#------------------------------------------------------------------------------ #$Date: 2020-11-25 07:11:19 +0200 (Wed, 25 Nov 2020) $ #$Revision: 259242 $ #$URL: file:///home/coder/svn-repositories/cod/cif/2/02/22/2022279.cif $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2022279 loop_ _publ_author_name 'Rutherford, Ryan Noboru' 'Ura, Shinji' 'Chan, Tak-Hang' 'Fukumoto, Kozo' 'Nishioka, Takanori' 'Renzetti, Andrea' _publ_section_title ; Dibenzoate esters of cis-tetralin-2,3-diol as analogs of (--)-epigallocatechin gallate: synthesis and crystal structure of anticancer drug candidates ; _journal_coeditor_code OP3007 _journal_issue 12 _journal_name_full 'Acta Crystallographica Section C' _journal_page_first ; ; _journal_paper_doi 10.1107/S2053229620014916 _journal_volume 76 _journal_year 2020 _chemical_formula_iupac 'C24 H14 F6 O4' _chemical_formula_moiety 'C24 H14 F6 O4' _chemical_formula_sum 'C24 H14 F6 O4' _chemical_formula_weight 480.35 _chemical_name_systematic ; (2R,3S)-1,2,3,4-Tetrahydronaphthalene-2,3-diyl bis(3,4,5-trifluorobenzoate) ; _space_group_crystal_system monoclinic _space_group_IT_number 15 _space_group_name_Hall '-C 2yc' _space_group_name_H-M_alt 'C 1 2/c 1' _atom_sites_solution_hydrogens geom _atom_sites_solution_primary dual _audit_creation_method ; Olex2 1.3 (compiled 2020.02.04 svn.rd84adfe8 for OlexSys, GUI svn.r6032) ; _cell_angle_alpha 90 _cell_angle_beta 97.204(4) _cell_angle_gamma 90 _cell_formula_units_Z 8 _cell_length_a 30.399(10) _cell_length_b 9.176(3) _cell_length_c 14.994(5) _cell_measurement_reflns_used 4720 _cell_measurement_temperature 193.4 _cell_measurement_theta_max 27.4794 _cell_measurement_theta_min 3.0057 _cell_volume 4149(2) _computing_cell_refinement ; CrystalClear (Rigaku, 2008) ; _computing_data_collection ; CrystalClear (Rigaku, 2008) ; _computing_data_reduction ; CrystalClear (Rigaku, 2008) ; _computing_molecular_graphics ; OLEX2 (Dolomanov et al., 2009) ; _computing_publication_material ; OLEX2 (Dolomanov et al., 2009) ; _computing_structure_refinement ; SHELXL2018 (Sheldrick, 2015b) ; _computing_structure_solution ; SHELXT2018 (Sheldrick, 2015a) ; _diffrn_ambient_temperature 193.4 _diffrn_detector_area_resol_mean 28.5714 _diffrn_measured_fraction_theta_full 0.995 _diffrn_measured_fraction_theta_max 0.995 _diffrn_measurement_device ; Rigaku Saturn724+ (2x2 bin mode) ; _diffrn_measurement_device_type 'Rigaku Saturn724+ (2x2 bin mode)' _diffrn_measurement_method dtprofit.ref _diffrn_radiation_type MoK\a _diffrn_radiation_wavelength 0.71075 _diffrn_reflns_av_R_equivalents 0.0360 _diffrn_reflns_av_unetI/netI 0.0291 _diffrn_reflns_limit_h_max 39 _diffrn_reflns_limit_h_min -39 _diffrn_reflns_limit_k_max 11 _diffrn_reflns_limit_k_min -11 _diffrn_reflns_limit_l_max 19 _diffrn_reflns_limit_l_min -19 _diffrn_reflns_number 20773 _diffrn_reflns_theta_full 25.242 _diffrn_reflns_theta_max 27.446 _diffrn_reflns_theta_min 3.006 _exptl_absorpt_coefficient_mu 0.140 _exptl_absorpt_correction_T_max 1.0000 _exptl_absorpt_correction_T_min 0.7129 _exptl_absorpt_correction_type empirical _exptl_absorpt_process_details DTABSCOR _exptl_crystal_colour colourless _exptl_crystal_density_diffrn 1.538 _exptl_crystal_description prism _exptl_crystal_F_000 1952 _exptl_crystal_size_max 0.175 _exptl_crystal_size_mid 0.094 _exptl_crystal_size_min 0.092 _refine_diff_density_max 0.196 _refine_diff_density_min -0.278 _refine_ls_extinction_method none _refine_ls_goodness_of_fit_ref 1.006 _refine_ls_hydrogen_treatment constr _refine_ls_matrix_type full _refine_ls_number_parameters 307 _refine_ls_number_reflns 4718 _refine_ls_number_restraints 0 _refine_ls_restrained_S_all 1.006 _refine_ls_R_factor_all 0.0572 _refine_ls_R_factor_gt 0.0410 _refine_ls_shift/su_max 0.000 _refine_ls_shift/su_mean 0.000 _refine_ls_structure_factor_coef Fsqd _refine_ls_weighting_details 'w=1/[\s^2^(Fo^2^)+(0.0689P)^2^] where P=(Fo^2^+2Fc^2^)/3' _refine_ls_weighting_scheme calc _refine_ls_wR_factor_gt 0.1111 _refine_ls_wR_factor_ref 0.1204 _reflns_number_gt 3317 _reflns_number_total 4718 _reflns_threshold_expression 'I > 2\s(I)' _cod_data_source_file op3007sup1.cif _cod_data_source_block 6 _cod_original_cell_volume 4150(2) _cod_database_code 2022279 _shelx_space_group_comment ; The symmetry employed for this shelxl refinement is uniquely defined by the following loop, which should always be used as a source of symmetry information in preference to the above space-group names. They are only intended as comments. ; _shelx_hkl_file ; 3 1 0 7013.48 17.93 -4 0 -1 0.04 0.36 4 0 1 0.46 0.71 -4 0 -1 -0.04 0.61 4 0 1 0.04 0.41 -4 0 -1 0.15 0.74 3 -1 -1 39.20 1.94 3 -1 -1 39.15 1.56 -3 -1 1 36.92 1.47 3 1 -1 39.16 1.56 3 1 -1 36.35 1.65 -3 -1 1 40.49 1.79 3 -1 -1 39.26 1.69 -3 1 1 38.03 1.60 -3 1 1 40.99 1.83 -3 1 1 35.18 1.47 -2 0 -2 134.32 1.40 2 0 2 142.93 1.72 -2 0 -2 144.97 1.75 -2 0 -2 156.36 2.76 2 0 2 159.77 2.62 3 1 1 1029.92 8.39 3 -1 1 1095.16 8.10 -3 1 -1 1120.44 8.36 3 -1 1 1041.95 8.37 3 1 1 1038.82 8.27 -3 1 -1 1126.16 8.86 -3 -1 -1 1122.42 7.15 1 -1 -2 67.56 2.36 -1 -1 2 59.48 2.28 1 1 -2 63.33 2.50 1 -1 -2 68.27 2.63 -1 -1 2 62.66 2.19 1 1 -2 63.48 2.20 1 -1 -2 61.14 2.17 -1 -1 2 70.32 2.77 1 1 -2 62.23 2.48 1 -1 -2 58.98 2.25 4 0 -2 226.87 3.24 4 0 -2 221.97 2.90 -1 -1 -2 899.18 7.53 1 -1 2 930.74 7.79 -1 -1 -2 896.76 6.00 1 1 2 846.94 7.11 -1 -1 -2 901.20 7.45 -1 1 -2 933.10 6.32 1 -1 2 867.17 7.57 3 -1 -2 0.38 0.99 3 1 -2 0.35 0.52 3 -1 -2 0.18 0.36 -3 -1 2 0.70 0.47 3 -1 -2 0.30 0.70 -3 1 2 0.34 0.53 3 1 -2 0.66 0.86 -3 -1 2 0.00 0.74 3 -1 -2 0.38 0.53 -3 -1 2 0.30 0.55 -3 1 2 0.20 0.46 3 1 -2 0.47 0.64 -5 -1 0 184.39 3.20 5 1 0 200.02 2.80 5 -1 0 185.81 2.83 -5 1 0 190.01 3.16 5 1 0 184.08 3.05 -5 -1 0 192.90 2.67 -5 1 0 173.30 3.06 5 -1 0 184.45 3.03 5 1 0 185.91 2.51 -5 -1 0 200.63 2.60 -5 1 0 187.20 2.96 6 0 0 4391.99 12.90 6 0 0 4513.41 11.39 -6 0 0 4473.69 11.38 -4 0 -2 1358.95 11.58 4 0 2 1334.79 11.05 4 0 2 1396.08 10.21 4 0 2 1402.31 9.87 0 0 3 0.06 0.18 0 0 3 0.70 0.97 0 0 -3 1.01 1.22 0 0 3 0.24 0.44 0 0 -3 0.03 0.20 0 0 -3 0.89 0.95 6 0 -1 0.24 0.57 -6 0 1 0.01 0.27 -6 0 1 0.08 0.61 6 0 -1 0.46 0.71 -6 0 1 0.58 1.27 6 0 -1 0.22 0.25 -2 0 3 0.58 0.83 2 0 -3 0.18 0.54 2 0 -3 0.05 0.15 2 0 -3 0.17 0.54 -2 0 3 0.35 0.52 2 0 -3 0.49 0.54 -3 1 -2 550.89 6.17 3 -1 2 553.24 4.58 -3 -1 -2 569.14 5.96 3 1 2 599.29 5.93 -3 1 -2 545.76 5.66 3 1 2 589.64 6.01 -5 -1 -1 0.85 0.37 5 1 1 0.62 0.28 5 -1 1 0.64 0.51 -5 1 -1 0.54 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1 414.31 5.13 -2 -2 1 418.45 5.26 -1 -1 -3 4223.36 28.76 -1 -1 -3 4298.95 