#------------------------------------------------------------------------------
#$Date: 2023-05-12 10:38:34 +0300 (Fri, 12 May 2023) $
#$Revision: 283713 $
#$URL: file:///home/coder/svn-repositories/cod/cif/8/10/71/8107184.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_8107184
loop_
_publ_author_name
'Zhang, Xiao-Yu'
'Liu, Xin-Fang'
'Zhao, Bei-Bei'
'Huang, Shi-Jie'
_publ_section_title
;
 Crystal structure of
 diaqua-bis(μ2-2-carboxy-3,4,5,6-tetrafluorobenzoato-κ2
 O:O′)-bis(phenanthroline-κ2
 N,N′)-bis(μ2-3,4,5,6-tetrafluorophthalato-κ3
 O:O,O′)dieuropium(III) -- phenanthroline (1/2), C40H19EuF8N4O9
;
_journal_issue                   4
_journal_name_full
'Zeitschrift für Kristallographie - New Crystal Structures'
_journal_page_first              671
_journal_page_last               674
_journal_paper_doi               10.1515/ncrs-2022-0089
_journal_volume                  237
_journal_year                    2022
_chemical_formula_moiety         'C28 H11 Eu F8 N2 O9, C12 H8 N2'
_chemical_formula_sum            'C40 H19 Eu F8 N4 O9'
_chemical_formula_weight         1003.55
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     dual
_cell_angle_alpha                102.266(2)
_cell_angle_beta                 97.689(2)
_cell_angle_gamma                105.630(3)
_cell_formula_units_Z            2
_cell_length_a                   11.3326(4)
_cell_length_b                   12.7652(4)
_cell_length_c                   13.2629(4)
_cell_measurement_reflns_used    8786
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      29.1110
_cell_measurement_theta_min      3.9000
_cell_volume                     1767.93(11)
_computing_cell_refinement       'CrysAlisPro 1.171.41.121a (Rigaku OD, 2021)'
_computing_data_collection       'CrysAlisPro 1.171.41.121a (Rigaku OD, 2021)'
_computing_data_reduction        'CrysAlisPro 1.171.41.121a (Rigaku OD, 2021)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'ShelXT (Sheldrick, 2015)'
_diffrn_ambient_temperature      293(2)
_diffrn_detector                 'CCD plate'
_diffrn_detector_area_resol_mean 8.0584
_diffrn_detector_type            EosS2
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.839
_diffrn_measurement_details
;
List of Runs (angles in degrees, time in seconds):

  # Type    Start    End  Width  tₑₓₚ   ω     θ     κ     φ   Frames
--------------------------------------------------------------------------
  1  ω      0.00  45.00   1.00    1.48    --   16.93  57.00 150.00   45
  2  ω    -10.00  42.00   1.00    1.48    --   16.93  77.00-120.00   52
  3  ω    -10.00  21.00   1.00    1.48    --   16.93  77.00  30.00   31
  4  ω    -50.00  34.00   1.00    1.48    --   16.93 -57.00 -90.00   84
  5  ω    -44.00  21.00   1.00    1.48    --   16.93 -57.00 150.00   65
  6  ω      5.00  38.00   1.00    1.48    --   16.93  77.00  60.00   33
  7  ω    -41.00  36.00   1.00    1.48    --   16.93 -38.00   0.00   77
;
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'SuperNova, Single source at offset/far, EosS2'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_type
'CrysAlisPro convention (1999,Acta A55,543-557)'
_diffrn_orient_matrix_UB_11      0.0135603000
_diffrn_orient_matrix_UB_12      0.0310538000
_diffrn_orient_matrix_UB_13      0.0535240000
_diffrn_orient_matrix_UB_21      -0.0444386000
_diffrn_orient_matrix_UB_22      -0.0445621000
_diffrn_orient_matrix_UB_23      0.0114542000
_diffrn_orient_matrix_UB_31      0.0474019000
_diffrn_orient_matrix_UB_32      -0.0249226000
_diffrn_orient_matrix_UB_33      0.0113144000
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0356
_diffrn_reflns_av_unetI/netI     0.0591
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.839
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            15476
_diffrn_reflns_point_group_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.839
