#------------------------------------------------------------------------------ #$Date: 2019-06-11 07:19:33 +0300 (Tue, 11 Jun 2019) $ #$Revision: 215810 $ #$URL: file:///home/coder/svn-repositories/cod/cif/2/02/16/2021659.cif $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2021659 loop_ _publ_author_name 'Xu, Jie' 'Zhang, Kou-Lin' _publ_section_title ; Preparation, characterization and luminescence-sensing properties of two ZnII MOFs with mixed 5-amino-2,4,6-tribromoisophthalic acid and bipyridyl-type ligands ; _journal_coeditor_code YF3173 _journal_issue 7 _journal_name_full 'Acta Crystallographica Section C Structural Chemistry' _journal_paper_doi 10.1107/S2053229619007435 _journal_volume 75 _journal_year 2019 _chemical_formula_iupac '[Zn (C8 H2 Br3 N O4) (C14 H14 N4 O2) (H2 O)2], H2 O' _chemical_formula_moiety 'C22 H20 Br3 N5 O8 Zn, H2 O' _chemical_formula_sum 'C22 H22 Br3 N5 O9 Zn' _chemical_formula_weight 805.54 _chemical_name_systematic 'Poly[[(\m-5-amino-2,4,6-tribromoisophthalato-\k^2^O^1^:O^3^)diaqua[\m-N,N'-bis(pyridin-4-ylmethyl)oxalamide-\k^2^N:N']zinc(II)] monohydrate]' _space_group_crystal_system orthorhombic _space_group_IT_number 19 _space_group_name_Hall 'P 2ac 2ab' _space_group_name_H-M_alt 'P 21 21 21' _symmetry_space_group_name_Hall 'P 2ac 2ab' _symmetry_space_group_name_H-M 'P 21 21 21' _atom_sites_solution_hydrogens mixed _audit_creation_method SHELXL-2016/6 _cell_angle_alpha 90 _cell_angle_beta 90 _cell_angle_gamma 90 _cell_formula_units_Z 4 _cell_length_a 8.5083(5) _cell_length_b 13.8444(10) _cell_length_c 22.4960(12) _cell_measurement_reflns_used 6891 _cell_measurement_temperature 293(2) _cell_measurement_theta_max 27.0617 _cell_measurement_theta_min 2.3323 _cell_volume 2649.9(3) _computing_cell_refinement ; SMART (Bruker, 2008) ; _computing_data_collection ; SMART (Bruker, 2008) ; _computing_data_reduction ; SAINT (Bruker, 2008) ; _computing_molecular_graphics ; SHELXTL (Bruker, 2008) ; _computing_publication_material ; SHELXTL (Bruker, 2008) ; _computing_structure_refinement ; SHELXL2016 (Sheldrick, 2015b) ; _computing_structure_solution ; SHELXL2016 (Sheldrick, 2015a) ; _diffrn_ambient_temperature 293(2) _diffrn_measured_fraction_theta_full 0.999 _diffrn_measured_fraction_theta_max 0.996 _diffrn_measurement_device_type 'Bruker SMART CCD area detector' _diffrn_measurement_method 'phi and omega scans' _diffrn_radiation_type MoK\a _diffrn_radiation_wavelength 0.71073 _diffrn_reflns_av_R_equivalents 0.0831 _diffrn_reflns_av_unetI/netI 0.1223 _diffrn_reflns_limit_h_max 10 _diffrn_reflns_limit_h_min -11 _diffrn_reflns_limit_k_max 17 _diffrn_reflns_limit_k_min -18 _diffrn_reflns_limit_l_max 27 _diffrn_reflns_limit_l_min -29 _diffrn_reflns_number 24793 _diffrn_reflns_theta_full 25.242 _diffrn_reflns_theta_max 27.536 _diffrn_reflns_theta_min 2.333 _exptl_absorpt_coefficient_mu 5.512 _exptl_absorpt_correction_T_max 0.314 _exptl_absorpt_correction_T_min 0.233 _exptl_absorpt_correction_type empirical _exptl_absorpt_process_details ; (SADABS; Bruker, 2008) ; _exptl_crystal_colour white _exptl_crystal_density_diffrn 2.019 _exptl_crystal_description needle _exptl_crystal_F_000 396 _exptl_crystal_size_max 0.28 _exptl_crystal_size_mid 0.25 _exptl_crystal_size_min 0.21 _refine_diff_density_max 1.696 _refine_diff_density_min -1.133 _refine_ls_abs_structure_details ; Flack x determined using 1290 quotients [(I+)-(I-)]/[(I+)+(I-)] (Parsons et al., 2013) ; _refine_ls_abs_structure_Flack 0.0(4) _refine_ls_extinction_method none _refine_ls_goodness_of_fit_ref 0.996 _refine_ls_hydrogen_treatment constr _refine_ls_matrix_type full _refine_ls_number_parameters 361 _refine_ls_number_reflns 6064 _refine_ls_number_restraints 0 _refine_ls_restrained_S_all 0.996 _refine_ls_R_factor_all 0.1097 _refine_ls_R_factor_gt 0.0457 _refine_ls_shift/su_max 0.000 _refine_ls_shift/su_mean 0.000 _refine_ls_structure_factor_coef Fsqd _refine_ls_weighting_details 'w=1/[\s^2^(Fo^2^)+(0.0320P)^2^] where P=(Fo^2^+2Fc^2^)/3' _refine_ls_weighting_scheme calc _refine_ls_wR_factor_gt 0.0688 _refine_ls_wR_factor_ref 0.0788 _reflns_number_gt 4032 _reflns_number_total 6064 _reflns_threshold_expression 'I > 2\s(I)' _cod_data_source_file yf3173sup1.cif _cod_data_source_block 2 _cod_database_code 2021659 _shelx_space_group_comment ; The symmetry employed for this shelxl refinement is uniquely defined by the following loop, which should always be used as a source of symmetry information in preference to the above space-group names. They are only intended as comments. ; _shelx_hkl_file ; -1 0 0 0.09 0.23 -1 0 0 0.11 0.23 1 0 0 0.40 0.31 1 0 0 0.09 0.18 2 0 0 181.16 7.49 2 0 0 187.76 7.53 -2 0 0 188.33 7.36 -2 0 0 185.50 7.25 3 0 0 -0.81 0.78 3 0 0 -1.15 1.04 -3 0 0 -0.47 0.61 -3 0 0 0.49 0.59 -4 0 0 225.41 9.24 4 0 0 223.60 10.15 4 0 0 220.18 9.91 -4 0 0 226.40 8.96 -5 0 0 0.60 0.83 5 0 0 0.16 1.95 -5 0 0 0.36 1.07 -6 0 0 7.68 1.31 6 0 0 13.28 4.02 -6 0 0 4.24 1.56 6 0 0 6.46 3.16 -7 0 0 1.39 1.12 -7 0 0 -1.02 1.60 7 0 0 0.59 4.05 7 0 0 0.77 5.06 -8 0 0 158.97 7.86 8 0 0 156.23 13.20 8 0 0 159.26 14.63 -8 0 0 152.62 6.87 -9 0 0 2.38 2.32 -9 