12.30 3 1 -3 76.72 3.31 3 -1 -3 77.40 2.78 -3 1 3 88.09 3.13 -3 1 3 75.48 3.19 3 -1 -3 76.20 2.97 -3 -1 3 73.25 2.74 3 -1 -3 75.74 2.91 -3 -1 3 80.89 3.09 3 1 -3 75.55 2.74 -3 1 3 76.02 4.00 2 2 1 242.08 2.94 -2 2 -1 249.77 4.27 -2 2 -1 246.79 3.67 2 -2 1 231.59 3.68 -2 -2 -1 249.75 4.38 -2 -2 -1 261.34 3.21 2 -2 1 250.21 4.59 2 2 1 239.44 4.06 6 0 2 99.35 3.51 -6 0 -2 104.06 3.55 6 0 2 105.94 3.88 -6 0 -2 109.77 4.07 -6 0 -2 119.09 4.52 -4 0 -3 0.13 0.56 4 0 3 -0.18 0.56 4 0 3 -0.01 0.37 -4 0 -3 0.00 0.52 -4 0 -3 1.39 1.81 4 2 0 1182.11 9.22 -4 -2 0 1244.74 11.33 -4 2 0 1247.80 11.84 4 2 0 1218.52 10.71 4 -2 0 1163.27 10.17 0 -2 -2 279.43 4.66 0 2 2 272.80 3.14 0 -2 -2 269.27 3.12 0 -2 2 294.20 4.51 0 -2 2 270.46 3.72 0 2 -2 262.08 4.31 7 1 0 339.85 3.95 -7 1 0 336.20 4.40 -7 -1 0 344.30 3.99 -7 -1 0 348.69 5.02 -7 1 0 367.82 5.27 -7 -1 0 353.99 4.16 7 1 0 340.89 4.07 7 1 -1 58.72 2.35 7 -1 -1 48.33 2.30 -7 -1 1 51.81 2.33 -7 -1 1 52.62 2.60 -7 1 1 52.26 2.71 7 -1 -1 46.27 2.06 -7 1 1 47.64 2.21 -7 -1 1 48.20 1.91 -4 2 1 115.01 4.28 -4 -2 1 110.18 4.41 -4 2 1 123.67 4.96 4 2 -1 120.47 4.37 -4 -2 1 117.59 4.60 4 -2 -1 107.25 3.98 3 -1 3 180.15 3.52 3 1 3 176.80 3.28 -3 1 -3 176.83 3.61 -3 1 -3 182.21 2.20 -3 -1 -3 180.88 3.11 3 1 3 178.55 3.08 3 1 3 175.70 1.76 -2 -2 2 318.48 4.37 2 2 -2 317.97 4.15 -2 -2 2 318.06 4.77 2 -2 -2 312.94 3.82 -2 2 2 307.14 3.74 -2 2 2 313.48 4.53 2 2 -2 340.10 5.59 -2 2 2 339.27 4.87 -6 0 3 0.11 0.38 -6 0 3 0.37 0.97 8 0 0 542.55 5.53 -8 0 0 564.67 6.65 -8 0 0 550.15 5.78 8 0 0 580.22 6.25 -8 0 1 0.47 1.61 8 0 -1 -0.09 0.34 -8 0 1 -0.04 0.53 5 1 -3 26.91 1.35 -5 -1 3 25.82 1.25 -5 1 3 25.59 1.83 -5 -1 3 25.67 1.73 -5 1 3 25.57 1.62 -5 -1 3 26.29 2.12 -5 1 3 24.30 1.16 5 -1 -3 24.23 1.13 5 1 -3 25.18 1.58 2 -2 2 39.94 1.82 2 2 2 39.33 2.11 2 2 2 42.83 1.60 -2 2 -2 40.36 3.38 -2 -2 -2 45.06 1.82 2 -2 2 44.31 3.14 -2 -2 -2 41.98 2.37 -2 2 -2 41.60 1.91 -7 -1 -1 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64.72 3.37 -6 -2 2 55.04 2.64 -6 2 2 54.94 2.77 -6 2 2 62.72 2.69 6 2 -2 67.85 2.88 6 -2 -2 67.41 3.08 -4 0 -4 122.44 4.88 4 0 4 119.24 4.20 4 0 4 118.83 4.05 -4 0 -4 109.07 4.06 -4 0 -4 117.26 4.01 -4 2 3 368.18 4.84 4 2 -3 354.58 4.80 -4 -2 3 335.78 5.42 4 -2 -3 362.88 4.78 -9 -1 1 343.44 5.31 9 1 -1 347.00 4.26 -9 -1 1 337.62 4.32 -9 1 1 327.81 4.27 9 -1 -1 320.01 4.11 -9 1 1 342.43 5.37 -9 -1 1 341.04 4.70 9 -1 -1 345.94 5.20 -5 -1 4 2524.35 8.36 -5 1 4 2590.01 12.02 -5 -1 4 2617.68 10.09 3 -1 4 55.66 2.78 -3 -1 -4 51.53 1.89 3 1 4 55.95 2.08 -3 -1 -4 58.34 2.54 -3 1 -4 56.34 1.93 -3 1 -4 57.65 3.29 9 1 0 2078.44 9.35 -9 -1 0 2097.91 11.72 -1 -3 0 1908.73 10.60 -10 0 1 -0.26 0.56 -10 0 1 0.56 1.07 10 0 -1 -0.03 0.86 9 -1 -2 127.14 4.31 -9 -1 2 127.94 4.82 -9 1 2 124.91 4.95 -9 1 2 131.83 4.50 -9 -1 2 132.03 4.37 9 1 -2 126.02 4.25 9 -1 -2 117.23 4.55 -10 0 0 508.63 6.84 10 0 0 481.77 5.83 -9 1 -1 0.32 1.08 9 1 1 0.74 0.36 9 1 1 1.04 0.71 9 1 1 0.54 0.44 -9 1 -1 0.80 1.16 -9 -1 -1 0.08 1.13 9 -1 1 0.60 0.63 -2 0 5 0.33 0.83 2 0 -5 0.00 0.33 -2 0 5 0.10 0.32 2 0 -5 -0.27 0.71 -6 -2 -2 1805.25 11.48 6 2 2 1804.47 11.58 -6 2 -2 1751.21 11.35 -6 -2 -2 1772.80 4.90 -1 3 1 329.38 5.30 1 3 -1 318.80 5.41 -1 -3 1 342.05 5.85 1 -3 -1 352.62 6.49 -1 -3 1 312.18 4.86 1 -3 -1 356.26 5.04 -4 2 -3 