#------------------------------------------------------------------------------ #$Date: 2019-06-25 06:58:24 +0300 (Tue, 25 Jun 2019) $ #$Revision: 216511 $ #$URL: file:///home/coder/svn-repositories/cod/cif/2/02/16/2021683.cif $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2021683 loop_ _publ_author_name 'Hsu, Wayne' _publ_section_title ; Luminescence properties and optimized structural conformations of the S~0~, S~1~ and T~1~ states of a tetranuclear formamidinate complex based on Au^I^ and Ag^I^ metal ions ; _journal_coeditor_code QS3083 _journal_issue 7 _journal_name_full 'Acta Crystallographica Section C' _journal_page_first ; ; _journal_paper_doi 10.1107/S2053229619008581 _journal_volume 75 _journal_year 2019 _chemical_formula_iupac '[Ag Au (C11 H9 N4)2]' _chemical_formula_moiety 'C22 H18 Ag Au N8' _chemical_formula_sum 'C22 H18 Ag Au N8' _chemical_formula_weight 699.28 _chemical_name_systematic Tetrakis[\m-N,N'-bis(pyridin-4-yl)formamidinato]digold(I)disilver(I) _space_group_crystal_system tetragonal _space_group_IT_number 118 _space_group_name_Hall 'P -4 -2n' _space_group_name_H-M_alt 'P -4 n 2' _symmetry_space_group_name_Hall 'P -4 -2n' _symmetry_space_group_name_H-M 'P -4 n 2' _atom_sites_solution_hydrogens geom _atom_sites_solution_primary iterative _audit_creation_method ; Olex2 1.2-beta (compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506) ; _cell_angle_alpha 90 _cell_angle_beta 90 _cell_angle_gamma 90 _cell_formula_units_Z 8 _cell_length_a 16.5350(4) _cell_length_b 16.5350(4) _cell_length_c 18.1127(4) _cell_measurement_reflns_used 9407 _cell_measurement_temperature 296(2) _cell_measurement_theta_max 28.29 _cell_measurement_theta_min 2.85 _cell_volume 4952.1(2) _computing_cell_refinement ; SAINT (Bruker, 2008) ; _computing_data_collection ; APEX2 (Bruker, 2008) ; _computing_data_reduction ; SAINT (Bruker, 2008) ; _computing_molecular_graphics ; OLEX2 (Dolomanov et al., 2009) ; _computing_publication_material ; OLEX2 (Dolomanov et al., 2009) ; _computing_structure_refinement ; SHELXL2018 (Sheldrick, 2015) ; _computing_structure_solution ; olex2.solve (Bourhis et al., 2015) ; _diffrn_ambient_temperature 296.15 _diffrn_measured_fraction_theta_full 0.999 _diffrn_measured_fraction_theta_max 0.995 _diffrn_measurement_device_type 'Bruker APEXII CCD' _diffrn_measurement_method '\f and \w scans' _diffrn_radiation_monochromator graphite _diffrn_radiation_type MoK\a _diffrn_radiation_wavelength 0.71073 _diffrn_reflns_av_R_equivalents 0.0486 _diffrn_reflns_av_unetI/netI 0.0464 _diffrn_reflns_limit_h_max 21 _diffrn_reflns_limit_h_min -16 _diffrn_reflns_limit_k_max 21 _diffrn_reflns_limit_k_min -22 _diffrn_reflns_limit_l_max 23 _diffrn_reflns_limit_l_min -24 _diffrn_reflns_number 23337 _diffrn_reflns_theta_full 25.242 _diffrn_reflns_theta_max 28.323 _diffrn_reflns_theta_min 1.668 _diffrn_standards_number 0 _exptl_absorpt_coefficient_mu 6.733 _exptl_absorpt_correction_T_max 0.7457 _exptl_absorpt_correction_T_min 0.3848 _exptl_absorpt_correction_type multi-scan _exptl_absorpt_process_details ; (SADABS; Bruker, 2008) ; _exptl_crystal_colour colourless _exptl_crystal_density_diffrn 1.876 _exptl_crystal_description plate _exptl_crystal_F_000 2656 _exptl_crystal_size_max 0.35 _exptl_crystal_size_mid 0.25 _exptl_crystal_size_min 0.2 _refine_diff_density_max 1.221 _refine_diff_density_min -0.763 _refine_ls_abs_structure_details ; Flack x determined using 1780 quotients [(I+)-(I-)]/[(I+)+(I-)] (Parsons et al., 2013) ; _refine_ls_abs_structure_Flack -0.070(14) _refine_ls_extinction_method none _refine_ls_goodness_of_fit_ref 1.052 _refine_ls_hydrogen_treatment constr _refine_ls_matrix_type full _refine_ls_number_parameters 299 _refine_ls_number_reflns 5627 _refine_ls_number_restraints 0 _refine_ls_restrained_S_all 1.052 _refine_ls_R_factor_all 0.0410 _refine_ls_R_factor_gt 0.0324 _refine_ls_shift/su_max 0.000 _refine_ls_shift/su_mean 0.000 _refine_ls_structure_factor_coef Fsqd _refine_ls_weighting_details 'w=1/[\s^2^(Fo^2^)+(0.0347P)^2^+5.3324P] where P=(Fo^2^+2Fc^2^)/3' _refine_ls_weighting_scheme calc _refine_ls_wR_factor_gt 0.0771 _refine_ls_wR_factor_ref 0.0802 _reflns_number_gt 4918 _reflns_number_total 5627 _reflns_threshold_expression 'I > 2\s(I)' _cod_data_source_file qs3083sup1.cif _cod_data_source_block I _cod_original_cell_volume 4952.1(3) _cod_database_code 2021683 _shelx_space_group_comment ; The symmetry employed for this shelxl refinement is uniquely defined by the following loop, which should always be used as a source of symmetry information in preference to the above space-group names. They are only intended as comments. ; _shelx_estimated_absorpt_t_min 0.202 _shelx_estimated_absorpt_t_max 0.346 _shelx_hkl_file ; -1 1 0 1000.00 35.96 2 1 0 -0.04 0.08 -2 -1 0 0.10 0.09 -1 2 0 0.04 0.06 -2 -1 0 0.07 0.10 1 -2 0 -0.01 0.08 2 0 0 585.05 22.50 -2 1 0 0.04 0.07 -1 -2 0 0.05 0.10 2 -1 0 0.08 0.08 -2 2 0 392.51 13.94 -2 -2 0 385.41 14.95 2 -2 0 386.17 14.93 -2 3 0 0.01 0.09 -3 -2 0 0.48 0.24 3 2 0 0.14 0.18 2 -3 0 0.00 0.15 1 -3 0 193.96 7.70 3 1 0 202.34 7.69 3 0 0 -0.21 