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         29.311
_diffrn_reflns_theta_min         3.375
_diffrn_source                   'micro-focus sealed X-ray tube'
_diffrn_source_type              'SuperNova (Mo) X-ray Source'
_exptl_absorpt_coefficient_mu    1.884
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.72959
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlisPro 1.171.41.121a (Rigaku Oxford Diffraction, 2021)
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            'clear colourless'
_exptl_crystal_colour_lustre     clear
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.885
_exptl_crystal_description       block
_exptl_crystal_F_000             988
_exptl_crystal_size_max          0.2
_exptl_crystal_size_mid          0.19
_exptl_crystal_size_min          0.18
_refine_diff_density_max         0.806
_refine_diff_density_min         -0.737
_refine_diff_density_rms         0.098
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.035
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     561
_refine_ls_number_reflns         8124
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.035
_refine_ls_R_factor_all          0.0378
_refine_ls_R_factor_gt           0.0329
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0192P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0619
_refine_ls_wR_factor_ref         0.0648
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                7356
_reflns_number_total             8124
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            suppl_j_ncrs-2022-0089_suppl.cif
_cod_data_source_block           eu-sf-lfll_auto
_cod_original_cell_volume        1767.93(10)
_cod_database_code               8107184
_chemical_oxdiff_formula         'C1 H1 O1 F1 N1 Eu1 '
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_max   0.728
_shelx_estimated_absorpt_t_min   0.704
_reflns_odcompleteness_completeness 99.79
_reflns_odcompleteness_iscentric 1
_reflns_odcompleteness_theta     26.32
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All O(H) groups, All O(H,H) groups
2.a Rotating group:
 O9(H9A,H9B)
2.b Aromatic/amide H refined with riding coordinates:
 C17(H17), C18(H18), C19(H19), C20(H20), C21(H21), C22(H22), C23(H23),
 C24(H24), C29(H29), C30(H30), C31(H31), C32(H32), C33(H33), C34(H34), C35(H35),
  C36(H36)
2.c Idealised tetrahedral OH refined as rotating group:
 O2(H2)
;
_olex2_submission_special_instructions 'No special instructions were received'
_oxdiff_exptl_absorpt_empirical_details
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
;
_oxdiff_exptl_absorpt_empirical_full_max 1.279
_oxdiff_exptl_absorpt_empirical_full_min 0.610
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.41561(2) 0.83464(2) 0.44811(2) 0.01876(5) Uani 1 1 d . . . . .
F1 F 0.46047(18) 0.79923(18) 0.99321(15) 0.0493(5) Uani 1 1 d . . . . .
F2 F 0.70361(19) 0.87105(17) 1.08322(14) 0.0460(5) Uani 1 1 d . . . . .
F3 F 0.86950(19) 1.01006(19) 1.00351(17) 0.0581(6) Uani 1 1 d . . . . .
F4 F 0.79489(17) 1.07238(17) 0.83285(15) 0.0444(5) Uani 1 1 d . . . . .
F5 F 0.17521(18) 1.12051(16) 0.31939(15) 0.0432(5) Uani 1 1 d . . . . .
F6 F -0.04741(18) 0.99019(18) 0.20795(14) 0.0452(5) Uani 1 1 d . . . . .
F7 F -0.17454(18) 0.80717(18) 0.26702(16) 0.0535(6) Uani 1 1 d . . . . .
F8 F -0.06679(18) 0.74943(17) 0.43103(17) 0.0501(5) Uani 1 1 d . . . . .
O1 O 0.3065(2) 0.7466(2) 0.7838(2) 0.0502(7) Uani 1 1 d . . . . .
O2 O 0.3219(2) 0.9269(2) 0.78681(18) 0.0407(6) Uani 1 1 d . . . . .
H2 H 0.2585 0.9008 0.7403 0.061 Uiso 1 1 calc GR . . . .
O3 O 0.49453(19) 0.88944(16) 0.63749(15) 0.0252(5) Uani 1 1 d . . . . .
O4 O 0.5758(2) 1.07722(17) 0.69839(16) 0.0300(5) Uani 1 1 d . . . . .
O5 O 0.3492(2) 1.17246(17) 0.50666(17) 0.0322(5) Uani 1 1 d . . . . .
O6 O 0.38206(17) 1.01242(16) 0.51217(15) 0.0221(4) Uani 1 1 d . . . . .
