#------------------------------------------------------------------------------
#$Date: 2023-11-01 02:01:48 +0200 (Wed, 01 Nov 2023) $
#$Revision: 287184 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/71/43/7714357.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7714357
loop_
_publ_author_name
'Kolos, Andrey'
'Nelyubina, Yulia V.'
'Podyacheva, Evgeniya'
'Perekalin, Dmitry S.'
_publ_section_title
;
 Rhodium complexes with planar-chiral cyclopentadienyl ligands: synthesis
 from tert-butylacetylene and catalytic performance in C-H activation of
 arylhydroxamates
;
_journal_name_full               'Dalton Transactions'
_journal_paper_doi               10.1039/D3DT03279E
_journal_year                    2023
_chemical_formula_moiety         'Br4 In, C26 H42 Rh'
_chemical_formula_sum            'C26 H42 Br4 In Rh'
_chemical_formula_weight         891.96
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2yn'
_space_group_name_H-M_alt        'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_audit_creation_date             2023-08-14
_audit_creation_method
;
Olex2 1.3
(compiled 2020.11.12 svn.r5f609507 for OlexSys, GUI svn.r6408)
;
_audit_update_record
;
2023-08-14 deposited with the CCDC.	2023-10-31 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 107.520(10)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   15.871(3)
_cell_length_b                   12.1783(17)
_cell_length_c                   16.655(3)
_cell_measurement_reflns_used    5164
_cell_measurement_temperature    100
_cell_measurement_theta_max      30.17
_cell_measurement_theta_min      2.28
_cell_volume                     3069.8(9)
_computing_molecular_graphics    'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_structure_refinement  'XL  (Sheldrick, 2008)'
_computing_structure_solution    'SHELXT 2014/4 (Sheldrick, 2014)'
_diffrn_ambient_temperature      100
_diffrn_measured_fraction_theta_full 0.973
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Bruker Quest D8'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.1166
_diffrn_reflns_av_unetI/netI     0.1045
_diffrn_reflns_Laue_measured_fraction_full 0.973
_diffrn_reflns_Laue_measured_fraction_max 0.999
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            21908
_diffrn_reflns_point_group_measured_fraction_full 0.973
_diffrn_reflns_point_group_measured_fraction_max 0.999
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         24.998
_diffrn_reflns_theta_min         2.107
_diffrn_source_current           1.4
_diffrn_source_power             0.07
_diffrn_source_voltage           50.0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    6.508
_exptl_absorpt_correction_T_max  0.0327
_exptl_absorpt_correction_T_min  0.0073
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
SADABS-2008/1 (Bruker,2008) was used for absorption correction.
wR2(int) was 0.1269 before and 0.0787 after correction.
The Ratio of minimum to maximum transmission is 0.2232.
The λ/2 correction factor is 0.0015.
;
_exptl_crystal_colour            red
_exptl_crystal_colour_primary    red
_exptl_crystal_density_diffrn    1.930
_exptl_crystal_description       plate
_exptl_crystal_F_000             1728
_exptl_crystal_size_max          0.15
_exptl_crystal_size_mid          0.03
_exptl_crystal_size_min          0.03
_refine_diff_density_max         2.710
_refine_diff_density_min         -1.294
_refine_diff_density_rms         0.343
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.084
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     314
_refine_ls_number_reflns         5398
_refine_ls_number_restraints     52
_refine_ls_restrained_S_all      1.079
_refine_ls_R_factor_all          0.2029
_refine_ls_R_factor_gt           0.1583
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.1060P)²+372.3386P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.3806
_refine_ls_wR_factor_ref         0.4089
_reflns_Friedel_coverage         0.000
_reflns_number_gt                3403
_reflns_number_total             5398
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d3dt03279e2.cif
_cod_data_source_block           fulvene-InBr4
_cod_original_cell_volume        3069.9(8)
_cod_database_code               7714357
_shelxl_version_number           2014/6
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_max   0.562
_shelx_estimated_absorpt_t_min   0.442
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2. Restrained distances
 C14'-C12
 2.2 with sigma of 0.02
 C13'-C12
 2.2 with sigma of 0.02
 C11-C14 \\sim C14'-C11
 with sigma of 0.02
 C11-C13 \\sim C13'-C11
 with sigma of 0.02
3. Uiso/Uaniso restraints and constraints
Uanis(C24) \\sim Ueq: with sigma of 0.005 and sigma for terminal atoms of 0.01
Uanis(C13) \\sim Ueq, Uanis(C14) \\sim Ueq: with sigma of 0.005 and sigma for
terminal atoms of 0.01
Uanis(C2) \\sim Ueq: with sigma of 0.005 and sigma for terminal atoms of 0.01
Uanis(C3) \\sim Ueq, Uanis(C4) \\sim Ueq: with sigma of 0.005 and sigma for
terminal atoms of 0.01
Uanis(C20) \\sim Ueq, Uanis(C26) \\sim Ueq: with sigma of 0.005 and sigma for
terminal atoms of 0.01
Uanis(C14) = Uanis(C14')
Uanis(C13) = Uanis(C13')
Uanis(In1') = Uanis(In1)
Uanis(Rh1') = Uanis(Rh1)
4. Others
 Sof(C13')=Sof(H13D)=Sof(H13E)=Sof(H13F)=Sof(C14')=Sof(H14D)=Sof(H14E)=
 Sof(H14F)=1-FVAR(1)
 Sof(C13)=Sof(H13A)=Sof(H13B)=Sof(H13C)=Sof(C14)=Sof(H14A)=Sof(H14B)=Sof(H14C)=
 FVAR(1)
 Sof(In1')=1-FVAR(2)
 Sof(In1)=FVAR(2)
 Sof(Rh1')=1-FVAR(3)
 Sof(Rh1)=FVAR(3)
5.a Ternary CH refined with riding coordinates:
 C19(H19), C20(H20), C23(H23), C24(H24)
5.b Secondary CH2 refined with riding coordinates:
 C21(H21A,H21B), C22(H22A,H22B), C25(H25A,H25B), C26(H26A,H26B)
5.c Me refined with riding coordinates:
 C14'(H14D,H14E,H14F)
5.d Aromatic/amide H refined with riding coordinates:
 C2(H2), C4(H4), C6(H6)
5.e Idealised Me refined as rotating group:
 C8(H8A,H8B,H8C), C9(H9A,H9B,H9C), C10(H10A,H10B,H10C), C12(H12A,H12B,H12C),
 C16(H16A,H16B,H16C), C17(H17A,H17B,H17C), C18(H18A,H18B,H18C), C13(H13A,H13B,
 H13C), C14(H14A,H14B,H14C), C13'(H13D,H13E,H13F)
;
_olex2_submission_special_instructions 'No special instructions were received'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Br1 Br 0.5101(3) 0.2594(3) 0.9091(3) 0.0635(11) Uani 1 1 d . . . . .
