#------------------------------------------------------------------------------
#$Date: 2018-09-26 06:29:44 +0300 (Wed, 26 Sep 2018) $
#$Revision: 211175 $
#$URL: file:///home/coder/svn-repositories/cod/cif/8/10/25/8102520.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_8102520
loop_
_publ_author_name
'Ling Chen'
_publ_section_title
;
 Crystal structure of
 (4-hydroxylcinnamato-O,O')-chloro-(1,10-phenanthroline-N,N')zinc(II)
 trihydrate, Zn(C9H7O3)(C10H8N2)Cl · 3H2O
;
_journal_issue                   4
_journal_name_full
'Zeitschrift für Kristallographie - New Crystal Structures'
_journal_page_first              565
_journal_volume                  224
_journal_year                    2009
_chemical_formula_moiety         'C19 H15 Cl N2 O3 Zn, 3(H2 O)'
_chemical_formula_sum            'C19 H21 Cl N2 O6 Zn'
_chemical_formula_weight         474.20
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 132.9460(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   10.2734(2)
_cell_length_b                   18.2611(3)
_cell_length_c                   15.0282(2)
_cell_measurement_reflns_used    1588
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      27.58
_cell_measurement_theta_min      2.16
_cell_volume                     2063.75(7)
_computing_cell_refinement       'SAINT (Bruker, 2006)'
_computing_data_collection       'APEXII (Bruker, 2006)'
_computing_data_reduction        SAINT
_computing_molecular_graphics    'SHELXTL (Sheldrick, 2008)'
_computing_publication_material  SHELXTL
_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.991
_diffrn_measured_fraction_theta_max 0.991
_diffrn_measurement_device_type  'Bruker APEX-II area-detector diffractometer'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0699
_diffrn_reflns_av_sigmaI/netI    0.0690
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       23
_diffrn_reflns_limit_k_min       -23
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            17812
_diffrn_reflns_theta_full        27.58
_diffrn_reflns_theta_max         27.58
_diffrn_reflns_theta_min         2.16
_diffrn_standards_decay_%        none
_diffrn_standards_interval_count none
_diffrn_standards_interval_time  none
_diffrn_standards_number         none
_exptl_absorpt_coefficient_mu    1.357
_exptl_absorpt_correction_T_max  .87
_exptl_absorpt_correction_T_min  .84
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   'SADABS (Sheldrick, 1996)'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.526
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             976
_exptl_crystal_size_max          .15
_exptl_crystal_size_mid          .11
_exptl_crystal_size_min          .10
_refine_diff_density_max         0.384
_refine_diff_density_min         -0.408
_refine_diff_density_rms         0.063
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.021
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     280
_refine_ls_number_reflns         4746
_refine_ls_number_restraints     11
_refine_ls_restrained_S_all      1.021
_refine_ls_R_factor_gt           0.0452
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0447P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0964
_refine_ls_wR_factor_ref         0.1141
_reflns_number_gt                2829
_reflns_number_total             4746
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            1267-2720.cff
_cod_data_source_block           Zn
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1555 2011-01-17 13:19:09Z saulius 
;
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               8102520
#BEGIN Tags that were not found in dictionaries:
_refine_ls_r_factor_ref          0.0950
#END Tags that were not found in dictionaries
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Zn1 Zn 0.29054(4) -0.15105(2) 0.60286(3) 0.04670(15) Uani 1 1 d U . .
Cl1 Cl 0.39981(12) -0.13961(6) 0.79085(8) 0.0734(3) Uani 1 1 d . . .
N1 N 0.2064(3) -0.05882(14) 0.4974(2) 0.0424(6) Uani 1 1 d . . .
N2 N 0.0167(3) -0.16394(14) 0.4851(2) 0.0416(6) Uani 1 1 d . . .
O1 O 1.2948(3) -0.44217(15) 0.7483(2) 0.0737(8) Uani 1 1 d D . .
H1 H 1.2515 -0.4828 0.7144 0.088 Uiso 1 1 d RD . .
O1W O 0.8244(4) -0.07808(19) 0.8548(3) 0.0876(9) Uani 1 1 d D . .
H1WA H 0.759(6) -0.106(3) 0.793(3) 0.131 Uiso 1 1 d D . .
H1WB H 0.752(5) -0.064(3) 0.859(5) 0.131 Uiso 1 1 d D . .
