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#$Date: 2024-02-04 14:01:39 +0200 (Sun, 04 Feb 2024) $
#$Revision: 289523 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/71/45/7714579.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7714579
loop_
_publ_author_name
'Lenz, Tabea'
'Hebenbrock, Marian'
_publ_section_title
;
 Phenylsilver - an unexpected one-dimensional coordination polymer of
 silver(I) tetrads.
;
_journal_issue                   2
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              423
_journal_page_last               427
_journal_paper_doi               10.1039/d3dt03007e
_journal_volume                  53
_journal_year                    2024
_chemical_formula_moiety         '12 * (C6 H5 Ag)'
_chemical_formula_sum            'C72 H60 Ag12'
_chemical_formula_weight         2219.64
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     intrinsic
_audit_creation_method           SHELXL-2019/1
_audit_update_record
;
2023-08-28 deposited with the CCDC.	2023-11-22 downloaded from the CCDC.
;
_cell_angle_alpha                107.4100(10)
_cell_angle_beta                 93.1020(10)
_cell_angle_gamma                90.7320(10)
_cell_formula_units_Z            1
_cell_length_a                   9.9863(4)
_cell_length_b                   10.8351(4)
_cell_length_c                   15.2489(6)
_cell_measurement_reflns_used    9336
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      27.45
_cell_measurement_theta_min      2.41
_cell_volume                     1571.35(11)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-2019/1 (Sheldrick, 2019)'
_computing_structure_solution    'SHELXS-97 (Sheldrick 2008)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.988
_diffrn_measured_fraction_theta_max 0.987
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0211
_diffrn_reflns_av_unetI/netI     0.0107
_diffrn_reflns_Laue_measured_fraction_full 0.988
_diffrn_reflns_Laue_measured_fraction_max 0.987
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            70328
_diffrn_reflns_point_group_measured_fraction_full 0.988
_diffrn_reflns_point_group_measured_fraction_max 0.987
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.513
_diffrn_reflns_theta_min         1.971
_diffrn_source                   'I-mu-S microsource X-ray tube'
_exptl_absorpt_coefficient_mu    3.690
_exptl_absorpt_correction_T_max  0.7455
_exptl_absorpt_correction_T_min  0.6521
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   ' Apex3 v2016.9-0 (Bruker, 2016)'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    2.346
_exptl_crystal_description       needle
_exptl_crystal_F_000             1056
_exptl_crystal_size_max          0.150
_exptl_crystal_size_mid          0.050
_exptl_crystal_size_min          0.020
_refine_diff_density_max         0.795
_refine_diff_density_min         -0.821
_refine_diff_density_rms         0.088
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.117
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     379
_refine_ls_number_reflns         7113
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.117
_refine_ls_R_factor_all          0.0179
_refine_ls_R_factor_gt           0.0173
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0176P)²+2.8472P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0436
_refine_ls_wR_factor_ref         0.0440
_reflns_Friedel_coverage         0.000
_reflns_number_gt                6940
_reflns_number_total             7113
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d3dt03007e2.cif
_cod_data_source_block           sad_a_CCDC2
_cod_depositor_comments
'Adding full bibliography for 7714575--7714579.cif.'
_cod_database_code               7714579
_shelx_shelxl_version_number     2019/1
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.608
_shelx_estimated_absorpt_t_max   0.930
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.42573(2) 0.86441(2) 0.36691(2) 0.01690(4) Uani 1 1 d . . . . .
Ag2 Ag 0.54212(2) 0.82738(2) 0.52069(2) 0.01576(4) Uani 1 1 d . . . . .
Ag3 Ag 0.78279(2) 0.77187(2) 0.44337(2) 0.01563(4) Uani 1 1 d . . . . .
Ag4 Ag 0.66282(2) 0.79132(2) 0.28247(2) 0.01568(4) Uani 1 1 d . . . . .
Ag5 Ag 0.64940(2) 0.55852(2) 0.10128(2) 0.01679(4) Uani 1 1 d . . . . .
Ag6 Ag 0.42399(2) 0.39616(2) 0.06051(2) 0.01807(4) Uani 1 1 d . . . . .
C1 C 0.4823(2) 0.8723(2) 0.23256(16) 0.0176(5) Uani 1 1 d . . . . .
C2 C 0.4997(2) 0.9973(2) 0.22377(17) 0.0198(5) Uani 1 1 d . . . . .
