#------------------------------------------------------------------------------ #$Date: 2019-10-25 07:02:28 +0300 (Fri, 25 Oct 2019) $ #$Revision: 219510 $ #$URL: file:///home/coder/svn-repositories/cod/cif/2/02/17/2021795.cif $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2021795 loop_ _publ_author_name 'Clendening, Reese A.' 'Zeller, Matthias' 'Ren, Tong' _publ_section_title ; Crystal structures of two (5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane)iron(III) complexes ; _journal_coeditor_code CU3157 _journal_issue 11 _journal_name_full 'Acta Crystallographica Section C' _journal_page_first ; ; _journal_paper_doi 10.1107/S2053229619013925 _journal_volume 75 _journal_year 2019 _chemical_absolute_configuration unk _chemical_formula_iupac '[Fe Cl2 (C16 H36 N4)] Cl' _chemical_formula_moiety 'C16 H36 Cl2 Fe N4 +, Cl -' _chemical_formula_sum 'C16 H36 Cl3 Fe N4' _chemical_formula_weight 446.69 _chemical_name_systematic ; Dichlorido(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane)iron(III) chloride ; _space_group_crystal_system orthorhombic _space_group_IT_number 43 _space_group_name_Hall 'F 2 -2d' _space_group_name_H-M_alt 'F d d 2' _symmetry_space_group_name_Hall 'F 2 -2d' _symmetry_space_group_name_H-M 'F d d 2' _atom_sites_solution_hydrogens mixed _atom_sites_solution_primary direct _atom_sites_solution_secondary difmap _audit_creation_method SHELXL-2018/3 _cell_angle_alpha 90 _cell_angle_beta 90 _cell_angle_gamma 90 _cell_formula_units_Z 8 _cell_length_a 34.5658(16) _cell_length_b 9.3832(4) _cell_length_c 12.5209(6) _cell_measurement_reflns_used 9904 _cell_measurement_temperature 150(2) _cell_measurement_theta_max 34.3886 _cell_measurement_theta_min 2.7761 _cell_volume 4061.0(3) _computing_cell_refinement ; SAINT (Bruker, 2018) ; _computing_data_collection ; APEX3 (Bruker, 2018) ; _computing_data_reduction ; SAINT (Bruker, 2018) ; _computing_molecular_graphics ; Mercury (Macrae et al., 2008) ; _computing_publication_material ; publCIF (Westrip, 2010) ; _computing_structure_refinement ; SHELXL2018 (Sheldrick, 2015) and SHELXLE (H\"ubschle et al., 2011) ; _computing_structure_solution ; SHELXM (Sheldrick, 2008) ; _diffrn_ambient_temperature 150(2) _diffrn_detector_area_resol_mean 10.4167 _diffrn_measured_fraction_theta_full 0.999 _diffrn_measured_fraction_theta_max 0.999 _diffrn_measurement_device_type 'Bruker D8 Quest CMOS' _diffrn_measurement_method 'omega and phi scans' _diffrn_radiation_monochromator 'Triumph curved graphite crystal' _diffrn_radiation_type MoK\a _diffrn_radiation_wavelength 0.71073 _diffrn_reflns_av_R_equivalents 0.0418 _diffrn_reflns_av_unetI/netI 0.0369 _diffrn_reflns_limit_h_max 54 _diffrn_reflns_limit_h_min -54 _diffrn_reflns_limit_k_max 14 _diffrn_reflns_limit_k_min -14 _diffrn_reflns_limit_l_max 19 _diffrn_reflns_limit_l_min -17 _diffrn_reflns_number 17097 _diffrn_reflns_theta_full 25.242 _diffrn_reflns_theta_max 34.412 _diffrn_reflns_theta_min 2.776 _diffrn_source 'sealed tube X-ray source' _exptl_absorpt_coefficient_mu 1.144 _exptl_absorpt_correction_T_max 0.7468 _exptl_absorpt_correction_T_min 0.5952 _exptl_absorpt_correction_type multi-scan _exptl_absorpt_process_details ; (Krause et al., 2015) ; _exptl_crystal_colour yellow _exptl_crystal_density_diffrn 1.461 _exptl_crystal_description Plate _exptl_crystal_F_000 1896 _exptl_crystal_size_max 0.180 _exptl_crystal_size_mid 0.170 _exptl_crystal_size_min 0.050 _refine_diff_density_max 0.864 _refine_diff_density_min -0.584 _refine_ls_abs_structure_details ; Refined as an inversion twin ; _refine_ls_abs_structure_Flack 0.004(13) _refine_ls_extinction_method none _refine_ls_goodness_of_fit_ref 1.057 _refine_ls_hydrogen_treatment mixed _refine_ls_matrix_type full _refine_ls_number_parameters 120 _refine_ls_number_reflns 4166 _refine_ls_number_restraints 2 _refine_ls_restrained_S_all 1.056 _refine_ls_R_factor_all 0.0281 _refine_ls_R_factor_gt 0.0249 _refine_ls_shift/su_max 0.030 _refine_ls_shift/su_mean 0.001 _refine_ls_structure_factor_coef Fsqd _refine_ls_weighting_details 'w=1/[\s^2^(Fo^2^)+(0.0327P)^2^] where P=(Fo^2^+2Fc^2^)/3' _refine_ls_weighting_scheme calc _refine_ls_wR_factor_gt 0.0621 _refine_ls_wR_factor_ref 0.0637 _reflns_number_gt 3897 _reflns_number_total 4166 _reflns_threshold_expression 'I > 2\s(I)' _cod_data_source_file cu3157sup1.cif _cod_data_source_block 1 _cod_database_code 2021795 _shelx_space_group_comment ; The symmetry employed for this shelxl refinement is uniquely defined by the following loop, which should always be used as a source of symmetry information in preference to the above space-group names. They are only intended as comments. ; _shelx_estimated_absorpt_t_min 0.821 _shelx_estimated_absorpt_t_max 0.945 _shelx_hkl_file ; 0 2 0 0.39 0.11 0 2 0 0.55 0.11 0 -2 0 0.48 0.11 0 -2 0 0.35 0.11 0 2 0 0.39 0.13 0 4 0 897.66 44.69 0 4 0 851.33 44.67 0 6 0 0.09 0.18 0 6 0 0.00 0.20 0 -8 0 129.04 6.49 0 8 0 125.47 6.48 0 8 0 113.14 6.42 0 10 0 -0.12 0.31 0 -10 0 0.05 0.35 0 -12 0 113.40 6.27 0 12 0 116.70 6.17 0 -14 0 -0.23 0.70 0 14 0 0.87 0.64 0 0 2 0.95 0.13 0 0 -2 0.48 0.32 0 0 2 0.69 0.35 0 0 -2 0.60 0.10 0 -2 -2 132.44 6.65 0 2 2 133.83 6.68 0 -2 2 147.88 6.67 0 -2 -2 114.28 6.66 0 -2 2 143.67 6.83 0 2 2 139.79 6.88 0 2 -2 120.50 6.79 0 2 -2 120.84 6.66 0 -2 -2 115.91 6.87 0 2 -2 116.85 6.63 0 -2 2 138.60 6.63 0 4 2 -0.01 0.15 0 4 2 0.38 0.20 0 4 2 