O2 O 0.3590(2) -0.24407(13) 0.56962(19) 0.0516(6) Uani 1 1 d . . .
O2W O -0.5565(5) -0.0145(3) 0.0598(5) 0.178(2) Uani 1 1 d D . .
H2WA H -0.625(10) -0.002(6) 0.070(9) 0.267 Uiso 1 1 d D . .
H2WB H -0.623(10) -0.029(6) -0.012(4) 0.267 Uiso 1 1 d D . .
O3 O 0.5542(3) -0.15601(14) 0.6458(2) 0.0563(6) Uani 1 1 d U . .
O3W O 0.1740(5) -0.3789(2) 0.4662(4) 0.1224(13) Uani 1 1 d D . .
H3WA H 0.212(10) -0.406(3) 0.525(4) 0.184 Uiso 1 1 d D . .
H3WB H 0.221(9) -0.3379(17) 0.502(5) 0.184 Uiso 1 1 d D . .
C1 C 0.8693(4) -0.37256(19) 0.6297(3) 0.0494(8) Uani 1 1 d . . .
H1A H 0.7504 -0.3865 0.5759 0.059 Uiso 1 1 calc R . .
C2 C 0.9912(4) -0.4181(2) 0.6462(3) 0.0534(9) Uani 1 1 d . . .
H2A H 0.9546 -0.4618 0.6030 0.064 Uiso 1 1 calc R . .
C3 C 1.1683(4) -0.3982(2) 0.7274(3) 0.0495(8) Uani 1 1 d . . .
C4 C 1.2206(4) -0.3333(2) 0.7887(3) 0.0589(10) Uani 1 1 d . . .
H4A H 1.3396 -0.3196 0.8423 0.071 Uiso 1 1 calc R . .
C5 C 1.0969(4) -0.2879(2) 0.7712(3) 0.0519(8) Uani 1 1 d . . .
H5A H 1.1338 -0.2441 0.8139 0.062 Uiso 1 1 calc R . .
C6 C 0.9185(4) -0.30699(18) 0.6906(3) 0.0412(7) Uani 1 1 d . . .
C7 C 0.7913(4) -0.25831(18) 0.6755(3) 0.0446(8) Uani 1 1 d . . .
H7A H 0.8353 -0.2136 0.7158 0.054 Uiso 1 1 calc R . .
C8 C 0.6204(4) -0.27099(19) 0.6106(3) 0.0488(8) Uani 1 1 d . . .
H8A H 0.5703 -0.3136 0.5645 0.059 Uiso 1 1 calc R . .
C9 C 0.5066(4) -0.2207(2) 0.6083(3) 0.0467(8) Uani 1 1 d . . .
C10 C -0.0691(4) -0.2189(2) 0.4855(3) 0.0525(8) Uani 1 1 d . . .
H10A H -0.0035 -0.2581 0.5379 0.063 Uiso 1 1 calc R . .
C11 C -0.2504(4) -0.2195(2) 0.4113(3) 0.0580(10) Uani 1 1 d . . .
H11A H -0.3071 -0.2585 0.4128 0.070 Uiso 1 1 calc R . .
C12 C -0.3454(4) -0.1616(2) 0.3353(3) 0.0587(10) Uani 1 1 d . . .
H12A H -0.4682 -0.1604 0.2849 0.070 Uiso 1 1 calc R . .
C13 C -0.2592(4) -0.1045(2) 0.3332(3) 0.0497(8) Uani 1 1 d . . .
H13A H -0.3232 -0.0649 0.2813 0.060 Uiso 1 1 calc R . .
C14 C -0.0772(3) -0.10723(18) 0.4088(2) 0.0384(7) Uani 1 1 d . . .
C15 C 0.0290(4) -0.04972(18) 0.4128(3) 0.0406(7) Uani 1 1 d . . .
C16 C -0.0459(4) 0.0096(2) 0.3359(3) 0.0545(9) Uani 1 1 d . . .
H16A H -0.1687 0.0156 0.2785 0.065 Uiso 1 1 calc R . .
C17 C 0.0609(5) 0.0599(2) 0.3441(3) 0.0630(10) Uani 1 1 d . . .
H17A H 0.0114 0.1000 0.2921 0.076 Uiso 1 1 calc R . .