H2 H 0.547573 1.061942 0.271859 0.024 Uiso 1 1 calc R U . . .
C3 C 0.4489(3) 1.0288(3) 0.14684(19) 0.0243(5) Uani 1 1 d . . . . .
H3 H 0.462112 1.113917 0.142981 0.029 Uiso 1 1 calc R U . . .
C4 C 0.3789(3) 0.9361(3) 0.07569(19) 0.0262(6) Uani 1 1 d . . . . .
H4 H 0.345004 0.957364 0.022774 0.031 Uiso 1 1 calc R U . . .
C5 C 0.3588(2) 0.8127(3) 0.08200(17) 0.0228(5) Uani 1 1 d . . . . .
H5 H 0.310529 0.748978 0.033522 0.027 Uiso 1 1 calc R U . . .
C6 C 0.4092(2) 0.7818(2) 0.15944(16) 0.0173(4) Uani 1 1 d . . . . .
H6 H 0.393617 0.696857 0.163044 0.021 Uiso 1 1 calc R U . . .
C7 C 0.3269(2) 0.8094(2) 0.47556(16) 0.0156(4) Uani 1 1 d . . . . .
C8 C 0.2548(2) 0.8923(2) 0.54430(18) 0.0207(5) Uani 1 1 d . . . . .
H8 H 0.286730 0.979151 0.571295 0.025 Uiso 1 1 calc R U . . .
C9 C 0.1379(3) 0.8517(3) 0.5743(2) 0.0300(6) Uani 1 1 d . . . . .
H9 H 0.093363 0.909676 0.622704 0.036 Uiso 1 1 calc R U . . .
C10 C 0.0862(3) 0.7277(3) 0.5341(2) 0.0275(6) Uani 1 1 d . . . . .
H10 H 0.006312 0.700025 0.554726 0.033 Uiso 1 1 calc R U . . .
C11 C 0.1515(3) 0.6442(3) 0.46389(18) 0.0229(5) Uani 1 1 d . . . . .
H11 H 0.114899 0.559578 0.434447 0.027 Uiso 1 1 calc R U . . .
C12 C 0.2706(2) 0.6836(2) 0.43620(16) 0.0191(5) Uani 1 1 d . . . . .
H12 H 0.315787 0.623773 0.389152 0.023 Uiso 1 1 calc R U . . .
C13 C 0.7362(2) 0.8052(2) 0.58782(16) 0.0165(4) Uani 1 1 d . . . . .
C14 C 0.8018(2) 0.9151(2) 0.64933(16) 0.0167(4) Uani 1 1 d . . . . .
H14 H 0.810840 0.991221 0.631197 0.020 Uiso 1 1 calc R U . . .
C15 C 0.8540(2) 0.9160(2) 0.73601(17) 0.0210(5) Uani 1 1 d . . . . .
H15 H 0.899040 0.991490 0.775682 0.025 Uiso 1 1 calc R U . . .
C16 C 0.8402(3) 0.8069(3) 0.76428(18) 0.0267(6) Uani 1 1 d . . . . .
H16 H 0.875697 0.807160 0.823411 0.032 Uiso 1 1 calc R U . . .
C17 C 0.7741(3) 0.6967(3) 0.7060(2) 0.0265(6) Uani 1 1 d . . . . .
H17 H 0.762475 0.622243 0.725767 0.032 Uiso 1 1 calc R U . . .
C18 C 0.7252(2) 0.6959(2) 0.61877(18) 0.0213(5) Uani 1 1 d . . . . .
H18 H 0.683052 0.618972 0.578797 0.026 Uiso 1 1 calc R U . . .
C19 C 0.8621(2) 0.7177(2) 0.30575(16) 0.0173(4) Uani 1 1 d . . . . .
C20 C 0.9674(2) 0.7941(2) 0.28921(18) 0.0210(5) Uani 1 1 d . . . . .
H20 H 0.961203 0.885590 0.308611 0.025 Uiso 1 1 calc R U . . .
C21 C 1.0802(3) 0.7391(3) 0.24528(18) 0.0230(5) Uani 1 1 d . . . . .
H21 H 1.148854 0.792921 0.234028 0.028 Uiso 1 1 calc R U . . .
C22 C 1.0928(3) 0.6066(3) 0.21795(18) 0.0245(5) Uani 1 1 d . . . . .
