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#$Date: 2022-11-23 10:55:44 +0200 (Wed, 23 Nov 2022) $
#$Revision: 279495 $
#$URL: file:///home/coder/svn-repositories/cod/cif/8/10/62/8106214.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_8106214
loop_
_publ_author_name
'Kuang, Xiao-Nan'
'Lin, Sen'
'Li, Si-Fan'
'Li, Yue'
'Xin, Xiu-Lan'
'Jin, Qiong-Hua'
_publ_section_title
;
 Crystal structure of a new polymorph of
 bis[μ-1,3-bis(diphenylphosphino)propane-κ2 P:P′-disilver(I)]
 bis(tetrafluoroborate), [Ag(dppp)]2(BF4)2, C54H52Ag2B2F8P4
;
_journal_issue                   4
_journal_name_full
'Zeitschrift für Kristallographie - New Crystal Structures'
_journal_page_first              551
_journal_page_last               553
_journal_paper_doi               10.1515/ncrs-2017-0285
_journal_volume                  233
_journal_year                    2018
_chemical_formula_sum            'C54 H52 Ag2 B2 F8 P4'
_chemical_formula_weight         1214.19
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2014/6
_cell_angle_alpha                100.8240(10)
_cell_angle_beta                 102.185(2)
_cell_angle_gamma                110.470(3)
_cell_formula_units_Z            2
_cell_length_a                   11.4869(4)
_cell_length_b                   12.9118(5)
_cell_length_c                   19.6858(6)
_cell_measurement_reflns_used    8334
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      28.3862
_cell_measurement_theta_min      2.9348
_cell_volume                     2562.32(17)
_computing_cell_refinement       'Bruker FRAMBO [1]'
_computing_data_collection       'Bruker FRAMBO [1]'
_computing_data_reduction        'Bruker SAINT [1]'
_computing_molecular_graphics    'Bruker SHELXTL [2]'
_computing_publication_material  'Bruker SHELXTL [2]'
_computing_structure_refinement  'SHELXL-2014/6 [2]'
_computing_structure_solution    'SHELXS-2014 [2]'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.976
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Bruker Smart CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0193
_diffrn_reflns_av_unetI/netI     0.0313
_diffrn_reflns_Laue_measured_fraction_full 0.976
_diffrn_reflns_Laue_measured_fraction_max 0.998
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_number            16198
_diffrn_reflns_point_group_measured_fraction_full 0.976
_diffrn_reflns_point_group_measured_fraction_max 0.998
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         25.019
_diffrn_reflns_theta_min         2.941
_exptl_absorpt_coefficient_mu    0.955
_exptl_absorpt_correction_T_max  0.7129
_exptl_absorpt_correction_T_min  0.6841
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.574
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1224
_exptl_crystal_size_max          0.430
_exptl_crystal_size_mid          0.400
_exptl_crystal_size_min          0.380
_refine_diff_density_max         0.509
_refine_diff_density_min         -0.513
_refine_diff_density_rms         0.066
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.059
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     631
_refine_ls_number_reflns         9051
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.059
_refine_ls_R_factor_all          0.0328
_refine_ls_R_factor_gt           0.0263
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0268P)²+1.2898P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0624
_refine_ls_wR_factor_ref         0.0666
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                7937
_reflns_number_total             9051
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            suppl_ncrs-2017-0285_suppl.cif
_cod_data_source_block           e
_cod_original_cell_volume        2562.31(16)
_cod_database_code               8106214
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.684
_shelx_estimated_absorpt_t_max   0.713
_shelxl_version_number           2014/6
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.38326(2) -0.14484(2) 0.05264(2) 0.01712(6) Uani 1 1 d . . . . .
Ag2 Ag 0.37532(2) 0.34918(2) 0.54432(2) 0.01759(6) Uani 1 1 d . . . . .
F1 F 0.61249(15) 0.95548(13) 0.01256(8) 0.0292(4) Uani 1 1 d . . . . .
F2 F 0.75579(17) 0.95568(18) 0.11149(9) 0.0496(5) Uani 1 1 d . . . . .
F3 F 0.76073(18) 0.88128(17) -0.00083(9) 0.0478(5) Uani 1 1 d . . . . .
F4 F 0.59187(17) 0.78949(15) 0.03978(11) 0.0503(5) Uani 1 1 d . . . . .
F5 F 0.42260(16) 0.74094(14) 0.49485(10) 0.0411(4) Uani 1 1 d . . . . .
F6 F 0.38281(17) 0.55591(14) 0.49048(9) 0.0394(4) Uani 1 1 d . . . . .
F7 F 0.21642(16) 0.60629(16) 0.44633(10) 0.0489(5) Uani 1 1 d . . . . .
F8 F 0.31553(19) 0.65901(19) 0.56727(10) 0.0554(6) Uani 1 1 d . . . . .
P1 P 0.42184(6) -0.01546(5) 0.16703(3) 0.01442(13) Uani 1 1 d . . . . .