C18 C 0.2409(5) 0.0503(2) 0.4295(3) 0.0613(10) Uani 1 1 d . . .
H18A H 0.3158 0.0838 0.4366 0.074 Uiso 1 1 calc R . .
C19 C 0.3092(4) -0.0094(2) 0.5044(3) 0.0549(9) Uani 1 1 d . . .
H19A H 0.4319 -0.0158 0.5624 0.066 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Zn Zn 0.2839 1.4301 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O2 Zn1 N1 122.04(10) . . ?
O2 Zn1 N2 101.02(9) . . ?
N1 Zn1 N2 79.76(10) . . ?
O2 Zn1 Cl1 115.56(7) . . ?
N1 Zn1 Cl1 119.00(8) . . ?
N2 Zn1 Cl1 108.09(7) . . ?
O2 Zn1 O3 60.01(8) . . ?
N1 Zn1 O3 92.55(9) . . ?
N2 Zn1 O3 151.58(9) . . ?
Cl1 Zn1 O3 99.60(7) . . ?
O2 Zn1 C9 30.23(10) . . ?
N1 Zn1 C9 109.76(10) . . ?
N2 Zn1 C9 128.64(11) . . ?
Cl1 Zn1 C9 109.61(7) . . ?
O3 Zn1 C9 29.79(9) . . ?
C19 N1 C15 118.7(3) . . ?
C19 N1 Zn1 126.7(2) . . ?
C15 N1 Zn1 114.6(2) . . ?
C10 N2 C14 119.2(3) . . ?
C10 N2 Zn1 126.5(2) . . ?
C14 N2 Zn1 114.02(19) . . ?
C3 O1 H1 110.7 . . ?
H1WA O1W H1WB 101(3) . . ?
C9 O2 Zn1 96.4(2) . . ?
H2WA O2W H2WB 106(10) . . ?
C9 O3 Zn1 83.60(18) . . ?
H3WA O3W H3WB 101(3) . . ?
C6 C1 C2 121.9(3) . . ?
C6 C1 H1A 119.0 . . ?
C2 C1 H1A 119.0 . . ?
C1 C2 C3 119.2(3) . . ?
C1 C2 H2A 120.4 . . ?
C3 C2 H2A 120.4 . . ?
C4 C3 O1 118.6(3) . . ?
C4 C3 C2 120.0(3) . . ?
O1 C3 C2 121.4(3) . . ?
C3 C4 C5 120.2(3) . . ?
C3 C4 H4A 119.9 . . ?
C5 C4 H4A 119.9 . . ?
C4 C5 C6 120.8(3) . . ?
C4 C5 H5A 119.6 . . ?
C6 C5 H5A 119.6 . . ?
C1 C6 C5 117.8(3) . . ?
C1 C6 C7 122.7(3) . . ?
C5 C6 C7 119.5(3) . . ?
C8 C7 C6 127.1(3) . . ?
C8 C7 H7A 116.5 . . ?
C6 C7 H7A 116.5 . . ?
C7 C8 C9 122.9(3) . . ?
C7 C8 H8A 118.6 . . ?
C9 C8 H8A 118.6 . . ?
O3 C9 O2 119.9(3) . . ?
O3 C9 C8 121.2(3) . . ?
O2 C9 C8 118.8(3) . . ?
O3 C9 Zn1 66.61(16) . . ?
O2 C9 Zn1 53.35(15) . . ?
C8 C9 Zn1 171.7(3) . . ?
N2 C10 C11 122.4(3) . . ?
N2 C10 H10A 118.8 . . ?
C11 C10 H10A 118.8 . . ?
C12 C11 C10 118.4(3) . . ?
C12 C11 H11A 120.8 . . ?
C10 C11 H11A 120.8 . . ?
C11 C12 C13 120.0(3) . . ?
C11 C12 H12A 120.0 . . ?
C13 C12 H12A 120.0 . . ?
C14 C13 C12 119.0(3) . . ?
C14 C13 H13A 120.5 . . ?
C12 C13 H13A 120.5 . . ?
N2 C14 C13 120.9(3) . . ?
N2 C14 C15 115.4(2) . . ?
C13 C14 C15 123.7(3) . . ?
N1 C15 C16 120.9(3) . . ?
N1 C15 C14 115.9(3) . . ?
C16 C15 C14 123.2(3) . . ?
