#------------------------------------------------------------------------------ #$Date: 2024-11-21 01:07:56 +0200 (Thu, 21 Nov 2024) $ #$Revision: 296017 $ #$URL: file:///home/coder/svn-repositories/cod/cif/1/57/32/1573215.cif $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/ # # All data on this site have been placed in the public domain by the # contributors. # data_1573215 loop_ _publ_author_name 'Xu, Zurong' 'Zhu, Dong' 'Wu, Rui' 'Zhu, Shifa' _publ_section_title ; Tandem Rh(II)-catalyzed 1,3-acyloxy migration/intermolecular [2+2] cycloaddition of electronically deficient propargylic esters with alkenes and alkynes ; _journal_name_full 'Chemical Science' _journal_paper_doi 10.1039/D4SC06458E _journal_year 2024 _chemical_formula_moiety 'C16 H14 O5' _chemical_formula_sum 'C16 H14 O5' _chemical_formula_weight 286.27 _space_group_crystal_system monoclinic _space_group_IT_number 4 _space_group_name_Hall 'P 2yb' _space_group_name_H-M_alt 'P 1 21 1' _atom_sites_solution_hydrogens geom _atom_sites_solution_primary dual _audit_creation_date 2021-11-27 _audit_creation_method ; Olex2 1.3 (compiled 2020.11.12 svn.r5f609507 for OlexSys, GUI svn.r6408) ; _audit_update_record ; 2024-02-27 deposited with the CCDC. 2024-11-18 downloaded from the CCDC. ; _cell_angle_alpha 90 _cell_angle_beta 92.683(5) _cell_angle_gamma 90 _cell_formula_units_Z 2 _cell_length_a 6.7856(4) _cell_length_b 6.0442(4) _cell_length_c 16.6292(9) _cell_measurement_reflns_used 2083 _cell_measurement_temperature 149.99(10) _cell_measurement_theta_max 73.3590 _cell_measurement_theta_min 5.3060 _cell_volume 681.27(7) _computing_cell_refinement 'CrysAlisPro 1.171.38.43f (Rigaku OD, 2015)' _computing_data_collection 'CrysAlisPro 1.171.38.43f (Rigaku OD, 2015)' _computing_data_reduction 'CrysAlisPro 1.171.38.43f (Rigaku OD, 2015)' _computing_molecular_graphics 'Olex2 1.3 (Dolomanov et al., 2009)' _computing_publication_material 'Olex2 1.3 (Dolomanov et al., 2009)' _computing_structure_refinement 'SHELXL 2018/3 (Sheldrick, 2015)' _computing_structure_solution 'SHELXT 2018/2 (Sheldrick, 2018)' _diffrn_ambient_environment N~2~ _diffrn_ambient_temperature 149.99(10) _diffrn_detector 'CCD plate' _diffrn_detector_area_resol_mean 5.2684 _diffrn_detector_type AtlasS2 _diffrn_measured_fraction_theta_full 0.998 _diffrn_measured_fraction_theta_max 0.962 _diffrn_measurement_details ; List of Runs (angles in degrees, time in seconds): # Type Start End Width t~exp~ \w \q \k \f Frames #-------------------------------------------------------------------------- 1 \w -2.00 61.00 1.00 1.00 -- 40.73 -57.00 0.00 63 2 \w 31.00 134.00 1.00 1.00 -- 106.95 -30.00 -90.00 103 3 \w 93.00 119.00 1.00 1.00 -- 106.95-125.00-180.00 26 4 \w 54.00 80.00 1.00 1.00 -- 106.95-125.00-180.00 26 5 \w 26.00 101.00 1.00 1.00 -- 106.95 -95.00 90.00 75 6 \w 86.00 111.00 1.00 1.00 -- 106.95 45.00 90.00 25 7 \w 132.00 164.00 1.00 1.00 -- 106.95 45.00 90.00 32 8 \w 115.00 177.00 1.00 1.00 -- 106.95 125.00 60.00 62 9 \w 94.00 170.00 1.00 1.00 -- 106.95 125.00 0.00 76 10 \w -34.00 3.00 1.00 1.00 -- 40.73 -77.00 150.00 37 11 \w -67.00 31.00 1.00 1.00 -- -40.73 57.00-120.00 98 ; _diffrn_measurement_device 'four-circle diffractometer' _diffrn_measurement_device_type 'SuperNova, Dual, Cu at zero, AtlasS2' _diffrn_measurement_method '\w scans' _diffrn_orient_matrix_type 'CrysAlisPro convention (1999,Acta A55,543-557)' _diffrn_orient_matrix_UB_11 0.0012453000 _diffrn_orient_matrix_UB_12 0.2295785000 _diffrn_orient_matrix_UB_13 0.0402826000 _diffrn_orient_matrix_UB_21 0.0244265000 _diffrn_orient_matrix_UB_22 -0.1101374000 _diffrn_orient_matrix_UB_23 0.0833625000 _diffrn_orient_matrix_UB_31 0.2260592000 _diffrn_orient_matrix_UB_32 0.0107062000 _diffrn_orient_matrix_UB_33 -0.0048817000 _diffrn_radiation_monochromator mirror _diffrn_radiation_probe x-ray _diffrn_radiation_type 'Cu K\a' _diffrn_radiation_wavelength 1.54184 _diffrn_reflns_av_R_equivalents 0.0449 _diffrn_reflns_av_unetI/netI 0.0340 _diffrn_reflns_Laue_measured_fraction_full 0.998 _diffrn_reflns_Laue_measured_fraction_max 0.962 _diffrn_reflns_limit_h_max 8 _diffrn_reflns_limit_h_min -5 _diffrn_reflns_limit_k_max 7 _diffrn_reflns_limit_k_min -6 _diffrn_reflns_limit_l_max 19 _diffrn_reflns_limit_l_min -20 _diffrn_reflns_number 2502 _diffrn_reflns_point_group_measured_fraction_full 0.727 _diffrn_reflns_point_group_measured_fraction_max 0.688 _diffrn_reflns_theta_full 67.684 _diffrn_reflns_theta_max 73.435 _diffrn_reflns_theta_min 2.660 _diffrn_source 'micro-focus sealed X-ray tube' _diffrn_source_type 'SuperNova (Cu) X-ray Source' _exptl_absorpt_coefficient_mu 0.871 _exptl_absorpt_correction_T_max 1.00000 _exptl_absorpt_correction_T_min 0.77547 _exptl_absorpt_correction_type multi-scan _exptl_absorpt_process_details ; CrysAlisPro 1.171.38.43f (Rigaku Oxford Diffraction, 2015) Empirical absorption correction using spherical harmonics, implemented in SCALE3 ABSPACK scaling algorithm. ; _exptl_crystal_colour yellow _exptl_crystal_colour_primary yellow _exptl_crystal_density_diffrn 1.396 _exptl_crystal_description block _exptl_crystal_F_000 300 _exptl_crystal_size_max 0.14 _exptl_crystal_size_mid 0.12 _exptl_crystal_size_min 0.11 _refine_diff_density_max 0.526 _refine_diff_density_min -0.362 _refine_diff_density_rms 0.107 _refine_ls_abs_structure_details ; Flack x determined using 415 quotients [(I+)-(I-)]/[(I+)+(I-)] (Parsons, Flack and Wagner, Acta Cryst. B69 (2013) 249-259). ; _refine_ls_abs_structure_Flack -0.1(3) _refine_ls_extinction_coef 0.0157(18) _refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc^2^\l^3^/sin(2\q)]^-1/4^ _refine_ls_extinction_method 'SHELXL-2018/3 (Sheldrick 2018)' _refine_ls_goodness_of_fit_ref 1.141 _refine_ls_hydrogen_treatment constr _refine_ls_matrix_type full _refine_ls_number_parameters 193 _refine_ls_number_reflns 1897 _refine_ls_number_restraints 1 _refine_ls_restrained_S_all 1.141 _refine_ls_R_factor_all 0.0853 _refine_ls_R_factor_gt 0.0834 _refine_ls_shift/su_max 0.008 _refine_ls_shift/su_mean 0.000 _refine_ls_structure_factor_coef Fsqd _refine_ls_weighting_details 'w=1/[\s^2^(Fo^2^)+(0.0728P)^2^+3.7566P] where P=(Fo^2^+2Fc^2^)/3' _refine_ls_weighting_scheme calc _refine_ls_wR_factor_gt 0.2455 _refine_ls_wR_factor_ref 0.2464 _reflns_Friedel_coverage 0.302 _reflns_Friedel_fraction_full 0.393 _reflns_Friedel_fraction_max 0.355 _reflns_number_gt 1864 _reflns_number_total 1897 _reflns_threshold_expression 'I > 2\s(I)' _cod_data_source_file d4sc06458e2.cif _cod_data_source_block 179-4 _cod_database_code 1573215 _shelx_shelxl_version_number 2018/3 _shelx_space_group_comment ; The symmetry employed for this shelxl refinement is uniquely defined by the following loop, which should always be used as a source of symmetry information in preference to the above space-group names. They are only intended as comments. ; _reflns_odcompleteness_completeness 99.78 _reflns_odcompleteness_iscentric 1 _reflns_odcompleteness_theta 66.97 _olex2_refinement_description ; 1. Fixed Uiso At 1.2 times of: All C(H) groups, All C(H,H) groups At 1.5 times of: All C(H,H,H) groups 2.a Secondary CH2 refined with riding coordinates: C8(H8A,H8B) 2.b Aromatic/amide H refined with riding coordinates: C2(H2), C3(H3), C5(H5), C6(H6), C10(H10), C12(H12) 2.c Idealised Me refined as rotating group: C14(H14A,H14B,H14C), C16(H16A,H16B,H16C) ; _shelx_res_file ; TITL 179-4_a.res in P2(1) 179-4.res created by SHELXL-2018/3 at 17:01:18 on 27-Nov-2021 REM Old TITL 179-4 in P2(1)/m REM SHELXT solution in P2(1): R1 0.123, Rweak 0.059, Alpha 0.002 REM 1.375 for 4 systematic absences, Orientation as input REM Flack x = 0.495 ( 0.296 ) from 433 Parsons' quotients REM Formula found by SHELXT: C16 O5 CELL 1.54184 6.7856 6.0442 16.6292 90 92.683 90 ZERR 2 0.0004 0.0004 0.0009 0 0.005 0 LATT -1 SYMM -X,0.5+Y,-Z SFAC C H O UNIT 32 28 10 L.S. 10 PLAN 5 CONF FREE C9 C7 BOND list 4 fmap 2 53 MORE -1 ACTA BOND $H REM REM REM WGHT 0.072800 3.756600 EXTI 0.015747 FVAR 1.31074 O1 3 -0.202264 0.162998 0.098288 11.00000 0.02292 0.03630 = 0.04148 0.00494 -0.01150 -0.00961 O2 3 -0.236380 0.509711 0.050930 11.00000 0.04398 0.03698 = 0.06343 0.01032 -0.02360 -0.00408 O3 3 1.304919 0.898851 0.366631 11.00000 0.02294 0.03362 = 0.03711 0.00089 -0.00097 -0.00884 O4 3 1.135325 0.484806 0.391086 11.00000 0.02330 0.02514 = 0.02306 -0.00213 -0.00090 0.00395 O5 3 1.142405 0.649408 0.512344 11.00000 0.03538 0.03725 = 0.03161 -0.01072 -0.00253 0.00866 C1 1 0.042573 0.419962 