#------------------------------------------------------------------------------
#$Date: 2024-06-06 01:51:13 +0300 (Thu, 06 Jun 2024) $
#$Revision: 292210 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/71/63/7716308.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7716308
loop_
_publ_author_name
'Dunes, Gabriel'
'Cordier, Marie'
'Kahlal, Samia'
'Pollnitz, Alpar'
'Saillard, Jean-Yves'
'Silvestru, Cristian'
'Sarazin, Yann'
_publ_section_title
;
 C--H Bond Activation at Antimony(III): Synthesis and Reactivity of
 Sb(III)-Oxyaryl Species
;
_journal_name_full               'Dalton Transactions'
_journal_paper_doi               10.1039/D4DT01400F
_journal_year                    2024
_chemical_compound_source        'synthesis as described'
_chemical_formula_moiety         'C26 H39 N2 O Sb'
_chemical_formula_sum            'C26 H39 N2 O Sb'
_chemical_formula_weight         517.34
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_audit_update_record
;
2024-02-28 deposited with the CCDC.	2024-05-31 downloaded from the CCDC.
;
_cell_angle_alpha                107.461(3)
_cell_angle_beta                 93.163(3)
_cell_angle_gamma                113.351(3)
_cell_formula_units_Z            2
_cell_length_a                   9.8727(10)
_cell_length_b                   10.5653(9)
_cell_length_c                   14.2599(14)
_cell_measurement_reflns_used    9896
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      27.4754
_cell_measurement_theta_min      2.2927
_cell_measurement_wavelength     0.710730
_cell_volume                     1276.7(2)
_computing_cell_refinement       'APEX3 (Bruker, 2015)'
_computing_data_collection       'Bruker APEX3 (Bruker, 2015)'
_computing_data_reduction        'SAINT (Bruker, 2014)'
_computing_molecular_graphics
;
   'SXGRAPH (L. Farrugia, 1999), Mercury (CSD, 2020)'
;
_computing_publication_material
'CRYSCALC (T. Roisnel, local program, ver. 2023)'
_computing_structure_refinement  'SHELXL-2018_3 (Sheldrick, 2018)'
_computing_structure_solution    'SHELXT 2018_2 (Sheldrick, 2018)'
_diffrn_ambient_temperature      150(2)
_diffrn_detector                 CMOS-PHOTON70
_diffrn_detector_area_resol_mean 7.39
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device_type  'D8 VENTURE Bruker AXS'
_diffrn_measurement_method       'rotation images'
_diffrn_orient_matrix_UB_11      0.1104354
_diffrn_orient_matrix_UB_12      0.0452596
_diffrn_orient_matrix_UB_13      0.0007235
_diffrn_orient_matrix_UB_21      0.0216785
_diffrn_orient_matrix_UB_22      0.0289224
_diffrn_orient_matrix_UB_23      0.0746446
_diffrn_orient_matrix_UB_31      0.0026179
_diffrn_orient_matrix_UB_32      -0.0961170
_diffrn_orient_matrix_UB_33      -0.0073745
_diffrn_radiation_monochromator  'multilayer monochromator'
_diffrn_radiation_probe          x-ray
_diffrn_radiation_source         'Incoatec microfocus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0263
_diffrn_reflns_av_unetI/netI     0.0183
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            31990
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.481
_diffrn_reflns_theta_min         2.242
_diffrn_source_current           1.00
_diffrn_source_power             50.0
_diffrn_source_voltage           50.00
_exptl_absorpt_coefficient_mu    1.099
_exptl_absorpt_correction_T_max  0.896
_exptl_absorpt_correction_T_min  0.781
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
  [Sheldrick, G.M. (2014). SADABS Bruker AXS Inc., Madison, Wisconsin, USA]
;
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.346
_exptl_crystal_description       prism
_exptl_crystal_F_000             536
_exptl_crystal_size_max          0.400
_exptl_crystal_size_mid          0.280
_exptl_crystal_size_min          0.100
_refine_diff_density_max         0.319
_refine_diff_density_min         -0.272
_refine_diff_density_rms         0.045
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.069
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     281
_refine_ls_number_reflns         5840
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.069
_refine_ls_R_factor_all          0.0171
_refine_ls_R_factor_gt           0.0158
_refine_ls_shift/su_max          0.004
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0171P)²+0.4073P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0388
_refine_ls_wR_factor_ref         0.0394
_reflns_number_gt                5583
_reflns_number_total             5840
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            d4dt01400f3.cif
_cod_data_source_block           3
_cod_database_code               7716308
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Sb1 Sb 0.73898(2) 0.65696(2) 0.26984(2) 0.01911(3) Uani 1 1 d . . . . .