C17 C16 C15 119.8(3) . . ?
C17 C16 H16A 120.1 . . ?
C15 C16 H16A 120.1 . . ?
C18 C17 C16 119.2(3) . . ?
C18 C17 H17A 120.4 . . ?
C16 C17 H17A 120.4 . . ?
C17 C18 C19 118.9(3) . . ?
C17 C18 H18A 120.6 . . ?
C19 C18 H18A 120.6 . . ?
N1 C19 C18 122.5(3) . . ?
N1 C19 H19A 118.7 . . ?
C18 C19 H19A 118.7 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Zn1 O2 2.027(2) . ?
Zn1 N1 2.057(3) . ?
Zn1 N2 2.078(2) . ?
Zn1 Cl1 2.2279(10) . ?
Zn1 O3 2.319(2) . ?
Zn1 C9 2.511(3) . ?
N1 C19 1.338(4) . ?
N1 C15 1.344(3) . ?
N2 C10 1.338(4) . ?
N2 C14 1.346(4) . ?
O1 C3 1.370(4) . ?
O1 H1 0.8371 . ?
O1W H1WA 0.85(4) . ?
O1W H1WB 0.83(7) . ?
O2 C9 1.272(4) . ?
O2W H2WA 0.85(14) . ?
O2W H2WB 0.84(5) . ?
O3 C9 1.255(4) . ?
O3W H3WA 0.84(5) . ?
O3W H3WB 0.85(2) . ?
C1 C6 1.377(4) . ?
C1 C2 1.379(4) . ?
C1 H1A 0.9300 . ?
C2 C3 1.381(4) . ?
C2 H2A 0.9300 . ?
C3 C4 1.366(5) . ?
C4 C5 1.384(5) . ?
C4 H4A 0.9300 . ?
C5 C6 1.387(4) . ?
C5 H5A 0.9300 . ?
C6 C7 1.464(4) . ?
C7 C8 1.325(4) . ?
C7 H7A 0.9300 . ?
C8 C9 1.468(4) . ?
C8 H8A 0.9300 . ?
C10 C11 1.372(4) . ?
C10 H10A 0.9300 . ?
C11 C12 1.362(5) . ?
C11 H11A 0.9300 . ?
C12 C13 1.382(5) . ?
C12 H12A 0.9300 . ?
C13 C14 1.376(4) . ?
C13 H13A 0.9300 . ?
C14 C15 1.486(4) . ?
C15 C16 1.376(4) . ?
C16 C17 1.370(5) . ?
C16 H16A 0.9300 . ?
C17 C18 1.365(5) . ?
C17 H17A 0.9300 . ?
C18 C19 1.368(5) . ?
C18 H18A 0.9300 . ?
C19 H19A 0.9300 . ?
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
O1 H1 O1W 0.84 1.90 2.734(4) 174.5 2_746
O1W H1WA O3 0.85(4) 1.95(3) 2.778(4) 163(5) .
O3W H3WA O2W 0.84(5) 2.52(8) 2.851(7) 105(6) 4_656
O3W H3WB O2 0.85(2) 2.00(5) 2.839(4) 166(7) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O2 Zn1 N1 C19 -79.8(3) . . . . ?
N2 Zn1 N1 C19 -176.5(3) . . . . ?
Cl1 Zn1 N1 C19 78.4(3) . . . . ?
O3 Zn1 N1 C19 -24.1(3) . . . . ?
C9 Zn1 N1 C19 -49.0(3) . . . . ?
O2 Zn1 N1 C15 99.3(2) . . . . ?
N2 Zn1 N1 C15 2.6(2) . . . . ?
Cl1 Zn1 N1 C15 -102.5(2) . . . . ?
O3 Zn1 N1 C15 155.1(2) . . . . ?
C9 Zn1 N1 C15 130.1(2) . . . . ?
O2 Zn1 N2 C10 59.4(3) . . . . ?
N1 Zn1 N2 C10 -179.6(3) . . . . ?
Cl1 Zn1 N2 C10 -62.3(3) . . . . ?
O3 Zn1 N2 C10 104.2(3) . . . . ?
C9 Zn1 N2 C10 73.2(3) . . . . ?
O2 Zn1 N2 C14 -125.8(2) . . . . ?
N1 Zn1 N2 C14 -4.88(19) . . . . ?
