#------------------------------------------------------------------------------
#$Date: 2016-02-18 14:25:00 +0200 (Thu, 18 Feb 2016) $
#$Revision: 176728 $
#$URL: svn://www.crystallography.net/cod/cif/8/00/01/8000131.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_8000131
loop_
_publ_author_name
'Usui, Yoko'
'Fukushima, Takashi'
'Nanjo, Masato'
'Mochida, Kunio'
'Akasaka, Kuniyoshi'
'Kudo, Takako'
'Komiya, Sanshiro'
_publ_section_title
;
 Synthesis and Kaleidoscopic Reactivities of
 Bis(tritolylgermyl)bis(dimethylphenylphosphine)platinum(II)
;
_journal_issue                   7
_journal_name_full               'Chemistry Letters'
_journal_page_first              810
_journal_paper_doi               10.1246/cl.2006.810
_journal_volume                  35
_journal_year                    2006
_chemical_formula_sum            'C58 H64 Ge2 P2 Pt'
_chemical_formula_weight         1163.30
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                104.025(5)
_cell_angle_beta                 102.670(5)
_cell_angle_gamma                112.854(4)
_cell_formula_units_Z            2
_cell_length_a                   12.5600(8)
_cell_length_b                   13.8290(10)
_cell_length_c                   17.4500(17)
_cell_measurement_reflns_used    10724
_cell_measurement_temperature    120
_cell_measurement_theta_max      27.5
_cell_measurement_theta_min      2.24
_cell_volume                     2537.7(4)
_computing_cell_refinement       SCALEPACK
_computing_data_collection       XPRESS
_computing_data_reduction        DENZO
_computing_molecular_graphics    ORTEP
_computing_publication_material  CIFTAB
_computing_structure_refinement  SHELXL-97
_computing_structure_solution    SIR-97
_diffrn_ambient_temperature      120
_diffrn_measured_fraction_theta_full 0.921
_diffrn_measured_fraction_theta_max 0.921
_diffrn_measurement_device_type  'MacScience DIP2030 imaging plate'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus rotating anode'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0000
_diffrn_reflns_av_sigmaI/netI    0.0690
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_number            10724
_diffrn_reflns_theta_full        27.50
_diffrn_reflns_theta_max         27.50
_diffrn_reflns_theta_min         2.24
_exptl_absorpt_coefficient_mu    4.026
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.522
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             1168
_exptl_crystal_size_max          0.10
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.07
_refine_diff_density_max         1.757
_refine_diff_density_min         -2.870
_refine_diff_density_rms         0.180
_refine_ls_extinction_coef       0.0025(3)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   0.990
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     572
_refine_ls_number_reflns         10724
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.990
_refine_ls_R_factor_all          0.0812
_refine_ls_R_factor_gt           0.0545
_refine_ls_shift/su_max          0.008
_refine_ls_shift/su_mean         0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1000P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1349
_refine_ls_wR_factor_ref         0.1526
_reflns_number_gt                7955
_reflns_number_total             10724
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            35-810sup2.cif
_cod_data_source_block           3-trans
_cod_depositor_comments
;
The following automatic conversions were performed:

'_exptl_crystal_density_meas' value 'not measured' was changed to '?'
- the value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 3008 2015-01-20 13:52:24Z robertas 
;
_cod_original_cell_volume        2537.7(3)
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               8000131
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Pt1 Pt 0.5000 0.0000 0.5000 0.02322(11) Uani 1 2 d S
Pt2 Pt 0.0000 0.0000 0.0000 0.02407(11) Uani 1 2 d S
Ge1 Ge 0.40051(7) -0.21038(6) 0.44334(5) 0.02532(17) Uani 1 1 d .
Ge2 Ge 0.15963(7) 0.19806(6) 0.09085(5) 0.02579(17) Uani 1 1 d .
P1 P 0.47789(16) 0.00490(14) 0.36673(11) 0.0254(4) Uani 1 1 d .
P2 P 0.15649(16) -0.03796(15) -0.02011(12) 0.0278(4) Uani 1 1 d .