H22 H 1.170653 0.569193 0.188957 0.029 Uiso 1 1 calc R U . . .
C23 C 0.9915(3) 0.5284(2) 0.23295(18) 0.0228(5) Uani 1 1 d . . . . .
H23 H 0.999366 0.437059 0.213780 0.027 Uiso 1 1 calc R U . . .
C24 C 0.8781(2) 0.5833(2) 0.27602(16) 0.0174(4) Uani 1 1 d . . . . .
H24 H 0.809368 0.528219 0.285646 0.021 Uiso 1 1 calc R U . . .
C25 C 0.7546(2) 0.6794(2) 0.03243(16) 0.0175(4) Uani 1 1 d . . . . .
C26 C 0.7481(2) 0.8153(2) 0.06761(17) 0.0196(5) Uani 1 1 d . . . . .
H26 H 0.666478 0.852185 0.090620 0.023 Uiso 1 1 calc R U . . .
C27 C 0.8574(3) 0.8964(3) 0.06954(18) 0.0234(5) Uani 1 1 d . . . . .
H27 H 0.850216 0.987451 0.094152 0.028 Uiso 1 1 calc R U . . .
C28 C 0.9776(3) 0.8448(3) 0.03551(19) 0.0265(6) Uani 1 1 d . . . . .
H28 H 1.052540 0.900315 0.036679 0.032 Uiso 1 1 calc R U . . .
C29 C 0.9875(3) 0.7127(3) 0.00011(19) 0.0255(5) Uani 1 1 d . . . . .
H29 H 1.069328 0.676928 -0.023328 0.031 Uiso 1 1 calc R U . . .
C30 C 0.8773(3) 0.6313(2) -0.00135(17) 0.0212(5) Uani 1 1 d . . . . .
H30 H 0.885768 0.540371 -0.026027 0.025 Uiso 1 1 calc R U . . .
C31 C 0.5714(3) 0.4303(2) 0.17675(17) 0.0200(5) Uani 1 1 d . . . . .
C32 C 0.5269(2) 0.4987(2) 0.26303(17) 0.0206(5) Uani 1 1 d . . . . .
H32 H 0.470684 0.570212 0.267538 0.025 Uiso 1 1 calc R U . . .
C33 C 0.5625(3) 0.4652(3) 0.34240(18) 0.0255(5) Uani 1 1 d . . . . .
H33 H 0.531876 0.514361 0.400010 0.031 Uiso 1 1 calc R U . . .
C34 C 0.6418(3) 0.3610(3) 0.33731(19) 0.0279(6) Uani 1 1 d . . . . .
H34 H 0.665050 0.337559 0.391299 0.033 Uiso 1 1 calc R U . . .
C35 C 0.6883(3) 0.2899(3) 0.25332(19) 0.0266(6) Uani 1 1 d . . . . .
H35 H 0.743519 0.217948 0.249658 0.032 Uiso 1 1 calc R U . . .
C36 C 0.6533(3) 0.3249(2) 0.17485(18) 0.0233(5) Uani 1 1 d . . . . .
H36 H 0.685860 0.275882 0.117804 0.028 Uiso 1 1 calc R U . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C1 Ag1 C7 162.40(9) . . ?
C1 Ag1 Ag2 138.79(6) . . ?
C7 Ag1 Ag2 52.42(6) . . ?
C1 Ag1 Ag4 51.44(6) . . ?
C7 Ag1 Ag4 132.52(6) . . ?
Ag2 Ag1 Ag4 88.040(8) . . ?
C1 Ag1 Ag2 98.73(7) . 2_676 ?
C7 Ag1 Ag2 95.66(6) . 2_676 ?
Ag2 Ag1 Ag2 85.328(7) . 2_676 ?
Ag4 Ag1 Ag2 107.330(7) . 2_676 ?
C1 Ag1 Ag3 94.96(6) . . ?
C7 Ag1 Ag3 93.52(6) . . ?
Ag2 Ag1 Ag3 43.966(5) . . ?
Ag4 Ag1 Ag3 44.202(5) . . ?
Ag2 Ag1 Ag3 96.061(6) 2_676 . ?
C13 Ag2 C7 162.70(9) . . ?
C13 Ag2 Ag1 143.26(6) . . ?
C7 Ag2 Ag1 52.00(6) . . ?