0.136571 11.00000 0.02016 0.02914 = 0.02778 -0.00055 -0.00411 -0.00006 C2 1 0.126764 0.628753 0.131802 11.00000 0.02600 0.02758 = 0.02692 0.00532 -0.00714 0.00339 AFIX 43 H2 2 0.065165 0.737710 0.100148 11.00000 -1.20000 AFIX 0 C3 1 0.303413 0.674733 0.174446 11.00000 0.01813 0.02449 = 0.02812 0.00089 0.00689 -0.00581 AFIX 43 H3 2 0.358220 0.815403 0.171695 11.00000 -1.20000 AFIX 0 C4 1 0.399046 0.512452 0.221199 11.00000 0.01591 0.02798 = 0.02350 -0.00332 0.00397 0.00253 C5 1 0.312045 0.302868 0.226753 11.00000 0.01687 0.02659 = 0.02757 0.00532 -0.00206 0.00073 AFIX 43 H5 2 0.373105 0.193487 0.258377 11.00000 -1.20000 AFIX 0 C6 1 0.134720 0.259256 0.184949 11.00000 0.03224 0.02246 = 0.03442 0.00497 -0.00687 -0.00312 AFIX 43 H6 2 0.076607 0.120689 0.189314 11.00000 -1.20000 AFIX 0 C7 1 0.583734 0.558665 0.265678 11.00000 0.02371 0.02460 = 0.02465 0.00052 -0.00163 -0.00105 C8 1 0.706159 0.768140 0.270937 11.00000 0.01671 0.02838 = 0.02733 0.00275 0.00556 0.00210 AFIX 23 H8A 2 0.645955 0.889548 0.298994 11.00000 -1.20000 H8B 2 0.758111 0.815634 0.220392 11.00000 -1.20000 AFIX 0 C9 1 0.848152 0.624528 0.323785 11.00000 0.02425 0.02346 = 0.02776 0.00160 0.00158 -0.00309 C10 1 0.713189 0.439890 0.313423 11.00000 0.02357 0.02627 = 0.03157 0.00033 0.00459 -0.00176 AFIX 43 H10 2 0.714517 0.295006 0.332269 11.00000 -1.20000 AFIX 0 C11 1 1.027767 0.658561 0.357206 11.00000 0.02361 0.02437 = 0.02247 -0.00041 -0.00333 -0.00391 C12 1 1.127211 0.870575 0.351593 11.00000 0.02378 0.02125 = 0.02966 -0.00156 -0.00067 -0.00172 AFIX 43 H12 2 1.051838 0.992770 0.335619 11.00000 -1.20000 AFIX 0 C13 1 1.199266 0.501196 0.469891 11.00000 0.01962 0.03105 = 0.02962 -0.00135 -0.00109 -0.00866 C14 1 1.339265 0.325035 0.492734 11.00000 0.02551 0.03789 = 0.02935 0.00462 -0.00136 0.00231 AFIX 137 H14A 2 1.274253 0.184241 0.488072 11.00000 -1.50000 H14B 2 1.387466 0.346895 0.547354 11.00000 -1.50000 H14C 2 1.447808 0.328545 0.457744 11.00000 -1.50000 AFIX 0 C15 1 -0.146401 0.376854 0.090416 11.00000 0.01847 0.03543 = 0.03040 -0.00016 -0.00520 0.00038 C16 1 -0.386002 0.101942 0.055948 11.00000 0.02062 0.04761 = 0.03874 0.00582 -0.00914 -0.01262 AFIX 137 H16A 2 -0.387879 0.159758 0.002148 11.00000 -1.50000 H16B 2 -0.494799 0.162001 0.083696 11.00000 -1.50000 H16C 2 -0.396928 -0.056341 0.053978 11.00000 -1.50000 AFIX 0 HKLF 4 REM 179-4_a.res in P2(1) REM wR2 = 0.2464, GooF = S = 1.141, Restrained GooF = 1.141 for all data REM R1 = 0.0834 for 1864 Fo > 4sig(Fo) and 0.0853 for all 1897 data REM 193 parameters refined using 1 restraints END WGHT 0.0725 3.7592 REM Highest difference peak 0.526, deepest hole -0.362, 1-sigma level 0.107 Q1 1 0.9118 0.4811 0.3925 11.00000 0.05 0.53 Q2 1 1.3720 0.6676 0.5174 11.00000 0.05 0.49 Q3 1 1.4388 0.5218 0.4667 11.00000 0.05 0.42 Q4 1 1.4119 0.1671 0.4798 11.00000 0.05 0.42 Q5 1 1.5891 0.3328 0.4966 11.00000 0.05 0.41 ; _shelx_res_checksum 21673 _shelx_hkl_file ; 0 0 1 149.70 1.30 0 0 2 207.92 2.17 0 0 3 110.92 1.94 0 0 4 321.13 3.90 0 0 5 1983.70 11.12 0 0 6 532.92 6.49 0 0 7 4200.86 20.23 0 0 8 798.82 9.82 0 0 9 507.88 8.47 0 0 -10 3.11 0.87 0 0 10 15.53 1.64 0 0 -11 1.67 0.71 0 0 12 2.04 0.76 0 0 -12 1.25 0.63 0 0 13 22.46 2.98 0 0 -13 18.22 2.65 0 0 -14 0.56 0.40 0 0 14 0.86 0.30 0 0 -14 0.42 0.61 0 0 15 1.47 0.81 0 0 -15 1.86 0.85 0 0 -16 2.30 0.82 0 0 -17 1.81 0.82 0 0 -17 1.50 0.73 0 0 -18 4.21 1.29 0 0 -19 13.98 2.21 0 0 -20 31.65 2.79 0 -1 0 0.44 0.19 0 -1 -1 5186.76 18.44 0 -1 -1 5210.39 16.00 0 -1 -2 3360.41 15.42 0 -1 -3 479.97 6.35 0 -1 -4 240.70 4.81 0 -1 -5 1501.67 13.15 0 -1 -6 132.18 4.27 0 1 6 143.06 3.55 0 1 7 1.06 0.34 0 -1 -7 1.62 0.54 0 1 8 563.97 8.21 0 -1 -8 537.06 10.42 0 -1 -9 422.88 10.07 0 1 9 445.91 7.79 0 -1 -10 177.71 7.27 0 1 10 213.15 5.88 0 -1 -11 357.96 11.27 0 -1 -12 932.92 19.85 0 1 12 995.73 17.77 0 1 -12 1045.27 18.26 0 -1 12 1093.01 20.05 0 1 -13 276.77 9.94 0 1 13 289.81 10.21 0 -1 -13 277.12 11.69 0 1 -13 297.24 10.27 0 1 -14 13.13 2.26 0 1 14 12.55 2.25 0 1 -15 54.48 4.91 0 1 15 54.72 4.75 0 1 -15 51.37 4.49 0 1 16 269.39 10.62 0 1 -16 242.68 9.72 0 1 -16 272.47 10.82 0 1 -17 13.19 2.32 0 -1 -17 10.83 2.27 0 1 -17 10.44 1.94 0 1 17 13.94 2.25 0 1 -18 34.36 3.49 0 -1 -18 28.88 3.44 0 -1 -19 6.03 1.44 0 -1 -20 149.02 6.29 0 -2 0 527.18 8.48 0 -2 0 459.27 6.83 0 -2 -1 687.62 8.88 0 -2 -1 717.86 9.34 0 -2 -2 597.65 9.08 0 -2 -2 596.71 8.27 0 -2 -3 1960.45 17.25 0 -2 -4 303.07 7.14 0 -2 -5 462.75 9.33 0 -2 -6 233.88 7.10 0 -2 -7 27.50 2.64 0 -2 -8 65.13 4.24 0 2 8 57.09 2.99 0 2 9 64.48 3.28 0 -2 -9 65.46 4.58 0 -2 -10 92.85 5.84 0 2 10 92.14 4.15 0 2 11 390.62 10.35 0 -2 -11 384.26 12.82 0 -2 -12 376.45 13.37 0 2 12 376.34 10.78 0 2 13 372.70 11.30 0 -2 -13 379.35 14.08 0 2 -13 400.82 13.20 0 2 14 116.83 6.54 0 2 -14 118.96 7.46 0 2 15 202.61 8.64 0 2 -15 188.21 9.26 0 2 16 19.21 2.64 0 -2 -17 15.62 2.62 0 2 17 15.56 2.26 0 -2 -18 39.25 3.90 0 -2 -19 91.08 5.29 0 -3 0 0.07 0.14 0 -3 -1 428.70 8.09 0 -3 -1 435.19 9.31 0 -3 -2 420.24 9.02 0 -3 -2 402.40 8.12 0 -3 -3 775.63 12.77 0 -3 -4 175.17 6.33 0 -3 -5 1271.10 18.27 0 -3 -6 450.50 11.62 0 -3 -7 67.48 4.67 0 -3 -8 158.99 7.65 0 3 9 107.39 5.09 0 3 9 102.84 4.91 0 3 10 116.65 5.22 0 3 10 121.96 5.64 0 3 11 202.03 7.54 0 3 12 176.06 7.41 0 3 13 12.98 2.05 0 3 14 39.88 3.63 0 3 15 1.51 0.71 0 -3 -15 4.74 1.44 0 -3 -16 18.65 2.77 0 3 16 18.65 2.33 0 -3 -17 72.11 5.09 0 3 17 71.06 4.15 0 3 -18 46.85 3.51 0 -3 -18 51.85 3.86 0 -4 0 377.40 10.96 0 -4 1 2.37 0.92 0 -4 -1 1.78 0.75 0 -4 2 115.69 6.40 0 -4 -2 123.12 6.05 0 -4 3 29.16 3.34 0 -4 4 1664.44 26.48 0 4 -5 626.41 17.22 0 -4 5 642.87 17.08 0 -4 6 518.65 15.91 0 4 6 451.72 11.37 0 4 7 85.21 4.88 0 -4 7 103.39 7.28 0 4 8 85.34 4.85 0 -4 8 108.19 7.53 0 4 9 93.13 5.03 0 4 9 89.59 5.16 0 4 10 44.25 3.49 0 4 11 19.12 2.31 0 4 12 66.80 4.41 0 4 13 47.94 3.67 0 4 14 132.65 5.92 0 4 15 92.60 4.55 0 4 -15 85.88 6.03 0 4 -16 34.51 3.42 0 4 16 38.56 2.63 0 4 -17 2.66 0.80 0 5 0 -0.45 0.58 0 -5 0 0.49 0.54 0 -5 1 186.85 9.27 0 5 1 176.38 8.81 0 5 -1 173.31 9.05 0 5 -2 208.55 10.01 0 5 2 220.77 9.57 0 -5 2 229.42 10.51 0 5 3 40.22 3.87 0 5 -3 35.40 4.21 0 -5 3 41.00 4.47 0 5 -4 122.69 7.99 0 5 4 122.55 6.51 0 5 -5 795.34 20.63 0 5 5 790.40 15.94 0 5 -6 724.34 20.08 0 5 6 735.04 14.95 0 5 7 212.12 7.77 0 5 -7 220.92 11.18 0 5 8 58.47 3.96 0 5 -8 71.95 6.38 0 5 -9 69.19 6.21 0 5 9 66.34 4.09 0 5 -10 172.54 9.55 0 5 10 152.39 6.01 0 5 -11 21.52 3.25 0 5 11 22.53 2.27 0 5 -12 54.48 4.96 0 5 12 57.12 3.46 0 5 13 47.37 2.91 0 5 -13 38.91 3.92 0 5 -14 6.22 1.38 0 5 -15 67.89 3.98 0 6 0 199.21 8.73 0 6 -1 39.98 4.05 0 6 1 40.16 3.74 0 6 -2 128.04 7.38 0 6 2 125.49 6.35 0 6 3 58.71 4.13 0 6 -3 58.16 5.01 0 6 4 8.52 1.49 0 6 -4 9.42 2.09 0 6 -4 9.59 2.00 0 6 -5 8.95 1.97 0 6 5 10.75 1.61 0 6 -5 8.90 1.92 0 6 6 30.94 2.58 0 6 -6 28.96 3.52 0 6 7 179.76 5.92 0 6 -7 177.92 8.55 0 6 8 19.17 1.83 0 6 -8 17.51 2.55 0 6 -9 0.75 0.36 0 6 -10 35.42 3.37 0 6 -11 166.78 6.71 0 6 -12 8.13 1.32 0 7 0 0.13 0.05 0 7 -1 3.52 0.74 0 7 -2 90.35 3.80 0 7 -3 28.30 2.13 0 7 -4 21.69 1.83 0 7 -5 6.12 0.92 1 0 -20 0.28 0.38 1 0 -19 41.24 3.85 1 0 -18 49.98 4.80 1 0 -17 7.41 1.90 1 0 -16 39.52 4.41 1 0 -15 63.90 5.61 1 0 -14 16.92 2.85 1 0 -14 16.77 3.00 1 0 -13 190.69 9.49 -1 0 13 147.37 7.51 -1 0 12 16.73 2.37 1 0 -12 7.44 1.71 1 0 -11 64.37 4.67 1 0 -10 0.91 0.59 1 0 -9 1158.67 16.52 1 0 -8 72.16 3.70 -1 0 7 115.48 2.40 1 0 -7 108.82 4.12 -1 0 6 3639.93 11.53 1 0 -6 3582.66 21.45 -1 0 5 3550.32 9.57 1 0 -5 3628.23 19.19 1 0 -3 214.82 3.88 1 0 -2 32.98 1.44 1 0 -1 24.41 0.73 1 0 -1 24.13 1.15 1 0 0 1170.64 6.10 1 0 0 1170.58 7.66 1 0 1 636.23 5.24 1 0 2 1989.44 8.42 1 0 3 0.54 0.17 1 0 4 970.75 9.19 1 0 5 1530.96 12.40 1 0 6 127.41 4.04 1 0 7 15.05 1.48 1 0 8 318.57 7.37 1 0 9 432.26 9.31 1 0 10 190.09 6.62 1 0 11 67.96 4.23 1 0 12 5.50 1.40 -1 0 -12 5.95 1.35 1 0 13 63.16 5.12 -1 0 -13 67.95 4.77 1 0 14 69.46 5.56 1 0 15 1.60 1.01 -1 0 -16 24.04 2.97 1 0 16 21.80 3.11 -1 0 -17 12.51 2.05 -1 0 -18 753.43 14.64 -1 0 -18 752.11 16.44 -1 0 -19 96.81 5.34 -1 0 -19 98.19 4.68 1 -1 -20 2.55 0.82 1 -1 -19 13.67 2.25 1 1 -18 73.41 5.20 1 -1 -18 73.88 5.76 1 1 -17 28.25 3.54 1 -1 -17 28.08 3.80 1 1 -16 117.13 7.48 1 -1 -16 131.76 8.20 1 -1 -15 213.70 10.52 1 1 -15 203.06 9.92 1 1 -14 2.02 0.82 1 1 -14 1.72 0.92 -1 1 14 1.39 0.69 1 -1 -13 258.98 11.58 1 1 -13 243.05 10.22 -1 1 13 236.11 9.09 1 1 -13 233.21 9.13 1 1 -12 48.86 4.01 1 1 -12 41.97 3.71 1 -1 -12 50.74 4.90 -1 1 12 42.07 3.59 1 1 -12 46.45 4.28 