0.38 0.36 0 4 -2 0.21 0.14 0 4 -2 0.17 0.17 0 -4 -2 0.47 0.37 0 -4 2 0.01 0.26 0 4 -2 0.01 0.26 0 -4 2 0.25 0.16 0 -4 -2 -0.25 0.19 0 6 -2 11.35 0.70 0 6 2 8.23 0.72 0 6 2 8.97 0.66 0 -6 -2 8.98 0.91 0 6 -2 9.56 0.68 0 6 2 9.27 0.90 0 8 2 0.24 0.32 0 8 2 0.17 0.25 0 -8 2 0.45 0.29 0 8 -2 -0.23 0.26 0 10 -2 67.10 3.95 0 -10 2 82.66 4.02 0 -10 -2 66.69 4.03 0 10 2 73.53 3.92 0 -12 2 0.51 0.52 0 12 2 0.18 0.40 0 12 -2 0.46 0.43 0 -12 -2 0.20 0.54 0 -14 -2 13.35 1.54 0 14 2 10.91 1.53 0 -14 2 11.98 1.80 0 -14 2 9.70 1.33 0 0 -4 919.21 48.35 0 0 4 955.88 48.75 0 0 -4 915.67 48.36 0 0 -4 1000.00 48.76 0 -2 4 -0.09 0.13 0 -2 -4 0.63 0.55 0 2 4 -0.15 0.13 0 2 -4 0.06 0.42 0 -2 4 -0.13 0.41 0 2 4 -0.01 0.14 0 -4 4 143.85 7.89 0 4 4 133.47 7.62 0 4 4 149.92 7.57 0 -4 4 165.10 7.54 0 4 -4 154.83 7.90 0 -4 -4 138.44 7.96 0 4 -4 147.29 7.60 0 -4 4 140.58 7.53 0 4 4 146.74 8.01 0 -6 4 0.04 0.43 0 6 -4 0.03 0.20 0 -6 -4 -0.64 0.55 0 6 -4 -0.06 0.40 0 6 4 -0.19 0.52 0 6 4 0.17 0.19 0 -6 4 0.06 0.20 0 8 4 30.36 2.01 0 8 4 30.75 2.45 0 -8 -4 32.61 2.35 0 8 4 32.55 1.89 0 -8 4 39.02 1.94 0 8 -4 33.50 1.94 0 10 4 -0.28 0.29 0 10 4 0.01 0.05 0 -10 4 -0.12 0.38 0 10 -4 -0.20 0.32 0 -10 -4 0.36 0.42 0 -12 4 5.24 0.73 0 12 4 4.61 0.61 0 -12 -4 7.00 1.17 0 -12 4 5.63 0.72 0 -14 4 -0.50 0.58 0 -14 -4 -0.09 0.76 0 0 6 0.02 0.15 0 0 6 0.36 0.65 0 0 -6 0.08 0.66 0 0 -6 0.17 0.14 0 0 6 0.08 0.13 0 -2 6 238.10 12.72 0 2 6 236.09 12.78 0 -2 6 234.29 12.17 0 2 6 231.46 12.14 0 2 -6 243.68 12.73 0 2 6 224.52 12.18 0 -2 -6 249.44 12.81 0 4 6 0.08 0.18 0 4 -6 0.64 0.63 0 4 6 0.13 0.58 0 -4 -6 0.00 0.68 0 -4 6 -0.02 0.18 0 -4 6 0.24 0.63 0 4 6 -0.04 0.20 0 -6 -6 136.64 8.34 0 -6 6 155.86 8.26 0 6 6 155.48 8.46 0 6 6 145.15 7.85 0 -6 6 151.89 7.81 0 6 -6 144.67 8.21 0 6 6 155.40 7.74 0 8 6 0.38 0.26 0 8 6 -0.22 0.33 0 -8 6 0.50 0.29 0 -8 -6 -0.42 0.91 0 8 -6 0.25 0.58 0 -8 6 0.08 0.61 0 8 6 -0.19 0.90 0 -8 6 0.50 0.30 0 10 6 61.42 3.40 0 10 6 53.77 4.71 0 -10 6 64.59 3.42 0 -10 -6 68.14 3.67 0 -10 -6 62.61 4.15 0 -10 6 60.71 3.49 0 12 6 0.54 0.43 0 -12 6 -0.27 0.52 0 -12 -6 0.57 0.62 0 -14 -6 15.34 1.84 0 -14 6 16.96 1.54 0 0 8 505.34 26.54 0 0 -8 504.82 26.50 0 0 -8 548.61 27.37 0 0 8 546.01 27.38 0 0 -8 489.05 26.50 0 -2 -8 -0.32 0.85 0 2 8 0.72 0.83 0 -2 8 0.63 0.82 0 -2 8 0.17 0.20 0 2 -8 0.62 0.89 0 2 8 0.12 0.20 0 2 8 0.06 0.20 0 -4 8 15.70 2.02 0 4 -8 15.78 1.95 0 -4 -8 17.10 2.09 0 -4 8 15.00 0.98 0 4 8 13.19 2.04 0 4 8 14.15 0.93 0 4 8 14.30 1.02 0 6 8 0.82 1.07 0 6 -8 -0.11 0.82 0 6 8 0.07 0.23 0 -6 8 0.12 0.28 0 6 8 0.23 0.33 0 -6 8 0.45 0.89 0 -6 -8 0.48 1.04 0 -8 -8 29.45 3.07 0 -8 8 27.67 1.76 0 -8 8 25.97 2.58 0 -8 -8 29.35 1.91 0 8 8 30.00 1.68 0 -10 -8 0.36 0.51 0 10 8 -0.07 0.36 0 -10 8 -0.05 0.40 0 -12 -8 26.23 2.20 0 -12 8 31.95 2.02 0 0 10 0.09 0.23 0 0 -10 -0.60 1.00 0 0 -10 -0.34 0.18 0 0 10 1.21 1.07 0 2 10 180.16 9.16 0 -2 -10 170.68 10.23 0 -2 -10 162.01 9.16 0 2 10 186.99 10.37 0 2 -10 169.40 10.17 0 -2 10 184.32 9.20 0 -2 10 184.17 10.28 0 4 10 -0.14 0.26 0 4 10 0.07 1.22 0 -4 10 1.66 1.29 0 4 -10 -0.91 0.96 0 -4 -10 -0.81 1.15 0 -4 10 0.12 0.27 0 -4 -10 0.20 0.32 0 6 10 64.26 3.76 0 -6 10 69.98 4.91 0 6 -10 78.90 5.42 0 -6 -10 69.07 3.86 0 -6 -10 72.94 5.18 0 -6 10 65.58 3.79 0 -8 10 -0.23 0.33 0 -8 -10 -0.14 0.42 0 8 10 -0.45 0.33 0 -10 -10 30.51 3.17 0 -10 10 36.25 2.71 0 -12 10 -1.24 0.53 0 -12 -10 -0.58 0.69 0 0 -12 149.23 7.52 0 0 -12 153.62 9.07 0 0 12 138.67 7.59 0 0 12 138.63 9.01 0 -2 -12 0.55 1.45 0 2 -12 -1.76 1.37 0 -2 -12 0.21 0.28 0 -2 12 0.67 1.56 0 2 12 -0.29 0.28 0 2 12 0.02 1.49 0 -2 12 -0.46 0.27 0 -4 -12 81.47 5.56 0 -4 12 59.67 5.22 0 -4 12 64.24 3.73 0 4 12 66.59 3.67 0 -4 -12 72.43 3.76 0 4 -12 70.35 5.28 0 4 12 61.61 5.83 0 6 12 -0.05 0.32 0 -6 12 0.57 0.37 0 -6 -12 0.18 0.39 0 -8 -12 21.17 1.59 0 -8 12 18.80 1.42 0 8 12 16.51 1.26 0 -10 -12 -0.36 0.64 0 -10 12 0.15 0.50 0 0 14 -0.29 0.34 0 0 14 0.43 1.92 0 0 -14 0.87 1.96 0 -2 14 60.97 3.48 0 2 14 61.92 3.45 0 -2 -14 58.02 5.52 0 -2 14 63.75 5.74 0 2 -14 61.97 5.54 0 -2 -14 66.51 3.46 0 4 14 -0.37 0.37 0 -4 14 0.39 0.39 0 -4 -14 0.47 0.41 0 -6 14 30.80 1.97 0 6 14 31.84 1.84 0 -6 -14 27.02 1.99 0 -8 -14 -0.17 0.65 0 -8 14 -0.51 0.49 0 -10 14 31.74 2.36 0 -10 -14 39.38 2.66 0 0 16 168.72 8.90 0 2 16 -0.16 0.47 0 -2 16 -0.06 0.43 0 4 16 14.52 1.26 0 -4 16 15.22 1.29 0 -4 -16 13.43 1.31 0 -6 16 -0.05 0.50 0 -6 -16 -0.45 0.64 0 -8 16 4.11 0.80 0 -8 -16 2.54 0.89 0 0 18 0.05 0.60 0 2 18 15.80 1.54 0 -2 18 15.86 1.49 0 -4 18 0.06 0.58 0 -6 18 41.89 2.74 1 -1 1 393.96 19.49 1 -1 1 373.51 19.57 -1 -1 -1 366.35 19.49 -1 -1 -1 365.13 19.59 1 -1 -1 371.86 19.49 -1 -1 1 386.43 19.49 -1 -1 1 412.98 19.56 1 -1 -1 382.94 19.59 1 -3 1 8.57 0.60 -1 3 1 9.11 0.59 1 3 -1 10.73 0.60 1 3 -1 11.51 0.60 1 -3 1 8.30 0.70 -1 -3 -1 10.20 0.74 1 -3 1 9.68 0.59 -1 -3 -1 11.37 0.59 -1 3 1 8.79 0.79 -1 3 1 8.40 0.62 1 -3 -1 10.41 0.80 1 3 1 10.23 0.59 1 3 1 10.50 0.75 -1 3 -1 10.36 0.69 1 -3 -1 11.46 0.60 -1 -3 1 9.64 0.60 1 3 1 8.59 0.62 -1 3 -1 10.87 0.61 -1 -3 1 9.36 0.59 -1 -5 -1 143.27 7.93 -1 5 1 136.62 7.93 -1 5 1 153.34 7.91 1 5 -1 150.18 7.91 1 5 -1 172.44 7.93 -1 5 1 150.33 8.00 -1 5 -1 158.05 7.93 -1 5 -1 154.41 7.92 1 5 1 139.26 7.94 1 5 1 167.89 7.95 1 5 1 158.46 7.90 -1 7 1 14.57 0.98 1 7 -1 16.80 1.02 1 7 -1 15.29 0.97 1 -7 1 14.76 1.02 -1 7 1 13.92 1.03 1 7 1 14.86 1.04 -1 7 -1 16.74 0.99 1 7 1 13.68 0.95 -1 9 1 21.21 