#------------------------------------------------------------------------------ #$Date: 2019-08-23 07:04:42 +0300 (Fri, 23 Aug 2019) $ #$Revision: 217669 $ #$URL: file:///home/coder/svn-repositories/cod/cif/2/02/17/2021753.cif $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2021753 loop_ _publ_author_name 'Granifo, Juan' 'Gavi\~no, Rub\'en' 'Su\'arez, Sebasti\'an' 'Baggio, Ricardo' _publ_section_title ; Structural characterization of a hybrid terpyridine--pyrazine ligand and its one-dimensional Zn^II^ coordination polymer: a computational approach to conventional and nonconventional intermolecular interactions ; _journal_coeditor_code FN3323 _journal_issue 9 _journal_name_full 'Acta Crystallographica Section C' _journal_page_first ; ; _journal_paper_doi 10.1107/S2053229619011161 _journal_volume 75 _journal_year 2019 _chemical_formula_iupac '[Zn (C5 H7 O2)2 (C25 H17 N5)]' _chemical_formula_moiety 'C35 H31 N5 O4 Zn' _chemical_formula_sum 'C35 H31 N5 O4 Zn' _chemical_formula_weight 651.02 _chemical_name_systematic catena-Poly[[bis(acetylacetonato-\k^2^O,O')zinc]-\m-4'-[4-(pyrazin-2-yl-\kN^4^)phenyl]-4,2':6',4''-terpyridine-\kN^1^] _space_group_crystal_system triclinic _space_group_IT_number 2 _space_group_name_Hall '-P 1' _space_group_name_H-M_alt 'P -1' _symmetry_space_group_name_Hall '-P 1' _symmetry_space_group_name_H-M 'P -1' _atom_sites_solution_hydrogens geom _atom_sites_solution_primary direct _atom_sites_solution_secondary difmap _audit_creation_method SHELXL-2018/1 _cell_angle_alpha 65.938(11) _cell_angle_beta 88.829(12) _cell_angle_gamma 76.828(10) _cell_formula_units_Z 2 _cell_length_a 10.8329(11) _cell_length_b 11.2168(16) _cell_length_c 14.259(3) _cell_measurement_reflns_used 1345 _cell_measurement_temperature 294(2) _cell_measurement_theta_max 27.66 _cell_measurement_theta_min 3.98 _cell_volume 1535.3(4) _computing_cell_refinement ; CrysAlis PRO (Oxford Diffraction, 2009) ; _computing_data_collection ; CrysAlis PRO (Oxford Diffraction, 2009) ; _computing_data_reduction ; CrysAlis PRO (Oxford Diffraction, 2009) ; _computing_molecular_graphics ; SHELXTL (Sheldrick, 2008) and Mercury (Macrae et al., 2008) ; _computing_publication_material ; SHELXL2014 (Sheldrick, 2015) and PLATON (Spek, 2009) ; _computing_structure_refinement ; SHELXL2014 (Sheldrick, 2015) ; _computing_structure_solution ; SHELXS97 (Sheldrick, 2008) ; _diffrn_ambient_temperature 294(2) _diffrn_detector 'CCD plate' _diffrn_measured_fraction_theta_full 0.996 _diffrn_measured_fraction_theta_max 0.827 _diffrn_measurement_device 'four-circle diffractometer' _diffrn_measurement_device_type 'Oxford Diffraction Xcalibur Sapphire3' _diffrn_measurement_method '\w scans' _diffrn_radiation_monochromator graphite _diffrn_radiation_probe x-ray _diffrn_radiation_type 'Mo K\a' _diffrn_radiation_wavelength 0.71073 _diffrn_reflns_av_R_equivalents 0.0457 _diffrn_reflns_av_unetI/netI 0.0889 _diffrn_reflns_limit_h_max 14 _diffrn_reflns_limit_h_min -9 _diffrn_reflns_limit_k_max 15 _diffrn_reflns_limit_k_min -14 _diffrn_reflns_limit_l_max 19 _diffrn_reflns_limit_l_min -18 _diffrn_reflns_number 13829 _diffrn_reflns_theta_full 25.242 _diffrn_reflns_theta_max 29.475 _diffrn_reflns_theta_min 3.733 _diffrn_source 'fine-focus sealed X-ray tube' _exptl_absorpt_coefficient_mu 0.848 _exptl_absorpt_correction_T_max 0.96 _exptl_absorpt_correction_T_min 0.82 _exptl_absorpt_correction_type multi-scan _exptl_absorpt_process_details ; (CrysAlis PRO; Oxford Diffraction, 2009) ; _exptl_crystal_colour colourless _exptl_crystal_density_diffrn 1.408 _exptl_crystal_description prism _exptl_crystal_F_000 676 _exptl_crystal_size_max 0.24 _exptl_crystal_size_mid 0.12 _exptl_crystal_size_min 0.08 _refine_diff_density_max 0.433 _refine_diff_density_min -0.412 _refine_ls_extinction_method none _refine_ls_goodness_of_fit_ref 1.057 _refine_ls_hydrogen_treatment mixed _refine_ls_matrix_type full _refine_ls_number_parameters 486 _refine_ls_number_reflns 7056 _refine_ls_number_restraints 0 _refine_ls_restrained_S_all 1.057 _refine_ls_R_factor_all 0.0977 _refine_ls_R_factor_gt 0.0552 _refine_ls_shift/su_max 0.002 _refine_ls_shift/su_mean 0.000 _refine_ls_structure_factor_coef Fsqd _refine_ls_weighting_details 'w=1/[\s^2^(Fo^2^)+(0.0383P)^2^+0.0182P] where P=(Fo^2^+2Fc^2^)/3' _refine_ls_weighting_scheme calc _refine_ls_wR_factor_gt 0.0989 _refine_ls_wR_factor_ref 0.1238 _reflns_number_gt 4668 _reflns_number_total 7056 _reflns_threshold_expression 'I > 2\s(I)' _cod_data_source_file fn3323sup1.cif _cod_data_source_block II _cod_original_cell_volume 1535.4(4) _cod_database_code 2021753 _shelx_space_group_comment ; The symmetry employed for this shelxl refinement is uniquely defined by the following loop, which should always be used as a source of symmetry information in preference to the above space-group names. They are only intended as comments. ; _shelx_hkl_file ; 0 0 -3 190169. 2247.85 6 0 0 3 202274. 1945.53 5 0 0 4 129223. 1821.80 5 0 0 -4 129072. 1787.25 5 0 0 -4 129633. 2131.50 6 0 0 5 17575.9 906.977 6 0 0 -5 16878.9 720.746 5 0 0 5 18035.8 767.790 5 0 0 -5 19230.9 928.509 6 0 0 -6 3112.53 464.117 1 0 0 6 3757.72 465.619 6 0 0 -6 4080.81 394.120 5 0 0 -6 3943.87 462.176 6 0 0 6 3682.68 388.387 5 0 0 7 19314.7 1145.94 6 0 0 -7 18869.0 911.475 5 0 0 7 17516.9 917.992 5 0 0 -8 19250.0 990.561 5 0 0 8 18956.3 1032.47 5 0 0 -8 18887.6 826.302 2 0 0 8 20116.4 1263.56 6 0 0 -9 3526.03 378.952 2 0 0 9 3019.61 536.622 6 0 0 9 2879.06 429.690 5 0 0 -10 892.524 213.677 2 0 0 -10 964.582 314.270 4 0 0 10 958.389 316.906 6 0 0 10 1078.46 271.825 5 0 0 11 17253.2 1378.08 3 0 0 11 18576.5 1480.43 6 0 0 -11 19298.0 1513.37 4 0 0 -11 18103.0 930.144 2 0 0 11 17838.4 1207.65 5 0 0 -12 2003.10 530.551 4 0 0 12 2059.06 548.592 6 0 0 12 2510.40 556.510 3 0 0 12 1512.18 367.486 5 0 0 13 1254.45 406.992 3 0 0 -13 1593.20 496.587 4 0 0 13 1111.60 372.084 6 0 0 14 1352.80 486.841 3 0 0 -14 1642.60 531.122 4 0 0 14 1905.86 586.442 6 0 0 15 2292.91 619.577 3 0 0 -15 3338.48 807.222 4 0 0 15 3412.41 782.875 6 0 0 16 252.113 285.997 6 0 0 -16-98.9780 267.653 4 0 0 16 232.033 283.977 3 0 0 17 307.174 286.549 3 0 0 17 1068.50 375.732 6 0 1 18-108.519 227.606 3 0 1 17 4953.10 956.111 6 0 1 17 4402.22 877.363 3 0 -1 -16 372.229 233.925 4 0 1 16 1369.82 503.965 3 0 1 16 1287.38 467.042 6 0 1 15 1133.70 383.611 5 0 1 15 963.492 395.764 3 0 1 15 1255.80 491.251 6 0 -1 -15 1473.27 542.378 4 0 1 14 2651.47 625.414 3 0 -1 -14 1652.74 521.301 4 0 1 14 2011.34 514.818 6 0 1 14 2067.04 506.682 5 0 1 13 4224.09 738.347 6 0 1 13 3825.85 637.024 5 0 1 13 4018.45 734.139 3 0 1 12 39.5995 176.901 3 0 1 12-148.945 239.924 6 0 1 12-94.4390 156.477 5 0 -1 -12-328.021 164.208 2 0 1 11 5375.80 749.932 3 0 1 11 6335.07 810.023 6 0 1 11 4323.72 609.149 5 0 1 10 1968.18 399.335 5 0 1 10 1966.51 436.690 6 0 1 10 1408.28 379.844 3 0 1 9-142.113 204.251 3 0 1 9 198.024 197.086 6 0 1 9-1.23043 118.548 5 0 1 8 19.9848 116.276 6 0 1 8 59.5438 108.714 5 0 -1 -8 245.203 118.136 6 0 1 8 92.5044 112.283 3 0 -1 -7 9312.93 660.115 5 0 1 7 8215.66 706.674 3 0 1 7 8675.02 711.977 6 0 -1 -7 9358.18 705.697 6 0 1 7 8105.09 644.171 5 0 -1 -6 126124. 2330.88 6 0 1 6 122016. 2528.90 3 0 -1 -6 124682. 2234.28 5 0 1 6 122956. 2357.66 6 0 1 6 119353. 2280.08 5 0 -1 -6 123649. 2809.45 1 0 -1 -5 37722.8 1397.28 1 0 1 5 37963.8 1179.49 5 0 1 5 38055.3 1271.82 3 0 -1 -5 37941.2 1136.97 5 0 -1 -5 38862.9 1151.08 6 0 1 5 37441.5 1161.29 6 0 1 4 696.450 156.587 5 0 -1 -4 737.840 187.231 1 0 1 4 806.051 177.047 3 0 -1 -4 740.808 140.289 6 0 1 4 761.604 149.324 6 0 1 3 175922. 1983.29 5 0 1 3 171887. 2045.45 3 0 -1 -3 165721. 1683.99 6 0 -1 -3 164873. 2203.34 1 0 -1 2 51700.0 1145.54 4 0 1 -2 54749.5 1238.72 6 0 1 -2 54440.1 794.643 5 0 1 -3 919.809 98.3821 2 0 1 -3 920.679 192.963 6 0 1 -3 900.140 127.888 5 0 1 -4 2961.78 201.209 2 0 1 -4 2886.39 366.591 6 0 1 -4 2548.95 244.572 5 0 -1 5 25242.8 881.662 5 0 1 -5 24778.7 659.792 2 0 1 -5 25752.1 864.914 5 0 1 -5 27707.1 1233.97 6 0 1 -6 3930.21 370.875 5 0 1 -6 3834.71 282.901 2 0 -1 6 4333.33 544.981 6 0 -1 6 4245.36 403.163 5 0 -1 7 941.688 218.789 5 0 -1 7 1114.47 319.927 6 0 1 -7 839.826 151.575 2 0 1 -7 1041.48 213.029 5 0 1 -8 788.724 155.495 2 0 1 -8 914.470 220.347 5 0 -1 8 632.202 271.400 6 0 1 -8 756.012 288.495 4 0 1 -9 147.981 78.2031 2 0 1 -9 139.186 191.391 4 0 -1 9-69.7724 154.288 6 0 1 -9 39.6057 115.352 5 0 1 -10 492.816 132.017 2 0 1 -10 437.577 270.016 4 0 -1 10 330.559 271.148 6 0 1 -11 814.390 425.904 4 0 -1 11-97.2109 313.964 6 0 1 -12 7645.29 1027.04 4 0 -1 12 7897.24 1077.42 6 0 -1 13 168.683 202.764 6 0 1 -13 83.1425 224.307 4 0 -1 14 88.5681 209.549 6 0 1 -14-240.938 379.419 4 0 -1 14-371.508 278.297 3 0 -1 15 1038.31 452.979 3 0 1 -15 843.659 410.441 4 0 -1 15 1043.09 458.405 6 0 -1 16 4445.14 960.758 6 0 -1 16 5776.40 1025.96 3 0 -1 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491.817 6 2 8 7 11859.1 1066.27 5 2 8 6 1582.51 379.043 5 -2 -8 -6 1468.54 234.106 6 2 8 6 1449.40 400.539 1 2 8 5-57.2038 133.105 5 2 8 5 11.2613 54.2808 7 -2 -8 -5 49.9964 74.4596 6 2 8 5 9.74478 151.646 1 2 8 4 478.683 203.049 5 2 8 4 848.886 206.565 7 2 8 4 823.460 361.545 1 -2 -8 -4 344.501 156.582 6 -2 -8 -3 8462.41 751.795 6 2 8 3 8247.75 808.996 5 -2 -8 -2 8074.75 789.870 6 2 8 2 7252.79 741.516 5 2 8 1 1076.71 278.659 5 -2 -8 -1 864.158 307.105 6 -2 -8 0 574.230 279.790 6 -2 -8 1 1170.85 383.456 6 -2 -8 2 268.114 242.514 6 -2 -8 3-85.2082 217.428 6 -2 -8 4 9329.43 1190.35 6 -2 -8 5 578.684 349.542 6 -2 -8 6 1310.16 480.519 6 -2 -8 7 1977.57 683.039 6 -2 -8 8 5050.35 1025.93 6 -2 -8 9 815.137 524.002 6 2 9 17 1041.76 526.925 1 2 9 17 597.896 388.683 5 2 9 16 5127.68 1077.81 1 2 9 16 4517.51 943.674 5 2 9 15 2063.41 640.510 5 2 9 15 2119.37 675.996 1 2 9 14 1906.00 582.440 5 2 9 14 3217.47 794.389 1 2 9 13 3588.18 765.203 5 2 9 13 3272.11 767.952 1 2 9 12 7289.69 1048.81 5 2 9 12 6330.46 1009.81 1 2 9 11 348.004 202.085 5 2 9 11-25.1566 269.885 1 2 9 10 176.167 288.747 1 2 9 10 519.308 322.297 5 2 9 9 13122.6 1308.39 1 2 9 9 12482.7 1224.17 5 2 9 8 3623.78 637.929 5 -2 -9 -8 2939.22 219.721 6 2 9 8 2674.32 596.470 1 2 9 7 430.480 213.866 5 -2 -9 -7 888.934 182.190 6 2 9 7 784.826 369.040 1 2 9 6 364.407 212.752 5 -2 -9 -6 425.925 152.747 6 2 9 6 347.756 253.159 1 2 9 5 2336.41 481.266 5 2 9 5 2460.41 361.260 7 2 9 5 2161.88 532.961 1 -2 -9 -5 2065.58 353.743 6 2 9 4 2909.74 415.886 7 -2 -9 -4 2045.06 392.973 6 2 9 4 1973.64 433.219 5 2 9 4 2402.09 550.216 1 -2 -9 -3 3692.47 559.502 6 2 9 3 4313.78 630.685 5 2 9 2 1022.41 304.851 5 -2 -9 -2 661.499 254.348 6 -2 -9 -1 5769.83 775.156 6 2 9 1 5817.47 698.315 5 -2 -9 0 1626.63 454.488 6 2 9 0 1207.73 321.711 5 2 9 -1 917.662 280.276 5 -2 -9 1 934.855 383.173 6 -2 -9 2 7266.06 1004.39 6 -2 -9 3 3190.54 715.802 6 -2 -9 4 133.453 292.538 6 -2 -9 5 3823.39 855.817 6 -2 -9 6 3272.94 834.006 6 -2 -9 7 137.201 332.946 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2734.04 635.108 6 -2 -10 2 2619.00 660.934 6 -2 -10 3 2666.92 695.977 6 -2 -10 4 5492.18 1043.97 6 -2 -10 5 352.981 310.453 6 -2 -10 6 499.488 353.140 6 2 11 16 1370.13 525.728 1 2 11 15 724.201 365.744 5 2 11 15 671.399 392.312 1 2 11 14 577.778 416.735 1 2 11 14 1045.67 506.315 5 2 11 13 1132.97 473.301 5 2 11 13 1546.08 564.747 1 2 11 12 474.724 384.720 5 2 11 12-55.4822 205.803 1 2 11 11 1328.72 462.553 5 2 11 11 1647.16 555.989 1 2 11 10 757.976 363.511 5 2 11 10 525.729 313.509 1 2 11 9 3281.98 692.559 5 2 11 9 4438.74 842.256 1 2 11 8 334.140 243.780 5 2 11 8 136.244 217.239 1 2 11 7 871.341 351.630 5 2 11 7 1101.01 423.840 1 -2 -11 -6 869.772 279.721 6 2 11 6 1228.06 424.297 5 2 11 6 545.471 293.496 1 -2 -11 -5 1790.95 403.598 6 2 11 5 1154.17 365.924 5 2 11 5 945.835 435.040 1 2 11 4 422.358 298.508 1 -2 -11 -4-41.9877 146.637 6 2 11 4-91.6618 166.240 5 2 11 3 4328.89 682.130 5 -2 -11 -3 3331.61 615.106 6 -2 -11 -2 5592.83 825.856 6 2 11 2 5101.92 727.866 5 2 11 1 597.011 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348.311 1 -3 13 9 15.5881 164.726 5 -3 13 10 1053.28 534.675 1 -3 13 10 792.423 396.637 5 -3 13 11 1499.23 542.083 5 -3 13 11 1809.27 696.439 1 3 -12 0 1170.58 480.135 6 3 -12 -1 657.711 442.837 6 3 -12 -2 2603.33 682.542 6 3 -12 -3-101.674 304.670 6 3 -12 -4 607.880 341.643 6 3 -12 -5-64.1273 177.260 6 -3 12 5 302.367 310.634 1 3 -12 -6 598.934 332.259 6 -3 12 6 175.356 267.016 1 -3 12 7 347.352 331.865 1 -3 12 7 901.541 369.084 5 -3 12 8 175.964 228.239 1 -3 12 8 649.381 322.437 5 -3 12 9 3356.72 810.650 1 -3 12 9 2109.55 611.054 5 -3 12 10-49.6523 206.942 5 -3 12 10-91.9237 243.912 