Br2 Br 0.6649(3) 0.3009(3) 0.7556(3) 0.0686(11) Uani 1 1 d . . . . .
Br3 Br 0.4125(3) 0.4317(3) 0.6953(3) 0.0729(12) Uani 1 1 d . . . . .
Br4 Br 0.4568(3) 0.0990(3) 0.6864(3) 0.0653(11) Uani 1 1 d . . . . .
In1 In 0.5091(2) 0.27439(19) 0.7609(2) 0.0479(10) Uani 0.962(10) 1 d . . P A 1
In1' In 0.535(6) 0.268(5) 0.730(6) 0.0479(10) Uani 0.038(10) 1 d . . P A 2
Rh1 Rh 0.2789(2) 0.8122(2) 0.5163(2) 0.0466(9) Uani 0.947(6) 1 d . . P J .
C1 C 0.354(2) 0.707(3) 0.6239(18) 0.048(8) Uani 1 1 d . . . . .
C2 C 0.2665(19) 0.663(2) 0.5783(19) 0.039(7) Uani 1 1 d . U . . .
H2 H 0.2191 0.6555 0.6017 0.047 Uiso 1 1 calc R U . B 2
C3 C 0.263(2) 0.638(3) 0.507(2) 0.053(8) Uani 1 1 d . U . . .
C4 C 0.343(2) 0.651(3) 0.488(2) 0.055(8) Uani 1 1 d . U . . .
H4 H 0.3554 0.6273 0.4387 0.066 Uiso 1 1 calc R U . J .
C5 C 0.405(2) 0.708(3) 0.559(2) 0.057(9) Uani 1 1 d . . . . .
C6 C 0.381(3) 0.767(3) 0.695(2) 0.068(11) Uani 1 1 d . . . . .
H6 H 0.4322 0.8105 0.7019 0.081 Uiso 1 1 calc R U . . .
C7 C 0.341(2) 0.772(3) 0.762(2) 0.063(10) Uani 1 1 d . . . . .
C8 C 0.257(2) 0.720(2) 0.758(2) 0.056(9) Uani 1 1 d . . . . .
H8A H 0.2636 0.6405 0.7556 0.084 Uiso 1 1 calc R U . . .
H8B H 0.2120 0.7453 0.7067 0.084 Uiso 1 1 calc R U . . .
H8C H 0.2401 0.7406 0.8074 0.084 Uiso 1 1 calc R U . . .
C9 C 0.409(3) 0.734(4) 0.837(3) 0.077(12) Uani 1 1 d . . . . .
H9A H 0.3889 0.7430 0.8866 0.115 Uiso 1 1 calc R U . . .
H9B H 0.4632 0.7778 0.8444 0.115 Uiso 1 1 calc R U . . .
H9C H 0.4223 0.6566 0.8304 0.115 Uiso 1 1 calc R U . . .
C10 C 0.323(3) 0.901(3) 0.780(3) 0.078(12) Uani 1 1 d . . . . .
H10A H 0.2753 0.9294 0.7322 0.117 Uiso 1 1 calc R U . . .
H10B H 0.3770 0.9432 0.7855 0.117 Uiso 1 1 calc R U . . .
H10C H 0.3062 0.9064 0.8314 0.117 Uiso 1 1 calc R U . . .
C11 C 0.189(2) 0.552(3) 0.447(3) 0.067(11) Uani 1 1 d D . . . .
C12 C 0.102(3) 0.547(3) 0.474(2) 0.066(10) Uani 1 1 d D . . . .
H12A H 0.1113 0.5007 0.5236 0.099 Uiso 1 1 calc R U . . .
H12B H 0.0538 0.5163 0.4274 0.099 Uiso 1 1 calc R U . . .
H12C H 0.0859 0.6214 0.4863 0.099 Uiso 1 1 calc R U . . .
C15 C 0.499(2) 0.730(3) 0.569(2) 0.057(9) Uani 1 1 d . . . . .
C16 C 0.556(3) 0.654(3) 0.645(3) 0.085(14) Uani 1 1 d . . . . .
H16A H 0.5620 0.5808 0.6232 0.128 Uiso 1 1 calc R U . . .
H16B H 0.5272 0.6495 0.6888 0.128 Uiso 1 1 calc R U . . .
H16C H 0.6153 0.6867 0.6684 0.128 Uiso 1 1 calc R U . . .
C17 C 0.529(2) 0.847(3) 0.584(3) 0.068(11) Uani 1 1 d . . . . .
H17A H 0.5874 0.8497 0.6272 0.102 Uiso 1 1 calc R U . . .
H17B H 0.4869 0.8897 0.6039 0.102 Uiso 1 1 calc R U . . .
H17C H 0.5340 0.8790 0.5317 0.102 Uiso 1 1 calc R U . . .
C18 C 0.523(2) 0.691(3) 0.489(2) 0.063(9) Uani 1 1 d . . . . .
H18A H 0.5123 0.6119 0.4810 0.094 Uiso 1 1 calc R U . . .
