#------------------------------------------------------------------------------ #$Date: 2020-11-25 07:11:19 +0200 (Wed, 25 Nov 2020) $ #$Revision: 259242 $ #$URL: file:///home/coder/svn-repositories/cod/cif/2/02/22/2022278.cif $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2022278 loop_ _publ_author_name 'Rutherford, Ryan Noboru' 'Ura, Shinji' 'Chan, Tak-Hang' 'Fukumoto, Kozo' 'Nishioka, Takanori' 'Renzetti, Andrea' _publ_section_title ; Dibenzoate esters of cis-tetralin-2,3-diol as analogs of (--)-epigallocatechin gallate: synthesis and crystal structure of anticancer drug candidates ; _journal_coeditor_code OP3007 _journal_issue 12 _journal_name_full 'Acta Crystallographica Section C' _journal_page_first ; ; _journal_paper_doi 10.1107/S2053229620014916 _journal_volume 76 _journal_year 2020 _chemical_formula_iupac 'C30 H32 O10' _chemical_formula_moiety 'C30 H32 O10' _chemical_formula_sum 'C30 H32 O10' _chemical_formula_weight 552.55 _chemical_name_systematic ; (2R,3S)-1,2,3,4-Tetrahydronaphthalene-2,3-diyl bis(3,4,5-trimethoxybenzoate) ; _space_group_crystal_system monoclinic _space_group_IT_number 14 _space_group_name_Hall '-P 2yn' _space_group_name_H-M_alt 'P 1 21/n 1' _atom_sites_solution_hydrogens geom _atom_sites_solution_primary dual _audit_creation_method ; Olex2 1.3 (compiled 2020.02.04 svn.rd84adfe8 for OlexSys, GUI svn.r6032) ; _cell_angle_alpha 90 _cell_angle_beta 117.432(5) _cell_angle_gamma 90 _cell_formula_units_Z 4 _cell_length_a 12.147(8) _cell_length_b 20.697(13) _cell_length_c 12.702(9) _cell_measurement_reflns_used 7542 _cell_measurement_temperature 193.4 _cell_measurement_theta_max 27.4850 _cell_measurement_theta_min 3.1594 _cell_volume 2834(3) _computing_cell_refinement ; CrystalClear-SM Expert (Rigaku, 2011) ; _computing_data_collection ; CrystalClear-SM Expert (Rigaku, 2011) ; _computing_data_reduction ; CrystalClear-SM Expert (Rigaku, 2011) ; _computing_molecular_graphics ; OLEX2 (Dolomanov et al., 2009) ; _computing_publication_material ; OLEX2 (Dolomanov et al., 2009) ; _computing_structure_refinement ; SHELXL2018 (Sheldrick, 2015b) ; _computing_structure_solution ; SHELXT2018 (Sheldrick, 2015a) ; _diffrn_ambient_temperature 193.4 _diffrn_detector_area_resol_mean 28.5714 _diffrn_measured_fraction_theta_full 0.998 _diffrn_measured_fraction_theta_max 0.993 _diffrn_measurement_device ; Rigaku Saturn724+ (2x2 bin mode) ; _diffrn_measurement_device_type 'Rigaku Saturn724+ (2x2 bin mode)' _diffrn_measurement_method 'profile data from \w-scans' _diffrn_measurement_specimen_support 'Mitegen 50um' _diffrn_radiation_type MoK\a _diffrn_radiation_wavelength 0.71075 _diffrn_reflns_av_R_equivalents 0.0510 _diffrn_reflns_av_unetI/netI 0.0536 _diffrn_reflns_limit_h_max 14 _diffrn_reflns_limit_h_min -15 _diffrn_reflns_limit_k_max 17 _diffrn_reflns_limit_k_min -26 _diffrn_reflns_limit_l_max 16 _diffrn_reflns_limit_l_min -16 _diffrn_reflns_number 19152 _diffrn_reflns_theta_full 25.242 _diffrn_reflns_theta_max 27.316 _diffrn_reflns_theta_min 3.159 _exptl_absorpt_coefficient_mu 0.097 _exptl_absorpt_correction_T_max 1.0000 _exptl_absorpt_correction_T_min 0.5513 _exptl_absorpt_correction_type empirical _exptl_absorpt_process_details DTABSCOR _exptl_crystal_colour colourless _exptl_crystal_density_diffrn 1.295 _exptl_crystal_description prism _exptl_crystal_F_000 1168 _exptl_crystal_size_max 0.17 _exptl_crystal_size_mid 0.05 _exptl_crystal_size_min 0.03 _refine_diff_density_max 0.207 _refine_diff_density_min -0.198 _refine_ls_extinction_method none _refine_ls_goodness_of_fit_ref 1.154 _refine_ls_hydrogen_treatment constr _refine_ls_matrix_type full _refine_ls_number_parameters 367 _refine_ls_number_reflns 6351 _refine_ls_number_restraints 0 _refine_ls_restrained_S_all 1.154 _refine_ls_R_factor_all 0.1139 _refine_ls_R_factor_gt 0.0696 _refine_ls_shift/su_max 0.000 _refine_ls_shift/su_mean 0.000 _refine_ls_structure_factor_coef Fsqd _refine_ls_weighting_details 'w=1/[\s^2^(Fo^2^)+(0.0603P)^2^+0.2555P] where P=(Fo^2^+2Fc^2^)/3' _refine_ls_weighting_scheme calc _refine_ls_wR_factor_gt 0.1431 _refine_ls_wR_factor_ref 0.1635 _reflns_number_gt 4312 _reflns_number_total 6351 _reflns_threshold_expression 'I > 2\s(I)' _cod_data_source_file op3007sup1.cif _cod_data_source_block 5 _cod_database_code 2022278 _shelx_space_group_comment ; The symmetry employed for this shelxl refinement is uniquely defined by the following loop, which should always be used as a source of symmetry information in preference to the above space-group names. They are only intended as comments. ; _shelx_hkl_file ; -1 0 -1 2.64 0.32 -1 0 -1 2.80 0.45 -1 0 -1 3.52 0.79 1 0 1 4.22 0.66 1 0 -2 2.56 0.44 -1 0 2 2.54 0.76 1 0 -2 2.18 0.66 -1 0 2 2.20 0.51 1 -1 1 146.89 3.07 -1 1 -1 138.93 3.34 1 1 1 144.72 2.92 -1 -1 -1 138.75 2.97 -1 1 -1 144.15 2.87 -1 -1 -1 142.56 3.25 -2 0 1 0.33 0.45 2 0 -1 0.44 0.37 2 0 -1 1.47 0.71 -2 0 1 0.38 0.47 1 1 -2 1.90 0.39 1 1 -2 2.42 0.77 1 -1 -2 1.76 0.67 -1 1 2 2.39 0.62 -1 1 2 1.50 0.64 1 -1 -2 1.51 0.37 -1 -1 2 2.37 0.47 -1 -1 2 3.42 0.86 0 -3 -1 13.31 1.16 0 -3 -1 13.47 0.85 0 3 1 12.82 0.85 0 3 1 14.96 0.90 0 -3 1 14.91 1.00 0 3 -1 13.97 0.85 0 3 -1 12.84 0.86 0 -3 1 13.49 0.82 -2 -1 1 960.20 5.99 2 -1 -1 960.34 5.42 2 1 -1 968.80 5.37 -1 -3 0 80.77 2.15 1 3 0 77.02 1.96 -1 3 0 87.21 2.11 -1 3 1 188.19 3.94 1 -3 -1 191.65 4.08 1 -3 -1 205.10 3.92 -1 3 1 197.79 3.84 1 3 -1 189.70 4.05 -1 -3 1 202.45 4.29 1 3 -1 184.82 3.69 -1 -3 1 188.40 3.80 0 0 -2 1248.78 7.18 0 0 2 1275.79 7.42 1 2 1 44.92 1.44 -1 -2 -1 41.11 1.19 -1 2 -1 41.12 1.12 1 -2 1 43.20 1.19 1 2 1 36.61 1.32 -1 2 -1 45.24 2.08 1 -2 1 41.21 1.59 0 1 2 673.85 5.13 0 1 -2 660.55 4.65 0 -1 -2 672.80 5.02 1 -2 -2 704.04 5.49 1 2 -2 688.93 5.94 1 2 -2 717.36 4.80 -2 0 0 1060.47 6.44 -2 0 2 1613.80 8.94 2 2 -1 762.49 5.45 -2 -2 1 792.90 5.26 2 2 -1 760.72 4.87 -2 2 1 766.51 5.10 2 -1 0 289.64 1.84 -2 1 0 287.36 1.83 -2 -1 0 292.35 3.22 2 -1 0 283.51 2.75 -2 1 0 297.51 2.79 0 4 0 206.24 4.39 0 -4 0 206.12 3.93 0 4 0 204.84 3.92 0 -4 0 205.91 4.42 2 1 -2 905.03 5.88 -2 -1 2 936.78 6.48 -2 1 2 944.86 6.41 0 2 -2 37.67 1.39 0 2 2 40.38 2.59 0 -2 -2 38.51 2.16 0 -2 2 42.62 1.59 0 2 -2 36.30 1.68 0 -2 2 37.53 1.46 0 -2 -2 38.14 1.47 0 2 2 39.32 1.47 -2 -2 0 71.53 2.14 -2 -2 0 76.69 1.84 2 2 0 67.18 1.82 2 -2 0 74.05 1.82 2 -2 0 70.81 1.69 -2 2 0 70.07 1.71 -2 2 0 66.46 1.56 2 2 -2 1.72 0.50 -2 2 2 2.25 0.78 -2 -2 2 2.19 0.62 2 2 -2 1.49 0.40 2 -2 -2 1.17 0.36 -2 -2 2 2.04 0.64 -2 2 2 2.21 0.77 -1 3 -1 2478.44 11.72 -1 -3 -1 2514.41 12.18 1 -3 1 2488.93 10.67 -1 -3 -1 2509.81 13.31 1 3 1 2478.06 12.03 0 -4 -1 158.60 3.76 0 4 -1 163.25 3.13 0 -4 -1 173.56 3.67 0 -4 -1 175.91 3.82 0 -4 1 169.26 3.87 0 -4 1 162.86 3.15 1 -3 -2 958.51 6.13 -1 3 2 964.39 6.30 -1 -3 2 945.44 5.84 1 4 0 6.82 0.68 -1 -4 0 6.43 0.97 -1 -4 0 5.88 0.76 1 4 0 5.31 0.70 1 -4 0 8.08 0.82 -1 4 0 6.78 0.72 1 4 -1 20.01 0.97 -1 -4 1 21.44 1.24 -1 -4 1 20.50 1.16 -1 4 1 25.59 1.77 1 -4 -1 22.50 1.65 1 -4 -1 20.38 1.13 2 3 -1 88.74 2.90 2 -3 -1 101.22 2.61 -2 3 1 89.51 2.28 -2 3 1 99.59 2.21 2 -3 -1 90.31 2.02 -2 -3 1 91.09 2.46 -2 -3 1 93.75 2.49 0 3 2 2008.91 11.19 0 -3 2 1987.17 9.84 0 3 -2 1973.39 9.58 -1 0 -2 1.14 0.51 1 0 2 1.60 0.40 2 3 0 153.49 3.32 -2 -3 0 162.24 3.85 -2 -3 0 166.65 3.58 2 -3 0 164.37 3.51 -2 3 0 158.92 3.42 -2 3 0 168.79 3.33 2 -3 0 158.21 3.18 2 -3 -2 1853.43 9.62 -2 3 2 1891.19 9.67 -2 -3 2 1864.43 10.80 -1 0 3 502.01 4.77 1 0 -3 526.71 5.27 -2 0 -1 1.38 0.39 -2 0 -1 1.36 0.67 -2 0 -1 1.36 0.32 -1 1 -2 413.83 4.10 -1 -1 -2 413.34 3.66 1 1 2 420.53 3.82 1 1 2 416.76 4.57 1 -1 2 411.37 4.07 -1 1 -2 410.39 3.98 0 -5 0 0.26 0.39 0 5 0 0.50 0.17 0 -5 0 -0.34 0.82 1 -1 -3 278.93 4.05 -1 1 3 267.28 3.64 1 1 -3 256.47 4.06 -2 0 3 1.92 1.02 2 0 -3 0.25 0.83 -2 1 -1 7.77 0.45 2 -1 1 9.14 1.22 -2 1 -1 7.99 0.72 2 -1 1 6.14 0.65 -2 -1 -1 7.59 0.46 -2 -1 -1 6.40 0.95 2 1 1 8.98 0.55 -1 -4 -1 404.42 4.57 -1 -4 -1 408.75 4.38 1 -4 1 407.99 3.92 -1 4 -1 419.82 2.67 1 -4 1 416.44 2.65 2 -1 -3 126.93 3.60 2 1 -3 113.81 3.14 -2 1 3 120.92 3.15 -2 -1 3 113.31 2.96 1 -4 -2 25.90 1.95 -1 4 2 29.38 1.56 1 -4 -2 26.63 1.48 1 4 -2 27.11 1.12 -1 -4 2 25.78 1.10 -1 -4 2 26.09 1.79 3 0 -1 3084.51 13.30 3 0 -2 0.70 0.74 -3 0 2 1.22 1.38 -3 0 2 1.28 0.74 -2 -4 1 25.97 1.26 -2 -4 1 26.54 1.42 2 -4 -1 25.14 1.04 -2 4 1 27.61 1.14 2 -4 -1 30.62 1.53 1 2 2 3814.10 17.48 