1 -3 12 11 302.001 268.534 5 -3 12 11 32.5358 228.774 1 -3 12 12-193.007 251.166 1 -3 12 12-238.047 233.617 5 -3 12 13 3257.77 839.683 1 -3 12 13 1956.16 676.318 5 -3 12 14 428.412 335.789 1 -3 12 15 620.425 409.887 1 3 -11 2 467.828 407.088 6 3 -11 1 2763.63 754.631 6 3 -11 0 172.862 267.127 6 3 -11 -1 831.603 416.406 6 3 -11 -2 4775.88 863.682 6 3 -11 -3 785.609 369.307 6 3 -11 -4 55.6885 209.636 6 3 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167.037 6 -3 10 6 86.1951 270.055 1 -3 10 7 3321.23 721.329 1 -3 10 7 2330.17 562.588 5 3 -10 -7 3927.52 630.778 6 3 -10 -8 2955.90 537.350 6 -3 10 8 3064.61 700.100 1 -3 10 8 2215.12 572.089 5 3 -10 -9 185.893 203.222 6 -3 10 9 72.1361 206.889 1 -3 10 9 216.538 176.397 5 -3 10 10 986.814 434.880 5 -3 10 10 1231.79 451.265 1 -3 10 11 128.827 222.795 1 -3 10 11 255.901 274.586 5 -3 10 12 2347.13 692.074 1 -3 10 12 3384.21 815.443 5 -3 10 13 765.029 403.684 1 -3 10 13 189.565 252.598 5 -3 10 14-195.003 261.115 1 -3 10 14-634.026 402.261 5 -3 10 15 770.652 468.557 1 -3 10 15 2011.18 664.630 5 -3 10 16 536.151 453.329 1 -3 10 17 1572.85 604.277 1 3 -9 5-443.937 380.164 6 3 -9 4-483.289 387.420 6 3 -9 3 1463.64 567.383 6 3 -9 2 2216.31 648.639 6 3 -9 1-91.5456 242.936 6 3 -9 0 1157.18 425.996 6 3 -9 -1 3821.99 730.398 6 3 -9 -2 3658.10 687.009 6 -3 9 2 3670.28 543.893 5 3 -9 -3 707.287 333.553 6 -3 9 3 647.418 268.030 5 3 -9 -4 2201.45 496.002 6 -3 9 4 3502.52 589.586 5 3 -9 -5 1490.17 396.328 6 -3 9 5 729.449 290.491 5 -3 9 6 6101.59 827.159 5 3 -9 -6 6706.47 817.973 6 -3 9 6 7575.96 1011.53 1 -3 9 7 269.884 327.153 1 3 -9 -7 209.074 208.300 6 -3 9 7 264.992 197.747 5 3 -9 -8 12667.7 989.586 7 -3 9 8 12567.4 1293.11 5 -3 9 8 14918.5 1412.71 1 -3 9 9 14108.8 1387.53 1 3 -9 -9 12817.6 988.557 7 -3 9 9 11601.7 1269.17 5 -3 9 10 1225.63 442.980 1 -3 9 10 1296.95 476.321 5 -3 9 11 213.312 215.622 1 -3 9 11 98.4651 223.623 5 -3 9 12 14941.1 1509.72 1 -3 9 12 13936.8 1534.30 5 -3 9 13 4629.79 865.207 1 -3 9 13 3307.26 784.689 5 -3 9 14 1605.95 538.492 1 -3 9 14 2201.61 650.343 5 -3 9 15 836.847 416.542 1 -3 9 15 732.065 435.057 5 -3 9 16 428.815 358.951 5 -3 9 16 1466.97 565.601 1 -3 9 17 32.9601 339.416 1 -3 9 18 295.552 311.595 1 3 -8 7 306.304 332.123 6 3 -8 6-663.988 423.522 6 3 -8 5 3966.75 893.041 6 3 -8 4 1939.93 630.149 6 3 -8 3 734.475 397.132 6 3 -8 2-35.0792 347.384 6 3 -8 1 2054.59 550.800 6 3 -8 0 452.270 275.627 6 -3 8 0 161.531 115.455 5 3 -8 -1 2.12479 178.565 6 -3 8 1 328.538 175.968 5 3 -8 -2 4092.99 675.262 6 -3 8 2 3357.61 497.966 5 -3 8 3 12002.0 979.920 5 3 -8 -3 13555.5 1168.84 6 -3 8 4 4944.93 669.980 5 3 -8 -4 5119.16 718.298 6 3 -8 -5 1858.01 423.018 6 -3 8 5 1588.09 403.232 5 3 -8 -6 24844.5 1404.86 7 -3 8 6 23885.8 1572.78 5 -3 8 6 24396.0 1658.69 1 -3 8 7 19767.0 1493.04 5 3 -8 -7 21995.3 1292.19 7 -3 8 7 20599.2 1541.70 1 -3 8 8 3965.14 691.275 1 -3 8 8 3703.58 684.696 5 3 -8 -8 5194.32 640.000 7 -3 8 9 10109.0 1096.69 1 3 -8 -9 9890.54 885.068 7 -3 8 9 8707.10 1065.87 5 -3 8 10 17989.9 1493.43 1 3 -8 -10 14418.6 1084.35 7 -3 8 10 15039.4 1423.35 5 -3 8 11 1945.21 544.661 1 -3 8 11 1348.79 461.575 5 -3 8 12 4940.16 853.367 1 -3 8 12 2763.90 640.907 5 -3 8 13 12158.6 1375.57 1 -3 8 13 11300.8 1382.68 5 -3 8 14-10.8996 223.550 1 -3 8 14 154.362 236.676 5 -3 8 15 4583.94 935.684 5 -3 8 15 5942.01 1036.83 1 -3 8 16 151.787 212.665 1 -3 8 16 335.721 353.384 5 -3 8 17 88.4634 328.298 1 3 -7 8 201.130 298.725 6 3 -7 7 588.691 400.172 6 3 -7 6-56.2753 301.277 6 3 -7 5 110.208 225.479 6 3 -7 4 1259.00 443.258 6 3 -7 3 1145.73 393.965 6 3 -7 2 156.420 261.805 6 3 -7 1 254.962 250.060 6 -3 7 -1 102.430 67.4583 5 3 -7 0 6590.95 863.302 6 -3 7 0 6969.74 574.111 5 3 -7 -1 11063.5 1055.24 6 -3 7 1 10061.3 756.962 5 3 -7 -2 4336.34 652.451 6 -3 7 2 4558.36 547.637 5 3 -7 -3 9946.67 951.242 6 -3 7 3 10346.7 868.533 5 -3 7 4 21893.0 1330.26 5 3 -7 -4 22589.5 1342.14 7 3 -7 -5 10455.7 891.411 7 -3 7 5 9331.74 920.314 5 -3 7 5 10829.3 1027.79 1 -3 7 6 367.987 250.281 1 3 -7 -6 37.3159 146.056 7 -3 7 6 104.883 187.338 5 3 -7 -7 15652.4 1102.77 7 -3 7 7 15649.3 1264.95 5 -3 7 7 16469.1 1274.68 1 -3 7 8 32529.4 1816.35 1 -3 7 8 32987.6 1902.51 5 -3 7 9 1964.97 467.040 1 -3 7 9 1794.57 495.932 5 -3 7 10 9049.03 1013.85 1 -3 7 10 7773.15 1002.33 5 -3 7 11 9391.47 1077.81 1 -3 7 11 9460.89 1144.65 5 -3 7 12 14783.1 1407.80 1 -3 7 12 13552.5 1416.96 5 -3 7 13 175.016 231.537 1 -3 7 13 247.438 239.946 5 -3 7 14-168.613 204.776 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4 9 13 1027.18 406.068 5 4 9 13 147.243 294.779 1 4 9 12 944.050 368.482 5 4 9 12 469.251 303.508 1 4 9 11 370.001 255.405 5 4 9 11 1332.27 460.415 1 4 9 10 409.787 251.059 5 4 9 10 806.551 399.738 1 4 9 9 4325.24 745.270 5 4 9 9 5954.44 906.279 1 4 9 8 3389.84 648.064 5 4 9 8 2973.21 629.709 1 4 9 7 4172.26 739.765 1 4 9 7 4176.25 686.077 5 4 9 6 1108.16 400.591 5 -4 -9 -6 799.496 178.551 6 4 9 6 562.677 343.214 1 4 9 5 2955.81 577.171 5 -4 -9 -5 3148.92 422.606 6 4 9 5 3230.90 413.935 6 4 9 5 3468.34 639.691 1 4 9 4 1553.29 430.492 5 -4 -9 -4 2120.29 385.666 6 4 9 4 2082.35 502.760 1 4 9 3 5051.34 781.706 1 -4 -9 -3 5700.45 696.154 6 4 9 2 4089.49 686.145 1 -4 -9 -2 3618.52 591.816 6 -4 -9 -1 626.833 332.670 6 -4 -9 0 4287.63 731.803 6 -4 -9 1 83.1555 192.573 6 -4 -9 2 2024.50 554.244 6 -4 -9 3 2672.20 662.017 6 -4 -9 4-47.1751 318.386 6 -4 -9 5 930.751 483.892 6 -4 -9 6 356.941 383.866 6 -4 -9 7 155.110 262.023 6 4 10 16-218.006 286.387 5 4 10 16 398.106 390.820 1 4 10 15-11.5510 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14-264.719 332.443 1 5 10 13 1635.30 518.357 5 5 10 13 2454.57 750.205 1 5 10 12-188.843 308.455 5 5 10 12 502.258 357.445 1 5 10 11 203.540 236.553 5 5 10 11 239.803 231.799 1 5 10 10 1643.64 508.284 5 5 10 10 1632.85 547.491 1 5 10 9 2286.97 640.698 5 5 10 9 3391.86 747.362 1 5 10 8 5773.76 939.889 1 5 10 8 6769.22 977.912 5 5 10 7 396.875 268.777 1 5 10 7 183.781 270.136 5 5 10 6 37.9066 229.522 5 5 10 6 628.536 310.601 1 5 10 5 16181.5 1467.88 1 -5 -10 -5 14386.3 993.885 6 5 10 5 14185.4 1330.01 5 -5 -10 -4 16903.5 1181.04 6 5 10 4 17770.5 1531.68 1 5 10 3 430.959 364.508 1 -5 -10 -3-87.8979 206.143 6 5 10 2 2219.77 552.022 1 -5 -10 -2 1733.62 469.258 6 -5 -10 -1 7715.61 980.207 6 5 10 1 8268.04 1063.92 1 -5 -10 0 1281.84 454.837 6 -5 -10 1 466.824 391.501 6 -5 -10 2 7391.01 1125.14 6 -5 -10 3 1663.57 579.605 6 -5 -10 4 1007.95 574.389 6 -5 -10 5 765.188 425.768 6 -5 -10 6-260.599 394.203 6 5 11 15 3384.86 846.716 5 5 11 14 165.252 259.518 5 5 11 14 191.046 224.285 1 5 11 13 122.208 175.126 5 5 11 13-359.845 420.652 1 5 11 12 384.343 304.226 5 5 11 12 868.562 439.704 1 5 11 11 2893.33 712.079 5 5 11 11 2351.21 671.433 1 5 11 10 1923.34 591.845 5 5 11 10 3124.94 768.292 1 5 11 9 1284.54 430.814 5 5 11 9 652.938 391.540 1 5 11 8 6514.61 1020.43 1 5 11 8 5634.96 906.421 5 5 11 7 2998.37 666.171 5 5 11 7 3089.01 728.910 1 5 11 6 2184.28 568.261 5 5 11 6 1756.80 572.620 1 5 11 5-49.5479 188.429 5 5 11 5 74.4120 237.971 1 -5 -11 -4 13565.2 1156.91 6 5 11 4 16771.2 1499.20 5 5 11 4 14451.6 1472.19 1 5 11 3 1634.99 504.829 5 5 11 3 1191.00 456.661 1 -5 -11 -3 1365.10 408.616 6 5 11 2 1322.78 474.591 1 -5 -11 -2 1730.35 487.599 6 5 11 1 848.772 403.452 1 -5 -11 -1 578.475 367.679 6 -5 -11 0 2796.53 671.049 6 -5 -11 1 1339.91 499.706 6 -5 -11 2 57.7972 314.351 6 -5 -11 3 17.6253 249.855 6 -5 -11 4 1127.49 565.221 6 5 12 13 2401.69 720.475 5 5 12 13 2301.97 763.765 1 5 12 12 800.684 422.349 5 5 12 12 905.691 462.095 1 5 12 11-344.614 308.203 5 5 12 11 811.949 441.968 1 5 12 10 3592.58 804.986 5 5 12 10 2845.47 745.190 1 5 12 9 1212.62 449.010 5 5 12 9 2507.54 717.020 1 5 12 8 888.396 447.964 1 5 12 8 676.362 351.373 5 5 12 7 382.255 280.489 5 5 12 7 574.970 387.266 1 5 12 6 1275.99 462.133 5 5 12 6 3666.08 834.856 1 5 12 5 437.433 304.969 5 5 12 5 556.920 322.336 1 5 12 4 1724.50 564.892 5 5 12 4 2852.78 721.971 1 5 12 3 780.234 367.912 5 5 12 3 1783.85 565.920 1 -5 -12 -3 1589.82 491.789 6 5 12 2-123.168 196.730 5 -5 -12 -2 213.079 214.823 6 5 12 1 594.138 314.113 5 -5 -12 -1 460.421 311.701 6 -5 -12 0 726.539 448.236 6 -5 -12 1 1323.43 523.445 6 -5 -12 2 571.630 353.848 6 -5 -12 3 465.458 455.609 6 5 13 12-103.215 210.689 5 5 13 12-813.382 476.159 1 5 13 11 3055.73 796.874 5 5 13 11 2578.07 767.875 1 5 13 10 141.928 267.305 5 5 13 10 248.961 331.452 1 5 13 9-999.413 457.128 5 5 13 9 291.733 265.115 1 5 13 8 1598.19 545.455 5 5 13 8 2736.35 774.143 1 5 13 7 36.6698 312.974 5 5 13 7 171.998 228.745 1 5 13 6 237.905 279.170 5 5 13 6 402.238 386.946 1 5 13 5 3218.28 735.163 5 5 13 5 4022.25 903.077 1 5 13 4 606.835 351.836 5 5 13 4 1944.01 647.601 1 5 13 3 171.868 238.910 5 5 13 3 408.192 425.224 1 5 13 2-165.137 201.491 5 5 13 2 421.101 360.840 1 5 13 1 1033.24 398.931 5 5 13 1 825.362 396.665 1 -5 -13 -1 78.2586 187.105 6 -5 -13 0 847.125 493.378 6 5 13 0 607.118 400.254 1 -5 -13 1 195.959 256.185 6 5 14 9-136.834 244.910 5 5 14 8-375.222 314.192 5 5 14 8-56.1240 343.389 1 5 14 7-445.706 310.734 5 5 14 7 622.332 412.865 1 5 14 6-94.5001 198.149 5 5 14 6 177.123 284.180 1 5 14 5-236.250 234.848 5 5 14 5-248.140 292.920 1 5 14 4-321.353 268.485 5 5 14 4 836.302 492.525 1 5 14 3 517.582 324.610 5 5 15 5 357.050 310.138 5 -6 12 6-844.016 469.061 1 6 -12 -6 147.200 251.742 6 6 -12 -7 1876.88 604.820 6 -6 12 7 3103.60 866.860 1 -6 12 8 919.963 457.408 1 -6 12 9 296.411 291.444 1 -6 12 10 578.981 399.178 1 6 -11 -3 673.597 387.219 6 6 -11 -4 643.992 423.043 6 6 -11 -5 2023.55 639.670 6 -6 11 5 1161.77 493.094 1 -6 11 6 1336.99 528.463 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925.615 7 -6 9 5 5089.25 800.204 5 6 -9 -6 183.900 226.666 7 -6 9 6 184.583 194.612 1 -6 9 6 374.617 336.461 5 6 -9 -7 460.125 302.450 7 -6 9 7 463.074 350.350 1 -6 9 7 130.453 227.548 5 6 -9 -8 2940.38 634.588 7 -6 9 8 2193.00 580.836 1 -6 9 8 1265.59 445.143 5 6 -9 -9 1020.91 379.051 7 -6 9 9 1110.75 395.797 1 -6 9 9 923.367 387.552 5 -6 9 10-110.218 169.696 1 6 -9 -10 16.6483 214.196 7 -6 9 10 194.715 249.059 5 -6 9 11-211.033 219.729 1 -6 9 11 619.531 384.319 5 -6 9 12 1811.87 574.762 5 -6 9 13 323.371 330.365 5 6 -8 4 3.82711 315.156 6 6 -8 3 277.671 312.418 6 6 -8 2 2588.32 697.193 6 6 -8 1 2369.23 650.925 6 6 -8 0 159.226 359.052 6 6 -8 -1 381.511 312.395 6 6 -8 -1 949.738 358.058 2 6 -8 -2 4916.48 882.058 6 6 -8 -3 1092.50 452.256 7 6 -8 -3 1343.22 455.761 6 6 -8 -4 96.6247 177.367 7 -6 8 4 56.1328 172.139 5 6 -8 -5 4233.00 760.264 7 -6 8 5 5108.82 799.908 5 6 -8 -6 7772.67 1016.24 7 -6 8 6 9354.86 1101.14 5 -6 8 6 10053.3 1133.92 1 6 -8 -7 2131.16 537.992 7 -6 8 7 1761.20 470.758 1 -6 8 7 1167.27 437.603 5 -6 8 8 910.899 370.220 1 -6 8 8 597.780 309.876 5 6 -8 -8 424.892 298.709 7 6 -8 -9 351.035 181.676 7 -6 8 9 463.621 315.139 5 -6 8 9 76.2828 181.624 1 -6 8 10 4344.30 751.762 1 6 -8 -10 2620.96 616.837 7 -6 8 10 3426.36 764.505 5 -6 8 11 16.5060 139.816 1 -6 8 11 367.955 315.754 5 -6 8 12-230.066 257.015 5 -6 8 13 1428.30 541.422 5 -6 8 14 2015.65 673.540 5 6 -7 6-78.2430 245.521 6 6 -7 5 1535.43 576.908 6 6 -7 4 4673.97 928.001 6 6 -7 3 874.663 409.012 6 6 -7 2-191.198 263.729 6 6 -7 1 2578.38 647.894 6 6 -7 1 3424.05 569.797 2 6 -7 0 47237.4 2632.54 6 6 -7 0 44335.5 2077.75 2 6 -7 -1 998.144 429.825 6 6 -7 -1 1124.48 393.165 2 6 -7 -2 1941.15 522.977 7 6 -7 -3 18622.5 1542.63 7 6 -7 -4 1639.31 488.895 7 -6 7 4 1126.64 375.155 5 6 -7 -5 2109.01 537.951 7 -6 7 5 2246.83 516.750 5 6 -7 -6 5108.41 829.649 7 -6 7 6 6012.20 852.451 5 -6 7 6 6736.97 848.088 1 6 -7 -7 3459.08 687.575 7 -6 7 7 3944.25 656.434 1 -6 7 7 3835.55 711.880 5 -6 7 8 337.192 214.356 1 -6 7 8 609.619 331.454 5 -6 7 9 369.408 237.704 1 -6 7 9 797.140 409.251 5 -6 7 10 9.16654 133.087 1 -6 7 10 447.018 367.314 5 -6 7 11 3857.53 684.539 1 -6 7 11 4172.81 845.869 5 -6 7 12 777.494 439.676 5 -6 7 13-59.3492 248.798 5 -6 7 14 399.359 240.434 5 6 -7 -15 1071.18 504.237 2 6 -6 7 2059.92 752.112 6 6 -6 6 6441.77 1125.45 6 6 -6 5 301.981 342.493 6 6 -6 4 2544.63 699.012 6 6 -6 3 2395.74 643.016 6 6 -6 2-390.182 407.682 6 6 -6 2-132.863 126.330 2 6 -6 1 101.788 219.273 6 6 -6 1 494.200 224.582 2 6 -6 0 8768.88 1096.10 6 6 -6 0 8494.78 1054.40 7 6 -6 0 8465.89 878.158 2 6 -6 -1 2830.17 630.715 7 6 -6 -1 2998.53 546.443 2 6 -6 -2 992.711 356.778 7 6 -6 -2 899.615 326.662 2 6 -6 -3 373.577 251.154 7 6 -6 -4 2765.21 581.171 7 6 -6 -5 3763.46 690.932 7 -6 6 5 4374.65 691.050 5 -6 6 5 4436.19 651.881 1 -6 6 6 4373.02 725.414 5 -6 6 6 4763.56 667.627 1 -6 6 7 125.422 162.960 1 -6 6 7-51.9759 244.745 5 -6 6 8 2543.03 577.987 5 -6 6 8 2790.80 514.602 1 -6 