#------------------------------------------------------------------------------
#$Date: 2025-03-04 07:30:27 +0200 (Tue, 04 Mar 2025) $
#$Revision: 297971 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/71/82/7718265.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7718265
loop_
_publ_author_name
'Zuffa, Caterina'
'Veclani, Daniele'
'Marchini, Marianna'
'Monti, Filippo'
'Cappuccino, Chiara'
'Maini, Lucia'
'Ventura, Barbara'
_publ_section_title
;
 Rationalization of the structural, electronic and photophysical
 properties of silver(I) halide n-picolylamine hybrid coordination
 polymers.
;
_journal_issue                   7
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              2799
_journal_page_last               2811
_journal_paper_doi               10.1039/d4dt03003f
_journal_volume                  54
_journal_year                    2025
_chemical_formula_moiety         'C6 H8 Ag Cl N2'
_chemical_formula_sum            'C6 H8 Ag Cl N2'
_chemical_formula_weight         251.46
_chemical_name_systematic        '[(AgCl)(4-pica)]n'
_chemical_properties_physical    Photo-sensitive
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_audit_update_record
;
2024-06-13 deposited with the CCDC.	2025-01-03 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 82.0479
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   6.185932
_cell_length_b                   7.247621
_cell_length_c                   17.400603
_cell_measurement_temperature    293
_cell_volume                     772.625
_computing_cell_refinement
;
 TOPAS-Academic v. 5.0
;
_computing_structure_refinement
;
 TOPAS-Academic v. 5.0
;
_computing_structure_solution
;
 TOPAS-Academic v. 5.0
;
_diffrn_ambient_temperature      293
_diffrn_measurement_device_type  Xpert-PRO
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           'Cu K\a'
_diffrn_radiation_wavelength     1.535
_exptl_crystal_colour            powder
_exptl_crystal_density_diffrn    2.162
_exptl_crystal_preparation       Luminescent
_pd_char_colour                  whitish
_pd_meas_number_of_points        4652
_pd_proc_2theta_range_inc        0.013
_pd_proc_2theta_range_max        69.96607
_pd_proc_2theta_range_min        9.50307
_pd_proc_ls_background_function  Chebyschev
_pd_proc_ls_prof_R_factor        0.0317
_pd_proc_ls_prof_wR_expected     0.0247
_pd_proc_ls_prof_wR_factor       0.0437
_pd_spec_mount_mode              transmission
_refine_ls_goodness_of_fit_all   1.77098
_refine_ls_hydrogen_treatment    constr
_refine_ls_number_parameters     0.000000
_refine_ls_R_I_factor            0.0114
_refine_ls_shift/su_max          0
_reflns_d_resolution_high        8.61664
_reflns_d_resolution_low         1.33523
_reflns_limit_h_max              4
_reflns_limit_h_min              0
_reflns_limit_k_max              5
_reflns_limit_k_min              -5
_reflns_limit_l_max              12
_reflns_limit_l_min              -12
_reflns_number_total             338
_cod_data_source_file            d4dt03003f2.cif
_cod_data_source_block           agcl_4pica_powder
_cod_original_cell_volume        772.624655
_cod_original_sg_symbol_H-M      P21/c
_cod_database_code               7718265
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z '
'-x, y+1/2, -z+1/2 '
'x, -y+1/2, z+1/2 '
'-x, -y, -z '
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_symmetry_multiplicity
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
_atom_site_B_iso_or_equiv
Ag1 Ag 4 0.60882 1.09645 0.9208198 1 4.161025
Cl1 Cl 4 0.26575 1.21986 1.024121 1 3.178013
N2 N 4 0.85721 0.32851 0.92817 1 3
C6 C 4 0.5029 0.54017 0.75731 1 3
N1 N 4 0.5811 0.50816 0.68254 1 3
C5 C 4 0.79315 0.44289 0.66167 1 3
C4 C 4 0.92716 0.40732 0.71688 1 3
C2 C 4 0.85088 0.4405 0.79357 1 3
C3 C 4 0.64224 0.50787 0.8111 1 3
C7 C 4 0.98561 0.4019 0.85763 1 3
H21 H 4 0.74278 0.42364 0.94827 1 6
H22 H 4 0.9592 0.30785 0.96831 1 6
H7A H 4 1.11118 0.30168 0.83664 1 6
H7B H 4 1.06236 0.53006 0.87222 1 6
H3 H 4 0.58299 0.53779 0.87169 1 6
H4 H 4 1.09128 0.35364 0.69998 1 6
H5 H 4 0.85384 0.41964 0.60066 1 6
H6 H 4 0.33695 0.58938 0.77457 1 6