0.11 0 -3 0 -0.37 0.13 -1 -3 0 192.86 7.43 3 -1 0 188.67 7.40 -2 -3 0 0.34 0.22 3 -2 0 0.20 0.15 -3 -3 0 71.98 3.21 3 -3 0 80.90 3.19 -3 3 0 82.86 2.91 -4 -3 0 1.72 0.29 3 -4 0 0.91 0.22 -3 4 0 1.50 0.17 4 3 0 1.10 0.23 -2 4 0 119.85 4.44 4 2 0 121.75 4.79 -4 -2 0 123.45 4.82 2 -4 0 119.94 4.82 4 1 0 5.00 0.39 1 -4 0 4.68 0.40 0 -4 0 335.90 13.01 4 0 0 335.23 12.97 4 -1 0 4.46 0.38 -1 -4 0 4.39 0.42 -2 -4 0 116.61 4.72 4 -2 0 120.21 4.70 -3 -4 0 1.62 0.30 4 -3 0 1.08 0.24 -4 4 0 16.26 0.72 4 -4 0 16.69 0.86 -4 -4 0 16.13 0.91 4 -5 0 8.45 0.59 -4 5 0 8.79 0.48 5 4 0 8.09 0.60 -5 -4 0 7.78 0.64 5 3 0 33.20 1.52 -3 5 0 33.20 1.34 3 -5 0 35.03 1.54 -5 -3 0 33.43 1.55 5 2 0 3.36 0.37 2 -5 0 3.24 0.39 1 -5 0 112.49 4.70 5 1 0 122.49 4.68 0 -5 0 -0.35 0.18 5 0 0 -0.19 0.17 5 -1 0 119.78 4.72 -1 -5 0 117.45 4.76 5 -2 0 2.62 0.31 -2 -5 0 3.18 0.38 5 -3 0 36.21 1.56 -3 -5 0 32.62 1.58 -4 -5 0 8.62 0.70 5 -4 0 9.73 0.64 5 -5 0 1.73 0.35 -5 5 0 1.71 0.29 -5 -5 0 1.79 0.39 -6 -5 0 1.98 0.40 6 5 0 1.26 0.33 5 -6 0 0.85 0.31 -5 6 0 1.37 0.22 6 4 0 10.50 0.73 4 -6 0 12.94 0.78 -4 6 0 12.11 0.62 -6 -4 0 12.61 0.83 6 3 0 18.13 0.95 -6 -3 0 17.56 0.99 3 -6 0 19.37 1.00 -3 6 0 18.16 0.82 6 2 0 154.84 5.97 2 -6 0 145.78 6.00 1 -6 0 2.88 0.40 6 1 0 2.86 0.38 6 0 0 192.16 7.44 0 -6 0 185.99 7.48 -1 -6 0 3.10 0.42 6 -1 0 3.21 0.37 6 -2 0 149.33 5.84 -2 -6 0 144.09 5.86 -3 -6 0 17.49 1.00 6 -3 0 18.78 0.96 6 -4 0 12.47 0.78 -4 -6 0 12.70 0.85 -5 -6 0 1.68 0.41 6 -5 0 1.25 0.34 6 -6 0 37.82 1.79 6 6 0 37.53 1.75 -6 -6 0 38.79 1.83 -6 6 0 36.69 1.52 -7 -6 0 1.42 0.40 7 6 0 1.11 0.35 -6 7 0 1.63 0.26 6 -7 0 2.24 0.43 5 -7 0 41.48 1.88 7 5 0 37.93 1.81 -7 -5 0 38.56 1.88 -5 7 0 40.19 1.61 -4 7 0 14.73 0.72 -7 -4 0 13.33 0.92 4 -7 0 14.76 0.92 7 4 0 15.14 0.89 3 -7 0 117.81 4.76 7 3 0 117.03 4.71 -3 7 0 113.66 4.33 2 -7 0 22.79 1.20 7 2 0 23.45 1.16 1 -7 0 359.45 14.23 7 1 0 370.30 14.18 7 0 0 0.30 0.22 0 -7 0 0.08 0.25 7 -1 0 369.75 14.32 -1 -7 0 367.24 14.36 7 -2 0 23.15 1.16 -2 -7 0 22.93 1.20 7 -3 0 113.68 4.67 -3 -7 0 115.75 4.71 7 -4 0 14.22 0.88 -4 -7 0 15.19 0.97 7 -5 0 42.40 1.97 -5 -7 0 42.18 2.03 7 -6 0 1.63 0.37 -6 -7 0 1.53 0.42 7 7 0 63.76 2.67 -7 7 0 59.04 2.34 -7 -7 0 59.42 2.72 7 -7 0 58.54 2.71 8 7 0 0.24 0.32 7 -8 0 0.52 0.37 -8 -7 0 -0.10 0.37 -7 8 0 0.64 0.23 8 6 0 70.23 3.12 -6 8 0 74.92 2.80 6 -8 0 71.71 3.20 -8 -6 0 72.67 3.19 -8 -5 0 1.14 0.40 8 5 0 0.84 0.33 -5 8 0 1.12 0.24 5 -8 0 1.17 0.38 -4 8 0 113.14 4.34 4 -8 0 116.93 4.81 8 4 0 118.14 4.76 8 3 0 26.49 1.26 -3 8 0 22.61 1.08 3 -8 0 24.26 1.29 8 2 0 317.10 12.27 2 -8 0 310.08 12.31 8 1 0 8.08 0.63 1 -8 0 7.98 0.65 8 0 0 529.83 20.21 0 -8 0 513.28 20.25 8 -1 0 8.25 0.64 -1 -8 0 8.02 0.70 8 -2 0 316.69 12.54 -2 -8 0 324.13 12.59 -3 -8 0 25.11 1.33 8 -3 0 23.46 1.27 8 -4 0 116.47 4.78 -4 -8 0 114.48 4.80 8 -5 0 0.71 0.35 -5 -8 0 0.58 0.39 8 -6 0 74.32 3.20 -6 -8 0 70.04 3.19 -7 -8 0 0.16 0.38 8 -7 0 0.84 0.40 8 -8 0 167.37 6.85 -8 -8 0 167.47 6.82 8 8 0 164.38 6.74 9 8 0 0.78 0.40 8 -9 0 1.22 0.48 -9 -8 0 1.26 0.48 -9 -7 0 164.58 6.66 7 -9 0 159.50 6.69 9 7 0 161.03 6.58 -7 9 0 162.69 6.01 9 6 0 0.97 0.36 -9 -6 0 0.95 0.43 6 -9 0 0.44 0.35 -6 9 0 0.70 0.24 9 5 0 91.05 3.87 -5 9 0 90.52 3.49 5 -9 0 92.79 3.94 4 -9 0 8.54 0.75 -4 9 0 9.99 0.62 9 4 0 8.31 0.73 -3 9 0 190.09 7.23 3 -9 0 197.79 7.88 9 3 0 199.79 7.82 2 -9 0 16.21 1.00 9 2 0 15.58 0.98 9 1 0 437.06 16.84 1 -9 0 427.23 16.89 9 0 0 0.39 0.29 0 -9 0 0.39 0.33 9 -1 0 423.40 16.74 -1 -9 0 436.32 16.80 9 -2 0 15.00 0.93 -2 -9 0 15.60 1.01 -3 -9 0 196.34 8.10 9 -3 0 207.54 8.11 9 -4 0 8.90 0.74 -4 -9 0 8.36 0.80 -5 -9 0 97.36 4.09 9 -5 0 92.28 4.05 9 -6 0 0.77 0.47 -6 -9 0 0.98 0.46 -7 -9 0 158.12 6.62 9 -7 0 164.13 6.66 8 9 0 1.18 0.41 -8 -9 0 0.65 0.47 9 -8 0 0.91 0.45 9 -9 0 314.68 12.27 -9 -9 0 304.49 12.18 9 9 0 298.17 12.09 -10 -9 0 3.42 0.66 9 -10 0 3.67 0.71 10 9 0 3.06 0.56 -10 -8 0 257.63 10.30 -8 10 0 254.51 9.40 10 8 0 258.47 10.23 8 -10 0 254.76 10.37 7 -10 0 14.32 1.08 -7 10 0 12.55 0.75 10 7 0 13.00 0.97 -10 -7 0 11.42 1.02 6 -10 0 166.57 7.10 10 6 0 172.62 7.02 -6 10 0 178.69 6.43 10 5 0 -0.02 0.32 5 -10 0 0.42 0.38 -5 10 0 0.08 0.23 -4 10 0 161.41 6.09 10 4 0 167.44 6.63 4 -10 0 161.51 6.70 -3 10 0 17.87 0.94 3 -10 0 17.45 1.14 10 3 0 16.94 1.08 2 -10 0 323.90 13.00 10 2 0 333.73 12.93 10 1 0 3.29 0.54 1 -10 0 3.71 0.56 10 0 0 458.41 17.85 0 -10 0 456.84 17.91 -1 -10 0 3.35 0.54 10 -1 0 3.47 0.56 -2 -10 0 324.86 12.90 10 -2 0 327.85 12.87 -3 -10 0 18.95 1.19 10 -3 0 18.93 1.17 10 -4 0 169.01 6.98 -4 -10 0 172.20 7.00 10 -5 0 0.51 0.37 -5 -10 0 0.63 0.43 10 -6 0 178.91 7.30 -6 -10 0 176.31 7.30 10 -7 0 13.47 1.06 -7 -10 0 10.79 1.04 -8 -10 0 247.78 10.07 10 -8 0 244.93 10.11 8 10 0 257.24 10.01 -9 -10 0 3.35 0.65 9 10 0 3.09 0.58 10 -9 0 2.90 0.65 10 10 0 232.39 9.58 -10 -10 0 239.47 9.68 10 -10 0 245.29 9.81 10 -11 0 3.79 0.73 -11 -10 0 3.18 0.71 11 10 0 4.34 0.66 11 9 0 175.13 7.20 9 -11 0 170.53 7.37 -11 -9 0 182.33 7.29 11 8 0 29.81 1.60 -11 -8 0 28.95 1.68 8 -11 0 26.06 1.66 -7 11 0 163.00 6.12 7 -11 0 166.02 6.87 11 7 0 163.21 6.72 6 -11 0 9.88 0.98 11 6 0 