6 9 140.235 131.240 1 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8 2.90413 135.043 1 -6 5 8 41.9466 229.361 5 -6 5 9 3429.41 550.513 1 -6 5 9 2027.62 556.234 5 -6 5 10 9328.36 939.483 1 -6 5 10 9284.14 1169.00 5 -6 5 11 7547.28 867.882 1 -6 5 11 5801.41 970.951 5 6 -5 -11 6006.31 975.386 2 -6 5 12 1094.89 454.828 5 6 -5 -12 861.392 361.037 2 -6 5 13 2827.96 701.388 5 6 -5 -13 2413.91 651.819 2 -6 5 14 2981.19 768.862 5 6 -5 -14 2068.38 615.108 2 6 -5 -15-301.293 323.080 2 6 -5 -16 4958.44 1011.97 2 6 -5 -17 325.547 388.414 2 6 -4 10 105.563 239.474 6 6 -4 9 812.217 494.848 6 6 -4 8 446.893 368.769 6 6 -4 7 6564.63 1060.03 6 6 -4 6-49.8646 319.340 6 6 -4 5-51.5970 196.359 6 6 -4 4 2216.04 353.960 2 6 -4 4 2393.78 556.811 6 6 -4 3 1218.91 417.864 6 6 -4 3 659.994 211.742 2 6 -4 2 2134.96 521.676 7 6 -4 2 2331.66 406.464 2 6 -4 2 2232.75 285.050 5 6 -4 1 19258.3 1494.38 7 6 -4 1 17552.6 903.381 5 6 -4 1 20377.9 1226.03 2 6 -4 0 9145.16 484.888 4 6 -4 0 8324.74 969.850 7 6 -4 0 8703.01 698.303 5 6 -4 0 9716.22 883.313 2 6 -4 -1 11.0490 208.659 7 6 -4 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3065.20 669.367 6 7 6 -4 123.964 165.377 2 -7 -6 4 340.187 347.093 6 7 6 -5 3728.52 716.234 2 -7 -6 5 1863.13 568.684 6 7 6 -6 1690.05 482.301 2 -7 -6 6 1747.99 558.158 6 7 6 -7 112.873 170.336 2 -7 -6 7-70.3506 257.580 6 7 6 -8 2548.13 623.939 2 -7 -6 8 1981.93 662.761 6 7 6 -9 2545.86 616.289 2 -7 -6 9 2146.66 721.936 6 -7 -6 10 2049.86 660.637 6 7 7 16 706.057 364.846 5 7 7 15 839.218 413.781 5 7 7 14 91.4721 149.365 5 7 7 13 562.172 379.042 5 7 7 12 2208.82 534.088 5 7 7 11 201.105 164.570 5 7 7 11 200.272 215.892 1 7 7 10 1289.51 418.287 5 7 7 10 1286.29 529.779 1 7 7 9 6989.60 993.216 1 7 7 9 6491.17 908.224 5 7 7 8 1970.06 311.588 7 7 7 8 1976.14 544.453 1 7 7 7 1040.42 378.962 1 7 7 7 953.600 394.707 2 7 7 6 114.131 159.427 2 7 7 6 569.953 268.449 1 7 7 5 1237.11 267.618 6 7 7 5 1270.45 387.748 1 7 7 5 1199.43 405.246 2 7 7 4-22.6872 165.305 1 7 7 4 183.108 185.140 2 7 7 3-64.1049 111.019 1 7 7 3-129.956 263.190 2 7 7 2 1314.11 410.378 2 7 7 2 1112.36 319.318 1 7 7 1 709.075 333.462 2 -7 -7 -1 380.906 127.761 3 7 7 1 789.501 269.658 1 7 7 0 3144.37 654.577 2 -7 -7 0 3028.03 377.909 3 7 7 0 3304.79 513.439 1 7 7 -1 1031.63 439.774 2 7 7 -1 957.603 296.095 1 -7 -7 1 1185.89 419.560 6 7 7 -2 195.332 189.684 2 7 7 -2 323.526 192.662 1 -7 -7 2 19.3788 209.106 6 7 7 -3 302.846 326.517 2 -7 -7 3 317.201 191.089 6 7 7 -4 551.716 266.563 2 -7 -7 4 578.536 321.281 6 7 7 -5-24.2643 243.970 2 -7 -7 5 89.2641 272.076 6 7 7 -6 93.0048 261.214 2 -7 -7 6-135.729 332.651 6 7 7 -7 5246.25 913.999 2 -7 -7 7 6727.68 1163.00 6 7 7 -8-160.493 213.979 2 -7 -7 8 197.595 292.382 6 -7 -7 9 1556.37 643.385 6 7 8 17 253.483 230.414 5 7 8 16 121.941 196.310 5 7 8 15 169.579 163.476 5 7 8 14 1544.17 483.001 5 7 8 13-120.655 216.865 5 7 8 13-300.127 267.921 1 7 8 12 1045.24 410.487 5 7 8 12 1187.31 504.068 1 7 8 11 3786.63 738.064 5 7 8 11 3566.80 798.970 1 7 8 10 1148.03 455.033 5 7 8 10 2016.62 602.160 1 7 8 9 157.277 285.582 5 7 8 9 69.5954 235.704 1 7 8 8 721.764 366.399 5 7 8 8 388.740 252.192 1 7 8 7 4369.07 757.795 2 7 8 7 4221.51 741.422 1 7 8 6 1141.19 407.302 1 7 8 6 1323.89 463.178 2 7 8 5 179.182 186.248 1 7 8 5 43.0852 180.445 2 7 8 4 1579.26 441.212 1 7 8 4 1828.09 519.892 2 7 8 3 26.9537 160.162 1 7 8 3 109.686 170.864 2 7 8 2 236.606 239.788 1 7 8 2 117.360 191.551 2 7 8 1 133.026 165.287 1 7 8 1-41.2987 194.312 2 7 8 0-25.8774 180.046 2 7 8 0 87.8953 174.546 1 -7 -8 0 55.1358 201.273 6 7 8 -1 929.810 366.230 2 7 8 -1 1204.07 362.308 1 -7 -8 1 1250.96 419.875 6 7 8 -2 1700.18 524.666 2 -7 -8 2 1996.37 584.504 6 7 8 -2 2403.57 499.242 1 7 8 -3 1067.49 397.303 2 -7 -8 3-32.7795 311.727 6 7 8 -4 1581.24 473.880 2 -7 -8 4 1499.24 564.597 6 7 8 -5 2740.85 649.382 2 -7 -8 5 3062.95 738.741 6 7 8 -6-496.035 302.238 2 -7 -8 6 294.420 363.207 6 -7 -8 7 618.255 419.915 6 -7 -8 8 3623.45 932.068 6 7 9 16 779.126 425.671 5 7 9 15 74.5402 203.562 5 7 9 14-280.675 258.858 5 7 9 14 294.772 295.592 1 7 9 13 3554.43 782.395 5 7 9 13 3602.66 873.388 1 7 9 12 5439.76 918.985 5 7 9 12 5437.93 1020.27 1 7 9 11 568.559 306.980 5 7 9 11 498.030 386.559 1 7 9 10 13566.0 1484.70 1 7 9 10 9512.51 1190.24 5 7 9 9 5978.65 952.149 1 7 9 9 6314.49 958.881 5 7 9 8 2327.88 576.778 5 7 9 8 925.589 350.082 1 7 9 7 772.851 312.629 1 7 9 6 3457.83 664.364 1 7 9 6 4626.49 855.931 2 7 9 5 3670.51 679.942 1 7 9 5 4256.77 794.870 2 7 9 4 1064.55 382.516 1 7 9 4 1248.39 456.403 2 7 9 3-32.8118 175.362 1 7 9 3 249.268 244.116 2 7 9 2 2362.04 528.534 1 7 9 2 2378.38 627.031 2 7 9 1 2209.99 524.329 1 -7 -9 -1 2935.36 612.393 6 7 9 1 3348.98 703.765 2 7 9 0 208.087 194.468 1 -7 -9 0 188.769 225.781 6 7 9 0 121.369 194.172 2 7 9 -1 2196.80 507.867 1 -7 -9 1 3264.96 716.040 6 7 9 -1 2885.58 669.767 2 -7 -9 2 6074.71 1001.15 6 7 9 -2 6929.08 918.327 1 7 9 -2 5917.20 930.911 2 -7 -9 3 4369.14 903.431 6 7 9 -3 4546.56 846.160 2 -7 -9 4 439.693 386.643 6 7 9 -4 433.454 316.495 2 -7 -9 5 5074.37 1002.40 6 7 9 -5 4777.50 853.572 2 -7 -9 6 1611.98 606.684 6 7 10 15 4891.99 966.760 5 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411.092 2 -7 -10 4 2059.13 683.075 6 7 10 -4 2214.05 601.714 2 -7 -10 5-160.597 344.873 6 7 11 14 675.685 419.114 5 7 11 13 1692.38 573.695 5 7 11 13 2839.16 827.021 1 7 11 12-169.228 226.316 5 7 11 12-456.543 368.119 1 7 11 11 1713.25 630.801 1 7 11 11 1644.16 551.130 5 7 11 10 1875.49 599.369 5 7 11 10 2553.91 694.130 1 7 11 9 653.441 347.480 5 7 11 9 1202.42 473.703 1 7 11 8-11.6154 229.805 5 7 11 8 376.112 360.217 1 7 11 7 363.786 193.192 5 7 11 7 1024.91 440.845 1 7 11 6 2065.07 606.625 1 7 11 6 693.655 386.257 5 7 11 5 287.526 188.243 1 7 11 4 13.7805 219.756 1 -7 -11 -3 1175.11 391.956 6 7 11 3 465.358 314.472 1 7 11 2 1726.67 526.689 1 -7 -11 -2 2499.26 604.361 6 7 11 1-786.589 389.775 1 -7 -11 -1 81.5351 186.459 6 7 11 0 854.303 438.741 1 7 11 0 728.330 378.032 2 -7 -11 0 224.751 262.978 6 7 11 -1 4274.46 849.954 1 7 11 -1 3393.57 829.065 2 -7 -11 1 4283.64 881.126 6 7 11 -2 3625.79 771.032 2 -7 -11 2 3388.91 802.735 6 7 11 -2 3613.80 784.017 1 7 11 -3 554.573 325.854 2 -7 -11 3 100.026 259.291 6 -7 -11 4 167.576 270.049 6 7 12 12 1123.23 518.755 1 7 12 12 1535.89 544.546 5 7 12 11-600.356 379.827 5 7 12 11-386.942 375.824 1 7 12 10 573.641 383.326 5 7 12 10 547.950 397.374 1 7 12 9 561.685 348.124 5 7 12 9-363.327 350.543 1 7 12 8 481.728 342.001 5 7 12 8 1071.01 485.520 1 7 12 7-22.5723 211.585 5 7 12 7 875.492 438.628 1 7 12 6 1065.97 489.454 1 7 12 6 1316.61 483.796 5 7 12 5 3283.58 760.049 5 7 12 5 3261.41 755.284 1 7 12 4 4241.43 853.020 1 7 12 3-194.297 273.706 1 7 12 2 157.085 198.049 1 7 12 1 3857.99 862.321 1 -7 -12 -1 3867.90 808.889 6 7 12 0 455.004 332.883 1 -7 -12 0 352.441 245.945 6 7 12 -1 789.084 415.704 1 -7 -12 1 1121.43 561.665 6 7 12 -2 1094.85 496.452 1 -7 -12 2-271.354 335.311 6 7 13 11-49.3845 262.648 1 7 13 10 101.684 263.818 1 7 13 9-389.231 294.908 5 7 13 9-276.576 349.805 1 7 13 8-196.489 258.259 5 7 13 8 416.193 332.294 1 7 13 7-532.773 377.367 1 7 13 7 306.443 297.954 5 7 13 6 515.723 390.562 5 7 13 6-65.0980 220.963 1 7 13 5 280.608 179.119 5 7 13 5 763.478 464.011 1 7 13 4-284.194 256.531 5 7 13 4-197.418 264.070 1 7 13 3 392.072 307.827 5 7 13 3 426.399 254.095 1 7 13 2-498.282 352.149 1 7 13 1 726.557 385.878 1 7 13 0 174.427 270.738 1 7 13 -1-58.8804 267.582 1 -7 -13 1 1341.17 604.772 6 7 14 6 1906.27 670.157 1 7 14 5 872.553 418.293 5 7 14 5 1328.65 598.184 1 7 14 4 445.436 335.565 5 7 14 4 170.911 317.166 1 7 14 3 482.349 348.586 5 7 14 2-195.487 251.853 5 8 -10 -5 272.324 275.358 2 8 -10 -6-32.9216 298.166 6 8 -10 -6 84.2251 240.438 7 8 -10 -6 556.398 356.507 2 8 -10 -7 969.893 464.963 7 8 -10 -7 90.0289 211.402 2 8 -10 -8 1632.95 546.705 7 8 -9 -2 1245.60 551.037 6 8 -9 -3 132.716 237.526 6 8 -9 -3-260.390 225.699 2 8 -9 -4 51.8409 214.380 7 8 -9 -4 375.311 276.173 6 8 -9 -4 234.315 227.421 2 8 -9 -5 1580.76 527.764 7 8 -9 -5 3769.59 822.672 2 -8 9 5 3004.88 703.653 1 8 -9 -6 1543.61 552.948 7 8 -9 -6 508.371 361.431 2 8 -9 -7-72.3368 270.072 7 8 -9 -7-126.171 223.713 2 8 -9 -8 2365.56 622.476 7 8 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924.521 2 8 -7 -5 4195.64 836.718 7 8 -7 -5 3130.87 704.400 2 -8 7 5 3896.62 683.076 1 8 -7 -6-809.328 394.513 2 8 -7 -6 5.07883 326.345 7 8 -7 -7 581.679 356.919 7 8 -7 -7 785.511 360.582 2 8 -7 -8 1997.77 626.646 2 8 -7 -8 1644.72 551.794 7 8 -7 -9 1609.26 565.390 2 8 -7 -10 492.294 372.833 2 8 -7 -11 609.117 352.606 2 8 -7 -12-434.034 362.384 2 8 -6 5 83.0352 168.889 6 8 -6 4-466.791 346.680 6 8 -6 3 1097.54 496.363 6 8 -6 2 1019.33 462.665 6 8 -6 1 2841.88 744.244 6 8 -6 0 237.104 291.289 7 8 -6 0 13.5196 139.975 2 8 -6 -1 1836.95 551.495 7 8 -6 -1 1543.18 484.768 2 8 -6 -2 1117.38 439.935 7 8 -6 -2 1177.21 400.413 2 8 -6 -3 1214.31 475.533 7 8 -6 -3 1231.79 441.168 2 8 -6 -4 84.0856 310.031 7 8 -6 -4 383.021 269.875 2 8 -6 -5 7562.25 1117.33 7 8 -6 -5 9470.74 1187.65 2 -8 6 5 7040.00 837.896 1 8 -6 -6 412.717 329.262 7 -8 6 6 631.629 235.992 1 8 -6 -7 754.228 321.478 2 8 -6 -8 1921.51 606.608 2 8 -6 -9 221.963 242.598 2 8 -6 -10 2012.38 620.683 2 8 -6 -11 498.193 351.946 2 8 -6 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501.304 3 -8 -3 -2 3501.91 452.161 1 -8 -3 -1 19316.4 925.041 4 8 3 1 18756.8 915.384 3 8 3 1 19566.4 1495.72 2 -8 -3 -1 20875.6 952.448 1 -8 -3 0 25890.8 1135.85 4 8 3 0 23661.5 866.347 3 8 3 0 25982.1 1721.35 2 -8 -3 1 66.9887 104.860 4 8 3 -1 42.2758 226.821 2 8 3 -2 8233.62 1006.54 2 8 3 -3 20961.8 1609.39 2 8 3 -4 21047.9 1638.31 2 8 3 -5 2553.03 608.362 2 8 3 -6 698.392 355.137 2 8 3 -7 7235.06 1024.28 2 8 3 -8 7242.61 1049.80 2 8 3 -9 2972.39 698.028 2 8 3 -10-157.301 241.889 2 8 3 -10-220.646 356.974 4 8 3 -11 2895.22 707.609 2 8 3 -11 1976.94 588.355 4 8 3 -12 624.203 370.119 2 8 3 -12 1345.82 516.522 4 8 4 14 1015.51 490.434 3 8 4 13 2577.03 701.836 3 8 4 12-384.307 226.135 5 8 4 12 26.5927 268.268 3 8 4 11 3442.03 597.318 5 8 4 11 2550.31 646.720 3 8 4 10 48.1865 128.946 5 8 4 10-242.272 173.051 6 8 4 10 318.614 265.944 3 8 4 9 3951.22 631.902 5 8 4 9 4034.83 583.761 6 8 4 9 3813.57 696.607 3 8 4 9 3640.84 615.642 2 8 4 8 1364.50 359.288 7 8 4 8 938.901 363.609 3 8 4 8 1198.52 363.480 2 8 4 7 5937.73 726.316 7 8 4 7 4520.21 699.268 3 8 4 7 5133.51 723.452 2 8 4 6 4486.20 682.209 2 8 4 6 3950.18 601.527 7 8 4 6 3548.08 582.392 3 8 4 5 1105.33 385.160 2 8 4 5 1375.72 360.197 3 8 4 4 3138.56 585.517 2 8 4 4 2988.28 481.626 3 8 4 3 30163.2 1370.15 3 8 4 3 29936.2 1850.03 2 8 4 2 7696.95 696.931 1 8 4 2 7409.58 620.655 3 8 4 2 7770.54 965.282 2 -8 -4 -2 7985.59 677.352 1 8 4 1 55.1780 84.9445 1 8 4 1-202.778 240.276 2 8 4 0 5020.54 782.956 2 8 4 0 5679.50 485.117 1 8 4 -1 12541.1 643.232 1 8 4 -1 12453.7 1245.72 2 8 4 -2 11327.2 541.742 1 8 4 -2 11298.0 1211.38 2 8 4 -3 1814.33 201.332 1 8 4 -3 2061.56 529.550 2 8 4 -4 25119.3 1835.10 2 8 4 -5 4074.56 761.723 2 8 4 -6 3923.34 780.472 2 8 4 -7 3419.20 699.098 2 8 4 -8 4235.20 800.299 2 8 4 -9 3710.24 776.546 2 8 4 -10-380.614 313.036 2 8 4 -11 430.902 340.880 2 8 5 14 1252.46 520.414 3 8 5 13 738.526 294.688 5 8 5 13 1583.68 501.585 3 8 5 12 531.294 278.316 5 8 5 12-82.3433 247.508 3 8 5 11-118.363 159.523 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227.683 2 8 7 0 67.8228 147.007 1 8 7 -1-255.814 242.532 2 8 7 -1 319.444 192.459 1 8 7 -2 3153.20 711.007 2 8 7 -2 2915.77 485.158 1 8 7 -3-25.1715 250.908 2 8 7 -3 1.96323 117.217 1 8 7 -4 560.769 341.833 2 -8 -7 4 933.478 421.938 6 8 7 -5 39.9006 184.098 2 -8 -7 5 639.843 461.111 6 8 7 -6 119.102 201.011 2 -8 -7 6 192.202 287.021 6 8 7 -7 2157.75 613.766 2 -8 -7 7 3178.19 858.387 6 8 7 -8 266.403 278.879 2 -8 -7 8 1546.20 711.827 6 8 8 16 995.826 434.857 5 8 8 15 1017.47 441.027 5 8 8 14-47.4086 190.036 5 8 8 13 675.417 343.654 5 8 8 12 2613.78 624.711 5 8 8 12 2965.27 811.414 1 8 8 11 71.1597 187.043 5 8 8 11-372.666 337.511 1 8 8 10 217.196 223.795 5 8 8 10-304.177 388.868 1 8 8 9 4073.18 786.925 1 8 8 9 4666.18 819.092 5 8 8 8 7734.84 1054.55 1 8 8 8 8016.46 1070.25 2 8 8 7 384.274 310.733 1 8 8 7 57.8475 213.800 2 8 8 6 548.501 326.768 2 8 8 6 929.151 378.951 1 8 8 5 15880.4 1346.15 1 8 8 5 15542.6 1489.71 2 8 8 4 2475.21 548.064 1 8 8 4 1360.14 503.063 2 8 8 3 1642.01 428.106 1 8 8 3 2218.28 597.227 2 8 8 2 5828.92 762.901 1 8 8 2 6859.55 1012.05 2 8 8 1 2641.11 633.581 2 8 8 1 3695.53 619.685 1 8 8 0 552.041 326.530 2 8 8 0 428.954 240.071 1 8 8 -1 149.861 269.006 2 8 8 -1 214.222 179.508 1 8 8 -2 3484.87 763.225 