#------------------------------------------------------------------------------
#$Date: 2025-03-04 21:58:40 +0200 (Tue, 04 Mar 2025) $
#$Revision: 298233 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/71/73/7717324.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7717324
loop_
_publ_author_name
'Bombaci, Matteo'
'Lo Presti, Francesca'
'Pellegrino, Anna L.'
'Lippi, Martina'
'Rossi, Patrizia'
'Tacconi, Leonardo'
'Sorace, Lorenzo'
'Malandrino, Graziella'
_publ_section_title
;
 Bifunctional heterobimetallic 3d-4f [Co(II)-RE, RE = Dy, Eu, and Y] ionic
 complexes: modulation of the magnetic-luminescence behaviour.
;
_journal_issue                   1
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              274
_journal_page_last               289
_journal_paper_doi               10.1039/d4dt01693a
_journal_volume                  54
_journal_year                    2024
_chemical_formula_sum            'C35 H27 Co Eu F30 O15'
_chemical_formula_weight         1468.45
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2yn'
_space_group_name_H-M_alt        'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2018/3
_audit_update_record
;
2024-06-07 deposited with the CCDC.	2024-10-28 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 95.082(2)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   14.3491(9)
_cell_length_b                   23.3241(13)
_cell_length_c                   15.1101(10)
_cell_measurement_reflns_used    9649
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      30.30
_cell_measurement_theta_min      2.23
_cell_volume                     5037.2(5)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-2014 (Sheldrick 2014)'
_computing_structure_solution    'SIR 2004 (Burla, 2005)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0731
_diffrn_reflns_av_unetI/netI     0.0415
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.996
_diffrn_reflns_limit_h_max       20
_diffrn_reflns_limit_h_min       -20
_diffrn_reflns_limit_k_max       33
_diffrn_reflns_limit_k_min       -33
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_number            119698
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.996
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         30.597
_diffrn_reflns_theta_min         2.050
_exptl_absorpt_coefficient_mu    1.736
_exptl_absorpt_correction_T_max  0.7461
_exptl_absorpt_correction_T_min  0.6487
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS-2016/2, Scheldrick 2015'
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    1.936
_exptl_crystal_description       prism
_exptl_crystal_F_000             2868
_exptl_crystal_size_max          0.2
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.17
_refine_diff_density_max         1.535
_refine_diff_density_min         -1.558
_refine_diff_density_rms         0.114
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.035
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     739
_refine_ls_number_reflns         15458
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.035
_refine_ls_R_factor_all          0.0535
_refine_ls_R_factor_gt           0.0359
_refine_ls_shift/su_max          0.004
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0345P)²+7.9046P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0796
_refine_ls_wR_factor_ref         0.0893
_reflns_Friedel_coverage         0.000
_reflns_number_gt                12340
_reflns_number_total             15458
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d4dt01693a2.cif
_cod_data_source_block           Eu-Co
_cod_depositor_comments
'Adding full bibliography for 7717324--7717325.cif.'
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               7717324
_shelx_shelxl_version_number     2018/3
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.93068(2) 0.72879(2) 0.73297(2) 0.01533(4) Uani 1 1 d . . . . .
O1A O 0.84370(14) 0.78549(8) 0.62420(13) 0.0229(4) Uani 1 1 d . . . . .
O2A O 1.02929(13) 0.75934(8) 0.61968(13) 0.0203(4) Uani 1 1 d . . . . .
C1A C 0.8571(2) 0.81049(12) 0.55211(18) 0.0221(5) Uani 1 1 d . . . . .
C2A C 0.9378(2) 0.81161(12) 0.50843(19) 0.0238(5) Uani 1 1 d . . . . .
H2A H 0.938007 0.830065 0.452401 0.029 Uiso 1 1 calc R U . . .
C3A C 1.01909(19) 0.78538(11) 0.54731(18) 0.0207(5) Uani 1 1 d . . . . .
C4A C 0.7703(2) 0.84238(15) 0.5113(2) 0.0335(7) Uani 1 1 d . . . . .
C5A C 1.1088(2) 0.78867(14) 0.4995(2) 0.0291(6) Uani 1 1 d . . . . .
F4A1 F 0.73857(18) 0.87873(11) 0.56896(16) 0.0565(7) Uani 1 1 d . . . . .