P2 P 0.73604(6) 0.29339(5) 0.05995(3) 0.01371(13) Uani 1 1 d . . . . .
P3 P 0.24449(6) 0.21244(5) 0.42887(3) 0.01350(13) Uani 1 1 d . . . . .
P4 P 0.55174(6) 0.54181(5) 0.33084(3) 0.01443(13) Uani 1 1 d . . . . .
B1 B 0.6826(3) 0.8955(3) 0.04083(16) 0.0238(7) Uani 1 1 d . . . . .
B2 B 0.3316(3) 0.6396(3) 0.49932(16) 0.0238(6) Uani 1 1 d . . . . .
C1 C 0.4879(2) 0.1364(2) 0.16801(13) 0.0170(5) Uani 1 1 d . . . . .
H1A H 0.4212 0.1516 0.1375 0.020 Uiso 1 1 calc R U . . .
H1B H 0.5114 0.1848 0.2170 0.020 Uiso 1 1 calc R U . . .
C2 C 0.6071(2) 0.1674(2) 0.14119(13) 0.0171(5) Uani 1 1 d . . . . .
H2A H 0.5893 0.1088 0.0970 0.021 Uiso 1 1 calc R U . . .
H2B H 0.6798 0.1684 0.1773 0.021 Uiso 1 1 calc R U . . .
C3 C 0.6449(2) 0.2855(2) 0.12630(13) 0.0175(5) Uani 1 1 d . . . . .
H3A H 0.6980 0.3460 0.1711 0.021 Uiso 1 1 calc R U . . .
H3B H 0.5669 0.2976 0.1079 0.021 Uiso 1 1 calc R U . . .
C4 C 0.2655(2) -0.0368(2) 0.18321(12) 0.0154(5) Uani 1 1 d . . . . .
C5 C 0.2296(2) -0.0793(2) 0.23894(12) 0.0177(5) Uani 1 1 d . . . . .
H5 H 0.2894 -0.0920 0.2726 0.021 Uiso 1 1 calc R U . . .
C6 C 0.1052(2) -0.1028(2) 0.24456(13) 0.0203(5) Uani 1 1 d . . . . .
H6 H 0.0821 -0.1312 0.2820 0.024 Uiso 1 1 calc R U . . .
C7 C 0.0157(2) -0.0844(2) 0.19508(13) 0.0210(5) Uani 1 1 d . . . . .
H7 H -0.0680 -0.1014 0.1987 0.025 Uiso 1 1 calc R U . . .
C8 C 0.0507(2) -0.0403(2) 0.13950(14) 0.0223(6) Uani 1 1 d . . . . .
H8 H -0.0089 -0.0260 0.1067 0.027 Uiso 1 1 calc R U . . .
C9 C 0.1739(2) -0.0178(2) 0.13314(13) 0.0202(5) Uani 1 1 d . . . . .
H9 H 0.1964 0.0101 0.0954 0.024 Uiso 1 1 calc R U . . .
C10 C 0.5254(2) -0.0234(2) 0.24735(12) 0.0168(5) Uani 1 1 d . . . . .
C11 C 0.5841(2) -0.1017(2) 0.24111(14) 0.0224(6) Uani 1 1 d . . . . .
H11 H 0.5700 -0.1495 0.1958 0.027 Uiso 1 1 calc R U . . .
C12 C 0.6634(3) -0.1079(2) 0.30258(15) 0.0284(6) Uani 1 1 d . . . . .
H12 H 0.7030 -0.1595 0.2983 0.034 Uiso 1 1 calc R U . . .
C13 C 0.6840(3) -0.0377(2) 0.37047(14) 0.0290(6) Uani 1 1 d . . . . .
H13 H 0.7358 -0.0435 0.4116 0.035 Uiso 1 1 calc R U . . .
C14 C 0.6277(3) 0.0406(3) 0.37694(14) 0.0291(6) Uani 1 1 d . . . . .
H14 H 0.6423 0.0883 0.4224 0.035 Uiso 1 1 calc R U . . .
C15 C 0.5495(2) 0.0482(2) 0.31591(13) 0.0231(6) Uani 1 1 d . . . . .
H15 H 0.5125 0.1018 0.3206 0.028 Uiso 1 1 calc R U . . .
C16 C 0.7784(2) 0.4398(2) 0.05292(12) 0.0171(5) Uani 1 1 d . . . . .
C17 C 0.9053(2) 0.5151(2) 0.06265(13) 0.0202(5) Uani 1 1 d . . . . .
H17 H 0.9733 0.4921 0.0745 0.024 Uiso 1 1 calc R U . . .
C18 C 0.9309(3) 0.6245(2) 0.05468(13) 0.0235(6) Uani 1 1 d . . . . .
H18 H 1.0161 0.6745 0.0612 0.028 Uiso 1 1 calc R U . . .
C19 C 0.8313(3) 0.6600(2) 0.03716(14) 0.0265(6) Uani 1 1 d . . . . .