O1 O 0.09785(11) 0.18492(10) 0.22849(9) 0.0328(2) Uani 1 1 d . . . . .
N1 N 0.71832(12) 0.75721(12) 0.13864(8) 0.0235(2) Uani 1 1 d . . . . .
N2 N 0.74483(12) 0.68067(12) 0.44600(8) 0.0221(2) Uani 1 1 d . . . . .
C1 C 0.71878(13) 0.85350(13) 0.34092(9) 0.0196(2) Uani 1 1 d . . . . .
C2 C 0.74708(14) 0.95549(14) 0.29307(10) 0.0227(3) Uani 1 1 d . . . . .
C3 C 0.73856(15) 1.08723(15) 0.34141(11) 0.0278(3) Uani 1 1 d . . . . .
H3 H 0.756658 1.158057 0.309687 0.033 Uiso 1 1 calc R U . . .
C4 C 0.70347(16) 1.11426(15) 0.43615(11) 0.0297(3) Uani 1 1 d . . . . .
H4 H 0.697352 1.203982 0.468761 0.036 Uiso 1 1 calc R U . . .
C5 C 0.67715(15) 1.01285(15) 0.48415(10) 0.0271(3) Uani 1 1 d . . . . .
H5 H 0.654319 1.033452 0.549323 0.032 Uiso 1 1 calc R U . . .
C6 C 0.68447(14) 0.88060(14) 0.43605(9) 0.0215(2) Uani 1 1 d . . . . .
C7 C 0.79183(16) 0.91988(15) 0.19251(10) 0.0280(3) Uani 1 1 d . . . . .
H7A H 0.760583 0.968931 0.152199 0.034 Uiso 1 1 calc R U . . .
H7B H 0.902590 0.956800 0.201970 0.034 Uiso 1 1 calc R U . . .
C8 C 0.79947(18) 0.71128(18) 0.06093(11) 0.0351(3) Uani 1 1 d . . . . .
H8A H 0.749754 0.603931 0.028363 0.053 Uiso 1 1 calc R U . . .
H8B H 0.903710 0.742120 0.092196 0.053 Uiso 1 1 calc R U . . .
H8C H 0.798707 0.757364 0.010756 0.053 Uiso 1 1 calc R U . . .
C9 C 0.56128(16) 0.71054(15) 0.09227(10) 0.0281(3) Uani 1 1 d . . . . .
H9A H 0.559708 0.744463 0.035530 0.042 Uiso 1 1 calc R U . . .
H9B H 0.512112 0.753207 0.141946 0.042 Uiso 1 1 calc R U . . .
H9C H 0.507521 0.602889 0.068478 0.042 Uiso 1 1 calc R U . . .
C10 C 0.65202(15) 0.76030(15) 0.47969(10) 0.0243(3) Uani 1 1 d . . . . .
H10A H 0.674862 0.803742 0.553850 0.029 Uiso 1 1 calc R U . . .
H10B H 0.543984 0.690581 0.457838 0.029 Uiso 1 1 calc R U . . .
C11 C 0.90236(16) 0.77045(16) 0.50132(11) 0.0306(3) Uani 1 1 d . . . . .
H11A H 0.942946 0.864511 0.490114 0.046 Uiso 1 1 calc R U . . .
H11B H 0.962960 0.717535 0.477349 0.046 Uiso 1 1 calc R U . . .
H11C H 0.905563 0.788805 0.573161 0.046 Uiso 1 1 calc R U . . .
C12 C 0.68381(16) 0.53754(15) 0.46086(11) 0.0285(3) Uani 1 1 d . . . . .
H12A H 0.681840 0.553640 0.532028 0.043 Uiso 1 1 calc R U . . .
H12B H 0.747719 0.487515 0.439277 0.043 Uiso 1 1 calc R U . . .
H12C H 0.581350 0.476447 0.421147 0.043 Uiso 1 1 calc R U . . .
