#------------------------------------------------------------------------------
#$Date: 2023-11-22 01:55:47 +0200 (Wed, 22 Nov 2023) $
#$Revision: 287714 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/71/45/7714522.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7714522
loop_
_publ_author_name
'Jordan, Rose'
'Maisuls, Ivan'
'Nair, Shruti Santosh'
'Dietzek, Benjamin'
'Strassert, Cristian Alejandro'
'Klein, Axel'
_publ_section_title
;
 Enhanced luminescence properties through heavy ancillary ligands in
 [Pt(CNC)(L)] complexes, L = AsPh3 and SbPh3
;
_journal_name_full               'Dalton Transactions'
_journal_paper_doi               10.1039/D3DT03225F
_journal_year                    2023
_chemical_formula_sum            'C41.5 H30 As Cl1.5 N O0.5 Pt'
_chemical_formula_weight         873.85
_chemical_name_systematic        '[Pt(dba)AsPh3] * 0.5 Et2O * 0.5 CHCl3'
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_Hall           '-C 2yc'
_space_group_name_H-M_alt        'C 1 2/c 1'
_atom_sites_solution_hydrogens   mixed
_audit_creation_method           SHELXL-2018/3
_audit_update_record
;
2022-08-02 deposited with the CCDC.	2023-11-21 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 118.864(2)
_cell_angle_gamma                90
_cell_formula_units_Z            8
_cell_length_a                   27.2312(16)
_cell_length_b                   10.5042(5)
_cell_length_c                   26.597(2)
_cell_measurement_reflns_used    9280
_cell_measurement_temperature    109(2)
_cell_measurement_theta_max      30.45
_cell_measurement_theta_min      2.98
_cell_volume                     6662.7(7)
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018)'
_computing_structure_solution    'SHELXT 2018/2 (Sheldrick, 2018)'
_diffrn_ambient_temperature      109(2)
_diffrn_measured_fraction_theta_full 0.994
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device_type  'Bruker D8 Venture'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0462
_diffrn_reflns_av_unetI/netI     0.0259
_diffrn_reflns_Laue_measured_fraction_full 0.994
_diffrn_reflns_Laue_measured_fraction_max 0.995
_diffrn_reflns_limit_h_max       38
_diffrn_reflns_limit_h_min       -38
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       37
_diffrn_reflns_limit_l_min       -37
_diffrn_reflns_number            85756
_diffrn_reflns_point_group_measured_fraction_full 0.994
_diffrn_reflns_point_group_measured_fraction_max 0.995
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         30.516
_diffrn_reflns_theta_min         2.119
_exptl_absorpt_coefficient_mu    5.352
_exptl_absorpt_correction_T_max  0.7461
_exptl_absorpt_correction_T_min  0.4455
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
'SADABS-2016/2 - Bruker AXS area detector scaling and absorption correction'
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    1.742
_exptl_crystal_description       prism
_exptl_crystal_F_000             3412
_exptl_crystal_preparation       Luminescent
_exptl_crystal_recrystallization_method
'Re-crystallisation from solvent: Et2O, CHCl3'
_exptl_crystal_size_max          0.1
_exptl_crystal_size_mid          0.1
_exptl_crystal_size_min          0.1
_refine_diff_density_max         0.629
_refine_diff_density_min         -0.665
_refine_diff_density_rms         0.088
_refine_ls_extinction_coef       0.000116(13)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     'SHELXL-2018/3 (Sheldrick 2018)'
_refine_ls_goodness_of_fit_ref   1.018
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     457
_refine_ls_number_reflns         10116
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.018
_refine_ls_R_factor_all          0.0229
_refine_ls_R_factor_gt           0.0199
_refine_ls_shift/su_max          0.005
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0163P)²+12.8826P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0454
_refine_ls_wR_factor_ref         0.0464
_reflns_Friedel_coverage         0.000
_reflns_number_gt                9318
_reflns_number_total             10116
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d3dt03225f2.cif
_cod_data_source_block           mo_Jordan_RJ_M_14_R_0ma
_cod_original_cell_volume        6662.6(8)
_cod_original_sg_symbol_H-M      'C 2/c'
_cod_original_formula_sum        'C41.50 H30 As Cl1.50 N O0.50 Pt'
_cod_database_code               7714522
_shelx_shelxl_version_number     2018/3
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
O1 O 0.48176(16) 0.2306(4) 0.24733(18) 0.0437(9) Uani 0.5 1 d . . P . .