1.31 1 9 -1 18.31 1.29 1 -9 1 20.83 1.38 -1 9 -1 19.25 1.31 1 9 1 22.01 1.30 -1 -9 1 23.33 1.40 1 9 1 21.41 1.41 1 -9 -1 17.78 1.39 1 11 -1 10.46 0.96 -1 -11 -1 10.63 1.11 -1 11 1 12.20 0.98 1 -11 1 12.57 1.11 -1 -11 1 14.52 1.15 -1 11 -1 10.08 0.97 1 -11 -1 9.80 1.10 1 11 1 11.05 0.95 -1 13 1 10.78 1.14 1 13 -1 11.45 1.19 -1 -13 -1 8.62 1.30 1 -13 1 11.35 1.34 -1 -13 1 11.60 1.34 1 13 1 12.35 1.16 1 -13 -1 10.56 1.36 -1 13 -1 9.94 1.14 1 -1 3 9.85 0.62 1 -1 3 9.33 1.03 1 1 -3 13.19 1.10 -1 -1 -3 11.84 1.12 1 1 -3 11.99 0.63 -1 1 3 9.48 1.08 -1 -1 -3 11.63 0.60 -1 1 3 9.21 0.62 -1 -1 -3 11.74 0.63 1 -1 -3 11.48 0.63 -1 -1 3 9.62 1.04 1 1 3 9.38 0.62 1 -1 -3 11.76 1.14 1 1 3 9.43 1.07 1 -1 -3 12.06 0.62 1 1 3 9.93 0.60 -1 1 -3 11.60 1.06 -1 -1 3 9.81 0.62 -1 3 3 257.77 12.59 -1 -3 -3 260.24 12.58 1 3 -3 265.31 12.83 1 -3 3 241.51 12.56 -1 3 3 244.38 12.91 -1 3 3 223.95 12.62 1 3 -3 249.37 12.60 1 -3 3 245.48 12.83 -1 -3 -3 249.58 12.90 1 3 -3 221.74 12.55 1 3 3 246.84 12.89 1 3 3 230.19 12.62 -1 3 -3 248.89 12.82 -1 3 -3 237.16 12.60 -1 -3 3 242.23 12.81 1 -3 -3 235.86 12.88 -1 -3 3 249.19 12.56 1 -3 -3 259.56 12.59 1 3 3 255.49 12.58 1 5 -3 408.86 21.11 1 5 -3 470.96 21.25 -1 5 3 362.45 21.13 -1 -5 -3 397.91 21.35 1 -5 3 382.36 21.24 1 5 -3 436.81 21.08 -1 5 3 427.44 21.10 -1 5 3 418.61 21.41 -1 -5 3 401.45 21.22 -1 5 -3 410.63 21.11 1 5 3 425.43 21.08 1 5 3 424.44 21.38 1 5 3 369.94 21.14 -1 5 -3 440.29 21.27 1 -5 -3 397.28 21.37 1 7 -3 116.49 6.18 -1 7 3 106.97 6.21 -1 7 3 121.13 6.43 -1 -7 -3 113.89 6.37 -1 7 3 120.37 6.15 1 7 -3 133.51 6.16 1 7 3 118.71 6.38 1 7 3 107.24 6.22 1 -7 -3 111.97 6.40 -1 7 -3 120.26 6.18 1 7 3 122.90 6.14 1 -9 3 66.89 3.44 1 9 -3 57.55 3.38 -1 9 3 63.36 3.36 1 9 3 57.08 3.47 1 9 3 62.65 3.34 1 -9 -3 57.81 3.48 -1 -9 3 67.78 3.45 -1 9 -3 60.90 3.41 -1 -11 -3 2.49 0.57 -1 11 3 3.31 0.49 1 11 -3 2.79 0.52 1 -11 3 3.35 0.56 -1 -11 3 3.55 0.57 1 11 3 3.04 0.48 -1 11 -3 2.96 0.52 1 -11 -3 2.64 0.62 -1 13 3 4.36 0.67 -1 -13 -3 3.39 0.80 1 -13 3 4.55 0.78 -1 -13 3 5.24 0.79 1 -13 -3 3.95 0.81 1 13 3 4.50 0.66 -1 -13 3 4.00 0.72 1 1 -5 10.03 1.38 -1 -1 -5 10.34 1.42 -1 1 5 15.34 1.52 1 -1 5 14.53 0.81 -1 1 5 14.42 0.81 1 -1 5 14.70 1.50 -1 1 5 14.10 0.80 1 1 5 14.19 0.81 1 -1 -5 11.84 1.48 -1 -1 5 15.24 1.51 -1 1 -5 10.27 1.39 1 1 5 14.53 0.79 -1 -1 5 13.94 0.81 1 1 5 13.43 1.46 1 -3 5 90.95 5.01 1 3 -5 83.56 4.96 -1 -3 -5 84.59 5.05 1 -3 5 87.90 4.52 -1 3 5 84.17 4.54 -1 -3 -5 79.78 4.48 -1 3 5 92.82 4.50 1 3 5 84.92 4.55 1 3 5 94.80 4.49 -1 -3 5 86.91 4.52 -1 -3 5 91.01 4.99 1 -3 -5 81.49 5.02 -1 3 -5 79.95 4.94 1 -5 5 124.14 7.30 1 5 -5 127.22 6.91 -1 -5 -5 120.72 7.02 -1 5 5 133.87 7.12 -1 5 5 119.30 6.58 -1 5 5 133.56 6.52 1 5 5 137.34 6.51 1 5 5 121.24 6.59 -1 -5 5 126.71 7.12 -1 5 -5 122.63 6.90 1 -5 -5 117.60 7.01 1 5 5 127.22 7.06 -1 5 -5 122.52 6.55 -1 -5 5 122.41 6.55 -1 7 5 42.23 2.15 1 7 -5 39.68 2.44 -1 7 5 41.21 2.82 1 -7 5 36.82 2.46 1 7 -5 36.07 2.19 -1 -7 -5 34.80 2.73 -1 7 -5 37.00 2.49 1 7 5 40.46 2.81 1 -7 -5 35.92 2.79 -1 7 -5 35.18 2.19 -1 -7 5 40.82 2.20 1 7 5 38.12 2.27 -1 -7 5 40.01 2.45 1 7 5 43.24 2.14 -1 9 5 9.31 1.34 1 -9 5 10.60 0.87 -1 -9 -5 9.07 1.63 -1 9 5 9.55 0.80 1 -9 -5 10.65 1.04 1 9 5 9.90 0.80 1 9 5 10.81 1.01 -1 -9 5 9.69 0.87 -1 9 -5 11.71 0.92 1 -9 -5 8.71 1.61 1 9 5 9.44 1.28 -1 -9 5 9.51 0.87 -1 11 5 1.31 0.43 1 -11 5 2.36 0.51 1 -11 5 1.07 0.46 -1 -11 -5 2.89 0.64 -1 11 -5 2.30 0.53 1 11 5 1.44 0.41 1 -11 -5 1.88 0.61 -1 -11 5 2.27 0.52 -1 -11 5 2.42 0.51 -1 -13 -5 2.40 0.76 1 -13 5 2.04 0.64 -1 13 5 2.91 0.95 -1 -13 5 2.58 0.64 1 -13 -5 1.17 0.67 1 -1 7 128.12 6.50 -1 -1 -7 126.59 7.22 -1 1 7 131.53 7.28 1 1 -7 130.98 7.23 1 -1 7 125.30 7.20 -1 1 7 121.09 6.49 -1 -1 7 120.80 7.17 1 -1 -7 125.89 7.24 1 1 7 121.18 6.49 1 1 7 123.60 6.48 1 -1 -7 121.21 6.49 1 1 7 130.44 7.27 -1 1 -7 125.41 7.19 -1 -1 7 123.71 6.50 -1 3 7 1.80 0.29 1 -3 7 1.92 0.30 -1 -3 -7 0.88 0.76 -1 3 7 1.35 0.85 1 3 -7 1.00 0.78 -1 3 7 2.11 0.28 1 -3 7 1.22 0.80 -1 -3 7 2.15 0.82 -1 -3 7 1.73 0.27 1 3 7 1.97 0.89 -1 3 -7 0.68 0.79 1 3 7 2.04 0.27 1 -3 -7 0.03 0.69 1 3 7 2.04 0.31 -1 -5 -7 36.60 3.02 -1 5 7 38.62 2.25 1 5 -7 35.13 2.83 1 -5 7 41.09 2.96 -1 5 7 41.36 2.15 -1 5 7 43.21 3.11 1 -5 7 40.17 2.21 1 5 7 42.72 3.07 1 5 7 41.62 2.14 1 -5 -7 36.96 3.00 -1 -5 7 39.89 2.93 -1 -5 7 39.38 2.21 -1 5 -7 34.96 2.82 1 5 7 37.70 2.25 1 -7 7 21.61 2.11 1 -7 7 20.38 1.31 1 7 -7 17.90 1.94 -1 7 7 21.02 2.44 -1 7 7 21.83 1.43 -1 -7 -7 18.03 2.29 -1 7 7 21.88 1.24 1 -7 -7 16.77 1.39 -1 -7 7 21.05 2.06 -1 7 -7 17.95 1.93 1 -7 -7 17.88 2.34 1 7 7 21.74 2.38 1 7 7 20.98 1.42 -1 -7 7 20.75 1.31 1 7 7 21.18 1.22 -1 -9 -7 8.74 1.58 1 -9 7 9.09 0.88 1 -9 7 8.02 1.18 -1 -9 -7 12.55 1.13 -1 9 7 8.56 0.80 1 -9 -7 9.85 1.61 -1 -9 7 7.06 1.00 1 9 7 11.32 0.82 -1 -9 7 8.94 0.87 1 9 7 9.80 1.05 1 -9 -7 12.27 1.09 -1 11 7 19.63 1.38 1 -11 7 18.36 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8 0 0.86 0.34 -10 -8 0 0.98 0.28 10 8 0 0.85 0.35 -10 8 0 1.55 0.79 -10 8 0 0.59 0.66 10 -8 0 1.04 0.37 10 10 0 14.70 1.20 10 -10 0 13.83 1.18 -10 -10 0 15.49 1.04 -10 10 0 13.19 1.13 10 12 0 1.48 0.63 -10 12 0 0.37 0.49 -10 -12 0 1.15 0.46 10 -12 0 1.27 0.56 -10 14 0 21.13 1.72 -10 -14 0 20.47 1.88 10 -14 0 19.27 1.86 10 0 -2 64.84 3.54 -10 0 -2 72.80 3.51 10 0 -2 70.58 3.57 10 0 2 64.52 3.56 -10 0 2 66.72 3.57 10 0 2 69.69 3.51 10 0 2 63.95 3.98 10 0 -2 70.28 4.02 -10 0 -2 70.50 4.03 -10 0 -2 68.58 3.57 -10 0 2 65.48 4.01 10 2 -2 56.64 2.63 10 -2 2 48.21 3.11 10 -2 2 49.23 2.62 10 2 -2 45.82 2.59 10 2 -2 49.15 3.02 -10 2 2 50.25 2.62 -10 -2 -2 44.71 3.01 -10 2 2 49.59 3.16 -10 2 -2 48.24 2.60 -10 -2 2 54.18 3.04 10 -2 -2 45.63 3.11 10 -2 -2 48.81 2.65 -10 2 -2 49.11 3.12 10 2 2 48.40 2.64 -10 -2 2 51.91 2.59 -10 2 -2 48.28 2.62 10 4 -2 240.47 11.94 -10 4 2 229.19 12.41 -10 -4 -2 259.18 12.30 -10 4 2 236.98 11.95 10 -4 2 211.69 12.34 10 -4 2 234.43 11.95 -10 4 -2 219.55 11.94 -10 -4 2 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0.04 0.12 -10 0 4 0.01 0.60 10 0 4 0.15 0.12 -10 0 4 0.15 0.18 10 0 -4 0.07 0.18 -10 0 -4 0.82 0.60 -10 0 4 -0.10 0.22 10 0 4 0.05 0.17 -10 0 -4 0.02 0.21 10 2 -4 229.82 11.27 10 2 -4 214.71 10.71 -10 2 4 205.23 10.73 -10 2 4 200.40 11.28 10 -2 4 205.19 10.71 -10 -2 -4 212.47 11.26 10 -2 4 204.16 11.27 10 2 4 205.63 10.76 -10 2 -4 221.58 10.72 10 2 4 198.85 11.22 -10 2 -4 206.76 10.71 -10 2 -4 212.83 11.28 -10 -2 4 196.00 11.14 10 -2 -4 214.10 10.77 10 -2 -4 211.72 11.31 -10 -2 4 193.74 10.71 10 -4 4 0.61 0.21 10 -4 4 0.22 0.56 -10 4 4 0.57 0.22 -10 -4 -4 0.82 0.61 10 4 -4 0.83 0.19 10 4 4 0.43 0.57 10 4 4 0.70 0.26 -10 -4 4 1.33 0.58 -10 -4 4 0.77 0.20 10 -4 -4 0.97 0.28 10 -4 -4 -0.01 0.65 -10 4 -4 0.47 0.21 -10 4 -4 0.34 0.64 -10 6 4 49.79 3.11 -10 6 4 50.85 3.62 -10 -6 -4 56.89 3.50 10 -6 4 54.46 2.97 10 6 -4 56.14 2.96 -10 6 -4 57.89 3.56 10 6 4 55.84 3.53 10 -6 -4 58.65 3.09 10 -6 -4 55.92 3.68 -10 6 -4 59.89 3.02 -10 -6 4 48.27 2.95 10 6 4 50.80 3.05 -10 -6 4 60.78 3.31 10 8 -4 19.46 1.18 -10 8 4 17.80 1.21 -10 8 4 18.05 2.15 10 -8 4 18.32 1.21 -10 -8 -4 17.26 1.71 -10 8 4 16.93 2.18 10 8 4 18.43 2.04 -10 -8 4 16.75 1.15 -10 8 -4 17.55 1.23 10 8 4 16.51 1.31 -10 8 -4 18.92 1.83 10 -8 -4 18.04 1.32 -10 10 4 42.13 3.76 -10 10 4 52.83 2.91 10 -10 4 50.28 2.89 10 -10 -4 54.82 3.06 10 10 4 49.53 3.03 -10 10 -4 55.15 2.96 -10 -10 4 48.07 2.84 -10 10 -4 50.60 2.96 10 -12 4 3.53 0.66 -10 12 4 3.06 0.63 10 12 4 3.79 0.91 -10 -12 4 2.69 0.58 -10 -12 4 4.29 0.71 -10 12 -4 4.63 1.17 10 -12 -4 2.75 0.83 -10 -14 -4 5.88 1.06 -10 14 4 5.47 0.86 -10 -14 4 6.30 0.92 -10 14 -4 6.68 0.95 10 -14 -4 6.42 1.07 10 0 6 243.93 12.42 10 0 6 251.37 13.19 10 0 -6 240.84 13.15 10 0 6 249.48 12.46 -10 0 6 230.57 12.46 -10 0 6 242.04 13.16 -10 0 -6 235.31 13.14 10 0 -6 243.50 12.46 10 2 -6 8.17 1.50 -10 2 6 7.71 0.61 10 2 -6 6.92 0.53 10 -2 6 6.69 1.13 -10 -2 -6 6.70 1.19 -10 2 6 6.90 1.18 10 -2 6 8.26 0.53 -10 2 -6 7.01 0.55 -10 2 -6 7.64 0.56 -10 2 -6 7.73 1.28 10 -2 -6 6.63 1.17 -10 -2 6 8.74 1.49 -10 -2 6 6.94 0.57 10 -2 -6 7.37 0.62 10 2 6 7.82 0.62 10 2 6 7.89 1.27 -10 -2 6 8.96 0.59 10 4 -6 149.85 7.82 10 4 -6 136.96 7.08 10 -4 6 136.96 7.09 10 -4 6 130.07 8.31 -10 4 6 139.40 7.97 -10 -4 -6 130.23 8.11 -10 4 6 135.19 7.15 10 -4 -6 141.53 7.22 10 4 6 133.60 7.21 -10 4 -6 140.51 7.16 10 -4 -6 137.94 7.93 -10 -4 6 129.90 7.68 -10 4 -6 132.71 7.08 -10 -4 6 131.93 7.15 -10 4 -6 132.34 7.82 -10 -4 6 153.92 7.10 -10 6 6 24.37 2.52 10 6 -6 22.67 1.37 10 -6 6 24.96 1.41 -10 -6 -6 23.48 2.39 10 -6 6 24.56 2.30 -10 6 6 27.42 1.50 10 6 -6 25.17 2.19 10 -6 -6 22.12 2.43 10 -6 -6 23.96 1.57 10 6 6 25.32 2.36 -10 -6 6 23.29 1.46 -10 -6 6 24.06 2.14 10 6 6 25.03 1.58 -10 6 -6 25.00 1.50 -10 6 -6 23.35 2.26 10 -8 6 49.64 2.50 -10 -8 -6 42.16 3.34 -10 8 6 50.15 2.56 10 -8 6 43.64 3.29 10 8 -6 40.86 2.44 -10 8 6 46.83 3.63 -10 8 -6 38.31 3.29 -10 -8 6 46.30 2.86 -10 -8 6 45.60 2.54 10 8 6 46.08 3.54 -10 -8 6 45.74 2.89 10 8 6 48.47 2.71 10 -8 -6 39.85 3.57 -10 8 -6 42.74 2.58 10 -8 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8.54 0.75 10 4 8 8.28 1.48 10 -6 8 209.83 11.36 -10 -6 -8 201.46 11.36 -10 6 8 211.07 10.40 10 6 -8 206.50 11.19 10 -6 -8 198.77 10.50 10 6 8 198.06 11.33 -10 -6 8 197.97 10.41 10 -6 -8 178.90 11.46 10 6 8 200.71 10.50 -10 6 -8 198.09 10.42 -10 -6 8 198.18 11.09 -10 6 -8 195.67 11.24 -10 8 8 10.28 0.88 10 -8 -8 10.86 1.07 10 8 8 9.98 1.06 -10 8 -8 10.19 0.94 -10 -8 8 9.22 0.89 -10 10 8 7.78 0.87 10 10 8 6.68 1.14 -10 -10 8 6.31 0.90 -10 10 -8 4.41 0.72 10 -10 -8 6.07 0.87 -10 12 8 1.82 0.64 10 -12 8 1.70 0.66 -10 -12 8 2.18 0.64 10 -12 -8 1.66 0.80 10 12 8 1.88 0.80 10 0 10 54.78 3.04 10 0 10 55.41 4.44 -10 0 -10 63.96 4.54 10 0 -10 64.55 4.49 10 0 10 53.57 3.04 -10 0 10 51.73 3.10 -10 0 10 53.55 4.37 10 0 -10 61.59 3.07 -10 -2 -10 2.93 1.35 10 -2 10 3.42 0.50 10 2 -10 6.05 1.49 -10 2 10 4.32 1.50 10 -2 10 3.83 1.35 -10 2 10 2.99 0.44 -10 -2 10 1.31 1.41 10 -2 -10 3.43 0.45 10 2 10 2.74 0.41 10 2 10 4.94 1.47 -10 -2 10 2.55 0.41 -10 2 -10 2.90 1.39 10 -2 -10 3.93 1.43 -10 4 10 30.72 3.43 10 -4 10 29.20 1.71 10 4 -10 23.50 3.07 -10 4 10 29.34 1.72 -10 -4 -10 26.13 3.12 10 -4 10 32.57 3.31 10 4 10 28.53 3.18 10 4 10 29.95 1.78 10 -4 -10 27.27 3.21 10 -4 -10 26.57 1.76 -10 -4 10 30.54 1.74 -10 -4 10 28.62 3.09 -10 4 -10 23.82 3.03 10 -6 10 0.98 1.33 10 -6 10 2.97 0.47 -10 6 10 2.31 0.43 10 6 10 2.95 0.54 -10 -6 10 2.41 0.45 -10 -6 10 1.19 1.68 10 -6 -10 0.60 2.03 10 -6 -10 3.28 0.55 10 -8 10 9.30 0.95 -10 8 10 7.50 0.89 -10 -8 10 10.37 0.97 10 -8 -10 12.17 1.17 10 8 10 9.49 1.14 -10 10 10 3.20 0.62 10 -10 10 2.36 0.59 10 -10 -10 2.41 0.75 10 10 10 3.16 0.78 -10 -12 -10 18.43 1.89 10 -12 10 15.95 1.54 10 -12 -10 18.84 1.91 -10 -12 10 14.42 1.56 10 0 12 -1.03 1.55 -10 0 -12 -0.76 1.51 10 0 -12 0.17 0.28 10 0 12 