C13 Ag2 Ag3 51.70(6) . . ?
C7 Ag2 Ag3 138.11(6) . . ?
Ag1 Ag2 Ag3 92.649(8) . . ?
C13 Ag2 Ag1 86.84(6) . 2_676 ?
C7 Ag2 Ag1 101.40(6) . 2_676 ?
Ag1 Ag2 Ag1 94.672(7) . 2_676 ?
Ag3 Ag2 Ag1 103.446(7) . 2_676 ?
C13 Ag2 Ag4 97.60(6) . . ?
C7 Ag2 Ag4 94.73(6) . . ?
Ag1 Ag2 Ag4 46.708(6) . . ?
Ag3 Ag2 Ag4 46.071(5) . . ?
Ag1 Ag2 Ag4 105.951(6) 2_676 . ?
C19 Ag3 C13 168.90(9) . . ?
C19 Ag3 Ag2 138.52(6) . . ?
C13 Ag3 Ag2 51.47(6) . . ?
C19 Ag3 Ag4 51.62(6) . . ?
C13 Ag3 Ag4 139.18(6) . . ?
Ag2 Ag3 Ag4 88.056(7) . . ?
C19 Ag3 Ag1 96.20(6) . . ?
C13 Ag3 Ag1 94.42(6) . . ?
Ag2 Ag3 Ag1 43.385(5) . . ?
Ag4 Ag3 Ag1 44.799(5) . . ?
C19 Ag4 C1 167.42(9) . . ?
C19 Ag4 Ag3 51.43(6) . . ?
C1 Ag4 Ag3 139.93(6) . . ?
C19 Ag4 Ag1 141.93(6) . . ?
C1 Ag4 Ag1 50.44(6) . . ?
Ag3 Ag4 Ag1 90.999(7) . . ?
C19 Ag4 Ag5 83.88(6) . . ?
C1 Ag4 Ag5 90.41(6) . . ?
Ag3 Ag4 Ag5 121.640(8) . . ?
Ag1 Ag4 Ag5 117.739(7) . . ?
C19 Ag4 Ag2 96.76(6) . . ?
C1 Ag4 Ag2 95.38(6) . . ?
Ag3 Ag4 Ag2 45.873(5) . . ?
Ag1 Ag4 Ag2 45.253(5) . . ?
Ag5 Ag4 Ag2 132.202(7) . . ?
C25 Ag5 C31 172.09(9) . . ?
C25 Ag5 Ag6 51.91(6) . 2_665 ?
C31 Ag5 Ag6 134.44(6) . 2_665 ?
C25 Ag5 Ag6 135.83(6) . . ?
C31 Ag5 Ag6 50.52(6) . . ?
Ag6 Ag5 Ag6 84.009(7) 2_665 . ?
C25 Ag5 Ag4 89.43(6) . . ?
C31 Ag5 Ag4 90.11(7) . . ?
Ag6 Ag5 Ag4 118.549(8) 2_665 . ?
Ag6 Ag5 Ag4 118.412(8) . . ?
C31 Ag6 C25 160.91(9) . 2_665 ?
C31 Ag6 Ag5 147.35(6) . 2_665 ?
C25 Ag6 Ag5 51.72(6) 2_665 2_665 ?
C31 Ag6 Ag5 51.47(6) . . ?
C25 Ag6 Ag5 147.60(6) 2_665 . ?
Ag5 Ag6 Ag5 95.991(7) 2_665 . ?
C6 C1 C2 116.1(2) . . ?
C6 C1 Ag1 112.55(16) . . ?
C2 C1 Ag1 115.76(17) . . ?
C6 C1 Ag4 113.13(17) . . ?
C2 C1 Ag4 115.56(17) . . ?
Ag1 C1 Ag4 78.12(8) . . ?
C3 C2 C1 121.9(2) . . ?
C3 C2 H2 119.0 . . ?
C1 C2 H2 119.0 . . ?
C4 C3 C2 120.1(2) . . ?
C4 C3 H3 119.9 . . ?
C2 C3 H3 119.9 . . ?
C5 C4 C3 119.8(2) . . ?
C5 C4 H4 120.1 . . ?
C3 C4 H4 120.1 . . ?
C4 C5 C6 119.9(2) . . ?
C4 C5 H5 120.0 . . ?
C6 C5 H5 120.0 . . ?