12.47 0.94 -6 11 0 11.37 0.74 11 5 0 106.84 4.45 5 -11 0 100.80 4.51 -5 11 0 106.75 4.03 -4 11 0 -0.24 0.24 4 -11 0 0.30 0.38 11 4 0 0.38 0.34 3 -11 0 180.09 7.36 -3 11 0 173.83 6.70 11 3 0 184.78 7.28 11 2 0 13.47 0.94 2 -11 0 12.14 0.96 1 -11 0 326.77 13.05 11 1 0 331.76 12.99 0 -11 0 0.22 0.40 11 0 0 0.31 0.35 -1 -11 0 320.16 12.96 11 -1 0 334.47 12.94 11 -2 0 11.66 0.92 -2 -11 0 11.64 0.96 11 -3 0 183.59 7.47 -3 -11 0 182.62 7.49 11 -4 0 0.37 0.42 -4 -11 0 -0.34 0.42 11 -5 0 113.03 4.82 -5 -11 0 110.40 4.80 -6 -11 0 11.35 1.07 11 -6 0 10.19 0.92 -7 -11 0 165.41 6.81 11 -7 0 161.03 6.83 11 -8 0 29.59 1.74 -8 -11 0 27.73 1.70 -9 -11 0 171.30 7.08 9 11 0 168.51 6.98 11 -9 0 171.39 7.19 10 11 0 2.64 0.59 -10 -11 0 2.57 0.66 11 -10 0 4.19 0.78 11 -11 0 145.05 6.29 11 -12 0 2.01 0.68 10 -12 0 101.14 4.61 12 9 0 23.02 1.46 9 -12 0 26.19 1.69 8 -12 0 114.66 5.19 12 8 0 122.60 5.06 7 -12 0 23.90 1.55 12 7 0 22.79 1.39 6 -12 0 62.44 3.00 12 6 0 61.36 2.86 -6 12 0 63.12 2.53 12 5 0 6.55 0.78 5 -12 0 8.17 0.91 -5 12 0 6.94 0.63 -4 12 0 73.93 2.96 12 4 0 74.02 3.29 4 -12 0 73.44 3.39 -3 12 0 6.47 0.68 3 -12 0 7.70 0.82 12 3 0 8.17 0.82 2 -12 0 133.49 5.81 12 2 0 142.90 5.76 1 -12 0 2.15 0.56 12 1 0 4.41 0.66 0 -12 0 215.21 8.57 12 0 0 205.05 8.48 12 -1 0 1.99 0.49 -1 -12 0 2.44 0.57 -2 -12 0 138.02 5.82 12 -2 0 137.97 5.78 -3 -12 0 8.23 0.90 12 -3 0 7.19 0.83 -4 -12 0 78.60 3.51 12 -4 0 74.83 3.48 -5 -12 0 8.93 1.01 12 -5 0 7.29 0.91 12 -6 0 65.57 3.10 -6 -12 0 64.95 3.11 12 -7 0 25.85 1.59 -7 -12 0 23.29 1.59 12 -8 0 121.27 5.36 -8 -12 0 123.78 5.30 12 -9 0 28.01 1.75 -9 -12 0 25.30 1.65 9 12 0 25.26 1.54 -10 -12 0 100.66 4.49 12 -10 0 102.17 4.66 12 -11 0 1.48 0.71 12 -12 0 81.05 3.95 12 -13 0 -0.68 0.61 11 -13 0 54.57 2.92 10 -13 0 12.68 1.23 9 -13 0 60.24 3.07 13 8 0 20.24 1.32 8 -13 0 19.65 1.47 13 7 0 39.66 2.02 7 -13 0 37.74 2.17 6 -13 0 12.08 1.15 13 6 0 12.46 1.03 13 5 0 23.40 1.42 -5 13 0 24.27 1.21 5 -13 0 21.20 1.46 4 -13 0 -0.56 0.46 -4 13 0 0.27 0.32 13 4 0 0.42 0.43 13 3 0 38.36 2.01 -3 13 0 39.34 1.81 3 -13 0 41.22 2.16 2 -13 0 11.41 1.06 13 2 0 11.88 1.02 13 1 0 98.94 4.28 1 -13 0 97.32 4.34 0 -13 0 0.76 0.50 13 0 0 0.24 0.42 -1 -13 0 99.66 4.32 13 -1 0 94.89 4.24 -2 -13 0 12.80 1.11 13 -2 0 13.42 1.09 13 -3 0 42.13 2.15 -3 -13 0 38.32 2.15 13 -4 0 -0.40 0.45 -4 -13 0 0.13 0.49 13 -5 0 24.21 1.61 -5 -13 0 30.13 1.75 -6 -13 0 12.12 1.19 13 -6 0 11.30 1.05 -7 -13 0 39.17 2.23 13 -7 0 41.69 2.27 -8 -13 0 18.11 1.45 13 -8 0 20.92 1.51 13 -9 0 65.75 3.21 -9 -13 0 60.22 3.05 13 -10 0 12.29 1.28 13 -11 0 56.51 3.01 13 -12 0 0.16 0.69 13 -13 0 36.40 2.36 13 -14 0 2.32 0.91 12 -14 0 38.88 2.45 11 -14 0 0.66 0.65 10 -14 0 41.40 2.39 9 -14 0 11.75 1.26 8 -14 0 26.67 1.75 14 7 0 5.98 0.83 7 -14 0 6.40 0.99 6 -14 0 13.64 1.26 14 6 0 13.99 1.12 14 5 0 2.71 0.60 5 -14 0 2.23 0.66 4 -14 0 11.74 1.09 14 4 0 12.72 1.08 3 -14 0 6.91 0.95 -3 14 0 6.99 0.78 14 3 0 6.84 0.84 2 -14 0 30.91 1.86 14 2 0 31.98 1.78 14 1 0 8.40 0.92 1 -14 0 8.20 1.02 14 0 0 53.16 2.65 0 -14 0 54.04 2.71 -1 -14 0 9.17 1.05 14 -1 0 10.75 1.02 -2 -14 0 32.11 1.87 14 -2 0 30.48 1.83 14 -3 0 6.57 0.92 -3 -14 0 7.67 1.04 14 -4 0 14.98 1.21 -4 -14 0 14.54 1.26 14 -5 0 1.63 0.66 -5 -14 0 2.51 0.75 14 -6 0 13.95 1.28 -6 -14 0 14.58 1.32 -7 -14 0 7.47 1.08 14 -7 0 7.20 0.97 14 -8 0 27.42 1.81 -8 -14 0 23.94 1.73 14 -9 0 10.73 1.24 14 -10 0 45.18 2.61 14 -11 0 -0.32 0.68 14 -12 0 37.21 2.35 14 -13 0 2.61 0.92 14 -14 0 18.46 1.76 14 -15 0 3.76 1.01 13 -15 0 19.06 1.75 12 -15 0 7.09 1.15 11 -15 0 37.29 2.38 10 -15 0 0.13 0.68 9 -15 0 29.77 1.96 8 -15 0 6.47 0.98 7 -15 0 13.44 1.33 6 -15 0 1.22 0.63 15 6 0 0.71 0.52 15 5 0 5.68 0.82 5 -15 0 6.21 1.00 15 4 0 2.22 0.60 4 -15 0 2.78 0.73 15 3 0 11.56 1.06 3 -15 0 10.98 1.16 15 2 0 13.24 1.20 2 -15 0 14.06 1.21 15 1 0 26.23 1.66 1 -15 0 24.03 1.70 15 0 0 -0.18 0.48 0 -15 0 -0.58 0.52 15 -1 0 26.75 1.69 -1 -15 0 26.29 1.75 15 -2 0 11.67 1.16 -2 -15 0 12.24 1.20 15 -3 0 12.05 1.19 -3 -15 0 11.47 1.20 15 -4 0 2.19 0.71 -4 -15 0 2.70 0.74 15 -5 0 6.26 0.95 -5 -15 0 7.99 1.09 -6 -15 0 1.36 0.72 15 -6 0 1.33 0.69 15 -7 0 14.19 1.36 -7 -15 0 12.60 1.35 15 -8 0 4.70 0.97 15 -9 0 35.40 2.26 15 -10 0 0.29 0.73 15 -11 0 36.39 2.35 15 -12 0 6.99 1.21 15 -13 0 20.37 1.87 15 -14 0 3.04 1.04 15 -15 0 4.48 1.16 14 -16 0 9.40 1.49 13 -16 0 18.81 1.83 12 -16 0 27.73 2.13 11 -16 0 8.53 1.33 10 -16 0 40.39 2.50 9 -16 0 1.22 0.79 8 -16 0 25.17 1.87 7 -16 0 3.99 0.89 6 -16 0 15.88 1.45 5 -16 0 0.14 0.63 4 -16 0 16.53 1.43 16 4 0 15.89 1.32 16 3 0 12.45 1.16 3 -16 0 12.37 1.29 16 2 0 31.33 1.88 2 -16 0 29.08 1.95 16 1 0 6.33 1.01 1 -16 0 5.08 0.92 16 0 0 42.61 2.37 0 -16 0 43.62 2.45 16 -1 0 3.86 0.85 -1 -16 0 5.12 0.90 16 -2 0 26.23 1.81 -2 -16 0 29.90 1.91 -3 -16 0 14.97 1.44 16 -3 0 14.13 1.34 16 -4 0 18.34 1.54 -4 -16 0 18.74 1.55 -5 -16 0 -0.36 0.68 16 -5 0 0.11 0.66 -6 -16 0 16.91 1.56 16 -6 0 18.35 1.56 16 -7 0 4.64 0.98 16 -8 0 25.24 1.89 16 -9 0 0.69 0.72 16 -10 0 48.26 2.88 16 -11 0 9.70 1.43 16 -12 0 25.91 2.09 16 -13 0 19.26 1.89 16 -14 0 8.23 1.46 13 -17 0 17.06 1.82 12 -17 0 26.15 2.06 11 -17 0 40.79 