H19 H 0.8492 0.7338 0.0322 0.032 Uiso 1 1 calc R U . . .
C20 C 0.7051(3) 0.5856(2) 0.02699(17) 0.0352(7) Uani 1 1 d . . . . .
H20 H 0.6377 0.6093 0.0151 0.042 Uiso 1 1 calc R U . . .
C21 C 0.6781(3) 0.4760(2) 0.03427(16) 0.0314(7) Uani 1 1 d . . . . .
H21 H 0.5924 0.4260 0.0267 0.038 Uiso 1 1 calc R U . . .
C22 C 0.8882(2) 0.2873(2) 0.10408(13) 0.0163(5) Uani 1 1 d . . . . .
C23 C 0.9350(2) 0.2182(2) 0.06524(14) 0.0214(6) Uani 1 1 d . . . . .
H23 H 0.8883 0.1750 0.0174 0.026 Uiso 1 1 calc R U . . .
C24 C 1.0522(3) 0.2135(2) 0.09802(16) 0.0298(7) Uani 1 1 d . . . . .
H24 H 1.0847 0.1684 0.0718 0.036 Uiso 1 1 calc R U . . .
C25 C 1.1199(3) 0.2752(2) 0.16885(16) 0.0325(7) Uani 1 1 d . . . . .
H25 H 1.1977 0.2711 0.1906 0.039 Uiso 1 1 calc R U . . .
C26 C 1.0735(3) 0.3436(2) 0.20832(16) 0.0342(7) Uani 1 1 d . . . . .
H26 H 1.1197 0.3850 0.2565 0.041 Uiso 1 1 calc R U . . .
C27 C 0.9586(3) 0.3501(2) 0.17610(14) 0.0249(6) Uani 1 1 d . . . . .
H27 H 0.9277 0.3965 0.2025 0.030 Uiso 1 1 calc R U . . .
C28 C 0.3278(2) 0.2303(2) 0.35919(12) 0.0160(5) Uani 1 1 d . . . . .
H28A H 0.4023 0.2105 0.3704 0.019 Uiso 1 1 calc R U . . .
H28B H 0.2689 0.1790 0.3123 0.019 Uiso 1 1 calc R U . . .
C29 C 0.3733(2) 0.3556(2) 0.35626(13) 0.0161(5) Uani 1 1 d . . . . .
H29A H 0.4114 0.4068 0.4053 0.019 Uiso 1 1 calc R U . . .
H29B H 0.2984 0.3687 0.3332 0.019 Uiso 1 1 calc R U . . .
C30 C 0.4737(2) 0.3855(2) 0.31466(12) 0.0162(5) Uani 1 1 d . . . . .
H30A H 0.4308 0.3485 0.2632 0.019 Uiso 1 1 calc R U . . .
H30B H 0.5393 0.3568 0.3302 0.019 Uiso 1 1 calc R U . . .
C31 C 0.1989(2) 0.0616(2) 0.42733(12) 0.0152(5) Uani 1 1 d . . . . .
C32 C 0.2952(3) 0.0181(2) 0.43240(12) 0.0200(5) Uani 1 1 d . . . . .
H32 H 0.3795 0.0651 0.4349 0.024 Uiso 1 1 calc R U . . .
C33 C 0.2648(3) -0.0954(2) 0.43374(13) 0.0244(6) Uani 1 1 d . . . . .
H33 H 0.3283 -0.1248 0.4358 0.029 Uiso 1 1 calc R U . . .
C34 C 0.1411(3) -0.1649(2) 0.43210(13) 0.0284(6) Uani 1 1 d . . . . .
H34 H 0.1217 -0.2404 0.4338 0.034 Uiso 1 1 calc R U . . .
C35 C 0.0456(3) -0.1220(2) 0.42792(14) 0.0291(6) Uani 1 1 d . . . . .
H35 H -0.0380 -0.1688 0.4266 0.035 Uiso 1 1 calc R U . . .
C36 C 0.0749(3) -0.0086(2) 0.42577(13) 0.0219(6) Uani 1 1 d . . . . .
H36 H 0.0107 0.0201 0.4233 0.026 Uiso 1 1 calc R U . . .
C37 C 0.0937(2) 0.2266(2) 0.39349(13) 0.0164(5) Uani 1 1 d . . . . .
C38 C 0.0089(2) 0.1593(2) 0.32467(14) 0.0234(6) Uani 1 1 d . . . . .
H38 H 0.0294 0.1057 0.2966 0.028 Uiso 1 1 calc R U . . .
C39 C -0.1052(3) 0.1718(2) 0.29788(16) 0.0309(7) Uani 1 1 d . . . . .
H39 H -0.1614 0.1267 0.2520 0.037 Uiso 1 1 calc R U . . .
C40 C -0.1354(3) 0.2514(3) 0.33947(17) 0.0335(7) Uani 1 1 d . . . . .
H40 H -0.2121 0.2598 0.3215 0.040 Uiso 1 1 calc R U . . .