C1 C 0.8387(7) -0.1497(8) 0.4085(6) 0.052(2) Uani 1 1 d .
H1A H 0.8590 -0.0855 0.4563 0.063 Uiso 1 1 d R
H1B H 0.8655 -0.1249 0.3661 0.063 Uiso 1 1 d R
H1C H 0.8792 -0.1913 0.4257 0.063 Uiso 1 1 d R
C2 C 0.7011(7) -0.2226(7) 0.3740(5) 0.0385(18) Uani 1 1 d .
C3 C 0.6448(7) -0.3239(7) 0.3038(5) 0.0356(17) Uani 1 1 d .
H3 H 0.6947 -0.3461 0.2766 0.043 Uiso 1 1 d R
C4 C 0.5191(8) -0.3903(7) 0.2721(6) 0.043(2) Uani 1 1 d .
H4 H 0.4826 -0.4591 0.2242 0.051 Uiso 1 1 d R
C5 C 0.4462(8) -0.3579(7) 0.3108(5) 0.0388(18) Uani 1 1 d .
H5 H 0.3584 -0.4043 0.2898 0.047 Uiso 1 1 d R
C6 C 0.4969(7) -0.2582(6) 0.3812(5) 0.0323(16) Uani 1 1 d .
C7 C 0.6235(8) -0.1934(7) 0.4117(5) 0.0371(17) Uani 1 1 d .
H7 H 0.6599 -0.1259 0.4607 0.044 Uiso 1 1 d R
C8 C 0.1291(10) -0.5018(10) 0.5734(7) 0.063(3) Uani 1 1 d .
H8A H 0.0778 -0.4692 0.5556 0.076 Uiso 1 1 d R
H8B H 0.1444 -0.4904 0.6320 0.076 Uiso 1 1 d R
H8C H 0.0882 -0.5811 0.5408 0.076 Uiso 1 1 d R
C9 C 0.2494(8) -0.4472(6) 0.5605(5) 0.0383(18) Uani 1 1 d .
C10 C 0.3415(9) -0.4783(7) 0.5803(5) 0.044(2) Uani 1 1 d .
H10 H 0.3290 -0.5359 0.6040 0.052 Uiso 1 1 d R
C11 C 0.4499(9) -0.4302(7) 0.5678(5) 0.0421(19) Uani 1 1 d .
H11 H 0.5135 -0.4504 0.5856 0.051 Uiso 1 1 d R
C12 C 0.4675(8) -0.3502(6) 0.5296(5) 0.0366(17) Uani 1 1 d .
H12 H 0.5412 -0.3189 0.5167 0.044 Uiso 1 1 d R
C13 C 0.3790(7) -0.3145(6) 0.5086(5) 0.0301(15) Uani 1 1 d .
C14 C 0.2706(7) -0.3642(6) 0.5235(5) 0.0365(17) Uani 1 1 d .
H14 H 0.2078 -0.3419 0.5084 0.044 Uiso 1 1 d R
C15 C -0.0445(8) -0.5647(6) 0.2261(6) 0.048(2) Uani 1 1 d .
H15A H 0.0066 -0.6003 0.2358 0.057 Uiso 1 1 d R
H15B H -0.0759 -0.5795 0.1669 0.057 Uiso 1 1 d R
H15C H -0.1121 -0.5943 0.2453 0.057 Uiso 1 1 d R
C16 C 0.0297(7) -0.4383(6) 0.2740(5) 0.0368(17) Uani 1 1 d .
C17 C -0.0228(7) -0.3695(6) 0.2696(5) 0.0356(17) Uani 1 1 d .
H17 H -0.1084 -0.4015 0.2362 0.043 Uiso 1 1 d R
C18 C 0.0458(8) -0.2523(7) 0.3136(5) 0.0365(17) Uani 1 1 d .
H18 H 0.0065 -0.2054 0.3103 0.044 Uiso 1 1 d R
C19 C 0.1704(7) -0.2067(6) 0.3614(4) 0.0282(14) Uani 1 1 d .