H18B H 0.5850 0.7069 0.4955 0.094 Uiso 1 1 calc R U . . .
H18C H 0.4856 0.7301 0.4391 0.094 Uiso 1 1 calc R U . . .
C19 C 0.176(2) 0.914(2) 0.535(2) 0.050(8) Uani 1 1 d . . . . .
H19 H 0.1486 0.8846 0.5778 0.060 Uiso 1 1 calc R U . C 1
C20 C 0.140(2) 0.867(3) 0.452(2) 0.058(9) Uani 1 1 d . U . . .
H20 H 0.0940 0.8095 0.4480 0.069 Uiso 1 1 calc R U . D 1
C21 C 0.131(2) 0.925(3) 0.371(2) 0.065(11) Uani 1 1 d . . . . .
H21A H 0.1212 1.0044 0.3777 0.078 Uiso 1 1 calc R U . E 2
H21B H 0.0792 0.8958 0.3268 0.078 Uiso 1 1 calc R U . E 2
C22 C 0.214(2) 0.909(2) 0.345(2) 0.064(10) Uani 1 1 d . . . . .
H22A H 0.2086 0.8392 0.3132 0.077 Uiso 1 1 calc R U . F 2
H22B H 0.2180 0.9692 0.3064 0.077 Uiso 1 1 calc R U . F 2
C23 C 0.297(2) 0.906(3) 0.416(2) 0.059(9) Uani 1 1 d . . . . .
H23 H 0.3490 0.8813 0.3985 0.070 Uiso 1 1 calc R U . G 1
C24 C 0.320(2) 0.973(3) 0.485(2) 0.047(7) Uani 1 1 d . U . . .
H24 H 0.3851 0.9883 0.5088 0.056 Uiso 1 1 calc R U . H 1
C25 C 0.260(2) 1.066(2) 0.497(2) 0.065(11) Uani 1 1 d . . . . .
H25A H 0.2966 1.1287 0.5258 0.078 Uiso 1 1 calc R U . . .
H25B H 0.2234 1.0922 0.4408 0.078 Uiso 1 1 calc R U . . .
C26 C 0.200(3) 1.031(4) 0.547(3) 0.077(11) Uani 1 1 d . U . . .
H26A H 0.2297 1.0444 0.6077 0.092 Uiso 1 1 calc R U . . .
H26B H 0.1453 1.0755 0.5303 0.092 Uiso 1 1 calc R U . . .
C13 C 0.228(3) 0.435(3) 0.451(3) 0.058(12) Uani 0.78(5) 1 d D U P I 1
H13A H 0.2690 0.4322 0.4167 0.087 Uiso 0.78(5) 1 calc R U P I 1
H13B H 0.1803 0.3818 0.4282 0.087 Uiso 0.78(5) 1 calc R U P I 1
H13C H 0.2600 0.4159 0.5091 0.087 Uiso 0.78(5) 1 calc R U P I 1
C14 C 0.167(4) 0.590(4) 0.356(3) 0.062(13) Uani 0.78(5) 1 d D U P I 1
H14A H 0.1301 0.5346 0.3192 0.093 Uiso 0.78(5) 1 calc R U P I 1
H14B H 0.2213 0.6009 0.3415 0.093 Uiso 0.78(5) 1 calc R U P I 1
H14C H 0.1342 0.6595 0.3501 0.093 Uiso 0.78(5) 1 calc R U P I 1
Rh1' Rh 0.223(4) 0.810(4) 0.470(4) 0.0466(9) Uani 0.053(6) 1 d . . P J 2
C13' C 0.231(5) 0.467(11) 0.517(7) 0.058(12) Uani 0.22(5) 1 d D . P I 2
H13D H 0.2511 0.4024 0.4925 0.087 Uiso 0.22(5) 1 calc R U P I 2
H13E H 0.1876 0.4440 0.5448 0.087 Uiso 0.22(5) 1 calc R U P I 2
H13F H 0.2821 0.5003 0.5591 0.087 Uiso 0.22(5) 1 calc R U P I 2
C14' C 0.140(6) 0.610(15) 0.366(6) 0.062(13) Uani 0.22(5) 1 d D . P I 2
H14D H 0.1458 0.6894 0.3744 0.093 Uiso 0.22(5) 1 calc R U P I 2
H14E H 0.1653 0.5883 0.3213 0.093 Uiso 0.22(5) 1 calc R U P I 2
H14F H 0.0775 0.5893 0.3496 0.093 Uiso 0.22(5) 1 calc R U P I 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Br Br -0.2901 2.4595 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
In In -0.7276 1.3100 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Br1 In1 Br2 109.44(17) . . ?
Br1 In1 Br3 108.3(2) . . ?
Br1 In1 Br4 109.63(17) . . ?
Br3 In1 Br2 111.50(18) . . ?
Br4 In1 Br2 106.07(19) . . ?
Br4 In1 Br3 111.92(17) . . ?
Br2 In1' Br3 121(3) . . ?
Br2 In1' Br4 129(4) . . ?
Br4 In1' Br3 107(3) . . ?
C1 Rh1 C4 60.9(11) . . ?
C1 Rh1 C5 39.4(12) . . ?
C1 Rh1 C20 140.1(13) . . ?
C2 Rh1 C1 39.3(12) . . ?
C2 Rh1 C3 32.9(11) . . ?
C2 Rh1 C4 59.2(12) . . ?
C2 Rh1 C5 65.1(12) . . ?
C2 Rh1 C19 103.7(12) . . ?
C2 Rh1 C20 105.4(12) . . ?
C2 Rh1 C24 164.0(12) . . ?
C3 Rh1 C1 60.7(12) . . ?
C3 Rh1 C4 36.8(12) . . ?
C3 Rh1 C5 63.3(13) . . ?
C3 Rh1 C19 120.2(12) . . ?
C3 Rh1 C20 100.6(13) . . ?
C3 Rh1 C24 156.2(12) . . ?