C41 C -0.0527(3) 0.3185(3) 0.40751(17) 0.0351(7) Uani 1 1 d . . . . .
H41 H -0.0740 0.3718 0.4353 0.042 Uiso 1 1 calc R U . . .
C42 C 0.0620(3) 0.3067(2) 0.43446(15) 0.0258(6) Uani 1 1 d . . . . .
H42 H 0.1181 0.3526 0.4802 0.031 Uiso 1 1 calc R U . . .
C43 C 0.6915(2) 0.5632(2) 0.29675(12) 0.0175(5) Uani 1 1 d . . . . .
C44 C 0.7877(2) 0.5332(2) 0.33311(14) 0.0237(6) Uani 1 1 d . . . . .
H44 H 0.7744 0.4984 0.3697 0.028 Uiso 1 1 calc R U . . .
C45 C 0.9021(3) 0.5547(2) 0.31525(15) 0.0290(6) Uani 1 1 d . . . . .
H45 H 0.9654 0.5340 0.3394 0.035 Uiso 1 1 calc R U . . .
C46 C 0.9219(3) 0.6075(2) 0.26094(16) 0.0334(7) Uani 1 1 d . . . . .
H46 H 0.9995 0.6235 0.2493 0.040 Uiso 1 1 calc R U . . .
C47 C 0.8280(3) 0.6364(2) 0.22436(15) 0.0299(6) Uani 1 1 d . . . . .
H47 H 0.8415 0.6703 0.1874 0.036 Uiso 1 1 calc R U . . .
C48 C 0.7127(3) 0.6152(2) 0.24211(13) 0.0221(6) Uani 1 1 d . . . . .
H48 H 0.6497 0.6358 0.2174 0.027 Uiso 1 1 calc R U . . .
C49 C 0.4351(2) 0.5789(2) 0.27357(13) 0.0192(5) Uani 1 1 d . . . . .
C50 C 0.3919(3) 0.5376(2) 0.19812(14) 0.0263(6) Uani 1 1 d . . . . .
H50 H 0.4233 0.4889 0.1743 0.032 Uiso 1 1 calc R U . . .
C51 C 0.3007(3) 0.5700(3) 0.15848(15) 0.0365(7) Uani 1 1 d . . . . .
H51 H 0.2728 0.5441 0.1081 0.044 Uiso 1 1 calc R U . . .
C52 C 0.2522(3) 0.6404(3) 0.19427(17) 0.0360(7) Uani 1 1 d . . . . .
H52 H 0.1923 0.6624 0.1678 0.043 Uiso 1 1 calc R U . . .
C53 C 0.2919(3) 0.6780(2) 0.26855(16) 0.0312(7) Uani 1 1 d . . . . .
H53 H 0.2569 0.7234 0.2922 0.037 Uiso 1 1 calc R U . . .
C54 C 0.3838(2) 0.6487(2) 0.30852(14) 0.0239(6) Uani 1 1 d . . . . .
H54 H 0.4115 0.6758 0.3589 0.029 Uiso 1 1 calc R U . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
B B 0.0013 0.0007 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
P1 Ag1 P2 158.75(2) . 2_655
P4 Ag2 P3 162.76(2) 2_666 .
C10 P1 C4 106.65(10) . .
C10 P1 C1 105.68(11) . .
C4 P1 C1 103.00(10) . .
C10 P1 Ag1 118.60(8) . .
C4 P1 Ag1 108.63(8) . .
C1 P1 Ag1 112.99(8) . .
C22 P2 C16 105.96(11) . .
C22 P2 C3 105.82(11) . .
C16 P2 C3 103.93(11) . .
C22 P2 Ag1 112.78(8) . 2_655
C16 P2 Ag1 114.77(8) . 2_655
C3 P2 Ag1 112.74(8) . 2_655
C37 P3 C31 106.08(11) . .
C37 P3 C28 105.09(11) . .
C31 P3 C28 104.91(10) . .
C37 P3 Ag2 112.87(8) . .
C31 P3 Ag2 115.00(7) . .
C28 P3 Ag2 112.06(8) . .
C49 P4 C43 109.21(11) . .
C49 P4 C30 105.72(11) . .
C43 P4 C30 104.27(11) . .
C49 P4 Ag2 113.39(8) . 2_666
C43 P4 Ag2 109.43(8) . 2_666
C30 P4 Ag2 114.33(8) . 2_666
F3 B1 F2 110.8(2) . .
F3 B1 F4 111.3(2) . .
F2 B1 F4 108.7(2) . .
F3 B1 F1 109.3(2) . .
F2 B1 F1 109.5(2) . .
F4 B1 F1 107.2(2) . .
F7 B2 F8 111.2(2) . .
F7 B2 F5 109.5(2) . .
F8 B2 F5 108.7(3) . .
F7 B2 F6 111.0(2) . .
F8 B2 F6 108.9(2) . .
F5 B2 F6 107.4(2) . .
C2 C1 P1 111.93(16) . .
C2 C1 H1A 109.2 . .