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_2
_geom_angle_site_symmetry_3
N1 Ag1 N2 130.317 2_656 1_555 1_565
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_1
_geom_bond_site_symmetry_2
Ag1 N2 2.29355 1_555 1_565
loop_
_pd_proc_point_id
_pd_meas_2theta_scan
_pd_proc_intensity_total
_pd_calc_intensity_total
_pd_proc_ls_weight
1 9.50307 1244.87662 1232.00989 0.00081
2 9.51607 1237.30782 1204.09009 0.00083
3 9.52907 1229.93806 1218.01013 0.00082
4 9.54207 1222.76372 1239.04004 0.00081
5 9.55507 1215.78407 1183.36011 0.00085
6 9.56807 1208.99858 1156.00000 0.00087
7 9.58107 1202.42205 1169.64001 0.00085
8 9.59407 1196.05617 1162.80994 0.00086
9 9.60707 1189.90876 1122.25000 0.00089
10 9.62007 1183.98450 1108.88989 0.00090
11 9.63307 1178.28999 1142.43994 0.00088
12 9.64607 1172.73251 1142.43994 0.00088
13 9.65907 1167.28249 1095.60986 0.00091
14 9.67207 1161.93723 1122.25000 0.00089
15 9.68507 1156.73858 1142.43994 0.00088
16 9.69807 1151.71501 1115.56006 0.00090
17 9.71107 1146.86386 1128.95984 0.00089
18 9.72407 1142.18592 1089.00000 0.00092
19 9.73707 1137.68583 1108.88989 0.00090
20 9.75007 1133.38001 1115.56006 0.00090
21 9.76307 1129.26227 1128.95984 0.00089
22 9.77607 1125.33907 1122.25000 0.00089
23 9.78907 1121.61761 1115.56006 0.00090
24 9.80207 1118.16516 1108.88989 0.00090
25 9.81507 1114.98220 1115.56006 0.00090
26 9.82807 1112.08781 1135.69006 0.00088
27 9.84107 1109.49526 1156.00000 0.00087
28 9.85407 1107.24085 1169.64001 0.00085
29 9.86707 1105.20463 1169.64001 0.00085
30 9.88007 1103.35359 1115.56006 0.00090
31 9.89307 1101.69950 1075.83997 0.00093
32 9.90607 1100.35259 1135.69006 0.00088
33 9.91907 1099.60424 1162.80994 0.00086
34 9.93207 1099.60669 1135.69006 0.00088
35 9.94507 1100.57716 1156.00000 0.00087
36 9.95807 1102.92505 1176.48999 0.00085
37 9.97107 1107.75894 1149.21008 0.00087
38 9.98407 1115.22462 1156.00000 0.00087
39 9.99707 1125.92001 1135.69006 0.00088
40 10.01007 1140.47611 1211.03992 0.00083
41 10.02307 1162.70877 1211.03992 0.00083
42 10.03607 1192.43181 1253.16016 0.00080
43 10.04907 1231.15522 1281.63989 0.00078
44 10.06207 1280.54828 1361.61011 0.00073
45 10.07507 1348.51391 1466.88989 0.00068
46 10.08807 1438.10776 1459.24011 0.00069
47 10.10107 1552.16984 1576.09009 0.00063
48 10.11407 1695.75879 1789.28992 0.00056
49 10.12707 1885.74727 1953.64001 0.00051
50 10.14007 2143.62419 2125.20996 0.00047
51 10.15307 2477.46333 2440.36011 0.00041
52 10.16607 2908.15297 2819.60986 0.00035
53 10.17907 3478.43239 3445.69019 0.00029
54 10.19207 4332.38560 4212.01025 0.00024
55 10.20507 5526.99340 5358.23975 0.00019
56 10.21807 7094.54721 6756.83936 0.00015
57 10.23107 9052.10492 9139.35938 0.00011
58 10.24407 10607.57242 11193.64063 0.00009
59 10.25707 10526.19980 11384.88965 0.00009
60 10.27007 8944.76713 9409.00000 0.00011
61 10.28307 6178.40848 6130.89063 0.00016
62 10.29607 4011.72138 3552.15991 0.00028
63 10.30907 2578.51795 2106.81006 0.00047
64 10.32207 1736.88447 1505.43994 0.00066
65 10.33507 1373.56222 1332.25000 0.00075
66 10.34807 1255.62517 1232.00989 0.00081
67 10.36107 1193.52000 1225.00000 0.00082
68 10.37407 1153.31108 1149.21008 0.00087
69 10.38707 1125.76317 1095.60986 0.00091
70 10.40007 1106.44557 1183.36011 0.00085
71 10.41307 1092.70539 1122.25000 0.00089
72 10.42607 1081.70726 1062.75989 0.00094
73 10.43907 1072.88141 1089.00000 0.00092
74 10.45207 1065.73727 1069.29004 0.00094
75 10.46507 1060.24651 1030.40991 0.00097
76 10.47807 1055.58987 1056.25000 0.00095
77 10.49107 1051.64327 1075.83997 0.00093
78 10.50407 1048.29382 1089.00000 0.00092
79 10.51707 1045.55151 1082.41016 0.00092
80 10.53007 1043.20581 1062.75989 0.00094
81 10.54307 1041.16655 1056.25000 0.00095
82 10.55607 1039.39281 1082.41016 0.00092
83 10.56907 1037.87513 1075.83997 0.00093
84 10.58207 1036.54915 1062.75989 0.00094
85 10.59507 1035.36297 1043.28992 0.00096
86 10.60807 1034.31299 1069.29004 0.00094
87 10.62107 1033.41756 1089.00000 0.00092
88 10.63407 1032.68726 1062.75989 0.00094
89 10.64707 1032.04456 1062.75989 0.00094
90 10.66007 1031.49583 1069.29004 0.00094