0 0 1.96 1.60 -10 0 0 48.79 5.51 -10 0 0 46.12 4.71 -11 0 0 3.38 3.54 0 -1 0 -0.54 0.33 0 1 0 -0.08 0.34 0 -1 0 -0.31 0.43 0 1 0 -0.56 0.38 -1 -1 0 92.72 4.26 -1 1 0 88.46 3.40 -1 -1 0 82.90 4.28 1 -1 0 84.65 3.40 1 1 0 91.11 4.34 -1 1 0 82.56 3.34 1 -1 0 91.12 3.41 -2 -1 0 23.03 1.85 -2 1 0 22.19 1.06 2 1 0 22.00 2.56 2 -1 0 24.16 1.36 -2 1 0 23.71 1.29 -2 -1 0 24.82 2.11 2 -1 0 23.24 1.16 2 1 0 23.86 2.28 3 1 0 82.17 4.92 3 1 0 88.41 5.37 3 -1 0 84.57 3.74 3 -1 0 81.10 3.90 -3 -1 0 82.85 4.27 -3 1 0 82.21 3.38 -3 1 0 82.78 3.68 -3 -1 0 84.27 4.21 4 -1 0 -0.36 1.12 4 1 0 -1.96 2.16 -4 1 0 0.18 0.46 4 1 0 -1.27 1.92 4 -1 0 -0.34 1.01 -4 1 0 0.03 0.72 -4 -1 0 -0.12 1.10 -4 -1 0 -0.35 1.07 -5 -1 0 195.11 8.40 5 -1 0 201.26 9.21 5 -1 0 201.96 9.07 -5 1 0 193.76 8.18 5 1 0 191.72 10.71 -5 1 0 182.97 7.97 -5 -1 0 194.93 8.60 5 1 0 190.96 10.22 6 1 0 59.16 6.52 -6 -1 0 59.94 3.74 -6 -1 0 63.59 4.21 6 -1 0 59.00 5.30 -6 1 0 61.56 3.03 6 -1 0 58.52 6.05 -6 1 0 62.32 3.81 6 1 0 65.29 7.13 -7 -1 0 0.67 1.72 -7 -1 0 1.43 1.41 7 -1 0 -2.46 4.38 7 1 0 1.11 5.35 -7 1 0 -0.36 1.53 7 1 0 -5.57 5.64 -7 1 0 -0.18 0.94 7 -1 0 0.61 3.39 8 -1 0 9.68 6.38 -8 1 0 4.87 1.35 -8 1 0 6.96 2.09 8 -1 0 11.20 5.67 8 1 0 22.83 9.65 -8 -1 0 3.81 2.42 8 1 0 26.71 8.07 -8 -1 0 4.96 1.70 -9 1 0 18.86 3.04 -9 -1 0 23.40 2.54 -9 -1 0 23.92 3.54 -9 1 0 20.85 2.52 -10 -1 0 8.05 3.22 -10 -1 0 6.29 2.15 -10 1 0 11.88 4.59 -11 1 0 4.22 3.36 -11 -1 0 0.06 4.88 0 2 0 6.24 1.25 0 -2 0 7.92 1.48 0 -2 0 4.60 1.15 0 2 0 6.63 1.39 -1 2 0 244.05 9.33 1 -2 0 234.78 8.98 1 2 0 244.37 10.63 -1 2 0 236.27 8.99 -1 -2 0 236.89 10.51 1 -2 0 234.20 9.49 -2 -2 0 901.16 34.17 -2 -2 0 919.90 34.03 2 -2 0 816.75 32.49 -2 2 0 828.54 32.44 2 2 0 920.45 34.43 2 -2 0 897.79 32.56 2 -2 0 847.84 32.32 3 -2 0 42.40 1.96 -3 -2 0 40.93 4.33 -3 2 0 41.42 2.34 3 -2 0 39.31 2.24 3 -2 0 45.74 2.03 3 2 0 45.81 4.73 3 2 0 41.14 4.51 -3 -2 0 43.48 3.37 4 -2 0 95.34 4.29 -4 -2 0 97.01 5.31 4 -2 0 91.54 4.61 -4 -2 0 94.32 5.51 4 2 0 102.42 7.40 -4 2 0 92.88 4.27 4 2 0 98.30 7.55 -4 2 0 97.00 3.92 -5 2 0 20.92 1.92 -5 2 0 21.06 1.42 5 -2 0 21.58 2.75 5 2 0 24.50 5.11 -5 -2 0 22.75 2.78 -5 -2 0 23.11 2.66 5 -2 0 24.38 2.86 5 2 0 15.12 4.32 6 -2 0 252.45 11.53 -6 -2 0 265.20 11.45 6 2 0 232.48 14.62 6 2 0 256.48 15.20 -6 2 0 248.91 10.41 -6 -2 0 242.35 10.97 -6 2 0 254.04 9.83 7 2 0 25.35 7.68 7 -2 0 23.03 3.86 7 2 0 13.38 6.70 -7 -2 0 26.56 3.35 -7 -2 0 26.07 2.92 7 -2 0 28.00 5.04 -7 2 0 25.22 2.01 -7 2 0 24.57 2.87 8 2 0 8.86 8.96 8 2 0 4.39 9.12 -8 -2 0 5.55 2.09 -8 -2 0 5.39 2.47 8 -2 0 10.99 4.79 8 -2 0 5.83 1.52 -8 2 0 4.61 1.98 8 -2 0 -9.12 5.67 -9 -2 0 20.37 2.84 9 -2 0 17.63 2.40 9 2 0 16.57 16.58 -9 -2 0 18.52 3.45 -9 2 0 22.37 3.07 -10 -2 0 -0.13 3.10 -10 -2 0 -2.86 2.31 0 3 0 -1.01 1.34 0 3 0 1.00 1.61 0 -3 0 0.01 1.50 0 -3 0 0.27 1.13 -1 3 0 100.59 5.03 -1 -3 0 101.99 6.53 1 -3 0 107.09 5.45 -1 3 0 108.47 4.37 -1 -3 0 103.22 7.29 1 -3 0 108.93 4.29 2 -3 0 188.34 8.05 2 3 0 178.71 9.75 2 -3 0 191.20 7.45 -2 3 0 196.64 7.42 -2 3 0 194.12 7.57 3 3 0 9.03 3.56 3 -3 0 6.36 0.91 -3 -3 0 8.23 2.49 3 -3 0 5.46 1.05 -3 -3 0 5.27 2.31 -3 3 0 5.54 0.82 3 -3 0 5.26 0.59 -4 -3 0 88.36 5.78 4 -3 0 90.72 4.33 4 -3 0 91.45 3.81 4 -3 0 86.96 4.04 -4 -3 0 83.80 5.87 4 3 0 93.90 8.24 -4 3 0 87.21 4.00 5 -3 0 91.79 4.31 -5 -3 0 96.33 5.95 5 -3 0 84.37 4.09 -5 3 0 85.15 4.21 5 3 0 86.84 9.08 5 -3 0 90.28 4.83 -5 -3 0 85.58 6.00 -6 -3 0 3.77 2.48 6 3 0 -12.06 5.98 6 3 0 4.57 6.19 6 -3 0 3.79 2.01 6 -3 0 2.87 1.15 -6 -3 0 5.01 2.28 6 -3 0 7.48 2.15 -6 3 0 3.85 1.36 -7 -3 0 -0.17 2.27 7 -3 0 -0.49 2.64 -7 3 0 -1.19 1.42 7 -3 0 -0.32 1.19 7 3 0 1.89 7.26 -7 -3 0 -0.43 2.13 7 -3 0 2.52 3.29 7 3 0 13.75 8.81 -8 3 0 8.59 2.17 8 -3 0 10.95 1.99 -8 -3 0 4.02 2.95 8 -3 0 6.58 5.48 8 -3 0 7.93 4.25 8 3 0 3.81 10.28 -8 -3 0 3.85 2.58 -9 -3 0 78.51 5.81 9 -3 0 78.43 5.19 -9 3 0 81.48 5.48 -9 -3 0 83.16 6.57 -10 -3 0 -5.05 2.61 -10 -3 0 -3.15 3.47 -10 3 0 -1.39 2.62 0 -4 0 286.84 13.26 0 4 0 316.86 14.67 0 -4 0 308.27 14.20 0 4 0 329.41 13.94 -1 -4 0 381.95 17.86 -1 4 0 365.32 15.14 -1 4 0 377.07 14.44 -1 -4 0 355.89 16.64 1 -4 0 346.57 14.04 1 -4 0 374.60 15.93 1 4 0 377.89 16.72 2 -4 0 20.04 1.30 2 -4 0 17.59 2.37 -2 4 0 20.30 1.94 -2 4 0 18.87 1.32 2 4 0 18.62 3.90 -2 -4 0 19.94 3.73 -3 4 0 118.28 4.94 3 4 0 129.80 8.82 3 -4 0 116.65 5.85 -3 4 0 118.80 4.91 -3 -4 0 111.38 7.68 3 -4 0 117.42 5.02 -4 -4 0 163.50 9.25 4 -4 0 159.21 6.85 4 -4 0 155.13 7.22 -4 4 0 162.94 6.60 4 -4 0 156.89 6.30 -4 -4 0 163.87 9.38 4 4 0 156.72 10.98 -5 -4 0 53.70 5.36 5 -4 0 50.77 3.54 5 -4 0 49.66 3.34 5 4 0 53.37 7.38 5 -4 0 49.38 2.71 -5 4 0 48.97 2.89 -5 -4 0 52.43 5.29 6 -4 0 -1.34 1.50 -6 -4 0 -0.93 2.38 6 4 0 7.73 6.51 6 -4 0 -0.16 1.71 -6 4 0 -0.94 1.09 -6 -4 0 0.70 2.70 6 -4 0 -2.04 1.53 -7 4 0 85.14 4.82 7 4 0 87.57 11.90 -7 -4 0 81.18 6.60 -7 -4 0 100.51 6.85 7 -4 0 93.19 6.34 7 -4 0 89.86 6.33 7 -4 0 83.86 5.17 -8 4 0 0.73 1.76 8 -4 0 3.57 2.32 -8 -4 0 -1.38 2.85 8 -4 0 4.49 4.74 -8 -4 0 -3.92 2.85 8 4 0 -3.13 13.03 -9 -4 0 18.93 4.24 -9 -4 0 16.38 3.52 -9 4 0 20.41 2.96 9 -4 0 9.70 3.86 -10 4 0 6.30 3.28 -10 -4 0 1.97 3.34 