P1 C1 H1A 109.2 . .
C2 C1 H1B 109.2 . .
P1 C1 H1B 109.2 . .
H1A C1 H1B 107.9 . .
C1 C2 C3 112.01(19) . .
C1 C2 H2A 109.2 . .
C3 C2 H2A 109.2 . .
C1 C2 H2B 109.2 . .
C3 C2 H2B 109.2 . .
H2A C2 H2B 107.9 . .
C2 C3 P2 110.40(16) . .
C2 C3 H3A 109.6 . .
P2 C3 H3A 109.6 . .
C2 C3 H3B 109.6 . .
P2 C3 H3B 109.6 . .
H3A C3 H3B 108.1 . .
C5 C4 C9 118.9(2) . .
C5 C4 P1 123.20(18) . .
C9 C4 P1 117.71(17) . .
C6 C5 C4 120.3(2) . .
C6 C5 H5 119.8 . .
C4 C5 H5 119.8 . .
C7 C6 C5 120.5(2) . .
C7 C6 H6 119.8 . .
C5 C6 H6 119.8 . .
C6 C7 C8 119.9(2) . .
C6 C7 H7 120.1 . .
C8 C7 H7 120.1 . .
C9 C8 C7 119.9(2) . .
C9 C8 H8 120.0 . .
C7 C8 H8 120.0 . .
C8 C9 C4 120.5(2) . .
C8 C9 H9 119.8 . .
C4 C9 H9 119.8 . .
C15 C10 C11 118.9(2) . .
C15 C10 P1 121.29(18) . .
C11 C10 P1 119.84(18) . .
C12 C11 C10 119.9(2) . .
C12 C11 H11 120.1 . .
C10 C11 H11 120.1 . .
C11 C12 C13 120.5(2) . .
C11 C12 H12 119.8 . .
C13 C12 H12 119.8 . .
C14 C13 C12 120.0(2) . .
C14 C13 H13 120.0 . .
C12 C13 H13 120.0 . .
C13 C14 C15 120.0(2) . .
C13 C14 H14 120.0 . .
C15 C14 H14 120.0 . .
C14 C15 C10 120.8(2) . .
C14 C15 H15 119.6 . .
C10 C15 H15 119.6 . .
C17 C16 C21 118.8(2) . .
C17 C16 P2 122.91(18) . .
C21 C16 P2 118.26(19) . .
C18 C17 C16 120.2(2) . .
C18 C17 H17 119.9 . .
C16 C17 H17 119.9 . .
C19 C18 C17 120.6(2) . .
C19 C18 H18 119.7 . .
C17 C18 H18 119.7 . .
C20 C19 C18 119.6(2) . .
C20 C19 H19 120.2 . .
C18 C19 H19 120.2 . .
C19 C20 C21 120.4(2) . .
C19 C20 H20 119.8 . .
C21 C20 H20 119.8 . .
C20 C21 C16 120.4(3) . .
C20 C21 H21 119.8 . .
C16 C21 H21 119.8 . .
C23 C22 C27 119.4(2) . .
C23 C22 P2 119.09(19) . .
C27 C22 P2 121.52(19) . .
C22 C23 C24 119.8(2) . .
C22 C23 H23 120.1 . .
C24 C23 H23 120.1 . .
C25 C24 C23 120.1(3) . .
C25 C24 H24 119.9 . .
C23 C24 H24 119.9 . .
C24 C25 C26 120.5(3) . .
C24 C25 H25 119.7 . .
C26 C25 H25 119.7 . .
C27 C26 C25 119.8(3) . .
C27 C26 H26 120.1 . .
C25 C26 H26 120.1 . .
C26 C27 C22 120.3(2) . .
C26 C27 H27 119.8 . .
C22 C27 H27 119.8 . .
C29 C28 P3 109.77(16) . .
C29 C28 H28A 109.7 . .
P3 C28 H28A 109.7 . .
C29 C28 H28B 109.7 . .
P3 C28 H28B 109.7 . .
H28A C28 H28B 108.2 . .
C28 C29 C30 112.74(19) . .
C28 C29 H29A 109.0 . .
C30 C29 H29A 109.0 . .
C28 C29 H29B 109.0 . .
C30 C29 H29B 109.0 . .
H29A C29 H29B 107.8 . .
C29 C30 P4 110.47(16) . .
C29 C30 H30A 109.6 . .
P4 C30 H30A 109.6 . .
C29 C30 H30B 109.6 . .
P4 C30 H30B 109.6 . .
H30A C30 H30B 108.1 . .
C36 C31 C32 119.3(2) . .
C36 C31 P3 122.22(18) . .
C32 C31 P3 118.39(18) . .
C33 C32 C31 119.9(2) . .
C33 C32 H32 120.1 . .
C31 C32 H32 120.1 . .
C34 C33 C32 120.5(2) . .
C34 C33 H33 119.7 . .
C32 C33 H33 119.7 . .
C33 C34 C35 119.9(2) . .