2310.54 16.15 0 0 5 0.30 0.67 0 0 -5 0.10 0.19 0 0 -5 0.32 0.36 3 3 0 10.17 1.22 -3 3 0 9.63 1.42 -3 3 0 9.22 1.76 -3 -3 0 11.23 2.45 3 -3 0 9.98 1.34 -10 0 2 1023.79 7.88 -10 0 2 962.41 7.27 -10 0 2 1001.54 10.53 -10 0 2 948.41 9.84 -6 2 3 100.30 3.79 6 2 -3 101.18 3.84 -6 -2 3 98.37 3.91 -6 -2 3 93.77 4.05 6 -2 -3 103.03 4.20 8 2 0 1665.49 9.50 8 -2 0 1684.39 10.58 -8 2 1 260.59 4.49 8 -2 -1 259.18 4.77 -8 -2 1 265.42 4.16 8 2 -1 250.12 4.07 -8 2 1 260.63 5.20 7 1 3 7.36 3.67 -7 1 -3 5.11 1.01 -7 1 -3 5.29 1.00 -7 -1 -3 4.77 0.97 7 -1 3 5.54 0.89 -7 -1 -3 5.18 1.01 4 0 -5 -0.04 0.37 -4 0 5 -0.47 0.97 4 0 -5 0.24 0.63 -4 0 5 0.00 0.65 4 0 -5 -0.19 0.52 -3 3 1 84.52 3.73 3 3 -1 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215.28 11.34 -17 5 4 108.69 6.75 -17 5 4 106.63 7.42 -17 -5 4 112.91 7.31 -17 -5 4 111.71 6.67 17 5 -4 102.92 6.22 17 -5 -4 97.54 6.16 0 -6 -7 55.70 4.25 0 -6 7 55.64 8.05 0 -6 -7 66.60 12.87 0 6 7 54.89 4.49 0 6 -7 56.68 4.96 0 -6 7 50.83 5.55 6 -6 6 0.71 1.24 -6 -6 -6 0.92 1.04 6 6 6 0.62 0.97 -6 6 -6 -0.26 1.18 6 -6 6 -0.05 1.33 6 0 -12 2.97 1.57 -6 0 12 4.06 2.33 -6 0 12 2.16 1.57 -15 -5 -4 16.17 5.72 15 -5 4 14.89 3.93 15 5 4 16.58 6.61 -15 5 -4 15.20 2.75 -15 5 -4 16.70 6.31 5 -3 -11 12.63 1.79 -5 -3 11 11.77 2.70 5 -3 -11 11.46 2.01 5 3 -11 15.06 4.19 -5 3 11 11.67 1.98 0 0 -12 33.01 3.35 0 0 12 33.30 3.44 -19 3 7 3.98 2.53 -19 -3 7 2.64 1.74 -19 -3 7 3.05 1.57 19 -3 -7 3.00 1.36 -19 3 7 3.45 1.71 -4 -6 7 85.48 6.24 4 -6 -7 92.56 11.84 -4 -6 7 91.43 6.77 4 -6 -7 84.81 5.92 4 6 -7 92.61 6.14 -4 6 7 90.28 6.80 24 0 1 1.54 2.39 -24 0 -1 1.06 1.36 -24 0 -1 1.36 1.83 -17 -5 -2 25.85 3.93 -17 5 -2 29.14 3.96 -17 5 -2 25.63 3.71 17 5 2 28.61 6.35 17 -5 2 25.71 3.08 -17 -5 -2 24.33 3.27 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219.03 11.28 -11 1 -10 202.72 11.88 11 -1 10 209.95 10.72 11 1 10 200.24 8.88 5 -7 3 29.22 6.26 5 -7 3 28.62 3.45 5 7 3 26.23 2.84 -5 -7 -3 29.87 2.86 -5 -7 -3 24.34 3.12 -5 7 -3 32.82 3.53 18 4 4 130.94 8.48 -18 4 -4 132.31 9.47 -18 4 -4 135.21 7.86 18 -4 4 141.28 8.64 -18 -4 -4 129.92 8.85 -1 -5 9 36.96 4.29 1 -5 -9 37.71 7.62 -1 -5 9 31.95 3.07 1 5 -9 36.15 7.23 1 -5 -9 31.36 5.97 -1 5 9 33.11 7.11 -14 6 3 100.59 7.56 -14 -6 3 93.40 6.29 -14 -6 3 92.97 6.40 14 6 -3 102.76 6.21 14 -6 -3 95.95 6.86 -14 6 3 96.12 6.73 -1 -3 -11 14.79 4.10 -1 3 -11 14.62 6.29 1 -3 11 14.42 5.31 2 -6 7 93.18 10.41 -2 -6 -7 104.35 8.72 2 -6 7 98.18 5.67 -2 6 -7 97.87 6.57 2 6 7 96.40 6.10 -2 -6 -7 96.36 5.10 -11 3 -9 20.99 6.94 11 -3 9 22.46 2.90 -11 -3 -9 22.99 3.88 -11 -3 -9 20.26 2.75 7 7 2 6.86 1.54 -7 7 -2 8.65 1.91 -7 -7 -2 7.24 1.87 7 -7 2 11.10 4.92 -7 -7 -2 6.44 3.54 7 -7 2 9.80 2.24 7 -3 -11 212.83 11.56 7 3 -11 202.84 10.18 -7 3 11 195.73 10.66 -7 -3 11 205.82 14.89 -7 3 11 196.91 11.67 -13 1 11 58.29 5.32 -13 -1 11 56.17 4.42 -13 1 11 53.21 7.03 -13 -1 11 55.68 6.88 -7 -7 3 9.32 4.23 7 7 -3 9.88 4.53 -7 7 3 9.18 4.84 7 -7 -3 7.44 2.73 -7 -7 3 6.16 1.90 7 -7 -3 8.77 2.24 6 6 -7 1.09 1.33 -6 -6 7 0.56 0.66 6 -6 -7 0.26 1.82 -6 -6 7 -0.46 1.27 6 -6 -7 0.79 1.40 -6 6 7 0.03 0.91 -10 -2 -10 0.88 1.61 10 -2 10 0.37 1.39 -10 2 -10 0.83 1.34 -10 -2 -10 0.22 1.28 5 -5 -9 85.95 8.11 -5 -5 9 78.56 5.19 -5 5 9 78.53 5.84 5 5 -9 82.50 6.60 5 -5 -9 81.25 5.36 -5 -5 9 85.75 8.19 -12 -6 5 