H19 H 0.2193 -0.1268 0.3910 0.034 Uiso 1 1 d R
C20 C 0.2284(7) -0.2730(6) 0.3683(4) 0.0299(15) Uani 1 1 d .
C21 C 0.1543(7) -0.3918(6) 0.3237(5) 0.0323(16) Uani 1 1 d .
H21 H 0.1911 -0.4405 0.3278 0.039 Uiso 1 1 d R
C22 C 0.3801(7) 0.0673(6) 0.3357(5) 0.0324(15) Uani 1 1 d .
H22A H 0.3738 0.0674 0.2799 0.039 Uiso 1 1 d R
H22B H 0.4150 0.1433 0.3745 0.039 Uiso 1 1 d R
H22C H 0.2995 0.0239 0.3363 0.039 Uiso 1 1 d R
C23 C 0.4084(7) -0.1227(6) 0.2729(5) 0.0356(17) Uani 1 1 d .
H23A H 0.4078 -0.1026 0.2239 0.043 Uiso 1 1 d R
H23B H 0.3254 -0.1701 0.2674 0.043 Uiso 1 1 d R
H23C H 0.4560 -0.1625 0.2779 0.043 Uiso 1 1 d R
C24 C 0.6232(6) 0.0823(6) 0.3529(4) 0.0290(15) Uani 1 1 d .
C25 C 0.7330(7) 0.1007(7) 0.4083(5) 0.0369(18) Uani 1 1 d .
H25 H 0.7320 0.0759 0.4551 0.044 Uiso 1 1 d R
C26 C 0.8441(7) 0.1537(7) 0.3960(6) 0.0429(19) Uani 1 1 d .
H26 H 0.9195 0.1662 0.4349 0.051 Uiso 1 1 d R
C27 C 0.8466(8) 0.1899(7) 0.3277(6) 0.044(2) Uani 1 1 d .
H27 H 0.9231 0.2263 0.3192 0.053 Uiso 1 1 d R
C28 C 0.7359(8) 0.1718(7) 0.2730(6) 0.0421(19) Uani 1 1 d .
H28 H 0.7358 0.1959 0.2258 0.050 Uiso 1 1 d R
C29 C 0.6256(7) 0.1183(7) 0.2854(5) 0.0377(17) Uani 1 1 d .
H29 H 0.5497 0.1058 0.2471 0.045 Uiso 1 1 d R
C30 C 0.5915(10) 0.4404(11) 0.0457(9) 0.085(4) Uani 1 1 d .
H30A H 0.5304 0.4353 -0.0014 0.101 Uiso 1 1 d R
H30B H 0.6414 0.4099 0.0257 0.101 Uiso 1 1 d R
H30C H 0.6428 0.5179 0.0821 0.101 Uiso 1 1 d R
C31 C 0.5296(9) 0.3742(8) 0.0952(7) 0.057(3) Uani 1 1 d .
C32 C 0.5982(9) 0.3688(9) 0.1657(8) 0.065(3) Uani 1 1 d .
H32 H 0.6864 0.4043 0.1821 0.078 Uiso 1 1 d R
C33 C 0.5434(8) 0.3132(8) 0.2144(6) 0.054(3) Uani 1 1 d .
H33 H 0.5931 0.3095 0.2629 0.065 Uiso 1 1 d R
C34 C 0.4157(7) 0.2631(6) 0.1916(5) 0.0392(18) Uani 1 1 d .
H34 H 0.3767 0.2269 0.2256 0.047 Uiso 1 1 d R
C35 C 0.3416(7) 0.2646(6) 0.1193(5) 0.0352(17) Uani 1 1 d .
C36 C 0.3994(7) 0.3206(6) 0.0722(5) 0.0371(18) Uani 1 1 d .
H36 H 0.3496 0.3234 0.0232 0.045 Uiso 1 1 d R
C37 C 0.2358(8) 0.6178(6) 0.0955(6) 0.046(2) Uani 1 1 d .