91 10.67307 1031.05573 1082.41016 0.00092
92 10.68607 1030.77429 1095.60986 0.00091
93 10.69907 1030.55743 1089.00000 0.00092
94 10.71207 1030.42579 1056.25000 0.00095
95 10.72507 1030.39878 1075.83997 0.00093
96 10.73807 1030.53577 1095.60986 0.00091
97 10.75107 1030.74316 1082.41016 0.00092
98 10.76407 1030.99869 1062.75989 0.00094
99 10.77707 1031.29236 1062.75989 0.00094
100 10.79007 1031.62348 1082.41016 0.00092
101 10.80307 1031.98778 1075.83997 0.00093
102 10.81607 1032.37931 1056.25000 0.00095
103 10.82907 1032.79558 1043.28992 0.00096
104 10.84207 1033.23437 1036.84009 0.00096
105 10.85507 1033.69075 1030.40991 0.00097
106 10.86807 1034.15730 1043.28992 0.00096
107 10.88107 1034.62718 1075.83997 0.00093
108 10.89407 1035.09291 1069.29004 0.00094
109 10.90707 1035.52390 1056.25000 0.00095
110 10.92007 1035.94614 1043.28992 0.00096
111 10.93307 1036.39883 1036.84009 0.00096
112 10.94607 1036.91764 1075.83997 0.00093
113 10.95907 1037.56664 1075.83997 0.00093
114 10.97207 1038.25508 1043.28992 0.00096
115 10.98507 1038.96370 1056.25000 0.00095
116 10.99807 1039.68355 1069.29004 0.00094
117 11.01107 1040.41295 1056.25000 0.00095
118 11.02407 1041.15059 1036.84009 0.00096
119 11.03707 1041.89508 1030.40991 0.00097
120 11.05007 1042.64544 1049.76013 0.00095
121 11.06307 1043.40052 1043.28992 0.00096
122 11.07607 1044.15814 1043.28992 0.00096
123 11.08907 1044.91667 1036.84009 0.00096
124 11.10207 1045.67416 1056.25000 0.00095
125 11.11507 1046.42850 1069.29004 0.00094
126 11.12807 1047.16912 1030.40991 0.00097
127 11.14107 1047.89082 1043.28992 0.00096
128 11.15407 1048.58798 1056.25000 0.00095
129 11.16707 1049.25757 1011.23993 0.00099
130 11.18007 1049.90711 1024.00000 0.00098
131 11.19307 1050.56905 1062.75989 0.00094
132 11.20607 1051.24553 1089.00000 0.00092
133 11.21907 1051.95185 1069.29004 0.00094
134 11.23207 1052.75552 1082.41016 0.00092
135 11.24507 1053.57852 1043.28992 0.00096
136 11.25807 1054.40763 1062.75989 0.00094
137 11.27107 1055.23865 1049.76013 0.00095
138 11.28407 1056.06913 1056.25000 0.00095
139 11.29707 1056.89705 1062.75989 0.00094
140 11.31007 1057.72214 1030.40991 0.00097
141 11.32307 1058.54406 1043.28992 0.00096
142 11.33607 1059.36251 1049.76013 0.00095
143 11.34907 1060.17719 1011.23993 0.00099
144 11.36207 1060.98780 1030.40991 0.00097
145 11.37507 1061.79408 1036.84009 0.00096
146 11.38807 1062.59575 1062.75989 0.00094
147 11.40107 1063.39254 1095.60986 0.00091
148 11.41407 1064.18419 1049.76013 0.00095
149 11.42707 1064.97046 1089.00000 0.00092
150 11.44007 1065.75111 1062.75989 0.00094
151 11.45307 1066.52590 1017.60999 0.00098
152 11.46607 1067.29461 1036.84009 0.00096
153 11.47907 1068.05701 1056.25000 0.00095
154 11.49207 1068.81290 1062.75989 0.00094
155 11.50507 1069.56208 1036.84009 0.00096
156 11.51807 1070.30433 1036.84009 0.00096
157 11.53107 1071.03948 1017.60999 0.00098
158 11.54407 1071.76734 1049.76013 0.00095
159 11.55707 1072.48773 1036.84009 0.00096
160 11.57007 1073.20049 1082.41016 0.00092
161 11.58307 1073.90544 1089.00000 0.00092
162 11.59607 1074.60243 1036.84009 0.00096
163 11.60907 1075.29132 1069.29004 0.00094
164 11.62207 1075.97195 1024.00000 0.00098
165 11.63507 1076.64419 1043.28992 0.00096
166 11.64807 1077.30790 1043.28992 0.00096
167 11.66107 1077.96296 1095.60986 0.00091
168 11.67407 1078.60925 1082.41016 0.00092
169 11.68707 1079.24666 1128.95984 0.00089
170 11.70007 1079.87507 1049.76013 0.00095
171 11.71307 1080.49438 1082.41016 0.00092
172 11.72607 1081.10450 1075.83997 0.00093
173 11.73907 1081.70534 1089.00000 0.00092
174 11.75207 1082.29684 1024.00000 0.00098
175 11.76507 1082.87897 1036.84009 0.00096
176 11.77807 1083.45175 1108.88989 0.00090
177 11.79107 1084.01521 1043.28992 0.00096
178 11.80407 1084.56957 1056.25000 0.00095
179 11.81707 1085.11534 1082.41016 0.00092
180 11.83007 1085.65279 1095.60986 0.00091
181 11.84307 1086.18242 1082.41016 0.00092
182 11.85607 1086.70514 1095.60986 0.00091
183 11.86907 1087.22394 1069.29004 0.00094
184 11.88207 1087.73963 1011.23993 0.00099
185 11.89507 1088.25441 1049.76013 0.00095