1 -1 -11 393.75 12.99 1 1 -11 398.38 10.79 1 -1 -10 379.08 11.95 1 1 -10 401.15 10.19 1 -1 -9 92.78 5.44 1 -1 -8 277.05 8.80 -1 1 8 291.66 4.97 1 -1 -7 278.57 8.03 -1 1 7 278.26 4.44 1 -1 -6 67.49 3.70 1 -1 -5 749.44 11.04 1 -1 -4 4217.52 24.36 1 -1 -3 9999.00 36.24 1 -1 -2 3081.69 19.26 1 -1 -1 699.40 9.12 1 -1 0 529.87 7.70 1 -1 1 241.25 4.74 1 -1 1 250.31 4.73 1 -1 2 588.39 7.70 -1 -1 -2 591.09 4.30 -1 -1 -2 588.68 3.55 -1 -1 -3 374.49 4.14 1 -1 3 380.58 6.87 1 1 4 1312.18 10.81 1 -1 5 520.57 8.60 1 1 5 520.73 7.11 1 -1 6 267.54 6.56 1 1 6 282.01 5.68 -1 -1 -6 270.21 5.53 -1 -1 -7 94.01 3.56 1 1 7 90.84 3.47 1 1 8 933.35 12.09 -1 -1 -8 937.36 12.38 1 1 9 157.98 5.32 -1 -1 -9 167.83 5.60 -1 -1 -10 348.86 9.15 1 1 10 367.15 8.79 1 1 11 24.98 2.47 1 1 11 26.78 2.78 -1 -1 -11 23.70 2.61 1 -1 11 33.80 3.55 1 1 12 106.23 5.95 1 1 12 114.84 5.69 -1 -1 -12 109.02 6.15 1 -1 12 105.19 6.58 -1 1 -13 66.15 5.00 1 1 13 64.81 4.93 -1 -1 -13 65.35 5.16 1 -1 13 62.22 5.23 -1 1 -14 5.70 1.51 1 1 14 12.21 2.19 -1 1 -15 59.19 4.93 1 1 15 61.19 5.10 1 1 16 21.16 3.00 -1 1 -16 18.44 2.71 -1 1 -17 74.09 5.07 -1 1 -17 62.27 4.81 -1 -1 -17 69.10 4.45 1 1 17 65.15 5.07 -1 1 -18 69.18 4.74 -1 -1 -18 69.40 4.05 -1 -1 -19 94.62 5.30 -1 -1 -20 90.07 4.42 1 -2 -19 13.76 2.06 1 -2 -18 20.08 2.88 1 -2 -17 49.99 4.84 1 -2 -16 115.12 7.61 -1 2 16 108.38 5.96 1 -2 -15 224.18 10.87 -1 2 15 199.97 8.26 -1 2 14 51.65 4.19 1 -2 -14 62.19 5.76 1 2 -13 51.60 4.24 1 -2 -13 53.92 5.63 -1 2 13 50.92 4.04 -1 2 12 7.28 1.42 1 -2 -12 8.03 2.08 1 2 -12 11.03 1.90 1 -2 -11 91.24 6.78 -1 2 11 83.59 4.72 1 -2 -10 160.52 8.50 1 -2 -9 100.83 6.35 1 -2 -8 602.04 14.36 1 -2 -7 342.79 10.28 1 -2 -6 223.80 7.99 1 -2 -5 149.64 6.01 1 -2 -4 433.45 9.85 1 -2 -3 537.23 10.56 1 -2 -2 867.84 12.94 1 -2 -1 2060.85 19.27 1 -2 -1 2095.76 18.05 1 -2 0 111.46 4.13 1 -2 0 101.65 3.89 1 -2 1 230.39 5.99 1 -2 1 192.35 5.26 -1 -2 -2 1720.24 10.22 -1 -2 -2 1740.24 11.72 1 -2 2 1726.43 17.40 -1 -2 -3 319.99 5.41 -1 -2 -3 336.55 4.70 -1 -2 -4 218.98 5.05 1 -2 4 223.34 7.26 -1 -2 -5 85.79 3.49 -1 -2 -6 1250.42 14.35 1 2 7 1347.51 14.91 -1 -2 -7 1372.35 16.34 -1 -2 -8 302.34 8.26 1 2 8 280.80 7.09 -1 -2 -9 514.87 11.53 1 2 9 471.77 9.78 -1 2 -10 59.65 4.45 1 2 10 62.52 3.80 -1 -2 -10 61.54 4.36 1 2 10 65.72 4.05 1 -2 11 321.22 11.28 -1 2 -11 321.81 10.98 1 2 11 333.52 9.07 1 2 11 339.00 9.84 1 2 12 13.89 1.96 -1 2 -12 12.10 2.22 1 2 12 13.51 2.10 1 2 13 15.45 2.35 -1 2 -13 16.21 2.68 1 2 14 30.82 3.39 -1 2 -14 30.96 3.74 1 2 15 18.97 2.71 -1 2 -15 17.46 2.84 1 2 16 62.83 4.79 -1 2 -16 61.09 5.18 1 2 17 9.30 1.72 1 2 18 53.70 3.86 -1 -2 -18 58.80 4.40 -1 -2 -19 30.74 2.80 1 -3 -18 55.28 3.88 1 -3 -17 8.04 1.74 1 3 -17 7.22 1.48 1 -3 -16 37.81 4.15 1 -3 -15 85.41 6.58 1 -3 -14 55.53 5.32 1 -3 -13 10.67 2.63 1 -3 -12 39.82 4.44 1 -3 -11 81.67 6.84 1 -3 -11 94.65 6.70 1 -3 -10 30.75 4.05 1 -3 -9 89.91 6.64 1 -3 -8 15.86 2.68 1 -3 -7 659.96 16.19 1 -3 -6 18.80 2.76 1 -3 -5 269.96 9.78 1 -3 -4 178.26 7.37 1 -3 -3 124.41 5.98 1 -3 -2 21.69 2.35 1 -3 -1 482.20 10.21 1 -3 -1 187.98 7.00 -1 -3 0 1562.48 18.40 1 -3 0 1622.88 20.29 -1 -3 -1 1202.25 14.38 1 -3 1 1197.70 17.50 -1 -3 -2 204.22 5.58 1 -3 2 183.44 7.01 1 -3 3 770.40 14.79 1 -3 4 691.48 14.70 1 -3 5 432.98 12.17 1 -3 6 76.11 5.30 1 -3 7 31.56 3.72 1 3 8 30.92 2.81 -1 3 -8 26.78 3.20 1 3 8 27.08 2.55 1 -3 8 26.56 3.36 1 3 9 144.03 6.20 1 3 9 121.23 5.51 -1 3 -9 128.77 7.34 1 -3 9 120.05 7.24 1 3 10 84.11 4.75 -1 3 -10 81.34 6.06 1 3 10 90.26 5.05 1 -3 10 74.98 5.77 -1 3 -11 172.54 9.09 1 3 11 178.94 7.24 1 3 11 191.54 7.56 1 3 12 107.50 5.89 1 3 13 368.70 11.29 1 3 14 28.34 3.12 1 3 15 153.85 7.06 1 3 16 62.34 4.26 -1 -3 -17 9.70 1.71 1 3 17 8.12 1.43 1 3 18 12.10 1.50 -1 -3 -18 11.83 1.68 1 4 -16 39.78 2.98 1 4 -16 40.09 3.42 1 4 -15 2.23 0.89 1 4 -14 24.91 3.43 1 4 -13 313.39 12.74 1 4 -12 165.44 9.60 1 4 -11 244.16 11.88 1 4 -10 157.92 9.68 1 4 -9 542.58 17.86 1 4 -8 951.56 23.11 1 4 -7 26.97 3.88 1 4 -6 75.40 6.39 1 -4 -6 85.47 5.95 1 4 -5 479.37 15.52 1 -4 -5 494.06 13.28 1 4 -4 60.48 5.48 1 -4 -4 85.90 5.35 1 -4 -3 44.45 3.93 1 4 -3 38.89 4.20 -1 -4 3 33.36 3.73 -1 -4 2 95.47 5.78 1 -4 -2 116.23 6.01 -1 -4 1 3.38 1.01 1 -4 -1 2.51 0.99 1 -4 0 487.11 13.76 -1 -4 0 448.00 11.20 1 -4 1 26.71 3.23 1 -4 2 41.40 4.14 1 4 3 49.08 4.33 1 -4 3 39.90 4.04 1 4 4 152.71 7.36 1 -4 4 126.21 7.48 1 -4 5 28.53 3.90 1 4 5 27.33 3.09 1 4 6 91.06 5.39 1 -4 6 73.90 5.88 1 4 7 5.33 1.25 1 -4 7 4.29 1.43 1 4 8 50.00 3.91 1 4 8 41.87 3.64 1 -4 8 47.56 4.92 1 4 9 72.85 4.67 1 4 10 76.26 4.76 1 4 11 47.33 3.75 1 4 12 100.17 5.45 1 4 13 149.72 6.64 1 4 14 235.55 8.00 1 4 15 35.18 2.90 -1 4 -16 28.77 3.07 1 4 16 23.86 2.15 -1 4 -17 26.19 2.45 1 5 -15 13.81 1.65 1 5 -15 13.33 1.53 1 5 -14 29.70 2.66 1 5 -14 31.16 2.98 1 5 -13 4.80 1.44 1 5 -12 6.53 1.75 1 5 -11 215.19 10.18 1 5 -10 184.79 9.82 1 5 -9 209.75 10.73 1 5 -8 29.74 4.30 1 5 -7 85.00 7.05 1 5 -6 57.76 5.72 1 5 -5 30.07 4.19 1 5 -4 37.69 4.55 1 5 -3 43.91 4.92 -1 -5 3 34.25 3.93 1 5 -2 34.95 4.53 1 5 -1 184.68 9.74 1 5 -1 168.91 9.95 1 5 0 923.59 21.14 1 -5 1 729.39 19.48 1 5 1 763.81 19.01 -1 5 -2 409.12 13.55 1 5 2 407.22 13.36 1 -5 2 389.08 14.27 -1 5 -3 117.93 7.49 1 5 3 117.60 7.00 1 5 4 49.27 4.33 -1 5 -4 49.91 5.00 1 5 5 52.71 4.33 -1 5 -5 50.57 5.16 -1 5 -6 12.19 2.59 1 5 6 11.83 1.97 1 5 7 101.47 5.62 -1 5 -7 94.73 7.18 1 5 8 168.59 6.94 -1 5 -8 157.79 9.25 -1 5 -9 14.64 2.94 1 5 9 10.66 1.70 1 5 10 1.34 0.86 -1 5 -10 2.96 1.62 -1 5 -11 128.70 7.81 1 5 11 118.78 5.31 1 5 12 80.92 4.29 -1 5 -12 85.18 6.04 -1 5 -13 214.37 8.86 1 5 13 201.03 6.29 1 5 14 38.48 2.46 -1 5 -14 41.93 3.50 -1 5 -15 28.95 2.44 1 6 -12 34.59 2.44 1 6 -11 19.34 2.00 1 6 -11 20.16 2.33 1 6 -10 10.52 1.57 1 6 -10 11.41 1.89 1 6 -9 4.98 1.14 1 6 -9 6.74 1.62 1 6 -8 51.93 4.53 1 6 -7 32.68 3.94 1 6 -6 30.49 3.68 1 6 -5 29.30 3.58 1 6 -4 69.89 5.50 1 6 -3 25.72 4.06 1 6 -2 64.37 5.46 1 6 -1 30.19 3.90 1 6 0 39.60 3.98 1 6 1 133.00 7.03 1 6 2 231.88 8.90 1 6 3 275.10 9.24 1 6 4 25.58 2.80 -1 6 -4 25.43 3.19 1 6 5 41.58 3.32 -1 6 -5 42.02 4.05 -1 6 -5 50.12 4.20 1 6 6 0.58 0.34 -1 6 -6 1.71 0.97 -1 6 -6 1.24 0.78 1 6 7 126.59 5.20 -1 6 -7 131.27 6.98 1 6 8 4.37 0.95 -1 6 -8 3.77 1.19 -1 6 -9 26.28 2.85 1 6 9 24.33 2.03 1 6 10 0.26 0.02 -1 6 -10 0.72 0.44 -1 6 -11 28.23 2.52 1 6 11 25.57 1.77 1 7 -6 20.20 1.80 1 7 -5 4.95 0.94 1 7 -4 16.05 1.74 1 7 -3 30.13 2.40 1 7 -2 64.89 3.51 1 7 -1 51.53 3.06 1 7 0 7.38 1.14 1 7 1 19.13 1.82 1 7 2 25.68 2.00 1 7 3 19.29 1.64 1 7 4 3.92 0.70 1 7 5 5.91 0.79 2 0 -20 24.71 2.01 2 0 -19 128.25 6.17 2 0 -18 45.42 4.40 2 0 -17 3.19 1.25 2 0 -16 178.10 9.99 2 0 -15 19.36 3.34 2 0 -14 24.52 3.76 2 0 -13 294.69 12.71 2 0 -13 328.81 13.24 2 0 -12 8.78 2.09 2 0 -12 10.76 2.23 2 0 -11 50.03 4.73 2 0 -11 45.24 4.60 2 0 -10 359.58 11.91 2 0 -9 348.66 10.83 2 0 -8 1932.85 23.62 2 0 -7 216.59 7.36 2 0 -6 16.69 1.87 2 0 -5 6.98 1.09 2 0 -4 62.12 3.02 2 0 -3 64.46 2.93 2 0 -2 549.88 8.13 2 0 -1 390.04 4.92 2 0 -1 353.22 6.44 2 0 0 4728.29 18.92 2 0 0 4720.37 21.71 2 0 1 148.20 3.57 2 0 1 133.90 3.37 2 0 2 40.31 2.01 2 0 3 163.02 4.32 2 0 4 234.57 5.55 2 0 5 901.61 11.68 2 0 6 0.31 0.26 2 0 7 506.46 10.13 2 0 8 736.90 13.03 2 0 9 2.77 0.86 2 0 10 17.85 2.31 2 0 11 9.92 1.80 2 0 11 20.60 2.64 2 0 12 44.32 4.03 2 0 12 44.60 4.08 2 0 13 138.91 7.50 -2 0 -13 129.84 6.52 2 0 13 116.59 6.94 2 0 14 836.50 18.95 2 0 15 397.55 13.19 -2 0 -16 153.41 7.48 2 0 16 136.97 7.37 -2 0 -17 3.58 1.09 -2 0 -18 256.41 8.40 2 0 19 3.06 0.98 -2 0 -19 3.68 0.90 -2 0 -19 2.77 0.77 2 -1 -20 8.66 1.26 2 1 -19 2.55 0.69 2 -1 -19 2.95 1.00 2 -1 -18 28.77 3.53 2 1 -18 23.99 2.67 2 -1 -17 49.19 5.04 2 1 -17 45.69 4.37 2 1 -16 16.79 2.86 2 -1 -16 18.66 3.25 2 1 -15 60.10 5.64 2 -1 -15 64.62 6.16 2 1 -14 98.37 7.28 2 -1 -14 105.85 8.02 2 -1 -13 228.48 11.46 2 1 -13 257.78 11.53 2 -1 -13 243.25 12.41 2 1 -13 212.77 10.64 2 1 -12 486.65 14.73 2 -1 -12 464.32 16.19 2 -1 -12 440.23 15.30 2 -1 -11 71.25 5.86 2 1 -11 77.07 5.44 2 -1 -11 73.53 6.09 2 1 -11 78.03 6.05 2 1 -10 55.36 4.25 2 -1 -10 54.95 4.96 2 1 -9 882.84 15.58 2 -1 -9 817.02 18.03 2 -1 -8 3305.12 33.25 2 1 -8 3348.47 27.89 2 -1 -7 1856.49 23.62 2 1 -7 1851.91 19.26 2 -1 -6 163.47 6.49 2 1 -6 164.10 5.16 2 1 -5 1974.83 16.71 2 -1 -5 1985.20 21.25 2 -1 -4 162.85 5.80 2 1 -4 174.10 4.51 2 -1 -3 605.67 10.85 2 1 -3 629.68 4.86 2 1 -3 609.12 7.74 2 1 -2 424.05 4.74 2 -1 -2 403.84 8.61 2 1 -2 412.31 5.54 2 -1 -1 1391.52 15.28 2 1 -1 1388.71 9.51 2 1 0 832.23 7.96 