F4A2 F 0.70128(14) 0.80495(11) 0.48889(15) 0.0484(6) Uani 1 1 d . . . . .
F4A3 F 0.78538(15) 0.87128(10) 0.43789(14) 0.0461(5) Uani 1 1 d . . . . .
F5A1 F 1.13468(16) 0.73644(9) 0.47571(16) 0.0470(6) Uani 1 1 d . . . . .
F5A2 F 1.10073(15) 0.82101(10) 0.42675(14) 0.0450(5) Uani 1 1 d . . . . .
F5A3 F 1.17863(13) 0.81023(10) 0.55296(15) 0.0441(5) Uani 1 1 d . . . . .
O1B O 0.84205(13) 0.64837(8) 0.77388(13) 0.0213(4) Uani 1 1 d . . . . .
O2B O 0.95253(14) 0.71623(8) 0.89052(13) 0.0221(4) Uani 1 1 d . . . . .
C1B C 0.82337(19) 0.62498(11) 0.84552(19) 0.0211(5) Uani 1 1 d . . . . .
C2B C 0.8556(2) 0.63992(12) 0.93131(19) 0.0243(6) Uani 1 1 d . . . . .
H2B H 0.834309 0.619378 0.979940 0.029 Uiso 1 1 calc R U . . .
C3B C 0.91905(19) 0.68490(11) 0.94727(18) 0.0205(5) Uani 1 1 d . . . . .
C4B C 0.7554(2) 0.57449(13) 0.8320(2) 0.0296(6) Uani 1 1 d . . . . .
C5B C 0.9549(2) 0.69742(13) 1.0442(2) 0.0267(6) Uani 1 1 d . . . . .
F4B1 F 0.67505(15) 0.59161(10) 0.78944(19) 0.0581(7) Uani 1 1 d . . . . .
F4B2 F 0.78903(16) 0.53435(9) 0.78183(17) 0.0502(6) Uani 1 1 d . . . . .
F4B3 F 0.7350(2) 0.55015(11) 0.90658(15) 0.0678(8) Uani 1 1 d . . . . .
F5B1 F 0.88733(14) 0.69438(11) 1.09820(13) 0.0451(5) Uani 1 1 d . . . . .
F5B2 F 1.01971(13) 0.65908(9) 1.07332(13) 0.0371(4) Uani 1 1 d . . . . .
F5B3 F 0.99568(19) 0.74849(9) 1.05326(13) 0.0493(6) Uani 1 1 d . . . . .
O3 O 0.89661(13) 0.66442(8) 0.60075(13) 0.0205(4) Uani 1 1 d . . . . .
O4 O 1.04326(13) 0.65121(8) 0.72356(13) 0.0195(4) Uani 1 1 d . . . . .
O5 O 1.09237(13) 0.75315(8) 0.79449(13) 0.0206(4) Uani 1 1 d . . . . .
O6 O 0.94788(14) 0.82468(8) 0.80237(13) 0.0229(4) Uani 1 1 d . . . . .
O7 O 0.78158(14) 0.76651(8) 0.78839(14) 0.0251(4) Uani 1 1 d . . . . .
C6 C 0.8008(2) 0.65525(13) 0.5663(2) 0.0264(6) Uani 1 1 d . . . . .
H6A H 0.767248 0.691892 0.563938 0.040 Uiso 1 1 calc R U . . .
H6B H 0.799293 0.638995 0.506373 0.040 Uiso 1 1 calc R U . . .
H6C H 0.770767 0.628639 0.605135 0.040 Uiso 1 1 calc R U . . .
C7 C 0.9473(2) 0.61111(11) 0.60480(19) 0.0235(5) Uani 1 1 d . . . . .
H7A H 0.944821 0.593434 0.545070 0.028 Uiso 1 1 calc R U . . .
H7B H 0.919163 0.584099 0.645410 0.028 Uiso 1 1 calc R U . . .
C8 C 1.0465(2) 0.62372(11) 0.63811(19) 0.0229(5) Uani 1 1 d . . . . .
H8A H 1.083334 0.587825 0.644334 0.027 Uiso 1 1 calc R U . . .
H8B H 1.075794 0.649423 0.596388 0.027 Uiso 1 1 calc R U . . .
C9 C 1.13253(19) 0.65720(12) 0.7749(2) 0.0242(6) Uani 1 1 d . . . . .
H9A H 1.178396 0.630365 0.752458 0.029 Uiso 1 1 calc R U . . .