C5 Rh1 C4 36.8(12) . . ?
C19 Rh1 C1 117.5(12) . . ?
C19 Rh1 C4 156.6(12) . . ?
C19 Rh1 C5 154.7(13) . . ?
C19 Rh1 C20 38.4(12) . . ?
C19 Rh1 C24 79.2(12) . . ?
C20 Rh1 C4 125.9(13) . . ?
C20 Rh1 C5 162.5(13) . . ?
C23 Rh1 C1 140.9(14) . . ?
C23 Rh1 C2 154.1(12) . . ?
C23 Rh1 C3 121.5(13) . . ?
C23 Rh1 C4 97.2(13) . . ?
C23 Rh1 C5 103.2(14) . . ?
C23 Rh1 C19 95.4(14) . . ?
C23 Rh1 C20 79.0(14) . . ?
C23 Rh1 C24 37.3(12) . . ?
C24 Rh1 C1 125.3(12) . . ?
C24 Rh1 C4 121.9(12) . . ?
C24 Rh1 C5 105.7(12) . . ?
C24 Rh1 C20 86.7(13) . . ?
Rh1' Rh1 C1 139(3) . . ?
Rh1' Rh1 C2 99(3) . . ?
Rh1' Rh1 C3 82(3) . . ?
Rh1' Rh1 C4 100(3) . . ?
Rh1' Rh1 C5 137(3) . . ?
Rh1' Rh1 C19 65(3) . . ?
Rh1' Rh1 C20 27(3) . . ?
Rh1' Rh1 C23 73(3) . . ?
Rh1' Rh1 C24 96(3) . . ?
C2 C1 Rh1 66.3(15) . . ?
C2 C1 C5 105(2) . . ?
C5 C1 Rh1 72.2(17) . . ?
C6 C1 Rh1 110(2) . . ?
C6 C1 C2 130(3) . . ?
C6 C1 C5 122(3) . . ?
Rh1 C2 H2 118.8 . . ?
Rh1 C2 Rh1' 22.9(14) . . ?
C1 C2 Rh1 74.4(17) . . ?
C1 C2 H2 124.6 . . ?
C1 C2 Rh1' 97(2) . . ?
C3 C2 Rh1 74(2) . . ?
C3 C2 C1 111(3) . . ?
C3 C2 H2 124.6 . . ?
C3 C2 Rh1' 63(2) . . ?
Rh1' C2 H2 106.4 . . ?
Rh1 C3 Rh1' 25.9(16) . . ?
C2 C3 Rh1 73(2) . . ?
C2 C3 C4 114(3) . . ?
C2 C3 C11 125(3) . . ?
C2 C3 Rh1' 88(3) . . ?
C4 C3 Rh1 79(2) . . ?
C4 C3 C11 117(3) . . ?
C4 C3 Rh1' 92(3) . . ?
C11 C3 Rh1 136(2) . . ?
C11 C3 Rh1' 110(3) . . ?
Rh1 C4 H4 130.6 . . ?
C3 C4 Rh1 64(2) . . ?
C3 C4 H4 126.0 . . ?
C3 C4 C5 108(3) . . ?
C5 C4 Rh1 70.5(19) . . ?
C5 C4 H4 126.0 . . ?
C1 C5 Rh1 68.4(16) . . ?
C4 C5 Rh1 73(2) . . ?
C4 C5 C1 101(3) . . ?
C4 C5 C15 126(3) . . ?
C15 C5 Rh1 134(2) . . ?
C15 C5 C1 130(3) . . ?
C1 C6 H6 116.2 . . ?
C1 C6 C7 128(4) . . ?
C7 C6 H6 116.2 . . ?
C6 C7 C8 123(3) . . ?
C6 C7 C9 105(3) . . ?
C6 C7 C10 109(3) . . ?
C8 C7 C9 110(3) . . ?
C8 C7 C10 103(3) . . ?
C9 C7 C10 106(3) . . ?
C7 C8 H8A 109.5 . . ?
C7 C8 H8B 109.5 . . ?
C7 C8 H8C 109.5 . . ?
H8A C8 H8B 109.5 . . ?
H8A C8 H8C 109.5 . . ?
H8B C8 H8C 109.5 . . ?
C7 C9 H9A 109.5 . . ?
C7 C9 H9B 109.5 . . ?
C7 C9 H9C 109.5 . . ?
H9A C9 H9B 109.5 . . ?
H9A C9 H9C 109.5 . . ?
H9B C9 H9C 109.5 . . ?
C7 C10 H10A 109.5 . . ?
C7 C10 H10B 109.5 . . ?
C7 C10 H10C 109.5 . . ?
H10A C10 H10B 109.5 . . ?
H10A C10 H10C 109.5 . . ?
H10B C10 H10C 109.5 . . ?
C12 C11 C3 112(3) . . ?
C13 C11 C3 111(3) . . ?
C13 C11 C12 109(3) . . ?
C14 C11 C3 108(3) . . ?
C14 C11 C12 109(4) . . ?
C14 C11 C13 107(4) . . ?
C13' C11 C3 84(6) . . ?
C13' C11 C12 89(3) . . ?
C14' C11 C3 109(8) . . ?
C14' C11 C12 90(3) . . ?
C14' C11 C13' 166(10) . . ?
C11 C12 H12A 109.5 . . ?
C11 C12 H12B 109.5 . . ?
C11 C12 H12C 109.5 . . ?
H12A C12 H12B 109.5 . . ?
H12A C12 H12C 109.5 . . ?
H12B C12 H12C 109.5 . . ?
C5 C15 C16 108(3) . . ?
C5 C15 C17 117(3) . . ?
C5 C15 C18 110(3) . . ?
C17 C15 C16 110(3) . . ?
C17 C15 C18 106(3) . . ?
C18 C15 C16 106(3) . . ?
C15 C16 H16A 109.5 . . ?
C15 C16 H16B 109.5 . . ?
C15 C16 H16C 109.5 . . ?