2 8 8 -2 3505.94 597.994 1 -8 -8 2 3904.07 787.779 6 8 8 -3 294.931 274.548 2 8 8 -3 1137.07 340.206 1 8 8 -4-49.1971 209.271 2 -8 -8 4 128.523 281.587 6 8 8 -5 630.645 363.144 2 -8 -8 5 754.485 402.183 6 8 8 -6 1933.05 587.200 2 -8 -8 6 2745.97 829.314 6 8 8 -7 632.521 361.734 2 -8 -8 7 932.641 473.600 6 8 9 15-28.7847 273.072 5 8 9 14 363.212 295.604 5 8 9 13 22.7391 301.342 1 8 9 13 646.154 357.116 5 8 9 12 126.611 213.189 5 8 9 12 683.011 464.699 1 8 9 11 10923.3 1406.92 1 8 9 11 10244.4 1273.78 5 8 9 10 3961.68 813.404 5 8 9 10 3277.92 775.407 1 8 9 9 469.344 295.423 5 8 9 9 791.230 411.525 1 8 9 8 200.702 203.448 1 8 9 7 22178.8 1768.48 1 8 9 7 18896.4 1698.66 2 8 9 6 5821.95 882.743 1 8 9 6 6421.21 993.717 2 8 9 5-77.1444 159.262 1 8 9 5 105.139 260.057 2 8 9 4 9233.54 1068.12 1 8 9 4 8441.59 1135.25 2 8 9 3 8345.45 988.862 1 8 9 3 9303.29 1206.24 2 8 9 2 605.853 265.292 1 8 9 2 96.7785 249.908 2 8 9 1 231.407 223.972 1 8 9 1-223.208 317.817 2 8 9 0 4931.25 739.223 1 8 9 0 3682.81 785.508 2 8 9 -1 607.174 282.397 1 -8 -9 1 1405.59 478.676 6 8 9 -2 2366.58 528.556 1 -8 -9 2 1917.70 598.385 6 8 9 -2 2007.35 586.553 2 -8 -9 3 383.820 375.209 6 8 9 -3 575.512 354.655 2 -8 -9 4 4332.62 939.130 6 8 9 -4 4607.21 885.596 2 -8 -9 5 169.958 318.258 6 8 9 -5 402.612 308.317 2 -8 -9 6 484.482 403.186 6 8 9 -6 805.304 386.048 2 8 10 14 103.985 213.415 5 8 10 14 26.1948 306.754 1 8 10 13 2557.06 692.920 5 8 10 13 2397.47 777.412 1 8 10 12 374.119 327.377 5 8 10 12 1151.87 522.912 1 8 10 11 763.320 389.094 5 8 10 11-71.3975 373.753 1 8 10 10 3474.57 773.086 5 8 10 10 4354.43 892.159 1 8 10 9 4585.25 894.148 1 8 10 9 4469.33 841.181 5 8 10 8 37.5364 217.227 5 8 10 8 492.487 350.439 1 8 10 7 189.403 234.133 1 8 10 6 5449.31 901.767 1 8 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645.110 2 9 -6 -8 930.916 407.245 2 9 -6 -9 1312.56 536.267 2 9 -6 -10-642.983 392.475 2 9 -6 -11-590.322 387.376 2 9 -5 5 142.032 205.808 6 9 -5 4 1158.41 500.416 6 9 -5 3-375.772 324.047 6 9 -5 2 3889.30 853.668 7 9 -5 2 4163.50 875.888 6 9 -5 1 1693.86 538.680 7 9 -5 1 984.029 365.201 2 9 -5 0 1383.68 518.560 7 9 -5 0 861.158 353.108 2 9 -5 -1 227.848 228.239 7 9 -5 -1 358.228 290.068 2 9 -5 -2 4453.16 875.665 7 9 -5 -2 2806.82 649.422 2 9 -5 -3 353.996 322.060 7 9 -5 -3 385.227 309.266 2 9 -5 -4 3580.41 810.212 7 9 -5 -4 2484.76 648.705 2 9 -5 -5 4177.73 819.576 2 9 -5 -6 2134.98 605.466 2 9 -5 -7 503.458 338.330 2 9 -5 -8 3867.69 825.077 2 9 -5 -9 1629.28 569.211 2 9 -5 -10 310.372 268.573 2 9 -5 -11 274.176 397.548 2 9 -5 -12 3908.78 921.867 2 9 -4 7 1275.35 543.074 6 9 -4 6-581.348 360.641 6 9 -4 5 924.903 430.229 6 9 -4 4 991.999 495.611 6 9 -4 3 751.815 400.089 7 9 -4 3 1416.99 526.497 6 9 -4 2 1674.51 583.670 7 9 -4 2 1274.78 386.091 2 9 -4 1 5575.11 947.100 7 9 -4 1 5542.96 802.700 2 9 -4 0 1974.58 603.246 7 9 -4 0 1342.86 421.267 2 9 -4 -1 1568.00 502.548 7 9 -4 -1 727.025 332.140 2 9 -4 -2 4829.16 898.427 7 9 -4 -2 5929.84 921.014 2 9 -4 -3 7206.84 1095.25 7 9 -4 -3 10188.1 1216.48 2 9 -4 -4 6300.48 965.537 2 9 -4 -5-120.885 181.576 2 9 -4 -6 1483.22 524.293 2 9 -4 -7 3673.12 791.983 2 9 -4 -8 2980.37 734.190 2 9 -4 -9-105.394 298.391 2 9 -4 -10 3114.21 779.115 2 9 -4 -11 1103.60 488.667 2 9 -4 -12 1988.61 662.860 2 9 -4 -13 703.229 443.105 2 9 -3 8 271.507 297.299 6 9 -3 7 2664.86 677.494 6 9 -3 6 2101.73 648.704 6 9 -3 5 220.991 259.854 6 9 -3 4 3714.42 782.063 7 9 -3 4 3351.24 746.304 6 9 -3 3 4502.70 842.774 7 9 -3 3 3763.37 632.904 2 9 -3 2 12952.4 1395.12 7 9 -3 2 11216.5 1109.37 2 9 -3 1 527.069 354.719 7 9 -3 1 230.828 202.374 2 9 -3 0 6774.45 1016.24 7 9 -3 0 8389.19 1007.41 2 9 -3 -1 4184.02 820.957 7 9 -3 -1 4073.27 728.364 2 9 -3 -2 4735.75 802.784 2 9 -3 -3 925.426 368.136 2 9 -3 -4 29538.6 2069.45 2 9 -3 -5 2120.84 577.338 2 9 -3 -6 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721.183 2 9 -1 -9 218.862 210.325 4 9 -1 -9 482.467 337.381 2 9 -1 -10 1426.37 411.348 4 9 -1 -10 1582.72 556.954 2 9 -1 -11 6172.17 889.040 4 9 -1 -11 5894.84 1040.67 2 9 -1 -12 777.693 275.678 4 9 -1 -12 133.145 251.202 2 9 -1 -13-371.466 283.160 4 9 -1 -13 930.027 564.572 2 9 -1 -14 1934.76 573.826 4 9 -1 -14 3143.98 825.062 2 9 0 12 574.501 353.806 6 9 0 11 1644.41 594.108 6 9 0 10 1057.21 438.763 6 9 0 9 388.591 268.167 6 9 0 8-32.4886 144.900 6 9 0 7 2159.03 562.164 6 9 0 6 4594.62 670.488 2 9 0 6 4737.33 805.942 7 9 0 5-451.420 233.648 2 9 0 5-491.094 289.650 7 9 0 4 2754.46 541.995 2 9 0 4 2524.95 587.189 7 9 0 3 26159.2 1866.57 7 9 0 3 27726.6 1739.70 2 9 0 2 4071.37 741.499 7 9 0 2 4436.64 712.396 2 9 0 1 1587.51 439.747 2 9 0 0 1108.19 362.604 2 9 0 -1 1789.61 475.922 2 9 0 -2 52.4502 205.719 2 9 0 -3 152.212 163.653 2 9 0 -4 327.595 298.448 2 9 0 -5 3736.05 726.667 2 9 0 -6 2046.21 392.226 4 9 0 -6 2122.84 554.902 2 9 0 -7 51.2237 129.748 4 9 0 -7 8.25677 191.372 2 9 0 -8 6647.77 792.176 4 9 0 -8 6701.23 1022.97 2 9 0 -9 8229.83 946.168 4 9 0 -9 8183.11 1171.27 2 9 0 -10 804.501 354.795 4 9 0 -10 230.119 318.349 2 9 0 -11 567.877 387.025 4 9 0 -11 88.4167 242.589 2 9 0 -12 1874.78 559.779 4 9 0 -12 1739.65 576.942 2 9 0 -13 947.570 434.212 4 9 0 -13 877.001 434.316 2 9 0 -14 938.016 441.606 4 9 0 -14 600.037 377.572 2 9 1 12-122.514 218.707 6 9 1 11 1124.12 444.368 6 9 1 10 232.879 224.675 6 9 1 9 6036.87 896.939 6 9 1 8 10113.8 1141.90 6 9 1 7 894.202 320.340 2 9 1 7 565.567 333.192 7 9 1 6 2323.05 487.035 2 9 1 6 2912.95 605.953 7 9 1 5 96.6205 165.243 2 9 1 5 612.497 312.846 7 9 1 4 348.243 222.422 2 9 1 4 462.124 234.340 7 9 1 3 1233.80 449.985 7 9 1 3 1696.93 477.102 2 9 1 2 1672.63 447.027 2 9 1 1 41.4100 159.336 2 9 1 0 144.671 165.637 2 9 1 -1 18.2547 276.057 2 9 1 -2 54.8225 202.057 2 9 1 -3 4837.83 799.325 2 9 1 -4 1644.01 460.087 2 9 1 -5 1016.92 412.384 2 9 1 -6 3860.31 777.717 2 9 1 -7 567.319 222.512 4 9 1 -7 1692.78 540.856 2 9 1 -8 55.0540 160.935 4 9 1 -8 218.232 360.437 2 9 1 -9 7797.84 953.118 4 9 1 -9 8958.32 1225.28 2 9 1 -10 7852.36 1017.08 4 9 1 -10 6560.82 1076.28 2 9 1 -11 366.385 294.327 4 9 1 -11 927.344 491.466 2 9 1 -12 426.407 297.134 4 9 1 -12 258.913 218.075 2 9 1 -13 830.239 378.643 4 9 1 -13 1084.11 465.473 2 9 1 -14 4554.89 972.167 2 9 2 12 1750.31 610.204 3 9 2 11 4221.24 762.604 6 9 2 10 3091.07 638.532 6 9 2 9 946.863 467.463 6 9 2 8 4070.94 716.689 7 9 2 8 5128.73 786.514 6 9 2 8 3370.80 574.544 2 9 2 7 10135.0 1078.44 7 9 2 7 9487.46 980.635 2 9 2 6 9603.63 1060.92 7 9 2 6 7379.93 884.041 2 9 2 5 7232.13 942.297 7 9 2 5 7076.43 883.792 2 9 2 4 1829.82 465.337 2 9 2 4 2429.32 562.731 7 9 2 3 52438.7 2469.69 2 9 2 2 10399.3 1125.64 2 9 2 1 4701.18 767.381 2 9 2 0 1973.91 509.595 2 9 2 -1 6995.82 493.688 3 9 2 -1 6942.45 951.263 2 9 2 -2 186.144 173.556 2 9 2 -2-90.5887 42.8308 3 9 2 -3 9261.17 1111.57 2 9 2 -4 14638.4 1432.13 2 9 2 -5 8884.15 1136.99 2 9 2 -6 117.674 226.894 2 9 2 -7 4071.42 829.821 2 9 2 -8 21526.4 1869.51 2 9 2 -9 934.055 382.156 4 9 2 -9 907.029 461.788 2 9 2 -10-248.887 290.913 4 9 2 -10-151.601 367.925 2 9 2 -11 5371.00 918.247 4 9 2 -11 6161.97 1063.27 2 9 2 -12 1206.18 540.548 2 9 2 -12 1204.44 578.696 4 9 2 -13 444.581 346.386 2 9 2 -13 566.712 373.653 4 9 3 13 4966.35 991.903 3 9 3 12 1692.76 560.851 3 9 3 11-6.63490 242.299 6 9 3 11 54.1272 214.299 3 9 3 10 6566.27 865.321 6 9 3 10 6849.77 1046.08 3 9 3 10 6636.85 794.896 5 9 3 9 18042.4 1388.77 6 9 3 9 17814.7 1598.48 3 9 3 9 18409.8 1356.10 2 9 3 9 17689.4 1291.11 5 9 3 8 52.7449 222.627 7 9 3 8 72.8659 173.321 3 9 3 8 133.304 145.313 2 9 3 7 228.214 142.271 2 9 3 7 1079.78 354.301 7 9 3 7 651.155 323.815 3 9 3 6 3828.57 659.145 2 9 3 6 3602.38 642.713 7 9 3 6 4506.51 714.706 3 9 3 5 447.682 243.291 2 9 3 5 762.178 286.059 7 9 3 5 494.997 252.190 3 9 3 4 99.1180 160.705 2 9 3 4 17.4473 141.676 3 9 3 3 5533.50 839.236 2 9 3 3 6189.06 685.652 3 9 3 2 2818.69 609.616 2 9 3 2 2796.05 423.788 3 9 3 1 2889.43 630.806 2 9 3 1 2557.48 370.762 3 9 3 0 231.815 190.868 2 9 3 0 164.030 86.5239 3 9 3 -1 5072.55 841.961 2 9 3 -2 19580.3 1628.00 2 9 3 -3 3442.62 706.435 2 9 3 -4 4241.18 789.007 2 9 3 -5 16600.0 1574.11 2 9 3 -6 4516.57 844.342 2 9 3 -7 774.540 465.988 2 9 3 -8 4482.62 873.708 2 9 3 -9 7594.55 1150.99 2 9 3 -10 1136.69 478.688 2 9 3 -11-732.359 415.854 2 9 3 -12-857.100 446.335 2 9 4 13 339.562 312.524 3 9 4 12 6127.32 1043.35 3 9 4 11 640.791 274.428 5 9 4 11 361.393 271.809 3 9 4 10 185.085 150.587 5 9 4 10-88.5346 192.924 6 9 4 10 177.943 294.871 3 9 4 10-54.7196 151.494 2 9 4 9 2632.28 531.564 5 9 4 9 1881.34 470.991 7 9 4 9 2930.72 547.214 6 9 4 9 2150.87 535.369 3 9 4 9 2249.73 502.154 2 9 4 8 10377.3 1030.20 7 9 4 8 7562.79 976.799 3 9 4 8 8990.40 1000.61 2 9 4 7 301.479 220.869 2 9 4 7 186.472 179.184 7 9 4 7 570.073 283.822 3 9 4 6 269.651 228.476 2 9 4 6 89.9847 169.703 7 9 4 6 135.277 163.449 3 9 4 5 1144.82 381.980 2 9 4 5 1472.38 378.963 3 9 4 4 4968.63 791.803 2 9 4 4 5314.80 649.188 3 9 4 3 7568.40 721.917 3 9 4 3 8724.36 1062.82 2 9 4 2 5605.17 892.491 2 9 4 2 4762.06 518.072 3 9 4 1 10442.6 1183.51 2 9 4 0 6033.89 929.459 2 9 4 -1 418.859 286.026 2 9 4 -2 10042.0 1210.88 2 9 4 -3 23137.0 1836.91 2 9 4 -4 2487.75 651.216 2 9 4 -5 1919.10 537.545 2 9 4 -6-767.989 409.165 2 9 4 -7 12325.0 1435.93 2 9 4 -8 1115.71 472.368 2 9 4 -9-625.608 367.665 2 9 4 -10 2953.99 743.676 2 9 4 -11 66.3253 259.151 2 9 5 13 2402.39 651.451 3 9 5 12 910.198 330.395 5 9 5 12 1082.28 453.055 3 9 5 11-163.123 187.171 5 9 5 11 333.706 186.532 3 9 5 10 4072.65 701.587 5 9 5 10 3405.81 693.548 3 9 5 9 240.419 213.689 7 9 5 9-41.7062 114.464 6 9 5 9-17.1107 185.558 3 9 5 9 115.748 188.180 2 9 5 8 789.760 281.062 7 9 5 8 982.601 326.047 3 9 5 8 975.561 371.428 2 9 5 7 805.775 312.672 7 9 5 7 544.548 242.530 3 9 5 7 1052.22 397.505 2 9 5 6 1472.06 435.833 2 9 5 6 1599.12 410.277 7 9 5 6 1299.21 376.822 3 9 5 5 233.019 280.971 2 9 5 5-10.6731 116.607 3 9 5 4 5808.76 859.655 2 9 5 4 5023.98 614.977 3 9 5 3 3220.59 659.999 2 9 5 3 3275.25 518.311 1 9 5 2 7849.32 741.597 1 9 5 2 7920.52 1039.34 2 9 5 1 12.8640 203.680 2 9 5 1-57.6712 93.3265 1 9 5 0 1526.08 472.864 2 9 5 0 1752.67 296.298 1 9 5 -1 6271.19 964.512 2 9 5 -2 2254.55 618.331 2 9 5 -3 645.438 408.136 2 9 5 -4 10147.4 1288.82 2 9 5 -5 563.370 377.091 2 9 5 -6-9.26198 263.970 2 9 5 -7-6.37584 233.014 2 9 5 -8 1324.17 497.290 2 9 5 -9-137.171 272.531 2 9 5 -10 1939.59 609.229 2 9 6 14 919.740 467.931 3 9 6 13 667.674 319.275 5 9 6 13 368.008 313.849 3 9 6 12-176.643 196.026 5 9 6 12 68.9709 220.522 3 9 6 11 447.928 247.454 5 9 6 11 311.299 210.310 3 9 6 10 679.730 308.531 5 9 6 10 358.668 243.232 3 9 6 9 248.992 169.436 7 9 6 9-131.612 182.121 3 9 6 9 12.8570 201.984 2 9 6 8 59.7457 132.023 7 9 6 8-106.776 151.423 3 9 6 8-88.5864 201.780 2 9 6 7 97.6580 116.934 7 9 6 7 374.754 229.681 3 9 6 7 213.175 164.262 2 9 6 6 814.612 343.564 1 9 6 6 639.307 340.101 2 9 6 5 1145.33 446.842 2 9 6 5 1377.47 387.478 1 9 6 4 3067.42 705.204 2 9 6 4 3488.22 583.586 1 9 6 3 3305.12 723.791 2 9 6 3 3393.52 545.160 1 9 6 2 1920.12 556.655 2 9 6 2 2265.18 421.260 1 9 6 1 4054.54 779.627 2 9 6 1 5500.98 620.952 1 9 6 0-67.1655 273.270 2 9 6 0 168.080 136.417 1 9 6 -1 2048.56 581.766 2 9 6 -2 1782.80 562.144 2 9 6 -3 5260.96 943.284 2 9 6 -4 70.1569 309.644 2 9 6 -5 1925.87 597.977 2 9 6 -6-86.9313 232.113 2 9 6 -7 1768.60 583.523 2 9 6 -8 1141.93 491.739 2 9 6 -9-459.981 335.755 2 9 7 14 201.943 225.515 5 9 7 14-474.628 350.797 3 9 7 13 284.212 242.857 5 9 7 13-192.413 251.047 3 9 7 12 1132.15 408.485 5 9 7 12 769.794 382.487 3 9 7 11 241.588 289.236 5 9 7 10 644.123 326.488 5 9 7 9 362.704 287.066 1 9 7 9 263.449 315.269 2 9 7 8 282.229 213.573 7 9 7 8 472.057 327.373 1 9 7 8 6.04309 197.898 2 9 7 7 1133.57 362.822 1 9 7 7 1716.68 522.988 2 9 7 6 622.677 214.923 1 9 7 6 606.995 289.032 2 9 7 5 591.062 294.595 1 9 7 5 606.040 309.846 2 9 7 4 9948.03 1016.49 1 9 7 4 10912.6 1264.31 2 9 7 3 4268.03 799.241 2 9 7 3 3959.22 607.436 1 9 7 2 516.305 320.247 2 9 7 2 312.066 243.579 1 9 7 1 1134.95 450.570 2 9 7 1 1099.38 310.304 1 9 7 0 5171.16 918.752 2 9 7 0 5300.45 636.136 1 9 7 -1 2225.10 598.647 2 9 7 -2 304.254 243.584 2 9 7 -3 7992.76 1179.51 2 9 7 -4 1323.83 488.327 2 9 7 -5 1534.21 507.543 2 9 7 -6 750.464 373.380 2 9 7 -7 468.442 346.278 2 9 7 -8 1727.26 586.484 2 9 8 15 1127.67 416.730 5 9 8 14-255.317 238.792 5 9 8 13 262.605 251.742 5 9 8 12 184.749 219.081 5 9 8 11 1160.44 461.209 5 9 8 11 40.4521 304.226 1 9 8 10 2269.61 600.945 5 9 8 10 2936.60 741.150 1 9 8 9 3416.05 708.990 5 9 8 9 2541.99 660.751 1 9 8 8 282.047 299.760 1 9 8 8 15.8217 147.490 2 9 8 7 6414.36 947.148 1 9 8 7 6140.49 977.037 