H9B H 1.125882 0.647774 0.837964 0.029 Uiso 1 1 calc R U . . .
C10 C 1.16649(19) 0.71765(12) 0.7677(2) 0.0243(6) Uani 1 1 d . . . . .
H10A H 1.224510 0.723734 0.807086 0.029 Uiso 1 1 calc R U . . .
H10B H 1.179332 0.726406 0.705803 0.029 Uiso 1 1 calc R U . . .
C11 C 1.1128(2) 0.81376(12) 0.7980(2) 0.0256(6) Uani 1 1 d . . . . .
H11A H 1.112036 0.829814 0.737281 0.031 Uiso 1 1 calc R U . . .
H11B H 1.175151 0.820750 0.829645 0.031 Uiso 1 1 calc R U . . .
C12 C 1.0378(2) 0.84060(12) 0.8470(2) 0.0265(6) Uani 1 1 d . . . . .
H12A H 1.042549 0.826907 0.909255 0.032 Uiso 1 1 calc R U . . .
H12B H 1.044743 0.882826 0.847461 0.032 Uiso 1 1 calc R U . . .
C13 C 0.8728(2) 0.84378(13) 0.8528(2) 0.0314(7) Uani 1 1 d . . . . .
H13A H 0.875954 0.885883 0.860752 0.038 Uiso 1 1 calc R U . . .
H13B H 0.878360 0.825588 0.912193 0.038 Uiso 1 1 calc R U . . .
C14 C 0.7819(2) 0.82743(13) 0.8031(2) 0.0319(7) Uani 1 1 d . . . . .
H14A H 0.729240 0.838224 0.837853 0.038 Uiso 1 1 calc R U . . .
H14B H 0.774300 0.847862 0.745470 0.038 Uiso 1 1 calc R U . . .
C15 C 0.6919(2) 0.74792(15) 0.7471(2) 0.0312(7) Uani 1 1 d . . . . .
H15A H 0.693081 0.706364 0.737679 0.047 Uiso 1 1 calc R U . . .
H15B H 0.642854 0.757416 0.785894 0.047 Uiso 1 1 calc R U . . .
H15C H 0.678984 0.767362 0.689869 0.047 Uiso 1 1 calc R U . . .
Co1 Co 0.25501(2) 0.48254(2) 0.66455(2) 0.01792(7) Uani 1 1 d . . . . .
O1C O 0.31656(14) 0.56224(8) 0.67390(14) 0.0244(4) Uani 1 1 d . . . . .
O2C O 0.35090(14) 0.45490(8) 0.76491(14) 0.0236(4) Uani 1 1 d . . . . .
C1C C 0.38464(19) 0.57599(11) 0.72715(19) 0.0213(5) Uani 1 1 d . . . . .
C2C C 0.4346(2) 0.54272(12) 0.7914(2) 0.0240(6) Uani 1 1 d . . . . .
H2C H 0.484398 0.559873 0.827695 0.029 Uiso 1 1 calc R U . . .
C3C C 0.41412(19) 0.48518(11) 0.80422(19) 0.0222(5) Uani 1 1 d . . . . .
C4C C 0.4143(2) 0.63875(12) 0.7187(2) 0.0295(6) Uani 1 1 d . . . . .
C5C C 0.4768(2) 0.45107(13) 0.8727(2) 0.0294(6) Uani 1 1 d . . . . .
F4C1 F 0.4077(3) 0.65521(12) 0.6358(2) 0.0911(12) Uani 1 1 d . . . . .
F4C2 F 0.50165(16) 0.64933(9) 0.7470(2) 0.0631(8) Uani 1 1 d . . . . .
F4C3 F 0.3624(2) 0.67190(9) 0.7625(3) 0.0937(13) Uani 1 1 d . . . . .
F5C1 F 0.52135(16) 0.40941(9) 0.83288(14) 0.0460(5) Uani 1 1 d . . . . .
F5C2 F 0.54231(14) 0.48265(9) 0.91781(14) 0.0401(5) Uani 1 1 d . . . . .
F5C3 F 0.42706(15) 0.42613(9) 0.93228(14) 0.0436(5) Uani 1 1 d . . . . .
O1D O 0.16392(14) 0.50906(8) 0.75432(13) 0.0228(4) Uani 1 1 d . . . . .
