Crystallography Open Database

Information card for entry 1572023

1572022 << 1572023 >> 1572024

Preview

Coordinates	1572023.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C104 H96 Cl2 P4 Rh2
Calculated formula	C104 H96 Cl2 P4 Rh2
Title of publication	Intermolecular C-H silylations of arenes and heteroarenes with mono-, bis-, and tris(trimethylsiloxy)hydrosilanes: control of silane redistribution under operationally diverse approaches.
Authors of publication	Swann, Noah; Tang, Kiki; Nam, Jihyeon; Lee, Jooyeon; Domin, Marek; Shaw, Thomas E.; Kozimor, Stosh A.; Som, Salina; Lee, Kangsang L.
Journal of publication	Chemical science
Year of publication	2024
Journal volume	15
Journal issue	30
Pages of publication	11912 - 11918
a	14.3389 ± 0.0008 Å
b	23.8027 ± 0.0013 Å
c	24.6313 ± 0.0013 Å
α	90°
β	90°
γ	90°
Cell volume	8406.8 ± 0.8 Å³
Cell temperature	100 K
Ambient diffraction temperature	100 K
Number of distinct elements	5
Space group number	19
Hermann-Mauguin space group symbol	P 21 21 21
Hall space group symbol	P 2ac 2ab
Residual factor for all reflections	0.0625
Residual factor for significantly intense reflections	0.0434
Weighted residual factors for significantly intense reflections	0.0945
Weighted residual factors for all reflections included in the refinement	0.1035
Goodness-of-fit parameter for all reflections included in the refinement	1.019
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
293774 (current)	2024-08-05	cif/ Updating files of 1572023 Original log message: Adding full bibliography for 1572023.cif.	1572023.cif
292667	2024-07-02	cif/ Adding structures of 1572023 via cif-deposit CGI script.	1572023.cif