2 9 8 6 10706.5 1174.34 1 9 8 6 9669.46 1221.21 2 9 8 5 1565.24 458.350 1 9 8 5 1667.92 489.679 2 9 8 4 588.492 311.332 1 9 8 4-46.6142 245.126 2 9 8 3 13081.9 1175.80 1 9 8 3 12796.2 1422.16 2 9 8 2 16987.8 1305.30 1 9 8 2 16415.9 1621.78 2 9 8 1 285.879 241.383 2 9 8 1 303.650 226.819 1 9 8 0 1639.49 572.368 2 9 8 0 1534.02 386.484 1 9 8 -1 14721.7 1589.70 2 9 8 -2 2550.84 697.499 2 9 8 -3 1392.22 520.457 2 9 8 -4 5028.40 976.374 2 9 8 -5-85.6161 250.431 2 9 8 -6 3620.54 836.452 2 9 8 -7-337.908 301.814 2 9 9 15-842.119 415.175 5 9 9 14-97.1875 278.654 5 9 9 13 838.252 383.736 5 9 9 12 1581.02 501.999 5 9 9 12 1865.79 653.123 1 9 9 11-221.297 199.890 5 9 9 11 63.3412 216.042 1 9 9 10 258.644 216.195 5 9 9 10 584.755 383.963 1 9 9 9 1407.97 471.954 5 9 9 9 1265.63 468.206 1 9 9 8 1935.36 572.908 1 9 9 8 2474.44 653.796 2 9 9 7 914.450 406.429 1 9 9 7 1350.06 482.920 2 9 9 6 1879.76 599.671 2 9 9 6 2092.89 545.910 1 9 9 5 3380.49 674.197 1 9 9 5 3696.33 816.595 2 9 9 4 5820.43 853.062 1 9 9 4 6083.38 1010.21 2 9 9 3 330.906 240.792 1 9 9 3 290.784 220.756 2 9 9 2 2709.15 573.909 1 9 9 2 2942.02 720.682 2 9 9 1 1869.67 484.493 1 9 9 1 2584.95 683.171 2 9 9 0 4533.45 881.123 2 9 9 -1 400.560 321.165 2 9 9 -2 2217.19 666.035 2 9 9 -3 2292.54 708.500 2 9 9 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769.538 2 10 -4 -7 15.6713 182.072 2 10 -4 -8 6440.65 1101.01 2 10 -4 -9 2364.81 686.731 2 10 -4 -10 757.893 424.904 2 10 -4 -11 1516.47 619.962 2 10 -3 7-44.7229 188.976 6 10 -3 6 236.092 347.644 6 10 -3 5 3549.84 824.519 6 10 -3 4 3790.64 814.685 7 10 -3 4 3732.12 835.351 6 10 -3 3-104.621 227.721 7 10 -3 2 3202.13 751.614 7 10 -3 2 2900.18 601.618 2 10 -3 1 4596.65 879.460 7 10 -3 1 3038.67 645.636 2 10 -3 0 2591.75 662.014 7 10 -3 0 3602.04 713.886 2 10 -3 -1-754.497 402.761 7 10 -3 -1-447.405 286.418 2 10 -3 -2 3871.95 852.937 7 10 -3 -2 4235.66 793.087 2 10 -3 -3 11998.0 1351.27 2 10 -3 -4 6263.41 1005.01 2 10 -3 -5 16.2242 180.106 2 10 -3 -6 6352.69 1049.45 2 10 -3 -7 4072.07 857.872 2 10 -3 -8 2932.13 731.566 2 10 -3 -9-33.9032 333.980 2 10 -3 -10 680.342 454.242 2 10 -3 -11 9974.50 1439.07 2 10 -2 8-49.5147 196.822 6 10 -2 7 1643.25 503.352 6 10 -2 6 856.118 419.914 6 10 -2 5-231.658 259.902 7 10 -2 5 261.171 326.648 6 10 -2 4 1561.67 505.094 7 10 -2 3 7305.24 1078.23 7 10 -2 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2 8 6487.77 935.310 7 10 2 8 5109.10 820.267 6 10 2 8 5079.78 746.491 2 10 2 7 1216.24 392.506 2 10 2 7 734.398 334.994 7 10 2 6 5653.50 823.210 2 10 2 6 6266.16 912.268 7 10 2 5 5495.99 844.699 2 10 2 5 6112.42 907.209 7 10 2 4 10448.0 1211.80 7 10 2 4 8960.04 1079.91 2 10 2 3 310.175 253.020 2 10 2 2 2257.68 553.909 2 10 2 1 3129.20 673.173 2 10 2 0 6364.17 976.842 2 10 2 0 9063.15 711.386 3 10 2 -1 2828.81 664.393 2 10 2 -2 1513.77 498.031 2 10 2 -3 8544.79 1159.19 2 10 2 -4-680.961 386.218 2 10 2 -5-564.599 344.959 2 10 2 -6 1413.32 458.932 2 10 2 -7 4185.70 849.717 2 10 2 -8 152.697 331.775 2 10 2 -9 2709.25 737.849 2 10 2 -10 6329.04 1133.28 2 10 2 -11 1587.25 621.986 2 10 2 -12 364.626 343.924 2 10 3 12 601.521 356.304 3 10 3 11 786.109 418.810 3 10 3 10 1003.06 350.959 6 10 3 10 511.423 379.882 3 10 3 9-347.861 212.379 5 10 3 9 267.757 217.800 6 10 3 9 106.809 183.702 3 10 3 9-467.577 250.882 2 10 3 8 3899.29 721.325 7 10 3 8 4518.29 809.668 3 10 3 8 4935.27 766.932 2 10 3 7 12186.6 1226.78 7 10 3 7 11130.1 1201.54 3 10 3 7 11673.9 1197.85 2 10 3 6 36.7560 144.480 2 10 3 6 551.039 293.124 7 10 3 6 830.654 334.492 3 10 3 5 758.495 308.651 7 10 3 5 813.528 305.443 3 10 3 4 41238.3 1968.24 3 10 3 4 43338.2 2412.84 2 10 3 3 13018.3 1032.51 3 10 3 3 12803.9 1330.44 2 10 3 2 722.079 375.224 2 10 3 2 115.395 115.769 3 10 3 1 724.571 405.724 2 10 3 1 253.379 136.149 3 10 3 0 1601.30 549.023 2 10 3 -1 4194.96 829.833 2 10 3 -2-455.646 316.101 2 10 3 -3 3652.75 773.620 2 10 3 -4 10704.6 1332.82 2 10 3 -5 2648.46 684.656 2 10 3 -6-19.1071 210.313 2 10 3 -7 9035.06 1273.21 2 10 3 -8 10163.6 1396.37 2 10 3 -9 277.292 274.903 2 10 3 -10-117.980 281.576 2 10 3 -11 1699.70 616.871 2 10 3 -12 780.306 459.224 2 10 4 12 391.714 308.800 3 10 4 11-596.129 353.221 3 10 4 10 5138.89 749.766 5 10 4 10 5045.05 895.639 3 10 4 9 6976.56 908.204 7 10 4 9 8079.14 943.740 6 10 4 9 5925.90 934.664 3 10 4 9 6907.22 922.264 2 10 4 8 152.758 183.652 7 10 4 8 383.546 216.075 3 10 4 8 199.459 208.894 2 10 4 7 3997.68 740.368 2 10 4 7 4604.20 739.109 7 10 4 7 3496.06 656.239 3 10 4 6 1315.04 449.230 2 10 4 6 1013.62 370.572 7 10 4 6 616.727 283.498 3 10 4 5 1865.61 507.881 2 10 4 5 2022.04 458.283 3 10 4 4 774.403 375.929 2 10 4 4 696.755 289.622 3 10 4 3 846.225 392.272 2 10 4 3 119.350 105.033 3 10 4 2 2604.83 634.756 2 10 4 2 2755.43 409.705 3 10 4 1 369.448 289.961 2 10 4 0 576.776 385.958 2 10 4 -1 1975.24 565.718 2 10 4 -2 8705.87 1193.40 2 10 4 -3 683.298 386.876 2 10 4 -4 977.084 461.033 2 10 4 -5 3181.87 778.522 2 10 4 -6 495.957 294.876 2 10 4 -7 30.8153 223.709 2 10 4 -8 2042.60 642.255 2 10 4 -9 3700.81 893.407 2 10 4 -10 27.9879 191.952 2 10 4 -11-89.6130 191.025 2 10 5 13 288.380 281.633 3 10 5 12 193.624 250.529 3 10 5 11 322.540 230.556 5 10 5 11-416.756 298.623 3 10 5 10 427.929 240.998 5 10 5 10 102.823 160.431 2 10 5 9 1656.60 446.152 7 10 5 9 1354.46 462.068 3 10 5 9 1657.30 478.135 2 10 5 8 72.0769 162.906 3 10 5 8 780.245 354.314 2 10 5 7 2685.48 565.656 7 10 5 7 2413.90 538.278 3 10 5 7 2807.31 624.181 2 10 5 6 3652.07 728.240 2 10 5 6 4496.16 740.020 7 10 5 6 4132.45 690.001 3 10 5 5 2985.99 668.416 2 10 5 5 1750.37 413.567 3 10 5 4 14083.7 1073.45 3 10 5 4 15300.6 1498.82 2 10 5 3 1917.51 564.713 2 10 5 2 341.686 276.033 2 10 5 1 39.1806 183.504 2 10 5 0 2022.90 575.804 2 10 5 -1 339.238 228.872 2 10 5 -2 3834.52 810.998 2 10 5 -3 2641.87 716.775 2 10 5 -4 3381.82 788.691 2 10 5 -5 35.4589 244.329 2 10 5 -6 168.045 281.278 2 10 5 -7 7498.78 1209.30 2 10 5 -8 159.621 275.478 2 10 5 -9 80.6155 297.360 2 10 5 -10 147.945 236.202 2 10 6 13 44.3900 192.010 3 10 6 12 266.944 224.408 5 10 6 12-22.7657 174.925 3 10 6 11 956.027 387.717 5 10 6 11 1073.99 462.390 3 10 6 10 5130.10 824.654 5 10 6 10 3695.89 743.331 3 10 6 10 4570.23 811.537 2 10 6 9 562.438 296.440 3 10 6 9 919.968 388.260 2 10 6 8 85.4009 171.328 7 10 6 8-388.917 251.407 3 10 6 8-433.489 288.668 2 10 6 7 275.911 213.071 7 10 6 7-112.092 193.280 3 10 6 7 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679.758 2 10 7 -2 14546.9 1647.98 2 10 7 -3 893.079 475.602 2 10 7 -4 438.827 344.120 2 10 7 -5-1075.34 509.552 2 10 7 -6 8899.57 1332.72 2 10 7 -7-51.3024 215.223 2 10 7 -8 146.994 241.378 2 10 8 14 445.198 301.572 5 10 8 13-53.1912 112.569 5 10 8 12 369.713 277.730 5 10 8 11 2044.99 599.648 5 10 8 10 612.288 339.126 5 10 8 9 1086.71 483.062 1 10 8 9 645.065 317.832 2 10 8 8 508.773 336.951 1 10 8 8 681.083 375.666 2 10 8 7 1403.68 457.300 1 10 8 7 586.920 340.336 2 10 8 6 413.301 292.312 1 10 8 6 272.940 281.817 2 10 8 5 3340.06 669.391 1 10 8 5 3771.15 792.308 2 10 8 4 1541.21 443.890 1 10 8 4 2325.87 649.896 2 10 8 3 5304.48 960.984 2 10 8 3 5654.32 778.176 1 10 8 2-6.40436 242.748 2 10 8 1 1716.37 564.869 2 10 8 0 5148.89 981.889 2 10 8 -1 2452.07 705.980 2 10 8 -2 145.582 248.972 2 10 8 -3 8249.85 1276.83 2 10 8 -4 1884.34 629.312 2 10 8 -5-249.277 287.247 2 10 8 -6 656.562 397.292 2 10 8 -7 3442.68 838.398 2 10 9 13 116.618 230.500 5 10 9 12-466.359 320.879 5 10 9 11 1292.98 484.433 5 10 9 11 1851.79 644.519 1 10 9 10 508.717 306.585 5 10 9 10-289.230 284.790 1 10 9 9 1006.09 452.933 1 10 9 8 154.116 226.304 1 10 9 8-171.281 314.721 2 10 9 7 3302.50 772.043 1 10 9 7 2945.15 735.633 2 10 9 6 916.529 371.616 1 10 9 6 669.236 384.817 2 10 9 5 2691.62 598.037 1 10 9 5 1428.16 526.954 2 10 9 4 1945.74 497.683 1 10 9 4 1894.82 635.289 2 10 9 3 2303.04 672.349 2 10 9 2 2523.69 684.027 2 10 9 1 557.070 368.045 2 10 9 0 3979.20 894.063 2 10 9 -1 1159.97 523.043 2 10 9 -2 4120.96 923.208 2 10 9 -3 695.013 419.408 2 10 9 -4 624.732 401.443 2 10 9 -5 1369.96 546.923 2 10 9 -6 2076.12 659.664 2 10 10 12 2688.35 768.899 1 10 10 11 754.165 419.139 5 10 10 11 836.048 476.985 1 10 10 10 648.365 341.942 5 10 10 10 1948.75 661.755 1 10 10 9 761.825 437.050 1 10 10 9 611.664 332.606 5 10 10 8 1271.68 505.452 1 10 10 7-67.1437 236.754 1 10 10 7 302.132 297.546 2 10 10 6 332.961 218.103 1 10 10 6-308.386 303.653 2 10 10 5 2884.70 669.806 1 10 10 5 2002.15 656.708 2 10 10 4 613.867 312.805 1 10 10 4 665.927 383.978 2 10 10 3-422.176 339.801 2 10 10 2 81.6112 200.608 2 10 10 1 1263.16 536.314 2 10 10 0 797.989 403.855 2 10 10 -1-342.842 324.916 2 10 10 -2 1727.90 598.529 2 10 10 -3 676.533 419.481 2 10 10 -4 1447.16 562.841 2 10 11 11 727.773 458.788 1 10 11 10 1394.59 573.521 1 10 11 9-539.649 351.330 5 10 11 9 925.303 473.028 1 10 11 8 993.097 448.490 1 10 11 7 850.747 442.801 1 10 11 6 146.266 251.888 2 10 11 6-321.152 293.812 1 10 11 5-362.182 285.488 1 10 11 5-97.0962 187.406 2 10 11 4-344.204 349.176 2 10 11 3 809.995 425.021 2 10 11 2-54.9935 200.348 2 10 11 1 184.139 252.674 2 10 11 0 24.1900 304.027 2 10 11 -1 115.378 203.598 2 10 12 10 135.321 258.298 1 10 12 9-868.762 465.805 1 10 12 8 483.842 273.940 1 10 12 7-355.382 237.100 1 10 12 6-466.921 323.875 1 10 13 8 2711.12 780.275 1 10 13 7 992.357 488.318 1 11 -7 -4-1008.40 445.721 2 11 -6 -2 2186.89 603.449 2 11 -6 -3 1207.55 509.399 2 11 -6 -4 1533.11 555.253 2 11 -6 -5 1121.70 447.615 2 11 -6 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495.008 7 11 -3 -1 1752.29 537.726 2 11 -3 -2 2670.76 771.322 7 11 -3 -2 2278.85 625.664 2 11 -3 -3 669.420 364.613 2 11 -3 -4 3583.70 832.509 2 11 -3 -5 2503.69 707.282 2 11 -3 -6 2230.98 666.579 2 11 -3 -7-96.4169 207.931 2 11 -3 -8 1914.52 635.016 2 11 -3 -9 2091.77 678.096 2 11 -2 6 396.586 355.921 6 11 -2 5 2820.12 704.921 7 11 -2 5 2678.05 743.724 6 11 -2 4 1566.11 526.398 7 11 -2 3 46.0815 119.228 2 11 -2 3-94.7867 305.432 7 11 -2 2 2276.34 645.045 7 11 -2 2 2023.02 548.726 2 11 -2 1 3170.58 778.090 7 11 -2 1 2954.90 705.394 2 11 -2 0 2296.75 660.380 7 11 -2 0 3118.71 708.573 2 11 -2 -1-938.417 480.987 7 11 -2 -1-76.3417 189.460 2 11 -2 -2 3959.75 818.117 2 11 -2 -3 6870.39 1077.33 2 11 -2 -4 2958.42 720.311 2 11 -2 -5-53.6295 195.555 2 11 -2 -6 2734.06 703.599 2 11 -2 -7 5654.28 1061.71 2 11 -2 -8 653.837 378.314 2 11 -2 -9 979.328 473.858 2 11 -2 -10 5997.22 1120.97 2 11 -1 8-449.793 340.813 6 11 -1 7 189.070 228.023 6 11 -1 6 900.716 451.134 7 11 -1 6 1795.68 613.144 6 11 -1 5 341.408 301.481 7 11 -1 4 2001.77 534.197 2 11 -1 4 1977.22 610.423 7 11 -1 3 3995.41 766.721 2 11 -1 3 4101.68 830.978 7 11 -1 2 1112.74 471.200 7 11 -1 2 1027.78 414.968 2 11 -1 1-701.639 412.417 7 11 -1 1 195.502 261.711 2 11 -1 0 3659.50 779.221 2 11 -1 -1 1056.04 417.317 2 11 -1 -2 666.825 352.624 2 11 -1 -3 3372.75 753.899 2 11 -1 -4 2926.93 743.112 2 11 -1 -5 1197.82 469.502 2 11 -1 -6 147.832 209.278 2 11 -1 -7 1862.13 605.584 2 11 -1 -8 238.110 388.516 2 11 -1 -9 1148.81 500.745 2 11 -1 -10-14.2010 202.822 2 11 0 10 394.625 301.631 6 11 0 9-201.619 239.330 6 11 0 8 119.869 211.633 6 11 0 7 228.329 278.734 7 11 0 7 98.6814 245.499 6 11 0 6 2663.56 677.564 7 11 0 5 848.907 360.439 2 11 0 5 1014.73 416.591 7 11 0 4-237.984 256.398 2 11 0 4 501.991 321.606 7 11 0 3 4231.50 793.801 2 11 0 3 4601.36 902.666 7 11 0 2 2971.35 710.904 7 11 0 2 2652.53 665.364 2 11 0 1 1868.07 550.674 2 11 0 0 1272.61 483.789 2 11 0 -1 5343.07 938.273 2 11 0 -2 14947.0 1587.29 2 11 0 -3 3224.20 777.997 2 11 0 -4-142.905 233.483 2 11 0 -5 4236.16 862.723 2 11 0 -6 1975.50 639.398 2 11 0 -7 2000.86 617.527 2 11 0 -8-242.732 305.253 2 11 0 -9 198.273 360.991 2 11 0 -10 6218.48 1146.46 2 11 1 10-466.640 294.529 6 11 1 9 87.3197 232.288 6 11 1 8 1800.28 549.568 6 11 1 7 99.9479 221.671 7 11 1 6-619.487 311.124 2 11 1 6-6.48591 232.065 7 11 1 5 1547.27 496.180 2 11 1 5 1856.64 564.207 7 11 1 4 6311.60 952.645 2 11 1 4 7393.47 1094.93 7 11 1 3 9504.41 1248.80 7 11 1 3 8294.52 1117.82 2 11 1 2 1480.74 464.083 2 11 1 1 6107.03 992.104 2 11 1 0 4219.01 805.281 2 11 1 -1 3157.15 699.736 2 11 1 -2 5652.45 965.282 2 11 1 -3 15537.8 1622.75 2 11 1 -4 2734.31 722.687 2 11 1 -5 107.820 228.393 2 11 1 -6 2920.00 757.924 2 11 1 -7 486.272 349.084 2 11 1 -8 577.805 417.092 2 11 1 -9-129.605 310.187 2 11 1 -10 1774.87 628.244 2 11 2 10 791.200 374.997 6 11 2 10 1344.93 499.673 3 11 2 9-351.318 253.069 6 11 2 8-78.5462 191.689 7 11 2 8 412.699 271.359 6 11 2 7 1149.70 395.156 2 11 2 7 1649.57 496.752 7 11 2 6 1991.15 544.239 2 11 2 6 1493.25 490.333 7 11 2 5-268.862 246.616 2 11 2 5 224.492 255.557 7 11 2 4 3338.16 