C13 C 0.51472(13) 0.50176(13) 0.23583(9) 0.0190(2) Uani 1 1 d . . . . .
C14 C 0.48609(14) 0.35252(13) 0.20597(9) 0.0191(2) Uani 1 1 d . . . . .
H14 H 0.566372 0.326763 0.191030 0.023 Uiso 1 1 calc R U . . .
C15 C 0.34617(14) 0.24193(13) 0.19747(9) 0.0182(2) Uani 1 1 d . . . . .
C16 C 0.22289(14) 0.27998(13) 0.22290(9) 0.0200(2) Uani 1 1 d . . . . .
C17 C 0.24900(13) 0.43176(13) 0.24122(9) 0.0176(2) Uani 1 1 d . . . . .
C18 C 0.39257(13) 0.53681(13) 0.25105(9) 0.0180(2) Uani 1 1 d . . . . .
H18 H 0.409619 0.636807 0.268816 0.022 Uiso 1 1 calc R U . . .
C19 C 0.31751(16) 0.07951(13) 0.16133(9) 0.0226(3) Uani 1 1 d . . . . .
C20 C 0.45521(19) 0.05876(16) 0.12980(12) 0.0348(3) Uani 1 1 d . . . . .
H20A H 0.538412 0.108530 0.187998 0.052 Uiso 1 1 calc R U . . .
H20B H 0.485257 0.100995 0.077588 0.052 Uiso 1 1 calc R U . . .
H20C H 0.430117 -0.046536 0.103639 0.052 Uiso 1 1 calc R U . . .
C21 C 0.18783(18) -0.00948(15) 0.06942(10) 0.0323(3) Uani 1 1 d . . . . .
H21A H 0.218682 0.022427 0.013064 0.049 Uiso 1 1 calc R U . . .
H21B H 0.099496 0.006834 0.085494 0.049 Uiso 1 1 calc R U . . .
H21C H 0.162627 -0.114460 0.051085 0.049 Uiso 1 1 calc R U . . .
C22 C 0.2785(2) 0.01554(16) 0.24486(11) 0.0371(4) Uani 1 1 d . . . . .
H22A H 0.251765 -0.090102 0.218585 0.056 Uiso 1 1 calc R U . . .
H22B H 0.193140 0.030670 0.269021 0.056 Uiso 1 1 calc R U . . .
H22C H 0.365705 0.065176 0.300371 0.056 Uiso 1 1 calc R U . . .
C23 C 0.11529(14) 0.47204(13) 0.24744(9) 0.0199(2) Uani 1 1 d . . . . .
C24 C -0.00707(16) 0.37286(17) 0.15213(11) 0.0329(3) Uani 1 1 d . . . . .
H24A H -0.093802 0.395988 0.157351 0.049 Uiso 1 1 calc R U . . .
H24B H -0.038658 0.269412 0.144793 0.049 Uiso 1 1 calc R U . . .
H24C H 0.033275 0.389990 0.093516 0.049 Uiso 1 1 calc R U . . .
C25 C 0.04739(16) 0.45304(16) 0.33916(11) 0.0287(3) Uani 1 1 d . . . . .
H25A H 0.121305 0.523685 0.400483 0.043 Uiso 1 1 calc R U . . .
H25B H 0.020300 0.352658 0.337957 0.043 Uiso 1 1 calc R U . . .
H25C H -0.042856 0.470635 0.337698 0.043 Uiso 1 1 calc R U . . .
C26 C 0.16141(16) 0.63159(15) 0.25456(12) 0.0308(3) Uani 1 1 d . . . . .
H26A H 0.236411 0.698285 0.316207 0.046 Uiso 1 1 calc R U . . .
H26B H 0.072730 0.651828 0.255639 0.046 Uiso 1 1 calc R U . . .
H26C H 0.204614 0.646804 0.196397 0.046 Uiso 1 1 calc R U . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sb Sb -0.5866 1.5461 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C13 Sb1 C1 101.02(5) . . ?
C13 Sb1 N2 89.09(4) . . ?
C1 Sb1 N2 74.16(4) . . ?
C13 Sb1 N1 96.54(4) . . ?
C1 Sb1 N1 73.94(4) . . ?
N2 Sb1 N1 148.10(4) . . ?