H37A H 0.2868 0.6331 0.1512 0.055 Uiso 1 1 d R
H37B H 0.1769 0.6452 0.0993 0.055 Uiso 1 1 d R
H37C H 0.2863 0.6548 0.0670 0.055 Uiso 1 1 d R
C38 C 0.1685(7) 0.4939(6) 0.0473(5) 0.0344(16) Uani 1 1 d .
C39 C 0.0879(8) 0.4474(7) -0.0360(5) 0.0403(18) Uani 1 1 d .
H39 H 0.0725 0.4960 -0.0627 0.048 Uiso 1 1 d R
C40 C 0.0287(7) 0.3324(7) -0.0803(5) 0.0370(17) Uani 1 1 d .
H40 H -0.0249 0.3016 -0.1380 0.044 Uiso 1 1 d R
C41 C 0.0485(7) 0.2612(6) -0.0417(4) 0.0311(15) Uani 1 1 d .
H41 H 0.0062 0.1814 -0.0725 0.037 Uiso 1 1 d R
C42 C 0.1273(6) 0.3024(6) 0.0415(5) 0.0297(15) Uani 1 1 d .
C43 C 0.1867(7) 0.4197(6) 0.0831(5) 0.0342(16) Uani 1 1 d .
H43 H 0.2427 0.4486 0.1399 0.041 Uiso 1 1 d R
C44 C 0.0775(8) 0.0479(7) 0.3413(6) 0.045(2) Uani 1 1 d .
H44A H 0.0507 -0.0182 0.2930 0.054 Uiso 1 1 d R
H44B H 0.0090 0.0436 0.3588 0.054 Uiso 1 1 d R
H44C H 0.1410 0.0525 0.3865 0.054 Uiso 1 1 d R
C45 C 0.1262(7) 0.1499(6) 0.3177(5) 0.0324(16) Uani 1 1 d .
C46 C 0.1721(7) 0.2570(7) 0.3757(5) 0.0377(18) Uani 1 1 d .
H46 H 0.1759 0.2663 0.4327 0.045 Uiso 1 1 d R
C47 C 0.2115(8) 0.3507(7) 0.3512(5) 0.0373(17) Uani 1 1 d .
H47 H 0.2435 0.4249 0.3920 0.045 Uiso 1 1 d R
C48 C 0.2044(7) 0.3349(6) 0.2685(5) 0.0350(17) Uani 1 1 d .
H48 H 0.2312 0.3986 0.2513 0.042 Uiso 1 1 d R
C49 C 0.1584(6) 0.2283(6) 0.2078(5) 0.0309(15) Uani 1 1 d .
C50 C 0.1194(6) 0.1363(6) 0.2347(5) 0.0301(15) Uani 1 1 d .
H50 H 0.0881 0.0619 0.1944 0.036 Uiso 1 1 d R
C51 C 0.2614(7) -0.0261(6) 0.0773(5) 0.0370(17) Uani 1 1 d .
H51A H 0.3247 -0.0427 0.0654 0.044 Uiso 1 1 d R
H51B H 0.2159 -0.0783 0.1000 0.044 Uiso 1 1 d R
H51C H 0.2983 0.0493 0.1177 0.044 Uiso 1 1 d R
C52 C 0.1256(7) -0.1742(6) -0.0901(5) 0.0334(16) Uani 1 1 d .
H52A H 0.2023 -0.1735 -0.0901 0.040 Uiso 1 1 d R
H52B H 0.0764 -0.1892 -0.1462 0.040 Uiso 1 1 d R
H52C H 0.0819 -0.2318 -0.0707 0.040 Uiso 1 1 d R
C53 C 0.2530(7) 0.0510(6) -0.0652(5) 0.0348(17) Uani 1 1 d .
C54 C 0.3749(8) 0.0731(8) -0.0521(7) 0.049(2) Uani 1 1 d .
H54 H 0.4131 0.0470 -0.0136 0.059 Uiso 1 1 d R
C55 C 0.4404(9) 0.1333(8) -0.0943(7) 0.058(3) Uani 1 1 d .
H55 H 0.5237 0.1469 -0.0867 0.070 Uiso 1 1 d R
C56 C 0.3875(10) 0.1725(8) -0.1482(7) 0.059(3) Uani 1 1 d .