O7 O 0.1417(2) 0.8916(2) 0.63660(17) 0.0390(6) Uani 1 1 d . . . . .
O8 O 0.23770(18) 0.80148(17) 0.52914(16) 0.0268(5) Uani 1 1 d . . . . .
O9 O 0.22775(19) 0.75510(18) 0.31263(16) 0.0321(5) Uani 1 1 d . . . . .
H9A H 0.1898 0.6823 0.3082 0.048 Uiso 1 1 d GR . . . .
H9B H 0.2464 0.7512 0.2488 0.048 Uiso 1 1 d GR . . . .
N1 N 0.3694(2) 0.63497(19) 0.46945(19) 0.0238(5) Uani 1 1 d . . . . .
N2 N 0.4643(2) 0.6908(2) 0.30306(19) 0.0250(6) Uani 1 1 d . . . . .
C1 C 0.5858(3) 0.9623(2) 0.8163(2) 0.0229(6) Uani 1 1 d . . . . .
C2 C 0.4994(3) 0.8915(2) 0.8583(2) 0.0245(7) Uani 1 1 d . . . . .
C3 C 0.5413(3) 0.8650(3) 0.9493(2) 0.0285(7) Uani 1 1 d . . . . .
C4 C 0.6646(3) 0.9028(3) 0.9981(2) 0.0317(8) Uani 1 1 d . . . . .
C5 C 0.7484(3) 0.9727(3) 0.9584(3) 0.0342(8) Uani 1 1 d . . . . .
C6 C 0.7078(3) 1.0036(3) 0.8688(2) 0.0286(7) Uani 1 1 d . . . . .
C7 C 0.5471(3) 0.9781(2) 0.7070(2) 0.0218(6) Uani 1 1 d . . . . .
C8 C 0.3637(3) 0.8447(3) 0.8053(2) 0.0302(7) Uani 1 1 d . . . . .
C9 C 0.1773(3) 1.0028(2) 0.4353(2) 0.0219(6) Uani 1 1 d . . . . .
C10 C 0.1139(3) 0.9047(3) 0.4619(2) 0.0235(6) Uani 1 1 d . . . . .
C11 C -0.0040(3) 0.8430(3) 0.4064(3) 0.0299(7) Uani 1 1 d . . . . .
C12 C -0.0600(3) 0.8717(3) 0.3214(2) 0.0321(8) Uani 1 1 d . . . . .
C13 C 0.0022(3) 0.9648(3) 0.2933(2) 0.0302(7) Uani 1 1 d . . . . .
C14 C 0.1176(3) 1.0302(3) 0.3509(2) 0.0270(7) Uani 1 1 d . . . . .
C15 C 0.3093(3) 1.0691(2) 0.4884(2) 0.0215(6) Uani 1 1 d . . . . .
C16 C 0.1702(3) 0.8630(2) 0.5501(2) 0.0253(7) Uani 1 1 d . . . . .
C17 C 0.3238(3) 0.6063(3) 0.5500(3) 0.0335(8) Uani 1 1 d . . . . .
H17 H 0.3120 0.6623 0.6015 0.040 Uiso 1 1 calc R . . . .
C18 C 0.2925(3) 0.4967(3) 0.5619(3) 0.0369(8) Uani 1 1 d . . . . .
H18 H 0.2599 0.4808 0.6196 0.044 Uiso 1 1 calc R . . . .
C19 C 0.3101(3) 0.4143(3) 0.4888(3) 0.0363(8) Uani 1 1 d . . . . .
H19 H 0.2908 0.3412 0.4963 0.044 Uiso 1 1 calc R . . . .
C20 C 0.3813(3) 0.3570(3) 0.3217(3) 0.0428(9) Uani 1 1 d . . . . .
H20 H 0.3631 0.2828 0.3260 0.051 Uiso 1 1 calc R . . . .
C21 C 0.4289(3) 0.3851(3) 0.2418(3) 0.0448(10) Uani 1 1 d . . . . .
H21 H 0.4432 0.3298 0.1911 0.054 Uiso 1 1 calc R . . . .
C22 C 0.5131(3) 0.5309(3) 0.1499(3) 0.0444(9) Uani 1 1 d . . . . .
H22 H 0.5301 0.4783 0.0984 0.053 Uiso 1 1 calc R . . . .