0 5 0 3.92 2.96 0 5 0 -2.92 2.75 0 -5 0 -0.73 1.66 0 -5 0 -1.86 2.27 -1 -5 0 372.04 18.29 -1 -5 0 410.54 19.51 1 -5 0 374.65 17.67 1 -5 0 391.98 15.33 1 5 0 409.24 18.36 -1 5 0 411.99 16.82 2 -5 0 65.25 5.64 -2 5 0 73.66 3.45 2 5 0 70.69 7.41 -2 -5 0 71.21 6.68 2 -5 0 67.17 3.17 -2 -5 0 68.58 8.29 -2 5 0 67.54 4.13 3 -5 0 147.49 7.93 -3 5 0 152.57 6.46 -3 -5 0 152.98 9.77 -3 5 0 147.05 6.23 3 5 0 157.96 11.10 4 -5 0 7.70 0.92 -4 -5 0 6.00 4.28 4 -5 0 7.67 1.28 4 5 0 12.34 5.66 -4 -5 0 1.06 3.32 4 -5 0 3.81 2.43 -4 5 0 7.75 1.19 5 5 0 58.62 8.46 5 -5 0 47.51 2.51 5 -5 0 48.87 3.35 -5 -5 0 52.40 6.00 -5 -5 0 43.07 5.42 -5 5 0 46.34 2.88 6 -5 0 -0.10 1.73 6 -5 0 2.26 2.06 -6 5 0 1.33 1.29 -6 -5 0 1.60 3.31 6 -5 0 1.27 1.32 6 5 0 -8.64 7.35 -6 -5 0 2.33 3.45 7 -5 0 38.30 4.17 7 -5 0 38.89 4.50 7 5 0 43.21 11.38 -7 -5 0 48.12 6.10 -7 5 0 39.84 3.29 7 -5 0 49.11 4.90 -7 -5 0 42.35 5.57 -8 -5 0 -1.89 3.56 8 -5 0 -4.20 3.92 -8 5 0 1.66 1.80 8 -5 0 0.67 3.17 -8 -5 0 3.39 3.57 -9 -5 0 84.41 7.46 -9 -5 0 91.49 7.97 -9 5 0 85.64 5.59 -10 -5 0 -0.62 6.96 -10 -5 0 6.94 3.86 0 6 0 16.54 3.73 0 -6 0 10.91 2.35 0 6 0 14.04 4.64 0 -6 0 11.43 3.75 1 6 0 81.25 9.68 -1 6 0 76.19 5.83 1 -6 0 82.53 4.13 1 6 0 73.36 7.54 -1 -6 0 76.75 8.03 1 -6 0 78.37 7.13 -1 6 0 82.98 5.74 -1 -6 0 84.45 8.42 2 6 0 5.60 4.16 2 -6 0 4.22 1.05 -2 6 0 3.85 1.19 2 -6 0 4.18 2.98 -2 -6 0 4.48 3.88 -2 6 0 2.59 2.29 -2 -6 0 2.38 5.28 -3 -6 0 16.90 4.52 3 -6 0 16.46 3.61 3 -6 0 23.56 1.86 -3 6 0 27.80 2.01 3 6 0 22.19 6.14 -3 6 0 23.70 2.89 -4 -6 0 366.82 18.59 4 -6 0 388.13 15.04 -4 6 0 384.07 14.90 4 6 0 390.24 21.23 -4 -6 0 383.39 20.78 -4 6 0 378.10 15.14 4 -6 0 374.62 17.04 -5 -6 0 3.99 4.23 5 6 0 1.18 6.82 5 -6 0 2.57 2.97 5 -6 0 2.80 1.53 -5 -6 0 4.67 3.92 -5 6 0 2.78 1.18 5 -6 0 2.35 1.25 6 -6 0 1.14 3.39 6 6 0 7.40 9.28 6 -6 0 4.46 1.85 6 -6 0 2.13 1.16 -6 -6 0 0.26 3.61 -6 6 0 -0.13 1.32 -6 -6 0 2.42 3.70 7 -6 0 89.83 7.55 7 -6 0 100.40 5.55 7 -6 0 96.25 6.61 -7 -6 0 110.80 9.01 -7 6 0 97.90 5.29 -7 -6 0 104.96 8.34 8 -6 0 23.23 4.80 -8 -6 0 29.11 4.95 -8 6 0 28.70 3.06 -8 -6 0 36.26 5.43 -9 6 0 -0.24 2.15 -9 -6 0 4.69 4.58 -9 -6 0 0.17 4.05 -10 -6 0 33.16 5.89 -10 6 0 19.02 4.36 -10 -6 0 20.42 5.30 0 -7 0 0.55 2.28 0 -7 0 4.83 4.06 0 7 0 2.90 3.32 0 7 0 7.91 4.88 1 7 0 156.35 13.75 -1 -7 0 152.53 11.40 -1 7 0 162.39 8.95 1 7 0 130.02 10.20 1 -7 0 142.12 10.20 1 -7 0 121.75 7.01 -1 -7 0 151.50 11.06 -1 7 0 155.14 8.96 -2 7 0 94.77 5.33 2 7 0 85.37 9.13 2 -7 0 93.58 4.39 -2 -7 0 89.51 9.48 -2 7 0 97.55 6.16 2 -7 0 80.92 7.75 3 -7 0 246.52 9.85 -3 -7 0 233.45 18.22 -3 7 0 250.19 10.20 3 7 0 236.66 15.32 -3 -7 0 230.86 14.91 -3 7 0 244.53 10.69 3 -7 0 237.15 13.40 -4 7 0 5.41 1.36 4 -7 0 5.49 1.30 4 -7 0 1.85 3.87 -4 -7 0 1.12 4.16 4 7 0 -1.18 6.68 -4 7 0 1.50 1.33 -4 -7 0 -3.47 5.94 -5 -7 0 173.89 13.30 5 7 0 186.37 17.36 5 -7 0 195.44 8.68 -5 7 0 211.45 8.62 5 -7 0 201.67 8.05 5 -7 0 202.51 11.63 -5 -7 0 187.12 13.12 6 -7 0 5.05 4.03 -6 -7 0 -4.35 4.21 -6 7 0 4.52 1.63 -6 -7 0 4.95 4.62 6 -7 0 2.10 1.19 6 -7 0 4.24 1.88 -7 7 0 37.81 3.62 7 -7 0 55.35 5.22 -7 -7 0 35.78 6.40 -7 -7 0 31.98 6.28 7 -7 0 43.40 6.17 7 -7 0 42.99 3.59 -8 7 0 0.71 1.98 8 -7 0 -4.90 5.08 -8 -7 0 -3.59 8.47 -8 -7 0 -3.70 4.34 -9 7 0 0.48 2.66 -9 -7 0 3.30 5.01 -9 -7 0 2.40 5.44 -10 7 0 7.80 2.99 -10 -7 0 7.98 5.49 0 8 0 31.30 7.04 0 -8 0 27.41 3.83 0 -8 0 41.11 6.89 0 8 0 29.08 5.37 1 -8 0 -6.06 4.33 -1 8 0 7.06 3.79 1 -8 0 1.61 1.44 -1 -8 0 8.02 5.11 -1 8 0 -2.78 3.17 -1 -8 0 -6.23 4.25 1 8 0 3.97 4.44 1 8 0 2.77 6.43 2 -8 0 234.09 9.83 -2 8 0 240.34 11.89 2 8 0 252.66 16.45 -2 -8 0 243.62 17.71 -2 8 0 240.14 11.39 2 -8 0 221.25 13.95 -2 -8 0 234.21 15.11 3 -8 0 149.24 11.26 -3 8 0 154.54 7.50 -3 -8 0 151.84 12.80 3 -8 0 141.33 6.59 -3 -8 0 157.22 16.45 -3 8 0 155.81 8.05 3 8 0 150.49 14.26 -4 8 0 -1.41 1.37 -4 8 0 3.41 1.72 -4 -8 0 5.04 9.82 4 -8 0 -1.08 4.27 4 8 0 4.48 8.03 -4 -8 0 1.17 4.97 4 -8 0 1.39 1.34 5 -8 0 12.10 2.09 5 -8 0 13.08 5.15 -5 8 0 12.65 2.04 5 -8 0 13.67 1.62 -5 -8 0 11.16 5.40 -5 -8 0 19.91 7.50 -6 8 0 109.22 5.65 -6 -8 0 97.86 10.85 6 -8 0 105.81 4.97 6 -8 0 107.01 6.26 -6 -8 0 115.67 11.83 6 -8 0 111.84 10.57 -7 8 0 -0.51 1.87 7 -8 0 -1.14 1.67 7 -8 0 0.72 5.90 -7 -8 0 1.88 5.35 -7 -8 0 2.22 6.24 -8 8 0 9.19 2.48 -8 -8 0 16.79 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1.04 2.96 -1 -9 -25 8.88 16.61 1 -9 -25 34.84 15.73 -1 -9 25 8.38 3.55 0 0 -26 62.53 7.74 1 0 -26 6.77 5.12 -1 0 -26 8.99 5.61 2 0 -26 -1.09 4.28 -2 0 -26 10.94 6.36 -3 0 -26 9.57 8.10 3 0 -26 7.09 4.53 -4 0 -26 22.95 10.67 4 0 -26 -2.02 4.71 5 0 -26 -0.99 4.89 0 1 -26 2.42 4.47 0 -1 -26 0.81 5.76 1 1 -26 1.69 4.29 -1 -1 -26 2.62 6.41 -1 1 -26 7.19 5.14 1 -1 -26 4.50 5.43 2 1 -26 -5.54 4.06 -2 -1 -26 5.88 7.37 2 -1 -26 13.44 5.72 -2 1 -26 0.94 5.56 -3 -1 -26 8.42 9.17 3 1 -26 13.44 4.62 3 -1 -26 10.69 7.72 -3 1 -26 12.07 8.51 3 -1 -26 13.70 5.75 -4 -1 -26 5.30 11.75 4 1 -26 -7.79 4.39 4 -1 -26 5.82 5.32 -4 1 -26 23.93 10.17 0 -2 -26 19.07 6.79 0 2 -26 9.66 4.43 1 2 -26 7.31 4.12 -1 -2 -26 14.81 7.34 -1 2 -26 20.92 4.90 1 -2 -26 9.25 6.47 -2 -2 -26 15.10 8.62 2 2 -26 7.62 4.30 