2 -1 0 855.48 11.77 2 1 1 900.05 8.67 2 -1 1 875.46 10.97 2 1 2 387.28 6.10 2 -1 2 441.36 7.64 2 1 3 242.14 5.10 2 -1 3 252.67 6.34 2 -1 3 259.31 5.99 2 1 4 1334.89 12.75 2 -1 4 1318.11 15.32 2 -1 4 1348.35 14.05 2 1 5 1531.97 14.58 2 -1 5 1536.72 15.38 2 -1 5 1492.68 17.13 2 -1 6 193.64 5.73 2 -1 6 210.12 6.83 2 1 6 205.08 5.74 2 -1 7 418.94 8.79 2 1 7 421.53 8.55 2 1 8 652.76 11.66 2 -1 8 671.49 13.77 2 1 9 23.46 2.35 -2 -1 -9 26.89 2.24 2 1 10 132.10 5.96 -2 -1 -10 140.77 5.46 2 1 10 140.75 6.16 2 1 11 33.49 3.21 2 -1 11 33.47 3.54 2 1 11 35.10 3.27 2 -1 12 57.90 4.90 2 1 12 62.21 4.63 2 1 12 64.45 4.70 2 1 13 31.84 3.48 2 1 14 341.59 11.61 -2 1 -14 263.05 10.47 -2 1 -15 241.32 9.86 2 1 15 247.07 10.00 -2 1 -16 229.27 9.39 2 1 16 229.76 9.36 2 1 17 24.49 2.90 -2 1 -17 26.63 3.05 -2 -1 -18 46.29 3.25 -2 1 -18 49.37 3.83 -2 -1 -19 31.58 2.71 -2 -1 -19 29.11 2.15 2 -2 -19 3.83 0.97 2 -2 -18 13.63 2.24 2 -2 -17 24.62 3.39 2 -2 -16 4.57 1.44 2 -2 -15 36.11 4.59 2 -2 -14 73.65 6.65 2 -2 -13 163.86 9.87 2 -2 -12 22.96 3.52 2 -2 -12 24.07 3.87 2 2 -12 19.98 2.80 2 -2 -11 70.75 6.38 2 -2 -11 76.42 6.31 2 2 -11 76.00 5.14 2 2 -10 77.58 4.75 2 -2 -10 79.37 6.13 2 -2 -10 70.59 6.10 2 -2 -9 73.93 5.86 2 2 -9 82.98 4.50 2 2 -8 346.33 8.40 2 -2 -8 343.39 12.03 2 2 -7 885.82 12.51 2 -2 -7 886.14 18.32 2 2 -6 293.82 6.55 2 -2 -6 295.43 10.09 2 -2 -5 408.88 11.29 2 2 -5 401.03 6.86 2 2 -4 99.19 3.01 2 -2 -4 101.16 5.44 2 -2 -3 1008.43 16.41 2 -2 -2 1390.50 18.43 2 -2 -1 719.62 13.21 2 -2 0 98.23 4.47 2 -2 1 313.07 8.00 2 -2 1 271.07 7.35 2 -2 2 1041.01 14.96 2 -2 3 1835.38 20.16 2 2 4 49.47 2.79 2 -2 4 69.17 3.99 2 2 5 39.84 2.56 2 -2 5 37.61 3.10 2 2 6 69.94 3.56 2 -2 6 64.96 4.20 2 2 7 223.83 6.70 2 -2 7 210.63 7.81 2 -2 8 38.95 3.45 2 2 8 41.94 3.03 2 2 9 58.45 3.80 2 2 9 54.43 3.69 2 -2 9 53.90 4.19 -2 2 -9 55.89 4.24 -2 2 -10 155.37 7.42 2 2 10 156.23 6.49 2 2 11 39.23 3.45 2 2 11 44.98 3.70 -2 2 -11 40.76 3.99 2 2 12 438.91 12.27 -2 2 -12 400.98 12.96 -2 2 -13 283.99 11.25 2 2 13 311.17 10.64 -2 2 -14 49.09 4.68 2 2 14 49.55 4.25 2 -2 15 12.79 2.44 2 2 15 14.46 2.28 -2 2 -15 14.72 2.50 -2 2 -16 30.28 3.49 2 2 16 28.54 3.11 2 -2 16 24.20 2.97 2 -2 17 10.81 1.74 2 2 17 15.89 2.16 2 2 18 63.17 3.85 -2 -2 -18 61.95 3.15 -2 -2 -19 51.88 3.14 2 -3 -18 4.68 0.92 2 -3 -17 16.38 2.25 2 3 -16 24.92 2.62 2 -3 -16 27.45 3.41 2 -3 -15 29.03 3.79 2 3 -15 26.27 2.96 2 3 -15 31.56 3.44 2 -3 -14 142.60 8.86 2 3 -14 133.14 7.71 2 3 -13 197.09 9.87 2 -3 -13 217.30 11.12 2 -3 -12 79.86 6.72 2 3 -12 76.04 6.32 2 -3 -11 220.49 10.96 2 -3 -10 53.13 5.13 2 -3 -10 49.77 5.53 2 -3 -9 46.06 5.14 2 -3 -8 137.09 8.60 2 3 -8 128.15 8.00 2 -3 -7 3.67 1.36 2 -3 -6 115.10 7.06 2 -3 -5 271.35 10.36 2 -3 -4 192.63 8.47 2 -3 -3 1150.65 20.28 2 -3 -2 92.31 5.31 2 -3 -1 63.39 4.04 2 -3 0 152.26 6.44 2 -3 1 361.69 10.58 2 -3 2 36.23 3.43 2 -3 3 897.38 17.42 2 -3 4 424.17 12.20 2 -3 5 43.57 4.00 2 3 6 44.84 3.30 2 -3 6 38.49 3.85 2 3 7 7.17 1.32 2 3 7 9.25 1.58 -2 3 -7 7.20 1.61 2 -3 7 6.78 1.60 2 3 8 43.26 3.47 -2 3 -8 35.58 3.73 2 3 8 37.23 3.18 2 -3 8 36.52 3.93 2 3 9 197.43 7.59 -2 3 -9 185.98 8.88 2 -3 9 178.90 8.78 2 3 10 57.18 4.13 2 3 10 52.81 4.11 -2 3 -10 53.77 4.95 -2 3 -11 128.70 7.87 2 3 11 122.34 6.11 -2 3 -12 87.75 6.57 2 3 12 93.11 5.50 2 3 13 41.94 3.73 2 3 14 35.15 3.39 2 3 15 15.13 2.13 2 3 16 2.48 0.82 2 3 17 3.04 0.81 2 3 18 92.62 3.74 2 4 -16 20.28 2.11 2 4 -15 126.80 5.93 2 4 -15 125.54 5.85 2 4 -14 154.40 7.12 2 4 -14 150.43 7.39 2 4 -13 391.00 13.18 2 4 -12 200.20 9.98 2 4 -11 91.66 7.04 2 4 -10 87.98 7.03 2 4 -9 6.12 1.89 2 4 -8 6.38 1.90 2 4 -7 14.67 2.88 2 -4 -7 19.81 3.28 2 -4 -6 12.74 2.45 2 4 -6 15.40 2.92 2 -4 -5 0.12 0.34 2 4 -5 0.71 0.48 2 4 -4 91.95 6.90 2 -4 -4 83.78 5.67 2 4 -3 54.37 5.18 2 -4 -3 44.91 4.20 2 -4 -2 136.75 7.02 -2 -4 2 146.56 7.28 2 4 -1 35.20 4.04 2 4 0 50.52 4.64 2 4 1 89.92 6.22 2 -4 2 54.60 4.99 2 4 2 63.47 5.15 2 4 3 92.52 6.03 2 -4 3 87.03 6.54 2 4 4 82.12 5.42 2 -4 4 72.03 5.98 2 -4 5 46.01 4.83 2 4 5 52.41 4.20 2 4 6 36.24 3.41 2 4 6 38.95 3.59 2 -4 6 34.01 4.21 2 4 7 11.33 1.89 2 4 7 13.84 2.10 2 -4 7 12.62 2.58 2 4 8 75.35 4.87 2 4 9 222.31 8.24 2 4 10 788.74 15.41 2 4 11 148.06 6.55 2 4 12 58.61 4.12 2 4 13 241.45 8.22 2 4 14 26.90 2.61 2 4 15 6.89 1.24 -2 4 -16 13.39 1.83 2 4 16 12.43 1.45 2 5 -14 92.47 4.55 2 5 -14 93.60 4.38 2 5 -13 10.26 1.65 2 5 -13 9.94 1.67 2 5 -12 15.41 2.20 2 5 -12 15.79 2.38 2 5 -11 32.67 3.64 2 5 -11 33.15 3.41 2 5 -10 77.71 5.99 2 5 -9 40.73 4.52 2 5 -8 112.00 7.67 2 5 -7 11.31 2.50 2 5 -6 43.80 4.90 2 5 -5 18.91 3.23 2 5 -4 218.69 9.34 2 5 -4 226.23 11.25 2 5 -3 452.45 16.05 2 5 -2 89.01 6.66 2 5 -1 13.79 2.64 2 5 0 276.00 11.62 2 5 1 51.80 4.95 2 5 2 141.86 8.02 2 5 3 17.84 2.67 2 5 4 26.45 3.10 2 5 5 15.86 2.32 2 5 6 69.80 4.75 -2 5 -6 64.84 5.56 2 5 7 303.30 9.63 -2 5 -7 302.14 12.00 2 5 8 68.08 4.40 -2 5 -8 66.79 5.65 2 5 9 144.28 6.15 -2 5 -9 141.47 8.07 2 5 10 39.22 3.10 -2 5 -10 41.80 4.25 -2 5 -11 22.54 2.99 2 5 11 20.73 2.14 -2 5 -12 58.99 4.47 2 5 12 60.18 3.57 -2 5 -13 28.24 2.80 2 5 13 26.63 2.19 2 5 14 40.97 2.41 -2 5 -14 43.60 2.95 2 6 -11 58.29 3.47 2 6 -11 56.62 3.43 2 6 -10 8.76 1.42 2 6 -10 10.07 1.60 2 6 -9 37.15 3.04 2 6 -9 38.16 3.35 2 6 -8 16.73 2.13 2 6 -8 18.66 2.47 2 6 -7 69.32 4.44 2 6 -7 70.58 5.04 2 6 -6 12.43 2.18 2 6 -6 11.92 1.88 2 6 -5 2.67 1.02 2 6 -4 57.30 4.88 2 6 -3 312.12 11.41 2 6 -2 474.68 13.92 2 6 -1 205.54 8.96 2 6 0 42.63 4.00 2 6 1 1.75 0.62 2 6 2 21.43 2.62 2 6 3 60.16 4.21 2 6 4 27.92 2.76 2 6 5 79.63 4.48 2 6 6 0.75 0.47 2 6 7 10.71 1.46 2 6 8 24.07 2.09 2 6 9 1.48 0.47 2 6 10 1.22 0.43 2 7 -5 7.54 1.06 2 7 -4 0.87 0.44 2 7 -3 3.27 0.75 2 7 -2 77.76 3.58 2 7 -1 38.64 2.52 2 7 0 5.81 0.95 2 7 1 25.18 1.95 2 7 2 23.23 1.85 2 7 3 36.94 2.17 2 7 4 43.57 2.20 3 0 -19 0.15 0.17 3 0 -18 29.33 2.96 3 0 -17 5.90 1.54 3 0 -16 58.81 5.46 3 0 -15 68.95 6.40 3 0 -14 244.72 12.33 3 0 -13 73.76 6.83 3 0 -12 54.61 5.68 3 0 -12 44.38 5.29 3 0 -11 9.37 2.58 3 0 -11 7.54 1.98 3 0 -10 1.42 0.97 3 0 -10 2.53 1.08 3 0 -9 79.85 5.83 3 0 -8 30.67 3.38 3 0 -7 15.80 2.28 3 0 -6 108.86 5.56 3 0 -5 4.31 1.02 3 0 -4 423.32 9.78 3 0 -3 443.55 9.46 3 0 -2 386.92 8.37 3 0 -1 768.79 9.32 3 0 -1 728.93 10.98 3 0 0 22.71 1.75 3 0 0 15.49 1.39 3 0 1 879.53 11.38 3 0 2 1731.81 16.88 3 0 3 3.94 0.89 3 0 4 48.93 3.12 3 0 5 969.86 14.68 3 0 6 2.06 0.76 3 0 7 64.28 4.20 3 0 8 6.62 1.42 3 0 9 2.75 0.95 3 0 10 984.55 19.39 3 0 10 934.47 17.01 3 0 11 41.01 3.72 3 0 11 57.78 4.77 3 0 12 26.53 3.13 3 0 13 37.55 3.80 3 0 14 280.40 10.44 3 0 15 67.38 4.84 -3 0 -16 10.71 1.86 3 0 17 42.73 4.09 -3 0 -17 50.04 3.67 3 0 18 0.32 0.37 -3 0 -18 1.16 0.53 3 -1 -19 4.86 0.98 3 1 -18 6.10 1.11 3 -1 -18 6.96 1.47 3 -1 -17 6.98 1.71 3 1 -17 6.31 1.37 3 -1 -16 184.41 9.96 3 1 -16 137.08 7.23 3 -1 -15 92.48 7.50 3 1 -15 70.12 5.78 3 1 -14 62.13 5.68 3 -1 -14 78.23 7.13 3 1 -13 113.51 7.91 3 -1 -13 121.57 8.99 3 -1 -12 604.23 19.90 3 1 -12 623.36 17.98 3 -1 -12 632.60 20.14 3 1 -11 284.51 11.53 3 -1 -11 281.58 12.94 3 -1 -11 275.02 13.20 3 1 -11 257.18 11.95 3 1 -10 363.69 13.85 3 1 -10 408.63 13.07 3 -1 -10 395.82 14.56 3 -1 -10 392.40 15.21 3 -1 -9 60.60 5.69 3 1 -9 58.01 4.63 3 -1 -9 59.52 5.30 3 1 -8 125.17 6.33 3 -1 -8 117.11 7.06 3 1 -7 184.60 7.21 3 -1 -7 183.11 8.42 3 1 -6 163.23 6.35 3 -1 -6 156.97 7.42 3 1 -5 178.33 6.14 3 -1 -5 171.60 7.39 3 -1 -4 202.82 7.67 3 1 -4 230.68 6.34 3 1 -3 818.20 10.79 3 -1 -3 746.30 14.23 3 1 -2 7.22 0.79 3 -1 -2 4.48 1.03 3 1 -1 343.55 5.89 3 -1 -1 310.85 8.50 3 1 0 800.49 9.46 3 -1 0 710.11 11.68 3 -1 1 96.14 4.18 3 1 1 98.90 3.54 3 1 2 848.36 10.95 3 1 3 390.94 7.77 3 1 4 236.63 6.40 3 -1 5 61.37 4.13 3 1 5 57.79 3.39 3 1 6 37.72 2.89 3 -1 6 40.92 3.52 3 1 7 166.91 6.43 3 1 8 97.63 5.20 3 1 9 123.09 6.21 3 1 9 133.07 5.85 3 1 10 975.53 18.51 3 1 10 984.84 16.81 3 -1 11 599.38 14.91 3 1 11 625.08 15.33 3 1 11 633.62 14.24 3 1 12 320.92 10.57 3 1 13 60.42 4.66 -3 1 -14 202.68 8.96 3 1 14 194.00 8.48 3 -1 15 61.79 5.62 -3 1 -15 66.42 4.94 3 1 15 70.67 4.98 3 -1 16 47.60 4.48 3 1 16 60.45 4.37 -3 1 -16 60.98 4.52 3 -1 17 18.92 2.49 3 1 17 17.63 2.66 -3 1 -17 22.11 2.49 -3 -1 -17 24.17 2.42 3 1 18 9.24 1.63 -3 1 -18 11.56 1.60 -3 -1 -18 10.69 1.39 3 -1 18 7.88 1.32 3 -2 -18 3.98 0.97 3 -2 -17 47.72 4.10 3 -2 -16 84.06 6.18 3 -2 -15 15.63 2.95 3 -2 -14 133.91 9.06 3 2 -14 162.48 8.30 3 -2 -13 75.03 6.94 3 2 -13 85.44 6.13 3 -2 -12 249.33 12.67 3 2 -12 269.00 10.96 3 2 -11 429.72 14.00 3 -2 -11 398.47 16.53 3 -2 -11 386.37 