C33 C34 H34 120.1 . .
C35 C34 H34 120.1 . .
C34 C35 C36 120.0(3) . .
C34 C35 H35 120.0 . .
C36 C35 H35 120.0 . .
C31 C36 C35 120.4(2) . .
C31 C36 H36 119.8 . .
C35 C36 H36 119.8 . .
C42 C37 C38 119.0(2) . .
C42 C37 P3 119.98(19) . .
C38 C37 P3 121.02(19) . .
C39 C38 C37 120.5(2) . .
C39 C38 H38 119.7 . .
C37 C38 H38 119.7 . .
C40 C39 C38 119.7(3) . .
C40 C39 H39 120.2 . .
C38 C39 H39 120.2 . .
C41 C40 C39 120.5(2) . .
C41 C40 H40 119.7 . .
C39 C40 H40 119.7 . .
C40 C41 C42 120.0(3) . .
C40 C41 H41 120.0 . .
C42 C41 H41 120.0 . .
C41 C42 C37 120.3(3) . .
C41 C42 H42 119.9 . .
C37 C42 H42 119.9 . .
C48 C43 C44 118.9(2) . .
C48 C43 P4 124.61(19) . .
C44 C43 P4 116.22(18) . .
C45 C44 C43 120.7(2) . .
C45 C44 H44 119.7 . .
C43 C44 H44 119.7 . .
C44 C45 C46 119.5(3) . .
C44 C45 H45 120.3 . .
C46 C45 H45 120.3 . .
C47 C46 C45 120.5(2) . .
C47 C46 H46 119.8 . .
C45 C46 H46 119.8 . .
C46 C47 C48 120.4(2) . .
C46 C47 H47 119.8 . .
C48 C47 H47 119.8 . .
C47 C48 C43 120.0(2) . .
C47 C48 H48 120.0 . .
C43 C48 H48 120.0 . .
C50 C49 C54 119.5(2) . .
C50 C49 P4 123.5(2) . .
C54 C49 P4 116.98(19) . .
C49 C50 C51 119.5(3) . .
C49 C50 H50 120.2 . .
C51 C50 H50 120.2 . .
C52 C51 C50 120.0(3) . .
C52 C51 H51 120.0 . .
C50 C51 H51 120.0 . .
C53 C52 C51 120.3(3) . .
C53 C52 H52 119.9 . .
C51 C52 H52 119.9 . .
C52 C53 C54 120.5(3) . .
C52 C53 H53 119.8 . .
C54 C53 H53 119.8 . .
C53 C54 C49 120.2(2) . .
C53 C54 H54 119.9 . .
C49 C54 H54 119.9 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 P1 2.3887(6) .
Ag1 P2 2.3983(6) 2_655
Ag2 P4 2.3937(6) 2_666
Ag2 P3 2.3949(6) .
F1 B1 1.403(3) .
F2 B1 1.374(3) .
F3 B1 1.371(3) .
F4 B1 1.394(3) .
F5 B2 1.392(3) .
F6 B2 1.401(3) .
F7 B2 1.369(3) .
F8 B2 1.377(3) .
P1 C10 1.811(2) .
P1 C4 1.825(2) .
P1 C1 1.832(2) .
P2 C22 1.816(2) .
P2 C16 1.820(2) .
P2 C3 1.834(2) .
P2 Ag1 2.3984(6) 2_655
P3 C37 1.811(2) .
P3 C31 1.823(2) .
P3 C28 1.836(2) .
P4 C49 1.819(2) .
P4 C43 1.821(2) .
P4 C30 1.830(2) .
P4 Ag2 2.3937(6) 2_666
C1 C2 1.522(3) .
C1 H1A 0.9700 .
C1 H1B 0.9700 .
C2 C3 1.536(3) .
C2 H2A 0.9700 .
C2 H2B 0.9700 .
C3 H3A 0.9700 .
C3 H3B 0.9700 .
C4 C5 1.390(3) .
C4 C9 1.405(3) .
C5 C6 1.387(3) .
C5 H5 0.9300 .
C6 C7 1.378(3) .
C6 H6 0.9300 .
C7 C8 1.394(3) .
C7 H7 0.9300 .
C8 C9 1.379(3) .
C8 H8 0.9300 .
C9 H9 0.9300 .
C10 C15 1.396(3) .
C10 C11 1.398(3) .
C11 C12 1.387(4) .
C11 H11 0.9300 .
C12 C13 1.387(4) .
C12 H12 0.9300 .
C13 C14 1.379(4) .
C13 H13 0.9300 .
C14 C15 1.382(3) .
C14 H14 0.9300 .
C15 H15 0.9300 .
C16 C17 1.388(3) .
C16 C21 1.394(3) .
C17 C18 1.385(3) .
C17 H17 0.9300 .
C18 C19 1.377(4) .
C18 H18 0.9300 .
C19 C20 1.377(4) .
C19 H19 0.9300 .
C20 C21 1.382(4) .
C20 H20 0.9300 .