C9 N1 C8 109.78(11) . . ?
C9 N1 C7 109.56(11) . . ?
C8 N1 C7 111.69(11) . . ?
C9 N1 Sb1 113.01(8) . . ?
C8 N1 Sb1 108.87(9) . . ?
C7 N1 Sb1 103.84(8) . . ?
C12 N2 C11 109.82(11) . . ?
C12 N2 C10 110.77(10) . . ?
C11 N2 C10 110.28(11) . . ?
C12 N2 Sb1 113.18(8) . . ?
C11 N2 Sb1 108.40(8) . . ?
C10 N2 Sb1 104.25(7) . . ?
C2 C1 C6 121.64(12) . . ?
C2 C1 Sb1 118.93(9) . . ?
C6 C1 Sb1 119.35(9) . . ?
C1 C2 C3 118.93(12) . . ?
C1 C2 C7 117.76(12) . . ?
C3 C2 C7 123.26(12) . . ?
C4 C3 C2 119.57(13) . . ?
C4 C3 H3 120.2 . . ?
C2 C3 H3 120.2 . . ?
C5 C4 C3 121.29(13) . . ?
C5 C4 H4 119.4 . . ?
C3 C4 H4 119.4 . . ?
C4 C5 C6 119.46(13) . . ?
C4 C5 H5 120.3 . . ?
C6 C5 H5 120.3 . . ?
C1 C6 C5 119.11(12) . . ?
C1 C6 C10 117.05(11) . . ?
C5 C6 C10 123.81(12) . . ?
N1 C7 C2 109.62(10) . . ?
N1 C7 H7A 109.7 . . ?
C2 C7 H7A 109.7 . . ?
N1 C7 H7B 109.7 . . ?
C2 C7 H7B 109.7 . . ?
H7A C7 H7B 108.2 . . ?
N1 C8 H8A 109.5 . . ?
N1 C8 H8B 109.5 . . ?
H8A C8 H8B 109.5 . . ?
N1 C8 H8C 109.5 . . ?
H8A C8 H8C 109.5 . . ?
H8B C8 H8C 109.5 . . ?
N1 C9 H9A 109.5 . . ?
N1 C9 H9B 109.5 . . ?
H9A C9 H9B 109.5 . . ?
N1 C9 H9C 109.5 . . ?
H9A C9 H9C 109.5 . . ?
H9B C9 H9C 109.5 . . ?
N2 C10 C6 110.01(10) . . ?
N2 C10 H10A 109.7 . . ?
C6 C10 H10A 109.7 . . ?
N2 C10 H10B 109.7 . . ?
C6 C10 H10B 109.7 . . ?
H10A C10 H10B 108.2 . . ?
N2 C11 H11A 109.5 . . ?
N2 C11 H11B 109.5 . . ?
H11A C11 H11B 109.5 . . ?
N2 C11 H11C 109.5 . . ?
H11A C11 H11C 109.5 . . ?
H11B C11 H11C 109.5 . . ?
N2 C12 H12A 109.5 . . ?
N2 C12 H12B 109.5 . . ?
H12A C12 H12B 109.5 . . ?
N2 C12 H12C 109.5 . . ?
H12A C12 H12C 109.5 . . ?
H12B C12 H12C 109.5 . . ?
C18 C13 C14 117.84(11) . . ?
C18 C13 Sb1 124.35(9) . . ?
C14 C13 Sb1 117.44(9) . . ?
C15 C14 C13 122.72(11) . . ?
C15 C14 H14 118.6 . . ?
C13 C14 H14 118.6 . . ?
C14 C15 C16 119.33(11) . . ?
C14 C15 C19 121.37(11) . . ?
C16 C15 C19 119.30(11) . . ?
O1 C16 C17 121.39(11) . . ?
O1 C16 C15 121.57(11) . . ?
C17 C16 C15 117.04(11) . . ?
C18 C17 C16 119.59(11) . . ?
C18 C17 C23 120.91(11) . . ?
C16 C17 C23 119.49(10) . . ?
C17 C18 C13 122.54(11) . . ?
C17 C18 H18 118.7 . . ?
C13 C18 H18 118.7 . . ?
C20 C19 C22 107.14(12) . . ?
C20 C19 C15 112.24(11) . . ?
C22 C19 C15 110.73(10) . . ?