1 -2 2 3870.07 17.34 3 1 -1 1307.47 6.79 3 -1 -1 1304.44 6.95 -3 -1 1 1338.17 7.04 -3 1 1 1318.44 6.93 -3 -1 1 1344.80 8.55 -3 1 2 1318.31 7.98 -3 -1 2 1345.57 8.52 3 1 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8.58 0 -1 3 1198.76 8.02 1 -3 2 26.42 1.91 -1 -3 -2 25.01 1.60 -1 3 -2 27.49 1.15 1 -3 2 26.00 1.32 -1 3 -2 25.60 1.08 -1 -3 -2 25.36 1.28 1 3 2 29.65 3.03 -3 0 0 0.29 0.81 1 -3 -3 70.97 2.58 -1 3 3 60.61 2.38 -1 -3 3 67.85 2.38 -1 -3 3 66.53 2.20 -2 3 -1 15.01 0.82 2 3 1 13.28 0.83 -2 -3 -1 10.21 1.04 -2 -3 -1 14.79 0.97 -2 3 -1 14.64 0.85 -2 3 -1 14.48 1.40 2 -3 1 14.94 0.96 -3 -1 0 710.49 3.64 3 -1 0 705.86 3.29 -3 -1 0 720.12 6.13 3 0 -3 69.78 2.95 -3 0 3 81.51 2.59 0 -2 -3 1972.84 11.59 0 -2 3 1942.99 11.78 0 -2 3 1999.32 11.19 -2 3 3 407.52 4.54 -2 -3 3 410.01 4.23 -2 -3 3 415.76 5.48 -3 1 3 2.45 0.85 -3 -1 3 3.38 0.95 3 1 -3 4.82 1.14 3 -1 -3 3.05 1.01 -1 -5 -1 266.13 3.72 -1 -5 -1 256.72 3.62 1 -5 1 259.70 3.46 1 -5 -2 17.17 1.69 1 -5 -2 17.64 1.52 -1 5 2 20.12 2.50 -1 -5 2 15.38 1.11 1 5 -2 13.95 0.83 -1 -5 2 16.62 1.27 -3 -3 1 165.31 4.10 -3 -3 1 188.71 4.06 3 3 -1 179.54 3.87 -3 3 1 170.09 3.72 3 -3 -1 178.30 3.91 3 -3 -1 184.75 3.85 -3 3 1 189.66 4.08 0 -6 0 245.76 2.54 -3 3 2 523.71 4.39 3 -3 -2 505.84 5.01 2 -5 -1 10.66 0.57 -2 5 1 15.87 1.65 2 -5 -1 11.62 1.36 -2 -5 1 14.18 2.51 -2 -5 1 10.76 1.01 -3 -2 0 72.03 1.75 -3 2 0 68.94 1.65 3 -2 0 69.62 2.01 -3 -2 0 75.88 2.55 3 2 0 68.77 1.66 3 -2 0 68.85 1.59 -3 2 0 73.52 2.08 -3 2 3 697.38 5.85 3 -2 -3 688.15 6.45 -3 -2 3 682.94 5.97 -3 -2 3 720.84 6.83 0 5 2 12.11 2.33 0 -5 -2 9.65 1.27 0 -5 2 8.14 1.53 0 5 -2 8.43 0.61 0 -5 2 12.34 2.02 0 -3 -3 219.45 5.06 0 3 3 209.68 5.80 0 -3 3 198.32 4.79 0 -3 3 187.03 4.26 0 6 -1 64.63 1.58 0 -6 1 70.78 1.90 0 -6 -1 68.24 1.98 0 -6 -1 71.57 2.61 0 -6 1 69.94 2.40 0 -6 -1 71.95 2.14 -1 4 -2 3437.09 15.39 1 -4 2 3556.57 15.92 -1 -6 0 431.58 4.23 -1 -6 0 441.01 5.02 1 -6 0 427.22 2.29 -2 5 0 10.17 1.13 2 -5 0 8.63 1.13 -2 -5 0 7.54 0.95 -2 -5 0 6.73 0.89 1 -6 -1 10.09 1.17 -1 -6 1 11.73 1.16 1 -6 -1 13.16 0.83 1 6 -1 11.38 0.81 1 -6 -1 12.73 1.74 -1 -6 1 13.19 0.84 -2 5 2 227.14 3.22 -2 -5 2 228.78 3.61 -2 -5 2 216.32 4.73 2 -5 -2 228.66 2.52 -1 -4 3 287.47 3.91 -1 -4 3 285.22 4.33 -1 4 3 275.13 3.86 1 -4 -3 268.64 5.49 -2 -4 -1 815.23 6.21 -2 4 -1 788.83 4.94 2 -4 1 821.03 5.86 -2 0 -2 1667.46 9.14 -2 0 -2 1686.48 10.92 -2 0 -2 1731.06 8.91 -2 -4 3 148.72 3.61 -2 4 3 159.96 3.83 -2 -4 3 158.72 4.21 2 -4 -3 145.73 3.95 3 3 0 674.13 4.67 3 -3 0 699.13 5.05 3 -3 0 677.62 4.57 -3 3 0 689.35 4.64 -2 1 -2 16.61 2.14 -2 1 -2 14.70 1.03 -2 -1 -2 13.57 0.80 -2 -1 -2 15.21 1.36 -2 1 -2 16.98 1.42 2 1 2 17.13 1.58 2 0 -4 569.86 6.45 -2 0 4 588.39 5.82 -3 -4 1 399.77 4.94 -3 -4 1 393.91 4.14 -3 4 1 377.12 3.25 3 -4 -1 391.84 4.14 3 -4 -1 372.41 3.19 3 -4 -2 21.13 1.35 3 -4 -2 21.64 0.98 -3 -4 2 24.14 2.29 -3 4 2 25.68 1.27 -3 3 3 66.87 2.35 3 -3 -3 63.65 2.37 -3 -3 3 64.57 2.65 -3 -3 3 69.57 4.04 -2 1 4 72.53 2.63 -2 -1 4 65.13 2.32 2 -1 -4 71.11 2.90 2 1 -4 67.71 2.68 1 0 3 535.46 5.57 -1 0 -3 548.58 5.10 1 0 -4 0.54 0.85 -1 0 4 1.40 0.75 1 -1 3 1531.60 10.35 -1 1 -3 1463.89 9.25 -2 -2 -2 872.65 7.95 2 -2 2 864.90 5.97 2 2 2 845.89 5.87 1 1 -4 1639.27 11.20 1 -1 -4 1602.57 11.29 -3 0 -1 259.56 3.83 -1 -6 -1 0.97 1.06 1 -6 1 0.46 0.27 -1 6 -1 0.61 0.13 -1 -6 -1 0.13 0.70 1 -6 1 1.15 0.96 0 4 3 2.40 1.00 0 -4 -3 2.20 0.68 0 -4 3 1.68 0.67 0 -4 3 2.49 0.75 4 0 -2 27.60 1.40 4 0 -2 31.08 3.02 -4 0 2 34.89 3.18 -1 -6 2 4.33 0.87 -1 6 2 6.67 1.42 -1 -6 2 5.98 0.67 1 -6 -2 4.72 0.89 1 6 -2 6.34 1.08 -2 -2 4 80.46 2.94 2 -2 -4 76.48 2.88 -2 2 4 77.99 2.67 -3 1 -1 64.50 1.36 -3 1 -1 62.73 2.14 -3 -1 -1 67.19 1.54 -3 -1 -1 69.46 2.47 -4 1 2 561.39 5.26 -4 -1 2 556.81 5.61 4 1 -2 550.40 4.92 4 -1 -2 545.48 4.87 -4 1 2 547.48 5.27 4 1 -2 547.64 4.87 2 -6 -1 94.12 2.01 -2 -6 1 91.41 2.66 -2 6 1 94.88 2.14 -2 -6 1 96.32 2.98 2 -6 -1 91.70 2.87 1 -2 3 3.63 1.01 -1 -2 -3 2.19 0.80 1 -2 3 2.17 0.62 1 2 3 1.52 0.35 -3 0 4 -0.32 0.72 -1 -2 4 19.86 1.92 1 -2 -4 17.47 1.64 -1 2 4 18.72 1.69 -1 -5 -2 1133.90 8.40 -1 -5 -2 1133.82 9.02 -1 5 -2 1119.93 6.33 1 -5 2 1157.46 6.63 0 -7 0 1.03 0.61 0 7 0 0.76 0.53 0 -7 0 0.21 0.94 -3 1 4 356.15 5.74 -3 -1 4 342.80 4.39 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12.85 1.94 -8 -1 -1 12.95 2.08 -2 -15 -2 44.73 2.98 2 -15 2 41.53 4.55 -2 -15 -2 40.37 3.23 1 -16 1 2.84 1.34 -1 -16 -1 6.34 1.41 -1 -16 -1 3.12 1.50 -6 6 9 24.74 6.14 -6 -6 9 25.16 3.30 6 -6 -9 25.08 2.96 6 6 -9 19.29 2.65 -3 0 -7 43.76 2.24 -3 0 -7 34.32 2.79 -5 -3 -5 1.05 1.21 -5 -3 -5 0.13 0.42 -5 3 -5 0.85 0.66 -5 3 -5 0.85 1.05 -1 -14 -4 10.66 2.34 1 -14 4 7.92 2.02 1 -14 4 10.28 2.10 -1 -14 -4 10.28 1.78 1 -16 -2 1.03 0.58 -1 -16 2 1.39 0.59 1 -16 -2 0.92 0.64 -1 -16 2 0.04 0.91 5 0 -10 0.06 0.54 -5 0 10 -0.27 0.88 -8 -9 4 0.54 0.42 -8 -9 4 0.89 0.93 -8 9 4 0.85 0.58 8 -9 -4 0.38 0.70 -1 11 7 92.16 7.86 1 -11 -7 84.60 4.03 -1 -11 7 91.14 3.92 -1 -11 7 86.99 10.83 4 -1 -10 2.31 1.66 -4 -1 10 1.52 0.78 -4 1 10 1.52 1.01 4 1 -10 1.22 0.76 -4 -3 -6 34.59 5.47 -4 -3 -6 41.67 3.03 -4 3 -6 39.24 2.23 -4 3 -6 44.68 2.90 4 -13 2 1.06 1.45 -4 -13 -2 2.97 1.81 -4 -13 -2 0.63 1.07 -3 -7 9 25.35 2.42 3 -7 -9 27.65 2.51 3 7 -9 21.58 2.40 -3 7 9 24.50 4.60 -3 1 -7 25.04 2.36 -3 -1 -7 35.36 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26.47 5.99 -4 -8 9 32.70 6.50 -4 -8 9 30.79 5.17 -7 0 -3 1.61 1.89 -6 7 9 8.44 1.65 6 7 -9 8.48 2.26 -6 -7 9 8.98 1.87 6 -7 -9 11.63 1.96 -1 -16 -2 35.37 3.06 1 -16 2 37.55 3.14 -1 -16 -2 30.85 2.14 0 -8 8 2.54 1.19 0 -8 8 1.06 0.93 0 -8 -8 1.67 1.42 0 8 8 2.22 1.25 8 -6 -8 13.32 3.04 -8 6 8 10.72 2.33 -8 -6 8 8.02 1.45 8 6 -8 15.31 3.41 -7 -1 -3 2.35 1.52 -7 1 -3 2.07 1.24 0 -14 -5 14.27 2.70 0 -14 -5 12.59 1.90 0 -14 5 13.30 2.38 0 -14 5 10.45 1.94 -1 -16 3 11.96 1.90 1 -16 -3 13.94 2.14 -1 -16 3 10.88 3.03 1 -16 -3 13.93 1.53 9 0 -8 3.02 2.18 -9 0 8 0.71 0.83 9 6 -6 42.46 2.79 -9 6 6 42.91 7.28 -9 -6 6 38.79 8.23 9 -6 -6 44.52 7.23 -6 4 -4 13.67 2.17 -6 -4 -4 10.91 2.21 -7 -10 0 7.19 1.53 -7 -10 0 6.17 1.57 -7 10 0 5.72 1.45 7 -10 0 9.09 1.45 -2 -16 -1 99.95 3.67 2 -16 1 101.53 4.61 -2 -16 -1 101.81 4.64 -5 -13 -1 131.30 4.58 -5 -13 -1 132.63 5.06 5 -13 1 125.25 4.18 6 -12 -6 1.50 1.19 -6 -12 6 -0.09 1.23 -6 -12 6 1.04 0.91 -6 12 6 1.55 1.10 -8 4 -1 125.28 4.19 -8 -4 -1 124.27 4.89 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6 10.71 3.06 -7 10 7 4.35 1.11 7 -10 -7 8.26 1.87 -7 -10 7 7.50 1.54 -7 -10 7 7.64 2.42 -7 -12 3 3.22 1.47 -7 -12 3 2.85 1.15 7 -12 -3 4.13 1.36 2 0 -10 25.98 2.93 -2 0 10 28.36 6.71 3 -11 5 1.29 1.54 -3 -11 -5 0.96 1.03 -3 -11 -5 2.33 1.68 -3 11 -5 1.09 0.96 -7 -12 4 21.37 2.68 -7 -12 4 20.53 5.35 7 -12 -4 21.62 2.32 -7 12 4 15.63 3.77 -5 12 7 12.31 2.96 5 -12 -7 8.29 2.00 -5 -12 7 9.71 2.35 -5 -12 7 9.64 2.55 -7 -9 -1 2.36 1.02 -7 -9 -1 1.16 1.28 7 -9 1 2.18 0.79 -7 9 -1 2.37 0.65 2 1 -10 6.74 2.56 -2 -1 10 5.89 1.67 2 -1 -10 6.89 1.76 -2 1 10 6.52 1.64 -7 -3 -3 4.91 1.94 -7 3 -3 4.52 1.39 -5 -14 0 75.25 9.29 -5 -14 0 72.16 3.62 5 -14 0 77.30 7.64 -8 -10 3 34.70 6.65 -8 -10 3 39.66 3.07 8 -10 -3 41.14 8.10 -8 10 3 31.71 4.39 -1 -12 -6 6.92 1.89 -1 -12 -6 7.01 1.98 1 -12 6 8.11 2.03 1 -12 6 9.12 2.51 -6 13 5 88.59 8.11 -6 -13 5 98.22 5.62 -6 -13 5 94.38 3.83 6 -13 -5 92.84 6.63 -7 -7 -2 1.52 0.53 7 -7 2 0.79 0.71 -7 -7 -2 2.27 1.42 -7 7 -2 4.11 1.13 -9 -4 1 19.93 2.76 -9 4 1 16.89 3.14 -3 -14 -3 34.76 2.72 -3 -14 -3 32.91 2.79 3 -14 3 34.42 2.80 3 4 -10 82.00 4.29 3 -4 -10 89.24 4.28 -3 -4 10 97.01 4.07 -3 4 10 91.67 4.93 0 -17 0 -0.50 1.03 0 -17 0 1.10 0.87 0 4 -9 12.14 2.10 0 -4 -9 11.82 2.03 0 4 9 11.29 2.18 0 -4 9 9.28 2.57 -3 -16 0 1.18 0.97 -3 -16 0 1.36 1.67 3 -16 0 1.91 2.25 -4 -9 -5 45.06 3.29 4 -9 5 50.49 2.98 -4 -9 -5 51.57 2.84 -4 9 -5 44.45 2.33 -2 -8 -7 13.51 1.68 2 -8 7 15.40 4.57 2 -8 7 17.86 4.25 -2 -8 -7 15.69 2.12 -9 -3 8 578.98 9.09 9 -3 -8 648.08 9.97 9 3 -8 654.18 10.37 -9 3 8 586.04 9.15 -6 -5 -4 5.19 1.73 -6 5 -4 9.38 1.63 -9 6 2 0.86 0.86 -9 -6 2 0.82 1.20 -9 -6 2 1.38 0.90 9 -6 -2 0.36 0.57 -2 -15 -3 2.61 1.87 -2 -15 -3 2.67 1.95 2 -15 3 1.28 1.33 1 -12 -7 20.95 2.46 1 -12 -7 24.39 2.39 -1 -12 7 22.12 4.42 -1 -12 7 27.71 5.36 -9 -7 3 79.64 5.20 -9 -7 3 78.61 9.51 9 -7 -3 102.63 3.14 -9 7 3 98.69 3.19 -8 -5 -1 27.46 2.87 -8 5 -1 21.86 1.88 -8 -10 5 -0.42 0.77 -8 -10 5 3.40 1.41 8 -10 -5 1.13 1.25 -8 10 5 0.15 0.52 3 -16 -3 43.55 3.45 -3 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15.06 3.32 2 -15 -5 14.84 2.66 -2 -15 5 18.42 2.26 -2 -15 5 16.38 3.39 -1 -10 -7 110.17 4.42 -1 -10 -7 110.50 4.87 1 -10 7 106.52 13.38 1 -10 7 119.29 7.09 -4 11 8 45.68 6.72 4 -11 -8 39.93 3.51 -4 -11 8 39.58 2.71 -4 -11 8 39.26 7.70 -5 -5 10 43.97 2.89 -5 5 10 28.97 6.24 5 -5 -10 38.23 3.10 5 5 -10 35.03 2.99 3 -11 -8 165.00 5.45 -3 11 8 184.63 9.00 -3 -11 8 166.40 12.72 -3 -11 8 169.57 5.98 -5 -9 -4 1.65 1.40 -5 9 -4 1.19 0.54 5 -9 4 1.41 1.02 -5 -9 -4 2.87 1.26 -3 14 6 15.82 2.88 3 -14 -6 15.09 3.08 -3 -14 6 16.95 3.45 -3 -14 6 18.12 2.17 -5 -11 -3 26.83 2.87 5 -11 3 17.51 3.52 -5 -11 -3 21.26 2.04 0 -17 1 49.92 3.31 0 -17 1 58.83 3.57 0 -17 -1 51.35 2.33 0 -17 -1 59.79 4.10 -6 10 8 74.35 9.42 6 -10 -8 64.07 3.74 -6 -10 8 62.22 4.93 -6 -10 8 67.67 3.58 -10 0 4 1.39 1.45 10 0 -4 0.10 0.41 -7 -12 2 0.20 0.86 -7 -12 2 1.35 1.11 7 -12 -2 2.21 1.34 1 -17 0 20.50 2.33 -1 -17 0 22.97 4.00 -1 -17 0 16.44 4.09 8 -7 -8 10.23 2.69 -8 -7 8 10.85 2.06 -8 7 8 13.11 2.78 8 7 -8 11.55 2.66 1 -17 -1 14.72 2.41 -1 -17 1 12.24 2.05 -1 -17 1 10.81 2.57 1 -17 -1 13.95 1.13 2 -14 -6 39.82 3.66 2 -14 -6 40.31 2.70 -2 -14 6 45.28 4.73 -2 -14 6 39.63 4.04 -2 8 9 2.09 1.32 2 -8 -9 1.80 0.97 -2 -8 9 0.15 0.68 -2 -8 9 1.13 0.77 1 -10 -8 8.79 1.92 -1 10 8 6.33 2.09 -1 -10 8 6.94 1.80 -1 -10 8 5.05 1.29 9 -7 -6 244.56 5.62 -9 -7 6 244.40 12.75 -9 7 6 257.69 5.49 -9 -7 6 256.99 6.01 -10 1 4 10.50 3.59 -10 -1 4 14.88 3.03 10 -1 -4 9.31 2.08 10 1 -4 7.95 2.01 -5 -6 -5 3.44 1.41 -5 -6 -5 2.59 0.82 -5 6 -5 3.67 1.20 -5 6 -5 2.66 0.97 3 -15 -5 3.73 1.55 3 -15 -5 4.83 1.18 -3 -15 5 5.69 1.96 -3 -15 5 6.76 1.48 -3 -9 -6 0.09 0.97 3 -9 6 1.11 0.99 -3 9 -6 4.16 1.81 -3 -9 -6 0.61 1.18 -4 -6 -6 8.55 1.52 -4 -6 -6 8.72 2.33 -4 6 -6 10.07 1.46 -4 6 -6 8.28 1.49 -8 -9 1 136.09 3.96 -8 -9 1 134.21 5.09 8 -9 -1 129.10 3.25 -8 9 1 131.01 3.11 7 2 -10 32.56 3.12 7 -2 -10 41.08 3.57 -7 -2 10 23.15 2.42 -7 2 10 32.34 3.82 -6 8 9 34.41 3.16 6 -8 -9 27.24 6.94 -6 -8 9 28.88 6.94 -6 -8 9 34.78 4.36 -1 -7 -8 7.15 1.42 -1 7 -8 10.11 1.96 1 -7 8 14.98 2.54 -4 -14 -2 3.22 1.92 4 -14 2 4.01 1.58 -4 -14 -2 2.59 1.13 10 2 -5 0.72 0.73 10 -2 -5 0.51 0.70 -10 -2 5 0.59 1.25 -10 2 5 1.43 1.05 -10 0 6 115.78 4.38 10 0 -6 111.89 3.78 -3 -13 -4 1.24 2.02 3 -13 4 1.57 1.07 -3 -13 -4 1.53 1.13 9 6 -7 77.15 6.38 9 -6 -7 76.64 3.54 -9 6 7 76.88 3.54 -9 -6 7 85.89 9.48 -7 4 -3 35.31 2.60 -7 -4 -3 37.43 3.39 -7 -12 5 69.55 10.48 -7 -12 5 81.68 10.34 -7 12 5 71.90 2.53 7 -12 -5 85.20 8.69 -7 9 8 0.81 0.83 7 -9 -8 0.59 1.81 -7 -9 8 2.97 1.47 -7 -9 8 0.84 0.48 -1 -15 -4 2.70 1.45 -1 -15 -4 2.32 1.75 1 -15 4 2.50 1.81 -2 -3 10 1.94 1.15 -2 3 10 1.65 1.06 2 -3 -10 -0.01 1.17 2 3 -10 1.17 1.27 10 -1 -6 168.18 4.52 10 1 -6 180.80 4.84 -10 -1 6 169.23 7.24 -10 1 6 169.99 5.62 -2 -11 -6 55.67 4.79 -2 -11 -6 53.74 3.56 2 -11 6 56.75 7.81 2 -11 6 52.72 7.45 4 -9 -9 62.67 4.97 -4 9 9 75.25 5.23 -4 -9 9 72.14 3.24 -4 -9 9 59.86 10.60 9 4 -8 239.71 6.45 -9 4 8 221.29 6.02 9 -4 -8 240.82 6.27 -9 -4 8 228.92 10.45 -1 7 9 11.25 2.96 -1 -7 9 12.41 2.70 1 -7 -9 9.22 3.02 1 7 -9 10.95 2.91 -10 -2 4 94.90 4.24 10 2 -4 92.31 2.82 -10 2 4 94.89 3.70 10 -2 -4 78.58 3.78 1 -15 -5 44.19 2.82 1 -15 -5 43.67 3.23 -1 -15 5 42.00 3.61 -1 -15 5 47.66 3.56 0 -9 -8 42.35 3.04 0 9 8 36.50 8.04 0 -9 8 36.40 7.36 0 -9 8 44.30 5.79 -2 -16 -2 1.03 0.95 2 -16 2 3.90 1.36 -2 -16 -2 3.81 1.50 -4 -13 -3 1.85 1.52 -4 -13 -3 0.16 0.63 4 -13 3 1.74 1.58 -8 -10 2 0.13 1.14 -8 -10 2 1.41 0.82 -8 10 2 0.17 0.36 8 -10 -2 1.02 0.92 -9 -5 1 20.10 2.28 -9 5 1 19.15 4.82 -3 -5 10 8.77 2.04 3 -5 -10 7.67 1.96 -3 5 10 7.39 1.20 3 5 -10 5.28 1.39 -7 -7 9 52.03 7.24 7 -7 -9 48.99 3.44 7 7 -9 37.31 5.00 -7 7 9 50.58 2.99 0 5 9 2.05 0.92 0 -5 9 2.42 0.72 0 -5 -9 1.52 1.06 0 5 -9 3.40 1.38 -5 -15 2 22.93 2.79 -5 -15 2 24.18 2.63 5 -15 -2 23.10 6.87 -4 14 6 10.59 2.41 4 -14 -6 8.13 1.75 -4 -14 6 8.03 3.02 -4 -14 6 10.24 2.78 -2 -4 -8 11.00 2.17 -2 -4 -8 10.54 2.14 -2 4 -8 10.27 2.95 2 -4 8 6.18 1.71 -9 0 0 1.11 1.76 2 -16 -4 78.23 6.50 -2 -16 4 83.94 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1.67 -8 -8 0 164.01 6.73 -8 -8 0 153.90 3.81 8 -8 0 144.31 3.18 -8 8 0 157.21 3.95 6 -5 -10 2.05 1.87 -6 5 10 3.85 1.30 -6 -5 10 3.99 1.48 6 5 -10 4.21 1.78 -5 9 9 7.07 1.74 5 -9 -9 5.49 1.52 -5 -9 9 6.83 1.47 -5 -9 9 7.54 1.64 -8 5 9 32.70 3.43 -8 -5 9 26.57 2.93 8 -5 -9 32.16 2.80 8 5 -9 37.36 4.56 -8 9 7 25.01 6.33 -8 -9 7 31.86 2.91 -8 -9 7 24.22 6.39 8 -9 -7 30.24 2.76 -1 -14 -5 5.07 1.47 -1 -14 -5 5.45 1.58 1 -14 5 4.37 1.06 1 -14 5 5.43 2.12 -4 -15 -1 60.12 3.48 -4 -15 -1 56.48 3.62 4 -15 1 56.12 3.50 -2 -13 -5 10.73 1.94 -2 -13 -5 12.02 2.54 2 -13 5 9.43 2.20 2 -13 5 11.36 3.46 -6 -6 -4 117.82 5.19 -6 6 -4 126.41 4.10 -6 -14 3 8.50 1.88 -6 -14 3 7.29 1.87 6 -14 -3 6.01 1.85 2 -17 -1 13.79 2.67 -2 -17 1 12.46 3.04 -2 -17 1 13.61 2.47 1 -16 -4 1.02 0.87 -1 -16 4 0.77 0.58 1 -16 -4 1.63 1.37 -1 -16 4 0.80 1.25 -9 -8 5 9.56 2.05 -9 8 5 9.86 1.37 -9 -8 5 7.09 1.98 9 -8 -5 7.40 1.49 -8 6 -1 59.13 2.73 -8 -6 -1 71.75 4.19 -8 0 -2 1.21 1.25 -8 -10 6 6.86 1.78 -8 10 6 6.99 1.36 8 -10 -6 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1.97 5 6 -10 0.22 1.24 -5 -6 10 0.94 1.03 2 -4 -10 37.02 3.09 2 4 -10 41.94 3.32 -2 4 10 28.27 5.89 -2 -4 10 35.17 4.27 -6 -14 2 2.63 1.40 -6 -14 2 2.32 1.24 6 -14 -2 3.82 1.76 -4 15 5 128.99 6.88 4 -15 -5 182.33 6.51 -4 -15 5 144.49 5.53 -4 -15 5 162.78 4.54 -2 13 7 54.31 8.79 2 -13 -7 56.18 3.68 -2 -13 7 50.16 6.15 -2 -13 7 56.25 6.76 -7 8 -2 29.11 2.02 7 -8 2 17.73 2.43 -7 -8 -2 23.48 1.65 -7 -8 -2 25.03 2.71 2 -17 0 3.87 2.48 -2 -17 0 1.58 1.28 -2 -17 0 1.43 1.11 -10 -3 6 2.94 1.65 10 -3 -6 1.16 1.36 10 3 -6 2.43 1.44 -10 3 6 1.54 0.99 -7 -5 -3 4.13 1.45 -7 5 -3 6.68 1.51 -3 -16 4 84.43 4.38 3 -16 -4 83.52 6.07 3 -16 -4 76.10 6.90 -3 -16 4 95.82 3.41 2 -17 -2 30.82 5.92 -2 -17 2 32.30 3.00 -2 -17 2 22.37 5.52 -5 -15 1 105.88 4.73 -5 -15 1 100.99 4.22 5 -15 -1 96.78 4.55 -6 -14 4 47.79 9.35 -6 -14 4 55.24 10.31 6 -14 -4 52.75 3.50 -9 -8 3 4.12 1.21 -9 -8 3 1.81 1.28 -9 8 3 4.34 1.07 9 -8 -3 2.97 0.99 -7 -12 1 7.68 1.91 -7 -12 1 7.88 1.57 7 -12 -1 9.54 2.12 -8 -2 -2 39.31 3.43 -4 -16 1 6.41 2.21 -4 -16 1 6.17 1.55 4 -16 -1 4.19 1.60 -9 -5 8 68.81 11.35 9 -5 -8 74.13 11.70 9 5 -8 66.47 12.16 -9 5 8 84.85 3.85 6 -12 -7 28.86 2.84 -6 12 7 24.37 4.21 -6 -12 7 25.26 6.50 -6 -12 7 29.31 2.54 -10 -2 3 16.22 2.76 -10 2 3 14.57 4.35 1 0 9 7.39 2.22 -1 0 -9 6.82 1.34 -6 13 6 182.88 6.36 -6 -13 6 190.69 8.69 -6 -13 6 190.01 17.00 6 -13 -6 195.42 6.32 -5 -15 4 4.95 1.58 -5 -15 4 3.94 1.38 5 -15 -4 2.80 1.36 -6 -11 -2 5.97 1.44 -6 -11 -2 3.13 2.00 6 -11 2 3.56 1.04 7 4 -10 57.49 4.26 -7 4 10 61.43 3.77 -7 -4 10 49.35 4.97 7 -4 -10 68.15 5.49 -4 -16 3 8.44 2.32 -4 -16 3 13.68 2.31 4 -16 -3 9.57 1.98 -2 -9 -7 54.98 3.32 2 -9 7 49.05 7.56 -2 -9 -7 47.85 6.95 2 -9 7 57.85 6.95 -10 0 7 0.32 1.28 10 0 -7 1.11 1.13 10 -4 -5 8.11 1.24 10 4 -5 10.88 1.75 -10 4 5 10.52 3.27 -10 -4 5 11.23 2.54 -5 -7 -5 4.24 1.04 -5 7 -5 5.55 1.10 -5 -7 -5 3.42 1.35 -7 -10 -1 1.42 1.43 -7 -10 -1 0.73 0.82 7 -10 1 -0.06 0.45 -8 -11 4 4.10 1.49 -8 -11 4 5.38 1.79 -8 11 4 2.45 1.13 8 -11 -4 5.38 1.46 -1 1 -9 3.94 1.48 1 1 9 3.05 0.92 -1 -1 -9 1.77 0.89 1 -1 9 1.15 0.84 -5 -13 -2 45.96 4.85 -5 -13 -2 47.42 3.04 5 -13 2 49.75 2.97 -4 -7 -6 1.35 1.56 -4 7 -6 0.65 0.76 -4 -7 -6 0.82 1.07 -10 -1 7 16.93 2.23 -10 1 7 23.19 2.55 10 -1 -7 20.78 2.09 10 1 -7 20.40 2.49 2 -5 8 6.22 2.48 -2 -5 -8 5.35 1.81 -2 -5 -8 6.35 1.19 -2 5 -8 6.80 1.77 -9 -3 0 20.43 6.62 -9 3 0 23.09 2.13 -7 11 7 27.45 5.80 7 -11 -7 23.65 2.58 -7 -11 7 25.93 7.09 -7 -11 7 28.86 4.03 -5 -14 -1 3.58 1.76 -5 -14 -1 4.03 1.48 5 -14 1 6.83 1.57 -8 8 8 1.18 0.63 -8 -8 8 0.97 1.19 8 -8 -8 2.77 1.67 -8 -8 8 2.07 1.54 9 -7 -7 50.21 5.87 9 7 -7 46.82 7.92 -9 -7 7 46.23 4.40 -9 7 7 48.48 6.22 -4 -10 -5 4.13 1.61 -4 10 -5 3.98 1.24 4 -10 5 3.39 1.56 -4 -10 -5 3.60 1.44 -1 0 10 0.27 1.10 1 0 -10 1.70 1.85 9 0 -9 148.20 5.45 -9 0 9 142.92 12.03 -9 -8 6 31.42 7.72 9 -8 -6 31.84 2.48 -9 -8 6 29.29 4.94 -9 8 6 27.71 4.38 -10 -4 4 2.47 1.21 10 4 -4 3.21 1.04 -10 4 4 2.35 0.99 10 -4 -4 3.14 0.83 -9 6 1 43.75 2.83 -9 -6 1 48.87 3.22 3 -6 -10 19.26 5.18 3 6 -10 17.25 2.59 -3 -6 10 23.10 2.53 -3 6 10 16.76 2.73 4 -12 4 1.14 0.85 -4 -12 -4 2.44 1.19 -4 -12 -4 3.00 2.18 0 6 9 1.43 0.76 