186 11.90807 1088.77069 1069.29004 0.00094
187 11.92107 1089.30339 1102.23999 0.00091
188 11.93407 1089.85777 1149.21008 0.00087
189 11.94707 1090.44662 1142.43994 0.00088
190 11.96007 1091.08580 1162.80994 0.00086
191 11.97307 1091.84629 1122.25000 0.00089
192 11.98607 1092.78015 1128.95984 0.00089
193 11.99907 1093.84023 1135.69006 0.00088
194 12.01207 1094.95247 1102.23999 0.00091
195 12.02507 1095.89414 1069.29004 0.00094
196 12.03807 1096.49823 1062.75989 0.00094
197 12.05107 1096.99060 1075.83997 0.00093
198 12.06407 1097.43366 1082.41016 0.00092
199 12.07707 1097.86598 1075.83997 0.00093
200 12.09007 1098.29214 1036.84009 0.00096
201 12.10307 1098.71134 1036.84009 0.00096
202 12.11607 1099.12372 1024.00000 0.00098
203 12.12907 1099.52942 1036.84009 0.00096
204 12.14207 1099.93015 1043.28992 0.00096
205 12.15507 1100.32479 1056.25000 0.00095
206 12.16807 1100.71351 1062.75989 0.00094
207 12.18107 1101.09653 1056.25000 0.00095
208 12.19407 1101.47559 1062.75989 0.00094
209 12.20707 1101.85057 1089.00000 0.00092
210 12.22007 1102.22137 1102.23999 0.00091
211 12.23307 1102.58853 1089.00000 0.00092
212 12.24607 1102.95422 1108.88989 0.00090
213 12.25907 1103.32052 1108.88989 0.00090
214 12.27207 1103.68719 1089.00000 0.00092
215 12.28507 1104.05577 1075.83997 0.00093
216 12.29807 1104.42947 1043.28992 0.00096
217 12.31107 1104.81796 1062.75989 0.00094
218 12.32407 1105.22183 1069.29004 0.00094
219 12.33707 1105.64768 1062.75989 0.00094
220 12.35007 1106.10279 1069.29004 0.00094
221 12.36307 1106.63541 1069.29004 0.00094
222 12.37607 1107.26589 1089.00000 0.00092
223 12.38907 1108.02705 1069.29004 0.00094
224 12.40207 1108.94043 1075.83997 0.00093
225 12.41507 1110.01951 1075.83997 0.00093
226 12.42807 1110.97114 1108.88989 0.00090
227 12.44107 1111.72557 1108.88989 0.00090
228 12.45407 1112.29040 1095.60986 0.00091
229 12.46707 1112.80124 1122.25000 0.00089
230 12.48007 1113.32740 1108.88989 0.00090
231 12.49307 1113.86899 1069.29004 0.00094
232 12.50607 1114.42840 1102.23999 0.00091
233 12.51907 1115.01036 1089.00000 0.00092
234 12.53207 1115.62781 1095.60986 0.00091
235 12.54507 1116.27455 1069.29004 0.00094
236 12.55807 1116.95453 1082.41016 0.00092
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239 12.59707 1119.31006 1075.83997 0.00093
240 12.61007 1120.23463 1082.41016 0.00092
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248 12.71407 1135.29274 1183.36011 0.00085
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250 12.74007 1141.24107 1128.95984 0.00089
251 12.75307 1143.78555 1135.69006 0.00088
252 12.76607 1146.38815 1169.64001 0.00085
253 12.77907 1149.14505 1135.69006 0.00088
254 12.79207 1152.12942 1142.43994 0.00088
255 12.80507 1155.50807 1169.64001 0.00085
256 12.81807 1159.22382 1267.35986 0.00079
257 12.83107 1163.31031 1162.80994 0.00086
258 12.84407 1167.80940 1183.36011 0.00085
259 12.85707 1172.95551 1197.15991 0.00084
260 12.87007 1178.79689 1267.35986 0.00079
261 12.88307 1185.36551 1211.03992 0.00083
262 12.89607 1192.76884 1225.00000 0.00082
263 12.90907 1201.38288 1246.08997 0.00080
264 12.92207 1211.66043 1239.04004 0.00081
265 12.93507 1223.67345 1267.35986 0.00079
266 12.94807 1237.81554 1303.20984 0.00077
267 12.96107 1254.85624 1281.63989 0.00078
268 12.97407 1277.48943 1398.76013 0.00071
269 12.98707 1306.59763 1346.89001 0.00074
270 13.00007 1344.33704 1369.00000 0.00073
271 13.01307 1393.08015 1428.83997 0.00070
272 13.02607 1466.44679 1536.64001 0.00065
273 13.03907 1567.05215 1616.04004 0.00062
274 13.05207 1702.01436 1764.00000 0.00057
275 13.06507 1879.48364 1866.24011 0.00054
276 13.07807 2134.46970 2143.68994 0.00047
277 13.09107 2488.12071 2410.80981 0.00041
278 13.10407 2958.48588 2809.00000 0.00036
279 13.11707 3575.85615 3457.43994 0.00029
280 13.13007 4432.82404 4329.64063 0.00023
281 13.14307 5683.50790 5490.80957 0.00018
282 13.15607 7413.54901 7089.63965 0.00014
283 13.16907 9789.59451 9409.00000 0.00011
284 13.18207 13119.24671 12904.95996 0.00008
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1804 32.94207 1073.73180 1017.60999 0.00098