C5 C6 C1 122.2(2) . . ?
C5 C6 H6 118.9 . . ?
C1 C6 H6 118.9 . . ?
C8 C7 C12 115.8(2) . . ?
C8 C7 Ag1 125.38(17) . . ?
C12 C7 Ag1 107.63(16) . . ?
C8 C7 Ag2 109.18(17) . . ?
C12 C7 Ag2 117.53(17) . . ?
Ag1 C7 Ag2 75.58(7) . . ?
C9 C8 C7 122.1(2) . . ?
C9 C8 H8 119.0 . . ?
C7 C8 H8 119.0 . . ?
C10 C9 C8 120.4(2) . . ?
C10 C9 H9 119.8 . . ?
C8 C9 H9 119.8 . . ?
C11 C10 C9 119.5(2) . . ?
C11 C10 H10 120.3 . . ?
C9 C10 H10 120.3 . . ?
C10 C11 C12 120.0(2) . . ?
C10 C11 H11 120.0 . . ?
C12 C11 H11 120.0 . . ?
C11 C12 C7 122.2(2) . . ?
C11 C12 H12 118.9 . . ?
C7 C12 H12 118.9 . . ?
C14 C13 C18 116.3(2) . . ?
C14 C13 Ag2 118.82(17) . . ?
C18 C13 Ag2 107.71(16) . . ?
C14 C13 Ag3 113.98(16) . . ?
C18 C13 Ag3 117.17(17) . . ?
Ag2 C13 Ag3 76.83(7) . . ?
C15 C14 C13 122.1(2) . . ?
C15 C14 H14 119.0 . . ?
C13 C14 H14 119.0 . . ?
C16 C15 C14 119.9(2) . . ?
C16 C15 H15 120.1 . . ?
C14 C15 H15 120.1 . . ?
C15 C16 C17 119.8(2) . . ?
C15 C16 H16 120.1 . . ?
C17 C16 H16 120.1 . . ?
C16 C17 C18 119.8(2) . . ?
C16 C17 H17 120.1 . . ?
C18 C17 H17 120.1 . . ?
C17 C18 C13 122.1(2) . . ?
C17 C18 H18 119.0 . . ?
C13 C18 H18 119.0 . . ?
C24 C19 C20 116.2(2) . . ?
C24 C19 Ag3 108.76(17) . . ?
C20 C19 Ag3 118.58(17) . . ?
C24 C19 Ag4 117.95(17) . . ?
C20 C19 Ag4 112.58(17) . . ?
Ag3 C19 Ag4 76.94(7) . . ?
C21 C20 C19 121.8(2) . . ?
C21 C20 H20 119.1 . . ?
C19 C20 H20 119.1 . . ?
C22 C21 C20 120.2(2) . . ?
C22 C21 H21 119.9 . . ?
C20 C21 H21 119.9 . . ?
C21 C22 C23 119.7(2) . . ?
C21 C22 H22 120.2 . . ?
C23 C22 H22 120.2 . . ?
C22 C23 C24 120.1(2) . . ?
C22 C23 H23 120.0 . . ?
C24 C23 H23 120.0 . . ?
C23 C24 C19 122.0(2) . . ?
C23 C24 H24 119.0 . . ?
C19 C24 H24 119.0 . . ?
C30 C25 C26 116.3(2) . . ?
C30 C25 Ag5 114.31(17) . . ?
C26 C25 Ag5 118.83(17) . . ?
C30 C25 Ag6 115.51(17) . 2_665 ?
C26 C25 Ag6 109.03(16) . 2_665 ?
Ag5 C25 Ag6 76.37(8) . 2_665 ?
C27 C26 C25 121.8(2) . . ?
C27 C26 H26 119.1 . . ?
C25 C26 H26 119.1 . . ?
C26 C27 C28 120.2(2) . . ?
C26 C27 H27 119.9 . . ?
C28 C27 H27 119.9 . . ?
C29 C28 C27 119.6(2) . . ?
C29 C28 H28 120.2 . . ?
C27 C28 H28 120.2 . . ?
C28 C29 C30 120.1(2) . . ?
C28 C29 H29 120.0 . . ?
C30 C29 H29 120.0 . . ?
C29 C30 C25 122.0(2) . . ?
C29 C30 H30 119.0 . . ?
C25 C30 H30 119.0 . . ?
