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#$Date: 2022-06-07 11:02:40 +0300 (Tue, 07 Jun 2022) $
#$Revision: 275866 $
#$URL: file:///home/coder/svn-repositories/cod/cif/8/10/53/8105350.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_8105350
loop_
_publ_author_name
'Lo, Kong Mun'
'Lee, See Mun'
'Tiekink, Edward R.T.'
_publ_section_title
;
 Crystal structure of bromido-triphenyl-(triphenylarsine
 oxide-\kO)tin(IV), C36H30AsBrOSn
;
_journal_issue                   4
_journal_name_full
'Zeitschrift für Kristallographie - New Crystal Structures'
_journal_page_first              981
_journal_page_last               983
_journal_paper_doi               10.1515/ncrs-2020-0138
_journal_volume                  235
_journal_year                    2020
_chemical_formula_moiety         'C36 H30 As Br O Sn'
_chemical_formula_sum            'C36 H30 As Br O Sn'
_chemical_formula_weight         752.12
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-2018/3
_cell_angle_alpha                102.3670(10)
_cell_angle_beta                 93.3690(10)
_cell_angle_gamma                103.1340(10)
_cell_formula_units_Z            2
_cell_length_a                   9.83160(10)
_cell_length_b                   10.8781(2)
_cell_length_c                   14.9388(2)
_cell_measurement_reflns_used    28007
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      76.2740
_cell_measurement_theta_min      3.0380
_cell_volume                     1510.07(4)
_computing_cell_refinement       'CrysAlisPro [1]'
_computing_data_collection       'CrysAlisPro [1]'
_computing_data_reduction        'CrysAlisPro [1]'
_computing_molecular_graphics    'ORTEP-3 for Windows [4]'
_computing_publication_material  'SHELXL-2018/3 [3]'
_computing_structure_refinement  'SHELXL-2018/3 [3]'
_computing_structure_solution    'SHELXT 2014/5 [2]'
_diffrn_ambient_temperature      100(2)
_diffrn_detector_area_resol_mean 5.2558
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'XtaLAB Synergy, Dualflex, AtlasS2'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54184
_diffrn_reflns_av_R_equivalents  0.0292
_diffrn_reflns_av_unetI/netI     0.0166
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 1.000
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -14
_diffrn_reflns_number            35879
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 1.000
_diffrn_reflns_theta_full        67.080
_diffrn_reflns_theta_max         67.080
_diffrn_reflns_theta_min         3.048
_diffrn_source                   'micro-focus sealed X-ray tube'
_exptl_absorpt_coefficient_mu    9.702
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  0.756
_exptl_absorpt_correction_type   gaussian
_exptl_absorpt_process_details   'CrysAlisPro [1]'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.654
_exptl_crystal_description       prism
_exptl_crystal_F_000             744
_exptl_crystal_size_max          0.158
_exptl_crystal_size_mid          0.076
_exptl_crystal_size_min          0.055
_refine_diff_density_max         0.301
_refine_diff_density_min         -0.728
_refine_diff_density_rms         0.074
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.045
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     361
_refine_ls_number_reflns         5393
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.045
_refine_ls_R_factor_all          0.0178
_refine_ls_R_factor_gt           0.0175
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0255P)²+1.2278P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0468
_refine_ls_wR_factor_ref         0.0469
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                5331
_reflns_number_total             5393
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            suppl_ncrs-2020-0138_suppl.cif
_cod_data_source_block           shelx
_cod_database_code               8105350
_shelx_shelxl_version_number     2018/3
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.309
_shelx_estimated_absorpt_t_max   0.617
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Sn Sn 0.78069(2) 0.55247(2) 0.73706(2) 0.01062(5) Uani 1 1 d . . . . .
As As 0.69267(2) 0.21868(2) 0.76382(2) 0.00971(6) Uani 1 1 d . . . . .
Br1 Br 0.87976(2) 0.75872(2) 0.66552(2) 0.01932(6) Uani 1 1 d . . . . .
O1 O 0.69163(14) 0.37567(13) 0.79001(9) 0.0131(3) Uani 1 1 d . . . . .
C1 C 0.6651(2) 0.44394(18) 0.60825(13) 0.0128(4) Uani 1 1 d . . . . .
C2 C 0.5188(2) 0.4096(2) 0.59939(14) 0.0170(4) Uani 1 1 d . . . . .
H2 H 0.470875 0.439276 0.649927 0.020 Uiso 1 1 calc R U . . .
C3 C 0.4420(2) 0.3326(2) 0.51763(15) 0.0223(5) Uani 1 1 d . . . . .