1805 32.95507 1056.99534 1017.60999 0.00098
1806 32.96807 1046.11245 1004.89008 0.00100
1807 32.98107 1038.91434 979.68994 0.00102
1808 32.99407 1034.34120 961.00000 0.00104
1809 33.00707 1031.65552 992.25000 0.00101
1810 33.02007 1029.91612 985.95996 0.00101
1811 33.03307 1028.81076 967.21002 0.00103
1812 33.04607 1028.25647 961.00000 0.00104
1813 33.05907 1028.17644 973.44006 0.00103
1814 33.07207 1028.48300 973.44006 0.00103
1815 33.08507 1029.10965 985.95996 0.00101
1816 33.09807 1030.09414 1004.89008 0.00100
1817 33.11107 1031.40855 1043.28992 0.00096
1818 33.12407 1033.05495 1030.40991 0.00097
1819 33.13707 1034.99545 979.68994 0.00102
1820 33.15007 1037.32791 967.21002 0.00103
1821 33.16307 1040.03693 985.95996 0.00101
1822 33.17607 1043.16387 998.56000 0.00100
1823 33.18907 1046.73058 1036.84009 0.00096
1824 33.20207 1050.89431 1030.40991 0.00097
1825 33.21507 1055.75490 1030.40991 0.00097
1826 33.22807 1061.38084 1075.83997 0.00093
1827 33.24107 1067.87582 1095.60986 0.00091
1828 33.25407 1075.53339 1108.88989 0.00090
1829 33.26707 1085.03924 1095.60986 0.00091
1830 33.28007 1096.63981 1108.88989 0.00090
1831 33.29307 1110.92975 1108.88989 0.00090
1832 33.30607 1128.76595 1135.69006 0.00088
1833 33.31907 1153.69411 1162.80994 0.00086
1834 33.33207 1187.34883 1232.00989 0.00081
1835 33.34507 1232.30000 1281.63989 0.00078
1836 33.35807 1291.49241 1354.23999 0.00074
1837 33.37107 1376.22250 1459.24011 0.00069
1838 33.38407 1487.96001 1584.03992 0.00063
1839 33.39707 1624.02707 1789.28992 0.00056
1840 33.41007 1781.92415 1900.95984 0.00053
1841 33.42307 1970.04740 2043.04004 0.00049
1842 33.43607 2166.80307 2313.60986 0.00043
1843 33.44907 2387.00483 2540.16016 0.00039
1844 33.46207 2646.71857 2787.83984 0.00036
1845 33.47507 2983.95963 3192.25000 0.00031
1846 33.48807 3382.29683 3540.25000 0.00028
1847 33.50107 3782.90529 4006.88989 0.00025
1848 33.51407 4126.46393 4316.48975 0.00023
1849 33.52707 4291.20274 4408.95996 0.00023
1850 33.54007 4221.05767 4329.64063 0.00023
1851 33.55307 4058.34473 4032.25000 0.00025
1852 33.56607 3880.38538 3943.83984 0.00025
1853 33.57907 3770.00400 3745.44019 0.00027
1854 33.59207 3767.90003 3672.35986 0.00027
1855 33.60507 3770.20057 3660.25000 0.00027
1856 33.61807 3674.53691 3588.01025 0.00028
1857 33.63107 3458.96562 3294.76025 0.00030
1858 33.64407 3133.62537 2905.21021 0.00034
1859 33.65707 2776.70918 2621.44019 0.00038
1860 33.67007 2475.13609 2410.80981 0.00041
1861 33.68307 2249.19483 2265.75977 0.00044
1862 33.69607 2104.63918 2052.08984 0.00049
1863 33.70907 2009.34208 1962.48999 0.00051
1864 33.72207 1924.40604 1900.95984 0.00053
1865 33.73507 1858.57649 1883.56018 0.00053
1866 33.74807 1823.88771 1874.88989 0.00053
1867 33.76107 1854.65590 1857.60986 0.00054
1868 33.77407 1971.34832 1998.09009 0.00050
1869 33.78707 2181.14521 2134.44019 0.00047
1870 33.80007 2490.76405 2460.15991 0.00041
1871 33.81307 2946.90619 2948.48999 0.00034
1872 33.82607 3461.59899 3340.83984 0.00030
1873 33.83907 3969.30913 3806.89014 0.00026
1874 33.85207 4406.58998 4369.20996 0.00023
1875 33.86507 4548.02690 4569.75977 0.00022
1876 33.87807 4426.82067 4569.75977 0.00022
1877 33.89107 4130.01579 4121.63965 0.00024
1878 33.90407 3729.58182 3782.25000 0.00026
1879 33.91707 3397.97542 3422.25000 0.00029
1880 33.93007 3163.27239 3169.68994 0.00032
1881 33.94307 2972.40352 3047.04004 0.00033
1882 33.95607 2788.81368 2798.41016 0.00036
1883 33.96907 2542.28129 2470.09009 0.00040
1884 33.98207 2253.05499 2209.00000 0.00045
1885 33.99507 1961.95616 1883.56018 0.00053
1886 34.00807 1693.22396 1632.16016 0.00061
1887 34.02107 1489.71089 1474.56006 0.00068
1888 34.03407 1348.44829 1310.44006 0.00076
1889 34.04707 1248.51424 1253.16016 0.00080
1890 34.06007 1181.71572 1162.80994 0.00086
1891 34.07307 1140.91171 1142.43994 0.00088
1892 34.08607 1113.34160 1095.60986 0.00091
1893 34.09907 1092.48543 1062.75989 0.00094
1894 34.11207 1076.42385 1043.28992 0.00096
1895 34.12507 1064.05646 992.25000 0.00101
1896 34.13807 1054.42703 1004.89008 0.00100
1897 34.15107 1046.60382 1024.00000 0.00098
1898 34.16407 1040.46363 1062.75989 0.00094