0.24 0.27 -10 0 12 -0.42 1.74 10 0 -12 -0.29 1.58 -10 0 12 -0.22 0.32 10 0 12 0.49 0.28 -10 2 12 80.39 4.53 -10 2 12 85.89 6.44 10 -2 12 79.05 6.11 10 -2 12 83.12 4.50 -10 -2 -12 84.91 6.33 10 2 -12 82.11 6.04 10 2 12 85.34 4.52 -10 -2 12 88.19 6.25 10 2 12 80.74 6.27 -10 -2 12 83.07 4.56 10 2 12 80.97 4.44 10 -2 -12 90.52 4.54 -10 2 -12 88.60 6.18 10 -4 12 16.24 2.57 -10 4 12 16.16 1.17 10 -4 12 16.32 1.14 10 -4 -12 15.72 1.20 -10 -4 12 13.13 2.28 -10 -4 12 16.64 1.21 -10 4 -12 13.82 2.73 10 4 12 15.66 1.19 10 -4 -12 16.28 2.74 -10 6 12 9.05 0.89 10 -6 12 9.83 0.93 10 6 12 10.27 1.03 -10 -6 12 8.90 0.96 10 -8 12 0.81 0.48 -10 8 12 0.86 0.46 10 -8 -12 0.78 0.60 -10 -8 12 0.14 0.47 10 8 12 1.11 0.60 10 -10 12 25.42 1.96 -10 10 12 29.55 1.94 10 10 12 28.56 2.21 -10 -10 12 26.07 1.97 10 -10 -12 29.61 2.22 10 0 14 65.18 5.72 10 0 14 62.65 3.34 -10 0 14 61.30 5.84 -10 0 -14 66.94 5.96 -10 0 14 62.49 3.43 10 0 -14 56.11 5.71 10 0 -14 54.00 3.51 10 -2 14 -0.73 2.27 -10 2 14 0.58 0.43 10 -2 14 0.52 0.36 -10 2 -14 1.51 2.18 10 -2 -14 0.92 0.43 -10 -2 14 0.32 0.43 10 2 14 -0.05 0.38 10 2 14 0.69 0.38 -10 -2 14 -0.56 2.20 10 -4 14 69.36 3.84 -10 4 14 66.70 3.84 -10 -4 14 68.89 3.90 10 -4 -14 71.28 3.90 10 4 14 69.16 3.87 -10 6 14 3.29 0.61 10 -6 14 3.34 0.61 10 -6 -14 3.97 0.70 10 6 14 3.79 0.69 -10 -6 14 2.80 0.67 -10 8 14 43.42 2.66 10 -8 14 43.49 2.70 -10 -8 14 41.34 2.70 10 8 14 45.60 2.86 10 -8 -14 42.98 2.84 -10 -10 -14 1.23 0.85 10 -10 14 1.92 0.70 -10 -10 14 1.38 0.69 10 -10 -14 2.30 0.89 -10 0 16 0.54 0.52 10 0 16 0.29 0.46 -10 2 16 9.09 1.10 10 -2 16 7.05 0.94 -10 -2 16 7.53 1.06 10 -4 16 3.76 0.67 -10 4 16 4.50 0.72 -10 -4 -16 3.01 0.71 -10 -4 16 3.81 0.72 10 -4 -16 3.82 0.75 -10 6 16 33.89 2.18 -10 -6 -16 26.31 3.06 10 -6 16 33.09 2.15 10 -6 -16 31.23 2.91 -10 -6 16 32.41 2.20 -10 -8 -16 2.13 0.89 10 -8 16 3.17 0.76 10 -8 -16 5.06 1.02 -10 -8 16 2.83 0.76 -10 0 18 24.62 1.93 -10 2 18 0.02 0.69 -10 -2 18 -0.21 0.61 10 -4 18 3.20 0.74 -10 4 18 1.74 0.75 -10 -4 18 2.80 0.77 11 1 -1 12.46 0.72 -11 1 1 9.93 1.37 -11 1 1 8.98 1.26 11 -1 1 10.67 0.72 -11 -1 -1 13.01 1.26 -11 1 1 10.42 0.68 11 -1 1 9.63 1.31 11 -1 -1 12.41 0.73 -11 1 -1 12.55 1.37 -11 -1 1 10.39 0.73 11 1 1 10.43 1.35 -11 1 -1 11.77 0.74 -11 -1 1 9.54 1.25 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6 -4 14.54 0.99 -14 6 4 14.28 1.04 -14 6 4 12.63 1.90 14 -6 4 13.91 1.01 14 -6 4 12.49 1.82 -14 -6 4 13.92 1.03 14 -6 -4 16.35 1.13 14 6 4 14.95 1.93 -14 -6 4 16.55 1.62 -14 6 -4 17.81 1.98 -14 -6 4 17.32 1.63 -14 6 -4 16.47 1.06 14 6 4 14.89 1.12 -14 8 4 2.38 1.20 -14 8 4 3.64 0.51 14 8 -4 2.53 0.49 -14 -8 -4 2.57 0.93 14 -8 4 2.24 0.50 -14 8 4 3.20 1.13 -14 -8 4 3.08 0.51 -14 -8 4 4.06 0.56 14 8 4 3.51 1.28 -14 8 -4 3.04 0.49 14 8 4 3.12 0.54 -14 8 -4 3.27 0.98 14 -8 -4 2.49 0.54 14 -10 4 33.32 2.15 14 10 -4 40.73 2.17 -14 10 4 33.60 2.17 14 10 4 31.21 2.27 14 -10 -4 32.53 2.27 -14 -10 4 39.58 2.11 -14 10 -4 35.38 2.21 14 -12 4 0.00 0.55 -14 12 4 0.46 0.55 14 12 -4 0.51 0.60 14 -12 -4 1.11 0.65 14 12 4 0.28 0.66 -14 -12 4 0.85 0.50 -14 12 -4 0.38 0.59 -14 14 4 1.32 0.73 14 14 4 2.54 0.95 -14 14 -4 3.24 0.84 14 -14 -4 1.80 0.90 -14 -14 4 2.71 0.78 -14 0 -6 67.81 4.63 14 0 6 75.38 4.74 14 0 6 76.27 3.86 14 0 6 77.92 3.78 14 0 -6 67.55 3.84 -14 0 6 71.18 3.84 14 0 -6 67.70 4.66 -14 0 6 75.38 4.70 -14 -2 -6 3.24 0.99 -14 2 6 2.73 0.98 14 -2 6 2.91 0.38 14 2 -6 2.53 0.32 -14 2 6 2.39 0.35 14 -2 6 2.70 1.06 14 2 6 2.21 0.36 14 -2 -6 3.17 1.05 14 -2 -6 2.81 0.47 -14 -2 6 3.45 1.04 -14 2 -6 2.36 0.30 -14 -2 6 2.87 0.40 14 2 6 1.98 0.91 -14 2 -6 1.42 0.85 14 4 -6 173.40 8.84 -14 4 6 164.59 9.77 -14 -4 -6 176.19 9.69 14 4 -6 194.50 9.70 -14 4 6 163.70 8.90 14 -4 6 166.25 8.85 14 -4 6 162.89 9.67 14 -4 -6 169.78 9.76 -14 4 -6 174.30 9.73 -14 -4 6 161.02 9.48 14 4 6 171.75 8.96 14 -4 -6 173.54 8.97 14 6 -6 1.96 0.93 -14 -6 -6 1.62 0.93 14 -6 6 2.10 1.10 14 -6 6 1.54 0.34 -14 6 6 1.86 1.02 14 6 -6 1.54 0.30 -14 6 6 1.53 0.35 14 -6 -6 1.55 0.43 -14 6 -6 1.46 0.98 14 6 6 0.86 1.03 -14 -6 6 1.10 0.85 14 -6 -6 1.39 1.15 -14 -6 6 1.22 0.32 14 6 6 1.40 0.40 -14 6 -6 1.35 0.36 -14 8 6 62.52 3.36 14 -8 6 62.33 3.30 14 -8 6 56.46 4.53 -14 -8 -6 56.43 4.20 14 8 -6 55.61 3.25 -14 -8 6 60.37 3.32 14 -8 -6 58.07 3.47 -14 8 -6 59.67 3.38 14 8 6 61.32 4.40 -14 -8 6 60.47 3.81 14 8 6 61.37 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53.67 3.06 30 -6 4 53.67 3.11 -30 6 -4 53.33 3.05 30 6 4 52.84 3.17 -30 -6 4 60.53 2.97 30 -6 -4 50.46 3.17 30 -8 4 22.82 1.64 -30 8 4 21.00 1.61 30 8 -4 22.82 1.65 -30 8 -4 19.46 1.61 30 8 4 21.53 1.78 -30 -8 4 23.02 1.47 30 -8 -4 20.90 1.77 -30 10 4 2.60 0.70 30 -10 4 3.52 0.79 30 10 -4 1.22 0.70 30 -10 -4 1.58 0.76 -30 10 -4 1.93 0.64 30 10 4 2.86 0.79 -30 12 4 0.43 0.74 30 -12 4 0.10 0.97 30 12 4 0.67 0.86 -30 12 -4 -0.38 0.68 30 -12 -4 0.52 0.83 30 0 6 87.87 4.93 -30 0 6 88.42 6.57 -30 0 6 83.31 6.43 -30 0 6 88.62 4.85 -30 0 -6 98.32 6.79 30 0 -6 93.49 4.96 30 0 6 93.08 6.70 30 -2 6 19.89 1.43 30 2 -6 21.11 1.47 -30 -2 -6 19.09 3.23 -30 2 6 22.53 3.49 -30 2 6 17.15 2.77 -30 2 6 21.64 1.40 30 -2 6 20.25 3.75 30 2 6 17.85 2.71 30 -2 -6 21.06 1.51 -30 -2 6 24.37 3.37 -30 2 -6 22.85 1.31 -30 -2 6 21.92 3.38 30 2 6 20.55 1.47 -30 -2 6 20.17 1.39 -30 2 -6 21.08 3.55 30 -4 6 81.69 4.42 -30 4 6 79.03 4.38 30 -4 6 76.05 6.34 -30 4 6 75.38 6.07 30 4 -6 81.11 4.40 -30 4 -6 81.83 4.33 -30 -4 6 79.72 4.33 -30 