15.58 3 -2 -10 239.27 11.90 3 2 -10 257.82 10.74 3 -2 -10 238.76 12.20 3 -2 -9 31.20 4.15 3 2 -9 30.84 3.65 3 -2 -9 41.00 4.81 3 -2 -8 520.24 16.19 3 -2 -8 500.74 16.03 3 -2 -7 206.98 9.85 3 -2 -6 417.48 13.49 3 -2 -5 349.77 11.76 3 -2 -4 117.86 6.45 3 -2 -3 422.05 11.87 3 2 -2 14.99 1.31 3 -2 -2 14.05 2.09 3 -2 -1 294.45 8.98 3 2 -1 320.52 6.35 3 2 0 702.80 9.94 3 -2 0 638.06 12.83 3 2 1 479.86 8.61 3 -2 1 452.98 10.94 3 2 2 147.03 4.97 3 2 3 49.75 3.00 3 2 4 57.77 3.41 3 2 5 599.92 11.37 3 -2 6 255.31 9.23 3 2 6 264.42 8.01 3 2 7 183.47 6.87 3 -2 7 190.72 8.07 3 -2 8 141.57 8.60 3 2 8 146.81 5.95 3 2 8 141.87 6.24 -3 2 -8 141.39 6.76 3 -2 9 130.67 8.50 3 2 9 144.60 6.14 3 2 9 143.87 6.70 -3 2 -9 137.69 6.96 3 -2 10 199.35 10.61 3 2 10 214.78 8.51 -3 2 -10 211.80 8.90 3 2 10 227.66 7.99 3 -2 11 113.72 7.99 3 2 11 131.57 6.42 -3 2 -11 121.84 6.94 -3 2 -12 301.60 11.16 3 2 12 322.37 10.31 3 -2 13 4.61 1.57 3 2 13 6.24 1.47 -3 2 -13 7.76 1.86 3 -2 14 84.49 6.19 -3 2 -14 90.74 6.02 3 2 14 103.76 5.85 3 -2 15 6.52 1.57 -3 2 -15 7.89 1.74 3 2 15 7.35 1.52 -3 2 -16 69.83 4.76 3 2 16 68.98 4.35 3 -2 16 57.53 4.14 3 2 17 48.03 3.66 3 -2 17 48.76 3.14 3 -3 -17 56.51 3.17 3 3 -16 227.54 7.70 3 -3 -16 146.56 6.32 3 3 -15 78.96 5.27 3 -3 -15 63.28 4.79 3 -3 -14 74.41 5.71 3 3 -14 88.27 5.85 3 -3 -13 131.00 8.03 3 3 -13 144.43 7.82 3 -3 -12 0.96 0.89 3 3 -12 0.77 0.65 3 3 -11 35.83 4.16 3 -3 -11 33.64 4.28 3 -3 -10 75.06 6.34 3 3 -10 81.89 6.29 3 3 -9 144.15 8.61 3 -3 -9 151.49 9.72 3 -3 -8 212.43 11.15 3 3 -8 199.31 10.14 3 -3 -7 27.11 3.91 3 3 -7 30.85 3.92 3 3 -6 51.53 4.97 3 -3 -6 49.01 5.04 3 3 -5 101.89 6.54 3 3 -5 105.37 7.01 3 -3 -5 100.46 7.01 3 -3 -4 200.32 9.52 3 -3 -3 444.79 13.17 3 -3 -2 494.56 13.02 3 -3 -1 692.17 15.59 3 -3 0 254.36 9.38 3 3 1 32.90 2.68 3 3 2 32.58 2.73 3 3 3 43.85 3.21 3 3 4 35.10 3.17 3 3 4 30.28 2.76 3 3 5 83.52 4.73 3 3 5 96.41 5.19 3 -3 5 85.39 6.16 3 3 6 456.43 11.40 3 3 6 477.75 11.51 3 3 7 481.70 11.65 -3 3 -7 450.79 13.21 3 3 7 459.30 11.79 3 -3 7 435.13 14.25 3 3 8 258.48 8.51 -3 3 -8 249.03 10.08 3 3 8 259.38 9.20 3 3 9 50.56 3.81 -3 3 -9 48.47 4.58 3 3 10 250.88 8.56 -3 3 -10 235.49 10.20 3 3 11 102.09 5.53 -3 3 -11 98.08 6.59 -3 3 -12 5.35 1.55 3 3 12 7.63 1.55 3 3 13 15.80 2.17 3 3 14 101.63 5.34 3 3 15 104.35 5.08 3 3 16 57.06 3.47 3 3 17 26.02 2.00 3 4 -15 10.18 1.64 3 4 -14 22.38 2.71 3 4 -13 1.76 0.82 3 4 -12 29.64 3.48 3 4 -12 30.00 3.33 3 4 -11 50.63 4.73 3 4 -11 48.83 4.58 3 4 -10 11.18 2.33 3 4 -10 12.55 2.45 3 4 -9 39.69 4.40 3 4 -9 42.53 4.70 3 4 -8 31.97 3.97 3 4 -8 32.04 4.11 3 4 -7 6.58 1.83 3 4 -7 8.71 2.23 3 4 -6 56.31 5.26 3 4 -6 68.70 6.22 3 4 -5 99.11 6.85 3 4 -5 117.65 8.10 3 -4 -5 107.21 7.19 3 4 -4 70.82 5.69 3 4 -4 83.49 6.76 3 -4 -4 69.66 5.68 3 4 -3 73.85 5.72 3 -4 -3 69.41 5.75 3 -4 -2 74.73 5.83 3 4 -2 85.19 6.09 3 4 -1 286.24 11.58 3 4 0 11.69 2.31 3 4 1 38.18 3.39 3 4 1 47.16 4.80 3 4 2 100.52 6.39 3 4 2 86.11 5.19 3 4 3 43.30 3.71 3 4 3 45.53 4.16 3 4 4 316.57 10.02 3 4 4 342.69 10.87 3 4 5 843.76 16.79 3 4 6 477.51 12.41 3 4 7 166.74 7.18 3 4 8 45.94 3.70 3 4 9 274.56 8.88 3 4 10 193.12 7.37 3 4 11 56.33 3.84 3 4 12 135.42 5.94 3 4 13 7.98 1.36 3 4 14 14.36 1.73 -3 4 -15 22.95 2.18 3 4 15 21.56 1.88 3 5 -13 9.00 1.48 3 5 -12 2.22 0.75 3 5 -11 4.60 1.30 3 5 -10 3.44 1.09 3 5 -9 9.37 1.93 3 5 -8 80.82 5.87 3 5 -7 12.26 2.33 3 5 -6 85.96 6.22 3 5 -5 41.82 4.36 3 5 -4 41.27 4.52 3 5 -4 38.70 4.26 3 5 -3 70.01 5.69 3 5 -3 57.52 5.37 3 5 -2 60.71 5.51 3 5 -1 47.02 4.74 3 5 0 74.45 5.85 3 5 1 50.31 4.73 3 5 2 32.65 3.63 3 5 3 80.97 5.37 3 5 4 33.89 3.40 3 5 5 15.01 2.23 3 5 6 5.73 1.33 3 5 7 32.16 2.97 3 5 8 86.45 4.63 3 5 9 8.24 1.39 3 5 10 36.64 2.74 3 5 11 23.88 2.15 3 5 12 6.72 1.08 3 5 13 2.28 0.58 3 6 -10 20.06 1.82 3 6 -9 9.00 1.42 3 6 -9 9.46 1.42 3 6 -8 66.42 4.08 3 6 -8 61.86 3.94 3 6 -7 111.18 5.47 3 6 -7 101.09 5.36 3 6 -6 235.10 8.03 3 6 -6 194.73 7.72 3 6 -5 101.46 5.74 3 6 -4 72.64 4.97 3 6 -3 1.61 0.89 3 6 -2 57.01 4.27 3 6 -1 41.76 3.63 3 6 0 30.87 2.99 3 6 1 4.18 1.25 3 6 2 17.23 2.11 3 6 3 68.48 4.11 3 6 4 26.64 2.46 3 6 5 10.45 1.46 3 6 6 16.17 1.77 3 6 7 8.79 1.22 3 6 8 34.19 2.22 3 6 9 3.60 0.68 3 7 -1 7.66 0.94 3 7 0 15.54 1.31 3 7 1 1.26 0.34 4 0 -18 59.73 3.42 4 0 -17 33.20 3.00 4 0 -16 48.54 4.17 4 0 -15 4.76 1.48 4 0 -14 7.81 1.98 4 0 -13 44.34 5.20 4 0 -12 36.20 4.74 4 0 -11 18.04 3.57 4 0 -10 128.25 8.41 4 0 -10 178.14 10.06 4 0 -9 111.45 7.67 4 0 -9 152.72 8.98 4 0 -8 278.67 11.76 4 0 -8 298.79 7.37 4 0 -7 78.25 6.34 4 0 -7 69.65 5.59 4 0 -6 43.34 4.07 4 0 -5 248.95 9.31 4 0 -4 37.24 3.35 4 0 -3 1002.15 16.33 4 0 -2 236.76 7.24 4 0 -1 1609.01 17.70 4 0 0 1658.24 18.71 4 0 1 237.78 7.26 4 0 2 543.92 11.73 4 0 3 31.29 3.04 4 0 4 192.78 7.78 4 0 5 84.66 5.35 4 0 6 202.25 10.07 4 0 6 203.65 8.62 4 0 7 406.45 14.92 4 0 7 366.39 11.70 4 0 8 91.48 7.56 4 0 8 54.93 4.85 4 0 9 95.12 7.91 4 0 9 66.56 5.65 4 0 10 55.43 6.02 4 0 11 104.68 8.33 4 0 12 132.03 9.29 4 0 13 2.84 1.15 4 0 13 7.71 2.64 4 0 14 11.45 2.49 4 0 15 80.14 6.11 4 0 16 49.43 4.20 -4 0 -16 47.69 3.37 -4 0 -17 27.51 2.32 4 0 17 39.02 3.36 4 -1 -18 4.47 0.98 4 -1 -17 55.67 3.93 4 1 -17 50.14 3.24 4 1 -16 142.35 6.35 4 -1 -16 163.92 7.64 4 -1 -15 19.10 2.97 4 1 -15 12.29 2.10 4 1 -14 91.22 6.18 4 -1 -14 133.90 8.29 4 1 -13 19.58 2.97 4 -1 -13 22.91 3.65 4 -1 -12 109.51 8.22 4 1 -12 93.62 6.75 4 -1 -11 257.00 12.99 4 1 -11 224.48 10.76 4 1 -10 57.45 5.24 4 -1 -10 71.27 6.50 4 -1 -10 82.40 7.20 4 1 -9 109.93 7.06 4 -1 -9 122.81 8.23 4 1 -9 147.38 8.88 4 -1 -9 137.87 9.00 4 -1 -8 555.48 16.90 4 1 -8 306.81 12.70 4 1 -8 316.56 8.12 4 -1 -8 502.28 16.28 4 1 -8 509.18 15.00 4 -1 -7 347.26 12.59 4 1 -7 273.07 11.76 4 1 -7 253.80 7.06 4 -1 -7 348.04 12.95 4 1 -7 333.85 11.56 4 -1 -6 292.75 11.38 4 -1 -5 330.41 11.62 4 -1 -4 196.06 8.43 4 -1 -3 281.75 9.92 4 -1 -2 249.78 8.56 4 -1 -1 453.69 10.48 4 -1 0 293.62 8.88 4 1 0 248.57 6.90 4 1 1 134.33 5.25 4 1 2 124.60 5.28 4 1 3 245.04 7.66 4 1 4 656.10 13.12 4 1 5 625.04 13.42 4 1 6 613.21 16.96 4 -1 6 630.56 18.02 4 -1 7 1155.33 25.27 4 1 7 1160.90 24.45 4 1 7 1145.66 19.85 4 -1 8 134.54 9.16 4 1 8 126.74 8.57 4 1 8 107.68 6.37 4 -1 9 56.70 6.15 4 1 9 57.17 6.04 4 1 9 39.52 4.04 4 -1 10 557.16 18.89 4 1 10 555.35 18.99 4 -1 11 189.70 11.06 4 1 11 197.66 11.48 4 1 11 211.76 8.06 4 -1 12 33.09 4.51 4 1 12 31.68 4.57 4 1 12 32.78 3.20 4 -1 13 232.21 11.34 4 1 13 233.35 11.84 -4 1 -13 240.06 9.18 4 1 13 249.52 8.80 4 -1 14 60.28 5.32 4 1 14 61.33 5.65 4 1 14 70.57 4.49 -4 1 -14 67.64 4.62 4 1 15 89.74 4.75 -4 1 -15 89.30 5.09 -4 1 -16 88.44 4.59 4 1 16 91.75 5.64 4 -1 16 89.35 5.36 4 1 17 30.30 2.68 -4 1 -17 36.63 2.60 -4 -1 -17 39.48 2.56 4 -1 17 29.73 2.49 4 -2 -17 16.14 1.89 4 -2 -16 148.92 6.53 4 -2 -15 117.20 6.59 4 -2 -14 60.59 5.27 4 2 -14 76.94 5.69 4 -2 -13 119.64 7.63 4 2 -13 109.58 6.01 4 -2 -12 260.04 12.05 4 2 -12 248.23 9.64 4 -2 -11 188.56 9.96 4 2 -11 170.81 8.11 4 -2 -10 79.72 6.63 4 2 -10 76.93 5.46 4 -2 -9 273.81 11.93 4 -2 -9 291.61 13.71 4 2 -9 251.67 9.97 4 -2 -8 136.79 7.99 4 2 -8 140.92 7.27 4 -2 -8 148.04 9.28 4 -2 -7 122.26 7.39 4 -2 -7 127.67 8.30 4 2 -7 133.56 7.06 4 -2 -6 253.59 9.73 4 2 -6 375.41 14.20 4 -2 -6 312.26 9.26 4 -2 -6 319.66 12.62 4 2 -6 249.03 9.52 4 2 -5 265.25 9.72 4 2 -5 253.33 11.42 4 2 -5 280.29 7.68 4 -2 -5 280.67 8.69 4 2 -4 231.28 10.62 4 2 -4 249.94 7.01 4 -2 -4 186.22 7.55 4 -2 -4 193.30 9.28 4 -2 -3 141.01 7.36 4 -2 -2 120.08 6.57 4 -2 -1 55.42 4.38 4 -2 0 60.44 4.44 4 2 1 149.10 5.55 4 2 2 103.80 4.84 4 2 3 80.81 4.55 4 -2 3 147.84 8.32 4 -2 4 432.72 14.19 4 2 4 375.44 10.14 4 -2 5 205.11 10.06 4 2 5 100.94 5.60 4 2 6 222.83 8.35 4 -2 6 227.63 11.09 4 2 7 282.13 8.12 4 2 7 283.09 9.85 4 -2 7 280.34 12.52 4 2 8 619.32 15.01 4 2 8 614.56 12.24 4 -2 9 150.44 9.42 4 2 9 158.46 8.95 4 2 9 159.27 6.52 -4 2 -9 162.86 7.57 4 -2 10 138.92 9.31 4 2 10 143.50 8.85 -4 2 -10 123.19 6.94 4 -2 11 378.63 14.62 4 2 11 412.53 14.81 -4 2 -11 403.11 12.24 4 2 11 379.55 10.60 4 2 12 140.58 8.51 4 -2 12 125.54 8.03 -4 2 -12 116.43 6.52 4 2 12 103.49 5.63 4 2 13 135.34 7.92 -4 2 -13 135.39 6.73 4 2 13 137.92 6.22 4 -2 13 123.95 7.40 4 2 14 123.96 6.99 -4 2 -14 106.46 5.78 4 2 14 108.19 5.34 4 -2 14 111.73 6.58 4 -2 15 93.35 5.14 4 2 15 88.37 4.47 4 2 16 59.66 3.12 4 -2 16 55.81 3.31 4 3 -15 35.17 3.12 4 -3 -15 20.69 2.14 4 -3 -14 13.56 1.94 4 3 -14 25.45 3.02 4 -3 -13 35.32 3.38 4 3 -13 66.71 5.47 4 -3 -12 11.61 2.08 4 3 -12 20.18 3.24 4 -3 -11 19.63 2.88 4 3 -11 30.46 4.15 4 3 -10 