H16A C16 H16B 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
C15 C17 H17A 109.5 . . ?
C15 C17 H17B 109.5 . . ?
C15 C17 H17C 109.5 . . ?
H17A C17 H17B 109.5 . . ?
H17A C17 H17C 109.5 . . ?
H17B C17 H17C 109.5 . . ?
C15 C18 H18A 109.5 . . ?
C15 C18 H18B 109.5 . . ?
C15 C18 H18C 109.5 . . ?
H18A C18 H18B 109.5 . . ?
H18A C18 H18C 109.5 . . ?
H18B C18 H18C 109.5 . . ?
Rh1 C19 H19 113.9 . . ?
C20 C19 Rh1 74(2) . . ?
C20 C19 H19 113.9 . . ?
C20 C19 C26 121(3) . . ?
C20 C19 Rh1' 47(2) . . ?
C26 C19 Rh1 114(2) . . ?
C26 C19 H19 113.9 . . ?
C26 C19 Rh1' 125(3) . . ?
Rh1' C19 Rh1 27.1(19) . . ?
Rh1 C20 H20 114.1 . . ?
C19 C20 Rh1 67.2(19) . . ?
C19 C20 H20 114.1 . . ?
C19 C20 C21 126(3) . . ?
C21 C20 Rh1 113(2) . . ?
C21 C20 H20 114.1 . . ?
Rh1' C20 Rh1 18(2) . . ?
Rh1' C20 C19 85(3) . . ?
Rh1' C20 C21 105(3) . . ?
C20 C21 H21A 109.6 . . ?
C20 C21 H21B 109.6 . . ?
C20 C21 C22 110(3) . . ?
C20 C21 Rh1' 37(2) . . ?
H21A C21 H21B 108.1 . . ?
C22 C21 H21A 109.6 . . ?
C22 C21 H21B 109.6 . . ?
C22 C21 Rh1' 73(2) . . ?
Rh1' C21 H21A 126.5 . . ?
Rh1' C21 H21B 121.2 . . ?
C21 C22 H22A 108.7 . . ?
C21 C22 H22B 108.7 . . ?
C21 C22 Rh1' 69(2) . . ?
H22A C22 H22B 107.6 . . ?
C23 C22 C21 114(3) . . ?
C23 C22 H22A 108.7 . . ?
C23 C22 H22B 108.7 . . ?
C23 C22 Rh1' 59(2) . . ?
Rh1' C22 H22A 90.6 . . ?
Rh1' C22 H22B 161.1 . . ?
Rh1 C23 H23 112.8 . . ?
C22 C23 Rh1 110(2) . . ?
C22 C23 H23 112.8 . . ?
C22 C23 Rh1' 83(3) . . ?
C24 C23 Rh1 74(2) . . ?
C24 C23 C22 128(3) . . ?
C24 C23 H23 112.8 . . ?
C24 C23 Rh1' 91(3) . . ?
Rh1' C23 Rh1 27.2(18) . . ?
Rh1 C24 H24 115.0 . . ?
Rh1 C24 Rh1' 23.2(14) . . ?
C23 C24 Rh1 69(2) . . ?
C23 C24 H24 115.0 . . ?
C23 C24 C25 122(3) . . ?
C23 C24 Rh1' 56(2) . . ?
C25 C24 Rh1 113(2) . . ?
C25 C24 H24 115.0 . . ?
C25 C24 Rh1' 102(2) . . ?
C24 C25 H25A 109.2 . . ?
C24 C25 H25B 109.2 . . ?
H25A C25 H25B 107.9 . . ?
C26 C25 C24 112(3) . . ?
C26 C25 H25A 109.2 . . ?
C26 C25 H25B 109.2 . . ?
C19 C26 C25 113(3) . . ?
C19 C26 H26A 109.1 . . ?
C19 C26 H26B 109.1 . . ?
C25 C26 H26A 109.1 . . ?
C25 C26 H26B 109.1 . . ?
H26A C26 H26B 107.8 . . ?
C11 C13 H13A 109.5 . . ?
C11 C13 H13B 109.5 . . ?
C11 C13 H13C 109.5 . . ?
H13A C13 H13B 109.5 . . ?
H13A C13 H13C 109.5 . . ?
H13B C13 H13C 109.5 . . ?
C11 C14 H14A 109.5 . . ?
C11 C14 H14B 109.5 . . ?
C11 C14 H14C 109.5 . . ?
H14A C14 H14B 109.5 . . ?
H14A C14 H14C 109.5 . . ?
H14B C14 H14C 109.5 . . ?
Rh1 Rh1' C2 58(3) . . ?
Rh1 Rh1' C3 72(3) . . ?
Rh1 Rh1' C19 88(4) . . ?
Rh1 Rh1' C20 136(5) . . ?
Rh1 Rh1' C21 140(4) . . ?
Rh1 Rh1' C22 118(4) . . ?
Rh1 Rh1' C23 80(3) . . ?
Rh1 Rh1' C24 61(3) . . ?
C3 Rh1' C2 29.0(12) . . ?
C3 Rh1' C21 146(3) . . ?
C3 Rh1' C22 131(3) . . ?
C3 Rh1' C24 128(3) . . ?
C19 Rh1' C2 98(3) . . ?
C19 Rh1' C3 126(3) . . ?
C19 Rh1' C21 75(2) . . ?
C19 Rh1' C22 103(2) . . ?
C19 Rh1' C23 104(2) . . ?
C19 Rh1' C24 76.0(19) . . ?
C20 Rh1' C2 123(3) . . ?
C20 Rh1' C3 133(4) . . ?
C20 Rh1' C19 48(2) . . ?
C20 Rh1' C21 38(2) . . ?
C20 Rh1' C22 76(3) . . ?
C20 Rh1' C23 104(3) . . ?
C20 Rh1' C24 98(3) . . ?
C21 Rh1' C2 158(3) . . ?
C21 Rh1' C22 37.8(15) . . ?