O2D O 0.18595(13) 0.40511(8) 0.65556(13) 0.0204(4) Uani 1 1 d . . . . .
C1D C 0.1060(2) 0.47769(12) 0.78884(18) 0.0221(5) Uani 1 1 d . . . . .
C2D C 0.08016(19) 0.42137(12) 0.76709(19) 0.0218(5) Uani 1 1 d . . . . .
H2D H 0.033771 0.403289 0.798524 0.026 Uiso 1 1 calc R U . . .
C3D C 0.12009(18) 0.39084(11) 0.70088(17) 0.0179(5) Uani 1 1 d . . . . .
C4D C 0.0578(3) 0.50693(13) 0.8632(2) 0.0340(7) Uani 1 1 d . . . . .
C5D C 0.08150(19) 0.33070(11) 0.6776(2) 0.0223(5) Uani 1 1 d . . . . .
F4D1 F 0.00216(19) 0.54828(10) 0.82965(18) 0.0637(8) Uani 1 1 d . . . . .
F4D2 F 0.0060(2) 0.47240(9) 0.90666(17) 0.0676(9) Uani 1 1 d . . . . .
F4D3 F 0.1187(2) 0.53239(14) 0.92049(17) 0.0763(9) Uani 1 1 d . . . . .
F5D1 F 0.00524(13) 0.31759(8) 0.71759(13) 0.0347(4) Uani 1 1 d . . . . .
F5D2 F 0.05946(15) 0.32552(8) 0.59085(13) 0.0386(5) Uani 1 1 d . . . . .
F5D3 F 0.14536(14) 0.29124(8) 0.70273(17) 0.0459(6) Uani 1 1 d . . . . .
O1E O 0.17219(13) 0.51438(8) 0.55617(13) 0.0205(4) Uani 1 1 d . . . . .
O2E O 0.34595(13) 0.45346(8) 0.57495(13) 0.0218(4) Uani 1 1 d . . . . .
C1E C 0.19623(18) 0.51858(10) 0.47873(18) 0.0188(5) Uani 1 1 d . . . . .
C2E C 0.27659(19) 0.49818(11) 0.44345(19) 0.0213(5) Uani 1 1 d . . . . .
H2E H 0.285796 0.506174 0.383191 0.026 Uiso 1 1 calc R U . . .
C3E C 0.34382(18) 0.46625(11) 0.49478(18) 0.0195(5) Uani 1 1 d . . . . .
C4E C 0.1244(2) 0.55158(12) 0.41632(19) 0.0240(6) Uani 1 1 d . . . . .
C5E C 0.4233(2) 0.43924(12) 0.4472(2) 0.0253(6) Uani 1 1 d . . . . .
F4E1 F 0.11967(15) 0.60634(7) 0.44192(13) 0.0379(5) Uani 1 1 d . . . . .
F4E2 F 0.03927(13) 0.52948(9) 0.41870(14) 0.0391(5) Uani 1 1 d . . . . .
F4E3 F 0.14436(14) 0.55241(8) 0.33178(12) 0.0345(4) Uani 1 1 d . . . . .
F5E1 F 0.50420(11) 0.43943(7) 0.49815(12) 0.0260(3) Uani 1 1 d . . . . .
F5E2 F 0.40364(13) 0.38393(8) 0.42913(15) 0.0408(5) Uani 1 1 d . . . . .
F5E3 F 0.43832(13) 0.46520(10) 0.37145(13) 0.0391(5) Uani 1 1 d . . . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Co Co 0.3494 0.9721 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1A Eu1 O1B 111.01(7) . . ?
O1A Eu1 O2B 140.47(7) . . ?
O1B Eu1 O2B 70.77(7) . . ?
O1A Eu1 O2A 69.60(7) . . ?
O1B Eu1 O2A 140.79(6) . . ?
O2B Eu1 O2A 134.92(7) . . ?
O1A Eu1 O4 133.08(7) . . ?
O1B Eu1 O4 78.59(6) . . ?
O2B Eu1 O4 86.45(7) . . ?
O2A Eu1 O4 75.27(6) . . ?
O1A Eu1 O6 79.43(7) . . ?
O1B Eu1 O6 129.68(7) . . ?
O2B Eu1 O6 71.90(7) . . ?
O2A Eu1 O6 89.49(6) . . ?
O4 Eu1 O6 130.85(6) . . ?