49.12 5.34 4 3 -9 24.76 3.84 4 3 -8 57.28 5.78 4 3 -7 61.41 6.06 4 3 -6 121.27 8.45 4 -3 -6 122.45 8.20 4 3 -5 217.61 11.33 4 -3 -5 194.15 9.88 4 -3 -4 391.38 10.98 4 3 -4 430.10 15.70 4 -3 -4 493.52 11.57 4 -3 -4 548.43 15.67 4 -3 -3 90.74 5.96 4 3 -3 130.84 8.54 4 -3 -3 289.61 9.16 4 -3 -3 296.91 11.38 4 -3 -2 396.18 11.50 4 -3 -2 415.30 13.13 4 -3 -1 264.99 9.73 4 -3 -1 281.85 10.89 4 3 0 364.03 13.26 4 -3 0 294.33 10.57 4 3 1 636.57 14.21 4 -3 1 624.27 16.01 4 -3 2 691.30 17.05 4 3 2 707.97 14.10 4 3 3 805.91 15.06 4 -3 3 781.08 18.72 4 3 4 112.83 5.66 4 3 4 109.42 5.94 4 3 5 63.33 4.18 4 3 5 63.05 4.56 4 3 6 408.53 10.37 4 -3 6 381.27 13.84 4 3 7 117.57 5.55 4 -3 7 123.10 7.86 4 3 8 12.03 1.82 4 -3 8 17.72 3.07 4 3 9 60.87 4.03 4 -3 9 69.96 5.88 4 3 10 70.75 4.39 4 -3 10 68.07 5.56 4 3 11 17.51 2.21 4 -3 11 21.94 3.01 4 -3 12 42.48 3.92 4 3 12 31.40 2.88 4 3 13 27.85 2.57 4 -3 13 28.90 2.80 4 3 14 16.69 1.85 4 3 15 23.66 1.99 4 4 -14 9.30 1.58 4 4 -13 71.61 4.89 4 4 -12 40.89 4.07 4 4 -11 81.12 6.07 4 4 -10 54.02 5.26 4 4 -9 30.64 4.18 4 4 -8 26.14 3.89 4 4 -7 9.93 2.53 4 4 -6 94.59 7.63 4 4 -5 413.78 13.87 4 4 -5 450.74 16.58 4 4 -4 62.79 5.41 4 -4 -4 60.01 4.41 4 4 -4 66.09 6.28 4 4 -3 147.20 8.33 4 4 -3 172.94 10.00 4 4 -2 247.10 11.72 4 4 -2 223.45 10.04 4 4 -1 211.72 10.79 4 4 -1 160.85 8.43 4 4 0 214.71 9.40 4 4 1 375.10 11.90 4 4 2 135.22 6.80 4 4 3 185.39 7.77 4 4 4 47.34 4.00 4 4 5 446.24 11.55 4 4 6 16.11 2.13 4 4 7 12.50 1.83 4 4 8 72.00 4.30 4 4 9 16.49 2.03 4 4 10 213.61 7.04 4 -4 11 11.91 1.66 4 4 11 12.53 1.73 4 4 12 61.10 3.51 4 4 13 8.47 1.18 4 5 -12 7.27 1.29 4 5 -11 28.05 2.88 4 5 -10 25.64 2.93 4 5 -10 21.99 2.18 4 5 -9 24.79 3.09 4 5 -9 22.40 2.43 4 5 -8 10.86 2.11 4 5 -8 10.63 1.78 4 5 -7 45.43 4.47 4 5 -7 41.31 3.76 4 5 -6 84.22 6.23 4 5 -6 83.13 5.54 4 5 -5 43.19 4.50 4 5 -5 38.57 3.85 4 5 -4 21.84 3.20 4 5 -4 19.07 2.73 4 -5 -3 19.76 2.37 4 5 -3 20.52 3.04 4 5 -3 17.29 2.60 4 -5 -2 76.28 5.19 4 5 -2 56.30 4.62 4 5 -1 14.33 2.27 4 5 0 18.66 2.55 4 5 1 30.90 3.14 4 5 2 21.66 2.55 4 5 3 22.27 2.52 4 5 4 29.75 2.83 4 5 5 141.01 5.93 4 5 6 7.97 1.37 4 5 7 10.00 1.43 4 5 8 15.38 1.72 4 5 9 22.94 2.01 4 -5 10 64.99 3.35 4 5 10 50.42 2.83 4 5 11 6.30 0.90 4 6 -6 0.53 0.31 4 6 -5 3.77 0.81 4 6 -4 5.54 1.01 4 6 -3 14.87 1.69 4 6 -2 20.50 2.01 4 -6 -1 92.96 3.87 4 6 -1 72.85 3.78 4 -6 0 12.57 1.73 4 6 0 13.44 1.61 4 -6 1 26.00 2.48 4 6 1 20.93 1.97 4 -6 2 59.22 3.96 4 6 2 40.80 2.71 4 6 3 22.54 1.91 4 -6 3 29.45 2.78 4 6 4 23.86 1.87 4 -6 4 34.44 2.93 4 6 5 4.58 0.78 4 -6 5 6.70 1.22 4 6 6 24.46 1.70 4 -6 6 36.46 2.67 4 -6 7 42.74 2.54 5 0 -17 14.09 1.51 5 0 -16 38.48 3.05 5 0 -15 59.38 4.26 5 0 -14 2.73 1.03 5 0 -13 2.06 1.02 5 0 -12 20.27 3.08 5 0 -11 31.01 3.94 5 0 -10 20.49 3.27 5 0 -9 67.82 3.69 5 0 -9 45.15 4.85 5 0 -8 178.27 8.58 5 0 -8 191.72 6.38 5 0 -7 7.65 2.08 5 0 -7 8.74 1.93 5 0 -7 8.39 1.32 5 0 -6 609.84 15.83 5 0 -6 634.23 11.60 5 0 -6 597.22 12.63 5 0 -5 121.67 7.03 5 0 -5 126.20 5.37 5 0 -5 106.74 5.33 5 0 -5 96.55 6.71 5 0 -4 271.36 9.15 5 0 -4 240.20 10.27 5 0 -3 8.99 2.11 5 0 -3 36.48 4.45 5 0 -2 475.52 13.05 5 0 -2 461.09 13.75 5 0 -1 46.12 4.42 5 0 -1 37.62 4.25 5 0 0 70.74 4.97 5 0 0 61.69 4.97 5 0 0 67.20 5.16 5 0 1 578.06 14.07 5 0 1 563.84 15.49 5 0 2 139.43 7.90 5 0 3 157.05 8.95 5 0 4 15.89 2.62 5 0 4 58.47 5.40 5 0 5 52.57 5.09 5 0 5 238.67 11.14 5 0 6 7.39 2.04 5 0 6 4.80 1.49 5 0 7 80.48 7.01 5 0 8 33.05 4.58 5 0 9 49.70 5.53 5 0 10 51.31 5.62 5 0 11 22.81 3.80 5 0 12 6.31 1.79 5 0 13 2.81 1.09 -5 0 -14 24.65 2.31 5 0 14 29.42 3.32 -5 0 -15 10.30 1.34 5 0 15 11.18 1.79 5 0 16 62.82 3.47 5 -1 -16 15.91 1.99 5 1 -16 13.37 1.56 5 1 -15 64.90 4.07 5 -1 -15 74.33 4.71 5 1 -14 58.05 4.35 5 -1 -14 61.27 4.75 5 -1 -13 47.59 4.61 5 1 -13 42.44 4.11 5 -1 -12 73.20 5.76 5 1 -12 67.68 5.31 5 -1 -11 97.88 6.92 5 1 -11 89.46 6.32 5 -1 -10 349.79 13.29 5 1 -10 326.23 12.36 5 -1 -9 81.45 6.42 5 1 -9 77.02 6.24 5 1 -8 55.07 5.55 5 1 -8 54.53 3.59 5 -1 -8 46.42 3.01 5 1 -8 32.73 4.01 5 -1 -8 33.74 4.16 5 1 -7 67.53 6.22 5 1 -7 66.84 3.94 5 -1 -7 58.11 3.67 5 -1 -7 90.48 7.17 5 1 -7 97.75 7.02 5 -1 -7 103.58 7.19 5 -1 -6 50.07 4.87 5 1 -6 47.06 4.81 5 1 -6 6.34 2.34 5 1 -6 10.58 1.86 5 -1 -6 38.07 3.40 5 -1 -6 42.05 4.73 5 -1 -5 70.81 5.01 5 1 -5 79.32 6.56 5 1 -5 147.39 8.15 5 1 -5 75.84 4.19 5 -1 -5 136.93 6.41 5 -1 -5 120.00 7.53 5 -1 -5 141.45 7.98 5 -1 -4 100.08 5.86 5 1 -4 110.21 7.34 5 1 -4 100.78 4.65 5 -1 -4 104.73 6.03 5 -1 -4 93.77 6.00 5 1 -4 89.12 6.22 5 -1 -4 86.04 6.01 5 -1 -3 361.19 10.75 5 -1 -3 304.44 10.43 5 -1 -3 431.35 12.94 5 1 -3 332.72 12.43 5 1 -3 325.16 8.33 5 -1 -3 453.17 12.99 5 -1 -3 377.98 11.25 5 1 -3 470.40 14.29 5 -1 -2 12.88 2.28 5 -1 -2 14.30 2.23 5 1 -2 7.60 2.51 5 1 -2 12.97 1.65 5 -1 -2 80.55 5.66 5 -1 -2 59.71 4.42 5 1 -2 92.03 6.14 5 -1 -2 92.83 5.96 5 -1 -1 8.58 1.93 5 1 -1 10.28 2.41 5 1 -1 9.53 1.49 5 -1 -1 58.66 5.19 5 1 -1 65.77 5.29 5 -1 -1 48.18 4.55 5 -1 0 134.76 6.40 5 1 0 148.65 7.66 5 1 0 120.25 4.97 5 -1 0 110.09 6.98 5 -1 1 190.06 7.57 5 1 1 178.90 6.09 5 1 2 641.41 14.98 5 -1 2 594.85 13.42 5 1 2 561.28 10.62 5 -1 2 660.68 18.33 5 1 2 573.20 15.61 5 1 3 57.30 4.38 5 -1 3 51.42 3.99 5 1 3 50.99 3.16 5 1 3 46.06 4.13 5 -1 3 89.88 6.89 5 1 3 76.32 5.95 5 -1 4 226.52 8.31 5 1 4 207.37 8.85 5 -1 4 237.21 11.39 5 1 4 202.49 9.43 5 -1 5 106.58 5.67 5 1 5 92.98 6.14 5 -1 5 96.09 7.24 5 1 5 90.92 6.41 5 -1 6 153.29 6.76 5 -1 6 142.69 9.05 5 1 6 136.92 8.26 5 -1 7 28.89 4.36 5 1 7 27.45 4.00 5 -1 8 135.88 9.06 5 1 8 138.21 8.75 5 1 9 690.78 19.65 5 -1 9 705.41 20.73 5 1 10 153.91 9.30 -5 1 -10 181.82 7.39 5 -1 10 160.19 9.73 5 1 11 63.00 5.85 -5 1 -11 67.88 4.43 5 -1 11 73.07 6.32 -5 1 -12 98.17 5.13 5 -1 12 92.41 6.66 5 1 12 92.50 6.70 -5 1 -13 23.99 2.42 5 -1 13 25.90 3.27 5 1 13 21.38 3.03 -5 1 -14 7.31 1.23 5 -1 14 8.89 1.76 5 1 14 7.86 1.67 -5 1 -15 32.14 2.30 -5 -1 -15 35.81 2.44 5 -1 15 31.10 2.77 5 1 15 27.64 2.50 5 -2 -15 25.36 2.46 5 -2 -14 8.25 1.69 5 2 -13 17.16 2.39 5 2 -13 19.05 2.24 5 -2 -13 19.78 2.74 5 2 -12 28.36 3.53 5 2 -12 23.33 2.66 5 -2 -12 25.16 3.26 5 2 -11 35.24 4.35 5 2 -11 35.60 3.60 5 -2 -11 45.49 4.52 5 2 -10 20.29 2.76 5 -2 -10 19.17 2.92 5 2 -9 77.95 5.52 5 -2 -9 90.04 6.43 5 2 -8 251.38 10.41 5 -2 -8 296.72 11.45 5 2 -7 107.52 6.71 5 -2 -7 118.14 7.13 5 2 -6 66.21 6.75 5 2 -6 56.09 4.88 5 -2 -6 55.02 4.76 5 -2 -5 89.95 5.56 5 2 -5 83.93 7.76 5 2 -5 114.15 5.46 5 -2 -5 279.68 9.55 5 -2 -5 247.91 11.08 5 2 -5 326.56 11.84 5 -2 -5 341.80 11.58 5 -2 -4 219.74 8.50 5 2 -4 255.82 12.59 5 2 -4 256.69 7.99 5 -2 -4 303.69 10.02 5 -2 -4 266.99 10.44 5 2 -4 316.94 11.40 5 -2 -4 298.04 10.35 5 -2 -3 673.60 14.71 5 2 -3 713.20 19.84 5 2 -3 703.93 12.62 5 -2 -3 736.60 16.66 5 -2 -3 687.77 17.33 5 2 -3 700.63 17.15 5 -2 -3 676.70 15.59 5 -2 -2 595.08 13.71 5 2 -2 644.13 18.06 5 2 -2 618.44 11.55 5 -2 -2 531.56 14.63 5 -2 -2 502.71 14.30 5 -2 -1 53.69 4.63 5 2 -1 48.70 3.38 5 2 0 685.44 16.91 5 -2 0 686.96 15.12 5 2 0 710.23 12.23 5 2 1 90.07 6.28 5 2 1 94.26 4.40 5 2 2 603.02 15.44 5 -2 2 612.69 15.57 5 2 2 583.43 10.66 5 2 3 471.24 12.80 5 -2 3 460.77 13.50 5 -2 3 444.60 15.36 5 2 4 811.06 15.81 5 -2 4 757.79 17.46 5 -2 5 47.04 4.37 5 -2 5 58.00 5.88 5 -2 6 280.09 10.32 5 -2 6 216.83 11.24 5 -2 7 677.92 15.04 5 -2 7 529.85 17.65 5 -2 8 179.07 7.29 5 -2 8 136.72 8.83 5 -2 9 11.09 2.53 5 -2 10 52.83 5.13 5 -2 11 24.21 3.26 5 -2 12 31.54 3.46 5 -2 13 25.93 2.82 5 -2 14 24.65 2.38 5 3 -14 14.23 1.62 5 3 -13 40.77 3.47 5 3 -12 32.04 3.56 5 3 -11 93.46 6.82 5 3 -10 34.28 4.47 5 3 -9 41.31 5.04 5 3 -8 195.19 11.22 5 3 -7 12.58 3.26 5 3 -6 219.93 12.40 5 -3 -5 331.37 10.04 5 3 -5 332.67 15.28 5 -3 -4 474.71 12.27 5 3 -4 498.01 18.25 5 -3 -4 485.28 12.38 5 -3 -3 789.57 15.95 5 -3 -3 769.14 15.56 5 -3 -2 211.93 8.45 5 3 -2 227.48 11.26 5 -3 -2 196.21 8.30 5 3 -1 239.86 10.99 5 -3 -1 245.50 9.77 5 -3 0 332.53 11.85 5 -3 0 326.65 11.55 5 3 1 105.77 6.58 5 -3 1 124.05 7.52 5 -3 2 781.46 19.83 5 -3 2 820.33 19.95 5 -3 3 507.96 16.05 5 -3 3 519.10 15.93 5 -3 4 104.22 7.33 5 -3 4 172.55 9.07 5 -3 5 178.37 9.41 5 -3 5 175.87 9.29 5 -3 6 147.95 8.16 5 -3 6 97.35 6.72 5 -3 7 53.43 4.76 5 -3 7 86.55 6.40 5 -3 8 9.85 1.83 5 -3 8 12.02 2.33 5 -3 9 10.49 1.61 5 -3 9 12.10 2.21 5 -3 10 54.35 4.28 5 -3 11 14.25 1.97 5 -3 12 9.35 1.39 5 4 -12 0.53 0.25 5 4 -11 28.62 3.09 5 4 -10 1.23 0.69 5 4 -9 252.22 10.94 5 4 -8 20.66 3.26 5 4 -7 62.40 6.08 5 4 -6 38.34 4.71 5 4 -5 13.90 2.83 5 -4 -4 8.70 1.57 5 4 -4 7.28 1.95 5 -4 -3 