1899 34.17707 1036.02126 1004.89008 0.00100
1900 34.19007 1033.60339 985.95996 0.00101
1901 34.20307 1032.69184 1049.76013 0.00095
1902 34.21607 1032.88626 1075.83997 0.00093
1903 34.22907 1033.76879 1030.40991 0.00097
1904 34.24207 1034.48016 1024.00000 0.00098
1905 34.25507 1033.28054 1024.00000 0.00098
1906 34.26807 1030.29467 1017.60999 0.00098
1907 34.28107 1025.90475 985.95996 0.00101
1908 34.29407 1020.80790 985.95996 0.00101
1909 34.30707 1016.60125 998.56000 0.00100
1910 34.32007 1013.48659 1004.89008 0.00100
1911 34.33307 1011.10107 1017.60999 0.00098
1912 34.34607 1009.12700 1017.60999 0.00098
1913 34.35907 1006.91727 1024.00000 0.00098
1914 34.37207 1004.49867 1011.23993 0.00099
1915 34.38507 1002.25352 992.25000 0.00101
1916 34.39807 1000.45815 979.68994 0.00102
1917 34.41107 999.40399 992.25000 0.00101
1918 34.42407 999.42472 1011.23993 0.00099
1919 34.43707 1000.26310 1011.23993 0.00099
1920 34.45007 1001.94127 1017.60999 0.00098
1921 34.46307 1004.48654 998.56000 0.00100
1922 34.47607 1008.31255 961.00000 0.00104
1923 34.48907 1013.59125 961.00000 0.00104
1924 34.50207 1020.65326 985.95996 0.00101
1925 34.51507 1030.00058 1004.89008 0.00100
1926 34.52807 1043.30117 1004.89008 0.00100
1927 34.54107 1062.93516 992.25000 0.00101
1928 34.55407 1090.37421 1011.23993 0.00099
1929 34.56707 1127.93603 1043.28992 0.00096
1930 34.58007 1180.47919 1089.00000 0.00092
1931 34.59307 1256.93886 1169.64001 0.00085
1932 34.60607 1352.50530 1281.63989 0.00078
1933 34.61907 1463.19734 1354.23999 0.00074
1934 34.63207 1584.11101 1497.69006 0.00067
1935 34.64507 1683.99567 1592.01013 0.00063
1936 34.65807 1740.53542 1672.81018 0.00060
1937 34.67107 1749.15725 1747.23999 0.00057
1938 34.68407 1710.67486 1747.23999 0.00057
1939 34.69707 1641.81478 1616.04004 0.00062
1940 34.71007 1590.09541 1544.48999 0.00065
1941 34.72307 1562.27769 1544.48999 0.00065
1942 34.73607 1565.94602 1505.43994 0.00066
1943 34.74907 1596.80565 1624.08997 0.00062
1944 34.76207 1640.81070 1608.00989 0.00062
1945 34.77507 1705.16315 1552.36011 0.00064
1946 34.78807 1810.73601 1764.00000 0.00057
1947 34.80107 1966.27832 1909.69006 0.00052
1948 34.81407 2159.19837 2088.48999 0.00048
1949 34.82707 2367.14017 2294.41016 0.00044
1950 34.84007 2546.69392 2530.08984 0.00040
1951 34.85307 2608.80056 2652.25000 0.00038
1952 34.86607 2566.02066 2641.96021 0.00038
1953 34.87907 2433.57093 2450.25000 0.00041
1954 34.89207 2243.41666 2227.84009 0.00045
1955 34.90507 2086.22496 2061.16016 0.00049
1956 34.91807 1971.79383 1892.25000 0.00053
1957 34.93107 1886.53133 1849.00000 0.00054
1958 34.94407 1813.24725 1831.83997 0.00055
1959 34.95707 1710.07088 1664.63989 0.00060
1960 34.97007 1585.17324 1584.03992 0.00063
1961 34.98307 1451.29366 1383.84009 0.00072
1962 34.99607 1320.49099 1281.63989 0.00078
1963 35.00907 1217.84781 1204.09009 0.00083
1964 35.02207 1142.06504 1095.60986 0.00091
1965 35.03507 1087.31501 1049.76013 0.00095
1966 35.04807 1050.19154 1062.75989 0.00094
1967 35.06107 1027.76800 1004.89008 0.00100
1968 35.07407 1012.46153 1056.25000 0.00095
1969 35.08707 1001.08832 1011.23993 0.00099
1970 35.10007 992.42011 948.63995 0.00105
1971 35.11307 985.74010 1024.00000 0.00098
1972 35.12607 980.34724 1036.84009 0.00096
1973 35.13907 975.74869 973.44006 0.00103
1974 35.15207 971.82165 1024.00000 0.00098
1975 35.16507 968.49960 1011.23993 0.00099
1976 35.17807 965.72827 930.25000 0.00107
1977 35.19107 963.30489 1030.40991 0.00097
1978 35.20407 961.18518 967.21002 0.00103
1979 35.21707 959.33724 924.15997 0.00108
1980 35.23007 957.78918 985.95996 0.00101
1981 35.24307 956.44583 1011.23993 0.00099
1982 35.25607 955.28228 961.00000 0.00104
1983 35.26907 954.27827 942.49005 0.00106
1984 35.28207 953.45751 936.36005 0.00107
1985 35.29507 952.78459 906.01001 0.00110
1986 35.30807 952.26312 954.81000 0.00105
1987 35.32107 951.88294 936.36005 0.00107
1988 35.33407 951.65418 942.49005 0.00106
1989 35.34707 951.56976 1004.89008 0.00100
1990 35.36007 951.61867 954.81000 0.00105
1991 35.37307 951.79321 918.08997 0.00109
1992 35.38607 952.10527 918.08997 0.00109