Cl1 Zn1 N2 C14 112.45(19) . . . . ?
O3 Zn1 N2 C14 -81.1(3) . . . . ?
C9 Zn1 N2 C14 -112.1(2) . . . . ?
N1 Zn1 O2 C9 73.6(2) . . . . ?
N2 Zn1 O2 C9 158.35(18) . . . . ?
Cl1 Zn1 O2 C9 -85.30(19) . . . . ?
O3 Zn1 O2 C9 1.11(18) . . . . ?
O2 Zn1 O3 C9 -1.13(18) . . . . ?
N1 Zn1 O3 C9 -127.10(19) . . . . ?
N2 Zn1 O3 C9 -54.1(3) . . . . ?
Cl1 Zn1 O3 C9 112.92(18) . . . . ?
C6 C1 C2 C3 1.1(5) . . . . ?
C1 C2 C3 C4 -1.3(5) . . . . ?
C1 C2 C3 O1 179.0(3) . . . . ?
O1 C3 C4 C5 -179.1(3) . . . . ?
C2 C3 C4 C5 1.1(5) . . . . ?
C3 C4 C5 C6 -0.7(5) . . . . ?
C2 C1 C6 C5 -0.6(5) . . . . ?
C2 C1 C6 C7 -179.2(3) . . . . ?
C4 C5 C6 C1 0.4(5) . . . . ?
C4 C5 C6 C7 179.1(3) . . . . ?
C1 C6 C7 C8 4.5(5) . . . . ?
C5 C6 C7 C8 -174.0(3) . . . . ?
C6 C7 C8 C9 175.5(3) . . . . ?
Zn1 O3 C9 O2 1.8(3) . . . . ?
Zn1 O3 C9 C8 -176.8(3) . . . . ?
Zn1 O2 C9 O3 -2.1(3) . . . . ?
Zn1 O2 C9 C8 176.6(2) . . . . ?
C7 C8 C9 O3 15.9(5) . . . . ?
C7 C8 C9 O2 -162.8(3) . . . . ?
O2 Zn1 C9 O3 178.1(3) . . . . ?
N1 Zn1 C9 O3 57.8(2) . . . . ?
N2 Zn1 C9 O3 150.44(18) . . . . ?
Cl1 Zn1 C9 O3 -74.58(19) . . . . ?
N1 Zn1 C9 O2 -120.21(18) . . . . ?
N2 Zn1 C9 O2 -27.6(2) . . . . ?
Cl1 Zn1 C9 O2 107.36(17) . . . . ?
O3 Zn1 C9 O2 -178.1(3) . . . . ?
C14 N2 C10 C11 -0.6(5) . . . . ?
Zn1 N2 C10 C11 173.9(2) . . . . ?
N2 C10 C11 C12 -0.4(5) . . . . ?
C10 C11 C12 C13 0.8(5) . . . . ?
C11 C12 C13 C14 -0.2(5) . . . . ?
C10 N2 C14 C13 1.2(4) . . . . ?
Zn1 N2 C14 C13 -174.0(2) . . . . ?
C10 N2 C14 C15 -178.6(3) . . . . ?
Zn1 N2 C14 C15 6.2(3) . . . . ?
C12 C13 C14 N2 -0.8(5) . . . . ?
C12 C13 C14 C15 179.0(3) . . . . ?
C19 N1 C15 C16 -0.8(4) . . . . ?
Zn1 N1 C15 C16 180.0(2) . . . . ?
C19 N1 C15 C14 179.1(3) . . . . ?
Zn1 N1 C15 C14 -0.1(3) . . . . ?
N2 C14 C15 N1 -4.1(4) . . . . ?
C13 C14 C15 N1 176.0(3) . . . . ?
N2 C14 C15 C16 175.8(3) . . . . ?
C13 C14 C15 C16 -4.0(5) . . . . ?
N1 C15 C16 C17 0.8(5) . . . . ?
C14 C15 C16 C17 -179.1(3) . . . . ?
C15 C16 C17 C18 -0.4(5) . . . . ?
C16 C17 C18 C19 0.1(5) . . . . ?
C15 N1 C19 C18 0.5(5) . . . . ?
Zn1 N1 C19 C18 179.6(3) . . . . ?
C17 C18 C19 N1 -0.1(5) . . . . ?