O1A Eu1 O5 123.15(7) . . ?
O1B Eu1 O5 125.84(7) . . ?
O2B Eu1 O5 67.68(7) . . ?
O2A Eu1 O5 67.24(7) . . ?
O4 Eu1 O5 65.83(6) . . ?
O6 Eu1 O5 65.18(6) . . ?
O1A Eu1 O3 74.29(7) . . ?
O1B Eu1 O3 70.40(6) . . ?
O2B Eu1 O3 135.85(6) . . ?
O2A Eu1 O3 72.46(6) . . ?
O4 Eu1 O3 66.01(6) . . ?
O6 Eu1 O3 151.97(6) . . ?
O5 Eu1 O3 122.89(6) . . ?
O1A Eu1 O7 68.08(7) . . ?
O1B Eu1 O7 72.55(6) . . ?
O2B Eu1 O7 75.68(7) . . ?
O2A Eu1 O7 134.21(6) . . ?
O4 Eu1 O7 149.71(6) . . ?
O6 Eu1 O7 66.41(7) . . ?
O5 Eu1 O7 125.90(7) . . ?
O3 Eu1 O7 111.17(7) . . ?
C1A O1A Eu1 137.88(18) . . ?
C3A O2A Eu1 137.02(18) . . ?
O1A C1A C2A 128.1(3) . . ?
O1A C1A C4A 113.0(3) . . ?
C2A C1A C4A 118.9(3) . . ?
C1A C2A C3A 119.6(3) . . ?
O2A C3A C2A 127.5(3) . . ?
O2A C3A C5A 113.5(2) . . ?
C2A C3A C5A 119.0(2) . . ?
F4A1 C4A F4A3 108.3(3) . . ?
F4A1 C4A F4A2 107.1(3) . . ?
F4A3 C4A F4A2 106.8(3) . . ?
F4A1 C4A C1A 111.1(3) . . ?
F4A3 C4A C1A 113.2(3) . . ?
F4A2 C4A C1A 110.0(3) . . ?
F5A3 C5A F5A2 107.0(3) . . ?
F5A3 C5A F5A1 107.3(3) . . ?
F5A2 C5A F5A1 107.5(3) . . ?
F5A3 C5A C3A 110.7(3) . . ?
F5A2 C5A C3A 113.8(3) . . ?
F5A1 C5A C3A 110.3(2) . . ?
C1B O1B Eu1 136.30(18) . . ?
C3B O2B Eu1 136.68(18) . . ?
O1B C1B C2B 128.1(3) . . ?
O1B C1B C4B 113.5(3) . . ?
C2B C1B C4B 118.4(2) . . ?
C1B C2B C3B 120.7(3) . . ?
O2B C3B C2B 127.1(3) . . ?
O2B C3B C5B 115.1(2) . . ?
C2B C3B C5B 117.8(2) . . ?
F4B3 C4B F4B2 107.8(3) . . ?
F4B3 C4B F4B1 107.1(3) . . ?
F4B2 C4B F4B1 106.2(3) . . ?
F4B3 C4B C1B 113.9(3) . . ?
F4B2 C4B C1B 111.1(2) . . ?
F4B1 C4B C1B 110.4(3) . . ?
F5B1 C5B F5B3 108.9(3) . . ?
F5B1 C5B F5B2 106.7(2) . . ?
F5B3 C5B F5B2 106.2(3) . . ?
F5B1 C5B C3B 112.1(3) . . ?
F5B3 C5B C3B 112.1(2) . . ?
F5B2 C5B C3B 110.6(2) . . ?
C7 O3 C6 110.4(2) . . ?
C7 O3 Eu1 114.88(15) . . ?
C6 O3 Eu1 119.20(16) . . ?
C9 O4 C8 115.2(2) . . ?
C9 O4 Eu1 117.21(15) . . ?
C8 O4 Eu1 117.07(15) . . ?
C10 O5 C11 115.0(2) . . ?
C10 O5 Eu1 116.93(15) . . ?
C11 O5 Eu1 114.65(16) . . ?
C13 O6 C12 110.5(2) . . ?
C13 O6 Eu1 116.85(17) . . ?
C12 O6 Eu1 118.68(15) . . ?
C14 O7 C15 110.7(2) . . ?
C14 O7 Eu1 113.87(17) . . ?
C15 O7 Eu1 120.04(17) . . ?