0 -6 -9 0.62 1.22 0 6 -9 0.58 0.97 0 -6 9 0.39 0.77 0 -12 -7 13.83 2.53 0 -12 -7 14.48 2.77 0 -12 7 16.24 3.25 0 -12 7 14.45 4.22 -8 -11 3 87.65 6.15 -8 -11 3 79.78 11.90 8 -11 -3 82.85 4.03 0 -15 -5 1.27 1.18 0 -15 -5 2.31 1.47 0 -15 5 0.39 0.38 0 -15 5 1.79 1.00 -1 1 10 4.83 1.50 -1 -1 10 5.93 1.56 1 -1 -10 8.30 2.08 1 1 -10 5.12 2.05 1 -8 8 7.69 3.29 -1 -8 -8 9.95 2.18 1 -8 8 7.08 1.86 -9 1 9 44.10 2.97 9 -1 -9 47.23 6.75 -9 -1 9 39.33 2.91 9 1 -9 41.04 6.50 -7 12 6 0.91 0.70 7 -12 -6 2.30 1.26 -7 -12 6 3.80 1.96 -7 -12 6 1.78 0.87 1 2 9 0.79 1.10 1 -2 9 1.57 1.10 -1 -2 -9 1.52 0.97 0 -16 -4 1.81 1.94 0 -16 4 0.63 1.28 0 -16 -4 0.49 0.88 3 -12 5 44.65 8.42 -3 -12 -5 55.38 3.79 -3 -12 -5 52.36 3.24 -8 3 -2 17.12 2.12 -8 -3 -2 20.27 3.06 2 -9 -9 14.05 4.07 -2 9 9 23.97 3.63 -2 -9 9 19.36 4.54 -2 -9 9 14.63 2.32 10 2 -7 21.80 3.04 -10 -2 7 24.49 2.64 -10 2 7 20.78 3.22 10 -2 -7 23.65 2.23 -10 -3 3 62.66 3.63 6 6 -10 15.65 2.61 6 -6 -10 14.05 2.48 -6 -6 10 17.67 2.43 -6 6 10 14.92 2.47 -5 0 -6 0.38 1.65 -5 -10 -4 4.13 2.07 5 -10 4 2.95 1.51 -5 -10 -4 1.89 1.22 -5 10 -4 2.21 0.72 10 4 -6 17.05 3.63 10 -4 -6 17.43 3.61 -10 -4 6 18.83 2.28 -10 4 6 17.27 2.16 -8 6 9 173.73 5.34 -8 -6 9 170.16 8.42 8 -6 -9 170.87 6.13 8 6 -9 160.56 13.59 -8 11 5 6.21 2.21 -8 -11 5 7.56 2.04 8 -11 -5 8.11 2.71 -8 -11 5 7.96 2.00 6 -9 -9 0.80 1.34 -6 9 9 1.43 1.45 -6 -9 9 -0.23 0.54 -6 -9 9 0.39 1.07 1 -8 -9 121.92 16.07 -1 8 9 124.89 16.24 -1 -8 9 162.18 10.45 -7 -13 3 84.19 4.96 -7 -13 3 82.84 7.38 7 -13 -3 89.47 4.05 -2 5 10 2.86 0.85 2 5 -10 3.72 1.73 2 -5 -10 3.24 1.63 -2 -5 10 3.10 1.51 -5 -1 -6 34.24 3.27 -5 1 -6 32.05 3.79 -5 -14 6 20.10 5.10 -5 14 6 13.59 2.54 -5 -14 6 18.51 2.91 5 -14 -6 13.83 5.05 -1 2 10 1.27 1.04 1 2 -10 1.00 0.64 1 -2 -10 1.99 1.66 -1 -2 10 1.32 1.82 -9 2 9 12.86 2.42 -9 -2 9 10.19 1.66 9 2 -9 11.41 2.47 9 -2 -9 11.09 2.33 -6 -14 1 27.48 2.66 -6 -14 1 25.30 2.96 6 -14 -1 22.60 2.58 -1 -11 -7 15.19 2.57 -1 -11 -7 17.13 2.83 1 -11 7 18.82 4.23 1 -11 7 14.98 4.72 -7 -13 4 8.79 2.90 -7 -13 4 7.20 1.89 7 -13 -4 6.60 1.83 -5 -13 7 26.21 4.81 -5 13 7 24.49 4.14 -5 -13 7 22.16 5.98 5 -13 -7 25.36 3.05 -1 -17 -2 34.07 5.22 1 -17 2 39.08 3.28 -1 -17 -2 38.93 3.17 3 -10 6 275.57 8.17 -3 -10 -6 262.05 6.95 -3 -10 -6 268.56 17.95 -3 10 -6 276.04 5.99 7 -8 -9 1.77 1.51 -7 8 9 2.61 1.28 -7 -8 9 0.15 1.01 8 0 -10 3.40 2.39 -8 0 10 2.36 1.60 -8 -10 1 10.03 2.28 -8 -10 1 12.77 2.48 8 -10 -1 14.11 1.77 1 -17 -3 245.54 7.54 1 -17 -3 257.73 5.58 -1 -17 3 238.28 4.45 -1 -17 3 245.23 7.20 -1 -13 -6 11.23 3.30 -1 -13 -6 14.23 2.47 1 -13 6 11.37 2.25 1 -13 6 11.68 3.50 -6 11 8 3.78 1.48 6 -11 -8 5.14 2.18 -6 -11 8 6.44 1.65 -6 -11 8 4.94 1.41 -6 7 -4 2.35 0.87 -6 -7 -4 3.49 1.21 6 -7 4 2.48 1.06 -6 -7 -4 3.19 1.65 -2 -17 -1 62.60 3.27 2 -17 1 60.08 4.00 -2 -17 -1 62.18 4.15 -8 -1 10 157.26 5.48 -8 1 10 165.70 6.21 8 1 -10 164.09 11.20 8 -1 -10 168.27 17.14 -8 7 -1 2.15 1.01 -8 -7 -1 1.43 1.47 -6 0 -5 0.64 1.40 1 -11 -8 184.62 6.40 -1 11 8 182.28 13.02 -1 -11 8 180.55 6.16 -1 -11 8 175.44 8.09 7 -10 -8 1.88 1.71 -7 10 8 1.40 1.18 -7 -10 8 1.82 0.82 -7 -10 8 0.91 1.12 -9 -4 0 2.98 1.71 -9 4 0 2.38 1.04 -2 -17 3 1.76 0.80 2 -17 -3 1.77 1.02 -2 -17 3 1.41 1.39 2 -17 -3 3.39 1.13 -4 12 8 55.49 8.64 4 -12 -8 59.54 3.88 -4 -12 8 55.18 7.81 -4 -12 8 56.04 2.94 -5 -2 -6 1.29 2.12 -5 2 -6 1.13 1.37 -1 3 -9 15.04 2.12 1 -3 9 11.26 2.56 1 3 9 12.48 2.98 -1 -3 -9 13.93 1.98 3 -12 -8 3.95 1.61 -3 12 8 2.83 1.76 -3 -12 8 2.41 1.23 -3 -12 8 2.36 1.26 -4 -16 0 13.98 2.20 -4 -16 0 10.18 2.54 4 -16 0 13.33 2.99 -4 0 -7 1.42 0.78 -4 0 -7 3.02 2.16 4 -10 -9 61.68 10.05 -4 10 9 87.41 11.64 -4 -10 9 78.93 7.88 -4 -10 9 83.54 3.86 -7 -6 -3 16.84 2.19 -7 6 -3 17.68 4.06 1 -13 -7 10.26 1.98 1 -13 -7 10.96 2.11 -1 -13 7 7.98 2.28 -1 -13 7 9.61 3.21 -4 7 10 46.23 6.44 4 -7 -10 31.73 3.16 4 7 -10 37.33 3.14 -4 -7 10 42.15 3.02 -5 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0 9.37 2.05 8 -9 0 6.74 1.10 -8 9 0 6.72 1.63 -4 -16 4 16.48 2.56 -4 -16 4 16.94 2.13 4 -16 -4 11.45 2.01 4 -16 -4 19.59 3.48 -10 0 2 8.84 2.22 8 -2 -10 2.26 1.51 8 2 -10 2.43 2.01 -8 2 10 1.31 0.90 -8 -2 10 1.88 1.04 -5 -15 0 2.79 2.16 -5 -15 0 1.27 1.28 5 -15 0 2.67 1.87 1 3 -10 33.65 3.06 -1 -3 10 29.81 7.65 1 -3 -10 32.63 4.82 -1 3 10 29.63 4.26 -8 -4 -2 46.70 3.58 -8 4 -2 35.87 2.56 0 -14 -6 98.94 4.76 0 -14 -6 114.04 5.49 0 -14 6 106.48 12.75 0 -14 6 106.69 3.23 -10 4 3 54.38 7.06 -10 -4 3 49.25 3.95 -9 -3 9 456.69 8.42 9 -3 -9 469.55 10.58 9 3 -9 452.45 9.88 -9 3 9 434.94 9.49 -9 -8 2 0.22 1.27 -9 -8 2 0.47 0.41 9 -8 -2 0.21 0.55 -9 8 2 0.47 0.89 -10 -5 4 106.00 11.60 -10 5 4 112.95 4.48 10 5 -4 110.62 6.85 10 -5 -4 112.87 3.27 -7 -13 2 27.48 2.64 -7 -13 2 32.46 2.92 7 -13 -2 30.28 3.10 9 -9 -5 0.77 0.90 -9 -9 5 1.37 1.08 -9 -9 5 1.30 0.88 -9 9 5 0.95 1.08 -3 -15 -3 5.99 1.72 -3 -15 -3 3.53 1.87 3 -15 3 5.25 1.88 -10 -1 2 17.59 2.84 -10 1 2 16.49 4.39 -6 2 -5 9.62 1.83 -6 -2 -5 6.66 1.74 -8 -11 2 49.41 3.51 -8 -11 2 45.40 3.20 8 -11 -2 44.22 5.65 -2 6 -8 15.43 2.39 2 -6 8 15.76 3.22 -2 -6 -8 17.22 2.42 -2 -6 -8 10.43 2.92 3 -10 -9 50.78 3.32 -3 10 9 56.11 9.17 -3 -10 9 54.48 9.31 -3 -10 9 56.82 9.56 -5 10 9 8.33 2.50 5 -10 -9 5.11 1.79 -5 -10 9 5.99 1.79 -5 -10 9 4.07 2.14 -4 2 -7 6.03 1.52 -4 -2 -7 4.67 1.24 -4 2 -7 6.07 1.85 -4 -2 -7 4.36 1.94 -2 -12 -6 29.00 3.20 -2 -12 -6 31.03 7.97 2 -12 6 24.24 4.46 2 -12 6 26.85 6.51 8 -10 -7 18.42 2.24 -8 10 7 18.01 3.01 -8 -10 7 25.22 3.36 -8 -10 7 19.50 3.95 0 -17 3 24.81 2.82 0 -17 -3 17.54 4.99 0 -17 -3 23.23 2.27 -2 -15 -4 10.22 2.25 -2 -15 -4 9.47 2.18 2 -15 4 11.46 2.31 -5 -3 -6 8.04 2.16 -5 3 -6 7.30 2.08 10 5 -6 1.39 1.60 -10 -5 6 1.66 1.22 -10 5 6 2.44 1.30 10 -5 -6 3.30 1.26 7 -13 -5 39.92 3.21 -7 13 5 22.44 5.23 -7 -13 5 35.65 8.26 -7 -13 5 34.95 6.35 5 -15 -5 15.43 2.42 -5 -15 5 12.93 2.14 -5 -15 5 12.71 1.95 -5 15 5 10.20 2.71 -7 -9 -2 119.60 3.57 -7 -9 -2 111.92 10.79 -7 9 -2 122.51 3.29 7 -9 2 124.46 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6.19 9 -9 -6 52.96 3.07 -9 9 6 49.02 6.94 -9 -9 6 51.11 8.22 -10 -3 2 2.19 2.16 -10 3 2 1.29 1.33 3 -14 -7 11.14 2.24 -3 14 7 8.89 2.56 -3 -14 7 9.07 1.49 -3 -14 7 10.86 2.04 -6 0 11 2.26 1.31 6 0 -11 -0.57 1.23 -8 5 -2 2.27 1.04 -8 -5 -2 0.87 1.45 -7 6 10 7.00 1.92 7 6 -10 5.87 2.29 7 -6 -10 4.74 1.86 -7 -6 10 8.29 1.98 -1 -9 -8 9.30 2.02 -1 -9 -8 6.82 1.97 1 -9 8 6.05 2.07 1 -9 8 7.17 2.00 -10 6 5 1.30 0.75 -10 -6 5 1.22 0.74 10 -6 -5 1.20 0.73 10 6 -5 0.39 0.84 -7 -1 -4 2.41 1.57 -7 1 -4 1.49 1.36 -10 -5 3 10.93 2.45 -10 5 3 9.76 2.25 -1 -16 -4 3.79 1.61 1 -16 4 1.61 1.50 -1 -16 -4 0.04 1.48 -3 0 -8 0.91 0.73 -3 0 -8 -0.11 1.68 -5 -4 -6 2.44 2.09 -5 4 -6 1.40 1.17 -6 -1 11 4.66 1.19 -6 1 11 3.00 1.76 6 -1 -11 2.27 1.39 6 1 -11 1.06 1.70 4 -15 -6 20.63 3.34 -4 15 6 14.12 3.65 -4 -15 6 25.23 5.12 -4 -15 6 19.72 5.51 0 -18 -1 0.95 1.35 0 -18 1 1.58 1.78 0 -18 -1 1.04 0.64 -2 -14 -5 0.78 1.32 -2 -14 -5 -0.07 1.47 2 -14 5 1.36 1.29 -7 -11 -1 89.40 4.66 -7 -11 -1 77.01 9.84 7 -11 1 79.65 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24.72 5.85 -2 -7 -8 18.38 2.44 -2 -7 -8 23.06 3.08 -2 7 -8 22.08 2.17 2 -17 -4 51.72 3.65 2 -17 -4 52.30 2.62 -2 -17 4 51.21 3.71 -2 -17 4 49.47 5.00 -5 -11 -4 1.80 0.96 5 -11 4 2.61 1.02 -5 -11 -4 6.13 2.16 -9 -1 -1 43.05 3.28 -9 1 -1 47.18 4.02 -6 -15 2 42.72 3.61 -6 -15 2 44.53 3.21 6 -15 -2 34.85 7.47 -8 -12 3 151.43 6.95 -8 -12 3 152.14 14.79 8 -12 -3 152.28 4.97 -1 -17 -3 1.03 1.48 1 -17 3 0.70 1.25 -1 -17 -3 1.57 0.99 4 3 -11 7.39 1.94 -4 -3 11 10.14 3.20 -4 3 11 9.46 2.87 4 -3 -11 8.88 2.17 -10 -4 2 62.69 3.76 -10 4 2 59.35 5.91 -6 14 6 74.15 7.49 6 -14 -6 90.55 5.65 -6 -14 6 84.83 12.18 -6 -14 6 82.91 5.86 -1 5 10 25.27 3.62 1 5 -10 24.94 8.00 1 -5 -10 28.72 2.89 -1 -5 10 27.84 5.01 10 3 -8 18.37 2.29 10 -3 -8 15.05 2.17 -10 -3 8 14.17 2.04 -10 3 8 13.84 2.99 9 5 -9 66.52 13.68 9 -5 -9 64.64 5.35 -9 -5 9 59.98 10.43 -9 5 9 65.43 8.38 1 -17 -4 0.26 0.86 1 -17 -4 0.98 1.37 -1 -17 4 1.44 1.88 -6 -15 4 7.68 2.96 -6 -15 4 10.19 3.27 6 -15 -4 7.15 2.02 -3 0 11 23.79 5.75 3 0 -11 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-10 85.81 4.55 -4 -17 1 20.64 4.63 -4 -17 1 15.35 2.24 4 -17 -1 12.62 2.24 7 0 -11 12.10 2.03 -7 0 11 13.04 2.41 -5 -9 -5 16.02 5.14 -5 -9 -5 17.30 2.49 -5 9 -5 19.92 1.75 5 -9 5 13.13 5.50 -7 -14 3 87.84 4.19 -7 -14 3 76.12 11.54 7 -14 -3 89.38 4.09 -2 -18 0 3.97 1.23 -2 -18 