H3 H 0.342152 0.311435 0.511968 0.027 Uiso 1 1 calc R U . . .
C4 C 0.5110(3) 0.2870(2) 0.44464(15) 0.0231(5) Uani 1 1 d . . . . .
H4 H 0.458781 0.233455 0.388917 0.028 Uiso 1 1 calc R U . . .
C5 C 0.6570(3) 0.3195(2) 0.45267(15) 0.0222(5) Uani 1 1 d . . . . .
H5 H 0.704572 0.287004 0.402748 0.027 Uiso 1 1 calc R U . . .
C6 C 0.7335(2) 0.3993(2) 0.53358(14) 0.0174(4) Uani 1 1 d . . . . .
H6 H 0.833255 0.423715 0.538001 0.021 Uiso 1 1 calc R U . . .
C7 C 0.9875(2) 0.53195(18) 0.77377(13) 0.0138(4) Uani 1 1 d . . . . .
C8 C 1.0990(2) 0.5641(2) 0.72234(15) 0.0181(4) Uani 1 1 d . . . . .
H8 H 1.084950 0.598993 0.670421 0.022 Uiso 1 1 calc R U . . .
C9 C 1.2304(2) 0.5454(2) 0.74644(17) 0.0241(5) Uani 1 1 d . . . . .
H9 H 1.305319 0.567521 0.710944 0.029 Uiso 1 1 calc R U . . .
C10 C 1.2523(2) 0.4945(2) 0.82198(17) 0.0245(5) Uani 1 1 d . . . . .
H10 H 1.342130 0.481936 0.838326 0.029 Uiso 1 1 calc R U . . .
C11 C 1.1424(2) 0.4620(2) 0.87383(15) 0.0207(4) Uani 1 1 d . . . . .
H11 H 1.156961 0.426572 0.925439 0.025 Uiso 1 1 calc R U . . .
C12 C 1.0119(2) 0.48123(19) 0.85021(14) 0.0162(4) Uani 1 1 d . . . . .
H12 H 0.937707 0.459715 0.886401 0.019 Uiso 1 1 calc R U . . .
C13 C 0.6917(2) 0.65907(19) 0.84714(13) 0.0127(4) Uani 1 1 d . . . . .
C14 C 0.6474(2) 0.60513(19) 0.92056(14) 0.0159(4) Uani 1 1 d . . . . .
H14 H 0.646868 0.517112 0.918440 0.019 Uiso 1 1 calc R U . . .
C15 C 0.6040(2) 0.6784(2) 0.99664(14) 0.0198(4) Uani 1 1 d . . . . .
H15 H 0.574648 0.640148 1.046027 0.024 Uiso 1 1 calc R U . . .
C16 C 0.6034(2) 0.8065(2) 1.00092(14) 0.0181(4) Uani 1 1 d . . . . .
H16 H 0.574089 0.856503 1.053098 0.022 Uiso 1 1 calc R U . . .
C17 C 0.6460(2) 0.8614(2) 0.92854(15) 0.0205(4) Uani 1 1 d . . . . .
H17 H 0.645558 0.949286 0.930939 0.025 Uiso 1 1 calc R U . . .
C18 C 0.6893(2) 0.7883(2) 0.85240(14) 0.0187(4) Uani 1 1 d . . . . .
H18 H 0.717795 0.826951 0.803028 0.022 Uiso 1 1 calc R U . . .
C19 C 0.7680(2) 0.16074(19) 0.65139(13) 0.0133(4) Uani 1 1 d . . . . .
C20 C 0.6827(2) 0.0670(2) 0.57993(14) 0.0170(4) Uani 1 1 d . . . . .
H20 H 0.588107 0.029310 0.587122 0.020 Uiso 1 1 calc R U . . .
C21 C 0.7374(2) 0.0287(2) 0.49753(14) 0.0208(4) Uani 1 1 d . . . . .
H21 H 0.680067 -0.036182 0.448434 0.025 Uiso 1 1 calc R U . . .
C22 C 0.8749(2) 0.0847(2) 0.48676(14) 0.0201(4) Uani 1 1 d . . . . .
H22 H 0.911131 0.059244 0.429995 0.024 Uiso 1 1 calc R U . . .
C23 C 0.9601(2) 0.1783(2) 0.55919(15) 0.0190(4) Uani 1 1 d . . . . .
H23 H 1.054520 0.216347 0.551712 0.023 Uiso 1 1 calc R U . . .
C24 C 0.9078(2) 0.21616(19) 0.64194(14) 0.0157(4) Uani 1 1 d . . . . .