2.65 10 -17 0 4.23 1.06 9 -17 0 46.33 2.77 8 -17 0 0.55 0.68 7 -17 0 31.52 2.14 6 -17 0 0.93 0.75 5 -17 0 37.06 2.26 4 -17 0 6.26 1.04 3 -17 0 48.83 2.71 17 3 0 46.45 2.55 17 2 0 17.22 1.42 2 -17 0 18.98 1.61 1 -17 0 68.49 3.44 17 1 0 66.80 3.34 17 0 0 0.28 0.61 0 -17 0 -0.31 0.68 -1 -17 0 70.66 3.51 17 -1 0 67.32 3.46 -2 -17 0 17.90 1.53 17 -2 0 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P-4n2 11488_0m.res created by SHELXL-2018/3 at 18:35:09 on 31-Jan-2019 CELL 0.71073 16.535 16.535 18.1127 90 90 90 ZERR 8 0.0004 0.0004 0.0004 0 0 0 LATT -1 SYMM -X,-Y,+Z SYMM +Y,-X,-Z SYMM -Y,+X,-Z SYMM 0.5+X,0.5-Y,0.5+Z SYMM 0.5-X,0.5+Y,0.5+Z SYMM 0.5+Y,0.5+X,0.5-Z SYMM 0.5-Y,0.5-X,0.5-Z SFAC C H Ag Au N UNIT 176 144 8 8 64 EADP Au2 Ag2 EADP Au3 Ag3 EXYZ Au2 Ag2 EXYZ Au3 Ag3 L.S. 20 PLAN 4 SIZE 0.2 0.25 0.35 TEMP 23 BOND$h ABIN fmap 2 acta OMIT 4 4 1 OMIT 0 0 2 REM REM REM WGHT 0.034700 5.332400 FVAR 0.03453 PART 1 AU1 4 0.398302 0.486374 0.243744 10.50000 0.01311 0.01014 = 0.03725 0.00141 0.00286 0.00162 AU2 4 0.500000 0.500000 0.376191 10.25000 0.01275 0.00938 = 0.02407 0.00000 0.00000 -0.00016 AU3 4 0.500000 0.500000 0.110494 10.25000 0.01329 0.01025 = 0.02460 0.00000 0.00000 0.00271 PART 0 PART 2 AG1 3 0.399069 0.491006 0.244153 10.50000 0.01040 0.01179 = 0.00722 0.00390 -0.00500 0.00039 AG2 3 0.500000 0.500000 0.376191 10.25000 0.01275 0.00938 = 0.02407 0.00000 0.00000 -0.00016 AG3 3 0.500000 0.500000 0.110494 10.25000 0.01329 0.01025 = 0.02460 0.00000 0.00000 0.00271 PART 0 N1 5 0.259695 0.748122 0.384423 11.00000 0.12105 0.04340 = 0.08024 0.00317 0.05946 0.02125 N2 5 0.384070 0.607072 0.224072 11.00000 0.02960 0.03826 = 0.04416 -0.00023 0.00489 0.00197 N3 5 0.458115 0.615577 0.111552 11.00000 0.04137 0.03187 = 0.03120 0.00265 0.00424 0.00809 N4 5 0.526152 0.786851 -0.051841 11.00000 0.06159 0.03727 = 0.08379 0.01596 0.00712 0.00092 N5 5 0.295300 0.202132 0.116386 11.00000 0.12272 0.01475 = 0.06085 -0.00086 -0.03651 -0.01625 N6 5 0.405802 0.368039 0.265899 11.00000 0.03493 0.02517 = 0.05066 0.00715 -0.01297 -0.00303 N7 5 0.481111 0.377619 0.378501 11.00000 0.02706 0.03140 = 0.04433 -0.00548 -0.00993 0.00084 N8 5 0.575539 0.237499 0.554639 11.00000 0.08292 0.03171 = 0.07339 0.00187 -0.02800 -0.01242 C1 1 0.240170 0.669742 0.368664 11.00000 0.09647 0.06217 = 0.14099 0.02164 0.07699 0.03693 AFIX 43 H1 2 0.197200 0.646704 0.394262 11.00000 -1.20000 AFIX 0 C2 1 0.279971 0.622078 0.317123 11.00000 0.06603 0.04030 = 0.12686 0.00867 0.05450 0.01309 AFIX 43 H2 2 0.263822 0.568785 0.309901 11.00000 -1.20000 AFIX 0 C3 1 0.343291 0.653190 0.276549 11.00000 0.05206 0.03630 = 0.06479 0.00848 0.00788 0.02422 C4 1 0.368868 0.735052 0.294500 11.00000 0.04940 0.06048 = 0.04107 -0.00454 -0.00378 0.02557 AFIX 43 H4 2 0.412216 0.759669 0.270723 11.00000 -1.20000 AFIX 0 C5 1 0.324207 0.775068 0.350045 11.00000 0.08044 0.05712 = 0.04578 -0.00572 -0.00846 0.03891 AFIX 43 H5 2 0.342498 0.826086 0.363770 11.00000 -1.20000 AFIX 0 C6 1 0.413063 0.646370 0.165793 11.00000 0.03752 0.02777 = 0.04363 0.00453 -0.00373 0.00516 AFIX 43 H6 2 0.400631 0.701102 0.162478 11.00000 -1.20000 AFIX 0 C7 1 0.574770 0.729194 -0.029262 11.00000 0.07308 0.03637 = 0.07844 0.00957 0.02650 0.00629 AFIX 43 H7 2 0.626603 0.728107 -0.049169 11.00000 -1.20000 AFIX 0 C8 1 0.555132 0.668976 0.022439 11.00000 0.03795 0.03785 = 0.05176 0.00261 0.00882 0.00759 AFIX 43 H8 2 0.592408 0.629170 0.035005 11.00000 -1.20000 AFIX 0 C9 1 0.476143 0.670306 0.055449 11.00000 0.03932 0.02843 = 0.04232 -0.00660 0.00147 0.00553 C10 1 0.423367 0.730847 0.030199 11.00000 0.04190 0.03670 = 0.05728 0.00040 0.00464 0.00411 AFIX 43 H10 2 0.370778 0.732982 0.048301 11.00000 -1.20000 AFIX 0 C11 1 0.448690 0.787668 -0.021527 11.00000 0.05188 0.02977 = 0.05963 0.00560 -0.00762 0.01017 AFIX 43 H11 2 0.412627 0.827633 -0.036408 11.00000 -1.20000 AFIX 0 C12 1 0.267300 0.279154 0.129784 11.00000 0.08110 0.04359 = 0.09183 0.00380 -0.05048 -0.01882 AFIX 43 H12 2 0.220664 0.294951 0.104969 11.00000 -1.20000 AFIX 0 C13 1 0.302480 0.335881 0.177264 11.00000 0.05894 0.04920 = 0.07766 0.00377 -0.03332 -0.01372 AFIX 43 H13 2 0.279966 0.387029 0.183072 11.00000 -1.20000 AFIX 0 C14 1 0.371985 0.313826 0.215558 11.00000 0.03571 0.03698 = 0.04963 -0.00671 -0.00824 -0.00967 C15 1 0.406774 0.236001 0.201181 11.00000 0.03628 0.04117 = 0.04876 -0.00233 -0.00301 -0.00804 AFIX 43 H15 2 0.454340 0.220553 0.224675 11.00000 -1.20000 AFIX 0 C16 1 0.369049 0.183800 0.151974 11.00000 0.07208 0.04869 = 0.05761 -0.00429 0.00556 -0.01043 AFIX 43 H16 2 0.393541 0.134369 0.141969 11.00000 -1.20000 AFIX 0 C17 1 0.442545 0.336613 0.325585 11.00000 0.02975 0.03364 = 0.04783 0.00110 0.00102 -0.00294 AFIX 43 H17 2 0.440952 0.280653 0.330536 11.00000 -1.20000 AFIX 0 C18 1 0.508125 0.215425 0.517930 11.00000 0.04250 0.04260 = 0.05748 0.01224 -0.00186 0.00595 AFIX 43 H18 2 0.483215 0.167427 0.532046 11.00000 -1.20000 AFIX 0 C19 1 0.473373 0.258430 0.461225 11.00000 0.04089 0.03428 = 0.04491 -0.00068 -0.00218 -0.00694 AFIX 43 H19 2 0.426165 0.239928 0.439004 11.00000 -1.20000 AFIX 0 C20 1 0.508779 0.328634 