2 -2 -26 1.88 5.65 2 -2 -26 9.71 3.74 -2 2 -26 11.85 5.05 3 2 -26 7.36 3.87 -3 -2 -26 4.86 9.84 3 -2 -26 7.90 5.98 3 -2 -26 13.41 4.80 -3 2 -26 4.74 6.63 -4 -2 -26 -8.27 12.56 4 2 -26 2.80 4.36 4 -2 -26 6.87 6.09 0 3 -26 2.92 3.99 0 -3 -26 7.86 7.67 -1 -3 -26 -9.21 7.95 1 3 -26 16.27 4.19 1 -3 -26 16.73 2.49 1 -3 -26 28.01 7.90 -1 3 -26 8.27 4.37 2 3 -26 3.18 3.73 -2 -3 -26 11.34 9.61 2 -3 -26 5.98 6.45 -2 3 -26 11.18 4.86 3 3 -26 0.68 3.74 -3 -3 -26 3.15 11.38 -3 3 -26 10.08 5.82 3 -3 -26 10.84 3.66 3 -3 -26 17.90 6.77 -4 -3 -26 36.78 14.40 4 3 -26 7.27 3.84 4 -3 -26 -4.23 6.24 -4 -3 26 2.57 3.54 0 -4 -26 5.56 8.09 0 -4 -26 7.05 1.37 0 4 -26 9.60 4.11 1 4 -26 8.29 3.65 -1 -4 -26 6.05 2.76 -1 -4 -26 8.05 1.08 -1 -4 -26 15.20 9.61 -1 4 -26 9.19 3.94 1 -4 -26 7.41 7.25 -2 -4 -26 18.37 2.01 -2 -4 -26 46.32 11.92 2 4 -26 15.38 3.94 -2 -4 -26 16.96 1.50 2 -4 -26 24.95 2.90 -2 4 -26 9.16 4.64 -2 -4 26 20.85 3.90 2 -4 -26 24.71 8.26 -3 -4 -26 5.51 1.09 3 4 -26 1.73 3.65 -3 -4 -26 7.62 13.95 -3 -4 -26 7.38 1.80 3 -4 -26 15.06 7.23 -3 -4 26 3.38 3.27 -3 4 -26 6.33 5.38 -4 -4 -26 26.41 2.81 -4 -4 -26 29.44 16.85 -4 -4 -26 33.04 3.20 -4 -4 26 22.00 4.35 4 -4 -26 30.57 8.44 0 -5 -26 4.56 9.86 0 5 -26 2.79 3.46 -1 -5 -26 -6.95 10.17 -1 -5 -26 10.48 1.39 1 5 -26 9.32 3.74 1 -5 -26 12.56 2.05 -1 5 -26 13.55 3.86 -1 -5 26 13.75 3.38 1 -5 -26 24.87 9.97 -2 -5 -26 1.97 12.80 -2 -5 -26 9.59 3.91 -2 5 -26 10.15 4.19 2 -5 -26 13.76 7.82 -2 -5 26 1.35 3.07 -3 -5 -26 5.70 13.57 -3 -5 -26 0.01 1.34 -3 -5 -26 0.59 2.82 3 -5 -26 6.27 8.37 -3 -5 26 -1.57 3.15 -4 -5 -26 -9.82 17.51 0 -6 -26 -4.29 10.56 0 -6 -26 0.33 1.38 0 -6 26 1.11 2.84 0 6 -26 -2.37 3.17 -1 -6 -26 4.83 11.37 -1 -6 26 0.45 3.21 -1 6 -26 2.83 3.58 1 -6 -26 9.45 9.76 -2 -6 -26 -4.27 14.13 -2 -6 -26 14.93 6.81 -2 6 -26 13.35 4.14 2 -6 -26 15.20 9.92 -2 -6 26 2.64 3.14 -3 -6 -26 -7.58 15.93 -3 -6 -26 3.78 4.40 -3 -6 26 1.57 3.28 3 -6 -26 -6.01 8.41 0 -7 -26 17.19 12.22 0 -7 26 5.24 3.33 -1 -7 -26 0.35 13.37 -1 7 -26 -2.70 3.42 -1 -7 26 2.63 3.22 1 -7 -26 9.73 11.94 -2 -7 -26 17.04 15.84 2 -7 -26 18.52 10.50 -2 7 -26 11.36 3.86 -2 -7 26 12.04 3.76 0 -8 -26 -12.22 14.11 0 -8 26 2.42 3.27 1 -8 26 1.88 3.14 -1 -8 -26 -38.07 14.92 -1 -8 26 5.16 3.47 -1 8 -26 -2.39 3.39 1 -8 -26 -7.36 12.47 0 0 -27 3.37 5.45 1 0 -27 -0.52 5.04 -1 0 -27 8.07 6.39 2 0 -27 3.18 5.41 -2 0 -27 11.41 7.48 -3 0 -27 2.86 8.55 3 0 -27 -9.78 4.81 4 0 -27 0.78 5.00 0 1 -27 16.16 5.53 0 -1 -27 6.08 6.47 1 1 -27 25.43 5.51 -1 -1 -27 39.64 8.04 1 -1 -27 14.42 6.48 -1 1 -27 15.74 6.19 -2 -1 -27 1.37 8.14 2 1 -27 12.09 5.21 2 -1 -27 1.31 5.87 -2 1 -27 1.43 6.31 -3 -1 -27 2.76 9.95 3 1 -27 14.70 5.32 -3 1 -27 33.06 9.07 3 -1 -27 21.00 6.40 -4 -1 -27 -2.30 13.24 4 1 -27 -6.13 4.27 4 -1 -27 4.09 5.77 0 2 -27 -4.27 4.45 0 -2 -27 14.28 7.76 1 2 -27 2.19 4.35 -1 -2 -27 15.60 8.32 1 -2 -27 10.89 7.19 -1 2 -27 6.85 5.46 -2 -2 -27 -3.09 8.79 2 2 -27 5.12 4.50 2 -2 -27 8.35 6.55 2 -2 -27 -2.23 4.74 -2 2 -27 -2.32 5.84 -3 -2 -27 16.10 10.68 3 2 -27 16.29 4.92 3 -2 -27 0.03 5.71 -3 2 -27 3.75 7.31 3 -2 -27 11.13 5.37 4 2 -27 10.01 4.99 -4 -2 -27 6.24 13.59 4 -2 -27 1.54 5.98 0 -3 -27 -7.48 7.66 0 3 -27 9.59 4.52 1 3 -27 2.84 3.99 -1 -3 -27 -1.64 9.24 1 -3 -27 1.36 2.53 -1 3 -27 5.81 5.02 1 -3 -27 3.51 7.14 -2 -3 -27 2.34 10.18 2 3 -27 6.79 4.21 2 -3 -27 20.98 3.87 2 -3 -27 8.00 7.50 -2 3 -27 12.78 5.84 -3 -3 -27 5.76 12.12 3 3 -27 1.68 4.25 -3 3 -27 2.75 6.50 3 -3 -27 0.95 6.60 0 4 -27 9.77 4.06 0 -4 -27 18.77 10.07 -1 -4 -27 -4.76 9.22 1 4 -27 4.28 4.13 1 -4 -27 -0.16 9.09 1 -4 -27 2.16 1.98 -1 4 -27 1.47 4.23 2 4 -27 -8.48 5.78 -2 -4 -27 -5.65 11.75 2 -4 -27 16.47 8.03 2 -4 -27 4.35 2.48 -2 4 -27 6.97 5.18 3 4 -27 8.89 4.26 -3 -4 -27 13.40 14.00 -3 -4 27 -1.99 3.56 3 -4 -27 1.83 7.97 0 5 -27 10.29 4.29 0 -5 -27 23.63 11.41 0 -5 -27 12.48 1.78 -1 -5 -27 3.18 1.19 1 5 -27 -2.28 3.59 -1 -5 -27 5.47 5.28 -1 -5 -27 16.01 12.12 1 -5 -27 7.21 1.94 1 -5 -27 3.47 10.02 -1 5 -27 -1.41 3.82 -2 -5 -27 6.36 14.26 2 5 -27 1.35 3.90 -2 -5 -27 6.49 2.96 -2 -5 -27 6.35 1.21 -2 -5 27 5.14 3.61 -2 5 -27 10.88 4.98 2 -5 -27 8.15 9.49 0 6 -27 7.23 3.83 0 -6 -27 33.52 13.11 0 -6 -27 13.59 2.45 -1 -6 -27 15.74 13.44 -1 -6 -27 3.55 1.38 1 6 -27 -1.78 3.68 1 -6 -27 28.03 11.02 -1 -6 27 3.90 3.34 -1 6 -27 1.84 4.11 -2 -6 -27 36.31 16.71 -2 -6 -27 13.55 5.45 -2 -6 27 11.41 4.00 2 -6 -27 0.03 10.73 -2 6 -27 22.23 4.85 0 0 -28 6.40 6.56 -1 0 -28 35.20 8.13 1 0 -28 41.68 7.79 -2 0 -28 4.27 7.87 2 0 -28 2.68 5.72 3 0 -28 14.97 5.82 -3 0 -28 24.57 10.56 0 1 -28 4.31 5.83 0 -1 -28 8.12 7.20 1 1 -28 5.12 5.85 -1 -1 -28 -2.53 7.39 1 -1 -28 11.60 7.38 -1 1 -28 4.28 6.01 2 1 -28 1.12 5.11 -2 -1 -28 18.34 9.81 -2 1 -28 11.18 7.43 2 -1 -28 17.41 6.58 -3 -1 -28 28.21 11.69 3 1 -28 0.73 5.29 -3 1 -28 12.19 9.13 3 -1 -28 5.00 5.98 0 2 -28 0.52 5.39 0 -2 -28 2.93 8.31 1 2 -28 -6.28 4.71 -1 -2 -28 -3.09 8.11 -1 2 -28 1.31 5.76 1 -2 -28 -1.18 7.41 2 2 -28 3.01 5.06 -2 -2 -28 12.01 9.27 2 -2 -28 3.45 7.02 -2 2 -28 8.04 6.80 0 -3 -28 11.47 9.39 0 3 -28 -6.88 4.50 1 3 -28 -0.22 4.33 -1 -3 -28 5.27 10.14 1 -3 -28 -2.50 8.60 -1 3 -28 11.90 5.71 2 3 -28 -0.11 4.43 -2 -3 -28 