C23 C 0.5408(3) 0.6399(3) 0.1465(3) 0.0439(9) Uani 1 1 d . . . . .
H23 H 0.5768 0.6627 0.0926 0.053 Uiso 1 1 calc R . . . .
C24 C 0.5151(3) 0.7173(3) 0.2241(3) 0.0355(8) Uani 1 1 d . . . . .
H24 H 0.5347 0.7918 0.2205 0.043 Uiso 1 1 calc R . . . .
C25 C 0.4374(3) 0.5815(2) 0.3077(2) 0.0248(7) Uani 1 1 d . . . . .
C26 C 0.3863(3) 0.5513(2) 0.3944(2) 0.0237(6) Uani 1 1 d . . . . .
C27 C 0.3575(3) 0.4393(3) 0.4019(3) 0.0302(7) Uani 1 1 d . . . . .
C28 C 0.4588(3) 0.4978(3) 0.2310(2) 0.0326(8) Uani 1 1 d . . . . .
N3 N 0.1721(3) 0.6067(2) 0.1003(2) 0.0401(7) Uani 1 1 d . . . . .
N4 N 0.0919(3) 0.5328(2) 0.2676(2) 0.0404(7) Uani 1 1 d . . . . .
C29 C 0.0470(4) 0.4953(4) 0.3439(3) 0.0522(10) Uani 1 1 d . . . . .
H29 H 0.0420 0.5479 0.4023 0.063 Uiso 1 1 calc R . . . .
C30 C 0.0064(4) 0.3823(4) 0.3430(3) 0.0601(12) Uani 1 1 d . . . . .
H30 H -0.0270 0.3600 0.3982 0.072 Uiso 1 1 calc R . . . .
C31 C 0.0168(4) 0.3055(4) 0.2600(4) 0.0560(11) Uani 1 1 d . . . . .
H31 H -0.0068 0.2295 0.2586 0.067 Uiso 1 1 calc R . . . .
C32 C 0.0727(4) 0.2634(3) 0.0852(4) 0.0589(12) Uani 1 1 d . . . . .
H32 H 0.0525 0.1872 0.0827 0.071 Uiso 1 1 calc R . . . .
C33 C 0.1101(4) 0.2983(3) 0.0034(3) 0.0600(12) Uani 1 1 d . . . . .
H33 H 0.1142 0.2459 -0.0555 0.072 Uiso 1 1 calc R . . . .
C34 C 0.1772(4) 0.4547(4) -0.0818(3) 0.0580(12) Uani 1 1 d . . . . .
H34 H 0.1787 0.4042 -0.1431 0.070 Uiso 1 1 calc R . . . .
C35 C 0.2069(4) 0.5661(4) -0.0758(3) 0.0600(12) Uani 1 1 d . . . . .
H35 H 0.2289 0.5933 -0.1327 0.072 Uiso 1 1 calc R . . . .
C36 C 0.2039(4) 0.6390(3) 0.0175(3) 0.0506(10) Uani 1 1 d . . . . .
H36 H 0.2259 0.7156 0.0215 0.061 Uiso 1 1 calc R . . . .
C37 C 0.1404(3) 0.4954(3) 0.0947(3) 0.0340(8) Uani 1 1 d . . . . .
C38 C 0.0991(3) 0.4565(3) 0.1818(3) 0.0327(8) Uani 1 1 d . . . . .
C39 C 0.0630(3) 0.3407(3) 0.1762(3) 0.0419(9) Uani 1 1 d . . . . .
C40 C 0.1438(3) 0.4150(3) 0.0047(3) 0.0436(9) Uani 1 1 d . . . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O3 Eu1 Eu1 68.94(5) . 2_676
O3 Eu1 O4 137.88(7) . 2_676
O3 Eu1 O5 68.99(7) . 2_676
O3 Eu1 O6 71.84(7) . 2_676
O3 Eu1 N1 84.13(7) . .
O3 Eu1 N2 129.13(7) . .
O3 Eu1 C15 65.77(7) . 2_676
O4 Eu1 Eu1 69.14(5) 2_676 2_676
O4 Eu1 O5 101.52(7) 2_676 2_676
O4 Eu1 O6 71.57(7) 2_676 2_676
O4 Eu1 N1 136.39(7) 2_676 .