C20 C19 C21 107.21(11) . . ?
C22 C19 C21 109.66(12) . . ?
C15 C19 C21 109.75(11) . . ?
C19 C20 H20A 109.5 . . ?
C19 C20 H20B 109.5 . . ?
H20A C20 H20B 109.5 . . ?
C19 C20 H20C 109.5 . . ?
H20A C20 H20C 109.5 . . ?
H20B C20 H20C 109.5 . . ?
C19 C21 H21A 109.5 . . ?
C19 C21 H21B 109.5 . . ?
H21A C21 H21B 109.5 . . ?
C19 C21 H21C 109.5 . . ?
H21A C21 H21C 109.5 . . ?
H21B C21 H21C 109.5 . . ?
C19 C22 H22A 109.5 . . ?
C19 C22 H22B 109.5 . . ?
H22A C22 H22B 109.5 . . ?
C19 C22 H22C 109.5 . . ?
H22A C22 H22C 109.5 . . ?
H22B C22 H22C 109.5 . . ?
C26 C23 C25 107.65(11) . . ?
C26 C23 C24 107.25(12) . . ?
C25 C23 C24 108.96(11) . . ?
C26 C23 C17 111.89(10) . . ?
C25 C23 C17 111.41(11) . . ?
C24 C23 C17 109.56(10) . . ?
C23 C24 H24A 109.5 . . ?
C23 C24 H24B 109.5 . . ?
H24A C24 H24B 109.5 . . ?
C23 C24 H24C 109.5 . . ?
H24A C24 H24C 109.5 . . ?
H24B C24 H24C 109.5 . . ?
C23 C25 H25A 109.5 . . ?
C23 C25 H25B 109.5 . . ?
H25A C25 H25B 109.5 . . ?
C23 C25 H25C 109.5 . . ?
H25A C25 H25C 109.5 . . ?
H25B C25 H25C 109.5 . . ?
C23 C26 H26A 109.5 . . ?
C23 C26 H26B 109.5 . . ?
H26A C26 H26B 109.5 . . ?
C23 C26 H26C 109.5 . . ?
H26A C26 H26C 109.5 . . ?
H26B C26 H26C 109.5 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Sb1 C13 2.0862(12) . ?
Sb1 C1 2.1134(13) . ?
Sb1 N2 2.4436(11) . ?
Sb1 N1 2.4458(11) . ?
O1 C16 1.2708(16) . ?
N1 C9 1.4728(17) . ?
N1 C8 1.4795(18) . ?
N1 C7 1.4926(17) . ?
N2 C12 1.4760(17) . ?
N2 C11 1.4788(17) . ?
N2 C10 1.4817(17) . ?
C1 C2 1.3885(18) . ?
C1 C6 1.3898(18) . ?
C2 C3 1.3939(19) . ?
C2 C7 1.5070(19) . ?
C3 C4 1.388(2) . ?
C3 H3 0.9500 . ?
C4 C5 1.387(2) . ?
C4 H4 0.9500 . ?
C5 C6 1.3923(19) . ?
C5 H5 0.9500 . ?
C6 C10 1.5097(18) . ?
C7 H7A 0.9900 . ?
C7 H7B 0.9900 . ?
C8 H8A 0.9800 . ?
C8 H8B 0.9800 . ?
C8 H8C 0.9800 . ?
C9 H9A 0.9800 . ?
C9 H9B 0.9800 . ?
C9 H9C 0.9800 . ?
C10 H10A 0.9900 . ?
C10 H10B 0.9900 . ?
C11 H11A 0.9800 . ?
C11 H11B 0.9800 . ?
C11 H11C 0.9800 . ?
C12 H12A 0.9800 . ?
C12 H12B 0.9800 . ?
C12 H12C 0.9800 . ?
C13 C18 1.4047(17) . ?
C13 C14 1.4063(17) . ?
C14 C15 1.3803(17) . ?
C14 H14 0.9500 . ?
C15 C16 1.4572(18) . ?
C15 C19 1.5358(16) . ?
C16 C17 1.4559(17) . ?
C17 C18 1.3777(17) . ?
C17 C23 1.5386(17) . ?
C18 H18 0.9500 . ?
C19 C20 1.531(2) . ?
C19 C22 1.5334(18) . ?