N1 N 0.44045(6) 0.19590(15) 0.45399(7) 0.0197(3) Uani 1 1 d . . . . .
C1 C 0.38403(8) 0.01984(18) 0.37757(8) 0.0209(3) Uani 1 1 d . . . . .
Cl2 Cl 0.05072(6) 0.13893(16) 0.29663(8) 0.0606(4) Uani 0.5 1 d . . P . .
C2 C 0.35853(9) -0.0807(2) 0.33975(9) 0.0258(4) Uani 1 1 d . . . . .
H2 H 0.319019 -0.090337 0.322718 0.031 Uiso 1 1 calc R U . . .
Cl3 Cl 0.03011(7) 0.05867(16) 0.31832(6) 0.0531(3) Uani 0.5 1 d . . P . .
C3 C 0.38911(9) -0.1688(2) 0.32572(9) 0.0287(4) Uani 1 1 d . . . . .
H3 H 0.369659 -0.236255 0.299934 0.034 Uiso 1 1 calc R U . . .
C4 C 0.44630(10) -0.1598(2) 0.34832(10) 0.0298(4) Uani 1 1 d . . . . .
H4 H 0.465874 -0.218834 0.337399 0.036 Uiso 1 1 calc R U . . .
C5 C 0.47536(8) -0.0625(2) 0.38765(9) 0.0257(4) Uani 1 1 d . . . . .
C6 C 0.44370(8) 0.02373(19) 0.40111(8) 0.0222(4) Uani 1 1 d . . . . .
C7 C 0.53527(9) -0.0462(2) 0.41597(9) 0.0319(5) Uani 1 1 d . . . . .
H7 H 0.556862 -0.103542 0.406927 0.038 Uiso 1 1 calc R U . . .
C8 C 0.56238(8) 0.0470(2) 0.45495(10) 0.0321(5) Uani 1 1 d . . . . .
H8 H 0.601993 0.053837 0.471912 0.039 Uiso 1 1 calc R U . . .
C9 C 0.53202(8) 0.1357(2) 0.47105(9) 0.0258(4) Uani 1 1 d . . . . .
C10 C 0.47305(8) 0.12000(19) 0.44239(8) 0.0217(3) Uani 1 1 d . . . . .
C18 C 0.36234(8) 0.32015(18) 0.46463(8) 0.0222(4) Uani 1 1 d . . . . .
C14 C 0.53701(10) 0.4119(2) 0.56562(9) 0.0345(5) Uani 1 1 d . . . . .
H14 H 0.575709 0.431848 0.587834 0.041 Uiso 1 1 calc R U . . .
C16 C 0.43902(9) 0.4553(2) 0.54140(9) 0.0290(4) Uani 1 1 d . . . . .
Pt1 Pt 0.35782(2) 0.16563(2) 0.41238(2) 0.01725(3) Uani 1 1 d . . . . .
As1 As 0.26209(2) 0.12044(2) 0.36061(2) 0.01682(4) Uani 1 1 d . . . . .
Cl1 Cl 0.06121(6) 0.06386(15) 0.22961(6) 0.0472(3) Uani 0.5 1 d . . P . .
C11 C 0.55462(8) 0.2323(2) 0.51227(9) 0.0293(4) Uani 1 1 d . . . . .
H11 H 0.594019 0.245516 0.532189 0.035 Uiso 1 1 calc R U . . .