O4 Eu1 N2 76.51(7) 2_676 .
O4 Eu1 C15 88.57(8) 2_676 2_676
O5 Eu1 Eu1 82.47(4) 2_676 2_676
O5 Eu1 C15 24.65(6) 2_676 2_676
O6 Eu1 Eu1 34.65(4) 2_676 2_676
O6 Eu1 Eu1 36.10(5) . 2_676
O6 Eu1 O3 74.12(6) . .
O6 Eu1 O4 74.71(6) . 2_676
O6 Eu1 O5 116.73(6) . 2_676
O6 Eu1 O5 49.90(6) 2_676 2_676
O6 Eu1 O6 70.75(7) . 2_676
O6 Eu1 O9 96.18(7) . .
O6 Eu1 N1 143.23(7) . .
O6 Eu1 N1 129.93(7) 2_676 .
O6 Eu1 N2 151.16(7) . .
O6 Eu1 N2 98.36(7) 2_676 .
O6 Eu1 C15 93.24(7) . 2_676
O6 Eu1 C15 25.49(6) 2_676 2_676
O8 Eu1 Eu1 104.59(5) . 2_676
O8 Eu1 O3 73.02(7) . .
O8 Eu1 O4 122.16(7) . 2_676
O8 Eu1 O5 135.62(7) . 2_676
O8 Eu1 O6 134.29(6) . 2_676
O8 Eu1 O6 72.21(6) . .
O8 Eu1 O9 70.90(7) . .
O8 Eu1 N1 73.25(7) . .
O8 Eu1 N2 126.58(8) . .
O8 Eu1 C15 138.68(7) . 2_676
O9 Eu1 Eu1 122.23(5) . 2_676
O9 Eu1 O3 143.88(7) . .
O9 Eu1 O4 67.12(7) . 2_676
O9 Eu1 O5 141.61(7) . 2_676
O9 Eu1 O6 138.65(7) . 2_676
O9 Eu1 N1 84.10(8) . .
O9 Eu1 N2 74.09(7) . .
O9 Eu1 C15 150.35(8) . 2_676
N1 Eu1 Eu1 152.01(5) . 2_676
N1 Eu1 O5 80.78(7) . 2_676
N1 Eu1 N2 64.09(8) . .
N1 Eu1 C15 104.55(8) . 2_676
N2 Eu1 Eu1 128.19(6) . 2_676
N2 Eu1 O5 67.55(7) . 2_676
N2 Eu1 C15 84.20(7) . 2_676
C15 Eu1 Eu1 58.04(5) 2_676 2_676
C8 O2 H2 109.5 . .
C7 O3 Eu1 137.06(19) . .
C7 O4 Eu1 135.46(19) . 2_676
C15 O5 Eu1 90.13(16) . 2_676
Eu1 O6 Eu1 109.25(7) . 2_676
C15 O6 Eu1 140.13(18) . .
C15 O6 Eu1 98.16(17) . 2_676
C16 O8 Eu1 128.90(19) . .
Eu1 O9 H9A 112.4 . .
Eu1 O9 H9B 110.6 . .
H9A O9 H9B 101.7 . .
C17 N1 Eu1 122.16(19) . .
C17 N1 C26 117.3(3) . .
C26 N1 Eu1 120.51(18) . .
C24 N2 Eu1 123.7(2) . .
C24 N2 C25 117.4(3) . .
C25 N2 Eu1 118.89(19) . .
C2 C1 C7 120.0(3) . .
C6 C1 C2 118.3(3) . .
C6 C1 C7 121.1(3) . .
C1 C2 C8 120.9(3) . .
C3 C2 C1 118.8(3) . .
C3 C2 C8 120.3(3) . .
F1 C3 C2 120.5(3) . .
F1 C3 C4 117.4(3) . .
C4 C3 C2 122.2(3) . .
F2 C4 C3 120.9(3) . .
F2 C4 C5 120.0(3) . .
C5 C4 C3 119.1(3) . .
F3 C5 C4 120.6(3) . .
F3 C5 C6 119.6(3) . .
C4 C5 C6 119.8(3) . .
F4 C6 C1 121.1(3) . .
F4 C6 C5 117.1(3) . .
C1 C6 C5 121.7(3) . .