0 4.09 1.95 2 -18 0 5.19 2.10 -6 8 10 2.41 1.78 6 -8 -10 0.92 1.02 6 8 -10 0.89 1.19 -6 -8 10 3.44 1.92 8 -8 -9 2.58 1.70 -8 8 9 5.25 2.01 8 8 -9 1.92 1.15 -8 -8 9 4.68 2.03 -2 -18 2 9.11 2.61 -2 -18 2 10.72 2.22 2 -18 -2 12.70 2.47 -4 9 -6 59.05 2.84 -4 -9 -6 59.23 4.01 4 -9 6 54.80 3.13 -4 -9 -6 56.95 5.29 7 -7 -10 4.79 1.72 -7 7 10 5.92 2.86 7 7 -10 1.57 1.81 -7 -7 10 3.72 1.09 -4 -17 3 34.45 3.52 -4 -17 3 37.38 5.64 4 -17 -3 40.60 3.74 -6 5 -5 -0.11 0.93 -6 -5 -5 0.49 1.44 -7 1 11 8.56 2.13 7 -1 -11 11.50 2.32 -7 -1 11 9.74 2.12 7 1 -11 13.91 2.25 -10 7 5 14.74 3.73 -10 -7 5 12.41 2.65 10 7 -5 14.49 3.27 10 -7 -5 14.95 1.95 -10 0 1 0.47 1.29 -3 11 9 109.12 6.61 3 -11 -9 113.45 5.15 -3 -11 9 99.61 6.20 -3 -11 9 98.43 6.74 -7 -10 -2 5.32 1.32 -7 -10 -2 6.12 1.84 7 -10 2 5.47 1.87 -7 -14 4 11.83 2.21 7 -14 -4 18.14 3.83 -7 -14 4 12.13 2.72 5 -14 -7 4.64 1.69 -5 14 7 2.65 1.23 -5 -14 7 3.83 1.59 -5 -14 7 3.58 1.57 -4 13 8 18.96 3.86 4 -13 -8 18.50 2.77 -4 -13 8 17.98 3.97 -4 -13 8 17.79 3.62 4 4 -11 -0.50 1.20 4 -4 -11 1.63 1.47 -4 -4 11 2.39 1.52 -4 4 11 2.82 1.44 3 -13 -8 0.16 1.33 -3 13 8 2.00 1.39 -3 -13 8 2.75 1.26 -3 -13 8 2.96 1.50 5 -11 -9 8.40 2.07 -5 11 9 10.16 2.51 -5 -11 9 10.10 1.74 -5 -11 9 9.80 2.00 -4 -5 -7 3.39 2.07 -4 5 -7 2.91 1.63 -4 -5 -7 0.51 0.95 -4 5 -7 1.01 0.74 -9 -9 7 1.16 0.67 9 -9 -7 1.09 1.26 -9 -9 7 2.35 1.17 -9 9 7 0.99 1.04 -9 3 -1 26.97 8.23 -9 -3 -1 39.33 3.59 8 -11 -7 0.43 1.16 -8 11 7 0.86 0.77 -8 -11 7 1.05 0.57 -8 -11 7 2.53 1.84 -5 -13 -3 3.43 2.27 -5 -13 -3 0.61 1.37 5 -13 3 0.53 0.77 0 -16 -5 20.25 3.13 0 -16 -5 21.11 2.28 0 -16 5 23.43 3.34 -10 1 1 0.19 1.19 -10 -1 1 1.55 1.49 10 -4 -8 8.19 2.51 -10 -4 8 8.27 2.90 -10 4 8 9.48 1.91 10 4 -8 8.01 1.86 -1 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4 -8 37.40 2.50 -3 -4 -8 32.93 3.30 -3 4 -8 43.11 3.20 -3 -4 -8 36.90 3.03 3 -3 -11 4.32 1.89 -3 3 11 3.61 0.90 -3 -3 11 5.11 2.35 3 3 -11 4.25 2.21 0 -17 -4 30.12 2.46 0 -17 -4 28.84 3.02 0 -17 4 31.48 3.78 -7 8 -3 17.12 1.63 -7 -8 -3 20.06 2.85 -9 0 10 0.63 1.07 9 0 -10 1.14 1.51 -10 2 1 3.27 1.64 -10 -2 1 0.61 1.51 8 -10 -8 2.90 1.84 -8 10 8 3.39 1.35 -8 -10 8 4.35 1.90 -8 -10 8 4.80 1.58 10 7 -6 36.48 7.88 -10 7 6 40.05 6.44 10 -7 -6 40.89 2.77 -10 -7 6 39.62 4.08 -2 -13 -6 3.59 2.15 -2 -13 -6 3.69 1.73 2 -13 6 4.03 1.96 -8 0 -3 2.43 2.01 1 6 -10 9.69 3.40 1 -6 -10 8.77 3.36 -1 -6 10 10.10 2.81 -1 6 10 6.89 2.08 9 -1 -10 133.51 5.48 -9 1 10 124.57 13.60 -9 -1 10 120.57 11.23 9 1 -10 130.07 5.61 -9 -8 8 1.44 1.67 9 -8 -8 0.80 1.40 9 8 -8 1.03 1.29 -9 8 8 1.23 1.32 9 6 -9 116.11 14.97 9 -6 -9 111.80 9.09 -9 -6 9 97.29 7.76 -9 6 9 111.55 5.27 -9 -10 6 7.26 3.67 9 -10 -6 10.63 1.89 -9 -10 6 13.34 3.88 -9 10 6 10.69 2.77 6 -15 -5 9.87 2.09 -6 -15 5 6.68 3.30 -6 -15 5 7.71 2.57 -7 -14 2 2.00 1.91 -7 -14 2 2.72 1.53 7 -14 -2 0.26 0.95 -8 1 -3 8.00 2.76 -8 -1 -3 6.78 1.91 -8 12 6 19.02 3.40 8 -12 -6 20.55 3.83 -8 -12 6 17.05 5.15 -8 -12 6 22.26 2.86 -1 -10 -8 1.31 1.58 -1 -10 -8 2.76 1.62 1 -10 8 1.96 1.17 1 -10 8 1.90 1.30 -6 -9 -4 79.84 3.59 6 -9 4 68.86 2.60 -6 9 -4 75.93 2.74 -6 -9 -4 87.48 4.83 0 -3 -10 2.55 2.02 0 3 10 1.72 0.71 0 -3 10 1.31 0.89 0 3 -10 3.01 1.54 -2 0 -9 1.77 1.09 2 0 9 1.20 0.76 -8 -9 -1 0.06 1.39 0 -15 -6 23.74 2.91 0 -15 -6 23.04 2.43 0 -15 6 20.48 7.06 -2 -11 -7 54.02 4.58 -2 -11 -7 58.79 4.48 2 -11 7 46.22 10.22 2 -11 7 52.19 7.19 -5 5 11 16.00 3.44 5 5 -11 13.19 3.85 5 -5 -11 17.20 2.92 -5 -5 11 15.76 2.28 -2 -8 -8 106.57 5.12 -2 -8 -8 102.55 4.22 2 -8 8 105.98 9.53 -5 -6 -6 1.98 0.63 -5 -6 -6 2.91 1.73 -5 6 -6 1.20 0.95 -5 13 8 15.29 3.09 5 -13 -8 17.33 2.38 -5 -13 8 16.63 3.38 -5 -13 8 15.93 3.52 -9 4 -1 65.65 3.28 -9 -4 -1 71.25 4.23 4 -9 -10 1.25 1.26 -4 9 10 1.80 1.71 -4 -9 10 1.02 1.71 -4 -9 10 1.03 1.13 7 -14 -5 19.99 2.91 -7 -14 5 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78.21 4.38 3 5 -11 81.38 4.93 -8 -1 11 70.65 6.25 8 -1 -11 72.18 4.41 8 1 -11 71.11 9.10 -8 1 11 71.11 8.83 -10 8 6 46.52 2.77 -10 -8 6 52.89 3.64 10 -8 -6 46.81 2.90 -10 -8 6 45.21 5.82 4 -12 -9 10.23 2.26 -4 12 9 13.32 2.63 -4 -12 9 7.61 1.90 -4 -12 9 9.38 2.99 9 -10 -7 5.18 1.91 -9 10 7 7.39 1.56 -9 -10 7 7.00 2.56 -9 -10 7 4.37 1.49 8 -13 -5 53.11 3.34 -8 -13 5 48.00 9.00 -8 -13 5 48.81 11.43 9 4 -10 11.66 2.16 -9 4 10 10.42 2.06 9 -4 -10 12.25 2.55 -9 -4 10 8.54 2.32 2 -15 -7 2.17 1.35 2 -15 -7 4.04 1.54 -2 -15 7 3.22 1.24 -2 -15 7 4.94 1.67 -1 -17 -4 3.59 2.16 -1 -17 -4 1.86 1.21 1 -17 4 3.87 1.93 0 -12 -8 23.74 2.74 0 -12 -8 25.60 3.15 0 -12 8 26.52 6.80 0 -12 8 32.06 6.13 -5 -7 -6 1.69 1.91 -5 -7 -6 0.50 0.58 -5 7 -6 1.06 0.92 4 -6 -11 2.86 2.15 -4 6 11 1.47 0.78 4 6 -11 1.08 1.31 -4 -6 11 0.73 0.95 -7 -9 -3 27.92 3.13 -8 -4 -3 1.20 1.65 -8 4 -3 2.07 1.46 -2 -3 11 23.25 6.40 2 3 -11 18.92 2.99 2 -3 -11 16.74 4.44 -2 3 11 18.94 4.09 -1 -16 -5 68.10 10.67 -1 -16 -5 75.49 4.03 1 -16 5 79.45 4.44 10 -6 -8 10.66 2.56 -10 -6 8 13.18 2.47 10 6 -8 12.78 3.00 -10 6 8 12.37 2.13 -7 -11 -2 9.56 1.91 -7 -11 -2 9.40 2.16 7 -11 2 6.11 2.62 -6 -16 3 31.19 3.27 -6 -16 3 33.54 5.54 6 -16 -3 29.76 6.65 -1 -13 -7 9.54 2.26 -1 -13 -7 7.26 1.87 1 -13 7 8.28 2.89 1 -13 7 6.90 1.60 -11 3 5 56.57 11.60 -11 -3 5 53.23 5.73 1 -17 -5 2.57 1.43 1 -17 -5 5.98 1.48 -1 -17 5 4.39 1.91 -4 -14 -4 2.70 1.60 4 -14 4 0.85 1.33 -4 -14 -4 2.47 1.18 -11 2 4 0.61 1.00 -11 -2 4 0.71 1.01 0 -19 0 1.39 1.00 11 0 -7 12.47 1.75 -11 0 7 12.62 2.34 0 -14 -7 22.52 3.41 0 -14 -7 28.87 3.30 0 -14 7 17.43 4.44 0 -14 7 21.09 3.96 9 -9 -8 11.33 1.95 -9 9 8 9.81 3.03 -9 -9 8 13.36 2.28 -9 -9 8 13.42 3.63 -7 6 -4 6.60 1.62 -7 -6 -4 12.69 2.74 -6 13 8 0.91 0.48 6 -13 -8 1.04 1.48 -6 -13 8 1.41 0.98 -6 -13 8 1.30 0.77 7 -14 -6 4.49 2.31 -7 -14 6 2.64 1.35 -7 -14 6 3.50 1.48 1 -16 -6 41.25 2.92 1 -16 -6 46.85 3.59 -1 -16 6 37.36 5.05 -8 -2 11 156.24 5.40 -8 2 11 154.40 7.83 8 2 -11 155.49 6.18 8 -2 -11 162.71 13.63 -11 3 6 60.23 3.51 11 3 -6 39.51 8.95 11 -3 -6 34.09 7.76 -11 -3 6 54.91 3.53 11 -1 -7 15.35 1.94 -11 1 7 15.17 2.27 11 1 -7 17.04 3.72 -11 -1 7 17.91 2.47 0 -5 10 5.66 2.41 0 -5 -10 4.28 1.70 0 5 10 3.18 1.60 0 5 -10 5.40 1.43 6 -15 -6 10.98 3.57 -6 -15 6 7.09 1.78 -6 -15 6 7.40 2.73 8 -7 -10 46.54 10.70 -8 7 10 52.67 7.85 -8 -7 10 45.90 10.99 8 7 -10 47.45 3.79 -3 -14 -5 1.57 1.33 -3 -14 -5 1.14 1.53 3 -14 5 2.35 1.37 -5 -17 2 38.76 3.55 -5 -17 2 31.79 5.20 5 -17 -2 37.43 3.53 -9 -11 3 34.29 6.75 9 -11 -3 35.28 2.61 -9 -11 3 22.48 6.70 -6 6 11 2.75 2.04 6 -6 -11 6.55 2.42 6 6 -11 3.51 2.07 -6 -6 11 2.21 1.03 -2 -4 -9 4.28 1.36 -2 4 -9 6.04 1.48 -2 -4 -9 7.79 2.46 2 -4 9 1.71 0.90 1 -13 -8 3.16 2.07 1 -13 -8 0.64 1.41 -1 -13 8 1.45 0.98 -1 -13 8 -0.02 0.57 3 -12 -9 2.56 1.98 -3 12 9 1.88 1.38 -3 -12 9 2.22 1.08 -3 -12 9 1.21 1.20 -9 -8 0 5.87 2.76 -9 8 0 4.66 1.47 -5 -17 3 43.70 4.61 -5 -17 3 39.63 7.68 5 -17 -3 40.24 5.37 -3 -6 -8 0.43 0.78 -3 6 -8 1.63 0.92 -3 6 -8 1.28 1.11 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11 5.61 2.80 -15 -6 5 1.49 1.60 -1 -20 -9 3.41 2.12 -1 -20 -9 3.82 2.06 1 -20 9 3.70 2.98 -8 -16 -5 8.21 3.48 1 -16 -12 1.18 1.34 1 -16 -12 3.57 1.74 -1 -16 12 1.59 1.75 -5 -25 4 0.82 1.61 5 -25 -4 4.25 2.44 3 -24 -7 5.30 2.55 -3 -24 7 2.17 1.35 -8 -21 -1 1.06 1.80 0 -26 -3 1.61 2.61 0 -26 3 1.35 2.34 10 -20 -7 1.26 2.06 -10 -20 7 2.32 1.90 -10 -20 7 0.75 0.90 -11 10 14 0.59 0.97 11 -10 -14 0.50 1.44 11 10 -14 0.70 1.36 -11 -10 14 -0.58 1.18 5 -18 -12 1.76 2.07 -5 -18 12 1.33 1.36 5 -16 -13 7.99 2.82 13 -13 -10 1.15 1.19 -13 -13 10 3.96 2.46 13 13 -10 5.38 2.29 -11 -8 -4 4.01 2.43 -4 -13 14 1.16 1.37 -4 13 14 2.61 1.41 4 13 -14 1.26 1.41 4 -13 -14 3.01 1.75 5 10 -15 1.64 1.75 5 -10 -15 0.36 1.72 -5 -10 15 3.34 1.74 -5 10 15 1.44 0.74 5 -23 -8 1.21 1.71 -5 -23 8 3.74 2.41 4 -21 -10 1.04 2.38 -4 -21 10 3.18 2.50 -14 -11 9 2.47 1.57 -7 -7 -9 1.62 1.74 -2 -19 -9 2.30 1.90 2 -19 9 1.04 1.10 -12 -17 6 0.73 1.19 -5 -14 -9 -0.12 1.81 -15 -7 6 2.04 1.38 -2 -24 -5 0.57 1.43 2 -24 5 1.47 2.26 2 -23 -8 1.90 2.20 -2 -23 8 0.03 0.79 -3 -21 -7 0.48 1.43 3 -21 7 1.68 1.47 -13 -8 13 4.01 2.46 13 -8 -13 6.50 3.03 13 8 -13 6.58 2.34 -13 8 13 2.17 1.24 5 -21 -10 0.84 1.78 -5 -21 10 1.10 1.37 8 -5 -16 1.13 1.60 8 5 -16 3.24 3.13 -8 -5 16 0.85 1.24 -8 5 16 1.76 1.24 10 -17 -11 1.61 1.49 -10 -17 11 2.55 2.16 -10 -17 11 1.59 1.65 6 -18 -12 1.83 2.40 -6 -18 12 1.47 1.51 1 -20 -10 1.90 1.68 1 -20 -10 3.40 1.79 -1 -20 10 1.51 1.36 -8 -7 -8 0.64 1.67 13 -4 -14 1.46 