C12 C 0.51979(8) 0.3096(2) 0.52448(9) 0.0270(4) Uani 1 1 d . . . . .
C13 C 0.46134(8) 0.28777(19) 0.49341(8) 0.0217(3) Uani 1 1 d . . . . .
C15 C 0.49859(10) 0.4804(2) 0.57309(10) 0.0344(5) Uani 1 1 d . . . . .
H15 H 0.511478 0.547709 0.600327 0.041 Uiso 1 1 calc R U . . .
C17 C 0.42017(9) 0.35761(18) 0.50063(8) 0.0233(4) Uani 1 1 d . . . . .
C19 C 0.32461(8) 0.39193(19) 0.47405(8) 0.0241(4) Uani 1 1 d . . . . .
H19 H 0.285667 0.374337 0.451982 0.029 Uiso 1 1 calc R U . . .
C20 C 0.34233(9) 0.48959(19) 0.51516(9) 0.0276(4) Uani 1 1 d . . . . .
H20 H 0.314811 0.534497 0.520332 0.033 Uiso 1 1 calc R U . . .
C21 C 0.39774(10) 0.5232(2) 0.54830(9) 0.0324(5) Uani 1 1 d . . . . .
H21 H 0.408096 0.590775 0.575293 0.039 Uiso 1 1 calc R U . . .
C22 C 0.23645(7) 0.09771(17) 0.27910(8) 0.0194(3) Uani 1 1 d . . . . .
C23 C 0.26267(9) 0.17009(19) 0.25539(9) 0.0248(4) Uani 1 1 d . . . . .
H23 H 0.291254 0.228683 0.278668 0.030 Uiso 1 1 calc R U . . .
C24 C 0.24722(10) 0.1571(2) 0.19753(9) 0.0298(4) Uani 1 1 d . . . . .
H24 H 0.264538 0.208428 0.181109 0.036 Uiso 1 1 calc R U . . .
C25 C 0.20655(9) 0.0693(2) 0.16393(9) 0.0299(4) Uani 1 1 d . . . . .
H25 H 0.196326 0.059826 0.124555 0.036 Uiso 1 1 calc R U . . .
C26 C 0.18087(9) -0.0044(2) 0.18747(9) 0.0273(4) Uani 1 1 d . . . . .
H26 H 0.153277 -0.065037 0.164380 0.033 Uiso 1 1 calc R U . . .
C27 C 0.19537(8) 0.01011(18) 0.24524(8) 0.0232(4) Uani 1 1 d . . . . .
H27 H 0.177256 -0.039626 0.261313 0.028 Uiso 1 1 calc R U . . .
C28 C 0.24174(8) -0.03642(18) 0.38407(8) 0.0199(3) Uani 1 1 d . . . . .
C29 C 0.28554(9) -0.1146(2) 0.42148(8) 0.0251(4) Uani 1 1 d . . . . .
H29 H 0.323262 -0.089185 0.434506 0.030 Uiso 1 1 calc R U . . .
C30 C 0.27436(10) -0.2292(2) 0.43982(9) 0.0314(4) Uani 1 1 d . . . . .
H30 H 0.304394 -0.281579 0.465760 0.038 Uiso 1 1 calc R U . . .
C31 C 0.21942(11) -0.2674(2) 0.42032(9) 0.0316(5) Uani 1 1 d . . . . .
H31 H 0.211689 -0.346351 0.432488 0.038 Uiso 1 1 calc R U . . .
C32 C 0.17588(10) -0.1902(2) 0.38308(10) 0.0299(4) Uani 1 1 d . . . . .
H32 H 0.138223 -0.216793 0.369499 0.036 Uiso 1 1 calc R U . . .
C33 C 0.18665(8) -0.07371(19) 0.36524(9) 0.0244(4) Uani 1 1 d . . . . .
H33 H 0.156523 -0.020190 0.340379 0.029 Uiso 1 1 calc R U . . .