4 -6 84.86 6.47 30 4 6 80.14 4.48 30 -4 -6 81.93 4.50 -30 -4 6 75.00 5.81 -30 6 6 10.20 1.04 30 -6 6 9.77 1.04 30 6 -6 10.95 1.02 30 6 6 10.89 1.16 30 -6 -6 11.61 1.22 -30 6 -6 12.16 0.99 -30 -6 6 10.67 0.98 30 8 -6 65.51 3.57 -30 8 6 55.95 3.56 30 -8 6 60.36 3.56 -30 -8 6 67.14 3.48 30 8 6 58.87 3.70 30 -8 -6 64.11 3.78 -30 8 -6 60.00 3.57 -30 10 6 1.42 0.65 30 -10 6 1.58 0.72 30 -10 -6 1.28 0.76 -30 10 -6 1.77 0.67 -30 -10 6 0.96 0.61 30 10 6 2.02 0.76 30 0 -8 0.42 0.40 -30 0 -8 -0.91 1.76 -30 0 8 0.41 1.86 30 0 8 0.48 0.39 30 0 8 0.47 2.61 -30 0 8 -0.18 0.37 -30 2 8 16.75 2.91 -30 -2 -8 19.21 3.27 30 -2 8 21.86 1.45 30 -2 8 16.37 2.94 30 2 -8 20.16 1.44 -30 2 8 21.73 1.44 -30 -2 8 15.00 2.65 30 -2 -8 20.91 1.51 30 2 8 21.52 1.50 -30 -2 8 22.83 1.45 -30 2 -8 21.33 1.32 -30 2 -8 23.64 3.88 -30 4 8 8.48 2.70 -30 4 8 11.38 1.03 30 -4 8 10.98 1.02 30 4 -8 10.94 1.00 30 -4 8 14.02 3.05 30 4 8 10.74 1.11 30 -4 -8 10.74 1.15 -30 4 -8 11.89 0.95 -30 -4 8 10.30 1.00 -30 6 8 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2 0 4.31 0.94 -50 2 0 4.39 0.73 50 -2 0 2.86 0.90 50 4 0 0.44 0.78 -50 4 0 0.47 0.62 50 -4 0 0.34 0.80 -50 6 0 0.65 0.70 50 6 0 -0.05 0.83 50 -6 0 0.53 0.84 -50 0 2 30.85 2.07 50 0 -2 33.83 2.42 50 0 2 31.25 2.39 50 2 -2 0.61 0.73 -50 2 2 0.38 0.58 50 -2 2 -0.58 0.67 50 2 2 1.24 0.79 -50 2 -2 1.87 0.59 50 -2 -2 -0.25 0.71 50 -4 2 27.49 2.37 50 4 -2 31.68 2.42 -50 4 2 29.20 2.10 50 4 2 30.05 2.46 -50 4 -2 32.96 2.16 50 -4 -2 33.95 2.49 -50 6 2 1.54 0.73 50 -6 2 1.91 0.89 50 6 -2 1.63 0.95 50 6 2 1.40 0.91 -50 6 -2 3.01 0.76 50 -6 -2 1.77 0.96 50 0 4 -0.30 0.69 -50 0 4 -0.28 0.58 50 0 -4 -0.25 0.75 -50 2 4 0.59 0.61 50 -2 4 -0.55 0.69 50 2 -4 1.12 0.76 50 -2 -4 0.90 0.76 50 2 4 0.98 0.81 -50 -2 4 1.29 0.61 -50 4 4 2.01 0.70 50 4 -4 2.20 0.88 50 -4 4 3.41 0.91 50 -4 -4 2.06 0.91 -50 4 -4 2.70 0.74 50 4 4 3.02 0.96 50 0 -6 18.69 1.87 -50 0 6 17.75 1.53 50 0 6 17.48 1.81 50 2 -6 0.73 0.81 -50 2 6 1.46 0.66 50 -2 6 1.84 0.81 50 2 6 2.38 0.84 50 -2 -6 1.98 0.87 -50 -2 6 -0.24 0.61 50 4 -6 8.02 1.20 50 -4 6 10.50 1.52 -50 4 6 7.55 0.99 50 4 6 8.94 1.25 50 -4 -6 7.28 1.24 50 0 -8 -1.26 0.78 50 0 8 -1.40 0.80 -50 0 8 0.38 0.67 -51 1 1 11.37 1.22 51 1 -1 10.79 1.52 51 -1 1 11.44 1.51 51 1 1 12.36 1.56 -51 1 -1 11.20 1.38 51 -1 -1 11.67 1.57 51 -3 1 10.72 1.56 51 3 -1 9.89 1.53 -51 3 1 8.03 1.24 -51 3 -1 11.85 1.25 51 -3 -1 10.06 1.55 51 3 1 9.89 1.52 51 5 -1 2.81 0.91 -51 5 1 1.93 0.74 51 -5 1 1.56 0.86 51 5 1 1.36 0.90 -51 5 -1 1.53 0.72 51 -5 -1 3.18 0.98 51 1 -3 4.39 0.95 51 -1 3 4.44 0.97 -51 1 3 5.62 0.78 51 1 3 6.09 1.06 51 -1 -3 4.53 1.02 -51 -1 3 6.15 0.77 51 -3 3 4.15 0.97 51 3 -3 4.47 0.96 -51 3 3 4.00 0.75 51 -3 -3 5.02 1.05 -51 3 -3 4.06 0.85 51 3 3 4.12 0.96 51 5 -3 9.85 1.67 -51 5 3 10.29 1.15 51 -5 3 10.58 1.62 -51 5 -3 11.48 1.43 51 5 3 14.67 1.78 51 -5 -3 12.09 1.85 -51 1 5 2.19 0.71 51 1 -5 4.44 0.92 51 -1 5 1.56 0.85 -51 -1 5 1.22 0.68 51 -1 -5 4.05 0.96 51 1 5 3.24 0.92 -51 3 5 4.77 0.82 51 3 -5 3.30 0.93 51 -3 5 4.20 0.94 51 -3 -5 2.01 0.96 51 3 5 5.78 1.02 51 -1 7 13.93 1.75 51 1 -7 16.98 1.80 -51 1 7 14.60 1.49 51 -1 -7 15.98 1.77 51 1 7 14.96 1.77 -51 -1 7 13.29 1.48 52 0 0 59.69 3.79 -52 2 0 3.17 0.72 52 2 0 2.85 0.91 52 -2 0 1.98 0.83 52 4 0 14.93 1.80 -52 4 0 16.14 1.54 52 -4 0 16.73 1.84 52 0 -2 0.67 0.84 52 0 2 0.31 0.76 52 -2 2 11.79 1.58 52 2 -2 10.16 1.53 -52 2 2 9.25 1.20 52 2 2 11.11 1.53 52 -2 -2 6.59 1.14 52 -4 2 -0.99 0.78 -52 4 2 0.71 0.70 52 4 -2 0.42 0.83 52 -4 -2 0.10 0.83 -52 4 -2 -0.65 0.67 52 4 2 0.10 0.82 52 0 4 1.40 0.80 52 0 -4 0.38 0.77 -52 0 4 0.15 0.61 -52 2 4 2.66 0.71 52 2 -4 3.37 0.93 52 -2 4 2.27 0.90 52 2 4 3.46 0.96 52 -2 -4 3.08 0.92 52 0 6 -0.29 0.76 -52 0 6 -1.07 0.62 52 0 -6 -0.27 0.81 -53 1 1 5.45 0.78 53 -1 1 3.67 1.01 53 1 -1 4.36 1.00 53 -1 -1 4.97 1.04 53 1 1 4.70 1.02 53 3 -1 1.20 0.84 -53 3 1 1.38 0.69 53 -3 1 0.91 0.84 53 3 1 1.77 0.90 53 -3 -1 1.56 0.85 -53 3 -1 1.66 0.70 53 -1 3 4.91 1.01 53 1 -3 6.58 1.08 -53 1 3 4.54 0.76 53 -1 -3 4.45 1.05 53 1 3 5.53 1.08 53 -3 3 10.84 1.64 53 3 -3 9.67 1.60 -53 3 3 10.16 1.30 53 3 3 7.95 1.25 53 -3 -3 8.51 1.25 53 -1 5 10.37 1.57 -53 1 5 8.49 1.00 53 1 -5 9.10 1.53 53 -1 -5 6.93 1.24 53 1 5 7.99 1.21 -53 -1 5 7.67 0.94 54 0 0 1.02 0.77 54 -2 0 8.24 1.24 -54 2 0 8.37 1.01 54 2 0 8.61 1.24 54 0 -2 15.81 1.83 54 0 2 16.18 1.85 -54 2 2 2.66 0.74 54 2 -2 3.49 1.01 54 -2 2 3.81 0.96 54 -2 -2 3.30 0.96 54 2 2 2.47 0.90 0 0 0 0.00 0.00 ; _shelx_hkl_checksum 29991 _shelx_res_file ; TITL RAC1027 in Fdd2 RAC1027_0m.res created by SHELXL-2018/3 at 11:36:15 on 05-Oct-2019 CELL 0.71073 34.5658 9.3832 12.5209 90.000 90.000 90.000 ZERR 8.00 0.0016 0.0004 0.0006 0.000 0.000 0.000 LATT -4 SYMM -X, -Y, Z SYMM 0.25+X, 0.25-Y, 0.25+Z SYMM 0.25-X, 0.25+Y, 0.25+Z SFAC C H N CL FE UNIT 128 288 32 24 8 LIST 6 ! automatically inserted. Change 6 to 4 for CHECKCIF!! TEMP -123.140 SIZE 0.05 0.17 0.18 L.S. 4 BOND $H ACTA CONF HTAB EQIV $2 x, y+1/2, z+1/2 HTAB N1 Cl2_$2 HTAB N2 Cl2 FMAP 2 PLAN 20 OMIT 4 0 0 TWIN SADI N1 H1 N2 H2 WGHT 0.032700 BASF 0.00381 FVAR 0.07220 FE1 5 0.000000 0.500000 0.471765 10.50000 0.01000 0.01121 = 0.00952 0.00000 0.00000 0.00018 CL1 4 0.040661 0.593993 0.599723 11.00000 0.01758 0.02242 = 0.01340 -0.00439 -0.00299 -0.00021 N1 3 -0.019799 0.719840 0.437645 11.00000 0.01123 0.01336 = 0.01142 -0.00110 -0.00017 0.00094 REM AFIX 13 H1 2 -0.009983 0.760008 0.492982 