C21 H21 0.9300 .
C22 C23 1.387(3) .
C22 C27 1.395(3) .
C23 C24 1.391(3) .
C23 H23 0.9300 .
C24 C25 1.369(4) .
C24 H24 0.9300 .
C25 C26 1.383(4) .
C25 H25 0.9300 .
C26 C27 1.377(4) .
C26 H26 0.9300 .
C27 H27 0.9300 .
C28 C29 1.533(3) .
C28 H28A 0.9700 .
C28 H28B 0.9700 .
C29 C30 1.534(3) .
C29 H29A 0.9700 .
C29 H29B 0.9700 .
C30 H30A 0.9700 .
C30 H30B 0.9700 .
C31 C36 1.386(3) .
C31 C32 1.400(3) .
C32 C33 1.390(3) .
C32 H32 0.9300 .
C33 C34 1.380(4) .
C33 H33 0.9300 .
C34 C35 1.386(4) .
C34 H34 0.9300 .
C35 C36 1.394(4) .
C35 H35 0.9300 .
C36 H36 0.9300 .
C37 C42 1.388(3) .
C37 C38 1.395(3) .
C38 C39 1.382(3) .
C38 H38 0.9300 .
C39 C40 1.378(4) .
C39 H39 0.9300 .
C40 C41 1.378(4) .
C40 H40 0.9300 .
C41 C42 1.385(4) .
C41 H41 0.9300 .
C42 H42 0.9300 .
C43 C48 1.391(3) .
C43 C44 1.398(3) .
C44 C45 1.380(4) .
C44 H44 0.9300 .
C45 C46 1.388(4) .
C45 H45 0.9300 .
C46 C47 1.369(4) .
C46 H46 0.9300 .
C47 C48 1.389(4) .
C47 H47 0.9300 .
C48 H48 0.9300 .
C49 C50 1.394(3) .
C49 C54 1.394(4) .
C50 C51 1.401(4) .
C50 H50 0.9300 .
C51 C52 1.384(4) .
C51 H51 0.9300 .
C52 C53 1.371(4) .
C52 H52 0.9300 .
C53 C54 1.384(3) .
C53 H53 0.9300 .
C54 H54 0.9300 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
C10 P1 C1 C2 79.22(18) . . . .
C4 P1 C1 C2 -169.05(16) . . . .
Ag1 P1 C1 C2 -52.03(18) . . . .
P1 C1 C2 C3 167.67(16) . . . .
C1 C2 C3 P2 -155.44(17) . . . .
C22 P2 C3 C2 -65.93(19) . . . .
C16 P2 C3 C2 -177.32(16) . . . .
Ag1 P2 C3 C2 57.78(17) 2_655 . . .
C10 P1 C4 C5 -14.3(2) . . . .
C1 P1 C4 C5 -125.3(2) . . . .
Ag1 P1 C4 C5 114.64(19) . . . .
C10 P1 C4 C9 170.91(19) . . . .
C1 P1 C4 C9 59.9(2) . . . .
Ag1 P1 C4 C9 -60.2(2) . . . .
C9 C4 C5 C6 0.3(4) . . . .
P1 C4 C5 C6 -174.47(18) . . . .
C4 C5 C6 C7 0.0(4) . . . .
C5 C6 C7 C8 -0.9(4) . . . .
C6 C7 C8 C9 1.6(4) . . . .
C7 C8 C9 C4 -1.3(4) . . . .
C5 C4 C9 C8 0.4(4) . . . .
P1 C4 C9 C8 175.42(19) . . . .
C4 P1 C10 C15 -55.8(2) . . . .
C1 P1 C10 C15 53.3(2) . . . .
Ag1 P1 C10 C15 -178.69(17) . . . .
C4 P1 C10 C11 124.9(2) . . . .
C1 P1 C10 C11 -125.9(2) . . . .
Ag1 P1 C10 C11 2.1(2) . . . .
C15 C10 C11 C12 0.8(4) . . . .
P1 C10 C11 C12 -180.0(2) . . . .
C10 C11 C12 C13 0.6(4) . . . .
C11 C12 C13 C14 -1.4(4) . . . .
C12 C13 C14 C15 0.8(4) . . . .
C13 C14 C15 C10 0.6(4) . . . .
C11 C10 C15 C14 -1.4(4) . . . .
P1 C10 C15 C14 179.3(2) . . . .
C22 P2 C16 C17 15.0(2) . . . .
C3 P2 C16 C17 126.3(2) . . . .
Ag1 P2 C16 C17 -110.2(2) 2_655 . . .
C22 P2 C16 C21 -167.5(2) . . . .
C3 P2 C16 C21 -56.2(2) . . . .
Ag1 P2 C16 C21 67.4(2) 2_655 . . .
C21 C16 C17 C18 0.7(4) . . . .
P2 C16 C17 C18 178.28(19) . . . .
C16 C17 C18 C19 0.1(4) . . . .
C17 C18 C19 C20 -0.5(4) . . . .