C34 C 0.20883(7) 0.24134(17) 0.36178(8) 0.0201(3) Uani 1 1 d . . . . .
C35 C 0.19272(8) 0.23315(19) 0.40389(9) 0.0249(4) Uani 1 1 d . . . . .
H35 H 0.205008 0.163615 0.429974 0.030 Uiso 1 1 calc R U . . .
C36 C 0.15865(9) 0.3266(2) 0.40792(10) 0.0298(4) Uani 1 1 d . . . . .
H36 H 0.147778 0.321304 0.436848 0.036 Uiso 1 1 calc R U . . .
C37 C 0.14060(9) 0.4275(2) 0.36955(11) 0.0330(5) Uani 1 1 d . . . . .
H37 H 0.116906 0.490856 0.371888 0.040 Uiso 1 1 calc R U . . .
C38 C 0.15695(10) 0.4361(2) 0.32797(11) 0.0329(5) Uani 1 1 d . . . . .
H38 H 0.144573 0.505654 0.301902 0.039 Uiso 1 1 calc R U . . .
C39 C 0.19144(9) 0.34356(19) 0.32403(9) 0.0256(4) Uani 1 1 d . . . . .
H39 H 0.203029 0.350249 0.295686 0.031 Uiso 1 1 calc R U . . .
C40 C 0.4200(3) 0.2684(6) 0.2850(2) 0.0480(13) Uani 0.5 1 d . . P . .
H40A H 0.408258 0.242580 0.313038 0.072 Uiso 0.5 1 calc R U P . .
H40B H 0.388539 0.258357 0.246116 0.072 Uiso 0.5 1 calc R U P . .
H40C H 0.431868 0.357681 0.291453 0.072 Uiso 0.5 1 calc R U P . .
C41 C 0.46324(19) 0.1946(4) 0.2912(2) 0.0770(13) Uani 1 1 d . . . . .
H1 H 0.445(2) 0.124(5) 0.286(2) 0.116 Uiso 1 1 d . U . . .
H1A H 0.498(2) 0.204(5) 0.332(2) 0.116 Uiso 1 1 d . U . . .
C42 C 0.5226(3) 0.1492(7) 0.2446(3) 0.0579(16) Uani 0.5 1 d . . P . .
C43 C 0.000000 0.0371(4) 0.250000 0.0650(15) Uani 1 2 d S T P . .
H01C H 0.000000 -0.050(5) 0.250000 0.055(13) Uiso 1 2 d S . P . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
As As 0.0499 2.0058 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C42 O1 O1 102.6(6) 2_655 2_655 ?
C42 O1 C42 69.1(8) 2_655 . ?
O1 O1 C42 38.0(3) 2_655 . ?
C42 O1 C41 56.8(6) 2_655 . ?
O1 O1 C41 127.2(6) 2_655 . ?
C42 O1 C41 116.3(5) . . ?
C13 N1 C10 122.33(16) . . ?
C13 N1 Pt1 119.34(13) . . ?
C10 N1 Pt1 118.29(13) . . ?
C2 C1 C6 113.75(17) . . ?
C2 C1 Pt1 136.07(14) . . ?
C6 C1 Pt1 110.13(13) . . ?
Cl3 Cl2 C43 62.88(11) . . ?
Cl3 Cl2 Cl1 113.70(12) . . ?
C43 Cl2 Cl1 62.72(7) . . ?
C1 C2 C3 122.48(19) . . ?
Cl2 Cl3 C43 71.45(15) . . ?
Cl2 Cl3 Cl1 109.94(12) . 2 ?
C43 Cl3 Cl1 61.79(6) . 2 ?
C4 C3 C2 121.9(2) . . ?
C3 C4 C5 119.23(18) . . ?
C4 C5 C6 117.60(18) . . ?
C4 C5 C7 124.48(19) . . ?
C6 C5 C7 117.9(2) . . ?
C5 C6 C10 117.93(17) . . ?
C5 C6 C1 125.04(19) . . ?