129.88 6.15 5 4 -3 125.95 7.97 5 -4 -2 21.33 2.60 5 4 -2 19.03 2.98 5 4 -1 262.24 10.18 5 -4 -1 267.19 9.92 5 4 0 35.12 3.63 5 -4 0 47.84 4.72 5 -4 1 24.97 3.29 5 -4 1 23.45 2.51 5 -4 2 16.57 3.17 5 -4 2 55.75 4.00 5 -4 3 8.94 2.02 5 -4 3 7.29 1.45 5 4 4 17.13 1.95 5 -4 4 24.92 3.41 5 -4 4 20.24 2.40 5 4 5 36.67 2.79 5 -4 5 48.20 4.66 5 4 6 117.02 4.88 5 -4 6 145.94 7.53 5 4 7 11.73 1.50 5 -4 7 13.73 2.15 5 -4 8 78.16 4.60 5 4 8 80.87 3.92 5 4 9 0.81 0.35 5 -4 9 1.79 0.60 5 -4 10 88.71 3.42 5 4 10 79.01 3.40 5 5 -9 7.41 1.25 5 5 -8 2.75 0.93 5 5 -7 7.45 1.42 5 5 -6 10.37 1.77 5 5 -5 65.81 4.33 5 5 -4 7.34 1.41 5 -5 -3 39.16 2.82 5 5 -3 27.19 2.62 5 -5 -2 24.43 2.35 5 -5 -1 88.05 4.61 5 -5 0 103.21 5.18 5 5 0 96.62 4.34 5 -5 1 60.40 4.11 5 5 1 53.26 3.16 5 5 2 29.13 2.29 5 -5 2 36.67 3.32 5 5 3 11.35 1.37 5 -5 3 12.38 1.92 5 5 4 41.36 2.56 5 -5 4 49.47 3.75 5 5 5 53.28 2.79 5 -5 5 66.20 4.12 5 5 6 35.62 2.17 5 -5 6 45.03 3.14 5 -5 7 79.08 3.63 5 5 7 67.73 2.85 5 -5 8 1.80 0.49 6 0 -15 7.61 1.12 6 0 -14 9.38 1.47 6 0 -13 8.19 1.53 6 0 -12 0.75 0.51 6 0 -11 7.76 1.80 6 0 -10 57.50 5.06 6 0 -9 4.98 1.56 6 0 -9 8.00 1.30 6 0 -9 5.65 1.30 6 0 -8 5.77 2.00 6 0 -8 3.70 1.13 6 0 -8 3.62 0.88 6 0 -7 7.02 1.68 6 0 -7 7.19 1.26 6 0 -6 63.77 5.16 6 0 -6 61.00 3.71 6 0 -5 14.11 2.43 6 0 -5 11.39 1.57 6 0 -5 10.55 1.96 6 0 -4 8.32 2.10 6 0 -4 9.12 1.97 6 0 -4 9.42 1.44 6 0 -4 6.49 1.39 6 0 -3 305.84 11.15 6 0 -3 285.85 8.34 6 0 -3 235.04 8.70 6 0 -3 247.45 11.13 6 0 -2 1.87 1.64 6 0 -2 1.66 0.86 6 0 -1 305.49 10.72 6 0 -1 251.71 9.79 6 0 0 147.59 8.15 6 0 1 43.37 4.38 6 0 2 103.98 6.89 6 0 3 44.66 4.67 6 0 4 75.25 6.15 6 0 5 107.72 7.60 6 0 6 813.17 21.15 6 0 7 187.01 9.95 6 0 8 102.92 7.22 6 0 9 0.04 0.21 6 0 10 26.26 3.39 6 0 11 2.61 0.96 6 0 12 136.92 6.71 6 0 13 0.59 0.41 6 1 -14 11.89 1.48 6 -1 -14 11.96 1.62 6 1 -13 3.70 0.96 6 -1 -13 3.58 0.96 6 1 -12 3.75 1.12 6 -1 -12 4.42 1.26 6 1 -11 28.28 3.26 6 -1 -11 30.96 3.43 6 1 -10 17.04 2.70 6 -1 -10 18.46 2.78 6 1 -9 158.14 8.11 6 -1 -9 167.40 5.19 6 1 -9 96.82 6.61 6 -1 -9 97.63 6.62 6 1 -8 47.44 4.61 6 -1 -8 51.58 3.12 6 1 -8 31.92 3.87 6 -1 -8 31.60 3.81 6 1 -7 138.68 8.08 6 1 -7 159.31 6.06 6 -1 -7 135.76 5.23 6 1 -7 96.42 6.91 6 -1 -7 99.38 6.74 6 1 -6 170.91 9.11 6 1 -6 182.93 6.47 6 -1 -6 154.13 5.76 6 1 -6 128.63 7.97 6 -1 -6 136.99 8.11 6 1 -5 139.87 8.29 6 1 -5 145.75 5.88 6 -1 -5 118.30 6.00 6 1 -5 104.88 7.18 6 -1 -5 101.45 6.95 6 1 -4 12.19 2.48 6 1 -4 11.78 1.66 6 -1 -4 9.59 2.07 6 -1 -4 9.73 2.28 6 -1 -3 6.77 1.86 6 1 -3 7.43 1.90 6 1 -3 8.38 1.37 6 -1 -3 12.00 2.44 6 1 -2 0.92 0.82 6 1 -2 0.47 0.31 6 1 -1 32.24 3.71 6 1 -1 26.23 2.41 6 -1 -1 30.81 3.60 6 1 0 159.09 5.94 6 -1 0 151.62 8.29 6 1 1 33.17 3.58 6 1 1 29.93 2.53 6 -1 1 27.55 3.69 6 1 2 146.41 5.49 6 1 2 139.95 7.36 6 -1 2 131.80 8.08 6 1 3 124.92 4.90 6 1 3 115.30 6.72 6 -1 3 115.02 7.72 6 1 4 115.04 6.85 6 -1 4 135.89 8.70 6 1 5 226.56 9.94 6 -1 5 240.54 11.59 6 -1 6 63.76 6.06 6 1 6 65.13 5.41 6 -1 7 40.12 4.71 6 1 7 36.50 4.06 6 -1 8 26.20 3.71 6 1 8 21.94 3.11 6 -1 9 39.72 4.33 6 1 9 37.13 3.86 6 -1 10 30.80 3.69 6 1 10 27.13 3.15 6 -1 11 22.86 2.92 6 1 11 21.55 2.61 6 -1 12 8.95 1.63 6 1 12 7.52 1.37 6 -1 13 76.16 4.08 6 -2 -13 19.88 2.00 6 2 -12 43.65 3.20 6 -2 -12 27.60 2.67 6 2 -11 19.78 2.44 6 2 -11 14.52 1.95 6 -2 -11 13.09 1.95 6 2 -10 31.41 3.11 6 -2 -10 28.96 3.09 6 2 -9 83.96 5.36 6 -2 -9 79.18 5.36 6 2 -8 179.97 8.24 6 -2 -8 179.81 8.32 6 2 -7 199.81 9.89 6 -2 -7 209.29 6.10 6 2 -7 155.43 7.94 6 -2 -7 152.56 7.64 6 2 -6 428.06 14.61 6 -2 -6 342.89 11.39 6 2 -5 17.45 3.00 6 -2 -5 14.05 2.28 6 2 -4 295.61 12.20 6 -2 -4 278.11 10.30 6 2 -3 25.65 2.56 6 -2 -3 33.94 3.68 6 2 -2 834.68 20.27 6 2 -2 861.30 14.02 6 -2 -1 16.26 2.46 6 2 -1 16.39 2.81 6 2 -1 22.88 2.32 6 -2 -1 15.83 2.57 6 -2 0 164.91 7.84 6 2 0 156.91 8.23 6 2 0 161.34 5.91 6 -2 1 79.53 5.44 6 2 1 70.10 5.24 6 2 1 77.43 4.00 6 -2 1 70.97 5.80 6 2 2 575.70 14.20 6 -2 2 561.92 14.44 6 2 2 577.41 10.44 6 -2 3 104.82 6.19 6 -2 3 95.85 8.24 6 -2 4 2.24 1.31 6 -2 4 1.45 0.59 6 -2 5 20.03 2.63 6 -2 5 33.11 4.38 6 -2 6 87.23 5.30 6 -2 6 66.50 5.80 6 -2 7 12.75 1.88 6 -2 7 9.91 2.29 6 -2 8 95.01 6.40 6 -2 9 46.41 4.21 6 -2 10 21.68 2.62 6 -2 11 5.04 1.12 6 -2 12 5.62 1.05 6 3 -12 25.21 2.09 6 3 -11 80.10 4.32 6 3 -10 14.05 2.03 6 3 -9 2.51 0.94 6 3 -8 35.67 3.78 6 3 -7 98.24 6.56 6 3 -6 119.80 7.40 6 3 -5 94.45 6.61 6 3 -4 323.49 12.08 6 3 -3 406.75 13.59 6 -3 -3 387.03 10.66 6 -3 -2 134.32 6.67 6 3 -2 122.07 7.44 6 -3 -2 113.25 5.82 6 -3 -1 74.17 5.06 6 3 -1 69.47 5.48 6 -3 0 256.30 9.52 6 3 0 243.58 9.73 6 3 1 81.20 5.25 6 -3 1 84.65 5.43 6 -3 1 83.49 5.58 6 -3 2 128.23 6.63 6 -3 2 157.94 7.91 6 -3 3 175.59 7.73 6 -3 3 216.46 9.29 6 -3 4 135.09 6.65 6 -3 4 114.82 6.61 6 -3 5 18.31 2.39 6 -3 5 17.67 2.59 6 -3 6 5.05 1.40 6 -3 6 3.28 0.94 6 -3 7 39.78 3.12 6 -3 7 26.30 2.93 6 -3 8 77.43 3.89 6 -3 8 50.49 3.77 6 -3 9 2.99 0.81 6 -3 10 28.84 2.19 6 4 -10 10.37 1.33 6 4 -9 6.98 1.22 6 4 -8 7.72 1.39 6 4 -7 32.56 3.02 6 4 -6 19.51 2.44 6 4 -5 31.62 3.18 6 4 -4 12.73 2.04 6 4 -3 16.86 2.33 6 -4 -2 19.34 2.21 6 4 -2 16.11 2.23 6 -4 -1 6.45 1.33 6 4 -1 4.98 1.14 6 -4 0 93.16 5.12 6 -4 1 17.65 2.27 6 -4 1 17.47 1.89 6 -4 2 3.50 0.97 6 -4 2 5.12 1.06 6 -4 3 26.66 2.68 6 -4 3 21.61 1.98 6 -4 4 22.56 2.39 6 -4 4 17.48 1.71 6 -4 5 9.02 1.46 6 -4 5 8.19 1.08 6 -4 6 12.85 1.59 6 -4 7 79.44 3.60 6 -5 1 57.66 3.01 6 -5 2 5.72 0.94 6 -5 3 71.28 3.22 6 -5 4 5.61 0.85 7 0 -10 22.23 2.55 7 0 -9 23.04 2.80 7 0 -8 9.96 1.97 7 0 -7 7.09 1.14 7 0 -6 41.62 2.73 7 0 -5 16.05 1.77 7 0 -4 24.83 2.25 7 0 -3 144.70 5.50 7 0 -3 129.67 5.43 7 0 -2 239.21 7.08 7 0 -2 195.01 6.83 7 0 -1 15.38 1.78 7 0 -1 12.50 1.80 7 0 0 483.28 10.04 7 0 0 453.05 11.66 7 0 1 135.34 5.24 7 0 1 122.72 6.28 7 0 2 232.02 6.71 7 0 2 211.57 8.51 7 0 3 6.26 1.42 7 0 3 6.90 1.12 7 0 4 44.15 2.67 7 0 4 33.94 3.50 7 0 5 1.10 0.83 7 0 6 0.66 0.64 7 0 7 41.73 3.65 7 0 8 0.72 0.53 7 0 9 137.74 5.77 7 0 10 65.11 3.55 7 -1 -10 39.61 3.20 7 -1 -9 72.20 4.64 7 1 -8 17.36 2.15 7 -1 -8 19.68 1.60 7 1 -7 64.28 4.47 7 -1 -7 65.27 3.17 7 1 -6 21.21 2.66 7 -1 -6 22.71 1.98 7 1 -5 78.18 5.27 7 1 -5 88.90 4.22 7 -1 -5 75.11 3.68 7 1 -4 132.33 6.89 7 1 -4 148.74 5.54 7 -1 -4 129.30 5.00 7 1 -3 6.80 1.64 7 1 -3 7.30 1.24 7 -1 -3 6.15 1.06 7 -1 -3 5.93 1.25 7 -1 -2 4.23 1.04 7 -1 -2 3.10 0.73 7 1 -1 140.37 5.30 7 -1 -1 136.63 6.54 7 1 0 15.22 1.73 7 -1 0 14.12 2.19 7 1 1 121.90 4.78 7 -1 1 101.11 5.90 7 1 2 24.86 2.07 7 -1 2 29.27 3.56 7 1 3 31.17 2.17 7 -1 3 32.53 3.58 7 -1 4 37.59 3.84 7 -1 5 52.59 2.98 7 -1 5 43.58 4.08 7 -1 6 6.30 1.56 7 -1 7 33.66 3.35 7 -1 8 13.74 2.00 7 -1 9 143.14 5.98 7 -1 10 1.17 0.48 7 2 -10 55.13 2.89 7 2 -9 37.33 2.79 7 2 -8 74.49 4.35 7 2 -7 73.70 4.65 7 -2 -7 85.66 3.18 7 2 -6 254.86 9.06 7 -2 -6 261.58 6.02 7 2 -5 4.56 1.20 7 -2 -5 1.45 0.45 7 2 -4 88.53 5.53 7 -2 -4 86.52 3.95 7 2 -3 195.51 8.27 7 -2 -3 175.78 6.67 7 2 -2 14.05 2.21 7 -2 -2 11.38 1.74 7 -2 -1 43.59 3.39 7 -2 0 3.42 0.96 7 -2 1 21.62 2.96 7 -2 2 18.03 2.95 7 -2 3 61.32 4.41 7 -2 4 122.76 6.26 7 -2 5 23.79 2.73 7 -2 6 8.20 1.48 7 -2 7 10.78 1.62 7 -2 8 0.33 0.28 7 -2 9 6.44 1.02 7 3 -8 53.49 3.11 7 3 -7 80.16 4.15 7 3 -6 72.21 4.19 7 3 -5 53.44 3.73 7 -3 -5 58.02 2.51 7 3 -4 21.25 2.39 7 -3 -4 28.20 1.93 7 3 -3 29.86 2.85 7 3 -2 239.78 7.80 7 -3 0 42.83 3.43 7 -3 1 2.99 0.85 7 -3 2 12.67 1.58 7 -3 3 15.37 1.73 7 -3 4 5.18 1.06 7 -3 5 25.72 2.09 7 -3 6 4.74 0.86 8 0 -3 73.89 3.10 8 0 -2 75.06 3.14 8 0 -1 13.07 1.31 8 0 0 4.14 0.77 8 0 1 8.71 1.04 8 0 2 5.77 0.84 8 0 2 39.68 2.20 8 -1 -5 145.10 3.80 8 -1 -4 16.63 1.36 8 -1 -3 66.60 2.85 8 -1 -2 40.56 2.27 8 -1 -1 16.69 1.46 8 -1 0 5.89 0.89 8 -1 1 44.45 2.33 8 -1 1 55.04 2.85 8 -1 2 46.35 2.26 8 -1 2 38.79 2.33 8 -1 3 3.11 0.57 8 -1 3 40.42 2.40 8 -1 4 20.37 1.61 8 -2 -3 8.52 0.88 8 -2 -2 12.13 1.10 8 -2 -1 9.38 0.97 8 -2 0 23.05 1.52 8 -2 1 5.10 0.70 8 -2 2 3.09 0.52 8 -2 2 4.59 0.76 0 0 0 0.00 0.00 TITL 179-4 in P2(1)/m REM P2(1)/m (#11 in standard setting) CELL 1.54184 6.785606 6.044200 16.629247 90.0000 92.6827 90.0000 ZERR 3.00 0.000358 0.000357 0.000905 0.0000 0.0049 0.0000 LATT 1 SYMM -x, y+1/2,-z SFAC C H N O UNIT 33.00 30.00 3.00 3.00 TREF HKLF 4 END _computing_structure_solution 'SHELXT 2018/2 (Sheldrick, 2018)' ; _shelx_hkl_checksum 39389 _olex2_submission_special_instructions 'No special instructions were received' _oxdiff_exptl_absorpt_empirical_details ; Empirical correction (ABSPACK) includes: - Absorption correction using spherical