710.468 2 11 2 4 3287.68 722.379 7 11 2 3 14160.6 1458.62 2 11 2 2 3101.59 696.770 2 11 2 1 888.896 418.772 2 11 2 0 13762.7 1479.47 2 11 2 -1 12650.4 1440.82 2 11 2 -2 2057.39 582.525 2 11 2 -3-322.424 394.604 2 11 2 -4 4060.23 854.232 2 11 2 -5 2042.36 654.305 2 11 2 -6 900.631 473.674 2 11 2 -7-113.524 341.472 2 11 2 -8 3438.05 865.083 2 11 2 -9 964.111 490.841 2 11 2 -10 1266.88 618.710 2 11 3 11 200.821 229.316 3 11 3 10 693.916 369.211 3 11 3 9 3001.94 664.691 6 11 3 9 2452.00 628.299 3 11 3 8 1031.18 422.619 7 11 3 8 877.222 459.281 3 11 3 8 809.957 333.415 2 11 3 7 321.786 239.618 2 11 3 7 27.6576 135.562 7 11 3 6 1117.92 423.360 7 11 3 6 371.555 260.842 3 11 3 5 3226.77 692.318 2 11 3 5 3122.55 665.231 7 11 3 5 3236.24 615.239 3 11 3 4 5277.16 915.851 2 11 3 4 3920.17 638.562 3 11 3 3-141.726 335.294 2 11 3 3-255.985 176.648 3 11 3 2 4402.70 845.309 2 11 3 1 3277.61 735.155 2 11 3 0 1973.80 602.185 2 11 3 -1 484.139 445.880 2 11 3 -2 20417.6 1883.23 2 11 3 -3-713.236 406.661 2 11 3 -4 1295.64 539.135 2 11 3 -5 62.0279 251.321 2 11 3 -6 189.423 286.643 2 11 3 -7 1360.84 512.927 2 11 3 -8-258.060 284.287 2 11 3 -9 1172.87 539.007 2 11 3 -10 2923.58 825.495 2 11 4 11 933.757 413.636 3 11 4 10 1476.59 517.792 3 11 4 9 587.739 289.024 7 11 4 9 892.418 376.861 3 11 4 9 133.501 166.446 2 11 4 8 1470.44 462.058 7 11 4 8 1762.02 512.429 3 11 4 8 1851.84 513.769 2 11 4 7 65.6428 149.954 2 11 4 7 443.836 266.048 7 11 4 7 339.527 247.597 3 11 4 6 1442.73 477.420 2 11 4 6 898.278 401.200 7 11 4 6 1912.32 509.246 3 11 4 5 2268.48 588.600 2 11 4 5 1357.22 431.834 7 11 4 5 1440.53 394.628 3 11 4 4 18021.4 1297.97 3 11 4 4 19971.7 1765.55 2 11 4 3 976.516 443.890 2 11 4 2 1300.35 499.290 2 11 4 1 5360.68 964.076 2 11 4 0 159.029 216.058 2 11 4 -1 1395.87 575.574 2 11 4 -2 216.391 248.382 2 11 4 -3 12.3304 319.892 2 11 4 -4 1331.39 496.062 2 11 4 -5 729.048 385.174 2 11 4 -6-706.356 425.041 2 11 4 -7 1704.32 603.813 2 11 4 -8 1996.60 688.156 2 11 4 -9 236.001 182.710 2 11 5 12-44.3539 173.240 3 11 5 11 462.303 314.670 3 11 5 10 2080.78 552.734 5 11 5 10 1091.79 440.487 3 11 5 10 2645.48 610.461 2 11 5 9 1084.36 404.131 7 11 5 9 924.787 389.320 3 11 5 9 1146.85 414.068 2 11 5 8 232.398 208.896 7 11 5 8 315.353 206.977 3 11 5 8 37.2740 152.430 2 11 5 7 2115.89 562.714 2 11 5 7 1378.99 467.146 7 11 5 7 846.244 339.183 3 11 5 6 200.398 272.898 2 11 5 6-292.224 249.798 7 11 5 6-141.053 167.553 3 11 5 5 1049.67 423.625 2 11 5 5 662.553 274.277 3 11 5 4 326.504 335.571 2 11 5 3 131.711 325.005 2 11 5 2 495.364 297.725 2 11 5 1 2413.53 645.357 2 11 5 0-8.68717 215.077 2 11 5 -1 203.867 251.757 2 11 5 -2 825.521 461.254 2 11 5 -3-92.9719 247.968 2 11 5 -4 113.349 259.866 2 11 5 -5-39.3066 231.043 2 11 5 -6 1292.85 551.915 2 11 5 -7 19.5566 299.517 2 11 5 -8 660.602 433.145 2 11 5 -9 963.577 505.279 2 11 6 12 1285.34 533.971 3 11 6 11 779.546 363.229 5 11 6 11 605.269 377.835 3 11 6 10 140.841 172.307 5 11 6 10-290.715 265.356 3 11 6 10 0.93954 126.258 2 11 6 9 683.182 342.722 3 11 6 9 501.505 310.921 2 11 6 8 6372.43 859.593 7 11 6 8 4353.09 761.668 3 11 6 8 3792.74 779.120 2 11 6 7-155.915 208.805 7 11 6 7 36.4355 173.235 3 11 6 7-46.0725 140.113 2 11 6 6 514.639 308.807 2 11 6 5 14899.9 1567.49 2 11 6 4 2424.73 664.738 2 11 6 3 514.769 346.152 2 11 6 2-100.539 238.224 2 11 6 1 143.371 242.169 2 11 6 0 1688.91 594.031 2 11 6 -1-255.685 445.797 2 11 6 -2 1194.95 433.049 2 11 6 -3 4304.58 920.923 2 11 6 -4 2163.07 698.721 2 11 6 -5-438.265 463.403 2 11 6 -6 5186.59 1069.64 2 11 6 -7 3711.70 892.495 2 11 6 -8-225.638 393.439 2 11 7 12 548.725 313.118 5 11 7 12-308.405 275.007 3 11 7 11 3301.35 709.003 5 11 7 10 2871.20 672.311 5 11 7 10 2946.23 725.270 2 11 7 9 336.898 272.441 2 11 7 8 1833.96 564.287 2 11 7 7 706.863 401.704 2 11 7 6 1585.60 563.680 2 11 7 5 855.526 488.949 2 11 7 4 86.3091 251.295 2 11 7 3 1870.19 619.926 2 11 7 2 320.234 210.330 2 11 7 1 325.310 299.919 2 11 7 0 1330.95 561.718 2 11 7 -1 4155.78 938.885 2 11 7 -2 72.1415 350.594 2 11 7 -3 561.000 388.792 2 11 7 -4 2815.27 817.081 2 11 7 -5 1274.13 570.593 2 11 7 -6 114.492 237.833 2 11 7 -7 1152.98 561.384 2 11 8 13 654.494 345.219 5 11 8 12 36.1235 139.161 5 11 8 11 671.151 344.667 5 11 8 10 2518.17 647.905 5 11 8 9 1539.86 519.024 2 11 8 8 1751.43 572.773 2 11 8 7 1873.93 615.162 2 11 8 6 467.361 308.405 2 11 8 5 7898.82 1197.31 2 11 8 4-48.4148 203.369 2 11 8 3 239.128 272.404 2 11 8 2 1186.61 534.182 2 11 8 1 902.402 441.084 2 11 8 0-13.3357 189.743 2 11 8 -1 2574.61 749.552 2 11 8 -2 1769.55 627.941 2 11 8 -3 1431.38 583.312 2 11 8 -4 92.6172 252.938 2 11 8 -5 1034.21 550.440 2 11 9 11 2839.74 717.673 5 11 9 10-238.734 226.992 5 11 9 9-97.6526 197.863 2 11 9 9 294.918 278.729 1 11 9 8 1491.33 542.670 1 11 9 8 1268.53 500.679 2 11 9 7 1358.39 535.081 2 11 9 6 122.420 293.298 2 11 9 5 1232.92 483.136 2 11 9 4 2473.33 690.846 2 11 9 3 1477.89 539.260 2 11 9 2 97.4711 221.350 2 11 9 1 2065.12 635.305 2 11 9 0 1589.74 606.698 2 11 9 -1 440.226 352.400 2 11 9 -2 646.139 422.214 2 11 9 -3 1008.45 540.990 2 11 10 11 903.054 413.862 1 11 10 10 2133.50 676.333 1 11 10 9-172.639 276.756 1 11 10 8 330.685 310.308 1 11 10 8-574.448 393.221 2 11 10 7 2480.03 704.661 2 11 10 6 1678.52 611.846 2 11 10 5 611.427 390.678 2 11 10 4 2203.52 697.844 2 11 10 3 878.360 454.972 2 11 10 2 1183.94 528.735 2 11 10 1-102.764 264.017 2 11 10 0 339.320 413.166 2 11 11 11 1073.39 520.213 1 11 11 10 358.359 353.246 1 11 11 9 416.892 340.639 1 12 -5 -2-519.280 314.381 2 12 -5 -3 292.988 273.098 2 12 -5 -4 1404.00 544.649 2 12 -4 -1 711.499 383.555 2 12 -4 -2 3126.07 779.546 2 12 -4 -3 235.595 229.103 2 12 -4 -4 29.7073 246.864 2 12 -4 -5 1346.47 523.090 2 12 -3 0 2453.72 714.683 7 12 -3 0 2452.94 662.483 2 12 -3 -1 1694.20 634.921 7 12 -3 -1 788.043 402.900 2 12 -3 -2 529.666 333.868 7 12 -3 -2 247.727 265.919 2 12 -3 -3 4047.60 986.626 7 12 -3 -3 5531.22 1032.89 2 12 -3 -4 2615.87 719.856 2 12 -3 -5 191.253 247.579 2 12 -3 -6-444.889 341.560 2 12 -2 3 762.338 425.006 7 12 -2 2 213.429 247.619 7 12 -2 2-472.460 310.488 2 12 -2 1 806.714 446.545 7 12 -2 1 767.966 379.190 2 12 -2 0-798.384 434.333 7 12 -2 0 332.455 262.007 2 12 -2 -1-264.532 309.010 7 12 -2 -1-195.018 255.965 2 12 -2 -2 497.590 286.549 2 12 -2 -3 283.492 289.746 2 12 -2 -4 1183.68 504.116 2 12 -2 -5 4156.97 912.192 2 12 -2 -6 2103.80 669.800 2 12 -2 -7-604.546 405.006 2 12 -1 6 1049.24 527.992 6 12 -1 5 703.585 416.885 7 12 -1 4-22.4337 294.731 7 12 -1 3 593.885 331.767 2 12 -1 3 357.511 323.862 7 12 -1 2 579.073 433.917 7 12 -1 2 1589.55 513.216 2 12 -1 1 430.409 331.278 7 12 -1 1 871.186 382.607 2 12 -1 0 1061.99 456.651 7 12 -1 0 747.921 327.434 2 12 -1 -1 824.710 391.295 2 12 -1 -2 2248.68 670.627 2 12 -1 -3 6265.69 1077.75 2 12 -1 -4 390.347 263.172 2 12 -1 -5 282.076 306.171 2 12 -1 -6 3559.46 865.450 2 12 -1 -7 4240.79 936.230 2 12 0 8 1744.88 581.259 6 12 0 7 1343.52 518.587 7 12 0 7 2360.26 662.022 6 12 0 6 1386.68 511.754 7 12 0 5 1392.49 489.503 7 12 0 4 84.9398 180.825 2 12 0 4-264.999 273.435 7 12 0 3 1326.81 467.834 2 12 0 3 1903.95 627.298 7 12 0 2-942.385 422.846 2 12 0 2-173.906 249.878 7 12 0 1 323.994 250.634 7 12 0 1 116.321 200.438 2 12 0 0 1590.55 553.286 2 12 0 -1 3334.42 786.051 2 12 0 -2 310.602 294.956 2 12 0 -3 1772.24 609.365 2 12 0 -4 4736.06 958.906 2 12 0 -5 1809.18 615.524 2 12 0 -6 610.299 349.710 2 12 0 -7 3947.98 923.542 2 12 1 9-295.714 268.085 6 12 1 8 967.014 417.660 6 12 1 7-95.2855 204.070 7 12 1 6 455.821 323.602 7 12 1 5 994.190 409.851 2 12 1 5 701.535 429.632 7 12 1 4-318.467 268.469 2 12 1 4 206.953 278.482 7 12 1 3 755.440 424.934 2 12 1 3 139.697 237.763 7 12 1 2 1645.32 564.587 7 12 1 2 1276.23 488.544 2 12 1 1-21.4484 176.971 2 12 1 0-836.741 417.597 2 12 1 -1 1864.50 570.240 2 12 1 -2 9842.84 1350.48 2 12 1 -3 1647.31 558.830 2 12 1 -4 576.798 364.584 2 12 1 -5 8049.84 1283.49 2 12 1 -6 5101.84 1020.42 2 12 1 -7 159.636 338.804 2 12 1 -8-510.541 422.022 2 12 2 9-148.860 227.855 6 12 2 9-20.5132 167.596 3 12 2 8 555.670 336.113 7 12 2 8 1323.36 458.113 6 12 2 8 1367.19 508.555 3 12 2 7-331.596 280.398 7 12 2 6-58.5092 145.665 2 12 2 6 454.634 401.578 7 12 2 5 1693.20 555.670 2 12 2 5 1525.03 532.868 7 12 2 4 5700.21 975.883 2 12 2 4 5827.65 1017.71 7 12 2 3 135.876 210.936 2 12 2 3 371.724 257.846 7 12 2 2-555.461 333.075 2 12 2 1 3406.08 779.727 2 12 2 0 2725.86 705.945 2 12 2 -1 282.394 298.566 2 12 2 -2 1287.79 495.427 2 12 2 -3 5200.13 1015.07 2 12 2 -4 2276.15 676.147 2 12 2 -5 24.9247 296.762 2 12 2 -6 4647.16 970.711 2 12 2 -7 1207.96 549.436 2 12 3 10 2100.42 633.216 3 12 3 9 472.262 347.588 3 12 3 8 465.608 289.320 7 12 3 8 195.134 211.894 3 12 3 7 2428.34 597.985 2 12 3 7 3977.24 787.486 7 12 3 7 2601.75 637.205 3 12 3 6 478.435 291.872 2 12 3 6 322.298 270.091 7 12 3 6 812.013 333.682 3 12 3 5-862.801 388.271 2 12 3 5-138.484 216.558 7 12 3 4 2167.63 615.302 2 12 3 4 2010.55 607.815 7 12 3 3 787.250 401.787 2 12 3 2 88.5688 223.784 2 12 3 1-161.470 241.435 2 12 3 0 2064.19 643.102 2 12 3 -1 11192.4 1461.52 2 12 3 -2 364.626 241.414 2 12 3 -3-64.2591 289.175 2 12 3 -4 1012.28 545.006 2 12 3 -5 389.665 378.126 2 12 3 -6 1084.68 442.501 2 12 3 -7 324.498 357.703 2 12 4 10 373.025 283.332 3 12 4 9 2206.12 541.826 7 12 4 9 2663.89 681.440 3 12 4 8 120.394 183.424 7 12 4 8 155.458 207.056 3 12 4 8-222.945 234.170 2 12 4 7-82.7900 177.204 2 12 4 7 534.374 303.772 7 12 4 7 494.977 287.412 3 12 4 6 1855.64 558.346 2 12 4 6 1138.09 484.286 7 12 4 5 3160.76 741.140 2 12 4 5 2110.98 600.916 7 12 4 4 4532.65 878.779 2 12 4 3-128.670 263.095 2 12 4 2 973.671 437.678 2 12 4 1 52.6610 217.728 2 12 4 0 1099.99 482.745 2 12 4 -1 410.357 310.020 2 12 4 -2 4465.35 956.866 2 12 4 -3-595.247 428.443 2 12 4 -4 1616.28 667.088 2 12 4 -5 11.8165 250.906 2 12 4 -6 139.409 396.129 2 12 4 -7 855.049 495.112 2 12 5 11 3132.00 774.210 3 12 5 10 81.4347 202.630 3 12 5 9 123.865 184.692 3 12 5 9 1082.90 425.372 2 12 5 8 1471.86 457.650 7 12 5 8 1569.71 492.985 3 12 5 8 1752.88 531.100 2 12 5 7 2016.21 623.983 2 12 5 7 1511.07 467.758 7 12 5 6 12.6475 237.951 2 12 5 6-663.623 341.618 7 12 5 5 1919.97 588.506 2 12 5 4 4788.72 952.428 2 12 5 3 61.1369 323.570 2 12 5 2 587.458 359.191 2 12 5 1 1856.22 608.076 2 12 5 0 1362.10 549.491 2 12 5 -1 422.397 345.567 2 12 5 -2 224.505 368.797 2 12 5 -3 428.028 379.148 2 12 5 -4 61.9511 245.625 2 12 5 -5 912.418 516.517 2 12 5 -6-8.36231 182.834 2 12 6 11 421.145 295.104 3 12 6 10 714.284 362.189 3 12 6 10 1445.23 488.733 2 12 6 9 2374.37 606.668 3 12 6 9 1627.38 535.762 2 12 6 8-243.966 262.495 2 12 6 7 115.416 215.607 7 12 6 7 22.6137 222.467 2 12 6 6 3713.95 823.313 2 12 6 6 1540.87 473.985 7 12 6 5 2722.86 713.159 2 12 6 4-183.427 244.487 2 12 6 3 1437.06 545.868 2 12 6 2 2805.51 726.205 2 12 6 1 122.790 294.896 2 12 6 0 385.622 327.721 2 12 6 -1 10328.2 1454.43 2 12 6 -2-137.631 280.938 2 12 6 -3 26.5856 347.348 2 12 6 -4 260.526 331.151 2 12 6 -5 1289.62 580.779 2 12 7 11 441.099 274.322 5 12 7 10 233.595 221.376 5 12 7 10 415.463 308.845 2 12 7 9 1811.33 571.047 2 12 7 8-187.684 257.678 2 12 7 7 114.879 218.969 2 12 7 6 385.920 313.413 2 12 7 5 15551.4 1720.43 2 12 7 4 4.72222 211.343 2 12 7 3 936.944 457.352 2 12 7 2 2599.40 736.994 2 12 7 1 672.740 248.062 2 12 7 0 927.773 546.853 2 12 7 -1 44.6049 238.818 2 12 7 -2 1141.01 505.210 2 12 7 -3 2108.91 738.559 2 12 8 10 679.353 361.021 5 12 8 10-326.092 271.199 2 12 8 9 281.988 271.155 2 12 8 8 1632.85 547.889 2 12 8 7 111.697 196.306 2 12 8 6 748.834 422.279 2 12 8 5-95.6534 255.433 2 12 8 4 3543.20 835.719 2 12 8 3 923.256 441.019 2 12 8 2 1649.90 603.580 2 12 8 1 545.150 470.650 2 12 8 0 2587.38 743.406 2 12 8 -1 1245.57 562.013 2 12 9 8 793.627 418.137 2 12 9 7-172.014 270.285 2 12 9 6 4257.79 940.848 2 12 9 5 504.180 347.769 2 12 9 4-164.340 258.428 2 12 9 3 139.481 262.993 2 12 9 2 1280.01 567.684 2 13 -3 -1-97.0225 184.077 2 13 -3 -2 405.675 301.557 2 13 -2 1 2087.07 620.806 2 13 -2 0 162.328 244.796 2 13 -2 -1 874.193 421.231 2 13 -2 -2-12.7669 177.166 2 13 -2 -3-179.912 231.615 2 13 -1 2 819.861 408.568 2 13 -1 1-897.432 445.962 2 13 -1 0 1236.29 485.494 2 13 -1 -1 529.300 361.413 2 13 -1 -2 1355.23 529.302 2 13 -1 -3 226.500 247.895 2 13 -1 -4 311.492 326.243 2 13 0 3-393.996 316.333 2 13 0 3-119.217 204.896 7 13 0 2 352.382 275.538 2 13 0 2 89.9762 260.845 7 13 0 1 782.908 460.365 7 13 0 1 752.481 422.107 2 13 0 0 161.846 235.495 2 13 0 -1 1287.37 523.339 2 13 0 -2 2415.77 742.951 2 13 0 -3 2583.47 770.771 2 13 0 -4 682.223 496.845 2 13 1 5 304.308 277.754 7 13 1 4-464.952 336.589 2 13 1 4 253.764 286.026 7 