1.58 13 4 -14 2.83 2.08 -13 -4 14 3.20 2.14 -13 4 14 3.09 1.79 9 -20 -9 2.49 2.32 -9 -20 9 1.23 1.01 -9 -20 9 1.13 1.25 12 2 -15 4.26 2.37 12 -2 -15 4.99 2.29 -12 -2 15 2.07 2.07 -12 2 15 1.99 2.12 -6 -24 0 2.29 2.38 6 -24 0 2.19 2.10 6 -5 -16 1.72 1.87 6 5 -16 1.40 2.50 -6 -5 16 2.53 1.91 -6 5 16 3.28 1.86 9 -18 -11 1.83 1.73 -9 -18 11 -0.05 1.08 -9 -18 11 1.68 1.90 -14 -8 2 2.12 2.25 -12 -16 9 4.01 1.84 -12 -16 9 1.47 1.71 12 -16 -9 1.78 1.36 -8 -14 -6 3.09 2.66 -12 -17 5 1.80 0.96 3 -26 0 0.77 0.97 -3 -26 0 2.80 1.94 -4 -3 -12 2.67 2.12 -4 3 -12 0.67 1.41 4 -24 -7 2.01 1.52 -4 -24 7 1.31 1.71 0 -25 -5 1.40 1.64 0 -25 5 2.30 1.97 -2 -22 -7 4.60 3.58 -2 -22 -7 4.05 1.99 2 -22 7 3.05 1.73 3 -8 -15 1.19 1.00 -3 -8 15 0.95 0.99 -3 8 15 0.97 1.62 3 8 -15 1.06 1.43 -7 -23 0 4.87 2.57 7 -23 0 3.81 2.26 -7 -23 0 2.76 1.76 0 -7 14 1.24 0.95 0 -7 -14 1.18 1.87 0 -7 -14 -0.08 0.94 0 7 -14 1.29 1.55 -4 -10 -11 0.50 1.90 9 -4 -16 2.59 1.77 9 4 -16 3.21 1.79 -9 4 16 1.73 1.85 -9 -4 16 2.61 1.93 12 8 -14 1.11 1.51 12 -8 -14 2.35 2.41 -12 -8 14 0.27 1.70 -12 8 14 1.10 1.21 14 3 -13 2.52 2.05 -14 3 13 0.93 0.86 14 -3 -13 2.65 2.05 -14 -3 13 0.48 1.20 -11 -15 -1 1.32 1.82 -3 -26 3 1.67 1.85 3 -26 -3 3.90 2.76 10 -19 -9 0.74 1.40 -10 -19 9 0.87 0.87 -10 -19 9 3.04 1.83 13 -12 -11 3.07 2.22 13 12 -11 4.16 2.47 0 -15 -12 1.48 1.58 0 -15 -12 -0.47 1.22 2 -24 -7 0.55 1.56 -2 -24 7 1.29 1.34 -7 16 13 2.62 1.57 7 -16 -13 3.97 2.35 -7 -16 13 5.31 2.41 -5 -20 -6 2.35 2.05 -14 7 12 2.01 1.55 14 -7 -12 2.19 1.24 14 7 -12 0.95 1.84 2 -17 -12 1.36 2.10 2 -17 -12 0.67 1.32 -2 -17 12 1.82 2.02 5 -4 -16 0.77 1.66 -5 4 16 2.60 1.82 -5 -4 16 4.71 2.10 5 4 -16 1.85 1.65 -10 0 16 4.17 1.91 10 0 -16 5.26 2.10 10 14 -13 1.12 1.59 10 -14 -13 0.45 1.42 -10 -14 13 3.01 1.65 2 -19 -11 2.29 1.85 -2 -19 11 1.43 0.97 4 -18 -12 1.77 1.73 -4 -18 12 0.84 1.13 6 -24 -6 3.68 2.39 -6 -24 6 6.82 2.76 8 -20 -10 5.47 2.52 -8 -20 10 7.33 4.09 9 -15 -13 2.09 2.27 9 15 -13 1.87 1.97 -9 -15 13 0.28 1.19 2 -22 -9 0.29 1.54 -2 -22 9 2.30 1.18 3 -21 -10 1.89 1.54 -3 -21 10 1.89 1.53 -5 -24 -2 8.84 2.61 5 -24 2 2.82 2.02 -6 -22 9 2.12 2.45 0 0 0 0.00 0.00 _computing_structure_solution 'SHELXT2018 (Sheldrick, 2015a)' ; _shelx_hkl_checksum 22199 _shelx_res_file ; TITL shelx_trans_a.res in P2(1)/n shelx_trans.res created by SHELXL-2018/3 at 14:43:02 on 20-Oct-2020 REM Old TITL AR-30A REM SHELXT solution in P2(1)/n: R1 0.215, Rweak 0.210, Alpha 0.057 REM 1.153 for 176 systematic absences, Orientation as input REM Formula found by SHELXT: C31 O9 CELL 0.71075 12.1473 20.6974 12.7019 90 117.432 90 ZERR 4 0.0084 0.0132 0.0088 0 0.005 0 LATT 1 SYMM 0.5-X,0.5+Y,0.5-Z SFAC C H O UNIT 120 128 40 L.S. 20 PLAN 2 TEMP -79.75 CONF list 4 MORE -1 BOND $H fmap 2 53 acta REM REM REM WGHT 0.060300 0.255500 FVAR 0.32381 O5 3 -0.534324 -0.896530 -0.491695 11.00000 0.05163 0.05114 = 0.04968 0.01391 0.02602 0.00796 O8 3 -0.063149 -0.484928 -0.264026 11.00000 0.04106 0.04794 = 0.05707 -0.01413 0.02370 -0.00986 O10 3 -0.421623 -0.608875 -0.369392 11.00000 0.04742 0.06156 = 0.06935 -0.02330 0.03895 -0.01630 O1 3 -0.410982 -0.782236 -0.766341 11.00000 0.05904 0.04586 = 0.07062 -0.00255 0.04713 -0.00291 O9 3 -0.272269 -0.508819 -0.252696 11.00000 0.04696 0.06728 = 0.06038 -0.02737 0.02846 -0.00688 O4 3 -0.733629 -0.833437 -0.504059 11.00000 0.05896 0.05651 = 0.05235 0.00160 0.03744 -0.00450 O3 3 -0.836227 -0.734628 -0.653859 11.00000 0.05399 0.05696 = 0.06653 0.01095 0.04069 0.01500 O7 3 -0.068246 -0.647431 -0.577265 11.00000 0.07913 0.06317 = 0.08023 -0.02052 0.06170 -0.02109 O2 3 -0.508957 -0.685208 -0.804403 11.00000 0.08780 0.05796 = 0.08519 0.02554 0.06149 0.01544 O6 3 -0.213213 -0.716040 -0.585380 11.00000 0.09025 0.07612 = 0.12906 -0.06023 0.08943 -0.04102 C22 1 -0.179457 -0.624298 -0.467519 11.00000 0.04148 0.03608 = 0.04128 0.00225 0.02356 0.00051 C23 1 -0.100528 -0.573997 -0.403230 11.00000 0.03928 0.03712 = 0.04236 0.00317 0.02173 0.00015 AFIX 43 H23 2 -0.026053 -0.566066 -0.408242 11.00000 -1.20000 AFIX 0 C16 1 -0.576356 -0.845015 -0.567752 11.00000 0.04109 0.03731 = 0.03524 0.00064 0.01625 -0.00052 C17 1 -0.518120 -0.822242 -0.632857 11.00000 0.03908 0.04234 = 0.04214 -0.00253 0.02122 0.00057 AFIX 43 H17 2 -0.446908 -0.843725 -0.628220 11.00000 -1.20000 AFIX 0 C24 1 -0.132785 -0.535620 -0.331596 11.00000 0.03611 0.03256 = 0.04114 -0.00084 0.01572 -0.00300 C15 1 -0.681754 -0.813831 -0.575354 11.00000 0.04160 0.04362 = 0.03905 -0.00348 0.02335 -0.00244 C25 1 -0.243693 -0.547379 -0.325255 11.00000 0.03977 0.04396 = 0.04066 -0.00561 0.02098 -0.00113 C13 1 -0.671252 -0.737026 -0.714949 11.00000 0.04544 0.04030 = 0.03907 0.00073 0.02054 0.00309 AFIX 43 H13 2 -0.702920 -0.700265 -0.764722 11.00000 -1.20000 AFIX 0 C26 1 -0.319080 -0.599434 -0.386749 11.00000 0.03762 0.04345 = 0.04502 -0.00412 0.02375 -0.00345 C27 1 -0.287583 -0.637957 -0.458545 11.00000 0.04473 0.03635 = 0.04516 -0.00416 0.02336 -0.00375 AFIX 43 H27 2 -0.338999 -0.673186 -0.501047 11.00000 -1.20000 AFIX 0 C14 1 -0.731126 -0.760707 -0.651199 11.00000 0.03647 0.04643 = 0.04049 -0.00277 0.02018 0.00416 C12 1 -0.564460 -0.768106 -0.704456 11.00000 0.04387 0.03995 = 0.03737 -0.00212 0.02277 -0.00080 C21 1 -0.146152 -0.662295 -0.548006 11.00000 0.04521 0.03929 = 0.05100 -0.00523 0.02686 -0.00525 C11 1 -0.494865 -0.739579 -0.764630 11.00000 0.05510 0.04633 = 0.04903 0.00069 0.03059 0.00338 C4 1 -0.177249 -0.879602 -0.692276 11.00000 0.03934 0.05874 = 0.05676 -0.01450 0.02851 -0.00833 C5 1 -0.238516 -0.870019 -0.815157 11.00000 0.04631 0.05054 = 0.05724 -0.01008 0.03499 -0.00761 C10 1 -0.247633 -0.922536 -0.888542 11.00000 0.05518 0.06239 = 0.06055 -0.01598 0.03344 -0.00927 AFIX 43 H10 2 -0.289511 -0.916916 -0.972157 11.00000 -1.20000 AFIX 0 C28 1 0.057621 -0.475371 -0.257169 11.00000 0.04471 0.05659 = 0.06659 -0.00665 0.02801 -0.01182 AFIX 137 H28A 2 0.102045 -0.441634 -0.198753 11.00000 -1.50000 H28B 2 0.048105 -0.462181 -0.335020 11.00000 -1.50000 H28C 2 0.104755 -0.515805 -0.233077 11.00000 -1.50000 AFIX 0 C20 1 -0.421195 -0.926648 -0.477230 11.00000 0.06271 0.06110 = 0.05150 0.01589 0.02711 0.02020 AFIX 137 H20A 2 -0.396467 -0.960181 -0.416071 11.00000 -1.50000 H20B 2 -0.355552 -0.894039 -0.453290 11.00000 -1.50000 H20C 2 -0.434660 -0.946199 -0.552497 11.00000 -1.50000 AFIX 0 C7 1 -0.128610 -0.940035 -0.647025 11.00000 0.04103 0.07164 = 0.06006 -0.00284 0.02006 -0.00234 AFIX 43 H7 2 -0.088559 -0.946604 -0.563626 11.00000 -1.20000 AFIX 0 C8 1 -0.137568 -0.990894 -0.721573 11.00000 0.04736 0.05120 = 0.09320 -0.00951 0.03147 -0.00376 AFIX 43 H8 2 -0.102523 -1.031730 -0.689360 11.00000 -1.20000 AFIX 0 C9 1 -0.197735 -0.981865 -0.842954 11.00000 0.05478 0.05690 = 0.07954 -0.02695 0.03251 -0.01214 AFIX 43 H9 2 -0.204577 -1.016519 -0.894666 11.00000 -1.20000 AFIX 0 C30 1 -0.495934 -0.664506 -0.422623 11.00000 0.05301 0.06260 = 0.08569 -0.02511 0.04267 -0.02193 AFIX 137 H30A 2 -0.443400 -0.703145 -0.399175 11.00000 -1.50000 H30B 2 -0.535756 -0.660060 -0.509144 11.00000 -1.50000 H30C 2 -0.559692 -0.668526 -0.396115 11.00000 -1.50000 AFIX 0 C1 1 -0.308028 -0.758415 -0.785502 11.00000 0.06848 0.04844 = 0.08519 -0.00294 0.06024 -0.00704 AFIX 13 H1 2 -0.325391 -0.713680 -0.818984 11.00000 -1.20000 AFIX 0 C6 1 -0.290164 -0.804819 -0.870051 11.00000 0.06951 0.05873 = 0.06583 -0.00389 0.05098 -0.00282 AFIX 23 H6A 2 -0.371033 -0.811385 -0.941016 11.00000 -1.20000 H6B 2 -0.233138 -0.784768 -0.896544 11.00000 -1.20000 AFIX 0 C3 1 -0.165675 -0.825111 -0.607038 11.00000 0.05189 0.07838 = 0.06168 -0.02604 0.02895 -0.00555 AFIX 23 H3A 2 -0.224050 -0.833192 -0.574052 11.00000 -1.20000 H3B 2 -0.080588 -0.825177 -0.540246 11.00000 -1.20000 AFIX 0 C2 1 -0.192516 -0.759319 -0.665603 11.00000 0.06725 0.06429 = 0.09616 -0.04190 0.06305 -0.02411 AFIX 13 H2 2 -0.119290 -0.744180 -0.674891 11.00000 -1.20000 AFIX 0 C18 1 -0.886992 -0.677632 -0.723888 11.00000 0.07000 0.05721 = 0.09834 0.02160 0.05417 0.02653 AFIX 137 H18A 2 -0.825022 -0.643004 -0.695129 11.00000 -1.50000 H18B 2 -0.960837 -0.663973 -0.717325 11.00000 -1.50000 H18C 2 -0.909800 -0.686979 -0.807053 11.00000 -1.50000 AFIX 0 C29 1 -0.378632 -0.468063 -0.312921 11.00000 0.06776 0.06319 = 0.11108 -0.02535 0.04898 0.00516 AFIX 137 H29A 2 -0.386657 -0.439387 -0.255441 11.00000 -1.50000 H29B 2 -0.453246 -0.494839 -0.351972 11.00000 -1.50000 H29C 2 -0.368699 -0.442105 -0.372516 