C18 C19 C20 C21 0.0(4) . . . .
C19 C20 C21 C16 0.8(5) . . . .
C17 C16 C21 C20 -1.2(4) . . . .
P2 C16 C21 C20 -178.8(2) . . . .
C16 P2 C22 C23 -113.4(2) . . . .
C3 P2 C22 C23 136.61(19) . . . .
Ag1 P2 C22 C23 12.9(2) 2_655 . . .
C16 P2 C22 C27 66.9(2) . . . .
C3 P2 C22 C27 -43.1(2) . . . .
Ag1 P2 C22 C27 -166.78(18) 2_655 . . .
C27 C22 C23 C24 -1.0(4) . . . .
P2 C22 C23 C24 179.30(18) . . . .
C22 C23 C24 C25 1.3(4) . . . .
C23 C24 C25 C26 -0.7(4) . . . .
C24 C25 C26 C27 -0.3(4) . . . .
C25 C26 C27 C22 0.6(4) . . . .
C23 C22 C27 C26 0.1(4) . . . .
P2 C22 C27 C26 179.8(2) . . . .
C37 P3 C28 C29 69.33(18) . . . .
C31 P3 C28 C29 -179.04(16) . . . .
Ag2 P3 C28 C29 -53.60(17) . . . .
P3 C28 C29 C30 164.81(16) . . . .
C28 C29 C30 P4 -166.79(16) . . . .
C49 P4 C30 C29 -78.18(18) . . . .
C43 P4 C30 C29 166.72(16) . . . .
Ag2 P4 C30 C29 47.27(18) 2_666 . . .
C37 P3 C31 C36 -21.5(2) . . . .
C28 P3 C31 C36 -132.4(2) . . . .
Ag2 P3 C31 C36 104.04(19) . . . .
C37 P3 C31 C32 162.54(18) . . . .
C28 P3 C31 C32 51.6(2) . . . .
Ag2 P3 C31 C32 -71.96(19) . . . .
C36 C31 C32 C33 1.8(3) . . . .
P3 C31 C32 C33 177.93(18) . . . .
C31 C32 C33 C34 -1.8(4) . . . .
C32 C33 C34 C35 1.0(4) . . . .
C33 C34 C35 C36 -0.3(4) . . . .
C32 C31 C36 C35 -1.1(4) . . . .
P3 C31 C36 C35 -177.10(19) . . . .
C34 C35 C36 C31 0.4(4) . . . .
C31 P3 C37 C42 123.7(2) . . . .
C28 P3 C37 C42 -125.5(2) . . . .
Ag2 P3 C37 C42 -3.1(2) . . . .
C31 P3 C37 C38 -57.5(2) . . . .
C28 P3 C37 C38 53.3(2) . . . .
Ag2 P3 C37 C38 175.73(17) . . . .
C42 C37 C38 C39 -0.4(4) . . . .
P3 C37 C38 C39 -179.23(19) . . . .
C37 C38 C39 C40 0.1(4) . . . .
C38 C39 C40 C41 0.0(4) . . . .
C39 C40 C41 C42 0.3(4) . . . .
C40 C41 C42 C37 -0.6(4) . . . .
C38 C37 C42 C41 0.7(4) . . . .
P3 C37 C42 C41 179.5(2) . . . .
C49 P4 C43 C48 8.4(2) . . . .
C30 P4 C43 C48 121.0(2) . . . .
Ag2 P4 C43 C48 -116.3(2) 2_666 . . .
C49 P4 C43 C44 -177.12(19) . . . .
C30 P4 C43 C44 -64.5(2) . . . .
Ag2 P4 C43 C44 58.2(2) 2_666 . . .
C48 C43 C44 C45 0.0(4) . . . .
P4 C43 C44 C45 -174.8(2) . . . .
C43 C44 C45 C46 0.5(4) . . . .
C44 C45 C46 C47 -1.1(4) . . . .
C45 C46 C47 C48 1.3(4) . . . .
C46 C47 C48 C43 -0.7(4) . . . .
C44 C43 C48 C47 0.1(4) . . . .
P4 C43 C48 C47 174.45(19) . . . .
C43 P4 C49 C50 49.3(2) . . . .
C30 P4 C49 C50 -62.4(2) . . . .
Ag2 P4 C49 C50 171.58(19) 2_666 . . .
C43 P4 C49 C54 -133.32(19) . . . .
C30 P4 C49 C54 115.0(2) . . . .
Ag2 P4 C49 C54 -11.0(2) 2_666 . . .
C54 C49 C50 C51 2.0(4) . . . .
P4 C49 C50 C51 179.4(2) . . . .
C49 C50 C51 C52 -1.3(4) . . . .
C50 C51 C52 C53 -0.6(4) . . . .
C51 C52 C53 C54 1.9(4) . . . .
C52 C53 C54 C49 -1.2(4) . . . .
C50 C49 C54 C53 -0.8(4) . . . .
P4 C49 C54 C53 -178.3(2) . . . .