H56 H 0.4333 0.2128 -0.1775 0.070 Uiso 1 1 d R
C57 C 0.2671(9) 0.1538(8) -0.1593(6) 0.054(2) Uani 1 1 d .
H57 H 0.2316 0.1844 -0.1952 0.065 Uiso 1 1 d R
C58 C 0.2020(8) 0.0941(7) -0.1187(5) 0.043(2) Uani 1 1 d .
H58 H 0.1185 0.0810 -0.1277 0.051 Uiso 1 1 d R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
P1 Pt1 P1 180.0 2_656 .
P1 Pt1 Ge1 88.48(5) 2_656 .
P1 Pt1 Ge1 91.52(5) . .
P1 Pt1 Ge1 91.52(5) 2_656 2_656
P1 Pt1 Ge1 88.48(5) . 2_656
Ge1 Pt1 Ge1 180.0 . 2_656
P2 Pt2 P2 180.0 . 2
P2 Pt2 Ge2 91.70(5) . 2
P2 Pt2 Ge2 88.30(5) 2 2
P2 Pt2 Ge2 88.31(5) . .
P2 Pt2 Ge2 91.69(5) 2 .
Ge2 Pt2 Ge2 180.0 2 .
C20 Ge1 C6 110.6(3) . .
C20 Ge1 C13 100.3(3) . .
C6 Ge1 C13 98.1(3) . .
C20 Ge1 Pt1 110.1(2) . .
C6 Ge1 Pt1 108.5(2) . .
C13 Ge1 Pt1 128.1(2) . .
C42 Ge2 C49 112.8(3) . .
C42 Ge2 C35 99.8(3) . .
C49 Ge2 C35 97.7(3) . .
C42 Ge2 Pt2 109.1(2) . .
C49 Ge2 Pt2 109.2(2) . .
C35 Ge2 Pt2 127.7(2) . .
C22 P1 C24 106.6(3) . .
C22 P1 C23 99.5(4) . .
C24 P1 C23 99.3(3) . .
C22 P1 Pt1 112.8(3) . .
C24 P1 Pt1 114.1(2) . .
C23 P1 Pt1 122.4(3) . .
C52 P2 C53 98.6(3) . .
C52 P2 C51 100.1(4) . .
C53 P2 C51 106.4(4) . .
C52 P2 Pt2 121.7(2) . .
C53 P2 Pt2 114.8(3) . .
C51 P2 Pt2 113.0(3) . .
C2 C1 H1A 108.5 . .
C2 C1 H1B 109.7 . .
H1A C1 H1B 109.5 . .
C2 C1 H1C 110.2 . .
H1A C1 H1C 109.5 . .
H1B C1 H1C 109.5 . .
C3 C2 C7 117.4(7) . .
C3 C2 C1 121.1(8) . .
C7 C2 C1 121.5(8) . .
C2 C3 C4 121.1(7) . .
C2 C3 H3 119.6 . .
C4 C3 H3 119.3 . .
C3 C4 C5 119.5(8) . .
C3 C4 H4 119.7 . .
C5 C4 H4 120.8 . .
C6 C5 C4 122.1(8) . .
C6 C5 H5 117.6 . .
C4 C5 H5 120.3 . .
C7 C6 C5 117.1(7) . .
C7 C6 Ge1 118.4(6) . .
C5 C6 Ge1 124.5(6) . .
C6 C7 C2 122.8(8) . .
C6 C7 H7 118.2 . .
C2 C7 H7 119.0 . .
C9 C8 H8A 109.8 . .
C9 C8 H8B 109.4 . .
H8A C8 H8B 109.5 . .
C9 C8 H8C 109.3 . .
H8A C8 H8C 109.5 . .
H8B C8 H8C 109.5 . .
C10 C9 C14 117.3(8) . .
C10 C9 C8 122.4(8) . .
C14 C9 C8 120.2(8) . .
C9 C10 C11 122.6(8) . .
C9 C10 H10 119.4 . .
C11 C10 H10 118.0 . .