11.00000 -1.20000 REM AFIX 0 N2 3 0.043596 0.556778 0.350093 11.00000 0.01084 0.01146 = 0.01156 0.00033 -0.00053 0.00009 REM AFIX 13 H2 2 0.035245 0.532676 0.289665 11.00000 -1.20000 REM AFIX 0 C1 1 0.002320 0.768059 0.342772 11.00000 0.01357 0.01204 = 0.01612 0.00245 0.00199 0.00178 AFIX 23 H1A 2 0.002287 0.873496 0.339879 11.00000 -1.20000 H1AB 2 -0.010308 0.732065 0.277130 11.00000 -1.20000 AFIX 0 C2 1 0.043568 0.714669 0.347260 11.00000 0.01305 0.01124 = 0.01798 0.00134 0.00095 -0.00084 AFIX 23 H2A 2 0.057976 0.748405 0.283775 11.00000 -1.20000 H2AB 2 0.056538 0.752492 0.411806 11.00000 -1.20000 MOLE 2 AFIX 0 C3 1 0.083204 0.496284 0.365082 11.00000 0.01009 0.01507 = 0.01380 0.00177 0.00060 0.00027 AFIX 13 H3 2 0.091517 0.515461 0.440218 11.00000 -1.20000 AFIX 0 C4 1 0.082778 0.334652 0.347884 11.00000 0.01258 0.01500 = 0.01593 0.00064 0.00303 0.00200 AFIX 23 H4A 2 0.070712 0.315941 0.277559 11.00000 -1.20000 H4AB 2 0.109969 0.302072 0.343351 11.00000 -1.20000 AFIX 0 C5 1 0.062166 0.241625 0.430604 11.00000 0.01147 0.01341 = 0.01375 0.00142 0.00063 0.00285 C6 1 0.113268 0.561510 0.289657 11.00000 0.01416 0.01938 = 0.02437 0.00512 0.00567 0.00100 AFIX 137 H6A 2 0.105473 0.544654 0.215473 11.00000 -1.50000 H6B 2 0.138525 0.517310 0.302598 11.00000 -1.50000 H6C 2 0.115042 0.664296 0.302647 11.00000 -1.50000 AFIX 0 C7 1 0.079631 0.257889 0.541834 11.00000 0.01811 0.02019 = 0.01652 0.00183 -0.00419 0.00212 AFIX 137 H7A 2 0.107197 0.233676 0.539414 11.00000 -1.50000 H7B 2 0.066338 0.193831 0.591581 11.00000 -1.50000 H7C 2 0.076579 0.356608 0.565959 11.00000 -1.50000 AFIX 0 C8 1 0.067053 0.084182 0.397810 11.00000 0.01746 0.01401 = 0.02104 0.00079 0.00167 0.00498 AFIX 137 H8A 2 0.059364 0.072337 0.322999 11.00000 -1.50000 H8B 2 0.050716 0.024097 0.443246 11.00000 -1.50000 H8C 2 0.094184 0.056091 0.406353 11.00000 -1.50000 AFIX 0 CL2 4 0.000000 0.500000 0.119776 10.50000 0.02668 0.02260 = 0.01375 0.00000 0.00000 -0.00696 HKLF 4 REM RAC1027 in Fdd2 REM wR2 = 0.0637, GooF = S = 1.057, Restrained GooF = 1.056 for all data REM R1 = 0.0249 for 3897 Fo > 4sig(Fo) and 0.0281 for all 4166 data REM 120 parameters refined using 2 restraints END WGHT 0.0326 0.0000 REM Instructions for potential hydrogen bonds HTAB N1 Cl1 HTAB N1 Cl2_$2 HTAB N2 Cl2 EQIV $3 -x, -y+3/2, z-1/2 HTAB C1 Cl1_$3 HTAB C1 Cl2 HTAB C2 Cl1 HTAB C3 Cl1 EQIV $4 x, y-1/2, z+1/2 HTAB C7 Cl2_$4 HTAB C7 Cl1 EQIV $5 x, y-1/2, z-1/2 HTAB C8 Cl1_$5 HTAB C8 Cl2_$4 REM Highest difference peak 0.864, deepest hole -0.584, 1-sigma level 0.070 Q1 1 0.0000 0.5000 0.5325 10.50000 0.05 0.86 Q2 1 0.0000 0.5000 0.4128 10.50000 0.05 0.83 Q3 1 0.0362 0.5861 0.5437 11.00000 0.05 0.53 Q4 1 0.0000 0.5000 0.0589 10.50000 0.05 0.52 Q5 1 0.0399 0.5922 0.6618 11.00000 0.05 0.49 Q6 1 0.0678 0.2427 0.4859 11.00000 0.05 0.38 Q7 1 0.0000 0.5000 0.1797 10.50000 0.05 0.37 Q8 1 0.0237 0.5559 0.4938 11.00000 0.05 0.30 Q9 1 0.0000 0.5000 0.5981 10.50000 0.05 0.30 Q10 1 0.0412 0.5948 0.2449 11.00000 0.05 0.29 Q11 1 0.0000 0.5000 0.2356 10.50000 0.05 0.28 Q12 1 -0.0158 0.7239 0.3840 11.00000 0.05 0.26 Q13 1 0.0407 0.4161 0.6041 11.00000 0.05 0.26 Q14 1 0.0455 0.0649 0.2199 11.00000 0.05 0.26 Q15 1 0.0395 0.5636 0.4060 11.00000 0.05 0.26 Q16 1 0.0125 0.5208 0.6441 11.00000 0.05 0.25 Q17 1 0.0172 0.5394 0.5831 11.00000 0.05 0.25 Q18 1 0.0017 0.8114 0.2201 11.00000 0.05 0.24 Q19 1 0.0419 0.6045 0.4896 11.00000 0.05 0.23 Q20 1 0.0442 0.6239 0.3537 11.00000 0.05 0.23 ; _shelx_res_checksum 82934 loop_ _space_group_symop_operation_xyz 'x, y, z' '-x, -y, z' 'x+1/4, -y+1/4, z+1/4' '-x+1/4, y+1/4, z+1/4' 'x, y+1/2, z+1/2' '-x, -y+1/2, z+1/2' 'x+1/4, -y+3/4, z+3/4' '-x+1/4, y+3/4, z+3/4' 'x+1/2, y, z+1/2' '-x+1/2, -y, z+1/2' 'x+3/4, -y+1/4, z+3/4' '-x+3/4, y+1/4, z+3/4' 'x+1/2, y+1/2, z' '-x+1/2, -y+1/2, z' 'x+3/4, -y+3/4, z+1/4' '-x+3/4, y+3/4, z+1/4' loop_ _atom_site_type_symbol _atom_site_label _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_U_iso_or_equiv _atom_site_adp_type _atom_site_calc_flag _atom_site_occupancy Fe Fe1 0.000000 0.500000 0.47177(2) 0.01024(7) Uani d 1 Cl Cl1 0.04066(2) 0.59399(4) 0.59972(4) 0.01780(8) Uani d 1 N N1 -0.01980(4) 0.71984(15) 0.43765(12) 0.0120(2) Uani d 1 H H1 -0.0100(7) 0.760(3) 0.493(2) 0.014 Uiso d 1 N N2 0.04360(3) 0.55678(13) 0.35009(12) 0.0113(2) Uani d 1 H H2 0.0352(7) 0.533(3) 0.2897(19) 0.014 Uiso d 1 C C1 0.00232(4) 0.76806(17) 0.34277(15) 0.0139(3) Uani d 1 H H1A 0.002287 0.873496 0.339879 0.017 Uiso calc 1 H H1AB -0.010308 0.732065 0.277130 0.017 Uiso calc 1 C C2 0.04357(4) 0.71467(16) 0.34726(16) 0.0141(3) Uani d 1 H H2A 0.057976 0.748405 0.283775 0.017 Uiso calc 1 H H2AB 0.056538 0.752492 0.411806 0.017 Uiso calc 1 C C3 0.08320(5) 0.49628(15) 0.36508(14) 0.0130(3) Uani d 1 H H3 0.091517 0.515461 0.440218 0.016 Uiso calc 1 C C4 0.08278(4) 0.33465(16) 0.34788(15) 0.0145(3) Uani d 1 H H4A 0.070712 0.315941 0.277559 0.017 Uiso calc 1 H H4AB 0.109969 0.302072 0.343351 0.017 Uiso calc 1 C C5 0.06217(5) 0.24162(15) 0.43060(14) 0.0129(3) Uani d 1 C C6 0.11327(5) 0.5615(2) 0.28966(16) 0.0193(3) Uani d 1 H H6A 0.105473 0.544654 0.215473 0.029 Uiso calc 1 H H6B 0.138525 0.517310 0.302598 0.029 Uiso calc 1 H H6C 0.115042 0.664296 0.302647 0.029 Uiso calc 1 C C7 0.07963(5) 0.25789(19) 0.54183(17) 0.0183(3) Uani d 1 H H7A 0.107197 0.233676 0.539414 0.027 Uiso calc 1 H H7B 0.066338 0.193831 0.591581 0.027 Uiso calc 1 H H7C 