0.437753 11.00000 0.03142 0.02513 = 0.04592 -0.00297 0.00264 -0.00142 C21 1 0.581516 0.352643 0.474175 11.00000 0.05757 0.03043 = 0.05481 0.00353 -0.01854 -0.00803 AFIX 43 H21 2 0.608530 0.399481 0.460039 11.00000 -1.20000 AFIX 0 C22 1 0.610803 0.305451 0.530317 11.00000 0.07395 0.04694 = 0.05813 -0.00524 -0.01947 0.00495 AFIX 43 H22 2 0.658488 0.321707 0.553144 11.00000 -1.20000 AFIX 0 HKLF 4 REM 11488_0m in P-4n2 REM wR2 = 0.0802, GooF = S = 1.052, Restrained GooF = 1.052 for all data REM R1 = 0.0324 for 4918 Fo > 4sig(Fo) and 0.0410 for all 5627 data REM 299 parameters refined using 0 restraints END WGHT 0.0347 5.4197 REM Highest difference peak 1.221, deepest hole -0.763, 1-sigma level 0.145 Q1 1 0.5000 0.5000 0.0592 10.50000 0.05 1.22 Q2 1 0.5000 0.5000 0.1527 10.50000 0.05 1.11 Q3 1 0.5000 0.5000 0.3223 10.50000 0.05 1.10 Q4 1 0.5000 0.5000 0.4209 10.50000 0.05 1.06 ; _shelx_res_checksum 44280 _shelx_fab_file ; -21 -6 -3 1.9864 3.1663 -21 -6 -2 2.7852 -2.5124 -21 -6 -1 -0.8124 -2.0935 -21 -5 -5 0.9468 -5.6120 -21 -5 -4 -1.3873 0.4553 -21 -5 -3 1.7425 6.3051 -21 -5 -2 0.9929 0.0785 -21 -5 -1 -1.7691 -2.0088 -21 -4 -4 2.4713 -0.6924 -21 -4 -3 1.5174 3.1320 -21 -4 -2 -0.5310 0.4944 -21 -4 -1 -0.1034 -2.4533 -21 -3 -3 -0.1324 1.7547 -21 -3 -2 4.0041 -3.0851 -21 -3 -1 0.7984 -1.1350 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-1.0315 17 11 0 -1.9705 -0.4954 17 11 1 -0.6567 5.7181 17 11 2 0.8342 1.0067 17 11 3 -0.5274 0.9226 17 11 4 -2.3698 0.6259 17 11 5 0.8032 0.3889 17 11 6 -0.5587 1.0359 17 11 7 1.0582 1.8475 17 11 8 -0.2589 0.3355 17 11 9 -1.2568 -0.3707 17 12 0 -1.6535 0.8007 17 12 1 0.7724 1.0516 17 12 2 0.5111 -0.3072 17 12 3 0.4844 -3.9977 17 12 4 0.0722 -0.3973 17 12 5 -2.6607 2.1290 17 12 8 -0.9226 1.6184 17 13 0 0.0636 -0.1749 17 13 1 2.7810 3.4141 17 13 2 -0.6219 1.4113 18 0 0 2.3445 -13.5422 18 0 2 0.6580 2.9864 18 0 4 -0.5230 1.8548 18 0 6 -0.4395 -2.1792 18 0 8 -1.3258 -0.2430 18 0 10 -2.2262 7.4829 18 0 12 -0.8063 -5.7230 18 1 0 0.3036 1.6822 18 1 1 0.5490 -0.3501 18 1 2 -0.2496 -0.0596 18 1 3 0.7702 1.5765 18 1 4 1.9711 1.7075 18 1 5 -0.8922 -1.0954 18 1 6 -3.7035 -1.9985 18 1 7 -3.7638 -1.1034 18 1 8 3.3116 0.5388 18 1 9 2.7145 2.4174 18 1 10 0.7161 -1.2312 18 1 11 2.4105 -0.4042 18 1 12 0.2576 2.3337 18 1 13 -0.9585 -0.5476 18 2 0 1.8586 -0.8779 18 2 1 -0.4725 -1.1189 18 2 2 -0.2698 -3.0659 18 2 3 -0.2438 0.6893 18 2 4 -0.4791 2.4211 18 2 5 2.1818 -3.7980 18 2 6 -0.0594 -1.3958 18 2 7 -2.2429 6.6643 18 2 8 -1.1732 -1.5228 18 2 9 -2.0041 -1.7123 18 2 10 -0.6319 10.2513 18 2 11 0.4867 2.2833 18 2 12 1.0480 -4.4560 18 2 13 3.9923 -2.2892 18 3 0 0.6246 -0.5138 18 3 1 -0.5828 0.4875 18 3 2 -0.5514 1.3043 18 3 3 -1.7024 -0.1859 18 3 4 1.0735 1.0729 18 3 5 3.2261 -0.9992 18 3 6 -1.0284 -0.8103 18 3 7 -0.5043 -2.0522 18 3 8 0.8550 -1.3897 18 3 9 -1.0344 0.8430 18 3 10 4.5902 1.4012 18 3 11 1.5068 2.3528 18 3 12 0.3216 -0.0488 18 3 13 -0.7998 -2.5572 18 4 0 -1.4876 0.4620 18 4 1 1.1366 -3.2933 18 4 2 0.0909 1.5449 18 4 3 -2.2510 2.1650 18 4 4 -0.5369 0.3043 18 4 5 0.5295 -0.9360 18 4 6 0.0680 -1.1913 18 4 7 0.5002 3.6587 18 4 8 -0.1602 -1.7775 18 4 9 -3.9615 0.6646 18 4 10 1.9451 11.0820 18 4 11 3.6146 0.2647 18 4 12 1.7928 -0.0988 18 4 13 -1.6357 1.1704 18 5 0 2.0009 0.5661 18 5 1 0.6971 1.8484 18 5 2 -5.3642 -2.8997 18 5 3 0.7685 -1.9187 18 5 4 4.1160 1.6286 18 5 5 -0.1744 -0.0424 18 5 6 0.4020 0.8743 18 5 7 1.2661 -1.2314 18 5 8 0.1931 -1.2489 18 5 9 -0.3926 -1.9830 18 5 10 2.7912 2.5955 18 5 11 -0.1166 2.4541 18 5 12 1.4832 -1.6015 18 6 0 -0.6039 -0.6049 18 6 1 0.3562 -1.8849 18 6 2 -1.6113 3.3793 18 6 3 -1.4964 1.8279 18 6 4 3.4067 0.8579 18 6 5 0.3199 -0.1837 18 6 6 -1.9695 -0.0054 18 6 7 -0.4204 2.3773 18 6 8 1.4587 -2.2134 18 6 9 -0.0624 -1.7582 18 6 10 0.7061 7.3470 18 6 11 -0.1592 2.0588 18 6 12 2.8393 1.5987 18 7 0 -3.4053 -0.3280 18 7 1 1.3937 3.1589 18 7 2 -5.9173 1.8869 18 7 3 2.9517 0.3556 18 7 4 7.1848 -2.0542 18 7 5 -3.9506 -1.2854 18 7 6 -0.9128 1.6511 18 7 7 -0.1799 0.0441 18 7 8 0.7974 0.5360 18 7 9 1.3109 -1.3792 18 7 10 1.2010 -0.8889 18 7 11 0.1853 0.6875 18 8 0 -1.0083 -0.3145 18 8 1 -0.6714 0.1868 18 8 2 -1.0649 0.5827 18 8 3 3.1350 -1.9800 18 8 4 3.7212 0.1544 18 8 5 -2.0743 0.8721 18 8 6 0.5509 -0.3764 18 8 7 -0.2654 -2.4512 18 8 8 -0.5923 0.6945 18 8 9 0.3802 0.4844 18 8 10 0.4299 0.7782 18 9 0 -2.9646 -1.1910 18 9 1 -0.0200 -0.0871 18 9 2 -5.3483 6.0829 18 9 3 2.0365 2.0094 18 9 4 6.6092 -3.5727 18 9 5 -4.3679 0.3187 18 9 6 -0.9047 2.9417 18 9 7 0.1804 -0.8241 18 9 8 -0.2151 -2.8319 18 9 9 0.7694 0.2295 18 10 0 2.7902 2.5924 18 10 1 0.7365 -3.9733 18 10 2 -2.5213 -1.5561 18 10 3 1.8093 -1.5122 18 10 4 2.3414 -1.0833 18 10 5 -0.8245 -0.4778 18 10 6 2.3553 -1.0639 18 10 7 -1.1396 -4.2040 18 10 8 -0.6551 0.5372 18 11 0 1.3520 0.1724 18 11 1 -0.3567 -3.4039 18 11 2 -2.8185 2.1886 18 11 3 -0.7872 5.3629 18 11 4 2.0472 -1.1817 18 12 0 -0.9591 0.8015 19 0 1 -0.0217 -1.9100 19 0 3 -2.1568 0.9315 19 0 5 2.0923 1.0242 19 0 7 2.3612 -1.4570 19 0 9 -1.5158 0.6329 19 0 11 -3.2013 0.1897 19 1 0 -1.7052 7.5276 19 1 1 0.5625 1.6293 19 1 2 0.4120 -0.2838 19 1 3 0.1891 -0.8677 19 1 4 -0.4575 -1.9795 19 1 5 -2.4660 3.1406 19 1 6 0.6601 0.4957 19 1 7 2.2555 -4.4183 19 1 8 0.8158 1.1515 19 1 9 0.5778 2.3053 19 1 10 2.3879 -8.1569 19 1 11 -0.3069 -1.7650 19 1 12 0.8393 6.5049 19 2 0 0.8455 0.1455 19 2 1 -0.8953 0.4364 19 2 2 -0.1264 -2.3516 19 2 3 1.0279 -0.5055 19 2 4 -0.6958 -1.2690 19 2 5 -0.6750 1.5556 19 2 6 1.7772 2.9560 19 2 7 0.2459 0.7945 19 2 8 -3.0937 -0.8782 19 2 9 1.0825 -0.8923 19 2 10 -2.3123 0.5285 19 2 11 -2.8677 -0.3644 19 2 12 -0.0407 -0.9386 19 3 0 0.6515 -2.1732 19 3 1 1.0457 2.8511 19 3 2 0.4481 0.5790 19 3 3 -0.7909 -0.5245 19 3 4 0.0897 0.7155 19 3 5 -0.3648 1.1628 19 3 6 -1.1566 -0.0205 19 3 7 0.5305 -3.2768 19 3 8 2.3338 1.4554 19 3 9 2.9843 1.5794 19 3 10 -2.2117 -10.2170 19 3 11 -2.7570 -2.1147 19 4 0 1.4126 -0.0314 19 4 1 2.0005 -1.3494 19 4 2 1.8301 -0.0875 19 4 3 -0.0519 1.4371 19 4 4 -0.0966 -0.0395 19 4 5 -1.4806 1.2314 19 4 6 -3.4126 -1.3270 19 4 7 -1.7609 1.0684 19 4 8 1.0122 2.3905 19 4 9 1.7593 0.5796 19 4 10 -3.5791 -2.8280 19 4 11 -0.3372 -1.0303 19 5 0 2.8882 0.2028 19 5 1 -1.1835 4.2117 19 5 2 -0.4426 -4.8386 19 5 3 2.3566 -4.3762 19 5 4 -1.1307 0.9023 19 5 5 0.3848 2.5051 19 5 6 -0.3032 0.2763 19 5 7 -1.0824 -2.9641 19 5 8 0.4444 2.3182 19 5 9 2.3074 2.6729 19 5 10 -2.2210 -9.9162 19 5 11 -2.5917 -2.3793 19 6 0 4.2219 -0.7055 19 6 1 -0.5044 -1.9410 19 6 2 5.2714 2.6407 19 6 3 -1.0931 -0.8387 19 6 4 -5.4602 -0.7631 19 6 5 0.8867 2.9880 19 6 6 0.0217 -0.2184 19 6 7 -1.2329 -1.2369 19 6 8 -0.8129 -1.2289 19 6 9 0.9749 2.2505 19 6 10 -0.9383 -0.3316 19 7 0 1.0565 2.7398 19 7 1 1.0790 0.2939 19 7 2 1.5465 -3.4729 19 7 3 -1.0601 -0.6109 19 7 4 -5.0715 -1.0350 19 7 5 0.1421 0.9988 19 7 6 1.1404 -0.4957 19 7 7 1.2927 -0.4280 19 7 8 -0.6556 1.2166 19 7 9 -1.3245 2.2464 19 8 0 3.7067 1.7800 19 8 1 -0.2648 -3.8897 19 8 2 6.1028 -4.4978 19 8 3 -1.1918 -1.9046 19 8 4 -5.6839 3.0100 19 8 5 2.7957 2.7668 19 8 6 1.2186 -0.1517 19 8 7 0.1034 -0.9793 19 8 8 -0.5183 -1.5519 19 9 0 -0.8670 -1.2909 19 9 1 1.1187 3.1002 19 9 2 2.1777 1.4489 19 9 3 -2.7200 0.9546 19 9 4 -3.2215 -0.5831 19 9 5 0.3512 0.2883 19 9 7 0.7542 3.6628 19 10 0 -1.5028 1.1026 19 10 1 -2.0458 1.3211 19 10 2 5.3461 -3.8271 20 0 0 1.8229 -14.0770 20 0 2 -1.9852 1.6023 20 0 4 1.3897 1.9770 20 0 6 -1.1848 -0.1412 20 0 8 0.5170 0.1537 20 0 10 -3.1363 3.4504 20 1 0 -0.0996 1.1973 20 1 1 2.3714 1.6328 20 1 2 -0.8631 0.5272 20 1 3 -0.8620 -0.9888 20 1 4 1.5093 1.1430 20 1 5 -0.8990 -1.3299 20 1 6 -2.2581 -2.6294 20 1 7 -0.1633 1.9224 20 1 8 2.5955 1.5832 20 1 9 -0.3867 -1.2496 20 1 10 1.1902 -0.5665 20 2 0 2.9173 1.6724 20 2 1 -1.8197 -2.1336 20 2 2 -3.2861 -2.5751 20 2 3 0.6911 1.0094 20 2 4 1.0218 -0.5239 20 2 5 2.3455 -3.2883 20 2 6 1.1058 1.3173 20 2 7 -2.3635 3.1726 20 2 8 -1.9314 -0.2842 20 2 9 -0.1969 -1.8051 20 3 0 -3.9252 -1.1412 20 3 1 -0.3730 -1.7047 20 3 2 1.6491 2.8780 20 3 3 -0.8021 1.5066 20 3 4 -2.8530 -0.7037 20 3 5 -0.1231 -2.9469 20 3 6 3.5894 -0.6989 20 3 7 1.7915 0.0935 20 3 8 -0.1090 0.1160 20 3 9 -1.1618 0.2112 20 4 0 -1.5992 3.7230 20 4 1 0.2770 -2.8783 20 4 2 -0.7997 1.4194 20 4 3 -0.1404 3.3335 20 4 4 0.8365 -2.3975 20 4 5 -1.4276 -2.6151 20 4 6 1.3678 0.2105 20 4 7 1.1088 1.0088 20 4 8 -1.9920 -0.3413 20 4 9 -1.4584 -1.9398 20 5 0 -3.9814 1.0281 20 5 1 -0.5161 -0.4479 20 5 2 -3.0731 -2.5712 20 5 3 -0.8276 1.3914 20 5 4 1.3817 0.7389 20 5 5 1.0449 -3.1932 20 5 6 3.2901 1.0700 20 5 7 1.5116 1.0233 20 5 8 -0.6867 -0.3449 20 6 0 -0.4954 -1.9239 20 6 1 0.9990 -1.3556 20 6 2 -1.1782 4.1156 20 6 3 -2.0607 4.6341 20 6 4 3.0944 0.9226 20 6 5 0.3432 -4.4254 20 6 6 0.0226 -0.4795 20 6 7 -0.5273 1.9482 20 7 0 -5.0503 -0.3020 20 7 1 -0.5740 1.8064 20 7 2 -3.9164 -0.7312 20 7 3 0.3435 2.8322 20 7 4 2.6784 0.1531 20 7 5 0.1774 -3.8444 20 7 6 0.4316 -1.3964 20 8 0 -0.2090 -3.7711 20 8 1 -1.2814 -1.0149 20 8 2 -1.4371 2.0449 20 8 3 0.8570 -0.1752 20 9 0 1.7063 -2.1529 20 9 1 0.9698 3.6046 21 0 1 -1.8149 -3.6181 21 0 3 1.0694 1.7694 21 0 5 0.2336 1.0437 21 0 7 0.1736 -2.4155 21 1 0 -3.2415 3.9248 21 1 1 0.5802 2.7156 21 1 2 3.9465 2.7193 21 1 3 0.6276 -2.4938 21 1 4 -0.7355 -1.2411 21 1 5 -1.9353 3.7111 21 1 6 -0.5372 -0.5033 21 1 7 1.2262 -1.9862 21 2 0 1.5925 0.2869 21 2 1 -2.4453 0.9506 21 2 2 -0.4114 -1.1539 21 2 3 1.7755 -1.4880 21 2 4 0.6151 -0.1913 21 2 5 0.8927 2.1214 21 2 6 0.1630 1.9444 21 2 7 -0.5346 -0.7142 21 3 0 -2.3915 -7.2934 21 3 1 0.7984 1.1350 21 3 2 4.0041 3.0851 21 3 3 -0.1324 -1.7547 21 3 4 -1.1852 2.3908 21 3 5 -0.2142 2.7384 21 3 6 -1.5441 -1.3146 21 4 0 4.1839 0.5056 21 4 1 -0.1034 2.4533 21 4 2 -0.5310 -0.4944 21 4 3 1.5174 -3.1320 21 4 4 2.4713 0.6924 21 4 5 0.1166 3.8929 21 4 6 -4.4479 -1.0455 21 5 0 0.5183 -3.5268 21 5 1 -1.7691 2.0088 21 5 2 0.9929 -0.0785 21 5 3 1.7425 -6.3051 21 5 4 -1.3873 -0.4553 21 5 5 0.9468 5.6120 21 6 0 3.6732 -0.9021 21 6 1 -0.8124 2.0935 21 6 2 2.7852 2.5124 21 6 3 1.9864 -3.1663 22 0 2 -3.9861 -1.8674 22 1 0 1.4385 2.3832 22 1 1 2.3159 2.1008 0 0 0 0.0 0.0 ; _shelx_fab_checksum 69150 loop_ _space_group_symop_operation_xyz 'x, y, z' '-x, -y, z' 'y, -x, -z' '-y, x, -z' 