C21 Rh1' C24 80.2(18) . . ?
C22 Rh1' C2 158(3) . . ?
C22 Rh1' C24 63.6(16) . . ?
C23 Rh1' C2 131(3) . . ?
C23 Rh1' C3 120(3) . . ?
C23 Rh1' C21 70(2) . . ?
C23 Rh1' C22 38.2(16) . . ?
C23 Rh1' C24 33.6(14) . . ?
C24 Rh1' C2 118(3) . . ?
C11 C13' H13D 109.5 . . ?
C11 C13' H13E 109.5 . . ?
C11 C13' H13F 109.5 . . ?
H13D C13' H13E 109.5 . . ?
H13D C13' H13F 109.5 . . ?
H13E C13' H13F 109.5 . . ?
C11 C14' H14D 109.5 . . ?
C11 C14' H14E 109.5 . . ?
C11 C14' H14F 109.5 . . ?
H14D C14' H14E 109.5 . . ?
H14D C14' H14F 109.5 . . ?
H14E C14' H14F 109.5 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Br1 In1 2.472(5) . ?
Br2 In1 2.522(5) . ?
Br2 In1' 2.02(9) . ?
Br3 In1 2.491(5) . ?
Br3 In1' 2.72(8) . ?
Br4 In1 2.483(4) . ?
Br4 In1' 2.40(7) . ?
Rh1 C1 2.24(3) . ?
Rh1 C2 2.13(3) . ?
Rh1 C3 2.14(4) . ?
Rh1 C4 2.32(4) . ?
Rh1 C5 2.29(3) . ?
Rh1 C19 2.15(3) . ?
Rh1 C20 2.25(4) . ?
Rh1 C23 2.11(4) . ?
Rh1 C24 2.18(3) . ?
Rh1 Rh1' 0.98(6) . ?
C1 C2 1.47(4) . ?
C1 C5 1.53(5) . ?
C1 C6 1.35(5) . ?
C2 H2 0.9500 . ?
C2 C3 1.21(4) . ?
C2 Rh1' 2.49(6) . ?
C3 C4 1.42(5) . ?
C3 C11 1.66(5) . ?
C3 Rh1' 2.22(6) . ?
C4 H4 0.9500 . ?
C4 C5 1.46(5) . ?
C5 C15 1.47(5) . ?
C6 H6 0.9500 . ?
C6 C7 1.44(5) . ?
C7 C8 1.45(5) . ?
C7 C9 1.46(5) . ?
C7 C10 1.63(5) . ?
C8 H8A 0.9800 . ?
C8 H8B 0.9800 . ?
C8 H8C 0.9800 . ?
C9 H9A 0.9800 . ?
C9 H9B 0.9800 . ?
C9 H9C 0.9800 . ?
C10 H10A 0.9800 . ?
C10 H10B 0.9800 . ?
C10 H10C 0.9800 . ?
C11 C12 1.58(5) . ?
C11 C13 1.55(5) . ?
C11 C14 1.52(5) . ?
C11 C13' 1.55(5) . ?
C11 C14' 1.52(6) . ?
C12 H12A 0.9800 . ?
C12 H12B 0.9800 . ?
C12 H12C 0.9800 . ?
C15 C16 1.60(5) . ?
C15 C17 1.50(5) . ?
C15 C18 1.58(5) . ?
C16 H16A 0.9800 . ?
C16 H16B 0.9800 . ?
C16 H16C 0.9800 . ?
C17 H17A 0.9800 . ?
C17 H17B 0.9800 . ?
C17 H17C 0.9800 . ?
C18 H18A 0.9800 . ?
C18 H18B 0.9800 . ?
C18 H18C 0.9800 . ?
C19 H19 1.0000 . ?
C19 C20 1.45(5) . ?
C19 C26 1.46(5) . ?
C19 Rh1' 1.95(6) . ?
C20 H20 1.0000 . ?
C20 C21 1.48(5) . ?
C20 Rh1' 1.44(7) . ?
C21 H21A 0.9900 . ?
C21 H21B 0.9900 . ?
C21 C22 1.52(5) . ?
C21 Rh1' 2.32(7) . ?
C22 H22A 0.9900 . ?
C22 H22B 0.9900 . ?
C22 C23 1.48(5) . ?
C22 Rh1' 2.38(7) . ?
C23 H23 1.0000 . ?
C23 C24 1.37(5) . ?
C23 Rh1' 2.05(6) . ?
C24 H24 1.0000 . ?
C24 C25 1.54(5) . ?
C24 Rh1' 2.48(6) . ?
C25 H25A 0.9900 . ?
C25 H25B 0.9900 . ?
C25 C26 1.51(5) . ?
C26 H26A 0.9900 . ?
C26 H26B 0.9900 . ?
C13 H13A 0.9800 . ?
C13 H13B 0.9800 . ?
C13 H13C 0.9800 . ?
C14 H14A 0.9800 . ?
C14 H14B 0.9800 . ?
C14 H14C 0.9800 . ?
C13' H13D 0.9800 . ?
C13' H13E 0.9800 . ?
C13' H13F 0.9800 . ?
C14' H14D 0.9800 . ?
C14' H14E 0.9800 . ?
C14' H14F 0.9800 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Rh1 C1 C2 C3 66(3) . . . . ?
Rh1 C1 C2 Rh1' 1.3(13) . . . . ?
Rh1 C1 C5 C4 -66(2) . . . . ?
Rh1 C1 C5 C15 130(3) . . . . ?
Rh1 C1 C6 C7 100(4) . . . . ?
Rh1 C2 C3 C4 69(3) . . . . ?
Rh1 C2 C3 C11 -135(3) . . . . ?
Rh1 C2 C3 Rh1' -21.9(16) . . . . ?
Rh1 C3 C4 C5 57(2) . . . . ?
Rh1 C3 C11 C12 -76(4) . . . . ?
Rh1 C3 C11 C13 161(3) . . . . ?
Rh1 C3 C11 C14 44(4) . . . . ?