0.076579 0.356608 0.565959 0.027 Uiso calc 1 C C8 0.06705(5) 0.08418(18) 0.39781(15) 0.0175(3) Uani d 1 H H8A 0.059364 0.072337 0.322999 0.026 Uiso calc 1 H H8B 0.050716 0.024097 0.443246 0.026 Uiso calc 1 H H8C 0.094184 0.056091 0.406353 0.026 Uiso calc 1 Cl Cl2 0.000000 0.500000 0.11978(5) 0.02101(12) Uani d 1 loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_12 _atom_site_aniso_U_13 _atom_site_aniso_U_23 Fe1 0.01000(12) 0.01121(12) 0.00952(13) 0.00018(11) 0.000 0.000 Cl1 0.01758(16) 0.02242(18) 0.01340(16) -0.00021(13) -0.00299(14) -0.00439(15) N1 0.0112(5) 0.0134(5) 0.0114(6) 0.0009(4) -0.0002(4) -0.0011(4) N2 0.0108(5) 0.0115(5) 0.0116(5) 0.0001(4) -0.0005(5) 0.0003(5) C1 0.0136(6) 0.0120(6) 0.0161(8) 0.0018(4) 0.0020(6) 0.0024(5) C2 0.0130(6) 0.0112(6) 0.0180(7) -0.0008(5) 0.0010(6) 0.0013(5) C3 0.0101(6) 0.0151(6) 0.0138(7) 0.0003(5) 0.0006(5) 0.0018(5) C4 0.0126(6) 0.0150(6) 0.0159(7) 0.0020(5) 0.0030(6) 0.0006(6) C5 0.0115(6) 0.0134(6) 0.0137(7) 0.0028(5) 0.0006(5) 0.0014(5) C6 0.0142(7) 0.0194(7) 0.0244(8) 0.0010(6) 0.0057(6) 0.0051(6) C7 0.0181(7) 0.0202(7) 0.0165(7) 0.0021(6) -0.0042(7) 0.0018(6) C8 0.0175(7) 0.0140(6) 0.0210(8) 0.0050(6) 0.0017(6) 0.0008(6) Cl2 0.0267(3) 0.0226(3) 0.0137(3) -0.0070(2) 0.000 0.000 loop_ _atom_type_symbol _atom_type_description _atom_type_scat_dispersion_real _atom_type_scat_dispersion_imag _atom_type_scat_source C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Fe Fe 0.3463 0.8444 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' loop_ _geom_angle_atom_site_label_1 _geom_angle_atom_site_label_2 _geom_angle_atom_site_label_3 _geom_angle_site_symmetry_1 _geom_angle_site_symmetry_3 _geom_angle _geom_angle_publ_flag N2 Fe1 N2 . 2_565 92.75(7) y N2 Fe1 N1 . . 81.55(5) y N2 Fe1 N1 2_565 . 83.15(5) ? N2 Fe1 N1 . 2_565 83.15(5) y N2 Fe1 N1 2_565 2_565 81.55(5) ? N1 Fe1 N1 . 2_565 157.76(8) y N2 Fe1 Cl1 . . 88.35(4) y N2 Fe1 Cl1 2_565 . 170.88(3) ? N1 Fe1 Cl1 . . 88.06(4) y N1 Fe1 Cl1 2_565 . 107.56(4) ? N2 Fe1 Cl1 . 2_565 170.88(3) y N2 Fe1 Cl1 2_565 2_565 88.34(4) ? N1 Fe1 Cl1 . 2_565 107.56(4) y N1 Fe1 Cl1 2_565 2_565 88.06(4) ? Cl1 Fe1 Cl1 . 2_565 92.01(2) y C1 N1 C5 . 2_565 112.32(13) ? C1 N1 Fe1 . . 106.22(9) ? C5 N1 Fe1 2_565 . 122.25(10) ? C1 N1 H1 . . 108.0(17) ? C5 N1 H1 2_565 . 109.0(16) ? Fe1 N1 H1 . . 97.5(17) ? C2 N2 C3 . . 112.55(11) ? C2 N2 Fe1 . . 104.91(10) ? C3 N2 Fe1 . . 116.56(10) ? C2 N2 H2 . . 104.3(17) ? C3 N2 H2 . . 109.0(16) ? Fe1 N2 H2 . . 108.8(17) ? N1 C1 C2 . . 110.80(14) ? N1 C1 H1A . . 109.5 ? C2 C1 H1A . . 109.5 ? N1 C1 H1AB . . 109.5 ? C2 C1 H1AB . . 109.5 ? H1A C1 H1AB . . 108.1 ? N2 C2 C1 . . 109.43(12) ? N2 C2 H2A . . 109.8 ? C1 C2 H2A . . 109.8 ? N2 C2 H2AB . . 109.8 ? C1 C2 H2AB . . 109.8 ? H2A C2 H2AB . . 108.2 ? N2 C3 C4 . . 110.47(12) ? N2 C3 C6 . . 113.11(13) ? C4 C3 C6 . . 108.39(14) ? N2 C3 H3 . . 108.2 ? C4 C3 H3 . . 108.2 ? C6 C3 H3 . . 108.2 ? C5 C4 C3 . . 118.29(14) ? C5 C4 H4A . . 107.7 ? C3 C4 H4A . . 107.7 ? C5 C4 H4AB . . 107.7 ? C3 C4 H4AB . . 107.7 ? H4A C4 H4AB . . 107.1 ? N1 C5 C7 2_565 . 107.84(14) ? N1 C5 C4 2_565 . 110.74(12) ? C7 C5 C4 . . 112.12(14) ? N1 C5 C8 2_565 . 110.54(13) ? C7 C5 C8 . . 107.19(13) ? C4 C5 C8 . . 108.37(14) ? C3 C6 H6A . . 109.5 ? C3 C6 H6B . . 109.5 ? H6A C6 H6B . . 109.5 ? C3 C6 H6C . . 109.5 ? H6A C6 H6C . . 109.5 ? H6B C6 H6C . . 109.5 ? C5 C7 H7A . . 109.5 ? C5 C7 H7B . . 109.5 ? H7A C7 H7B . . 109.5 ? C5 C7 H7C . . 109.5 ? H7A C7 H7C . . 109.5 ? H7B C7 H7C . . 109.5 ? C5 C8 H8A . . 109.5 ? C5 C8 H8B . . 109.5 ? H8A C8 H8B . . 109.5 ? C5 C8 H8C . . 109.5 ? H8A C8 H8C . . 109.5 ? H8B C8 H8C . . 109.5 ? loop_ _geom_bond_atom_site_label_1 _geom_bond_atom_site_label_2 _geom_bond_site_symmetry_2 _geom_bond_distance _geom_bond_publ_flag Fe1 N2 . 2.2081(14) y Fe1 N2 2_565 2.2081(14) ? Fe1 N1 . 2.2149(14) y Fe1 N1 2_565 2.2150(14) y Fe1 Cl1 . 2.3065(5) y Fe1 Cl1 2_565 2.3066(5) ? N1 C1 . 1.483(2) ? N1 C5 2_565 1.511(2) ? N1 H1 . 0.86(2) ? N2 C2 . 1.4819(19) ? N2 C3 . 1.494(2) ? N2 H2 . 0.84(2) ? C1 C2 . 1.512(2) ? C1 H1A . 0.9900 ? C1 H1AB . 0.9900 ? C2 H2A . 0.9900 ? C2 H2AB . 0.9900 ? C3 C4 . 1.532(2) ? C3 C6 . 1.532(2) ? C3 H3 . 1.0000 ? C4 C5 . 1.530(2) ? C4 H4A . 0.9900 ? C4 H4AB . 0.9900 ? C5 C7 . 1.526(3) ? C5 C8 . 1.543(2) ? C6 H6A . 0.9800 ? C6 H6B . 0.9800 ? C6 H6C . 0.9800 ? C7 H7A . 0.9800 ? C7 H7B . 0.9800 ? C7 H7C . 0.9800 ? C8 H8A . 0.9800 ? C8 H8B . 0.9800 ? C8 H8C . 0.9800 ? loop_ _geom_hbond_atom_site_label_D _geom_hbond_atom_site_label_H _geom_hbond_atom_site_label_A _geom_hbond_site_symmetry_A _geom_hbond_distance_DH _geom_hbond_distance_HA _geom_hbond_distance_DA _geom_hbond_angle_DHA _geom_hbond_publ_flag N1 H1 Cl2 5 0.86(2) 2.78(2) 3.5467(15) 150(2) yes N2 H2 Cl2 . 0.84(2) 2.47(2) 3.2971(16) 168(2) yes loop_ _geom_torsion_atom_site_label_1 _geom_torsion_atom_site_label_2 _geom_torsion_atom_site_label_3 _geom_torsion_atom_site_label_4 _geom_torsion_site_symmetry_1 _geom_torsion_site_symmetry_4 _geom_torsion C5 N1 C1 C2 2_565 . -174.18(13) Fe1 N1 C1 C2 . . -38.12(15) C3 N2 C2 C1 . . -174.53(14) Fe1 N2 C2 C1 . . -46.83(16) N1 C1 C2 N2 . . 59.91(19) C2 N2 C3 C4 . . -170.07(15) Fe1 N2 C3 C4 . . 68.67(15) C2 N2 C3 C6 . . -48.38(19) Fe1 N2 C3 C6 . . -169.64(11) N2 C3 C4 C5 . . -69.37(19) C6 C3 C4 C5 . . 166.19(14) C3 C4 C5 N1 . 2_565 60.64(19) C3 C4 C5 C7 . . -59.86(18) C3 C4 C5 C8 . . -177.95(14) _cod_database_fobs_code 2021795