C10 C6 C1 117.01(17) . . ?
C8 C7 C5 123.2(2) . . ?
C7 C8 C9 121.02(19) . . ?
C11 C9 C10 117.51(19) . . ?
C11 C9 C8 127.10(19) . . ?
C10 C9 C8 115.4(2) . . ?
N1 C10 C9 120.90(19) . . ?
N1 C10 C6 114.49(16) . . ?
C9 C10 C6 124.58(18) . . ?
C19 C18 C17 113.31(18) . . ?
C19 C18 Pt1 136.49(15) . . ?
C17 C18 Pt1 110.18(13) . . ?
C15 C14 C12 120.9(2) . . ?
C17 C16 C21 116.9(2) . . ?
C17 C16 C15 118.3(2) . . ?
C21 C16 C15 124.7(2) . . ?
N1 Pt1 C1 80.06(7) . . ?
N1 Pt1 C18 79.62(7) . . ?
C1 Pt1 C18 159.62(8) . . ?
N1 Pt1 As1 176.54(5) . . ?
C1 Pt1 As1 96.48(5) . . ?
C18 Pt1 As1 103.84(6) . . ?
C28 As1 C34 102.68(8) . . ?
C28 As1 C22 104.50(8) . . ?
C34 As1 C22 103.27(8) . . ?
C28 As1 Pt1 113.26(6) . . ?
C34 As1 Pt1 119.22(5) . . ?
C22 As1 Pt1 112.34(5) . . ?
C43 Cl1 Cl2 49.39(9) . . ?
C43 Cl1 Cl3 44.96(5) . 2 ?
Cl2 Cl1 Cl3 85.48(7) . 2 ?
C9 C11 C12 120.73(18) . . ?
C11 C12 C13 117.89(19) . . ?
C11 C12 C14 126.9(2) . . ?
C13 C12 C14 115.2(2) . . ?
N1 C13 C12 120.61(18) . . ?
N1 C13 C17 114.39(16) . . ?
C12 C13 C17 125.00(19) . . ?
C14 C15 C16 122.9(2) . . ?
C16 C17 C13 117.59(19) . . ?
C16 C17 C18 125.97(19) . . ?
C13 C17 C18 116.45(17) . . ?
C18 C19 C20 122.03(19) . . ?
C21 C20 C19 123.0(2) . . ?
C20 C21 C16 118.73(19) . . ?
C23 C22 C27 119.89(17) . . ?
C23 C22 As1 116.95(14) . . ?
C27 C22 As1 123.11(14) . . ?
C22 C23 C24 120.13(19) . . ?
C25 C24 C23 119.9(2) . . ?
C26 C25 C24 120.20(19) . . ?
C25 C26 C27 120.12(19) . . ?
C22 C27 C26 119.70(19) . . ?
C33 C28 C29 119.66(18) . . ?
C33 C28 As1 123.46(14) . . ?
C29 C28 As1 116.88(14) . . ?
C30 C29 C28 120.3(2) . . ?
C31 C30 C29 120.0(2) . . ?
C32 C31 C30 119.7(2) . . ?
C31 C32 C33 120.7(2) . . ?
C28 C33 C32 119.53(19) . . ?
C39 C34 C35 120.07(18) . . ?
C39 C34 As1 119.45(15) . . ?
C35 C34 As1 120.15(14) . . ?
C34 C35 C36 120.07(19) . . ?
C37 C36 C35 119.7(2) . . ?
C38 C37 C36 120.22(19) . . ?
C37 C38 C39 120.4(2) . . ?
C34 C39 C38 119.6(2) . . ?
C42 C41 C40 132.9(5) 2_655 . ?
C42 C41 O1 36.2(3) 2_655 . ?
C40 C41 O1 110.8(4) . . ?
O1 C42 C41 87.0(7) 2_655 2_655 ?
O1 C42 C42 73.7(6) 2_655 2_655 ?