O3 C7 O4 128.6(3) . .
O3 C7 C1 114.6(3) . .
O4 C7 C1 116.8(3) . .
O1 C8 O2 127.3(3) . .
O1 C8 C2 123.1(3) . .
O2 C8 C2 109.6(3) . .
C10 C9 C15 121.5(3) . .
C14 C9 C10 117.7(3) . .
C14 C9 C15 120.6(3) . .
C9 C10 C16 123.1(3) . .
C11 C10 C9 119.2(3) . .
C11 C10 C16 117.8(3) . .
F8 C11 C10 120.2(3) . .
F8 C11 C12 118.1(3) . .
C10 C11 C12 121.6(3) . .
F7 C12 C11 119.9(3) . .
F7 C12 C13 120.6(3) . .
C13 C12 C11 119.5(3) . .
F6 C13 C12 120.4(3) . .
F6 C13 C14 120.0(3) . .
C12 C13 C14 119.6(3) . .
F5 C14 C9 120.5(3) . .
F5 C14 C13 117.1(3) . .
C13 C14 C9 122.3(3) . .
O5 C15 Eu1 65.22(16) . 2_676
O5 C15 O6 120.7(3) . .
O5 C15 C9 122.8(2) . .
O6 C15 Eu1 56.35(14) . 2_676
O6 C15 C9 116.5(2) . .
C9 C15 Eu1 166.48(18) . 2_676
O7 C16 O8 126.1(3) . .
O7 C16 C10 115.9(2) . .
O8 C16 C10 118.0(3) . .
N1 C17 H17 118.1 . .
N1 C17 C18 123.7(3) . .
C18 C17 H17 118.1 . .
C17 C18 H18 120.4 . .
C19 C18 C17 119.2(3) . .
C19 C18 H18 120.4 . .
C18 C19 H19 120.1 . .
C18 C19 C27 119.7(3) . .
C27 C19 H19 120.1 . .
C21 C20 H20 119.5 . .
C21 C20 C27 121.1(3) . .
C27 C20 H20 119.5 . .
C20 C21 H21 119.0 . .
C20 C21 C28 122.0(3) . .
C28 C21 H21 119.0 . .
C23 C22 H22 120.2 . .
C23 C22 C28 119.7(3) . .
C28 C22 H22 120.2 . .
C22 C23 H23 120.3 . .
C22 C23 C24 119.4(3) . .
C24 C23 H23 120.3 . .
N2 C24 C23 123.5(3) . .
N2 C24 H24 118.3 . .
C23 C24 H24 118.3 . .
N2 C25 C26 118.6(3) . .
N2 C25 C28 122.4(3) . .
C28 C25 C26 119.0(3) . .
N1 C26 C25 117.8(3) . .
N1 C26 C27 122.0(3) . .
C27 C26 C25 120.2(3) . .
C19 C27 C20 123.2(3) . .
C19 C27 C26 118.1(3) . .
C26 C27 C20 118.7(3) . .
C22 C28 C21 123.3(3) . .
C22 C28 C25 117.5(3) . .
C25 C28 C21 119.1(3) . .
C36 N3 C37 117.9(3) . .
C29 N4 C38 118.3(3) . .
N4 C29 H29 117.9 . .
N4 C29 C30 124.2(4) . .
C30 C29 H29 117.9 . .
C29 C30 H30 120.8 . .
C31 C30 C29 118.4(4) . .
C31 C30 H30 120.8 . .
C30 C31 H31 120.1 . .
C30 C31 C39 119.7(4) . .
C39 C31 H31 120.1 . .
C33 C32 H32 119.4 . .
C33 C32 C39 121.3(4) . .
C39 C32 H32 119.4 . .
C32 C33 H33 119.4 . .
C32 C33 C40 121.1(4) . .
C40 C33 H33 119.4 . .
C35 C34 H34 120.0 . .
C35 C34 C40 120.1(4) . .
C40 C34 H34 120.0 . .
C34 C35 H35 120.9 . .
C34 C35 C36 118.3(4) . .
C36 C35 H35 120.9 . .
N3 C36 C35 124.3(4) . .
N3 C36 H36 117.9 . .
C35 C36 H36 117.9 . .
N3 C37 C38 119.4(3) . .
N3 C37 C40 122.1(3) . .