C10 C11 C12 119.0(8) . .
C10 C11 H11 120.2 . .
C12 C11 H11 120.9 . .
C11 C12 C13 121.3(8) . .
C11 C12 H12 120.2 . .
C13 C12 H12 118.5 . .
C14 C13 C12 118.0(7) . .
C14 C13 Ge1 121.5(6) . .
C12 C13 Ge1 119.9(6) . .
C13 C14 C9 121.7(8) . .
C13 C14 H14 119.3 . .
C9 C14 H14 119.0 . .
C16 C15 H15A 110.1 . .
C16 C15 H15B 109.4 . .
H15A C15 H15B 109.5 . .
C16 C15 H15C 108.9 . .
H15A C15 H15C 109.5 . .
H15B C15 H15C 109.5 . .
C17 C16 C21 119.4(7) . .
C17 C16 C15 121.0(7) . .
C21 C16 C15 119.5(7) . .
C16 C17 C18 121.2(7) . .
C16 C17 H17 119.4 . .
C18 C17 H17 119.5 . .
C19 C18 C17 118.9(7) . .
C19 C18 H18 121.3 . .
C17 C18 H18 119.8 . .
C20 C19 C18 122.3(7) . .
C20 C19 H19 117.5 . .
C18 C19 H19 120.2 . .
C19 C20 C21 116.8(7) . .
C19 C20 Ge1 122.3(5) . .
C21 C20 Ge1 120.7(6) . .
C16 C21 C20 121.4(7) . .
C16 C21 H21 119.6 . .
C20 C21 H21 119.0 . .
P1 C22 H22A 109.6 . .
P1 C22 H22B 109.7 . .
H22A C22 H22B 109.5 . .
P1 C22 H22C 109.2 . .
H22A C22 H22C 109.5 . .
H22B C22 H22C 109.5 . .
P1 C23 H23A 109.4 . .
P1 C23 H23B 109.7 . .
H23A C23 H23B 109.5 . .
P1 C23 H23C 109.3 . .
H23A C23 H23C 109.5 . .
H23B C23 H23C 109.5 . .
C29 C24 C25 119.0(7) . .
C29 C24 P1 121.3(6) . .
C25 C24 P1 119.6(6) . .
C24 C25 C26 120.6(8) . .
C24 C25 H25 119.4 . .
C26 C25 H25 120.0 . .
C25 C26 C27 120.4(8) . .
C25 C26 H26 119.7 . .
C27 C26 H26 119.8 . .
C28 C27 C26 118.4(7) . .
C28 C27 H27 121.2 . .
C26 C27 H27 120.4 . .
C27 C28 C29 120.8(8) . .
C27 C28 H28 119.6 . .
C29 C28 H28 119.7 . .
C24 C29 C28 120.8(8) . .
C24 C29 H29 119.1 . .
C28 C29 H29 120.1 . .
C31 C30 H30A 110.3 . .
C31 C30 H30B 109.0 . .
H30A C30 H30B 109.5 . .
C31 C30 H30C 109.1 . .
H30A C30 H30C 109.5 . .
H30B C30 H30C 109.5 . .
C32 C31 C36 118.1(10) . .
C32 C31 C30 121.1(10) . .
C36 C31 C30 120.8(10) . .
C31 C32 C33 122.0(9) . .
C31 C32 H32 119.2 . .
C33 C32 H32 118.8 . .
C34 C33 C32 119.0(9) . .
C34 C33 H33 120.4 . .
C32 C33 H33 120.6 . .
C33 C34 C35 121.1(9) . .
C33 C34 H34 120.2 . .
C35 C34 H34 118.8 . .
C36 C35 C34 118.3(8) . .
C36 C35 Ge2 121.3(6) . .
C34 C35 Ge2 120.2(6) . .
C35 C36 C31 121.5(9) . .
C35 C36 H36 118.9 . .
C31 C36 H36 119.5 . .
C38 C37 H37A 109.7 . .
C38 C37 H37B 109.1 . .
H37A C37 H37B 109.5 . .
C38 C37 H37C 109.7 . .