13 1 3 716.741 407.319 2 13 1 3 927.534 513.728 7 13 1 2 559.418 388.326 2 13 1 2 8.82083 213.891 7 13 1 1-88.9817 260.840 2 13 1 0 180.451 330.080 2 13 1 -1 3137.88 808.510 2 13 1 -2 468.944 360.674 2 13 1 -3 515.842 374.188 2 13 1 -4 1878.67 644.336 2 13 2 8 1525.08 519.436 6 13 2 7 1382.94 561.457 7 13 2 6 1456.76 559.587 7 13 2 5 1453.43 507.752 2 13 2 5 1486.19 516.735 7 13 2 4-191.789 237.015 2 13 2 4 108.092 188.546 7 13 2 3 838.477 443.230 2 13 2 3 818.739 405.695 7 13 2 2 2010.78 698.101 2 13 2 1 2223.32 664.336 2 13 2 0 1238.26 491.478 2 13 2 -1 1270.81 521.801 2 13 2 -2 6157.56 1143.62 2 13 2 -3-774.539 432.665 2 13 2 -4 241.161 261.457 2 13 3 8 1021.53 416.549 7 13 3 7 1612.27 532.403 7 13 3 6 1093.83 437.584 2 13 3 6 901.862 415.879 7 13 3 5 358.291 285.227 2 13 3 5 2052.73 632.106 7 13 3 4 3603.56 856.137 2 13 3 4 3079.22 775.095 7 13 3 3 119.208 249.959 2 13 3 2 286.572 187.729 2 13 3 1 1163.65 451.343 2 13 3 0 3299.98 827.435 2 13 3 -1 61.9675 205.231 2 13 3 -2 986.617 546.227 2 13 3 -3 82.1601 377.137 2 13 3 -4 224.820 307.333 2 13 4 8-722.709 366.573 7 13 4 7 1743.37 562.697 2 13 4 7 1378.93 490.948 7 13 4 6 1926.62 594.032 2 13 4 6 2172.68 609.743 7 13 4 5-369.235 294.543 2 13 4 5 743.808 403.744 7 13 4 4 1110.21 485.396 2 13 4 3 1920.59 610.957 2 13 4 2 980.081 416.656 2 13 4 1-701.988 412.782 2 13 4 0 687.528 428.437 2 13 4 -1 6412.64 1178.16 2 13 4 -2 929.966 503.843 2 13 4 -3 338.887 194.295 2 13 5 8 336.579 182.327 2 13 5 7 621.899 369.912 2 13 5 7-390.092 273.175 7 13 5 6 1896.09 599.199 2 13 5 6 824.781 396.647 7 13 5 5 6101.55 1081.12 2 13 5 5 6390.82 1074.45 7 13 5 4 1348.64 493.763 2 13 5 3-770.892 444.755 2 13 5 2 2012.15 650.812 2 13 5 1 1980.29 636.168 2 13 5 0 118.215 179.624 2 13 5 -1 66.4515 363.867 2 13 5 -2 1824.88 666.791 2 13 6 9 301.509 230.127 2 13 6 8 1304.50 537.952 2 13 6 7 159.021 212.113 2 13 6 6 347.611 296.147 2 13 6 6 126.890 200.821 7 13 6 5 1970.65 627.960 2 13 6 4 1320.50 575.364 2 13 6 3-523.394 360.844 2 13 6 2-86.3314 203.661 2 13 6 1 372.543 321.808 2 13 6 0 5566.40 1132.30 2 13 6 -1 617.964 413.355 2 13 7 9-37.8635 178.816 2 13 7 8 179.179 244.473 2 13 7 7 170.401 243.167 2 13 7 6 843.035 407.781 2 13 7 5 979.626 484.750 2 13 7 4-54.2269 237.523 2 13 7 3 680.860 424.688 2 13 7 2-33.5627 208.001 2 14 -1 1 575.360 362.788 2 14 0 2 2594.14 732.539 2 14 0 1 872.882 470.122 2 14 1 3-415.978 315.227 2 14 1 2 5331.07 1073.90 2 14 1 1 703.577 419.385 2 14 1 0-211.960 294.768 2 14 2 4 1109.74 503.544 2 14 2 3 881.287 452.951 2 14 2 2-561.218 386.043 2 14 2 1-280.827 281.291 2 14 3 5 174.795 233.142 2 14 3 4-1170.67 514.070 2 14 3 4-853.371 455.953 7 14 3 3 910.905 457.613 2 14 3 3 325.677 330.420 7 14 3 2 2566.13 732.393 2 14 3 1-249.473 304.861 2 14 4 7 68.5982 188.585 7 14 4 6 1787.32 603.870 2 14 4 6 522.436 345.051 7 14 4 5-130.159 208.161 2 14 4 5 169.874 231.824 7 14 4 4-13.1182 207.188 2 14 4 4 249.781 289.425 7 14 4 3-840.939 454.532 2 14 5 6 551.005 355.971 7 14 5 5-1397.52 535.617 7 14 6 5 984.236 458.217 7 0 0 0 0.00 0.00 0 ; _shelx_hkl_checksum 29495 _shelx_res_file ; TITL exp_4494 in P-1 TMP.res created by SHELXL-2018/1 at 07:05:34 on 06-Aug-2019 REM transformed to space group : CELL 0.71073 10.8329 11.2168 14.2595 65.938 88.829 76.828 ZERR 2 0.0011 0.0016 0.0025 0.011 0.012 0.010 LATT 1 SFAC C H O N Zn UNIT 70 62 8 10 2 MERG 2 L.S. 20 ACTA BOND $H HTAB FMAP 2 PLAN 20 REM Instructions for potential hydrogen bonds HTAB C11 O12 EQIV $3 -x, -y+2, -z HTAB C21 N31_$3 EQIV $4 -x+1, -y+1, -z+1 HTAB C41 O22_$4 HTAB C51 O13 EQIV $1 x+1, y, z-1 HTAB C231 O12_$1 HTAB C241 O13_$1 WGHT 0.038300 0.018200 FVAR 3.68605 ZN1 5 0.296020 0.688956 0.632932 11.00000 0.02509 0.03476 = 0.02952 -0.01321 0.00554 -0.00585 N11 4 0.340046 0.727478 0.473035 11.00000 0.02751 0.03131 = 0.02608 -0.01226 0.00440 -0.00386 N21 4 0.333844 0.863452 0.089902 11.00000 0.02760 0.03756 = 0.02538 -0.01355 0.00540 -0.00638 N31 4 0.034463 1.069407 -0.231401 11.00000 0.03527 0.05486 = 0.03636 -0.01013 -0.00411 -0.01005 N41 4 1.247972 0.644511 -0.194603 11.00000 0.02635 0.04051 = 0.02954 -0.01201 0.00645 -0.00458 N51 4 1.191743 0.599599 0.007562 11.00000 0.02790 0.08824 = 0.02889 -0.01942 0.00242 -0.00178 C11 1 0.254702 0.805084 0.391566 11.00000 0.02434 0.04491 = 0.02979 -0.01484 0.00612 -0.00134 REM AFIX 43 H11 2 0.174187 0.839307 0.403723 11.00000 0.04020 REM AFIX 0 C21 1 0.281616 0.831335 0.291334 11.00000 0.02524 0.04696 = 0.02550 -0.01196 0.00315 -0.00029 REM AFIX 43 H21 2 0.220650 0.887371 0.235778 11.00000 0.06278 REM AFIX 0 C31 1 0.400858 0.776402 0.269582 11.00000 0.02821 0.03266 = 0.02412 -0.01182 0.00457 -0.00530 C41 1 0.488998 0.694570 0.354087 11.00000 0.02482 0.03945 = 0.02844 -0.01446 0.00391 0.00380 REM AFIX 43 H41 2 0.565287 0.650155 0.349012 11.00000 0.03405 REM AFIX 0 C51 1 0.454674 0.674544 0.451817 11.00000 0.02768 0.03441 = 0.02711 -0.01011 0.00091 0.00504 REM AFIX 43 H51 2 0.514836 0.614445 0.507776 11.00000 0.05438 REM AFIX 0 C61 1 0.432554 0.802465 0.161850 11.00000 0.02628 0.03146 = 0.02486 -0.01030 0.00616 -0.00590 C71 1 0.556775 0.767208 0.138045 11.00000 0.02616 0.04454 = 0.02259 -0.01044 -0.00052 0.00098 REM AFIX 43 H71 2 0.616924 0.728510 0.191081 11.00000 0.03170 REM AFIX 0 C81 1 0.584224 0.793010 0.037123 11.00000 0.02927 0.02964 = 0.02374 -0.00920 0.00637 -0.00397 C91 1 0.480974 0.853851 -0.036227 11.00000 0.02778 0.04321 = 0.02541 -0.01553 0.00867 -0.00655 REM AFIX 43 H91 2 0.495722 0.864931 -0.103120 11.00000 0.03300 REM AFIX 0 C101 1 0.359077 0.887642 -0.007952 11.00000 0.02959 0.03112 = 0.02641 -0.01277 0.00348 -0.00651 C111 1 0.141600 0.995139 -0.246192 11.00000 0.04499 0.05694 = 0.02867 -0.01702 -0.00144 -0.01561 REM AFIX 43 H111 2 0.139270 0.983828 -0.308472 11.00000 0.03374 REM AFIX 0 C121 1 0.247895 0.937335 -0.177737 11.00000 0.03798 0.04827 = 0.02979 -0.01913 0.00496 -0.00646 REM AFIX 43 H121 2 0.317038 0.886355 -0.191951 11.00000 0.03584 REM AFIX 0 C131 1 0.247355 0.952921 -0.086166 11.00000 0.02556 0.03211 = 0.02600 -0.00838 0.00288 -0.00775 C141 1 0.136634 1.030801 -0.069824 11.00000 0.03085 0.03968 = 0.03189 -0.01320 0.00886 -0.01124 REM AFIX 43 H141 2 0.123053 1.046869 -0.007915 11.00000 0.05005 REM AFIX 0 C151 1 0.035043 1.086199 -0.144137 11.00000 0.02697 0.05079 = 0.04423 -0.01686 0.00642 -0.00240 REM AFIX 43 H151 2 -0.042325 1.141625 -0.130933 11.00000 0.06410 REM AFIX 0 C161 1 0.716564 0.758492 0.008754 11.00000 0.02559 0.03807 = 0.02682 -0.01496 0.00833 -0.00385 C171 1 0.749277 0.819922 -0.091597 11.00000 0.02666 0.04898 = 0.02535 -0.01030 0.00394 0.00023 REM AFIX 43 H171 2 0.677898 0.888396 -0.144540 11.00000 0.03538 REM AFIX 0 C181 1 0.871718 0.789369 -0.117347 11.00000 0.03407 0.04803 = 0.02199 -0.00547 0.00858 -0.00631 REM AFIX 43 H181 2 0.891347 0.833523 -0.182935 11.00000 0.05128 REM AFIX 0 C191 1 0.968121 0.696024 -0.043576 11.00000 0.02672 0.03990 = 0.02641 -0.01293 0.00468 -0.00531 C201 1 0.936221 0.636280 0.056925 11.00000 0.03148 0.03918 = 0.02632 -0.01070 0.00033 -0.00163 REM AFIX 43 H201 2 0.999539 0.573021 0.112264 11.00000 0.03928 REM AFIX 0 C211 1 0.813037 0.665831 0.082419 11.00000 0.03363 0.03657 = 0.02187 -0.00702 0.00666 -0.00275 REM AFIX 43 H211 2 0.793588 0.619032 0.150659 11.00000 0.03531 REM AFIX 0 C221 1 1.100372 0.659132 -0.070259 11.00000 0.02217 0.04142 = 0.02895 -0.01480 0.00523 -0.00330 C231 1 1.130004 0.680330 -0.169937 11.00000 0.02875 0.03655 = 0.02826 -0.01358 0.00497 -0.00408 REM AFIX 43 H231 2 1.068184 0.718172 -0.222429 11.00000 0.04864 REM AFIX 0 C241 1 1.337419 0.585154 -0.116782 11.00000 0.02812 0.08079 = 0.03280 -0.01844 0.00430 0.00139 REM AFIX 43 H241 2 1.421444 0.561239 -0.133867 11.00000 0.05357 REM AFIX 0 C251 1 1.308735 0.564313 -0.017839 11.00000 0.02601 0.12034 = 0.03308 -0.02072 -0.00416 0.00638 REM AFIX 43 H251 2 1.374681 0.524692 0.035610 11.00000 0.08912 REM AFIX 0 O12 3 0.111355 0.797504 0.591522 11.00000 0.02946 0.03973 = 0.03383 -0.01401 0.00386 -0.00387 O22 3 0.239550 0.517153 0.652418 11.00000 0.03448 0.03317 = 0.03947 -0.01286 0.00241 -0.00754 C12 1 0.016977 0.753207 0.582574 11.00000 0.02957 0.05888 = 0.02544 -0.00624 0.00077 -0.00464 C22 1 0.020701 0.621202 0.600783 11.00000 0.03257 0.06545 = 0.05347 -0.01821 -0.00329 -0.01956 REM AFIX 43 H22 2 -0.048852 0.599552 0.598498 11.00000 0.07037 REM AFIX 0 C32 1 0.128269 0.512650 0.632549 11.00000 0.04596 0.04858 = 0.02653 -0.00958 0.00014 -0.02128 C42 1 -0.109715 0.856257 0.552053 11.00000 0.03377 0.08115 = 0.07217 -0.01235 -0.00001 0.00420 AFIX 137 H42A 2 -0.141705 0.868459 0.611626 11.00000 -1.50000 H42B 2 -0.169191 0.825221 0.524065 11.00000 -1.50000 H42C 2 -0.098442 0.940318 0.501149 11.00000 -1.50000 AFIX 0 C52 1 0.112422 0.376220 0.646145 11.00000 0.10476 0.06277 = 0.07312 -0.01859 -0.01338 -0.04526 AFIX 137 H52A 2 0.146515 0.356666 0.589922 11.00000 -1.50000 H52B 2 0.023710 0.376549 0.647283 11.00000 -1.50000 H52C 2 0.156976 0.308807 0.709862 11.00000 -1.50000 AFIX 0 O13 3 0.477354 0.577158 0.691374 11.00000 0.02652 0.04369 = 0.03406 -0.01736 0.00436 -0.00704 O23 3 0.349508 0.856584 0.625388 11.00000 0.04157 0.03918 = 0.04432 -0.02137 0.00901 -0.01394 C13 1 0.571868 0.621609 0.700274 11.00000 0.03172 0.06096 = 0.02685 -0.01865 0.00771 -0.01298 C23 1 0.566534 0.753997 0.682517 11.00000 0.03489 0.07709 = 0.05851 -0.03358 0.00776 -0.02664 REM AFIX 43 H23 2 0.639197 0.769489 0.694506 11.00000 0.06857 REM AFIX 0 C33 1 0.460258 0.863180 0.645210 11.00000 0.05841 0.05423 = 0.03090 -0.02336 0.01782 -0.03139 C43 1 0.697916 0.519588 0.732135 11.00000 0.03003 0.08731 = 0.06738 -0.03022 -0.00166 -0.00644 AFIX 137 H43A 2 0.688664 0.439652 0.789420 11.00000 -1.50000 H43B 2 0.759584 0.556254 0.751847 11.00000 -1.50000 H43C 2 0.725820 0.497848 0.675439 11.00000 -1.50000 AFIX 0 C53 1 0.475863 1.001783 0.625852 11.00000 0.08194 0.06509 = 0.06708 -0.03478 0.02291 -0.04622 AFIX 137 H53A 2 0.428018 1.066677 0.562725 11.00000 -1.50000 H53B 2 0.564167 1.002716 0.620713 11.00000 -1.50000 H53C 2 0.445306 1.023890 0.681838 11.00000 -1.50000 AFIX 0 HKLF 4 REM exp_4494 in P-1 REM R1 = 0.0552 for 4668 Fo > 4sig(Fo) and 0.0977 for all 7056 data REM 486 parameters refined using 0 restraints END WGHT 0.0383 0.0312 REM Instructions for potential hydrogen bonds HTAB C11 O12 HTAB C21 N31_$3 HTAB C41 O22_$4 HTAB C51 O13 HTAB C231 O12_$1 HTAB C241 O13_$1 EQIV $5 -x, -y+2, -z+1 HTAB C42 O12_$5 REM Highest difference peak 0.433, deepest hole -0.412, 1-sigma level 0.088 Q1 1 -0.1074 1.0625 -0.1014 11.00000 0.05 0.43 Q2 1 0.2806 0.5917 0.6168 11.00000 0.05 0.36 Q3 1 0.4237 0.8826 0.3109 11.00000 0.05 0.32 Q4 1 1.3224 0.6973 -0.0782 11.00000 0.05 0.31 Q5 1 0.2206 0.5816 0.6709 11.00000 0.05 0.31 Q6 1 1.3569 0.4200 0.0405 11.00000 0.05 0.31 Q7 1 -0.0288 0.5965 0.5204 11.00000 0.05 0.31 Q8 1 0.0092 0.5571 0.7217 11.00000 0.05 0.30 Q9 1 0.0317 0.3234 0.5421 11.00000 0.05 0.30 Q10 1 -0.1361 0.3317 0.6125 11.00000 0.05 0.30 Q11 1 0.0367 0.2843 0.7430 11.00000 0.05 0.30 Q12 1 -0.2206 1.0102 0.5404 11.00000 0.05 0.29 Q13 1 1.2401 0.7416 0.0502 11.00000 0.05 0.29 Q14 1 0.6359 1.0617 0.6424 11.00000 0.05 0.29 Q15 1 0.3278 0.5410 0.5102 11.00000 0.05 0.28 Q16 1 0.2508 0.5235 0.5697 11.00000 0.05 0.28 Q17 1 -0.0325 0.9607 0.6137 11.00000 0.05 0.28 Q18 1 0.3435 0.7289 0.5305 11.00000 0.05 0.28 Q19 1 1.4212 0.4403 -0.1228 11.00000 0.05 0.28 Q20 1 0.0799 0.9128 0.5731 11.00000 0.05 0.28 ; _shelx_res_checksum 32749 loop_ _space_group_symop_operation_xyz 'x, y, z' '-x, -y, -z' loop_ _atom_site_type_symbol _atom_site_label _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_U_iso_or_equiv _atom_site_adp_type _atom_site_calc_flag _atom_site_occupancy Zn Zn1 0.29602(3) 0.68896(4) 0.63293(2) 0.03012(13) Uani d 1 N N11 0.3400(2) 0.7275(2) 0.47304(17) 0.0288(6) Uani d 1 N N21 0.3338(2) 0.8635(2) 0.08990(17) 0.0303(6) Uani d 1 N N31 0.0345(3) 1.0694(3) -0.2314(2) 0.0451(7) Uani d 1 N N41 1.2480(2) 0.6445(3) -0.19460(18) 0.0336(6) Uani d 1 N N51 1.1917(3) 0.5996(3) 0.00756(19) 0.0521(9) Uani d 1 C C11 0.2547(3) 0.8051(3) 0.3916(2) 0.0345(8) Uani d 1 H H11 0.174(3) 0.839(3) 0.404(2) 0.040(9) Uiso d 1 C C21 0.2816(3) 0.8313(3) 0.2913(2) 0.0351(8) Uani d 1 H H21 0.221(3) 0.887(3) 0.236(3) 0.063(11) Uiso d 1 C C31 0.4009(3) 0.7764(3) 0.2696(2) 0.0287(7) Uani d 1 C C41 0.4890(3) 0.6946(3) 0.3541(2) 0.0328(8) Uani d 1 H H41 0.565(3) 0.650(3) 0.349(2) 0.034(9) Uiso d 1 C C51 0.4547(3) 0.6745(3) 0.4518(2) 0.0328(7) Uani d 1 H H51 0.515(3) 0.614(3) 0.508(2) 0.054(10) Uiso d 1 C C61 0.4326(3) 0.8025(3) 0.1619(2) 0.0282(7) Uani d 1 C C71 0.5568(3) 0.7672(3) 0.1380(2) 0.0339(8) Uani d 1 H H71 0.617(3) 0.729(3) 0.191(2) 