'x+1/2, -y+1/2, z+1/2' '-x+1/2, y+1/2, z+1/2' 'y+1/2, x+1/2, -z+1/2' '-y+1/2, -x+1/2, -z+1/2' loop_ _atom_site_type_symbol _atom_site_label _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_U_iso_or_equiv _atom_site_adp_type _atom_site_calc_flag _atom_site_occupancy _atom_site_disorder_assembly _atom_site_disorder_group Au Au1 0.3983(2) 0.4864(3) 0.24374(17) 0.0202(7) Uani d 0.5 A 1 Au Au2 0.500000 0.500000 0.37619(3) 0.01540(15) Uani d 0.5 A 1 Au Au3 0.500000 0.500000 0.11049(3) 0.01605(16) Uani d 0.5 A 1 Ag Ag1 0.3991(4) 0.4910(5) 0.2442(2) 0.0098(10) Uani d 0.5 A 2 Ag Ag2 0.500000 0.500000 0.37619(3) 0.01540(15) Uani d 0.5 A 2 Ag Ag3 0.500000 0.500000 0.11049(3) 0.01605(16) Uani d 0.5 A 2 N N1 0.2597(9) 0.7481(8) 0.3844(6) 0.082(4) Uani d 1 . . N N2 0.3841(5) 0.6071(5) 0.2241(4) 0.037(2) Uani d 1 . . N N3 0.4581(6) 0.6156(5) 0.1116(4) 0.035(2) Uani d 1 . . N N4 0.5262(8) 0.7869(7) -0.0518(7) 0.061(3) Uani d 1 . . N N5 0.2953(9) 0.2021(6) 0.1164(5) 0.066(3) Uani d 1 . . N N6 0.4058(5) 0.3680(5) 0.2659(5) 0.037(2) Uani d 1 . . N N7 0.4811(5) 0.3776(5) 0.3785(5) 0.034(2) Uani d 1 . . N N8 0.5755(8) 0.2375(6) 0.5546(7) 0.063(3) Uani d 1 . . C C1 0.2402(11) 0.6697(10) 0.3687(10) 0.100(7) Uani d 1 . . H H1 0.197200 0.646704 0.394262 0.120 Uiso calc 1 . . C C2 0.2800(9) 0.6221(8) 0.3171(9) 0.078(5) Uani d 1 . . H H2 0.263822 0.568785 0.309901 0.093 Uiso calc 1 . . C C3 0.3433(7) 0.6532(7) 0.2765(7) 0.051(3) Uani d 1 . . C C4 0.3689(8) 0.7351(8) 0.2945(6) 0.050(3) Uani d 1 . . H H4 0.412216 0.759669 0.270723 0.060 Uiso calc 1 . . C C5 0.3242(9) 0.7751(8) 0.3500(7) 0.061(4) Uani d 1 . . H H5 0.342498 0.826086 0.363770 0.073 Uiso calc 1 . . C C6 0.4131(7) 0.6464(6) 0.1658(6) 0.036(2) Uani d 1 . . H H6 0.400631 0.701102 0.162478 0.044 Uiso calc 1 . . C C7 0.5748(9) 0.7292(8) -0.0293(8) 0.063(4) Uani d 1 . . H H7 0.626603 0.728107 -0.049169 0.075 Uiso calc 1 . . C C8 0.5551(7) 0.6690(7) 0.0224(6) 0.043(3) Uani d 1 . . H H8 0.592408 0.629170 0.035005 0.051 Uiso calc 1 . . C C9 0.4761(8) 0.6703(8) 0.0554(6) 0.037(3) Uani d 1 . . C C10 0.4234(8) 0.7308(7) 0.0302(6) 0.045(3) Uani d 1 . . H H10 0.370778 0.732982 0.048301 0.054 Uiso calc 1 . . C C11 0.4487(9) 0.7877(8) -0.0215(7) 0.047(3) Uani d 1 . . H H11 0.412627 0.827633 -0.036408 0.057 Uiso calc 1 . . C C12 0.2673(9) 0.2792(8) 0.1298(8) 0.072(5) Uani d 1 . . H H12 0.220664 0.294951 0.104969 0.087 Uiso calc 1 . . C C13 0.3025(8) 0.3359(9) 0.1773(7) 0.062(4) Uani d 1 . . H H13 0.279966 0.387029 0.183072 0.074 Uiso calc 1 . . C C14 0.3720(7) 0.3138(7) 0.2156(6) 0.041(3) Uani d 1 . . C C15 0.4068(7) 0.2360(7) 0.2012(6) 0.042(3) Uani d 1 . . H H15 0.454340 0.220553 0.224675 0.050 Uiso calc 1 . . C C16 0.3690(9) 0.1838(8) 0.1520(7) 0.059(4) Uani d 1 . . H H16 0.393541 0.134369 0.141969 0.071 Uiso calc 1 . . C C17 0.4425(6) 0.3366(7) 0.3256(6) 0.037(3) Uani d 1 . . H H17 0.440952 0.280653 0.330536 0.044 Uiso calc 1 . . C C18 0.5081(8) 0.2154(9) 0.5179(7) 0.048(4) Uani d 1 . . H H18 0.483215 0.167427 0.532046 0.057 Uiso calc 1 . . C C19 0.4734(7) 0.2584(7) 0.4612(6) 0.040(3) Uani d 1 . . H H19 0.426165 0.239928 0.439004 0.048 Uiso calc 1 . . C C20 0.5088(7) 0.3286(8) 0.4378(7) 0.034(3) Uani d 1 . . C C21 0.5815(8) 0.3526(7) 0.4742(6) 0.048(3) Uani d 1 . . H H21 0.608530 0.399481 0.460039 0.057 Uiso calc 1 . . C C22 0.6108(9) 0.3055(8) 0.5303(7) 0.060(4) Uani d 1 . . H H22 0.658488 0.321707 0.553144 0.072 Uiso calc 1 . . loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_12 _atom_site_aniso_U_13 _atom_site_aniso_U_23 Au1 0.0131(12) 0.0101(8) 0.0372(13) 0.0016(7) 0.0029(10) 0.0014(10) Au2 0.0128(4) 0.0094(4) 0.0241(3) -0.0002(3) 0.000 0.000 Au3 0.0133(5) 0.0102(4) 0.0246(3) 0.0027(3) 0.000 0.000 Ag1 0.010(2) 0.0118(19) 0.0072(15) 0.0004(14) -0.0050(14) 0.0039(15) Ag2 0.0128(4) 0.0094(4) 0.0241(3) -0.0002(3) 0.000 0.000 Ag3 0.0133(5) 0.0102(4) 0.0246(3) 0.0027(3) 0.000 0.000 N1 0.121(14) 0.043(8) 0.080(8) 0.021(7) 0.059(8) 0.003(6) N2 0.030(5) 0.038(5) 0.044(5) 0.002(4) 0.005(4) 0.000(4) N3 0.041(6) 0.032(5) 0.031(4) 0.008(4) 0.004(4) 0.003(4) N4 0.062(8) 0.037(7) 0.084(9) 0.001(6) 0.007(7) 0.016(6) N5 0.123(13) 0.015(6) 0.061(7) -0.016(5) -0.037(7) -0.001(5) N6 0.035(4) 0.025(4) 0.051(6) -0.003(3) -0.013(4) 0.007(4) N7 0.027(5) 0.031(5) 0.044(5) 0.001(4) -0.010(4) -0.005(4) N8 0.083(10) 0.032(6) 0.073(8) -0.012(6) -0.028(7) 0.002(6) C1 0.096(14) 0.062(11) 0.141(16) 0.037(9) 0.077(12) 0.022(11) C2 0.066(10) 0.040(8) 0.127(14) 0.013(7) 0.054(10) 0.009(8) C3 0.052(7) 0.036(7) 0.065(8) 0.024(5) 0.008(6) 0.008(6) C4 0.049(8) 0.060(9) 0.041(6) 0.026(6) -0.004(6) -0.005(6) C5 0.080(11) 0.057(9) 0.046(7) 0.039(7) -0.008(7) -0.006(6) C6 0.038(6) 0.028(6) 0.044(6) 0.005(5) -0.004(5) 0.005(5) C7 0.073(10) 0.036(7) 0.078(10) 0.006(7) 0.026(8) 0.010(7) C8 0.038(7) 0.038(7) 0.052(7) 0.008(5) 0.009(5) 0.003(5) C9 0.039(8) 0.028(7) 0.042(6) 0.006(5) 0.001(5) -0.007(5) C10 0.042(7) 0.037(7) 0.057(8) 0.004(5) 0.005(6) 0.000(6) C11 0.052(9) 0.030(7) 0.060(8) 0.010(6) -0.008(6) 0.006(6) C12 0.081(11) 0.044(8) 0.092(10) -0.019(7) -0.050(9) 0.004(8) C13 0.059(9) 0.049(8) 