O3 C7 C8 107.9(2) . . ?
O4 C8 C7 106.4(2) . . ?
O4 C9 C10 109.3(2) . . ?
O5 C10 C9 105.6(2) . . ?
O5 C11 C12 106.0(2) . . ?
O6 C12 C11 108.2(2) . . ?
O6 C13 C14 108.4(2) . . ?
O7 C14 C13 108.7(2) . . ?
O1C Co1 O2D 176.64(8) . . ?
O1C Co1 O2C 88.71(8) . . ?
O2D Co1 O2C 93.46(8) . . ?
O1C Co1 O1D 88.68(8) . . ?
O2D Co1 O1D 88.68(8) . . ?
O2C Co1 O1D 91.76(8) . . ?
O1C Co1 O1E 86.74(8) . . ?
O2D Co1 O1E 91.33(8) . . ?
O2C Co1 O1E 173.02(8) . . ?
O1D Co1 O1E 93.43(8) . . ?
O1C Co1 O2E 92.82(8) . . ?
O2D Co1 O2E 89.83(8) . . ?
O2C Co1 O2E 87.73(8) . . ?
O1D Co1 O2E 178.40(8) . . ?
O1E Co1 O2E 87.21(8) . . ?
C1C O1C Co1 125.57(18) . . ?
C3C O2C Co1 125.42(18) . . ?
O1C C1C C2C 129.1(3) . . ?
O1C C1C C4C 113.4(3) . . ?
C2C C1C C4C 117.5(3) . . ?
C1C C2C C3C 122.2(3) . . ?
O2C C3C C2C 129.0(3) . . ?
O2C C3C C5C 112.5(2) . . ?
C2C C3C C5C 118.5(3) . . ?
F4C3 C4C F4C1 108.6(3) . . ?
F4C3 C4C F4C2 107.2(3) . . ?
F4C1 C4C F4C2 104.1(3) . . ?
F4C3 C4C C1C 110.6(2) . . ?
F4C1 C4C C1C 111.4(3) . . ?
F4C2 C4C C1C 114.6(3) . . ?
F5C3 C5C F5C2 106.9(3) . . ?
F5C3 C5C F5C1 107.1(3) . . ?
F5C2 C5C F5C1 106.7(3) . . ?
F5C3 C5C C3C 111.5(3) . . ?
F5C2 C5C C3C 113.8(2) . . ?
F5C1 C5C C3C 110.5(2) . . ?
C1D O1D Co1 125.49(18) . . ?
C3D O2D Co1 125.16(17) . . ?
O1D C1D C2D 128.5(3) . . ?
O1D C1D C4D 113.9(2) . . ?
C2D C1D C4D 117.6(2) . . ?
C3D C2D C1D 122.2(2) . . ?
O2D C3D C2D 129.2(2) . . ?
O2D C3D C5D 112.9(2) . . ?
C2D C3D C5D 117.9(2) . . ?
F4D2 C4D F4D3 108.7(3) . . ?
F4D2 C4D F4D1 106.9(3) . . ?
F4D3 C4D F4D1 105.4(3) . . ?
F4D2 C4D C1D 114.0(2) . . ?
F4D3 C4D C1D 111.5(3) . . ?
F4D1 C4D C1D 109.8(3) . . ?
F5D2 C5D F5D3 108.5(2) . . ?
F5D2 C5D F5D1 107.1(2) . . ?
F5D3 C5D F5D1 106.6(2) . . ?
F5D2 C5D C3D 111.0(2) . . ?
F5D3 C5D C3D 109.9(2) . . ?
F5D1 C5D C3D 113.6(2) . . ?
C1E O1E Co1 125.43(17) . . ?
C3E O2E Co1 126.41(17) . . ?
O1E C1E C2E 129.4(3) . . ?
O1E C1E C4E 112.7(2) . . ?
C2E C1E C4E 117.8(2) . . ?
C1E C2E C3E 121.5(3) . . ?
O2E C3E C2E 128.6(2) . . ?
O2E C3E C5E 113.7(2) . . ?
C2E C3E C5E 117.6(2) . . ?
F4E2 C4E F4E3 107.9(2) . . ?
F4E2 C4E F4E1 106.9(2) . . ?
F4E3 C4E F4E1 106.5(2) . . ?
F4E2 C4E C1E 110.9(2) . . ?