0.032(8) Uiso d 1 C C81 0.5842(3) 0.7930(3) 0.0371(2) 0.0288(7) Uani d 1 C C91 0.4810(3) 0.8539(3) -0.0362(2) 0.0321(7) Uani d 1 H H91 0.496(3) 0.865(3) -0.103(2) 0.033(8) Uiso d 1 C C101 0.3591(3) 0.8876(3) -0.0080(2) 0.0289(7) Uani d 1 C C111 0.1416(3) 0.9951(4) -0.2462(3) 0.0431(9) Uani d 1 H H111 0.139(3) 0.984(3) -0.308(2) 0.034(8) Uiso d 1 C C121 0.2479(3) 0.9373(4) -0.1777(2) 0.0384(8) Uani d 1 H H121 0.317(3) 0.886(3) -0.192(2) 0.036(9) Uiso d 1 C C131 0.2474(3) 0.9529(3) -0.0862(2) 0.0290(7) Uani d 1 C C141 0.1366(3) 1.0308(3) -0.0698(2) 0.0343(8) Uani d 1 H H141 0.123(3) 1.047(3) -0.008(2) 0.050(10) Uiso d 1 C C151 0.0350(3) 1.0862(4) -0.1441(3) 0.0429(9) Uani d 1 H H151 -0.042(3) 1.142(3) -0.131(2) 0.064(11) Uiso d 1 C C161 0.7166(3) 0.7585(3) 0.0088(2) 0.0304(7) Uani d 1 C C171 0.7493(3) 0.8199(3) -0.0916(2) 0.0371(8) Uani d 1 H H171 0.678(3) 0.888(3) -0.145(2) 0.035(8) Uiso d 1 C C181 0.8717(3) 0.7894(4) -0.1173(2) 0.0385(8) Uani d 1 H H181 0.891(3) 0.834(3) -0.183(2) 0.051(10) Uiso d 1 C C191 0.9681(3) 0.6960(3) -0.0436(2) 0.0318(7) Uani d 1 C C201 0.9362(3) 0.6363(3) 0.0569(2) 0.0345(8) Uani d 1 H H201 1.000(3) 0.573(3) 0.112(2) 0.039(9) Uiso d 1 C C211 0.8130(3) 0.6658(3) 0.0824(2) 0.0335(8) Uani d 1 H H211 0.794(3) 0.619(3) 0.151(2) 0.035(8) Uiso d 1 C C221 1.1004(3) 0.6591(3) -0.0703(2) 0.0316(7) Uani d 1 C C231 1.1300(3) 0.6803(3) -0.1699(2) 0.0318(7) Uani d 1 H H231 1.068(3) 0.718(3) -0.222(2) 0.049(10) Uiso d 1 C C241 1.3374(4) 0.5852(4) -0.1168(3) 0.0515(11) Uani d 1 H H241 1.421(3) 0.561(3) -0.134(2) 0.054(10) Uiso d 1 C C251 1.3087(4) 0.5643(5) -0.0178(3) 0.0677(14) Uani d 1 H H251 1.375(4) 0.525(4) 0.036(3) 0.089(14) Uiso d 1 O O12 0.1114(2) 0.7975(2) 0.59152(15) 0.0356(5) Uani d 1 O O22 0.2395(2) 0.5172(2) 0.65242(15) 0.0365(5) Uani d 1 C C12 0.0170(3) 0.7532(4) 0.5826(2) 0.0428(9) Uani d 1 C C22 0.0207(4) 0.6212(4) 0.6008(3) 0.0512(10) Uani d 1 H H22 -0.049(4) 0.600(4) 0.598(3) 0.070(13) Uiso d 1 C C32 0.1283(3) 0.5127(4) 0.6325(2) 0.0406(8) Uani d 1 C C42 -0.1097(4) 0.8563(4) 0.5521(3) 0.0720(13) Uani d 1 H H42A -0.141705 0.868459 0.611626 0.108 Uiso calc 1 H H42B -0.169191 0.825221 0.524065 0.108 Uiso calc 1 H H42C -0.098442 0.940318 0.501149 0.108 Uiso calc 1 C C52 0.1124(5) 0.3762(4) 0.6461(3) 0.0787(14) Uani d 1 H H52A 0.146515 0.356666 0.589922 0.118 Uiso calc 1 H H52B 0.023710 0.376549 0.647283 0.118 Uiso calc 1 H H52C 0.156976 0.308807 0.709862 0.118 Uiso calc 1 O O13 0.47735(19) 0.5772(2) 0.69137(15) 0.0346(5) Uani d 1 O O23 0.3495(2) 0.8566(2) 0.62539(15) 0.0396(5) Uani d 1 C C13 0.5719(3) 0.6216(4) 0.7003(2) 0.0394(8) Uani d 1 C C23 0.5665(4) 0.7540(5) 0.6825(3) 0.0527(11) Uani d 1 H H23 0.639(4) 0.769(4) 0.695(3) 0.069(13) Uiso d 1 C C33 0.4603(4) 0.8632(4) 0.6452(2) 0.0430(9) Uani d 1 C C43 0.6979(3) 0.5196(4) 0.7321(3) 0.0634(12) Uani d 1 H H43A 0.688664 0.439652 0.789420 0.095 Uiso calc 1 H H43B 0.759584 0.556254 0.751847 0.095 Uiso calc 1 H H43C 0.725820 0.497848 0.675439 0.095 Uiso calc 1 C C53 0.4759(4) 1.0018(4) 0.6259(3) 0.0641(12) Uani d 1 H H53A 0.428018 1.066677 0.562725 0.096 Uiso calc 1 H H53B 0.564167 1.002716 0.620713 0.096 Uiso calc 1 H H53C 0.445306 1.023890 0.681838 0.096 Uiso calc 1 loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_12 _atom_site_aniso_U_13 _atom_site_aniso_U_23 Zn1 0.0251(2) 0.0348(2) 0.0295(2) -0.00585(16) 0.00554(15) -0.01321(17) N11 0.0275(15) 0.0313(15) 0.0261(13) -0.0039(12) 0.0044(11) -0.0123(12) N21 0.0276(14) 0.0376(16) 0.0254(13) -0.0064(12) 0.0054(11) -0.0135(12) N31 0.0353(18) 0.055(2) 0.0364(15) -0.0101(15) -0.0041(13) -0.0101(15) N41 0.0263(15) 0.0405(16) 0.0295(13) -0.0046(12) 0.0064(11) -0.0120(13) N51 0.0279(17) 0.088(2) 0.0289(14) -0.0018(16) 0.0024(12) -0.0194(16) C11 0.0243(18) 0.045(2) 0.0298(16) -0.0013(16) 0.0061(14) -0.0148(16) C21 0.0252(18) 0.047(2) 0.0255(16) -0.0003(16) 0.0031(14) -0.0120(16) C31 0.0282(17) 0.0327(18) 0.0241(14) -0.0053(14) 0.0046(13) -0.0118(14) C41 0.0248(18) 0.039(2) 0.0284(16) 0.0038(15) 0.0039(14) -0.0145(15) C51 0.0277(18) 0.0344(19) 0.0271(16) 0.0050(15) 0.0009(14) -0.0101(15) C61 0.0263(17) 0.0315(18) 0.0249(15) -0.0059(14) 0.0062(13) -0.0103(14) C71 0.0262(18) 0.045(2) 0.0226(15) 0.0010(15) -0.0005(13) -0.0104(15) C81 0.0293(18) 0.0296(17) 0.0237(14) -0.0040(14) 0.0064(13) -0.0092(14) C91 0.0278(18) 0.043(2) 0.0254(15) -0.0066(15) 0.0087(13) -0.0155(16) C101 0.0296(18) 0.0311(17) 0.0264(15) -0.0065(14) 0.0035(13) -0.0128(14) C111 0.045(2) 0.057(2) 0.0287(17) -0.0156(19) -0.0014(16) -0.0170(18) C121 0.038(2) 0.048(2) 0.0298(17) -0.0065(17) 0.0050(15) -0.0191(17) C131 0.0256(17) 0.0321(18) 0.0260(15) -0.0077(14) 0.0029(13) -0.0084(14) C141 0.0308(19) 0.040(2) 0.0319(17) -0.0112(15) 0.0089(14) -0.0132(16) C151 0.027(2) 0.051(2) 0.044(2) -0.0024(17) 0.0064(16) -0.0169(19) C161 0.0256(17) 0.0381(19) 0.0268(15) -0.0039(14) 0.0083(13) -0.0150(15) C171 0.0267(18) 0.049(2) 0.0253(16) 0.0002(16) 0.0039(14) -0.0103(16) C181 0.034(2) 0.048(2) 0.0220(16) -0.0063(17) 0.0086(14) -0.0055(17) C191 0.0267(18) 0.040(2) 0.0264(15) -0.0053(15) 0.0047(13) -0.0129(15) C201 0.0315(19) 0.039(2) 0.0263(16) -0.0016(16) 0.0003(14) -0.0107(16) C211 0.034(2) 0.037(2) 0.0219(15) -0.0027(15) 0.0067(14) -0.0070(15) C221 0.0222(17) 0.041(2) 0.0289(16) -0.0033(14) 0.0052(13) -0.0148(15) C231 0.0287(19) 0.0366(19) 0.0283(16) -0.0041(15) 0.0050(14) -0.0136(16) C241 0.028(2) 0.081(3) 0.0328(18) 0.001(2) 0.0043(16) -0.018(2) C251 0.026(2) 0.120(4) 0.0331(19) 0.006(2) -0.0042(17) -0.021(2) O12 0.0295(13) 0.0397(13) 0.0338(12) -0.0039(10) 0.0039(10) -0.0140(11) O22 0.0345(13) 0.0332(13) 0.0395(12) -0.0075(10) 0.0024(10) -0.0129(11) C12 0.030(2) 0.059(3) 0.0254(16) -0.0046(18) 0.0008(14) -0.0062(18) C22 0.033(2) 0.065(3) 0.053(2) -0.020(2) -0.0033(18) -0.018(2) C32 0.046(2) 0.049(2) 0.0265(16) -0.0213(19) 0.0001(15) -0.0096(17) C42 0.034(2) 0.081(3) 0.072(3) 0.004(2) 0.000(2) -0.012(2) C52 0.105(4) 0.063(3) 0.073(3) -0.045(3) -0.013(3) -0.019(3) O13 0.0265(12) 0.0437(14) 0.0341(11) -0.0070(10) 0.0044(9) -0.0174(11) O23 0.0416(15) 0.0392(14) 0.0443(13) -0.0139(11) 0.0090(11) -0.0214(12) C13 0.032(2) 0.061(2) 0.0268(16) -0.0130(18) 0.0077(14) -0.0187(18) C23 0.035(2) 0.077(3) 0.059(2) -0.027(2) 0.0078(19) -0.034(2) C33 0.058(3) 0.054(2) 0.0309(17) -0.031(2) 0.0178(17) -0.0234(18) C43 0.030(2) 0.087(3) 0.067(3) -0.006(2) -0.0017(19) -0.030(2) C53 0.082(3) 0.065(3) 0.067(3) -0.046(2) 0.023(2) -0.035(2) loop_ _atom_type_symbol _atom_type_description _atom_type_scat_dispersion_real _atom_type_scat_dispersion_imag _atom_type_scat_source C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Zn Zn 0.2839 1.4301 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' loop_ _geom_angle_atom_site_label_1 _geom_angle_atom_site_label_2 _geom_angle_atom_site_label_3 _geom_angle_site_symmetry_3 _geom_angle O12 Zn1 O23 . 90.15(9) O12 Zn1 O13 . 173.47(7) O23 Zn1 O13 . 89.10(9) O12 Zn1 O22 . 89.73(9) O23 Zn1 O22 . 175.50(8) O13 Zn1 O22 . 90.51(8) O12 Zn1 N11 . 93.75(8) O23 Zn1 N11 . 92.53(9) O13 Zn1 N11 . 92.77(8) O22 Zn1 N11 . 91.97(8) O12 Zn1 N41 1_456 86.32(8) O23 Zn1 N41 1_456 88.29(9) O13 Zn1 N41 1_456 87.17(8) O22 Zn1 N41 1_456 87.22(9) N11 Zn1 N41 1_456 179.18(9) C51 N11 C11 . 116.1(3) C51 N11 Zn1 . 121.14(19) C11 N11 Zn1 . 122.7(2) C61 N21 C101 . 117.2(3) C151 N31 C111 . 115.8(3) C241 N41 C231 . 115.7(3) C241 N41 Zn1 1_654 122.0(2) C231 N41 Zn1 1_654 122.26(19) C251 N51 C221 . 115.8(3) N11 C11 C21 . 123.2(3) N11 C11 H11 . 118.3(19) C21 C11 H11 . 118.4(19) C11 C21 C31 . 120.4(3) C11 C21 H21 . 121(2) C31 C21 H21 . 118(2) C21 C31 C41 . 116.4(3) C21 C31 C61 . 121.6(3) C41 C31 C61 . 122.0(3) C51 C41 C31 . 119.5(3) C51 C41 H41 . 116.9(19) C31 C41 H41 . 123.5(18) N11 C51 C41 . 124.3(3) N11 C51 H51 . 118(2) C41 C51 H51 . 117(2) N21 C61 C71 . 122.6(3) N21 C61 C31 . 115.7(3) C71 C61 C31 . 121.7(3) C61 C71 C81 . 120.8(3) C61 C71 H71 . 116.3(18) C81 C71 H71 . 122.9(18) C91 C81 C71 . 116.0(3) C91 C81 C161 . 121.8(3) C71 C81 C161 . 122.1(3) C81 C91 C101 . 120.6(3) C81 C91 H91 . 117.7(17) C101 C91 H91 . 121.5(17) N21 C101 C91 . 122.8(3) N21 C101 C131 . 116.1(3) C91 C101 C131 . 121.1(3) N31 C111 C121 . 123.9(3) N31 C111 H111 . 114.6(17) C121 C111 H111 . 121.5(18) C111 C121 C131 . 120.1(3) C111 C121 H121 . 119.4(18) C131 C121 H121 . 120.5(18) C121 C131 C141 . 116.7(3) C121 C131 C101 . 121.9(3) C141 C131 C101 . 121.5(3) C151 C141 C131 . 118.8(3) C151 C141 H141 . 116.4(19) C131 C141 H141 . 124.7(19) N31 C151 C141 . 124.6(3) N31 C151 H151 . 118.1(19) C141 C151 H151 . 117(2) C171 C161 C211 . 117.4(3) C171 C161 C81 . 121.5(3) C211 C161 C81 . 121.1(3) C181 C171 C161 . 121.4(3) C181 C171 H171 . 122.1(16) C161 C171 H171 . 116.5(16) C171 C181 C191 . 121.1(3) C171 C181 H181 . 120(2) C191 C181 H181 . 119(2) C201 C191 C181 . 117.6(3) C201 C191 C221 . 120.4(3) C181 C191 C221 . 122.0(3) C211 C201 C191 . 121.2(3) C211 C201 H201 . 117.2(18) C191 C201 H201 . 121.6(18) C201 C211 C161 . 121.3(3) C201 C211 H211 . 119.0(18) C161 C211 H211 . 119.7(18) N51 C221 C231 . 120.4(3) N51 C221 C191 . 117.0(3) C231 C221 C191 . 122.6(3) N41 C231 C221 . 123.2(3) N41 C231 H231 . 116(2) C221 C231 H231 . 121(2) N41 C241 C251 . 121.3(3) N41 C241 H241 . 116(2) C251 C241 H241 . 122(2) N51 C251 C241 . 123.5(3) N51 C251 H251 . 117(3) C241 C251 H251 . 119(3) C12 O12 Zn1 . 126.3(2) C32 O22 Zn1 . 125.4(2) O12 C12 C22 . 125.6(3) O12 C12 C42 . 115.0(3) C22 C12 C42 . 119.3(3) C12 C22 C32 . 126.9(3) C12 C22 H22 . 119(3) C32 C22 H22 . 114(3) O22 C32 C22 . 125.9(3) O22 C32 C52 . 115.5(3) C22 C32 C52 . 118.6(3) C12 C42 H42A . 109.5 C12 C42 H42B . 109.5 H42A C42 H42B . 109.5 C12 C42 H42C . 109.5 H42A C42 H42C . 109.5 H42B C42 H42C . 109.5 C32 C52 H52A . 109.5 C32 C52 H52B . 109.5 H52A C52 H52B . 109.5 C32 C52 H52C . 109.5 H52A C52 H52C . 109.5 H52B C52 H52C . 109.5 C13 O13 Zn1 . 126.6(2) C33 O23 Zn1 . 126.5(2) O13 C13 C23 . 125.0(3) O13 C13 C43 . 115.4(3) C23 C13 C43 . 119.5(3) C13 C23 C33 . 127.1(3) C13 C23 H23 . 115(3) C33 C23 H23 . 118(3) O23 C33 C23 . 125.2(3) O23 C33 C53 . 115.8(3) C23 C33 C53 . 118.9(3) C13 C43 H43A . 109.5 C13 C43 H43B . 109.5 H43A C43 H43B . 109.5 C13 C43 H43C . 109.5 H43A C43 H43C . 109.5 H43B C43 H43C . 109.5 C33 C53 H53A . 109.5 C33 C53 H53B . 109.5 H53A C53 H53B . 109.5 C33 C53 H53C . 109.5 H53A C53 H53C . 109.5 H53B C53 H53C . 109.5 loop_ _geom_bond_atom_site_label_1 _geom_bond_atom_site_label_2 _geom_bond_site_symmetry_2 _geom_bond_distance Zn1 O12 . 2.046(2) Zn1 O23 . 2.052(2) Zn1 O13 . 2.054(2) Zn1 O22 . 2.064(2) Zn1 N11 . 2.204(2) Zn1 N41 1_456 2.374(2) N11 C51 . 1.335(4) N11 C11 . 1.347(4) N21 C61 . 1.343(3) N21 C101 . 1.343(3) N31 C151 . 1.333(4) N31 C111 . 1.333(4) N41 C241 . 1.327(4) N41 C231 . 1.335(4) N51 C251 . 1.328(4) N51 C221 . 1.340(4) C11 C21 . 1.376(4) C11 H11 . 0.91(3) C21 C31 . 1.386(4) C21 H21 . 0.94(3) C31 C41 . 1.397(4) C31 C61 . 1.490(4) C41 C51 . 1.376(4) C41 H41 . 0.88(3) C51 H51 . 0.95(3) C61 C71 . 1.390(4) C71 C81 . 1.388(4) C71 H71 . 0.90(3) C81 C91 . 1.389(4) C81 C161 . 1.490(4) C91 C101 . 1.387(4) C91 H91 . 0.93(3) C101 C131 . 1.493(4) C111 C121 . 1.374(4) C111 H111 . 0.95(3) C121 C131 . 1.386(4) C121 H121 . 0.91(3) C131 C141 . 1.390(4) C141 C151 . 1.385(4) C141 H141 . 0.97(3) C151 H151 . 0.99(4) C161 C171 . 1.391(4) C161 C211 . 1.391(4) C171 C181 . 1.374(4) C171 H171 . 1.02(3) C181 C191 . 1.394(4) C181 H181 . 0.91(3) C191 C201 . 1.387(4) C191 C221 . 1.485(4) C201 C211 . 1.378(4) C201 H201 . 0.97(3) C211 H211 . 0.94(3) C221 C231 . 1.386(4) C231 H231 . 0.91(3) C241 C251 . 1.374(5) C241 H241 . 0.94(3) C251 H251 . 0.94(4) O12 C12 . 1.264(4) O22 C32 . 1.261(4) C12 C22 . 1.386(5) C12 C42 . 1.517(5) C22 C32 . 1.404(5) C22 H22 . 0.85(4) C32 C52 . 1.512(5) C42 H42A . 0.9600 C42 H42B . 0.9600 C42 H42C . 0.9600 C52 H52A . 0.9600 C52 H52B . 0.9600 C52 H52C . 0.9600 O13 C13 . 1.266(4) O23 C33 . 1.263(4) C13 C23 . 1.388(5) C13 C43 . 1.507(5) C23 C33 . 1.400(5) C23 H23 . 0.88(4) C33 C53 . 1.513(5) C43 H43A . 0.9600 C43 H43B . 0.9600 C43 H43C . 0.9600 C53 H53A . 0.9600 C53 H53B . 0.9600 C53 H53C . 0.9600 loop_ _geom_hbond_atom_site_label_D _geom_hbond_atom_site_label_H _geom_hbond_atom_site_label_A _geom_hbond_site_symmetry_A _geom_hbond_distance_DH _geom_hbond_distance_HA _geom_hbond_distance_DA _geom_hbond_angle_DHA _geom_hbond_publ_flag C11 H11 O12 . 0.91(3) 2.63(3) 3.198(4) 121(2) no C21 H21 N31 2_575 0.94(3) 2.69(4) 3.362(4) 129(3) no C41 H41 O22 2_666 0.88(3) 2.49(3) 3.359(4) 168(3) no C51 H51 O13 . 0.95(3) 2.52(3) 3.129(4) 122(3) no C231 H231 O12 1_654 0.91(3) 2.50(3) 3.098(4) 124(3) no C241 H241 O13 1_654 0.94(3) 2.50(3) 3.124(4) 124(2) no _cod_database_fobs_code 2021753