C32 C31 C36 116.0(2) . . ?
C32 C31 Ag6 115.96(18) . . ?
C36 C31 Ag6 114.65(17) . . ?
C32 C31 Ag5 112.86(17) . . ?
C36 C31 Ag5 113.65(18) . . ?
Ag6 C31 Ag5 78.01(8) . . ?
C33 C32 C31 122.0(2) . . ?
C33 C32 H32 119.0 . . ?
C31 C32 H32 119.0 . . ?
C34 C33 C32 120.0(3) . . ?
C34 C33 H33 120.0 . . ?
C32 C33 H33 120.0 . . ?
C33 C34 C35 120.1(2) . . ?
C33 C34 H34 119.9 . . ?
C35 C34 H34 119.9 . . ?
C36 C35 C34 119.4(3) . . ?
C36 C35 H35 120.3 . . ?
C34 C35 H35 120.3 . . ?
C35 C36 C31 122.4(3) . . ?
C35 C36 H36 118.8 . . ?
C31 C36 H36 118.8 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 C1 2.180(2) . ?
Ag1 C7 2.197(2) . ?
Ag1 Ag2 2.7002(3) . ?
Ag1 Ag4 2.7673(3) . ?
Ag1 Ag2 3.2682(3) 2_676 ?
Ag1 Ag3 3.9268(3) . ?
Ag2 C13 2.193(2) . ?
Ag2 C7 2.209(2) . ?
Ag2 Ag3 2.7290(2) . ?
Ag2 Ag4 3.7997(3) . ?
Ag3 C19 2.198(2) . ?
Ag3 C13 2.199(2) . ?
Ag3 Ag4 2.7381(3) . ?
Ag4 C19 2.204(2) . ?
Ag4 C1 2.211(2) . ?
Ag4 Ag5 3.1297(3) . ?
Ag5 C25 2.198(2) . ?
Ag5 C31 2.211(2) . ?
Ag5 Ag6 2.7209(3) 2_665 ?
Ag5 Ag6 2.7643(3) . ?
Ag6 C31 2.181(2) . ?
Ag6 C25 2.204(2) 2_665 ?
C1 C6 1.406(3) . ?
C1 C2 1.410(3) . ?
C2 C3 1.389(4) . ?
C2 H2 0.9500 . ?
C3 C4 1.386(4) . ?
C3 H3 0.9500 . ?
C4 C5 1.382(4) . ?
C4 H4 0.9500 . ?
C5 C6 1.391(3) . ?
C5 H5 0.9500 . ?
C6 H6 0.9500 . ?
C7 C8 1.400(3) . ?
C7 C12 1.411(3) . ?
C8 C9 1.389(4) . ?
C8 H8 0.9500 . ?
C9 C10 1.380(4) . ?
C9 H9 0.9500 . ?
C10 C11 1.379(4) . ?
C10 H10 0.9500 . ?
C11 C12 1.387(3) . ?
C11 H11 0.9500 . ?
C12 H12 0.9500 . ?
C13 C14 1.404(3) . ?
C13 C18 1.405(3) . ?
C14 C15 1.391(3) . ?
C14 H14 0.9500 . ?
C15 C16 1.382(4) . ?
C15 H15 0.9500 . ?
C16 C17 1.389(4) . ?
C16 H16 0.9500 . ?
C17 C18 1.390(4) . ?
C17 H17 0.9500 . ?
C18 H18 0.9500 . ?
C19 C24 1.404(3) . ?
C19 C20 1.409(3) . ?
C20 C21 1.390(3) . ?
C20 H20 0.9500 . ?
C21 C22 1.379(4) . ?
C21 H21 0.9500 . ?
C22 C23 1.383(4) . ?
C22 H22 0.9500 . ?
C23 C24 1.389(3) . ?
C23 H23 0.9500 . ?
C24 H24 0.9500 . ?
C25 C30 1.401(3) . ?
C25 C26 1.412(3) . ?
C26 C27 1.386(3) . ?
C26 H26 0.9500 . ?
C27 C28 1.391(4) . ?
C27 H27 0.9500 . ?
C28 C29 1.377(4) . ?
C28 H28 0.9500 . ?
C29 C30 1.397(4) . ?
C29 H29 0.9500 . ?
C30 H30 0.9500 . ?
C31 C32 1.402(4) . ?
C31 C36 1.408(4) . ?