6.32 2.44 -12 -6 5 5.34 2.15 -12 6 5 6.21 1.96 -12 6 5 7.65 3.15 12 6 -5 6.37 3.35 12 -6 -5 4.80 2.04 -8 0 -11 0.64 1.46 8 0 11 0.43 0.91 -10 6 6 74.62 6.20 -10 -6 6 72.39 6.22 -10 -6 6 70.88 5.67 10 -6 -6 71.01 6.10 -10 6 6 70.86 5.27 10 6 -6 74.27 7.75 8 -4 9 38.68 4.06 -8 -4 -9 34.71 7.25 8 4 9 34.94 8.35 -8 4 -9 32.43 3.87 -8 0 12 2.46 1.34 8 0 -12 3.24 1.11 -8 0 12 3.74 1.83 -22 0 7 1.95 2.37 -22 0 7 0.02 1.05 -8 -4 10 516.09 21.57 -8 -4 10 557.69 25.16 -8 4 10 487.56 24.22 8 -4 -10 519.55 22.64 8 4 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5.89 2.14 -12 -4 12 5.50 2.56 -12 4 12 4.70 3.17 -12 4 12 3.25 2.36 28 -2 -4 4.22 2.41 -28 2 4 5.05 2.20 -28 -2 4 2.90 2.05 28 2 -4 4.87 2.31 -14 6 -7 47.18 5.08 -14 6 -7 64.65 7.12 14 6 7 58.47 9.27 -14 -6 -7 54.55 11.04 14 -6 7 57.39 5.81 4 6 10 57.09 8.91 -4 -6 -10 54.91 5.46 -4 6 -10 56.03 9.75 4 -6 10 56.44 5.93 13 -3 11 91.08 7.62 -13 3 -11 87.11 7.79 -13 -3 -11 96.05 8.23 -13 -3 -11 93.06 7.61 -4 2 14 45.29 5.20 4 2 -14 45.02 4.63 -4 -2 14 48.95 5.69 4 -2 -14 45.45 4.74 22 0 8 26.47 5.59 -22 0 -8 28.36 3.22 -22 0 -8 28.24 12.09 -16 -4 11 19.24 3.96 16 -4 -11 21.19 3.59 -16 4 11 15.89 8.23 -16 -4 11 17.70 2.60 9 -7 -8 0.16 1.51 9 -7 -8 0.40 1.94 -9 7 8 0.74 1.93 9 7 -8 0.77 1.69 -9 -7 8 0.23 2.46 -9 -7 8 2.08 2.30 -10 8 4 83.87 7.31 -10 -8 4 76.72 6.78 -10 -8 4 70.40 7.19 10 -8 -4 85.95 7.53 10 8 -4 86.53 7.33 19 5 6 17.87 6.07 -19 5 -6 16.75 5.30 -19 5 -6 16.53 3.96 -19 -5 -6 17.25 9.55 19 -5 6 18.10 6.13 -27 3 4 23.76 7.17 -27 -3 4 23.92 3.45 -27 -3 4 23.93 3.58 27 -3 -4 29.45 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34.03 11.54 23 -3 6 33.00 12.95 29 -1 -3 1.06 1.98 -29 -1 3 0.41 1.83 -29 1 3 1.18 2.10 29 1 -3 1.48 2.31 12 -6 8 23.87 3.39 -12 -6 -8 24.38 6.80 -12 6 -8 28.19 6.09 12 6 8 25.06 8.28 26 0 5 0.20 1.24 -26 0 -5 0.37 1.27 -26 0 -5 -0.20 1.52 -16 0 13 0.38 1.03 -16 0 13 -0.13 1.91 -27 1 7 7.83 2.51 -27 -1 7 8.95 3.09 27 -1 -7 7.12 2.27 6 -8 5 79.87 7.01 6 -8 5 82.12 7.33 6 8 5 74.10 6.37 -6 8 -5 76.37 6.82 -6 -8 -5 80.94 7.66 -20 -4 -7 16.90 5.72 20 -4 7 16.00 3.29 -20 4 -7 18.15 9.76 -20 -4 -7 14.60 5.88 -20 4 -7 14.94 2.66 -28 -2 -1 72.37 6.30 28 2 1 74.20 6.14 -28 2 -1 69.07 7.14 -28 2 -1 75.57 7.48 -28 -2 -1 69.09 6.67 28 -2 1 78.51 6.79 12 8 1 223.31 15.43 -12 8 -1 224.78 15.68 -12 8 -1 196.28 15.74 -12 -8 -1 194.81 15.05 12 -8 1 218.97 15.90 -9 -1 -13 42.85 5.03 -9 1 -13 44.69 10.96 9 -1 13 44.78 4.87 -26 -4 3 9.60 3.21 -26 -4 3 9.97 3.93 26 -4 -3 11.92 4.45 -26 4 3 10.97 4.70 -26 4 3 10.02 2.77 28 0 -6 20.37 3.38 -28 0 6 21.65 3.73 -3 -1 -14 16.70 2.60 3 -1 14 18.69 2.82 3 1 14 18.44 2.26 -3 1 -14 20.84 3.38 -19 1 12 1.37 1.63 -19 1 12 0.84 1.94 -19 -1 12 1.97 1.72 -19 -1 12 1.28 2.10 0 -2 -14 1.63 1.17 0 2 14 1.44 1.50 0 2 -14 1.48 1.53 0 -2 14 1.74 1.61 26 4 0 13.58 1.99 -26 4 0 13.29 4.02 -26 -4 0 11.90 2.28 -26 4 0 15.60 3.76 -26 -4 0 13.52 4.23 26 -4 0 16.38 3.91 10 -6 -10 6.78 5.22 -10 6 10 8.11 5.23 -10 6 10 7.19 4.29 10 6 -10 7.81 1.99 -10 -6 10 8.29 2.05 -10 -6 10 9.95 3.47 -18 2 12 0.63 0.87 -18 -2 12 0.90 1.78 -18 -2 12 0.71 0.82 18 -2 -12 1.73 3.03 -19 3 11 31.59 8.30 19 -3 -11 34.12 4.13 -19 -3 11 30.07 13.12 -19 -3 11 36.86 4.30 2 -8 6 31.11 3.46 2 -8 6 33.72 5.71 2 8 6 33.42 9.78 -2 8 -6 31.73 3.74 -2 -8 -6 31.53 3.98 -17 -7 4 198.78 13.30 -17 -7 4 217.32 17.14 17 7 -4 207.40 13.91 17 -7 -4 229.96 16.13 -17 7 4 219.74 15.64 -17 7 4 213.41 16.65 -5 -3 -13 30.85 4.81 5 -3 13 32.59 4.53 -5 3 -13 30.22 3.63 4 0 14 122.79 8.72 -4 0 -14 121.23 9.30 18 -6 -7 0.78 1.99 -18 -6 7 2.85 2.47 -18 6 7 1.61 1.83 18 6 -7 1.22 0.90 -18 -6 7 2.53 2.33 -18 6 7 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29 -7 -8 11.22 4.35 -29 -7 8 10.16 4.04 -29 7 8 6.46 4.93 13 11 -4 1.86 2.63 -13 11 4 2.74 3.55 13 -11 -4 2.38 2.15 13 -11 -4 2.59 3.32 -13 -11 4 3.26 2.39 -5 -11 7 1.52 2.25 -5 11 7 0.46 1.61 5 -11 -7 3.14 3.85 5 11 -7 3.49 3.28 -20 -8 -9 0.05 1.34 20 8 9 -0.06 1.40 -20 8 -9 1.12 1.36 20 -8 9 1.39 2.31 -39 -1 1 0.32 1.52 -39 1 1 0.09 1.55 39 1 -1 -0.02 1.12 39 -1 -1 1.82 2.49 -11 -11 -4 5.95 4.30 11 11 4 3.87 2.99 -11 11 -4 3.40 4.21 11 -11 4 3.46 2.67 11 -11 4 2.85 2.69 -23 -9 -4 2.33 2.15 23 -9 4 4.35 4.82 -23 9 -4 2.88 2.60 23 9 4 2.63 2.24 -15 -3 18 1.60 1.79 -26 0 16 1.06 1.96 26 -6 9 3.13 2.70 -26 -6 -9 1.57 2.67 -26 -6 -9 -0.01 1.72 -26 6 -9 1.50 1.35 -25 -9 -1 18.54 11.92 -25 9 -1 21.32 4.38 25 -9 1 25.46 5.50 -25 9 -1 21.79 8.46 -35 5 -1 -0.02 1.57 -35 -5 -1 0.60 1.77 35 -5 1 0.60 1.88 -20 10 -2 15.18 3.92 -20 -10 -2 11.68 6.83 20 -10 2 15.82 8.63 20 10 2 10.63 8.15 -5 7 -15 3.01 5.20 5 7 15 4.10 3.67 5 -7 15 3.34 2.40 -18 8 -10 1.35 2.11 18 -8 10 1.26 2.95 -18 -8 -10 2.61 2.20 18 8 10 1.82 2.19 -34 -4 -5 1.69 2.86 -34 -4 -5 0.55 0.82 34 -4 5 0.50 2.55 -34 4 -5 0.73 1.55 -39 1 4 3.15 2.41 -39 -1 4 3.56 3.39 39 -1 -4 1.86 2.18 39 1 -4 2.24 2.36 -25 7 -8 0.69 1.88 -25 -7 -8 1.24 2.43 -25 -7 -8 1.02 1.62 25 -7 8 0.81 2.02 -38 2 6 2.36 2.58 -38 -2 6 0.48 2.19 38 -2 -6 1.20 1.79 38 2 -6 0.32 1.44 -28 -8 -2 31.40 6.33 28 8 2 26.98 8.75 28 -8 2 33.35 6.50 -28 8 -2 30.61 6.31 37 -3 2 4.60 6.07 -37 -3 -2 10.14 3.97 -20 2 -15 2.54 2.98 -20 -2 -15 1.51 2.15 -11 -9 12 1.31 2.34 11 -9 -12 0.61 1.62 -11 9 12 1.12 1.60 -37 -1 -4 1.32 1.39 -37 1 -4 1.48 1.34 -37 -1 -4 1.96 2.23 -37 1 -4 0.50 0.97 -20 4 -14 42.97 8.18 -20 -4 -14 49.97 8.26 13 9 10 6.92 3.26 -13 -9 -10 4.18 2.23 13 -9 10 7.01 4.14 -34 -2 -7 0.18 1.24 -34 2 -7 0.82 1.32 -34 -2 -7 1.38 1.56 -22 6 14 1.41 2.00 -22 -6 14 0.62 1.49 22 -6 -14 1.57 2.18 -36 -4 -2 7.85 2.97 36 -4 2 9.37 3.73 5 -9 12 3.68 3.38 -5 -9 -12 3.03 2.29 -5 9 -12 1.94 2.63 5 9 12 2.58 4.09 -18 0 -16 4.66 2.91 -25 5 14 0.43 0.94 -25 -5 14 0.96 1.14 25 -5 -14 0.47 1.58 14 -6 -16 2.31 2.66 -14 -6 16 5.02 2.76 -10 0 -18 3.72 2.66 -23 -9 7 2.03 2.08 -23 -9 7 1.93 2.38 -23 9 7 3.60 3.22 -36 0 10 0.67 2.00 36 0 -10 0.90 2.80 -13 -7 15 10.22 4.28 13 -7 -15 7.39 4.01 -26 8 8 2.03 2.47 -26 -8 8 1.65 1.57 -26 -8 8 2.50 2.69 22 -2 -17 -0.03 1.58 -22 -2 17 1.61 2.53 7 -11 6 10.56 3.70 7 11 6 6.99 5.66 -7 11 -6 8.48 5.17 -7 -11 -6 6.27 3.61 10 -8 -14 4.75 7.08 -10 -8 14 6.68 9.14 -6 6 -16 4.80 4.74 -6 -6 -16 3.74 4.57 6 -6 16 6.67 3.96 29 -5 -12 1.44 2.49 -29 -5 12 1.32 1.47 -29 5 12 1.41 1.55 -29 -5 12 0.93 1.84 -21 -7 13 2.16 2.37 -21 7 13 2.06 1.57 5 -5 17 5.34 3.04 -5 -5 -17 8.66 4.17 -5 5 -17 6.07 4.10 -18 6 -13 2.26 2.54 -18 -6 -13 2.90 3.72 18 -6 13 1.46 1.65 -34 6 2 2.78 3.32 -34 -6 2 1.74 2.25 -2 -4 -18 0.85 1.49 0 -2 19 5.49 2.19 14 10 7 0.97 1.57 -14 -10 -7 0.03 1.80 14 -10 7 0.66 1.74 4 -10 10 0.99 2.74 4 10 10 1.88 2.08 -4 -10 -10 