1993 35.39907 952.57575 973.44006 0.00103
1994 35.41207 953.22124 973.44006 0.00103
1995 35.42507 954.03096 942.49005 0.00106
1996 35.43807 955.02193 961.00000 0.00104
1997 35.45107 956.23073 973.44006 0.00103
1998 35.46407 957.75728 992.25000 0.00101
1999 35.47707 959.60003 961.00000 0.00104
2000 35.49007 961.83381 967.21002 0.00103
2001 35.50307 964.55593 1030.40991 0.00097
2002 35.51607 968.16538 998.56000 0.00100
2003 35.52907 972.79444 992.25000 0.00101
2004 35.54207 978.69331 998.56000 0.00100
2005 35.55507 986.22028 1036.84009 0.00096
2006 35.56807 996.62637 1043.28992 0.00096
2007 35.58107 1011.36757 1062.75989 0.00094
2008 35.59407 1031.53296 1056.25000 0.00095
2009 35.60707 1058.86961 1069.29004 0.00094
2010 35.62007 1097.57208 1102.23999 0.00091
2011 35.63307 1155.67401 1162.80994 0.00086
2012 35.64607 1233.19710 1253.16016 0.00080
2013 35.65907 1331.21430 1376.40991 0.00073
2014 35.67207 1451.03335 1528.80994 0.00065
2015 35.68507 1583.94812 1640.25000 0.00061
2016 35.69807 1700.00520 1780.84009 0.00056
2017 35.71107 1781.48932 1892.25000 0.00053
2018 35.72407 1812.38865 1900.95984 0.00053
2019 35.73707 1762.19537 1814.75989 0.00055
2020 35.75007 1682.53508 1713.96008 0.00058
2021 35.76307 1600.89349 1656.49011 0.00060
2022 35.77607 1536.45133 1576.09009 0.00063
2023 35.78907 1505.64226 1568.15991 0.00064
2024 35.80207 1489.47498 1584.03992 0.00063
2025 35.81507 1474.61487 1536.64001 0.00065
2026 35.82807 1462.22423 1474.56006 0.00068
2027 35.84107 1451.38005 1406.25000 0.00071
2028 35.85407 1456.16156 1436.41016 0.00070
2029 35.86707 1488.55270 1513.21008 0.00066
2030 35.88007 1557.85483 1568.15991 0.00064
2031 35.89307 1651.29628 1689.20984 0.00059
2032 35.90607 1748.70057 1831.83997 0.00055
2033 35.91907 1826.07817 1900.95984 0.00053
2034 35.93207 1847.90416 1900.95984 0.00053
2035 35.94507 1797.91524 1874.88989 0.00053
2036 35.95807 1715.89230 1857.60986 0.00054
2037 35.97107 1620.47247 1705.68994 0.00059
2038 35.98407 1539.28507 1600.00000 0.00063
2039 35.99707 1490.76037 1584.03992 0.00063
2040 36.01007 1452.91508 1521.00000 0.00066
2041 36.02307 1416.12669 1421.29004 0.00070
2042 36.03607 1369.79566 1361.61011 0.00073
2043 36.04907 1305.58987 1324.96008 0.00075
2044 36.06207 1239.74872 1296.00000 0.00077
2045 36.07507 1178.42251 1211.03992 0.00083
2046 36.08807 1127.84002 1162.80994 0.00086
2047 36.10107 1096.86926 1142.43994 0.00088
2048 36.11407 1079.09596 1128.95984 0.00089
2049 36.12707 1072.32195 1056.25000 0.00095
2050 36.14007 1076.04750 1089.00000 0.00092
2051 36.15307 1091.76771 1122.25000 0.00089
2052 36.16607 1118.26175 1082.41016 0.00092
2053 36.17907 1157.73296 1135.69006 0.00088
2054 36.19207 1213.21074 1218.01013 0.00082
2055 36.20507 1303.54521 1239.04004 0.00081
2056 36.21807 1431.00110 1339.55994 0.00075
2057 36.23107 1602.12232 1497.69006 0.00067
2058 36.24407 1821.68656 1697.44006 0.00059
2059 36.25707 2101.62480 2043.04004 0.00049
2060 36.27007 2404.58163 2313.60986 0.00043
2061 36.28307 2677.47711 2580.63989 0.00039
2062 36.29607 2878.44111 2840.88989 0.00035
2063 36.30907 2946.95744 2970.25000 0.00034
2064 36.32207 2825.78542 2916.00000 0.00034
2065 36.33507 2629.90634 2704.00000 0.00037
2066 36.34807 2413.97561 2440.36011 0.00041
2067 36.36107 2228.97986 2313.60986 0.00043
2068 36.37407 2122.63903 2190.23999 0.00046
2069 36.38707 2042.69935 2052.08984 0.00049
2070 36.40007 1956.76821 1998.09009 0.00050
2071 36.41307 1846.50202 1840.41016 0.00054
2072 36.42607 1696.61923 1664.63989 0.00060
2073 36.43907 1532.82554 1521.00000 0.00066
2074 36.45207 1381.74426 1369.00000 0.00073
2075 36.46507 1253.19181 1204.09009 0.00083
2076 36.47807 1154.29656 1043.28992 0.00096
2077 36.49107 1093.09524 1043.28992 0.00096
2078 36.50407 1049.96993 1056.25000 0.00095
2079 36.51707 1020.40268 985.95996 0.00101
2080 36.53007 1000.35895 1017.60999 0.00098
2081 36.54307 987.09872 998.56000 0.00100
2082 36.55607 977.18300 1011.23993 0.00099
2083 36.56907 969.26253 948.63995 0.00105
2084 36.58207 962.85538 942.49005 0.00106
2085 36.59507 957.70159 948.63995 0.00105
2086 36.60807 953.65947 973.44006 0.00103