C40 C37 C38 118.5(3) . .
N4 C38 C37 119.0(3) . .
N4 C38 C39 121.0(3) . .
C39 C38 C37 120.0(3) . .
C31 C39 C32 122.3(4) . .
C31 C39 C38 118.4(4) . .
C38 C39 C32 119.3(4) . .
C34 C40 C33 123.0(4) . .
C34 C40 C37 117.2(4) . .
C37 C40 C33 119.8(4) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Eu1 Eu1 3.9814(3) 2_676
Eu1 O3 2.4317(19) .
Eu1 O4 2.444(2) 2_676
Eu1 O5 2.683(2) 2_676
Eu1 O6 2.3976(17) .
Eu1 O6 2.485(2) 2_676
Eu1 O8 2.3900(19) .
Eu1 O9 2.414(2) .
Eu1 N1 2.545(2) .
Eu1 N2 2.590(2) .
Eu1 C15 2.955(3) 2_676
F1 C3 1.349(3) .
F2 C4 1.338(3) .
F3 C5 1.333(4) .
F4 C6 1.345(3) .
F5 C14 1.342(3) .
F6 C13 1.336(3) .
F7 C12 1.343(3) .
F8 C11 1.346(3) .
O1 C8 1.196(4) .
O2 H2 0.8200 .
O2 C8 1.315(4) .
O3 C7 1.238(3) .
O4 Eu1 2.444(2) 2_676
O4 C7 1.252(3) .
O5 Eu1 2.683(2) 2_676
O5 C15 1.232(3) .
O6 Eu1 2.485(2) 2_676
O6 C15 1.285(3) .
O7 C16 1.240(3) .
O8 C16 1.252(3) .
O9 H9A 0.8976 .
O9 H9B 0.8947 .
N1 C17 1.324(4) .
N1 C26 1.370(3) .
N2 C24 1.322(4) .
N2 C25 1.361(4) .
C1 C2 1.403(4) .
C1 C6 1.367(4) .
C1 C7 1.529(4) .
C2 C3 1.381(4) .
C2 C8 1.501(4) .
C3 C4 1.366(4) .
C4 C5 1.361(5) .
C5 C6 1.389(4) .
C9 C10 1.407(4) .
C9 C14 1.387(4) .
C9 C15 1.494(4) .
C10 C11 1.367(4) .
C10 C16 1.519(4) .
C11 C12 1.384(4) .
C12 C13 1.363(4) .
C13 C14 1.366(4) .
C15 Eu1 2.955(3) 2_676
C17 H17 0.9300 .
C17 C18 1.396(4) .
C18 H18 0.9300 .
C18 C19 1.348(4) .
C19 H19 0.9300 .
C19 C27 1.395(4) .
C20 H20 0.9300 .
C20 C21 1.324(5) .
C20 C27 1.436(4) .
C21 H21 0.9300 .
C21 C28 1.429(5) .
C22 H22 0.9300 .
C22 C23 1.353(5) .
C22 C28 1.394(5) .
C23 H23 0.9300 .
C23 C24 1.387(4) .
C24 H24 0.9300 .
C25 C26 1.434(4) .
C25 C28 1.407(4) .
C26 C27 1.406(4) .
N3 C36 1.312(4) .
N3 C37 1.352(4) .
N4 C29 1.314(4) .
N4 C38 1.359(4) .
C29 H29 0.9300 .
C29 C30 1.388(5) .
C30 H30 0.9300 .
C30 C31 1.351(5) .
C31 H31 0.9300 .
C31 C39 1.397(5) .
C32 H32 0.9300 .
C32 C33 1.335(5) .
C32 C39 1.425(5) .
C33 H33 0.9300 .
C33 C40 1.430(5) .
C34 H34 0.9300 .
C34 C35 1.353(6) .
C34 C40 1.405(5) .
C35 H35 0.9300 .
C35 C36 1.393(5) .
C36 H36 0.9300 .
C37 C38 1.437(4) .
C37 C40 1.411(4) .
C38 C39 1.406(5) .
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
O2 H2 O7 0.82 1.74 2.526(3) 160.4 .
O9 H9A N4 0.90 1.85 2.731(4) 166.1 .
O9 H9B N3 0.89 2.27 2.921(3) 129.1 .