C32 C33 1.394(3) . ?
C32 H32 0.9500 . ?
C33 C34 1.372(4) . ?
C33 H33 0.9500 . ?
C34 C35 1.390(4) . ?
C34 H34 0.9500 . ?
C35 C36 1.388(4) . ?
C35 H35 0.9500 . ?
C36 H36 0.9500 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C6 C1 C2 C3 -0.8(4) . . . . ?
Ag1 C1 C2 C3 -136.1(2) . . . . ?
Ag4 C1 C2 C3 135.2(2) . . . . ?
C1 C2 C3 C4 -0.1(4) . . . . ?
C2 C3 C4 C5 0.7(4) . . . . ?
C3 C4 C5 C6 -0.3(4) . . . . ?
C4 C5 C6 C1 -0.7(4) . . . . ?
C2 C1 C6 C5 1.2(3) . . . . ?
Ag1 C1 C6 C5 137.8(2) . . . . ?
Ag4 C1 C6 C5 -135.9(2) . . . . ?
C12 C7 C8 C9 2.4(4) . . . . ?
Ag1 C7 C8 C9 141.4(2) . . . . ?
Ag2 C7 C8 C9 -133.0(2) . . . . ?
C7 C8 C9 C10 -2.4(4) . . . . ?
C8 C9 C10 C11 0.0(4) . . . . ?
C9 C10 C11 C12 2.2(4) . . . . ?
C10 C11 C12 C7 -2.1(4) . . . . ?
C8 C7 C12 C11 -0.1(4) . . . . ?
Ag1 C7 C12 C11 -146.0(2) . . . . ?
Ag2 C7 C12 C11 131.4(2) . . . . ?
C18 C13 C14 C15 0.4(3) . . . . ?
Ag2 C13 C14 C15 131.7(2) . . . . ?
Ag3 C13 C14 C15 -140.6(2) . . . . ?
C13 C14 C15 C16 -1.0(4) . . . . ?
C14 C15 C16 C17 0.0(4) . . . . ?
C15 C16 C17 C18 1.6(4) . . . . ?
C16 C17 C18 C13 -2.2(4) . . . . ?
C14 C13 C18 C17 1.2(4) . . . . ?
Ag2 C13 C18 C17 -135.1(2) . . . . ?
Ag3 C13 C18 C17 140.9(2) . . . . ?
C24 C19 C20 C21 0.5(4) . . . . ?
Ag3 C19 C20 C21 133.1(2) . . . . ?
Ag4 C19 C20 C21 -139.9(2) . . . . ?
C19 C20 C21 C22 -1.2(4) . . . . ?
C20 C21 C22 C23 1.2(4) . . . . ?
C21 C22 C23 C24 -0.5(4) . . . . ?
C22 C23 C24 C19 -0.2(4) . . . . ?
C20 C19 C24 C23 0.2(4) . . . . ?
Ag3 C19 C24 C23 -136.7(2) . . . . ?
Ag4 C19 C24 C23 138.4(2) . . . . ?
C30 C25 C26 C27 -0.7(4) . . . . ?
Ag5 C25 C26 C27 142.0(2) . . . . ?
Ag6 C25 C26 C27 -133.4(2) 2_665 . . . ?
C25 C26 C27 C28 0.6(4) . . . . ?
C26 C27 C28 C29 -0.1(4) . . . . ?
C27 C28 C29 C30 -0.1(4) . . . . ?
C28 C29 C30 C25 0.0(4) . . . . ?
C26 C25 C30 C29 0.4(4) . . . . ?
Ag5 C25 C30 C29 -144.0(2) . . . . ?
Ag6 C25 C30 C29 130.1(2) 2_665 . . . ?
C36 C31 C32 C33 0.5(4) . . . . ?
Ag6 C31 C32 C33 139.5(2) . . . . ?
Ag5 C31 C32 C33 -133.1(2) . . . . ?
C31 C32 C33 C34 -1.0(4) . . . . ?
C32 C33 C34 C35 0.9(4) . . . . ?
C33 C34 C35 C36 -0.2(4) . . . . ?
C34 C35 C36 C31 -0.3(4) . . . . ?
C32 C31 C36 C35 0.1(4) . . . . ?
Ag6 C31 C36 C35 -139.4(2) . . . . ?
Ag5 C31 C36 C35 133.4(2) . . . . ?