Rh1 C3 C11 C13' -163(4) . . . . ?
Rh1 C3 C11 C14' 22(6) . . . . ?
Rh1 C4 C5 C1 62.9(19) . . . . ?
Rh1 C4 C5 C15 -133(3) . . . . ?
Rh1 C5 C15 C16 149(3) . . . . ?
Rh1 C5 C15 C17 24(6) . . . . ?
Rh1 C5 C15 C18 -97(4) . . . . ?
Rh1 C19 C20 C21 -102(4) . . . . ?
Rh1 C19 C20 Rh1' 2(2) . . . . ?
Rh1 C19 C26 C25 34(4) . . . . ?
Rh1 C20 C21 C22 12(3) . . . . ?
Rh1 C20 C21 Rh1' 17(2) . . . . ?
Rh1 C20 Rh1' C2 75(7) . . . . ?
Rh1 C20 Rh1' C3 110(9) . . . . ?
Rh1 C20 Rh1' C19 7(7) . . . . ?
Rh1 C20 Rh1' C21 -119(6) . . . . ?
Rh1 C20 Rh1' C22 -116(7) . . . . ?
Rh1 C20 Rh1' C23 -90(6) . . . . ?
Rh1 C20 Rh1' C24 -56(6) . . . . ?
Rh1 C23 C24 C25 -105(3) . . . . ?
Rh1 C23 C24 Rh1' -21.8(17) . . . . ?
Rh1 C24 C25 C26 15(4) . . . . ?
C1 Rh1 Rh1' C2 3(3) . . . . ?
C1 Rh1 Rh1' C3 -25(4) . . . . ?
C1 Rh1 Rh1' C19 104(4) . . . . ?
C1 Rh1 Rh1' C20 109(6) . . . . ?
C1 Rh1 Rh1' C21 167(3) . . . . ?
C1 Rh1 Rh1' C22 -152(2) . . . . ?
C1 Rh1 Rh1' C23 -151(3) . . . . ?
C1 Rh1 Rh1' C24 179(4) . . . . ?
C1 C2 C3 Rh1 -66(2) . . . . ?
C1 C2 C3 C4 3(4) . . . . ?
C1 C2 C3 C11 159(3) . . . . ?
C1 C2 C3 Rh1' -88(3) . . . . ?
C1 C5 C15 C16 50(5) . . . . ?
C1 C5 C15 C17 -74(5) . . . . ?
C1 C5 C15 C18 165(3) . . . . ?
C1 C6 C7 C8 -7(7) . . . . ?
C1 C6 C7 C9 120(5) . . . . ?
C1 C6 C7 C10 -127(4) . . . . ?
C2 Rh1 Rh1' C3 -28.0(15) . . . . ?
C2 Rh1 Rh1' C19 100.8(18) . . . . ?
C2 Rh1 Rh1' C20 106(6) . . . . ?
C2 Rh1 Rh1' C21 164(6) . . . . ?
C2 Rh1 Rh1' C22 -155(3) . . . . ?
C2 Rh1 Rh1' C23 -154.6(14) . . . . ?
C2 Rh1 Rh1' C24 175.8(14) . . . . ?
C2 C1 C5 Rh1 58.4(18) . . . . ?
C2 C1 C5 C4 -8(3) . . . . ?
C2 C1 C5 C15 -171(3) . . . . ?
C2 C1 C6 C7 24(7) . . . . ?
C2 C3 C4 Rh1 -66(3) . . . . ?
C2 C3 C4 C5 -9(4) . . . . ?
C2 C3 C11 C12 26(5) . . . . ?
C2 C3 C11 C13 -97(4) . . . . ?
C2 C3 C11 C14 146(4) . . . . ?
C2 C3 C11 C13' -61(5) . . . . ?
C2 C3 C11 C14' 124(5) . . . . ?
C3 Rh1 Rh1' C2 28.0(15) . . . . ?
C3 Rh1 Rh1' C19 129(2) . . . . ?
C3 Rh1 Rh1' C20 134(6) . . . . ?
C3 Rh1 Rh1' C21 -168(6) . . . . ?
C3 Rh1 Rh1' C22 -127(3) . . . . ?
C3 Rh1 Rh1' C23 -126.6(18) . . . . ?
C3 Rh1 Rh1' C24 -156.1(13) . . . . ?
C3 C4 C5 Rh1 -53(2) . . . . ?
C3 C4 C5 C1 9(3) . . . . ?
C3 C4 C5 C15 174(3) . . . . ?
C4 Rh1 Rh1' C2 60.1(13) . . . . ?
C4 Rh1 Rh1' C3 32.1(15) . . . . ?
C4 Rh1 Rh1' C19 160.9(15) . . . . ?
C4 Rh1 Rh1' C20 166(6) . . . . ?
C4 Rh1 Rh1' C21 -136(6) . . . . ?
C4 Rh1 Rh1' C22 -95(3) . . . . ?
C4 Rh1 Rh1' C23 -94.4(16) . . . . ?
C4 Rh1 Rh1' C24 -124.0(14) . . . . ?
C4 C3 C11 C12 -179(3) . . . . ?
C4 C3 C11 C13 59(4) . . . . ?
C4 C3 C11 C14 -58(4) . . . . ?
C4 C3 C11 C13' 95(4) . . . . ?
C4 C3 C11 C14' -80(5) . . . . ?
C4 C5 C15 C16 -110(4) . . . . ?
C4 C5 C15 C17 126(4) . . . . ?
C4 C5 C15 C18 5(5) . . . . ?
C5 Rh1 Rh1' C2 63(3) . . . . ?
C5 Rh1 Rh1' C3 35(4) . . . . ?
C5 Rh1 Rh1' C19 164(3) . . . . ?
C5 Rh1 Rh1' C20 169(4) . . . . ?
C5 Rh1 Rh1' C21 -133(4) . . . . ?
C5 Rh1 Rh1' C22 -92(4) . . . . ?
