) . ?
C59 C83 1.380(5) . ?
C61 H61 0.9500 . ?
C61 C63 1.383(5) . ?
C31 H31 0.9500 . ?
C31 C77 1.390(5) . ?
C63 H63 0.9500 . ?
C63 C91 1.390(6) . ?
C2 H2 0.9500 . ?
C2 C35 1.386(5) . ?
C65 H65 0.9500 . ?
C67 H67 0.9500 . ?
C67 C11 1.390(5) . ?
C17 C75 1.389(6) . ?
C17 C13 1.500(5) . ?
C69 H69 0.9500 . ?
C69 C85 1.388(6) . ?
C35 H35 0.9500 . ?
C35 C73 1.386(5) . ?
C71 H71 0.9500 . ?
C71 C5 1.385(5) . ?
C9 H9 0.9500 . ?
C9 C25 1.379(5) . ?
C73 H73 0.9500 . ?
C37 H37 0.9500 . ?
C37 C5 1.379(6) . ?
C75 H75 0.9500 . ?
C75 C81 1.386(6) . ?
C77 H77 0.9500 . ?
C39 H39 0.9500 . ?
C39 C49 1.392(6) . ?
C79 C47 1.503(6) . ?
C79 C97 1.389(6) . ?
C5 H5 0.9500 . ?
C81 C93 1.502(6) . ?
C83 H83 0.9500 . ?
C83 C3 1.383(5) . ?
C85 H85 0.9500 . ?
C85 C99 1.374(6) . ?
C43 H43 0.9500 . ?
C43 C99 1.394(5) . ?
C87 C11 1.501(4) . ?
C45 H45 0.9500 . ?
C45 C101 1.395(6) . ?
C91 H91 0.9500 . ?
C91 C25 1.389(6) . ?
C95 C97 1.369(8) . ?
C95 C53 1.498(10) . ?
C95 C107 1.521(11) . ?
C3 C51 1.528(7) . ?
C3 C105 1.532(7) . ?
C97 H97 0.9500 . ?
C49 H49 0.9500 . ?
C49 C101 1.375(7) . ?
C99 H99 0.9500 . ?
C25 H25 0.9500 . ?
C101 H101 0.9500 . ?
C51 F15 1.333(8) . ?
C51 F31 1.365(9) . ?
C51 F2 1.312(9) . ?
C103 F33 1.278(6) . ?
C103 F17 1.332(5) . ?
C103 F35 1.323(6) . ?
C103 F39 1.345(8) . ?
C103 F5 1.264(8) . ?
C103 F41 1.345(7) . ?
C13 F9 1.269(7) . ?
C13 F37 1.340(6) . ?
C13 F19 1.284(7) . ?
C13 F21 1.327(7) . ?
C13 F43 1.300(7) . ?
C13 F11 1.360(7) . ?
C105 F45 1.308(10) . ?
C105 F23 1.329(10) . ?
C105 F47 1.321(10) . ?
C53 F3 1.323(10) . ?
C53 F49 1.348(10) . ?
C53 F25 1.309(10) . ?
C107 F51 1.341(11) . ?
C107 F13 1.330(11) . ?
C107 F53 1.332(12) . ?
loop_
_smtbx_masks_void_nr
_smtbx_masks_void_average_x
_smtbx_masks_void_average_y
_smtbx_masks_void_average_z
_smtbx_masks_void_volume
_smtbx_masks_void_count_electrons
_smtbx_masks_void_content
1 0.078 0.182 0.459 25.1 0.0 ?
2 0.000 0.500 0.000 738.8 129.8 ?
3 -0.078 0.818 0.541 25.1 0.0 ?