H24 H 0.966066 0.278993 0.691694 0.019 Uiso 1 1 calc R U . . .
C25 C 0.7981(2) 0.18617(18) 0.86439(13) 0.0128(4) Uani 1 1 d . . . . .
C26 C 0.9084(2) 0.1262(2) 0.85161(15) 0.0179(4) Uani 1 1 d . . . . .
H26 H 0.928468 0.091814 0.791238 0.021 Uiso 1 1 calc R U . . .
C27 C 0.9891(2) 0.1175(2) 0.92865(16) 0.0228(5) Uani 1 1 d . . . . .
H27 H 1.066662 0.079195 0.920912 0.027 Uiso 1 1 calc R U . . .
C28 C 0.9568(2) 0.1643(2) 1.01673(16) 0.0224(5) Uani 1 1 d . . . . .
H28 H 1.012568 0.158006 1.068909 0.027 Uiso 1 1 calc R U . . .
C29 C 0.8436(2) 0.2201(2) 1.02907(15) 0.0203(4) Uani 1 1 d . . . . .
H29 H 0.820044 0.249387 1.089398 0.024 Uiso 1 1 calc R U . . .
C30 C 0.7647(2) 0.23313(19) 0.95272(14) 0.0154(4) Uani 1 1 d . . . . .
H30 H 0.688841 0.273633 0.960667 0.018 Uiso 1 1 calc R U . . .
C31 C 0.5021(2) 0.12307(19) 0.75776(13) 0.0125(4) Uani 1 1 d . . . . .
C32 C 0.4716(2) -0.0060(2) 0.76344(14) 0.0175(4) Uani 1 1 d . . . . .
H32 H 0.544719 -0.049488 0.766518 0.021 Uiso 1 1 calc R U . . .
C33 C 0.3328(3) -0.0705(2) 0.76455(15) 0.0250(5) Uani 1 1 d . . . . .
H33 H 0.310563 -0.158785 0.768413 0.030 Uiso 1 1 calc R U . . .
C34 C 0.2268(2) -0.0068(2) 0.76006(15) 0.0272(5) Uani 1 1 d . . . . .
H34 H 0.132132 -0.051425 0.761224 0.033 Uiso 1 1 calc R U . . .
C35 C 0.2574(2) 0.1212(2) 0.75388(14) 0.0244(5) Uani 1 1 d . . . . .
H35 H 0.183873 0.164171 0.750373 0.029 Uiso 1 1 calc R U . . .
C36 C 0.3961(2) 0.1872(2) 0.75281(14) 0.0173(4) Uani 1 1 d . . . . .
H36 H 0.417873 0.275403 0.748731 0.021 Uiso 1 1 calc R U . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
As As -0.9300 1.0051 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Br Br -0.6763 1.2805 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sn Sn 0.0259 5.4591 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C1 Sn C7 120.16(7) . .
C1 Sn C13 124.06(7) . .
C7 Sn C13 114.86(7) . .
C1 Sn O1 85.54(6) . .
C7 Sn O1 88.52(6) . .
C13 Sn O1 86.55(6) . .
C1 Sn Br1 91.65(5) . .
C7 Sn Br1 93.09(5) . .
C13 Sn Br1 94.87(5) . .
O1 Sn Br1 177.18(3) . .
O1 As C31 106.45(8) . .
O1 As C25 107.69(7) . .
C31 As C25 107.76(8) . .
O1 As C19 115.55(7) . .
C31 As C19 109.79(8) . .
C25 As C19 109.31(8) . .
As O1 Sn 136.77(7) . .
C2 C1 C6 118.77(18) . .
C2 C1 Sn 120.09(14) . .
C6 C1 Sn 121.02(15) . .
C1 C2 C3 120.9(2) . .
C1 C2 H2 119.6 . .
C3 C2 H2 119.6 . .
C4 C3 C2 119.8(2) . .
C4 C3 H3 120.1 . .
C2 C3 H3 120.1 . .
C3 C4 C5 120.0(2) . .
C3 C4 H4 120.0 . .
C5 C4 H4 120.0 . .
C6 C5 C4 120.1(2) . .
C6 C5 H5 120.0 . .
C4 C5 H5 120.0 . .
C5 C6 C1 120.4(2) . .
C5 C6 H6 119.8 . .
C1 C6 H6 119.8 . .
C12 C7 C8 118.24(19) . .
C12 C7 Sn 119.47(14) . .
C8 C7 Sn 122.27(15) . .
C9 C8 C7 120.6(2) . .
C9 C8 H8 119.7 . .