11.00000 -1.50000 AFIX 0 C19 1 -0.825344 -0.882484 -0.553729 11.00000 0.06831 0.09927 = 0.07533 -0.00193 0.04078 -0.03008 AFIX 137 H19A 2 -0.856009 -0.894023 -0.497085 11.00000 -1.50000 H19B 2 -0.788930 -0.920687 -0.571186 11.00000 -1.50000 H19C 2 -0.894300 -0.866544 -0.627148 11.00000 -1.50000 AFIX 0 HKLF 4 REM shelx_trans_a.res in P2(1)/n REM wR2 = 0.1635, GooF = S = 1.154, Restrained GooF = 1.154 for all data REM R1 = 0.0696 for 4312 Fo > 4sig(Fo) and 0.1139 for all 6351 data REM 367 parameters refined using 0 restraints END WGHT 0.0603 0.2514 REM Highest difference peak 0.207, deepest hole -0.198, 1-sigma level 0.039 Q1 1 -0.3194 -0.8536 -0.5947 11.00000 0.05 0.21 Q2 1 -0.0357 -0.6813 -0.5232 11.00000 0.05 0.19 ; _shelx_res_checksum 6764 loop_ _space_group_symop_operation_xyz 'x, y, z' '-x+1/2, y+1/2, -z+1/2' '-x, -y, -z' 'x-1/2, -y-1/2, z-1/2' loop_ _atom_site_type_symbol _atom_site_label _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_U_iso_or_equiv _atom_site_adp_type _atom_site_calc_flag _atom_site_occupancy _atom_site_disorder_assembly _atom_site_disorder_group O O5 -0.53432(15) -0.89653(8) -0.49170(14) 0.0498(4) Uani d 1 . . O O8 -0.06315(14) -0.48493(8) -0.26403(14) 0.0483(4) Uani d 1 . . O O10 -0.42162(15) -0.60887(8) -0.36939(16) 0.0547(5) Uani d 1 . . O O1 -0.41098(16) -0.78224(7) -0.76634(15) 0.0518(5) Uani d 1 . . O O9 -0.27227(15) -0.50882(8) -0.25270(15) 0.0568(5) Uani d 1 . . O O4 -0.73363(16) -0.83344(8) -0.50406(14) 0.0513(4) Uani d 1 . . O O3 -0.83623(15) -0.73463(8) -0.65386(15) 0.0541(5) Uani d 1 . . O O7 -0.06825(17) -0.64743(9) -0.57726(17) 0.0644(5) Uani d 1 . . O O2 -0.50896(18) -0.68521(9) -0.80440(17) 0.0685(6) Uani d 1 . . O O6 -0.21321(19) -0.71604(9) -0.5854(2) 0.0833(7) Uani d 1 . . C C22 -0.1795(2) -0.62430(10) -0.46752(19) 0.0379(5) Uani d 1 . . C C23 -0.1005(2) -0.57400(10) -0.40323(19) 0.0384(5) Uani d 1 . . H H23 -0.026053 -0.566066 -0.408242 0.046 Uiso calc 1 . . C C16 -0.5764(2) -0.84501(10) -0.56775(18) 0.0384(5) Uani d 1 . . C C17 -0.5181(2) -0.82224(11) -0.63286(19) 0.0402(5) Uani d 1 . . H H17 -0.446908 -0.843725 -0.628220 0.048 Uiso calc 1 . . C C24 -0.1328(2) -0.53562(10) -0.33160(19) 0.0374(5) Uani d 1 . . C C15 -0.6818(2) -0.81383(11) -0.57535(19) 0.0396(5) Uani d 1 . . C C25 -0.2437(2) -0.54738(11) -0.32526(19) 0.0405(5) Uani d 1 . . C C13 -0.6713(2) -0.73703(11) -0.71495(19) 0.0412(5) Uani d 1 . . H H13 -0.702920 -0.700265 -0.764722 0.049 Uiso calc 1 . . C C26 -0.3191(2) -0.59943(11) -0.3867(2) 0.0402(5) Uani d 1 . . C C27 -0.2876(2) -0.63796(11) -0.4585(2) 0.0411(5) Uani d 1 . . H H27 -0.338999 -0.673186 -0.501047 0.049 Uiso calc 1 . . C C14 -0.7311(2) -0.76071(11) -0.65120(19) 0.0402(5) Uani d 1 . . C C12 -0.5645(2) -0.76811(11) -0.70446(19) 0.0388(5) Uani d 1 . . C C21 -0.1462(2) -0.66230(11) -0.5480(2) 0.0433(6) Uani d 1 . . C C11 -0.4949(2) -0.73958(12) -0.7646(2) 0.0476(6) Uani d 1 . . C C4 -0.1772(2) -0.87960(13) -0.6923(2) 0.0491(6) Uani d 1 . . C C5 -0.2385(2) -0.87002(12) -0.8152(2) 0.0470(6) Uani d 1 . . C C10 -0.2476(2) -0.92254(13) -0.8885(2) 0.0567(7) Uani d 1 . . H H10 -0.289511 -0.916916 -0.972157 0.068 Uiso calc 1 . . C C28 0.0576(2) -0.47537(12) -0.2572(2) 0.0550(7) Uani d 1 . . H H28A 0.102045 -0.441634 -0.198753 0.083 Uiso calc 1 . . H H28B 0.048105 -0.462181 -0.335020 0.083 Uiso calc 1 . . H H28C 0.104755 -0.515805 -0.233077 0.083 Uiso calc 1 . . C C20 -0.4212(2) -0.92665(13) -0.4772(2) 0.0581(7) Uani d 1 . . H H20A -0.396467 -0.960181 -0.416071 0.087 Uiso calc 1 . . H H20B -0.355552 -0.894039 -0.453290 0.087 Uiso calc 1 . . H H20C -0.434660 -0.946199 -0.552497 0.087 Uiso calc 1 . . C C7 -0.1286(2) -0.94004(14) -0.6470(3) 0.0588(7) Uani d 1 . . H H7 -0.088559 -0.946604 -0.563626 0.071 Uiso calc 1 . . C C8 -0.1376(2) -0.99089(14) -0.7216(3) 0.0643(8) Uani d 1 . . H H8 -0.102523 -1.031730 -0.689360 0.077 Uiso calc 1 . . C C9 -0.1977(2) -0.98186(14) -0.8430(3) 0.0631(8) Uani d 1 . . H H9 -0.204577 -1.016519 -0.894666 0.076 Uiso calc 1 . . C C30 -0.4959(2) -0.66451(13) -0.4226(3) 0.0629(8) Uani d 1 . . H H30A -0.443400 -0.703145 -0.399175 0.094 Uiso calc 1 . . H H30B -0.535756 -0.660060 -0.509144 0.094 Uiso calc 1 . . H H30C -0.559692 -0.668526 -0.396115 0.094 Uiso calc 1 . . C C1 -0.3080(3) -0.75842(13) -0.7855(3) 0.0577(7) Uani d 1 . . H H1 -0.325391 -0.713680 -0.818984 0.069 Uiso calc 1 . . C C6 -0.2902(3) -0.80482(12) -0.8701(2) 0.0570(7) Uani d 1 . . H H6A -0.371033 -0.811385 -0.941016 0.068 Uiso calc 1 . . H H6B -0.233138 -0.784768 -0.896544 0.068 Uiso calc 1 . . C C3 -0.1657(3) -0.82511(14) -0.6070(2) 0.0629(8) Uani d 1 . . H H3A -0.224050 -0.833192 -0.574052 0.075 Uiso calc 1 . . H H3B -0.080588 -0.825177 -0.540246 0.075 Uiso calc 1 . . C C2 -0.1925(3) -0.75932(13) -0.6656(3) 0.0660(9) Uani d 1 . . H H2 -0.119290 -0.744180 -0.674891 0.079 Uiso calc 1 . . C C18 -0.8870(3) -0.67763(13) -0.7239(3) 0.0692(8) Uani d 1 . . H H18A -0.825022 -0.643004 -0.695129 0.104 Uiso calc 1 . . H H18B -0.960837 -0.663973 -0.717325 0.104 Uiso calc 1 . . H H18C -0.909800 -0.686979 -0.807053 0.104 Uiso calc 1 . . C C29 -0.3786(3) -0.46806(14) -0.3129(3) 0.0776(9) Uani d 1 . . H H29A -0.386657 -0.439387 -0.255441 0.116 Uiso calc 1 . . H H29B -0.453246 -0.494839 -0.351972 0.116 Uiso calc 1 . . H H29C -0.368699 -0.442105 -0.372516 0.116 Uiso calc 1 . . C C19 -0.8253(3) -0.88248(16) -0.5537(3) 0.0780(9) Uani d 1 . . H H19A -0.856009 -0.894023 -0.497085 0.117 Uiso calc 1 . . H H19B -0.788930 -0.920687 -0.571186 0.117 Uiso calc 1 . . H H19C -0.894300 -0.866544 -0.627148 0.117 Uiso calc 1 . . loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_12 _atom_site_aniso_U_13 _atom_site_aniso_U_23 O5 0.0516(11) 0.0511(10) 0.0497(10) 0.0080(8) 0.0260(9) 0.0139(8) O8 0.0411(10) 0.0479(10) 0.0571(10) -0.0099(8) 0.0237(8) -0.0141(8) O10 0.0474(10) 0.0616(11) 0.0693(12) -0.0163(9) 0.0389(9) -0.0233(9) O1 0.0590(11) 0.0459(10) 0.0706(12) -0.0029(8) 0.0471(10) -0.0026(8) O9 0.0470(10) 0.0673(12) 0.0604(11) -0.0069(9) 0.0285(9) -0.0274(9) O4 0.0590(11) 0.0565(10) 0.0524(10) -0.0045(9) 0.0374(9) 0.0016(8) O3 0.0540(11) 0.0570(11) 0.0665(11) 0.0150(9) 0.0407(9) 0.0110(9) O7 0.0791(13) 0.0632(12) 0.0802(13) -0.0211(10) 0.0617(12) -0.0205(10) O2 0.0878(14) 0.0580(12) 0.0852(14) 0.0154(10) 0.0615(12) 0.0255(10) O6 0.0903(15) 0.0761(14) 0.1291(18) -0.0410(12) 0.0894(15) -0.0602(13) C22 0.0415(13) 0.0361(12) 0.0413(12) 0.0005(10) 0.0236(11) 0.0022(10) C23 0.0393(13) 0.0371(12) 0.0424(12) 0.0002(10) 0.0217(11) 0.0032(10) C16 0.0411(14) 0.0373(13) 0.0352(12) -0.0005(10) 0.0162(11) 0.0006(10) C17 0.0391(13) 0.0423(13) 0.0421(12) 0.0006(10) 0.0212(11) -0.0025(10) C24 0.0361(13) 0.0326(12) 0.0411(12) -0.0030(10) 0.0157(11) -0.0008(10) C15 0.0416(13) 0.0436(13) 0.0390(12) -0.0024(11) 0.0234(11) -0.0035(10) C25 0.0398(14) 0.0440(13) 0.0407(13) -0.0011(11) 0.0210(11) -0.0056(10) C13 0.0454(14) 0.0403(13) 0.0391(12) 0.0031(11) 0.0205(11) 0.0007(10) C26 0.0376(13) 0.0435(13) 0.0450(13) -0.0034(11) 0.0237(11) -0.0041(10) C27 0.0447(14) 0.0364(13) 0.0452(13) -0.0037(10) 0.0234(11) -0.0042(10) C14 0.0365(13) 0.0464(14) 0.0405(12) 0.0042(11) 0.0202(11) -0.0028(10) C12 0.0439(14) 0.0400(13) 0.0374(12) -0.0008(11) 0.0228(11) -0.0021(10) C21 0.0452(15) 0.0393(13) 0.0510(14) -0.0053(11) 0.0269(12) -0.0052(11) C11 0.0551(16) 0.0463(15) 0.0490(14) 0.0034(12) 0.0306(13) 0.0007(12) C4 0.0393(14) 0.0587(16) 0.0568(16) -0.0083(12) 0.0285(13) -0.0145(13) C5 0.0463(15) 0.0505(15) 0.0572(15) -0.0076(12) 0.0350(13) -0.0101(12) C10 0.0552(17) 0.0624(18) 0.0605(16) -0.0093(14) 0.0334(14) -0.0160(14) C28 0.0447(15) 0.0566(16) 0.0666(17) -0.0118(13) 0.0280(14) -0.0066(13) C20 0.0627(18) 0.0611(17) 0.0515(15) 0.0202(14) 0.0271(14) 0.0159(13) C7 0.0410(15) 0.0716(19) 0.0601(17) -0.0023(14) 0.0201(13) -0.0028(15) C8 0.0474(17) 0.0512(17) 0.093(2) -0.0038(13) 0.0315(17) -0.0095(16) C9 0.0548(18) 0.0569(18) 0.080(2) -0.0121(14) 0.0325(16) -0.0270(16) C30 0.0530(17) 0.0626(17) 0.086(2) -0.0219(14) 0.0427(16) -0.0251(15) C1 0.0685(19) 0.0484(15) 0.085(2) -0.0070(13) 0.0602(18) -0.0029(14) C6 0.0695(18) 0.0587(17) 0.0658(17) -0.0028(14) 0.0510(15) -0.0039(13) C3 0.0519(17) 0.078(2) 0.0617(17) -0.0055(15) 0.0290(14) -0.0260(15) C2 0.0673(19) 0.0643(19) 0.096(2) -0.0241(15) 0.0630(19) -0.0419(17) C18 0.0700(19) 0.0572(17) 0.098(2) 0.0265(15) 0.0542(18) 0.0216(16) C29 0.068(2) 0.0632(19) 0.111(3) 0.0052(16) 0.0490(19) -0.0254(18) C19 0.068(2) 0.099(2) 0.075(2) -0.0301(18) 0.0408(17) -0.0019(18) loop_ _atom_type_symbol _atom_type_description _atom_type_scat_dispersion_real _atom_type_scat_dispersion_imag _atom_type_scat_source C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' loop_ _geom_angle_atom_site_label_1 _geom_angle_atom_site_label_2 _geom_angle_atom_site_label_3 _geom_angle_site_symmetry_1 _geom_angle_site_symmetry_3 _geom_angle _geom_angle_publ_flag C16 O5 C20 . . 