2087 36.62107 950.33027 961.00000 0.00104
2088 36.63407 947.66338 961.00000 0.00104
2089 36.64707 945.66446 961.00000 0.00104
2090 36.66007 944.34363 906.01001 0.00110
2091 36.67307 943.44872 985.95996 0.00101
2092 36.68607 942.84123 967.21002 0.00103
2093 36.69907 942.35385 906.01001 0.00110
2094 36.71207 941.63835 900.00000 0.00111
2095 36.72507 940.74079 882.09003 0.00113
2096 36.73807 939.69132 936.36005 0.00107
2097 36.75107 938.62363 936.36005 0.00107
2098 36.76407 937.88063 888.03998 0.00113
2099 36.77707 937.52963 954.81000 0.00105
2100 36.79007 937.47022 924.15997 0.00108
2101 36.80307 937.63885 936.36005 0.00107
2102 36.81607 937.91302 924.15997 0.00108
2103 36.82907 938.26460 912.04004 0.00110
2104 36.84207 938.75772 900.00000 0.00111
2105 36.85507 939.42864 918.08997 0.00109
2106 36.86807 940.42175 936.36005 0.00107
2107 36.88107 941.76267 954.81000 0.00105
2108 36.89407 943.44975 973.44006 0.00103
2109 36.90707 945.46790 998.56000 0.00100
2110 36.92007 947.88358 942.49005 0.00106
2111 36.93307 950.77748 948.63995 0.00105
2112 36.94607 954.13538 936.36005 0.00107
2113 36.95907 958.00622 918.08997 0.00109
2114 36.97207 962.47233 948.63995 0.00105
2115 36.98507 967.98093 948.63995 0.00105
2116 36.99807 974.56798 936.36005 0.00107
2117 37.01107 982.50356 985.95996 0.00101
2118 37.02407 992.08014 1004.89008 0.00100
2119 37.03707 1004.51959 1024.00000 0.00098
2120 37.05007 1020.84665 1089.00000 0.00092
2121 37.06307 1042.01332 1075.83997 0.00093
2122 37.07607 1069.49009 1049.76013 0.00095
2123 37.08907 1106.57117 1049.76013 0.00095
2124 37.10207 1161.62702 1089.00000 0.00092
2125 37.11507 1237.76884 1190.25000 0.00084
2126 37.12807 1340.84879 1260.25000 0.00079
2127 37.14107 1477.06405 1376.40991 0.00073
2128 37.15407 1672.34007 1592.01013 0.00063
2129 37.16707 1910.99843 1797.76013 0.00056
2130 37.18007 2175.62472 2025.00000 0.00049
2131 37.19307 2445.02410 2304.00000 0.00043
2132 37.20607 2662.54408 2520.04004 0.00040
2133 37.21907 2751.66603 2693.61011 0.00037
2134 37.23207 2720.99985 2766.75977 0.00036
2135 37.24507 2589.15652 2580.63989 0.00039
2136 37.25807 2393.69484 2430.48999 0.00041
2137 37.27107 2233.43132 2284.83984 0.00044
2138 37.28407 2128.53492 2143.68994 0.00047
2139 37.29707 2067.03186 2070.25000 0.00048
2140 37.31007 2032.72834 2052.08984 0.00049
2141 37.32307 1983.98315 1962.48999 0.00051
2142 37.33607 1916.51451 1874.88989 0.00053
2143 37.34907 1848.65754 1789.28992 0.00056
2144 37.36207 1798.08860 1738.89001 0.00058
2145 37.37507 1793.61132 1722.25000 0.00058
2146 37.38807 1874.19020 1849.00000 0.00054
2147 37.40107 2047.14067 2034.00989 0.00049
2148 37.41407 2297.68548 2342.56006 0.00043
2149 37.42707 2610.99010 2704.00000 0.00037
2150 37.44007 2962.60056 3014.01025 0.00033
2151 37.45307 3246.33804 3271.84009 0.00031
2152 37.46607 3401.96219 3364.00000 0.00030
2153 37.47907 3410.54257 3504.64014 0.00029
2154 37.49207 3259.93375 3306.25000 0.00030
2155 37.50507 2998.91245 3036.00977 0.00033
2156 37.51807 2775.39001 2724.84009 0.00037
2157 37.53107 2609.18383 2631.68994 0.00038
2158 37.54407 2505.48979 2560.35986 0.00039
2159 37.55707 2437.77563 2500.00000 0.00040
2160 37.57007 2335.67775 2284.83984 0.00044
2161 37.58307 2183.84953 2180.89014 0.00046
2162 37.59607 1989.69497 1998.09009 0.00050
2163 37.60907 1773.73237 1772.40991 0.00056
2164 37.62207 1580.81737 1521.00000 0.00066
2165 37.63507 1423.87076 1346.89001 0.00074
2166 37.64807 1303.00549 1376.40991 0.00073
2167 37.66107 1215.45409 1232.00989 0.00081
2168 37.67407 1157.71027 1190.25000 0.00084
2169 37.68707 1111.22880 1102.23999 0.00091
2170 37.70007 1073.39781 1069.29004 0.00094
2171 37.71307 1043.71484 1075.83997 0.00093
2172 37.72607 1021.10940 1017.60999 0.00098
2173 37.73907 1003.22566 1075.83997 0.00093
2174 37.75207 990.16271 1011.23993 0.00099
2175 37.76507 980.23641 1036.84009 0.00096
2176 37.77807 972.81618 1024.00000 0.00098
2177 37.79107 967.23314 1017.60999 0.00098
2178 37.80407 963.02347 998.56000 0.00100
2179 37.81707 959.80140 979.68994 0.00102
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