harmonics - Frame scaling ; _oxdiff_exptl_absorpt_empirical_full_max 1.502 _oxdiff_exptl_absorpt_empirical_full_min 0.480 loop_ _space_group_symop_operation_xyz 'x, y, z' '-x, y+1/2, -z' loop_ _atom_site_label _atom_site_type_symbol _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_U_iso_or_equiv _atom_site_adp_type _atom_site_occupancy _atom_site_site_symmetry_order _atom_site_calc_flag _atom_site_refinement_flags_posn _atom_site_refinement_flags_adp _atom_site_refinement_flags_occupancy _atom_site_disorder_assembly _atom_site_disorder_group O1 O -0.2023(4) 0.1630(7) 0.0983(2) 0.0340(9) Uani 1 1 d . . . . . O2 O -0.2364(5) 0.5097(8) 0.0509(2) 0.0489(11) Uani 1 1 d . . . . . O3 O 1.3049(4) 0.8989(6) 0.3666(2) 0.0313(9) Uani 1 1 d . . . . . O4 O 1.1353(4) 0.4848(6) 0.39109(17) 0.0239(7) Uani 1 1 d . . . . . O5 O 1.1424(5) 0.6494(7) 0.5123(2) 0.0349(9) Uani 1 1 d . . . . . C1 C 0.0426(6) 0.4200(9) 0.1366(3) 0.0259(11) Uani 1 1 d . . . . . C2 C 0.1268(6) 0.6288(9) 0.1318(3) 0.0271(11) Uani 1 1 d . . . . . H2 H 0.065165 0.737710 0.100148 0.033 Uiso 1 1 calc R U . . . C3 C 0.3034(6) 0.6747(9) 0.1744(2) 0.0234(10) Uani 1 1 d . . . . . H3 H 0.358220 0.815403 0.171695 0.028 Uiso 1 1 calc R U . . . C4 C 0.3990(6) 0.5125(8) 0.2212(2) 0.0224(10) Uani 1 1 d . . . . . C5 C 0.3120(6) 0.3029(8) 0.2268(3) 0.0238(11) Uani 1 1 d . . . . . H5 H 0.373105 0.193487 0.258377 0.029 Uiso 1 1 calc R U . . . C6 C 0.1347(7) 0.2593(9) 0.1849(3) 0.0300(12) Uani 1 1 d . . . . . H6 H 0.076607 0.120689 0.189314 0.036 Uiso 1 1 calc R U . . . C7 C 0.5837(6) 0.5587(8) 0.2657(3) 0.0244(11) Uani 1 1 d . . . . . C8 C 0.7062(6) 0.7681(9) 0.2709(3) 0.0240(11) Uani 1 1 d . . . . . H8A H 0.645955 0.889548 0.298994 0.029 Uiso 1 1 calc R U . . . H8B H 0.758111 0.815634 0.220392 0.029 Uiso 1 1 calc R U . . . C9 C 0.8482(6) 0.6245(9) 0.3238(3) 0.0251(11) Uani 1 1 d . . . . . C10 C 0.7132(6) 0.4399(8) 0.3134(3) 0.0270(12) Uani 1 1 d . . . . . H10 H 0.714517 0.295006 0.332269 0.032 Uiso 1 1 calc R U . . . C11 C 1.0278(6) 0.6586(9) 0.3572(2) 0.0236(10) Uani 1 1 d . . . . . C12 C 1.1272(6) 0.8706(8) 0.3516(3) 0.0250(11) Uani 1 1 d . . . . . H12 H 1.051838 0.992770 0.335619 0.030 Uiso 1 1 calc R U . . . C13 C 1.1993(6) 0.5012(9) 0.4699(3) 0.0268(11) Uani 1 1 d . . . . . C14 C 1.3393(7) 0.3250(10) 0.4927(3) 0.0310(12) Uani 1 1 d . . . . . H14A H 1.274253 0.184241 0.488072 0.046 Uiso 1 1 calc R U . . . H14B H 1.387466 0.346895 0.547354 0.046 Uiso 1 1 calc R U . . . H14C H 1.447808 0.328545 0.457744 0.046 Uiso 1 1 calc R U . . . C15 C -0.1464(6) 0.3769(10) 0.0904(3) 0.0283(12) Uani 1 1 d . . . . . C16 C -0.3860(6) 0.1019(10) 0.0559(3) 0.0360(14) Uani 1 1 d . . . . . H16A H -0.387879 0.159758 0.002148 0.054 Uiso 1 1 calc R U . . . H16B H -0.494799 0.162001 0.083696 0.054 Uiso 1 1 calc R U . . . H16C H -0.396928 -0.056341 0.053978 0.054 Uiso 1 1 calc R U . . . loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_23 _atom_site_aniso_U_13 _atom_site_aniso_U_12 O1 0.0229(14) 0.0363(19) 0.0415(17) 0.0049(17) -0.0115(13) -0.0096(15) O2 0.044(2) 0.037(2) 0.063(2) 0.010(2) -0.0236(17) -0.0041(19) O3 0.0229(14) 0.0336(18) 0.0371(16) 0.0009(16) -0.0010(12) -0.0088(15) O4 0.0233(13) 0.0251(15) 0.0231(12) -0.0021(14) -0.0009(11) 0.0040(14) O5 0.0354(16) 0.0372(19) 0.0316(15) -0.0107(17) -0.0025(13) 0.0087(17) C1 0.0202(18) 0.029(3) 0.028(2) -0.001(2) -0.0041(16) -0.0001(19) C2 0.026(2) 0.028(2) 0.027(2) 0.005(2) -0.0071(16) 0.003(2) C3 0.0181(17) 0.024(2) 0.0281(19) 0.001(2) 0.0069(15) -0.0058(18) C4 0.0159(17) 0.028(2) 0.0235(17) -0.003(2) 0.0040(14) 0.0025(19) C5 0.0169(18) 0.027(2) 0.0276(19) 0.005(2) -0.0021(16) 0.0007(19) C6 0.032(2) 0.022(2) 0.034(2) 0.005(2) -0.0069(19) -0.003(2) C7 0.024(2) 0.025(2) 0.0246(19) 0.0005(19) -0.0016(17) -0.0011(19) C8 0.0167(18) 0.028(2) 0.0273(19) 0.003(2) 0.0056(16) 0.0021(19) C9 0.0243(19) 0.023(2) 0.0278(19) 0.002(2) 0.0016(16) -0.003(2) C10 0.024(2) 0.026(3) 0.032(2) 0.000(2) 0.0046(17) -0.0018(19) C11 0.0236(19) 0.024(2) 0.0225(18) 0.000(2) -0.0033(16) -0.004(2) C12 0.0238(19) 0.021(2) 0.030(2) -0.002(2) -0.0007(16) -0.002(2) C13 0.0196(18) 0.031(2) 0.030(2) -0.001(2) -0.0011(16) -0.009(2) C14 0.026(2) 0.038(3) 0.029(2) 0.005(2) -0.0014(17) 0.002(2) C15 0.0185(18) 0.035(3) 0.030(2) 0.000(2) -0.0052(16) 0.000(2) C16 0.021(2) 0.048(3) 0.039(2) 0.006(3) -0.0091(18) -0.013(2) loop_ _atom_type_symbol _atom_type_description _atom_type_scat_dispersion_real _atom_type_scat_dispersion_imag _atom_type_scat_source C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' loop_ _geom_angle_atom_site_label_1 _geom_angle_atom_site_label_2 _geom_angle_atom_site_label_3 _geom_angle _geom_angle_site_symmetry_1 _geom_angle_site_symmetry_3 _geom_angle_publ_flag C15 O1 C16 115.7(4) . . ? C13 O4 C11 118.3(4) . . ? C2 C1 C6 119.5(4) . . ? C2 C1 C15 118.5(4) . . ? C6 C1 C15 122.0(5) . . ? C1 C2 H2 120.0 . . ? C1 C2 C3 119.9(4) . . ? C3 C2 H2 120.0 . . ? C2 C3 H3 119.6 . . ? C2 C3 C4 120.8(5) . . ? C4 C3 H3 119.6 . . ? C3 C4 C5 119.1(4) . . ? C3 C4 C7 121.1(4) . . ? C5 C4 C7 119.7(4) . . ? C4 C5 H5 120.1 . . ? C6 C5 C4 119.8(4) . . ? C6 C5 H5 120.1 . . ? C1 C6 H6 119.6 . . ? C5 C6 C1 120.9(5) . . ? C5 C6 H6 119.6 . . ? C4 C7 C8 130.4(4) . . ? C10 C7 C4 135.5(5) . . ? C10 C7 C8 94.0(4) . . ? C7 C8 H8A 114.7 . . ? C7 C8 H8B 114.7 . . ? C7 C8 C9 83.6(4) . . ? H8A C8 H8B 111.8 . . ? C9 C8 H8A 114.7 . . ? C9 C8 H8B 114.7 . . ? C10 C9 C8 89.5(3) . . ? C11 C9 C8 133.4(5) . . ? C11 C9 C10 136.9(5) . . ? C7 C10 C9 92.9(4) . . ? C7 C10 H10 133.6 . . ? C9 C10 H10 133.6 . . ? O4 C11 C12 117.2(4) . . ? C9 C11 O4 120.5(5) . . ? C9 C11 C12 121.9(4) . . ? O3 C12 C11 124.2(4) . . ? O3 C12 H12 117.9 . . ? C11 C12 H12 117.9 . . ? O4 C13 C14 111.7(4) . . ? O5 C13 O4 121.1(4) . . ? O5 C13 C14 127.2(4) . . ? C13 C14 H14A 109.5 . . ? C13 C14 H14B 109.5 . . ? C13 C14 H14C 109.5 . . ? H14A C14 H14B 109.5 . . ? H14A C14 H14C 109.5 . . ? H14B C14 H14C 109.5 . . ? O1 C15 C1 110.8(4) . . ? O2 C15 O1 124.0(4) . . ? O2 C15 C1 125.1(5) . . ? O1 C16 H16A 109.5 . . ? O1 C16 H16B 109.5 . . ? O1 C16 H16C 109.5 . . ? H16A C16 H16B 109.5 . . ? H16A C16 H16C 109.5 . . ? H16B C16 H16C 109.5 . . ? loop_ _geom_bond_atom_site_label_1 _geom_bond_atom_site_label_2 _geom_bond_distance _geom_bond_site_symmetry_2 _geom_bond_publ_flag O1 C15 1.355(7) . ? O1 C16 1.451(5) . ? O2 C15 1.188(7) . ? O3 C12 1.232(5) . ? O4 C11 1.384(6) . ? O4 C13 1.365(5) . ? O5 C13 1.215(6) . ? C1 C2 1.389(7) . ? C1 C6 1.391(7) . ? C1 C15 1.486(6) . ? C2 H2 0.9300 . ? C2 C3 1.392(6) . ? C3 H3 0.9300 . ? C3 C4 1.393(6) . ? C4 C5 1.402(7) . ? C4 C7 1.452(6) . ? C5 H5 0.9300 . ? C5 C6 1.386(6) . ? C6 H6 0.9300 . ? C7 C8 1.515(7) . ? C7 C10 1.361(6) . ? C8 H8A 0.9700 . ? C8 H8B 0.9700 . ? C8 C9 1.541(6) . ? C9 C10 1.449(7) . ? C9 C11 1.332(6) . ? C10 H10 0.9300 . ? C11 C12 1.453(7) . ? C12 H12 0.9300 . ? C13 C14 1.465(7) . ? C14 H14A 0.9600 . ? C14 H14B 0.9600 . ? C14 H14C 0.9600 . ? C16 H16A 0.9600 . ? C16 H16B 0.9600 . ? C16 H16C 0.9600 . ? loop_ _geom_torsion_atom_site_label_1 _geom_torsion_atom_site_label_2 _geom_torsion_atom_site_label_3 _geom_torsion_atom_site_label_4 _geom_torsion _geom_torsion_site_symmetry_1 _geom_torsion_site_symmetry_2 _geom_torsion_site_symmetry_3 _geom_torsion_site_symmetry_4 _geom_torsion_publ_flag O4 C11 C12 O3 8.3(7) . . . . ? C1 C2 C3 C4 0.9(7) . . . . ? C2 C1 C6 C5 -1.7(7) . . . . ? C2 C1 C15 O1 176.7(4) . . . . ? C2 C1 C15 O2 -2.4(7) . . . . ? C2 C3 C4 C5 -1.8(6) . . . . ? C2 C3 C4 C7 179.8(4) . . . . ? C3 C4 C5 C6 1.0(6) . . . . ? C3 C4 C7 C8 -1.0(7) . . . . ? C3 C4 C7 C10 -177.8(5) . . . . ? C4 C5 C6 C1 0.8(7) . . . . ? C4 C7 C8 C9 -177.2(5) . . . . ? C4 C7 C10 C9 176.9(5) . . . . ? C5 C4 C7 C8 -179.3(4) . . . . ? C5 C4 C7 C10 3.8(8) . . . . ? C6 C1 C2 C3 0.8(7) . . . . ? C6 C1 C15 O1 -4.3(6) . . . . ? C6 C1 C15 O2 176.6(5) . . . . ? C7 C4 C5 C6 179.4(4) . . . . ? C7 C8 C9 C10 -0.6(3) . . . . ? C7 C8 C9 C11 173.9(5) . . . . ? C8 C7 C10 C9 -0.6(4) . . . . ? C8 C9 C10 C7 0.6(4) . . . . ? C8 C9 C11 O4 -169.0(4) . . . . ? C8 C9 C11 C12 3.8(8) . . . . ? C9 C11 C12 O3 -164.7(5) . . . . ? C10 C7 C8 C9 0.6(4) . . . . ? C10 C9 C11 O4 2.9(8) . . . . ? C10 C9 C11 C12 175.7(5) . . . . ? C11 O4 C13 O5 9.6(6) . . . . ? C11 O4 C13 C14 -169.8(4) . . . . ? C11 C9 C10 C7 -173.5(6) . . . . ? C13 O4 C11 C9 -123.2(5) . . . . ? C13 O4 C11 C12 63.7(5) . . . . ? C15 C1 C2 C3 179.8(4) . . . . ? C15 C1 C6 C5 179.3(4) . . . . ? C16 O1 C15 O2 -1.2(7) . . . . ? C16 O1 C15 C1 179.7(4) . . . . ?