116.76(18) ? C24 O8 C28 . . 117.33(18) ? C26 O10 C30 . . 117.43(18) ? C11 O1 C1 . . 119.26(19) ? C25 O9 C29 . . 115.2(2) ? C15 O4 C19 . . 114.81(19) ? C14 O3 C18 . . 117.91(18) ? C21 O6 C2 . . 119.15(19) ? C23 C22 C27 . . 121.4(2) ? C23 C22 C21 . . 117.8(2) ? C27 C22 C21 . . 120.8(2) ? C22 C23 H23 . . 120.6 ? C24 C23 C22 . . 118.9(2) ? C24 C23 H23 . . 120.6 ? O5 C16 C17 . . 123.7(2) ? O5 C16 C15 . . 116.13(19) ? C17 C16 C15 . . 120.1(2) ? C16 C17 H17 . . 120.1 ? C12 C17 C16 . . 119.9(2) ? C12 C17 H17 . . 120.1 ? O8 C24 C23 . . 124.5(2) ? O8 C24 C25 . . 115.27(19) ? C23 C24 C25 . . 120.2(2) ? O4 C15 C16 . . 120.0(2) ? O4 C15 C14 . . 120.1(2) ? C16 C15 C14 . . 119.9(2) ? O9 C25 C24 . . 118.7(2) ? O9 C25 C26 . . 121.2(2) ? C26 C25 C24 . . 120.0(2) ? C14 C13 H13 . . 120.4 ? C12 C13 H13 . . 120.4 ? C12 C13 C14 . . 119.3(2) ? O10 C26 C25 . . 115.40(19) ? O10 C26 C27 . . 124.5(2) ? C27 C26 C25 . . 120.1(2) ? C22 C27 H27 . . 120.3 ? C26 C27 C22 . . 119.3(2) ? C26 C27 H27 . . 120.3 ? O3 C14 C15 . . 115.10(19) ? O3 C14 C13 . . 124.9(2) ? C15 C14 C13 . . 120.0(2) ? C17 C12 C13 . . 120.8(2) ? C17 C12 C11 . . 119.9(2) ? C13 C12 C11 . . 119.1(2) ? O7 C21 O6 . . 122.8(2) ? O7 C21 C22 . . 125.3(2) ? O6 C21 C22 . . 111.84(19) ? O1 C11 C12 . . 110.9(2) ? O2 C11 O1 . . 124.1(2) ? O2 C11 C12 . . 125.0(2) ? C5 C4 C3 . . 121.0(2) ? C7 C4 C5 . . 119.7(2) ? C7 C4 C3 . . 119.3(2) ? C4 C5 C10 . . 118.0(2) ? C4 C5 C6 . . 122.3(2) ? C10 C5 C6 . . 119.7(2) ? C5 C10 H10 . . 119.1 ? C9 C10 C5 . . 121.9(3) ? C9 C10 H10 . . 119.1 ? O8 C28 H28A . . 109.5 ? O8 C28 H28B . . 109.5 ? O8 C28 H28C . . 109.5 ? H28A C28 H28B . . 109.5 ? H28A C28 H28C . . 109.5 ? H28B C28 H28C . . 109.5 ? O5 C20 H20A . . 109.5 ? O5 C20 H20B . . 109.5 ? O5 C20 H20C . . 109.5 ? H20A C20 H20B . . 109.5 ? H20A C20 H20C . . 109.5 ? H20B C20 H20C . . 109.5 ? C4 C7 H7 . . 119.5 ? C8 C7 C4 . . 121.1(3) ? C8 C7 H7 . . 119.5 ? C7 C8 H8 . . 120.2 ? C9 C8 C7 . . 119.6(3) ? C9 C8 H8 . . 120.2 ? C10 C9 C8 . . 119.7(3) ? C10 C9 H9 . . 120.2 ? C8 C9 H9 . . 120.2 ? O10 C30 H30A . . 109.5 ? O10 C30 H30B . . 109.5 ? O10 C30 H30C . . 109.5 ? H30A C30 H30B . . 109.5 ? H30A C30 H30C . . 109.5 ? H30B C30 H30C . . 109.5 ? O1 C1 H1 . . 110.7 ? O1 C1 C6 . . 108.3(2) ? O1 C1 C2 . . 107.1(2) ? C6 C1 H1 . . 110.7 ? C2 C1 H1 . . 110.7 ? C2 C1 C6 . . 109.3(2) ? C5 C6 C1 . . 113.5(2) ? C5 C6 H6A . . 108.9 ? C5 C6 H6B . . 108.9 ? C1 C6 H6A . . 108.9 ? C1 C6 H6B . . 108.9 ? H6A C6 H6B . . 107.7 ? C4 C3 H3A . . 109.0 ? C4 C3 H3B . . 109.0 ? H3A C3 H3B . . 107.8 ? C2 C3 C4 . . 112.8(2) ? C2 C3 H3A . . 109.0 ? C2 C3 H3B . . 109.0 ? O6 C2 C1 . . 108.3(2) ? O6 C2 C3 . . 106.0(2) ? O6 C2 H2 . . 109.8 ? C1 C2 H2 . . 109.8 ? C3 C2 C1 . . 113.2(2) ? C3 C2 H2 . . 109.8 ? O3 C18 H18A . . 109.5 ? O3 C18 H18B . . 109.5 ? O3 C18 H18C . . 109.5 ? H18A C18 H18B . . 109.5 ? H18A C18 H18C . . 109.5 ? H18B C18 H18C . . 109.5 ? O9 C29 H29A . . 109.5 ? O9 C29 H29B . . 109.5 ? O9 C29 H29C . . 109.5 ? H29A C29 H29B . . 109.5 ? H29A C29 H29C . . 109.5 ? H29B C29 H29C . . 109.5 ? O4 C19 H19A . . 109.5 ? O4 C19 H19B . . 109.5 ? O4 C19 H19C . . 109.5 ? H19A C19 H19B . . 109.5 ? H19A C19 H19C . . 109.5 ? H19B C19 H19C . . 109.5 ? loop_ _geom_bond_atom_site_label_1 _geom_bond_atom_site_label_2 _geom_bond_site_symmetry_2 _geom_bond_distance _geom_bond_publ_flag O5 C16 . 1.370(3) ? O5 C20 . 1.442(3) ? O8 C24 . 1.373(3) ? O8 C28 . 1.443(3) ? O10 C26 . 1.375(3) ? O10 C30 . 1.427(3) ? O1 C11 . 1.356(3) ? O1 C1 . 1.465(3) ? O9 C25 . 1.379(3) ? O9 C29 . 1.434(3) ? O4 C15 . 1.381(3) ? O4 C19 . 1.422(3) ? O3 C14 . 1.372(3) ? O3 C18 . 1.434(3) ? O7 C21 . 1.205(3) ? O2 C11 . 1.213(3) ? O6 C21 . 1.330(3) ? O6 C2 . 1.463(3) ? C22 C23 . 1.396(3) ? C22 C27 . 1.399(3) ? C22 C21 . 1.486(3) ? C23 H23 . 0.9500 ? C23 C24 . 1.393(3) ? C16 C17 . 1.395(3) ? C16 C15 . 1.397(3) ? C17 H17 . 0.9500 ? C17 C12 . 1.388(3) ? C24 C25 . 1.407(3) ? C15 C14 . 1.402(3) ? C25 C26 . 1.397(3) ? C13 H13 . 0.9500 ? C13 C14 . 1.403(3) ? C13 C12 . 1.398(3) ? C26 C27 . 1.391(3) ? C27 H27 . 0.9500 ? C12 C11 . 1.498(3) ? C4 C5 . 1.400(4) ? C4 C7 . 1.390(4) ? C4 C3 . 1.524(3) ? C5 C10 . 1.403(3) ? C5 C6 . 1.516(4) ? C10 H10 . 0.9500 ? C10 C9 . 1.374(4) ? C28 H28A . 0.9800 ? C28 H28B . 0.9800 ? C28 H28C . 0.9800 ? C20 H20A . 0.9800 ? C20 H20B . 0.9800 ? C20 H20C . 0.9800 ? C7 H7 . 0.9500 ? C7 C8 . 1.386(4) ? C8 H8 . 0.9500 ? C8 C9 . 1.381(4) ? C9 H9 . 0.9500 ? C30 H30A . 0.9800 ? C30 H30B . 0.9800 ? C30 H30C . 0.9800 ? C1 H1 . 1.0000 ? C1 C6 . 1.529(3) ? C1 C2 . 1.523(4) ? C6 H6A . 0.9900 ? C6 H6B . 0.9900 ? C3 H3A . 0.9900 ? C3 H3B . 0.9900 ? C3 C2 . 1.513(4) ? C2 H2 . 1.0000 ? C18 H18A . 0.9800 ? C18 H18B . 0.9800 ? C18 H18C . 0.9800 ? C29 H29A . 0.9800 ? C29 H29B . 0.9800 ? C29 H29C . 0.9800 ? C19 H19A . 0.9800 ? C19 H19B . 0.9800 ? C19 H19C . 0.9800 ? loop_ _geom_torsion_atom_site_label_1 _geom_torsion_atom_site_label_2 _geom_torsion_atom_site_label_3 _geom_torsion_atom_site_label_4 _geom_torsion_site_symmetry_1 _geom_torsion_site_symmetry_2 _geom_torsion_site_symmetry_3 _geom_torsion_site_symmetry_4 _geom_torsion _geom_torsion_publ_flag O5 C16 C17 C12 . . . . -177.5(2) ? O5 C16 C15 O4 . . . . 3.2(3) ? O5 C16 C15 C14 . . . . -179.90(19) ? O8 C24 C25 O9 . . . . -0.8(3) ? O8 C24 C25 C26 . . . . -177.4(2) ? O10 C26 C27 C22 . . . . -178.8(2) ? O1 C1 C6 C5 . . . . -70.1(3) ? O1 C1 C2 O6 . . . . -61.3(3) ? O1 C1 C2 C3 . . . . 55.9(3) ? O9 C25 C26 O10 . . . . 0.0(3) ? O9 C25 C26 C27 . . . . -179.4(2) ? O4 C15 C14 O3 . . . . -4.5(3) ? O4 C15 C14 C13 . . . . 173.9(2) ? C22 C23 C24 O8 . . . . 179.86(19) ? C22 C23 C24 C25 . . . . -0.4(3) ? C23 C22 C27 C26 . . . . 1.9(3) ? C23 C22 C21 O7 . . . . -12.5(4) ? C23 C22 C21 O6 . . . . 167.4(2) ? C23 C24 C25 O9 . . . . 179.5(2) ? C23 C24 C25 C26 . . . . 2.9(3) ? C16 C17 C12 C13 . . . . -1.9(3) ? C16 C17 C12 C11 . . . . 173.8(2) ? C16 C15 C14 O3 . . . . 178.59(19) ? C16 C15 C14 C13 . . . . -3.1(3) ? C17 C16 C15 O4 . . . . -175.08(19) ? C17 C16 C15 C14 . . . . 1.9(3) ? C17 C12 C11 O1 . . . . 17.2(3) ? C17 C12 C11 O2 . . . . -161.3(2) ? C24 C25 C26 O10 . . . . 176.5(2) ? C24 C25 C26 C27 . . . . -2.9(3) ? C15 C16 C17 C12 . . . . 0.6(3) ? C25 C26 C27 C22 . . . . 0.5(3) ? C13 C12 C11 O1 . . . . -167.11(19) ? C13 C12 C11 O2 . . . . 14.4(4) ? C27 C22 C23 C24 . . . . -2.0(3) ? C27 C22 C21 O7 . . . . 166.3(2) ? C27 C22 C21 O6 . . . . -13.7(3) ? C14 C13 C12 C17 . . . . 0.6(3) ? C14 C13 C12 C11 . . . . -175.0(2) ? C12 C13 C14 O3 . . . . 180.0(2) ? C12 C13 C14 C15 . . . . 1.8(3) ? C21 O6 C2 C1 . . . . -113.0(3) ? C21 O6 C2 C3 . . . . 125.3(3) ? C21 C22 C23 C24 . . . . 176.9(2) ? C21 C22 C27 C26 . . . . -176.9(2) ? C11 O1 C1 C6 . . . . -138.2(2) ? C11 O1 C1 C2 . . . . 104.0(2) ? C4 C5 C10 C9 . . . . -0.5(4) ? C4 C5 C6 C1 . . . . -19.2(3) ? C4 C7 C8 C9 . . . . -1.2(4) ? C4 C3 C2 O6 . . . . 164.0(2) ? C4 C3 C2 C1 . . . . 45.4(3) ? C5 C4 C7 C8 . . . . 1.3(4) ? C5 C4 C3 C2 . . . . -16.2(3) ? C5 C10 C9 C8 . . . . 0.6(4) ? C10 C5 C6 C1 . . . . 163.2(2) ? C28 O8 C24 C23 . . . . -7.0(3) ? C28 O8 C24 C25 . . . . 173.3(2) ? C20 O5 C16 C17 . . . . 2.0(3) ? C20 O5 C16 C15 . . . . -176.2(2) ? C7 C4 C5 C10 . . . . -0.4(3) ? C7 C4 C5 C6 . . . . -178.1(2) ? C7 C4 C3 C2 . . . . 165.3(2) ? C7 C8 C9 C10 . . . . 0.3(4) ? C30 O10 C26 C25 . . . . -175.0(2) ? C30 O10 C26 C27 . . . . 4.3(3) ? C1 O1 C11 O2 . . . . 17.9(4) ? C1 O1 C11 C12 . . . . -160.6(2) ? C6 C5 C10 C9 . . . . 177.2(2) ? C6 C1 C2 O6 . . . . -178.4(2) ? C6 C1 C2 C3 . . . . -61.2(3) ? C3 C4 C5 C10 . . . . -178.9(2) ? C3 C4 C5 C6 . . . . 3.4(3) ? C3 C4 C7 C8 . . . . 179.8(2) ? C2 O6 C21 O7 . . . . -0.1(4) ? C2 O6 C21 C22 . . . . 180.0(2) ? C2 C1 C6 C5 . . . . 46.3(3) ? C18 O3 C14 C15 . . . . 176.1(2) ? C18 O3 C14 C13 . . . . -2.1(3) ? C29 O9 C25 C24 . . . . 113.3(2) ? C29 O9 C25 C26 . . . . -70.1(3) ? C19 O4 C15 C16 . . . . -89.8(3) ? C19 O4 C15 C14 . . . . 93.3(3) ? _cod_database_fobs_code 2022278