H37A C37 H37C 109.5 . .
H37B C37 H37C 109.5 . .
C39 C38 C43 117.0(7) . .
C39 C38 C37 122.1(7) . .
C43 C38 C37 120.9(7) . .
C38 C39 C40 121.2(8) . .
C38 C39 H39 119.3 . .
C40 C39 H39 119.5 . .
C41 C40 C39 119.9(7) . .
C41 C40 H40 119.7 . .
C39 C40 H40 120.4 . .
C40 C41 C42 121.7(7) . .
C40 C41 H41 119.5 . .
C42 C41 H41 118.8 . .
C41 C42 C43 116.2(7) . .
C41 C42 Ge2 119.8(5) . .
C43 C42 Ge2 123.8(6) . .
C38 C43 C42 124.1(7) . .
C38 C43 H43 119.5 . .
C42 C43 H43 116.4 . .
C45 C44 H44A 108.9 . .
C45 C44 H44B 109.4 . .
H44A C44 H44B 109.5 . .
C45 C44 H44C 110.1 . .
H44A C44 H44C 109.5 . .
H44B C44 H44C 109.5 . .
C46 C45 C50 119.1(7) . .
C46 C45 C44 121.3(7) . .
C50 C45 C44 119.6(7) . .
C45 C46 C47 120.3(7) . .
C45 C46 H46 119.0 . .
C47 C46 H46 120.7 . .
C48 C47 C46 119.5(7) . .
C48 C47 H47 120.7 . .
C46 C47 H47 119.8 . .
C49 C48 C47 122.2(7) . .
C49 C48 H48 117.9 . .
C47 C48 H48 119.9 . .
C48 C49 C50 116.7(7) . .
C48 C49 Ge2 125.1(6) . .
C50 C49 Ge2 117.9(5) . .
C45 C50 C49 122.3(7) . .
C45 C50 H50 119.2 . .
C49 C50 H50 118.5 . .
P2 C51 H51A 109.6 . .
P2 C51 H51B 109.5 . .
H51A C51 H51B 109.5 . .
P2 C51 H51C 109.3 . .
H51A C51 H51C 109.5 . .
H51B C51 H51C 109.5 . .
P2 C52 H52A 109.3 . .
P2 C52 H52B 109.7 . .
H52A C52 H52B 109.5 . .
P2 C52 H52C 109.5 . .
H52A C52 H52C 109.5 . .
H52B C52 H52C 109.5 . .
C54 C53 C58 117.9(8) . .
C54 C53 P2 122.7(7) . .
C58 C53 P2 119.3(6) . .
C53 C54 C55 119.9(10) . .
C53 C54 H54 119.4 . .
C55 C54 H54 120.7 . .
C56 C55 C54 121.2(9) . .
C56 C55 H55 118.7 . .
C54 C55 H55 120.1 . .
C55 C56 C57 119.1(8) . .
C55 C56 H56 120.2 . .
C57 C56 H56 120.7 . .
C58 C57 C56 120.1(10) . .
C58 C57 H57 121.1 . .
C56 C57 H57 118.9 . .
C57 C58 C53 121.8(9) . .
C57 C58 H58 119.1 . .
C53 C58 H58 119.2 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Pt1 P1 2.3016(17) 2_656
Pt1 P1 2.3016(17) .
Pt1 Ge1 2.4986(7) .
Pt1 Ge1 2.4986(7) 2_656
Pt2 P2 2.2971(18) .
Pt2 P2 2.2971(18) 2
Pt2 Ge2 2.5041(7) 2
Pt2 Ge2 2.5041(7) .
Ge1 C20 1.972(8) .
Ge1 C6 1.982(8) .
Ge1 C13 2.018(7) .
Ge2 C42 1.973(8) .
Ge2 C49 1.986(7) .
Ge2 C35 1.991(8) .
P1 C22 1.818(7) .
P1 C24 1.826(7) .
P1 C23 1.826(7) .
P2 C52 1.816(7) .
P2 C53 1.825(8) .
P2 C51 1.835(8) .
C1 C2 1.503(11) .