F4E3 C4E C1E 113.9(2) . . ?
F4E1 C4E C1E 110.4(2) . . ?
F5E3 C5E F5E1 107.2(2) . . ?
F5E3 C5E F5E2 108.0(3) . . ?
F5E1 C5E F5E2 106.1(2) . . ?
F5E3 C5E C3E 113.6(2) . . ?
F5E1 C5E C3E 111.9(2) . . ?
F5E2 C5E C3E 109.7(2) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O1A 2.376(2) . ?
Eu1 O1B 2.3785(19) . ?
Eu1 O2B 2.392(2) . ?
Eu1 O2A 2.4226(19) . ?
Eu1 O4 2.4382(18) . ?
Eu1 O6 2.4733(19) . ?
Eu1 O5 2.4875(19) . ?
Eu1 O3 2.5122(19) . ?
Eu1 O7 2.524(2) . ?
O1A C1A 1.265(3) . ?
O2A C3A 1.248(3) . ?
C1A C2A 1.383(4) . ?
C1A C4A 1.532(4) . ?
C2A C3A 1.400(4) . ?
C3A C5A 1.532(4) . ?
C4A F4A1 1.325(4) . ?
C4A F4A3 1.332(4) . ?
C4A F4A2 1.341(4) . ?
C5A F5A3 1.329(4) . ?
C5A F5A2 1.330(4) . ?
C5A F5A1 1.332(4) . ?
O1B C1B 1.262(3) . ?
O2B C3B 1.254(3) . ?
C1B C2B 1.382(4) . ?
C1B C4B 1.531(4) . ?
C2B C3B 1.396(4) . ?
C3B C5B 1.537(4) . ?
C4B F4B3 1.318(4) . ?
C4B F4B2 1.322(4) . ?
C4B F4B1 1.331(4) . ?
C5B F5B1 1.324(3) . ?
C5B F5B3 1.329(4) . ?
C5B F5B2 1.336(4) . ?
O3 C7 1.439(3) . ?
O3 C6 1.442(3) . ?
O4 C9 1.445(3) . ?
O4 C8 1.446(3) . ?
O5 C10 1.434(3) . ?
O5 C11 1.444(3) . ?
O6 C13 1.443(3) . ?
O6 C12 1.450(4) . ?
O7 C14 1.438(3) . ?
O7 C15 1.446(4) . ?
C7 C8 1.497(4) . ?
C9 C10 1.499(4) . ?
C11 C12 1.497(4) . ?
C13 C14 1.496(5) . ?
Co1 O1C 2.0577(19) . ?
Co1 O2D 2.0587(18) . ?
Co1 O2C 2.059(2) . ?
Co1 O1D 2.060(2) . ?
Co1 O1E 2.074(2) . ?
Co1 O2E 2.0757(19) . ?
O1C C1C 1.251(3) . ?
O2C C3C 1.257(3) . ?
C1C C2C 1.391(4) . ?
C1C C4C 1.533(4) . ?
C2C C3C 1.391(4) . ?
C3C C5C 1.532(4) . ?
C4C F4C3 1.295(4) . ?
C4C F4C1 1.305(4) . ?
C4C F4C2 1.312(4) . ?
C5C F5C3 1.331(4) . ?
C5C F5C2 1.334(4) . ?
C5C F5C1 1.335(3) . ?
O1D C1D 1.255(3) . ?
O2D C3D 1.260(3) . ?
C1D C2D 1.396(4) . ?
C1D C4D 1.532(4) . ?
C2D C3D 1.392(4) . ?
C3D C5D 1.537(4) . ?
C4D F4D2 1.311(4) . ?
C4D F4D3 1.316(4) . ?
C4D F4D1 1.324(4) . ?
C5D F5D2 1.327(3) . ?
C5D F5D3 1.330(3) . ?
C5D F5D1 1.331(3) . ?
O1E C1E 1.253(3) . ?
O2E C3E 1.245(3) . ?
C1E C2E 1.396(4) . ?
C1E C4E 1.540(4) . ?
C2E C3E 1.398(4) . ?
C3E C5E 1.536(4) . ?
C4E F4E2 1.330(3) . ?
C4E F4E3 1.334(3) . ?
C4E F4E1 1.338(3) . ?
C5E F5E3 1.329(4) . ?
C5E F5E1 1.335(3) . ?
C5E F5E2 1.344(3) . ?