C5 Rh1 Rh1' C23 -91(4) . . . . ?
C5 Rh1 Rh1' C24 -121(4) . . . . ?
C5 C1 C2 Rh1 -62(2) . . . . ?
C5 C1 C2 C3 3(4) . . . . ?
C5 C1 C2 Rh1' -61(3) . . . . ?
C5 C1 C6 C7 -179(4) . . . . ?
C6 C1 C2 Rh1 97(4) . . . . ?
C6 C1 C2 C3 162(4) . . . . ?
C6 C1 C2 Rh1' 98(4) . . . . ?
C6 C1 C5 Rh1 -103(3) . . . . ?
C6 C1 C5 C4 -169(3) . . . . ?
C6 C1 C5 C15 27(5) . . . . ?
C11 C3 C4 Rh1 136(3) . . . . ?
C11 C3 C4 C5 -167(3) . . . . ?
C19 Rh1 Rh1' C2 -100.8(18) . . . . ?
C19 Rh1 Rh1' C3 -129(2) . . . . ?
C19 Rh1 Rh1' C20 5(5) . . . . ?
C19 Rh1 Rh1' C21 63(5) . . . . ?
C19 Rh1 Rh1' C22 104(3) . . . . ?
C19 Rh1 Rh1' C23 105(2) . . . . ?
C19 Rh1 Rh1' C24 75.1(19) . . . . ?
C19 C20 C21 C22 90(4) . . . . ?
C19 C20 C21 Rh1' 94(5) . . . . ?
C19 C20 Rh1' Rh1 -7(7) . . . . ?
C19 C20 Rh1' C2 69(4) . . . . ?
C19 C20 Rh1' C3 104(5) . . . . ?
C19 C20 Rh1' C21 -126(4) . . . . ?
C19 C20 Rh1' C22 -123(2) . . . . ?
C19 C20 Rh1' C23 -96(3) . . . . ?
C19 C20 Rh1' C24 -63(3) . . . . ?
C20 Rh1 Rh1' C2 -106(6) . . . . ?
C20 Rh1 Rh1' C3 -134(6) . . . . ?
C20 Rh1 Rh1' C19 -5(5) . . . . ?
C20 Rh1 Rh1' C21 58(6) . . . . ?
C20 Rh1 Rh1' C22 99(7) . . . . ?
C20 Rh1 Rh1' C23 100(6) . . . . ?
C20 Rh1 Rh1' C24 70(6) . . . . ?
C20 C19 C26 C25 -52(5) . . . . ?
C20 C21 C22 C23 -36(4) . . . . ?
C20 C21 C22 Rh1' 3(3) . . . . ?
C21 C20 Rh1' Rh1 119(6) . . . . ?
C21 C20 Rh1' C2 -166(3) . . . . ?
C21 C20 Rh1' C3 -131(4) . . . . ?
C21 C20 Rh1' C19 126(4) . . . . ?
C21 C20 Rh1' C22 3(3) . . . . ?
C21 C20 Rh1' C23 29(4) . . . . ?
C21 C20 Rh1' C24 63(3) . . . . ?
C21 C22 C23 Rh1 42(3) . . . . ?
C21 C22 C23 C24 -43(5) . . . . ?
C21 C22 C23 Rh1' 43(3) . . . . ?
C22 C23 C24 Rh1 103(4) . . . . ?
C22 C23 C24 C25 -1(6) . . . . ?
C22 C23 C24 Rh1' 82(4) . . . . ?
C23 Rh1 Rh1' C2 154.6(14) . . . . ?
C23 Rh1 Rh1' C3 126.6(18) . . . . ?
C23 Rh1 Rh1' C19 -105(2) . . . . ?
C23 Rh1 Rh1' C20 -100(6) . . . . ?
C23 Rh1 Rh1' C21 -41(5) . . . . ?
C23 Rh1 Rh1' C22 -1(2) . . . . ?
C23 Rh1 Rh1' C24 -29.6(17) . . . . ?
C23 C24 C25 C26 93(4) . . . . ?
C24 Rh1 Rh1' C2 -175.8(14) . . . . ?
C24 Rh1 Rh1' C3 156.1(13) . . . . ?
C24 Rh1 Rh1' C19 -75.1(19) . . . . ?
C24 Rh1 Rh1' C20 -70(6) . . . . ?
C24 Rh1 Rh1' C21 -12(6) . . . . ?
C24 Rh1 Rh1' C22 29(3) . . . . ?
C24 Rh1 Rh1' C23 29.6(17) . . . . ?
C24 C25 C26 C19 -31(5) . . . . ?
C26 C19 C20 Rh1 108(3) . . . . ?
C26 C19 C20 C21 6(6) . . . . ?
C26 C19 C20 Rh1' 111(4) . . . . ?
Rh1' C2 C3 Rh1 21.9(16) . . . . ?
Rh1' C2 C3 C4 91(3) . . . . ?
Rh1' C2 C3 C11 -113(4) . . . . ?
Rh1' C3 C4 Rh1 22.5(16) . . . . ?
Rh1' C3 C4 C5 80(3) . . . . ?
Rh1' C3 C11 C12 -76(3) . . . . ?
Rh1' C3 C11 C13' -162(4) . . . . ?
Rh1' C3 C11 C14' 23(5) . . . . ?
Rh1' C19 C20 Rh1 -2(2) . . . . ?
Rh1' C19 C20 C21 -104(4) . . . . ?
Rh1' C19 C26 C25 5(5) . . . . ?
Rh1' C20 C21 C22 -4(4) . . . . ?
Rh1' C21 C22 C23 -38(3) . . . . ?
Rh1' C22 C23 Rh1 -0.5(16) . . . . ?
Rh1' C22 C23 C24 -85(4) . . . . ?
Rh1' C23 C24 Rh1 21.8(17) . . . . ?
Rh1' C23 C24 C25 -83(3) . . . . ?
Rh1' C24 C25 C26 36(4) . . . . ?