C19 C21 1.5369(18) . ?
C20 H20A 0.9800 . ?
C20 H20B 0.9800 . ?
C20 H20C 0.9800 . ?
C21 H21A 0.9800 . ?
C21 H21B 0.9800 . ?
C21 H21C 0.9800 . ?
C22 H22A 0.9800 . ?
C22 H22B 0.9800 . ?
C22 H22C 0.9800 . ?
C23 C26 1.5306(18) . ?
C23 C25 1.5323(18) . ?
C23 C24 1.5379(18) . ?
C24 H24A 0.9800 . ?
C24 H24B 0.9800 . ?
C24 H24C 0.9800 . ?
C25 H25A 0.9800 . ?
C25 H25B 0.9800 . ?
C25 H25C 0.9800 . ?
C26 H26A 0.9800 . ?
C26 H26B 0.9800 . ?
C26 H26C 0.9800 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C6 C1 C2 C3 -0.95(18) . . . . ?
Sb1 C1 C2 C3 -177.92(9) . . . . ?
C6 C1 C2 C7 176.63(11) . . . . ?
Sb1 C1 C2 C7 -0.34(15) . . . . ?
C1 C2 C3 C4 0.55(19) . . . . ?
C7 C2 C3 C4 -176.89(12) . . . . ?
C2 C3 C4 C5 0.3(2) . . . . ?
C3 C4 C5 C6 -0.7(2) . . . . ?
C2 C1 C6 C5 0.53(18) . . . . ?
Sb1 C1 C6 C5 177.49(9) . . . . ?
C2 C1 C6 C10 178.53(11) . . . . ?
Sb1 C1 C6 C10 -4.51(15) . . . . ?
C4 C5 C6 C1 0.29(19) . . . . ?
C4 C5 C6 C10 -177.57(12) . . . . ?
C9 N1 C7 C2 80.09(14) . . . . ?
C8 N1 C7 C2 -158.04(12) . . . . ?
Sb1 N1 C7 C2 -40.89(12) . . . . ?
C1 C2 C7 N1 31.47(16) . . . . ?
C3 C2 C7 N1 -151.05(12) . . . . ?
C12 N2 C10 C6 -162.63(11) . . . . ?
C11 N2 C10 C6 75.60(13) . . . . ?
Sb1 N2 C10 C6 -40.57(11) . . . . ?
C1 C6 C10 N2 33.67(15) . . . . ?
C5 C6 C10 N2 -148.42(12) . . . . ?
C18 C13 C14 C15 -4.21(19) . . . . ?
Sb1 C13 C14 C15 169.10(9) . . . . ?
C13 C14 C15 C16 -1.76(18) . . . . ?
C13 C14 C15 C19 177.97(11) . . . . ?
C14 C15 C16 O1 -171.01(12) . . . . ?
C19 C15 C16 O1 9.25(18) . . . . ?
C14 C15 C16 C17 9.27(17) . . . . ?
C19 C15 C16 C17 -170.47(11) . . . . ?
O1 C16 C17 C18 169.19(12) . . . . ?
C15 C16 C17 C18 -11.09(17) . . . . ?
O1 C16 C17 C23 -11.90(18) . . . . ?
C15 C16 C17 C23 167.82(11) . . . . ?
C16 C17 C18 C13 5.47(19) . . . . ?
C23 C17 C18 C13 -173.43(11) . . . . ?
C14 C13 C18 C17 2.30(19) . . . . ?
Sb1 C13 C18 C17 -170.50(9) . . . . ?
C14 C15 C19 C20 -4.47(17) . . . . ?
C16 C15 C19 C20 175.27(11) . . . . ?
C14 C15 C19 C22 115.22(14) . . . . ?
C16 C15 C19 C22 -65.04(16) . . . . ?
C14 C15 C19 C21 -123.58(13) . . . . ?
C16 C15 C19 C21 56.16(15) . . . . ?
C18 C17 C23 C26 5.65(17) . . . . ?
C16 C17 C23 C26 -173.25(12) . . . . ?
C18 C17 C23 C25 -114.91(13) . . . . ?
C16 C17 C23 C25 66.19(14) . . . . ?
C18 C17 C23 C24 124.45(13) . . . . ?
C16 C17 C23 C24 -54.45(15) . . . . ?