C41 C42 C42 140.2(7) 2_655 2_655 ?
O1 C42 O1 39.5(5) 2_655 . ?
C41 C42 O1 109.7(5) 2_655 . ?
C42 C42 O1 37.2(3) 2_655 . ?
Cl3 C43 Cl3 163.8(3) 2 . ?
Cl3 C43 Cl2 121.5(2) 2 . ?
Cl3 C43 Cl2 45.67(10) . . ?
Cl3 C43 Cl2 45.67(10) 2 2 ?
Cl3 C43 Cl2 121.6(2) . 2 ?
Cl2 C43 Cl2 102.8(3) . 2 ?
Cl3 C43 Cl1 104.40(9) 2 2 ?
Cl3 C43 Cl1 73.26(7) . 2 ?
Cl2 C43 Cl1 101.64(14) . 2 ?
Cl2 C43 Cl1 67.89(10) 2 2 ?
Cl3 C43 Cl1 73.26(7) 2 . ?
Cl3 C43 Cl1 104.40(9) . . ?
Cl2 C43 Cl1 67.89(10) . . ?
Cl2 C43 Cl1 101.64(14) 2 . ?
Cl1 C43 Cl1 163.9(3) 2 . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
O1 C42 0.903(7) 2_655 ?
O1 O1 0.933(7) 2_655 ?
O1 C42 1.432(7) . ?
O1 C41 1.527(6) . ?
N1 C13 1.334(3) . ?
N1 C10 1.335(2) . ?
N1 Pt1 1.9961(15) . ?
C1 C2 1.391(3) . ?
C1 C6 1.432(3) . ?
C1 Pt1 2.0854(18) . ?
Cl2 Cl3 1.293(2) . ?
Cl2 C43 1.713(3) . ?
Cl2 Cl1 2.091(2) . ?
C2 C3 1.411(3) . ?
Cl3 C43 1.6084(15) . ?
Cl3 Cl1 2.180(2) 2 ?
C3 C4 1.375(3) . ?
C4 C5 1.402(3) . ?
C5 C6 1.411(3) . ?
C5 C7 1.439(3) . ?
C6 C10 1.421(3) . ?
C7 C8 1.356(4) . ?
C8 C9 1.442(3) . ?
C9 C11 1.399(3) . ?
C9 C10 1.416(3) . ?
C18 C19 1.391(3) . ?
C18 C17 1.448(3) . ?
C18 Pt1 2.1015(19) . ?
C14 C15 1.361(4) . ?
C14 C12 1.441(3) . ?
C16 C17 1.398(3) . ?
C16 C21 1.417(3) . ?
C16 C15 1.446(3) . ?
Pt1 As1 2.3348(2) . ?
As1 C28 1.9353(19) . ?
As1 C34 1.9392(18) . ?
As1 C22 1.9450(18) . ?
Cl1 C43 2.0059(14) . ?
C11 C12 1.401(3) . ?
C12 C13 1.414(3) . ?
C13 C17 1.428(3) . ?
C19 C20 1.404(3) . ?
C20 C21 1.376(3) . ?
C22 C23 1.386(3) . ?
C22 C27 1.392(3) . ?
C23 C24 1.392(3) . ?
C24 C25 1.386(3) . ?
C25 C26 1.379(3) . ?
C26 C27 1.398(3) . ?
C28 C33 1.389(3) . ?
C28 C29 1.393(3) . ?
C29 C30 1.387(3) . ?
C30 C31 1.385(3) . ?
C31 C32 1.382(3) . ?
C32 C33 1.394(3) . ?
C34 C39 1.388(3) . ?
C34 C35 1.389(3) . ?
C35 C36 1.390(3) . ?
C36 C37 1.386(3) . ?
C37 C38 1.380(3) . ?
C38 C39 1.390(3) . ?
C40 C41 1.352(8) . ?
C41 C42 1.279(9) 2_655 ?
C42 C42 1.395(16) 2_655 ?