5.66 11.01 2 -3 -28 13.45 4.22 2 -3 -28 10.23 8.35 -2 3 -28 16.35 6.49 0 4 -28 4.83 4.75 0 -4 -28 -9.76 10.03 1 4 -28 2.96 4.60 -1 -4 -28 -25.26 10.30 -1 4 -28 16.36 5.16 1 -4 -28 0.85 2.37 1 -4 -28 14.16 9.43 0 5 -28 17.16 4.69 0 -5 -28 17.52 1.98 0 -5 -28 33.44 12.46 0 0 -29 4.18 6.66 1 0 -29 -4.74 6.39 -1 0 -29 -13.93 7.67 0 1 -29 2.54 6.56 0 -1 -29 9.25 8.49 -1 -1 -29 2.02 9.17 1 1 -29 10.15 6.32 1 -1 -29 21.87 7.96 -1 1 -29 28.63 7.76 0 2 -29 9.64 6.17 0 -2 -29 21.22 9.69 0 0 0 0.00 0.00 ; _shelx_hkl_checksum 60456 _shelx_res_file ; TITL XJ.res created by SHELXL-2016/6 at 19:25:55 on 31-Oct-2018 CELL 0.71073 8.5083 13.8444 22.4960 90.000 90.000 90.000 ZERR 4.00 0.0005 0.0010 0.0012 0.000 0.000 0.000 LATT -1 SYMM 0.5-X, -Y, 0.5+Z SYMM -X, 0.5+Y, 0.5-Z SYMM 0.5+X, 0.5-Y, -Z SFAC C H N O Zn Br UNIT 22 22 5 9 1 3 L.S. 10 ACTA BOND $H FMAP 2 PLAN 5 EQIV $8 1/2-x,1-y,1/2+z HTAB O3W O3_$8 EQIV $4 1-x,1/2+y,1/2-z HTAB O2W O3_$4 EQIV $6 1+x,y,z HTAB O2W O3W_$6 HTAB O1W O3W_$6 HTAB N2 O2_$6 EQIV $7 -1/2+x,3/2-y,-z HTAB N3 O6_$7 EQIV $5 2-x,-1/2+y,1/2-z HTAB N4 O2W_$5 HTAB O1W O5_$5 EQIV $3 3/2-x,1-y,1/2+z HTAB C21 N3_$3 HTAB O2W Br3_$3 HTAB O3W O6_$3 HTAB CONF FREE O1 O2 FREE Zn1 H1WB FREE Zn1 H2WB WGHT 0.032000 FVAR 0.11849 MOLE 2 O4 4 0.400481 0.239748 0.154598 11.00000 0.03222 0.03056 = 0.02610 0.00345 -0.00015 -0.00452 MOLE 1 BR1 6 0.994780 0.576280 0.151892 11.00000 0.02293 0.04831 = 0.05686 -0.01140 0.00551 -0.01151 BR2 6 0.359511 0.482572 0.192775 11.00000 0.01891 0.03811 = 0.05277 -0.01796 0.00532 -0.00184 BR3 6 0.738989 0.224885 0.062556 11.00000 0.05534 0.03746 = 0.03714 -0.01684 0.00450 0.00659 C1 1 0.673000 0.592559 0.215978 11.00000 0.00662 0.02948 = 0.03564 -0.00467 -0.00082 -0.00601 C2 1 0.685461 0.510102 0.171401 11.00000 0.02356 0.01329 = 0.01775 0.00036 -0.00508 0.00134 C3 1 0.560189 0.448656 0.161965 11.00000 0.02272 0.02251 = 0.01906 -0.00394 0.00147 0.00542 C4 1 0.571108 0.365413 0.128675 11.00000 0.02471 0.01629 = 0.01593 0.00164 -0.00498 -0.00105 C5 1 0.719003 0.343561 0.104785 11.00000 0.03387 0.02545 = 0.01789 -0.00430 0.00227 0.00707 C6 1 0.848833 0.402951 0.110849 11.00000 0.02268 0.03445 = 0.01744 -0.00268 0.01000 0.00451 C7 1 0.825764 0.487285 0.144047 11.00000 0.02026 0.02628 = 0.02342 -0.00059 -0.00134 0.00108 MOLE 2 C8 1 0.430701 0.302775 0.116781 11.00000 0.02888 0.02513 = 0.02103 -0.00581 0.00566 -0.00640 MOLE 1 C9 1 0.930900 0.773874 0.273011 11.00000 0.02922 0.02852 = 0.03550 0.00511 0.00392 0.00894 AFIX 43 H9 2 0.831663 0.802030 0.272725 11.00000 -1.20000 AFIX 0 C10 1 1.049984 0.817106 0.240013 11.00000 0.03501 0.02988 = 0.03085 0.01492 0.00231 0.00374 AFIX 43 H10 2 1.030355 0.872952 0.218270 11.00000 -1.20000 AFIX 0 C11 1 1.196944 0.776082 0.240028 11.00000 0.02764 0.02413 = 0.01255 -0.00794 -0.00017 0.00098 C12 1 1.219456 0.695451 0.273582 11.00000 0.02327 0.03141 = 0.03150 0.00413 -0.00452 0.00469 AFIX 43 H12 2 1.318121 0.666639 0.275046 11.00000 -1.20000 AFIX 0 C13 1 1.096527 0.656376 0.305390 11.00000 0.02775 0.02925 = 0.03348 0.00757 -0.00422 0.00235 AFIX 43 H13 2 1.114525 0.601386 0.328136 11.00000 -1.20000 AFIX 0 C14 1 1.331439 0.819478 0.204084 11.00000 0.02437 0.03412 = 0.02232 -0.00271 0.00127 -0.00195 AFIX 23 H14A 2 1.304531 0.885056 0.192818 11.00000 -1.20000 H14B 2 1.425171 0.822048 0.228578 11.00000 -1.20000 AFIX 0 C15 1 1.279494 0.771957 0.101589 11.00000 0.02151 0.02233 = 0.02826 -0.00122 0.00680 -0.00281 C16 1 1.333769 0.712183 0.048674 11.00000 0.03099 0.02415 = 0.02775 -0.00204 0.00093 -0.00296 C17 1 1.269321 0.679445 -0.055807 11.00000 0.03502 0.04433 = 0.02645 -0.01176 -0.00269 -0.00755 AFIX 23 H17A 2 1.373986 0.651669 -0.055767 11.00000 -1.20000 H17B 2 1.266971 0.729025 -0.086261 11.00000 -1.20000 AFIX 0 C18 1 1.153635 0.601537 -0.072583 11.00000 0.02458 0.02054 = 0.02965 -0.00408 -0.00509 0.00833 C19 1 1.156226 0.563277 -0.128767 11.00000 0.02321 0.04568 = 0.02401 -0.01089 -0.00010 -0.00589 AFIX 43 H19 2 1.233512 0.582581 -0.155478 11.00000 -1.20000 AFIX 0 C20 1 0.568619 0.498896 0.444781 11.00000 0.04792 0.05329 = 0.01880 -0.01054 0.00037 -0.01619 AFIX 43 H20 2 0.645206 0.520586 0.471084 11.00000 -1.20000 AFIX 0 C21 1 0.461882 0.432514 0.465355 11.00000 0.04089 0.03478 = 0.02395 -0.00157 0.00356 -0.01033 AFIX 43 H21 2 0.467101 0.410624 0.504389 11.00000 -1.20000 AFIX 0 C22 1 0.454535 0.503410 0.354057 11.00000 0.02656 0.04583 = 0.03107 0.01278 0.00253 0.00512 AFIX 43 H22 2 0.448721 0.528192 0.315696 11.00000 -1.20000 AFIX 0 N1 3 0.952348 0.694679 0.304720 11.00000 0.02856 0.01937 = 0.02300 0.00105 0.00032 -0.00070 N2 3 1.364401 0.762782 0.150344 11.00000 0.02239 0.02461 = 0.02055 0.00325 0.00163 0.00148 AFIX 43 H2 2 1.441254 0.722437 0.150657 11.00000 -1.20000 AFIX 0 N3 3 1.242636 0.724668 0.001036 11.00000 0.02154 0.04339 = 0.03418 -0.01317 -0.00445 0.00165 AFIX 43 H3 2 1.162610 0.762205 0.004460 11.00000 -1.20000 AFIX 0 N4 3 0.990193 0.381887 0.083682 11.00000 0.03052 0.04329 = 0.04234 -0.00813 0.01407 0.00246 AFIX 93 H4A 2 0.999273 0.330692 0.062304 11.00000 -1.20000 H4B 2 1.069191 0.419958 0.088133 11.00000 -1.20000 AFIX 0 N5 3 0.570146 0.534627 0.389428 