C7 C8 H8 119.7 . .
C8 C9 C10 120.3(2) . .
C8 C9 H9 119.9 . .
C10 C9 H9 119.9 . .
C9 C10 C11 119.8(2) . .
C9 C10 H10 120.1 . .
C11 C10 H10 120.1 . .
C12 C11 C10 120.0(2) . .
C12 C11 H11 120.0 . .
C10 C11 H11 120.0 . .
C11 C12 C7 121.07(19) . .
C11 C12 H12 119.5 . .
C7 C12 H12 119.5 . .
C18 C13 C14 117.77(18) . .
C18 C13 Sn 121.21(14) . .
C14 C13 Sn 120.71(14) . .
C15 C14 C13 120.96(19) . .
C15 C14 H14 119.5 . .
C13 C14 H14 119.5 . .
C16 C15 C14 120.43(19) . .
C16 C15 H15 119.8 . .
C14 C15 H15 119.8 . .
C15 C16 C17 119.45(19) . .
C15 C16 H16 120.3 . .
C17 C16 H16 120.3 . .
C18 C17 C16 120.21(19) . .
C18 C17 H17 119.9 . .
C16 C17 H17 119.9 . .
C17 C18 C13 121.18(19) . .
C17 C18 H18 119.4 . .
C13 C18 H18 119.4 . .
C20 C19 C24 120.93(18) . .
C20 C19 As 119.79(15) . .
C24 C19 As 119.26(15) . .
C19 C20 C21 119.25(19) . .
C19 C20 H20 120.4 . .
C21 C20 H20 120.4 . .
C22 C21 C20 120.3(2) . .
C22 C21 H21 119.8 . .
C20 C21 H21 119.8 . .
C21 C22 C23 120.02(19) . .
C21 C22 H22 120.0 . .
C23 C22 H22 120.0 . .
C24 C23 C22 120.27(19) . .
C24 C23 H23 119.9 . .
C22 C23 H23 119.9 . .
C23 C24 C19 119.17(19) . .
C23 C24 H24 120.4 . .
C19 C24 H24 120.4 . .
C26 C25 C30 120.96(19) . .
C26 C25 As 122.25(15) . .
C30 C25 As 116.67(15) . .
C25 C26 C27 119.0(2) . .
C25 C26 H26 120.5 . .
C27 C26 H26 120.5 . .
C26 C27 C28 120.4(2) . .
C26 C27 H27 119.8 . .
C28 C27 H27 119.8 . .
C29 C28 C27 120.4(2) . .
C29 C28 H28 119.8 . .
C27 C28 H28 119.8 . .
C28 C29 C30 119.7(2) . .
C28 C29 H29 120.1 . .
C30 C29 H29 120.1 . .
C29 C30 C25 119.45(19) . .
C29 C30 H30 120.3 . .
C25 C30 H30 120.3 . .
C36 C31 C32 120.90(18) . .
C36 C31 As 118.57(15) . .
C32 C31 As 120.43(15) . .
C33 C32 C31 119.1(2) . .
C33 C32 H32 120.5 . .
C31 C32 H32 120.5 . .
C34 C33 C32 120.2(2) . .
C34 C33 H33 119.9 . .
C32 C33 H33 119.9 . .
C35 C34 C33 120.6(2) . .
C35 C34 H34 119.7 . .
C33 C34 H34 119.7 . .
C34 C35 C36 119.9(2) . .
C34 C35 H35 120.1 . .
C36 C35 H35 120.1 . .
C31 C36 C35 119.4(2) . .
C31 C36 H36 120.3 . .
C35 C36 H36 120.3 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Sn C1 2.1326(19) .
Sn C7 2.147(2) .
Sn C13 2.1514(19) .
Sn O1 2.2493(13) .
Sn Br1 2.6983(2) .
As O1 1.6709(13) .
As C31 1.9115(19) .
As C25 1.9150(19) .
As C19 1.9160(19) .
C1 C2 1.392(3) .
C1 C6 1.392(3) .
C2 C3 1.389(3) .
C2 H2 0.9500 .
C3 C4 1.380(3) .
C3 H3 0.9500 .
C4 C5 1.390(3) .
C4 H4 0.9500 .
C5 C6 1.388(3) .
C5 H5 0.9500 .
C6 H6 0.9500 .
C7 C12 1.401(3) .
C7 C8 1.398(3) .
C8 C9 1.391(3) .
C8 H8 0.9500 .
C9 C10 1.385(3) .
C9 H9 0.9500 .
C10 C11 1.391(3) .
C10 H10 0.9500 .
