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#$Date: 2024-04-25 17:59:02 +0300 (Thu, 25 Apr 2024) $
#$Revision: 291351 $
#$URL: file:///home/coder/svn-repositories/cod/cif/9/00/49/9004981.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided the American Mineralogist Crystal Structure Database,
# http://rruff.geo.arizona.edu/AMS/amcsd.php
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_9004981
loop_
_publ_author_name
'Pinto, D.'
'Balic-Zunic T'
'Bonaccorsi, E.'
'Borodaev, Y. S.'
'Garavelli, A.'
'Garbarino, C.'
'Makovicky, E.'
'Mozgova, N. N.'
'Vurro, F.'
_publ_section_title
;Rare sulfosalts from Vulcano, Aeolian Islands, Italy. VII. Cl-bearing
 galenobismutite Locality: Vulcano, Aeolian Islands, Italy Sample: FF-1991a
;
_journal_name_full               'The Canadian Mineralogist'
_journal_page_first              443
_journal_page_last               457
_journal_paper_doi               10.2113/gscanmin.44.2.443
_journal_volume                  44
_journal_year                    2006
_chemical_compound_source        'Vulcano, Aeolian Islands, Italy'
_chemical_formula_sum            'Bi1.85 Cl0.168 Pb1.14 S3.738 Se0.094'
_chemical_name_mineral           Galenobismutite
_space_group_IT_number           62
_symmetry_space_group_name_Hall  '-P 2c 2n'
_symmetry_space_group_name_H-M   'P n a m'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_length_a                   11.832
_cell_length_b                   14.640
_cell_length_c                   4.0817
_cell_formula_units_Z            4
_cell_volume                     707.034
_database_code_amcsd             0006084
_exptl_crystal_density_diffrn    7.103
_cod_original_formula_sum        'Pb1.14 Bi1.85 S3.738 Se.094 Cl.168'
_cod_database_code               9004981
loop_
_space_group_symop_operation_xyz
x,y,z
x,y,1/2-z
-x,-y,1/2+z
1/2-x,1/2+y,1/2+z
1/2+x,1/2-y,1/2-z
1/2+x,1/2-y,z
1/2-x,1/2+y,-z
-x,-y,-z
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
_atom_site_U_iso_or_equiv
PbM3 0.24859 0.65368 0.25000 1.00000 0.03010
BiM1 0.06735 0.38982 0.25000 1.00000 0.02010
BiM2 0.10188 0.90348 0.25000 0.85000 0.02680
PbM2 0.10188 0.90348 0.25000 0.14000 0.02680
S1 0.33714 0.01493 0.25000 0.89500 0.02200
Se1 0.33714 0.01493 0.25000 0.06300 0.02200
Cl1 0.33714 0.01493 0.25000 0.04200 0.02200
S2 0.25920 0.29667 0.25000 0.95800 0.01570
Cl2 0.25920 0.29667 0.25000 0.04200 0.01570
S3 0.05640 0.09310 0.25000 0.94500 0.01900
Se3 0.05640 0.09310 0.25000 0.01300 0.01900
Cl3 0.05640 0.09310 0.25000 0.04200 0.01900
S4 0.01770 0.71200 0.25000 0.94000 0.01700
Se4 0.01770 0.71200 0.25000 0.01800 0.01700
Cl4 0.01770 0.71200 0.25000 0.04200 0.01700
loop_
_cod_related_entry_id
_cod_related_entry_database
_cod_related_entry_code
1 AMCSD 0006084