11.00000 0.02979 0.02191 = 0.02912 0.00104 0.00521 0.00124 O1 4 0.704925 0.562857 0.268691 11.00000 0.03845 0.02351 = 0.02207 -0.00497 0.00372 -0.00788 MOLE 2 O2 4 0.636855 0.673254 0.200106 11.00000 0.04897 0.02312 = 0.04852 -0.00467 -0.01300 0.01225 O3 4 0.353810 0.323070 0.071338 11.00000 0.05210 0.04163 = 0.03083 0.01104 -0.01971 -0.02674 MOLE 1 O5 4 1.162734 0.823557 0.097198 11.00000 0.03350 0.04435 = 0.03347 -0.01471 -0.00581 0.01230 O6 4 1.452472 0.660391 0.050908 11.00000 0.04201 0.04735 = 0.02796 -0.00881 -0.00207 0.01659 MOLE 2 O1W 4 0.922527 0.507042 0.376680 11.00000 0.04480 0.03219 = 0.04396 0.01483 -0.00930 -0.00436 AFIX 3 H1WA 2 0.881540 0.442380 0.378767 11.00000 -1.50000 H1WB 2 1.012260 0.516110 0.404962 11.00000 -1.50000 AFIX 0 O3W 4 0.022322 0.534387 0.497199 11.00000 0.07879 0.03543 = 0.03539 0.00050 -0.01744 -0.00092 AFIX 3 H3WA 2 -0.002527 0.481500 0.513991 11.00000 -1.50000 H3WB 2 0.054357 0.574599 0.522777 11.00000 -1.50000 AFIX 0 MOLE 1 ZN1 5 0.755878 0.625280 0.347712 11.00000 0.02971 0.02169 = 0.02270 -0.00183 0.00445 -0.00149 O2W 4 0.839647 0.676898 0.431560 11.00000 0.05111 0.04856 = 0.04248 0.00036 -0.00666 0.01035 AFIX 3 H2WA 2 0.782861 0.713443 0.453277 11.00000 -1.50000 H2WB 2 0.863352 0.626235 0.451095 11.00000 -1.50000 AFIX 0 HKLF 4 REM REM R1 = 0.0457 for 4032 Fo > 4sig(Fo) and 0.1097 for all 6064 data REM 361 parameters refined using 0 restraints END WGHT 0.0314 0.0000 REM Instructions for potential hydrogen bonds HTAB C9 Br2_$4 HTAB C13 O1W EQIV $9 -x+2, y+1/2, -z+1/2 HTAB C14 O1_$9 EQIV $10 x+1/2, -y+3/2, -z HTAB C17 O5_$10 HTAB C22 Br2 HTAB C22 O1 HTAB N2 O2_$6 HTAB N3 O6_$7 HTAB N4 Br3 HTAB N4 O2W_$5 HTAB N4 Br1 HTAB O1W O5_$5 HTAB O1W O3W_$6 HTAB O3W O6_$3 HTAB O3W O3_$8 HTAB O2W Br3_$3 HTAB O2W O3_$4 HTAB O2W O3W_$6 REM Highest difference peak 1.696, deepest hole -1.133, 1-sigma level 0.116 Q1 1 0.7295 0.2702 0.0316 11.00000 0.05 1.70 Q2 1 0.7520 0.1233 0.0546 11.00000 0.05 0.49 Q3 1 0.1546 0.4445 0.4839 11.00000 0.05 0.47 Q4 1 0.7347 0.4333 0.0494 11.00000 0.05 0.44 Q5 1 0.6176 0.4112 0.1983 11.00000 0.05 0.42 ; _shelx_res_checksum 1617 loop_ _space_group_symop_operation_xyz 'x, y, z' '-x+1/2, -y, z+1/2' '-x, y+1/2, -z+1/2' 'x+1/2, -y+1/2, -z' loop_ _atom_site_type_symbol _atom_site_label _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_U_iso_or_equiv _atom_site_adp_type _atom_site_calc_flag _atom_site_occupancy O O4 0.4005(5) 0.2397(4) 0.1546(2) 0.0296(12) Uani d 1 Br Br1 0.99478(8) 0.57628(7) 0.15189(4) 0.0427(2) Uani d 1 Br Br2 0.35951(8) 0.48257(6) 0.19278(3) 0.0366(2) Uani d 1 Br Br3 0.73899(10) 0.22488(7) 0.06256(3) 0.0433(2) Uani d 1 C C1 0.6730(7) 0.5926(6) 0.2160(3) 0.0239(18) Uani d 1 C C2 0.6855(7) 0.5101(5) 0.1714(3) 0.0182(16) Uani d 1 C C3 0.5602(7) 0.4487(6) 0.1620(3) 0.0214(18) Uani d 1 C C4 0.5711(7) 0.3654(6) 0.1287(3) 0.0190(16) Uani d 1 C C5 0.7190(8) 0.3436(6) 0.1048(3) 0.0257(18) Uani d 1 C C6 0.8488(7) 0.4030(6) 0.1108(3) 0.0249(18) Uani d 1 C C7 0.8258(7) 0.4873(6) 0.1440(3) 0.0233(17) Uani d 1 C C8 0.4307(8) 0.3028(6) 0.1168(3) 0.0250(19) Uani d 1 C C9 0.9309(8) 0.7739(6) 0.2730(3) 0.031(2) Uani d 1 H H9 0.831663 0.802030 0.272725 0.037 Uiso calc 1 C C10 1.0500(8) 0.8171(6) 0.2400(3) 0.032(2) Uani d 1 H H10 1.030355 0.872952 0.218270 0.038 Uiso calc 1 C C11 1.1969(7) 0.7761(6) 0.2400(3) 0.0214(17) Uani d 1 C C12 1.2195(8) 0.6955(6) 0.2736(3) 0.0287(19) Uani d 1 H H12 1.318121 0.666639 0.275046 0.034 Uiso calc 1 C C13 1.0965(7) 0.6564(6) 0.3054(3) 0.0302(19) Uani d 1 H H13 1.114525 0.601386 0.328136 0.036 Uiso calc 1 C C14 1.3314(7) 0.8195(6) 0.2041(3) 0.0269(18) Uani d 1 H H14A 1.304531 0.885056 0.192818 0.032 Uiso calc 1 H H14B 1.425171 0.822048 0.228578 0.032 Uiso calc 1 C C15 1.2795(7) 0.7720(6) 0.1016(3) 0.0240(17) Uani d 1 C C16 1.3338(8) 0.7122(6) 0.0487(3) 0.0276(19) Uani d 1 C C17 1.2693(9) 0.6794(6) -0.0558(3) 0.035(2) Uani d 1 H H17A 1.373986 0.651669 -0.055767 0.042 Uiso calc 1 H H17B 1.266971 0.729025 -0.086261 0.042 Uiso calc 1 C C18 1.1536(7) 0.6015(5) -0.0726(3) 0.0249(18) Uani d 1 C C19 1.1562(8) 0.5633(6) -0.1288(3) 0.031(2) Uani d 1 H H19 1.233512 0.582581 -0.155478 0.037 Uiso calc 1 C C20 0.5686(9) 0.4989(7) 0.4448(3) 0.040(2) Uani d 1 H H20 0.645206 0.520586 0.471084 0.048 Uiso calc 1 C C21 0.4619(8) 0.4325(7) 0.4654(3) 0.033(2) Uani d 1 H H21 0.467101 0.410624 0.504389 0.040 Uiso calc 1 C C22 0.4545(7) 0.5034(6) 0.3541(3) 0.034(2) Uani d 1 H H22 0.448721 0.528192 0.315696 0.041 Uiso calc 1 N N1 0.9523(6) 0.6947(5) 0.3047(2) 0.0236(15) Uani d 1 N N2 1.3644(6) 0.7628(4) 0.1503(2) 0.0225(13) Uani d 1 H H2 1.441254 0.722437 0.150657 0.027 Uiso calc 1 N N3 1.2426(7) 0.7247(5) 0.0010(2) 0.0330(16) Uani d 1 H H3 1.162610 0.762205 0.004460 0.040 Uiso calc 1 N N4 0.9902(7) 0.3819(5) 0.0837(2) 0.0387(17) Uani d 1 H H4A 0.999273 0.330692 0.062304 0.046 Uiso calc 1 H H4B 1.069191 0.419958 0.088133 0.046 Uiso calc 1 N N5 0.5701(6) 0.5346(5) 0.3894(2) 0.0269(16) Uani d 1 O O1 0.7049(5) 0.5629(4) 0.26869(18) 0.0280(12) Uani d 1 O O2 0.6369(6) 0.6733(4) 0.2001(2) 0.0402(14) Uani d 1 O O3 0.3538(6) 0.3231(4) 0.0713(2) 0.0415(15) Uani