C11 C12 1.384(3) .
C11 H11 0.9500 .
C12 H12 0.9500 .
C13 C18 1.397(3) .
C13 C14 1.397(3) .
C14 C15 1.389(3) .
C14 H14 0.9500 .
C15 C16 1.384(3) .
C15 H15 0.9500 .
C16 C17 1.384(3) .
C16 H16 0.9500 .
C17 C18 1.389(3) .
C17 H17 0.9500 .
C18 H18 0.9500 .
C19 C20 1.386(3) .
C19 C24 1.398(3) .
C20 C21 1.392(3) .
C20 H20 0.9500 .
C21 C22 1.385(3) .
C21 H21 0.9500 .
C22 C23 1.395(3) .
C22 H22 0.9500 .
C23 C24 1.384(3) .
C23 H23 0.9500 .
C24 H24 0.9500 .
C25 C26 1.389(3) .
C25 C30 1.396(3) .
C26 C27 1.392(3) .
C26 H26 0.9500 .
C27 C28 1.388(3) .
C27 H27 0.9500 .
C28 C29 1.387(3) .
C28 H28 0.9500 .
C29 C30 1.392(3) .
C29 H29 0.9500 .
C30 H30 0.9500 .
C31 C36 1.387(3) .
C31 C32 1.390(3) .
C32 C33 1.389(3) .
C32 H32 0.9500 .
C33 C34 1.383(4) .
C33 H33 0.9500 .
C34 C35 1.380(4) .
C34 H34 0.9500 .
C35 C36 1.392(3) .
C35 H35 0.9500 .
C36 H36 0.9500 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
C31 As O1 Sn -131.67(11) . . . .
C25 As O1 Sn 112.99(11) . . . .
C19 As O1 Sn -9.50(14) . . . .
C6 C1 C2 C3 -0.2(3) . . . .
Sn C1 C2 C3 -176.25(15) . . . .
C1 C2 C3 C4 1.4(3) . . . .
C2 C3 C4 C5 -0.8(3) . . . .
C3 C4 C5 C6 -1.0(3) . . . .
C4 C5 C6 C1 2.2(3) . . . .
C2 C1 C6 C5 -1.6(3) . . . .
Sn C1 C6 C5 174.46(15) . . . .
C12 C7 C8 C9 0.3(3) . . . .
Sn C7 C8 C9 -177.82(16) . . . .
C7 C8 C9 C10 0.0(3) . . . .
C8 C9 C10 C11 0.1(3) . . . .
C9 C10 C11 C12 -0.4(3) . . . .
C10 C11 C12 C7 0.7(3) . . . .
C8 C7 C12 C11 -0.7(3) . . . .
Sn C7 C12 C11 177.51(15) . . . .
C18 C13 C14 C15 -0.7(3) . . . .
Sn C13 C14 C15 172.97(16) . . . .
C13 C14 C15 C16 0.3(3) . . . .
C14 C15 C16 C17 0.2(3) . . . .
C15 C16 C17 C18 -0.2(3) . . . .
C16 C17 C18 C13 -0.3(3) . . . .
C14 C13 C18 C17 0.8(3) . . . .
Sn C13 C18 C17 -172.91(16) . . . .
C24 C19 C20 C21 -0.5(3) . . . .
As C19 C20 C21 177.97(16) . . . .
C19 C20 C21 C22 -0.7(3) . . . .
C20 C21 C22 C23 1.1(3) . . . .
C21 C22 C23 C24 -0.2(3) . . . .
C22 C23 C24 C19 -1.0(3) . . . .
C20 C19 C24 C23 1.4(3) . . . .
As C19 C24 C23 -177.15(15) . . . .
C30 C25 C26 C27 -2.2(3) . . . .
As C25 C26 C27 173.67(15) . . . .
C25 C26 C27 C28 2.0(3) . . . .
C26 C27 C28 C29 0.1(3) . . . .
C27 C28 C29 C30 -2.1(3) . . . .
C28 C29 C30 C25 1.9(3) . . . .
C26 C25 C30 C29 0.3(3) . . . .
As C25 C30 C29 -175.84(15) . . . .
C36 C31 C32 C33 -0.3(3) . . . .
As C31 C32 C33 176.07(15) . . . .
C31 C32 C33 C34 0.0(3) . . . .
C32 C33 C34 C35 0.4(3) . . . .
C33 C34 C35 C36 -0.5(3) . . . .
C32 C31 C36 C35 0.2(3) . . . .
As C31 C36 C35 -176.21(15) . . . .
C34 C35 C36 C31 0.2(3) . . . .