C1 H1A 0.9600 .
C1 H1B 0.9599 .
C1 H1C 0.9601 .
C2 C3 1.407(11) .
C2 C7 1.416(11) .
C3 C4 1.374(11) .
C3 H3 0.9601 .
C4 C5 1.391(11) .
C4 H4 0.9601 .
C5 C6 1.404(10) .
C5 H5 0.9600 .
C6 C7 1.380(11) .
C7 H7 0.9600 .
C8 C9 1.499(12) .
C8 H8A 0.9601 .
C8 H8B 0.9601 .
C8 H8C 0.9600 .
C9 C10 1.387(12) .
C9 C14 1.416(10) .
C10 C11 1.357(12) .
C10 H10 0.9600 .
C11 C12 1.396(11) .
C11 H11 0.9600 .
C12 C13 1.396(11) .
C12 H12 0.9599 .
C13 C14 1.382(10) .
C14 H14 0.9600 .
C15 C16 1.519(10) .
C15 H15A 0.9600 .
C15 H15B 0.9600 .
C15 H15C 0.9599 .
C16 C17 1.360(11) .
C16 C21 1.403(11) .
C17 C18 1.408(11) .
C17 H17 0.9600 .
C18 C19 1.396(11) .
C18 H18 0.9599 .
C19 C20 1.387(10) .
C19 H19 0.9600 .
C20 C21 1.430(9) .
C21 H21 0.9600 .
C22 H22A 0.9601 .
C22 H22B 0.9600 .
C22 H22C 0.9600 .
C23 H23A 0.9600 .
C23 H23B 0.9600 .
C23 H23C 0.9600 .
C24 C29 1.386(10) .
C24 C25 1.388(11) .
C25 C26 1.394(11) .
C25 H25 0.9601 .
C26 C27 1.402(12) .
C26 H26 0.9600 .
C27 C28 1.392(13) .
C27 H27 0.9599 .
C28 C29 1.389(10) .
C28 H28 0.9600 .
C29 H29 0.9601 .
C30 C31 1.521(14) .
C30 H30A 0.9600 .
C30 H30B 0.9599 .
C30 H30C 0.9600 .
C31 C32 1.374(16) .
C31 C36 1.419(11) .
C32 C33 1.397(16) .
C32 H32 0.9600 .
C33 C34 1.391(11) .
C33 H33 0.9599 .
C34 C35 1.405(12) .
C34 H34 0.9600 .
C35 C36 1.392(11) .
C36 H36 0.9600 .
C37 C38 1.490(10) .
C37 H37A 0.9601 .
C37 H37B 0.9601 .
C37 H37C 0.9599 .
C38 C39 1.395(11) .
C38 C43 1.388(11) .
C39 C40 1.382(11) .
C39 H39 0.9599 .
C40 C41 1.387(11) .
C40 H40 0.9600 .
C41 C42 1.393(10) .
C41 H41 0.9599 .
C42 C43 1.403(10) .
C43 H43 0.9599 .
C44 C45 1.502(10) .
C44 H44A 0.9600 .
C44 H44B 0.9600 .
C44 H44C 0.9601 .
C45 C46 1.380(11) .
C45 C50 1.394(10) .
C46 C47 1.402(11) .
C46 H46 0.9599 .
C47 C48 1.384(10) .
C47 H47 0.9601 .
C48 C49 1.394(9) .
C48 H48 0.9600 .
C49 C50 1.410(10) .
C50 H50 0.9600 .
C51 H51A 0.9600 .
C51 H51B 0.9599 .
C51 H51C 0.9600 .
C52 H52A 0.9600 .
C52 H52B 0.9599 .
C52 H52C 0.9600 .
C53 C54 1.393(11) .
C53 C58 1.394(12) .
C54 C55 1.394(13) .
C54 H54 0.9600 .
C55 C56 1.369(16) .
C55 H55 0.9600 .
C56 C57 1.390(14) .
C56 H56 0.9600 .
C57 C58 1.367(11) .
C57 H57 0.9600 .
C58 H58 0.9599 .