d 1 O O5 1.1627(6) 0.8236(4) 0.0972(2) 0.0371(14) Uani d 1 O O6 1.4525(6) 0.6604(4) 0.0509(2) 0.0391(15) Uani d 1 O O1W 0.9225(6) 0.5070(4) 0.3767(2) 0.0403(15) Uani d 1 H H1WA 0.881540 0.442380 0.378767 0.060 Uiso d 1 H H1WB 1.012260 0.516110 0.404962 0.060 Uiso d 1 O O3W 0.0223(7) 0.5344(4) 0.4972(2) 0.0499(16) Uani d 1 H H3WA -0.002527 0.481500 0.513991 0.075 Uiso d 1 H H3WB 0.054357 0.574599 0.522777 0.075 Uiso d 1 Zn Zn1 0.75588(9) 0.62528(6) 0.34771(3) 0.0247(2) Uani d 1 O O2W 0.8396(6) 0.6769(4) 0.4316(2) 0.0474(15) Uani d 1 H H2WA 0.782861 0.713443 0.453277 0.071 Uiso d 1 H H2WB 0.863352 0.626235 0.451095 0.071 Uiso d 1 loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_12 _atom_site_aniso_U_13 _atom_site_aniso_U_23 O4 0.032(3) 0.031(4) 0.026(2) -0.005(3) 0.000(2) 0.003(3) Br1 0.0229(3) 0.0483(6) 0.0569(5) -0.0115(4) 0.0055(4) -0.0114(5) Br2 0.0189(3) 0.0381(6) 0.0528(4) -0.0018(4) 0.0053(3) -0.0180(4) Br3 0.0553(5) 0.0375(6) 0.0371(4) 0.0066(5) 0.0045(4) -0.0168(4) C1 0.007(3) 0.029(6) 0.036(4) -0.006(3) -0.001(3) -0.005(4) C2 0.024(3) 0.013(5) 0.018(3) 0.001(3) -0.005(2) 0.000(3) C3 0.023(3) 0.023(5) 0.019(3) 0.005(3) 0.001(3) -0.004(3) C4 0.025(3) 0.016(5) 0.016(3) -0.001(3) -0.005(3) 0.002(3) C5 0.034(4) 0.025(5) 0.018(3) 0.007(4) 0.002(3) -0.004(3) C6 0.023(3) 0.034(6) 0.017(3) 0.005(4) 0.010(3) -0.003(4) C7 0.020(3) 0.026(5) 0.023(3) 0.001(3) -0.001(3) -0.001(4) C8 0.029(4) 0.025(6) 0.021(4) -0.006(4) 0.006(3) -0.006(4) C9 0.029(4) 0.029(6) 0.035(4) 0.009(4) 0.004(3) 0.005(4) C10 0.035(4) 0.030(6) 0.031(4) 0.004(4) 0.002(3) 0.015(4) C11 0.028(4) 0.024(5) 0.013(3) 0.001(3) 0.000(3) -0.008(3) C12 0.023(4) 0.031(6) 0.032(4) 0.005(4) -0.005(3) 0.004(4) C13 0.028(4) 0.029(6) 0.033(4) 0.002(4) -0.004(3) 0.008(4) C14 0.024(4) 0.034(5) 0.022(4) -0.002(4) 0.001(3) -0.003(4) C15 0.022(4) 0.022(5) 0.028(4) -0.003(4) 0.007(3) -0.001(4) C16 0.031(4) 0.024(5) 0.028(4) -0.003(4) 0.001(3) -0.002(4) C17 0.035(4) 0.044(6) 0.026(4) -0.008(4) -0.003(3) -0.012(4) C18 0.025(3) 0.021(5) 0.030(4) 0.008(3) -0.005(3) -0.004(3) C19 0.023(3) 0.046(6) 0.024(4) -0.006(4) 0.000(3) -0.011(4) C20 0.048(4) 0.053(7) 0.019(4) -0.016(5) 0.000(3) -0.011(4) C21 0.041(4) 0.035(6) 0.024(4) -0.010(4) 0.004(3) -0.002(4) C22 0.027(3) 0.046(7) 0.031(4) 0.005(4) 0.003(3) 0.013(4) N1 0.029(3) 0.019(4) 0.023(3) -0.001(3) 0.000(2) 0.001(3) N2 0.022(3) 0.025(4) 0.021(3) 0.001(3) 0.002(3) 0.003(3) N3 0.022(3) 0.043(5) 0.034(3) 0.002(4) -0.004(3) -0.013(3) N4 0.031(3) 0.043(5) 0.042(3) 0.002(4) 0.014(3) -0.008(3) N5 0.030(3) 0.022(5) 0.029(3) 0.001(3) 0.005(3) 0.001(3) O1 0.038(3) 0.024(3) 0.022(2) -0.008(2) 0.004(2) -0.005(2) O2 0.049(3) 0.023(4) 0.049(3) 0.012(3) -0.013(3) -0.005(3) O3 0.052(3) 0.042(4) 0.031(3) -0.027(3) -0.020(3) 0.011(3) O5 0.034(3) 0.044(4) 0.033(3) 0.012(3) -0.006(2) -0.015(3) O6 0.042(3) 0.047(4) 0.028(3) 0.017(3) -0.002(2) -0.009(3) O1W 0.045(3) 0.032(4) 0.044(3) -0.004(3) -0.009(2) 0.015(3) O3W 0.079(4) 0.035(4) 0.035(3) -0.001(3) -0.017(3) 0.001(3) Zn1 0.0297(4) 0.0217(5) 0.0227(4) -0.0015(4) 0.0045(4) -0.0018(4) O2W 0.051(3) 0.049(4) 0.042(3) 0.010(3) -0.007(3) 0.000(3) loop_ _atom_type_symbol _atom_type_description _atom_type_scat_dispersion_real _atom_type_scat_dispersion_imag _atom_type_scat_source C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Zn Zn 0.2839 1.4301 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Br Br -0.2901 2.4595 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' loop_ _geom_angle_atom_site_label_1 _geom_angle_atom_site_label_2 _geom_angle_atom_site_label_3 _geom_angle_site_symmetry_1 _geom_angle_site_symmetry_3 _geom_angle C8 O4 Zn1 . 3_645 130.7(4) O2 C1 O1 . . 128.4(7) O2 C1 C2 . . 121.0(6) O1 C1 C2 . . 110.7(7) C7 C2 C3 . . 117.3(6) C7 C2 C1 . . 121.7(6) C3 C2 C1 . . 120.6(5) C4 C3 C2 . . 123.2(6) C4 C3 Br2 . . 117.7(5) C2 C3 Br2 . . 119.0(5) C3 C4 C5 . . 116.7(6) C3 C4 C8 . . 121.8(6) C5 C4 C8 . . 121.5(7) C6 C5 C4 . . 123.4(7) C6 C5 Br3 . . 119.4(5) C4 C5 Br3 . . 117.2(5) N4 C6 C5 . . 121.8(7) N4 C6 C7 . . 122.3(7) C5 C6 C7 . . 115.9(5) C2 C7 C6 . . 123.4(6) C2 C7 Br1 . . 117.7(5) C6 C7 Br1 . . 118.9(4) O4 C8 O3 . . 127.6(7) O4 C8 C4 . . 116.6(6) O3 C8 C4 . . 115.7(7) N1 C9 C10 . . 123.0(7) N1 C9 H9 . . 118.5 C10 C9 H9 . . 118.5 C11 C10 C9 . . 119.0(7) C11 C10 H10 . . 120.5 C9 C10 H10 . . 120.5 C12 C11 C10 . . 117.9(6) C12 C11 C14 . . 120.8(6) C10 C11 C14 . . 121.4(7) C11 C12 C13 . . 120.2(7) C11 C12 H12 . . 119.9 C13 C12 H12 . . 119.9 N1 C13 C12 . . 122.4(7) N1 C13 H13 . . 118.8 C12 C13 H13 . . 118.8 N2 C14 C11 . . 111.7(6) N2 C14 H14A . . 109.3 C11 C14 H14A . . 109.3 N2 C14 H14B . . 109.3 C11 C14 H14B . . 109.3 H14A C14 H14B . . 107.9 O5 C15 N2 . . 124.5(6) O5 C15 C16 . . 119.9(6) N2 C15 C16 . . 115.6(6) O6 C16 N3 . . 125.5(6) O6 C16 C15 . . 122.0(6) N3 C16 C15 . . 112.4(6) N3 C17 C18 . . 115.4(6) N3 C17 H17A . . 108.4 C18 C17 H17A . . 108.4 N3 C17 H17B . . 108.4 C18 C17 H17B . . 108.4 H17A C17 H17B . . 107.5 C19 C18 C21 . 2_664 116.6(7) C19 C18 C17 . . 119.8(6) C21 C18 C17 2_664 . 123.5(6) C18 C19 C22 . 2_664 120.5(7) C18 C19 H19 . . 119.7 C22 C19 H19 2_664 . 119.7 N5 C20 C21 . . 