0.078(10) -0.014(7) -0.033(7) 0.004(7) C14 0.036(6) 0.037(6) 0.050(7) -0.010(5) -0.008(5) -0.007(5) C15 0.036(6) 0.041(7) 0.049(7) -0.008(5) -0.003(5) -0.002(5) C16 0.072(10) 0.049(8) 0.058(8) -0.010(7) 0.006(7) -0.004(6) C17 0.030(6) 0.034(6) 0.048(7) -0.003(4) 0.001(5) 0.001(5) C18 0.042(8) 0.043(8) 0.057(8) 0.006(6) -0.002(6) 0.012(6) C19 0.041(7) 0.034(7) 0.045(6) -0.007(5) -0.002(5) -0.001(5) C20 0.031(7) 0.025(7) 0.046(6) -0.001(5) 0.003(5) -0.003(5) C21 0.058(9) 0.030(6) 0.055(7) -0.008(6) -0.019(6) 0.004(5) C22 0.074(10) 0.047(8) 0.058(8) 0.005(7) -0.019(7) -0.005(7) loop_ _atom_type_symbol _atom_type_description _atom_type_scat_dispersion_real _atom_type_scat_dispersion_imag _atom_type_scat_source C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' loop_ _geom_angle_atom_site_label_1 _geom_angle_atom_site_label_2 _geom_angle_atom_site_label_3 _geom_angle_site_symmetry_1 _geom_angle_site_symmetry_3 _geom_angle Au2 Au1 Au3 . . 109.63(13) N2 Au1 Au2 . . 97.7(3) N2 Au1 Au3 . . 81.3(3) N6 Au1 Au2 . . 82.9(3) N6 Au1 Au3 . . 101.7(3) N6 Au1 N2 . . 176.6(4) Au1 Au2 Au1 2_665 . 70.54(15) N7 Au2 Au1 2_665 2_665 81.6(3) N7 Au2 Au1 . 2_665 100.4(3) N7 Au2 Au1 . . 81.6(3) N7 Au2 Au1 2_665 . 100.4(3) N7 Au2 N7 2_665 . 177.7(5) Au1 Au3 Au1 . 2_665 70.21(14) N3 Au3 Au1 . . 82.5(2) N3 Au3 Au1 . 2_665 96.6(3) N3 Au3 Au1 2_665 2_665 82.5(2) N3 Au3 Au1 2_665 . 96.6(3) N3 Au3 N3 . 2_665 178.9(4) Ag2 Ag1 Ag3 . . 110.3(2) N2 Ag1 Ag2 . . 100.0(4) N2 Ag1 Ag3 . . 82.5(3) N2 Ag1 N6 . . 175.8(5) N6 Ag1 Ag2 . . 82.2(3) N6 Ag1 Ag3 . . 100.1(3) N7 Ag2 Ag1 . . 83.1(3) N7 Ag2 Ag1 2_665 . 98.9(3) N7 Ag2 N7 2_665 . 177.7(5) N3 Ag3 Ag1 . . 81.2(3) N3 Ag3 Ag1 2_665 . 97.9(3) N3 Ag3 N3 . 2_665 178.9(4) C5 N1 C1 . . 114.5(12) C3 N2 Au1 . . 118.2(7) C3 N2 Ag1 . . 117.9(7) C6 N2 Au1 . . 125.1(7) C6 N2 Ag1 . . 125.3(7) C6 N2 C3 . . 116.7(9) C6 N3 Au3 . . 123.8(7) C6 N3 Ag3 . . 123.8(7) C6 N3 C9 . . 114.1(9) C9 N3 Au3 . . 122.1(7) C9 N3 Ag3 . . 122.1(7) C7 N4 C11 . . 116.6(12) C12 N5 C16 . . 114.1(10) C14 N6 Au1 . . 118.2(7) C14 N6 Ag1 . . 119.0(7) C17 N6 Au1 . . 124.5(7) C17 N6 Ag1 . . 123.8(7) C17 N6 C14 . . 117.3(8) C17 N7 Au2 . . 124.0(7) C17 N7 Ag2 . . 124.0(7) C17 N7 C20 . . 114.0(9) C20 N7 Au2 . . 122.0(7) C20 N7 Ag2 . . 122.0(7) C22 N8 C18 . . 115.1(12) N1 C1 H1 . . 117.7 N1 C1 C2 . . 124.6(15) C2 C1 H1 . . 117.7 C1 C2 H2 . . 119.8 C3 C2 C1 . . 120.5(14) C3 C2 H2 . . 119.8 N2 C3 C4 . . 121.4(11) C2 C3 N2 . . 121.8(12) C2 C3 C4 . . 116.7(11) C3 C4 H4 . . 121.9 C5 C4 C3 . . 116.3(13) C5 C4 H4 . . 121.9 N1 C5 C4 . . 127.1(14) N1 C5 H5 . . 116.4 C4 C5 H5 . . 116.4 N2 C6 N3 . . 126.9(10) N2 C6 H6 . . 116.6 N3 C6 H6 . . 116.6 N4 C7 H7 . . 117.2 N4 C7 C8 . . 125.5(14) C8 C7 H7 . . 117.2 C7 C8 H8 . . 120.8 C7 C8 C9 . . 118.5(12) C9 C8 H8 . . 120.8 N3 C9 C8 . . 119.2(11) N3 C9 C10 . . 124.6(11) C10 C9 C8 . . 116.1(11) C9 C10 H10 . . 119.5 C11 C10 C9 . . 120.9(12) C11 C10 H10 . . 119.5 N4 C11 H11 . . 118.8 C10 C11 N4 . . 122.4(12) C10 C11 H11 . . 118.8 N5 C12 H12 . . 117.0 N5 C12 C13 . . 126.1(13) C13 C12 H12 . . 117.0 C12 C13 H13 . . 120.8 C14 C13 C12 . . 118.3(13) C14 C13 H13 . . 120.8 N6 C14 C15 . . 122.3(10) C13 C14 N6 . . 119.2(10) C13 C14 C15 . . 118.4(10) C14 C15 H15 . . 120.2 C16 C15 C14 . . 119.6(11) C16 C15 H15 . . 120.2 N5 C16 H16 . . 118.4 C15 C16 N5 . . 123.2(12) C15 C16 H16 . . 118.4 N6 C17 H17 . . 116.7 N7 C17 N6 . . 126.6(10) N7 C17 H17 . . 116.7 N8 C18 H18 . . 117.5 N8 C18 C19 . . 125.0(13) C19 C18 H18 . . 117.5 C18 C19 H19 . . 120.3 C20 C19 C18 . . 119.5(12) C20 C19 H19 . . 120.3 N7 C20 C21 . . 117.5(11) C19 C20 N7 . . 125.5(11) C19 C20 C21 . . 116.9(11) C20 C21 H21 . . 120.6 C22 C21 C20 . . 118.8(12) C22 C21 H21 . . 120.6 N8 C22 C21 . . 124.6(13) N8 C22 H22 . . 117.7 C21 C22 H22 . . 117.7 loop_ _geom_bond_atom_site_label_1 _geom_bond_atom_site_label_2 _geom_bond_site_symmetry_2 _geom_bond_distance Au1 Au2 . 2.938(3) Au1 Au3 . 2.950(4) Au1 N2 . 2.041(9) Au1 N6 . 2.001(9) Au2 N7 . 2.048(9) Au2 N7 2_665 2.048(9) Au3 N3 . 2.033(8) Au3 N3 2_665 2.033(8) Ag1 Ag2 . 2.920(5) Ag1 Ag3 . 2.944(6) Ag1 N2 . 1.969(11) Ag1 N6 . 2.074(11) Ag2 N7 2_665 2.048(9) Ag2 N7 . 2.048(9) Ag3 N3 . 2.033(8) Ag3 N3 2_665 2.033(8) N1 C1 . 1.37(2) N1 C5 . 1.313(17) N2 C3 . 1.393(13) N2 C6 . 1.329(12) N3 C6 . 1.334(12) N3 C9 . 1.393(15) N4 C7 . 1.312(16) N4 C11 . 1.394(18) N5 C12 . 1.377(16) N5 C16 . 1.412(17) N6 C14 . 1.396(12) N6 C17 . 1.345(12) N7 C17 . 1.336(12) N7 C20 . 1.420(15) N8 C18 . 1.348(16) N8 C22 . 1.340(17) C1 H1 . 0.9300 C1 C2 . 1.388(18) C2 H2 . 0.9300 C2 C3 . 1.379(17) C3 C4 . 1.455(17) C4 H4 . 0.9300 C4 C5 . 1.413(16) C5 H5 . 0.9300 C6 H6 . 0.9300 C7 H7 . 0.9300 C7 C8 . 1.405(16) C8 H8 . 0.9300 C8 C9 . 1.437(16) C9 C10 . 1.405(16) C10 H10 . 0.9300 C10 C11 . 1.391(16) C11 H11 . 0.9300 C12 H12 . 0.9300 C12 C13 . 1.399(16) C13 H13 . 0.9300 C13 C14 . 1.391(16) C14 C15 . 1.433(16) C15 H15 . 0.9300 C15 C16 . 1.389(16) C16 H16 . 0.9300 C17 H17 . 0.9300 C18 H18 . 0.9300 C18 C19 . 1.375(17) C19 H19 . 0.9300 C19 C20 . 1.368(17) C20 C21 . 1.428(16) C21 H21 . 0.9300 C21 C22 . 1.370(16) C22 H22 . 0.9300 _cod_database_fobs_code 2021683