124.5(7) N5 C20 H20 . . 117.7 C21 C20 H20 . . 117.7 C20 C21 C18 . 2_665 119.3(7) C20 C21 H21 . . 120.3 C18 C21 H21 2_665 . 120.3 N5 C22 C19 . 2_665 123.7(6) N5 C22 H22 . . 118.2 C19 C22 H22 2_665 . 118.2 C9 N1 C13 . . 117.5(6) C9 N1 Zn1 . . 120.3(4) C13 N1 Zn1 . . 122.0(5) C15 N2 C14 . . 121.9(6) C15 N2 H2 . . 119.1 C14 N2 H2 . . 119.1 C16 N3 C17 . . 124.4(6) C16 N3 H3 . . 117.8 C17 N3 H3 . . 117.8 C6 N4 H4A . . 120.0 C6 N4 H4B . . 120.0 H4A N4 H4B . . 120.0 C22 N5 C20 . . 115.3(6) C22 N5 Zn1 . . 117.0(5) C20 N5 Zn1 . . 127.4(5) C1 O1 Zn1 . . 136.0(5) Zn1 O1W H1WA . . 117.4 Zn1 O1W H1WB . . 124.8 H1WA O1W H1WB . . 111.2 H3WA O3W H3WB . . 110.2 O1 Zn1 O4 . 3_655 99.63(19) O1 Zn1 O2W . . 171.3(2) O4 Zn1 O2W 3_655 . 88.9(2) O1 Zn1 N1 . . 87.84(19) O4 Zn1 N1 3_655 . 98.4(2) O2W Zn1 N1 . . 89.3(2) O1 Zn1 N5 . . 88.7(2) O4 Zn1 N5 3_655 . 89.2(2) O2W Zn1 N5 . . 93.0(2) N1 Zn1 N5 . . 172.1(2) O1 Zn1 O1W . . 94.5(2) O4 Zn1 O1W 3_655 . 164.67(18) O2W Zn1 O1W . . 77.2(2) N1 Zn1 O1W . . 88.0(2) N5 Zn1 O1W . . 85.2(2) Zn1 O2W H2WA . . 120.9 Zn1 O2W H2WB . . 105.0 H2WA O2W H2WB . . 109.1 loop_ _geom_bond_atom_site_label_1 _geom_bond_atom_site_label_2 _geom_bond_site_symmetry_2 _geom_bond_distance O4 C8 . 1.245(8) O4 Zn1 3_645 2.070(5) Br1 C7 . 1.902(7) Br2 C3 . 1.902(6) Br3 C5 . 1.905(7) C1 O2 . 1.213(9) C1 O1 . 1.284(8) C1 C2 . 1.523(10) C2 C7 . 1.380(8) C2 C3 . 1.380(9) C3 C4 . 1.378(10) C4 C5 . 1.401(9) C4 C8 . 1.500(9) C5 C6 . 1.384(10) C6 N4 . 1.380(8) C6 C7 . 1.400(10) C8 O3 . 1.246(8) C9 N1 . 1.321(9) C9 C10 . 1.391(9) C9 H9 . 0.9300 C10 C11 . 1.373(9) C10 H10 . 0.9300 C11 C12 . 1.361(10) C11 C14 . 1.525(9) C12 C13 . 1.378(9) C12 H12 . 0.9300 C13 N1 . 1.337(8) C13 H13 . 0.9300 C14 N2 . 1.468(8) C14 H14A . 0.9700 C14 H14B . 0.9700 C15 O5 . 1.228(8) C15 N2 . 1.319(8) C15 C16 . 1.522(10) C16 O6 . 1.240(8) C16 N3 . 1.334(8) C17 N3 . 1.442(8) C17 C18 . 1.508(10) C17 H17A . 0.9700 C17 H17B . 0.9700 C18 C19 . 1.371(9) C18 C21 2_664 1.384(9) C19 C22 2_664 1.375(10) C19 H19 . 0.9300 C20 N5 . 1.340(9) C20 C21 . 1.372(11) C20 H20 . 0.9300 C21 H21 . 0.9300 C22 N5 . 1.337(8) C22 H22 . 0.9300 N1 Zn1 . 2.157(5) N2 H2 . 0.8600 N3 H3 . 0.8600 N4 H4A . 0.8600 N4 H4B . 0.8600 N5 Zn1 . 2.226(6) O1 Zn1 . 2.024(4) O1W Zn1 . 2.262(5) O1W H1WA . 0.9619 O1W H1WB . 1.0017 O3W H3WA . 0.8506 O3W H3WB . 0.8458 Zn1 O2W . 2.139(5) O2W H2WA . 0.8533 O2W H2WB . 0.8519 loop_ _geom_hbond_atom_site_label_D _geom_hbond_atom_site_label_H _geom_hbond_atom_site_label_A _geom_hbond_site_symmetry_A _geom_hbond_distance_DH _geom_hbond_distance_HA _geom_hbond_distance_DA _geom_hbond_angle_DHA O3W H3WB O3 2_565 0.85 1.95 2.790(7) 170.9 O2W H2WA O3 3_655 0.85 1.99 2.609(8) 128.6 O2W H2WB O3W 1_655 0.85 2.13 2.914(7) 153.4 O1W H1WB O3W 1_655 1.00 2.09 2.866(6) 132.6 N2 H2 O2 1_655 0.86 2.11 2.857(8) 144.3 N3 H3 O6 4_465 0.86 2.43 3.161(8) 143.5 N4 H4A O2W 3_745 0.86 2.54 3.204(9) 135.2 O1W H1WA O5 3_745 0.96 1.77 2.706(8) 162.9 C21 H21 N3 2_665 0.93 2.59 2.900(10) 100.1 O2W H2WA Br3 2_665 0.85 2.61 3.314(5) 140.7 O3W H3WA O6 2_665 0.85 2.17 2.963(8) 154.0 loop_ _geom_torsion_atom_site_label_1 _geom_torsion_atom_site_label_2 _geom_torsion_atom_site_label_3 _geom_torsion_atom_site_label_4 _geom_torsion_site_symmetry_1 _geom_torsion_site_symmetry_4 _geom_torsion O2 C1 C2 C7 . . 92.3(8) O1 C1 C2 C7 . . -87.8(7) O2 C1 C2 C3 . . -95.0(8) O1 C1 C2 C3 . . 84.9(7) C7 C2 C3 C4 . . 2.3(10) C1 C2 C3 C4 . . -170.7(6) C7 C2 C3 Br2 . . -174.5(5) C1 C2 C3 Br2 . . 12.5(9) C2 C3 C4 C5 . . 1.1(10) Br2 C3 C4 C5 . . 177.9(5) C2 C3 C4 C8 . . -176.9(7) Br2 C3 C4 C8 . . -0.1(9) C3 C4 C5 C6 . . -3.0(10) C8 C4 C5 C6 . . 175.0(6) C3 C4 C5 Br3 . . 176.4(5) C8 C4 C5 Br3 . . -5.5(9) C4 C5 C6 N4 . . -176.0(6) Br3 C5 C6 N4 . . 4.5(9) C4 C5 C6 C7 . . 1.4(10) Br3 C5 C6 C7 . . -178.1(5) C3 C2 C7 C6 . . -4.1(10) C1 C2 C7 C6 . . 168.8(7) C3 C2 C7 Br1 . . 175.5(5) C1 C2 C7 Br1 . . -11.6(9) N4 C6 C7 C2 . . 179.7(6) C5 C6 C7 C2 . . 2.3(10) N4 C6 C7 Br1 . . 0.2(9) C5 C6 C7 Br1 . . -177.2(5) Zn1 O4 C8 O3 3_645 . 13.9(11) Zn1 O4 C8 C4 3_645 . -169.7(4) C3 C4 C8 O4 . . -87.4(9) C5 C4 C8 O4 . . 94.7(8) C3 C4 C8 O3 . . 89.5(8) C5 C4 C8 O3 . . -88.4(9) N1 C9 C10 C11 . . 0.1(12) C9 C10 C11 C12 . . -1.2(11) C9 C10 C11 C14 . . 179.2(6) C10 C11 C12 C13 . . 1.1(10) C14 C11 C12 C13 . . -179.3(6) C11 C12 C13 N1 . . 0.2(11) C12 C11 C14 N2 . . 75.7(7) C10 C11 C14 N2 . . -104.8(8) O5 C15 C16 O6 . . 178.8(7) N2 C15 C16 O6 . . -1.9(10) O5 C15 C16 N3 . . 0.5(10) N2 C15 C16 N3 . . 179.8(6) N3 C17 C18 C19 . . 171.4(7) N3 C17 C18 C21 . 2_664 -6.2(11) C21 C18 C19 C22 2_664 2_664 1.8(11) C17 C18 C19 C22 . 2_664 -175.9(7) N5 C20 C21 C18 . 2_665 0.1(13) C10 C9 N1 C13 . . 1.2(11) C10 C9 N1 Zn1 . . -174.2(6) C12 C13 N1 C9 . . -1.3(10) C12 C13 N1 Zn1 . . 173.9(5) O5 C15 N2 C14 . . -3.8(11) C16 C15 N2 C14 . . 176.9(6) C11 C14 N2 C15 . . 80.7(8) O6 C16 N3 C17 . . -0.2(12) C15 C16 N3 C17 . . 178.0(7) C18 C17 N3 C16 . . 109.2(8) C19 C22 N5 C20 2_665 . -2.4(11) C19 C22 N5 Zn1 2_665 . 171.0(6) C21 C20 N5 C22 . . 2.1(12) C21 C20 N5 Zn1 . . -170.4(6) O2 C1 O1 Zn1 . . -14.4(10) C2 C1 O1 Zn1 . . 165.7(4) _cod_database_fobs_code 2021659