1.75 2.29 22 8 8 4.81 5.50 22 -8 8 4.77 3.16 -22 -8 -8 4.29 2.27 -19 -3 -15 9.87 3.84 -19 3 -15 5.29 8.18 21 -9 6 23.48 5.43 -21 -9 -6 18.90 5.13 21 9 6 15.18 12.30 3 11 7 1.65 1.79 -3 -11 -7 3.95 3.45 -3 11 -7 1.50 2.03 3 -11 7 4.47 3.36 -30 -6 -6 2.12 2.44 30 -6 6 4.47 3.39 -30 -6 -6 3.37 2.54 -30 6 -6 4.66 3.05 -15 -11 1 0.48 1.77 -15 11 1 0.43 1.86 15 11 -1 0.28 1.56 -19 5 16 2.00 2.21 -19 -5 16 1.90 2.62 -23 -1 17 4.39 3.38 -18 -4 17 0.52 1.58 18 -4 -17 0.77 1.75 -34 -6 3 3.08 2.72 -34 6 3 2.13 2.88 0 0 0 0.00 0.00 _computing_structure_solution 'SHELXT2018 (Sheldrick, 2015a)' ; _shelx_hkl_checksum 13495 _shelx_res_file ; TITL shelx_trans_a.res in C2/c shelx_trans.res created by SHELXL-2018/3 at 15:27:06 on 20-Oct-2020 REM Old TITL AR-51A REM SHELXT solution in C2/c: R1 0.259, Rweak 0.306, Alpha 0.041 REM 0.483 for 268 systematic absences, Orientation as input REM Formula found by SHELXT: C25 F1 O5 CELL 0.71075 30.3993 9.1762 14.9943 90 97.204 90 ZERR 8 0.0103 0.003 0.0049 0 0.004 0 LATT 7 SYMM -X,+Y,0.5-Z SFAC C H F O UNIT 192 112 48 32 L.S. 30 PLAN 5 TEMP -79.75 CONF BOND list 4 MORE -1 BOND $H fmap 2 53 acta REM REM REM WGHT 0.068900 FVAR 0.32840 O1 4 -0.421501 -0.244012 -0.298596 11.00000 0.04067 0.03720 = 0.05590 -0.00272 -0.00662 -0.00025 F5 3 -0.290142 -0.266962 -0.757968 11.00000 0.08930 0.07644 = 0.04998 -0.00393 -0.00087 0.01047 O3 4 -0.347759 -0.146829 -0.378572 11.00000 0.04449 0.05642 = 0.05126 -0.00668 -0.00038 -0.00977 O4 4 -0.282295 -0.028979 -0.361967 11.00000 0.04625 0.06857 = 0.06233 -0.01229 -0.00487 -0.01253 F4 3 -0.234414 -0.070777 -0.670275 11.00000 0.07964 0.09592 = 0.07303 -0.00081 0.02247 -0.01770 F6 3 -0.356909 -0.379076 -0.678858 11.00000 0.09324 0.09449 = 0.07306 -0.02870 -0.00509 -0.03329 O2 4 -0.484164 -0.140701 -0.364805 11.00000 0.05581 0.04654 = 0.12625 0.00051 -0.02821 0.00730 F1 3 -0.578258 -0.570512 -0.467554 11.00000 0.08664 0.14460 = 0.08366 -0.01499 0.00020 -0.07052 F3 3 -0.450070 -0.774370 -0.312621 11.00000 0.15481 0.04236 = 0.12436 0.01359 0.03573 0.00341 F2 3 -0.531101 -0.806125 -0.407464 11.00000 0.17726 0.07442 = 0.11911 -0.02332 0.04608 -0.07410 C19 1 -0.307128 -0.141806 -0.501933 11.00000 0.03969 0.04215 = 0.05148 -0.00043 -0.00710 0.00351 C18 1 -0.310379 -0.098022 -0.407605 11.00000 0.04012 0.04506 = 0.05535 -0.00134 -0.00317 -0.00080 C12 1 -0.479529 -0.398684 -0.356245 11.00000 0.04855 0.04546 = 0.03764 -0.00294 0.00607 -0.00677 C24 1 -0.335822 -0.242598 -0.546983 11.00000 0.04606 0.05479 = 0.06035 -0.00282 -0.00370 -0.00699 AFIX 43 H24 2 -0.359297 -0.283633 -0.518978 11.00000 -1.20000 AFIX 0 C5 1 -0.381708 -0.140367 -0.112680 11.00000 0.04983 0.04916 = 0.05548 -0.01399 -0.00090 -0.00473 C11 1 -0.462750 -0.247142 -0.341075 11.00000 0.04018 0.04336 = 0.05226 -0.00299 -0.00323 0.00182 C3 1 -0.331773 -0.231098 -0.224332 11.00000 0.04203 0.06732 = 0.05616 -0.00630 -0.00230 0.00745 AFIX 23 H3A 2 -0.340438 -0.327858 -0.249968 11.00000 -1.20000 H3B 2 -0.299146 -0.222529 -0.221040 11.00000 -1.20000 AFIX 0 C20 1 -0.272977 -0.082397 -0.543660 11.00000 0.04453 0.04660 = 0.05700 -0.00024 -0.00329 -0.00086 AFIX 43 H20 2 -0.253370 -0.013052 -0.513025 11.00000 -1.20000 AFIX 0 C2 1 -0.353276 -0.113846 -0.285857 11.00000 0.04404 0.05234 = 0.05156 -0.00941 -0.00067 -0.00625 AFIX 13 H2 2 -0.338585 -0.018539 -0.268980 11.00000 -1.20000 AFIX 0 C4 1 -0.344862 -0.221029 -0.130562 11.00000 0.04839 0.05748 = 0.05183 -0.01090 -0.00460 -0.00012 C6 1 -0.409109 -0.054032 -0.185507 11.00000 0.04660 0.04452 = 0.06760 -0.01326 0.00226 0.00017 AFIX 23 H6A 2 -0.401557 0.050513 -0.177655 11.00000 -1.20000 H6B 2 -0.440867 -0.065419 -0.178400 11.00000 -1.20000 AFIX 0 C23 1 -0.329597 -0.281810 -0.632848 11.00000 0.05632 0.05308 = 0.05551 -0.00822 -0.01125 -0.00343 C13 1 -0.521829 -0.414644 -0.403171 11.00000 0.05188 0.06559 = 0.04386 -0.00153 0.00352 -0.01451 AFIX 43 H13 2 -0.538970 -0.331635 -0.423176 11.00000 -1.20000 AFIX 0 C22 1 -0.295749 -0.224998 -0.674708 11.00000 0.05941 0.05277 = 0.04543 0.00045 -0.00576 0.01318 C1 1 -0.402154 -0.099924 -0.279586 11.00000 0.04378 0.03744 = 0.05903 -0.00417 -0.00264 -0.00222 AFIX 13 H1 2 -0.415907 -0.027404 -0.324470 11.00000 -1.20000 AFIX 0 C17 1 -0.454769 -0.519074 -0.325898 11.00000 0.06375 0.04312 = 0.04950 -0.00020 0.01251 -0.00255 AFIX 43 H17 2 -0.425934 -0.508165 -0.293956 11.00000 -1.20000 AFIX 0 C10 1 -0.392519 -0.137884 -0.024922 11.00000 0.06568 0.06518 = 0.06050 -0.02098 0.00805 -0.00417 AFIX 43 H10 2 -0.417454 -0.083226 -0.011767 11.00000 -1.20000 AFIX 0 C21 1 -0.267810 -0.124588 -0.629264 11.00000 0.04891 0.05374 = 0.05708 0.00678 0.00184 0.00363 C14 1 -0.538105 -0.551648 -0.419778 11.00000 0.07018 0.08760 = 0.04980 -0.00932 0.01177 -0.04111 C7 1 -0.320212 -0.295904 -0.061090 11.00000 0.06854 0.07905 = 0.05733 -0.00894 -0.00858 0.01620 AFIX 43 H7 2 -0.295142 -0.350722 -0.073316 11.00000 -1.20000 AFIX 0 C9 1 -0.367604 -0.213400 0.042775 11.00000 0.09864 0.07688 = 0.05088 -0.01486 0.00730 -0.00698 AFIX 43 H9 2 -0.375514 -0.210948 0.102072 11.00000 -1.20000 AFIX 0 C16 1 -0.472854 -0.655022 -0.343026 11.00000 0.10364 0.04090 = 0.06504 0.00382 0.02932 -0.00604 C15 1 -0.514324 -0.672638 -0.389974 11.00000 0.11030 0.05878 = 0.06319 -0.01323 0.03075 -0.04383 C8 1 -0.331189 -0.292651 0.024885 11.00000 0.09737 0.08456 = 0.05195 -0.00636 -0.00775 0.01370 AFIX 43 H8 2 -0.313866 -0.344500 0.071637 11.00000 -1.20000 AFIX 0 HKLF 4 REM shelx_trans_a.res in C2/c REM wR2 = 0.1204, GooF = S = 1.006, Restrained GooF = 1.006 for all data REM R1 = 0.0410 for 3317 Fo > 4sig(Fo) and 0.0572 for all 4718 data REM 307 parameters refined using 0 restraints END WGHT 0.0689 0.0000 REM Highest difference peak 0.196, deepest hole -0.278, 1-sigma level 0.034 Q1 1 -0.2792 -0.1963 -0.6376 11.00000 0.05 0.16 Q2 1 -0.5187 -0.6270 -0.4087 11.00000 0.05 0.15 Q3 1 -0.3006 -0.1742 -0.5005 11.00000 0.05 0.14 Q4 1 -0.4813 -0.3666 -0.3440 11.00000 0.05 0.14 Q5 1 -0.4947 -0.4070 -0.3591 11.00000 0.05 0.14 ; _shelx_res_checksum 55265 loop_ _space_group_symop_operation_xyz 'x, y, z' '-x, y, -z+1/2' 'x+1/2, y+1/2, z' '-x+1/2, y+1/2, -z+1/2' '-x, -y, -z' 'x, -y, z-1/2' '-x+1/2, -y+1/2, -z' 'x+1/2, -y+1/2, z-1/2' loop_ _atom_site_type_symbol _atom_site_label _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_U_iso_or_equiv _atom_site_adp_type _atom_site_calc_flag _atom_site_occupancy _atom_site_disorder_assembly _atom_site_disorder_group O O1 -0.42150(3) -0.24401(9) -0.29860(6) 0.0457(2) Uani d 1 . . F F5 -0.29014(3) -0.26696(10) -0.75797(6) 0.0727(3) Uani d 1 . . O O3 -0.34776(3) -0.14683(10) -0.37857(6) 0.0513(2) Uani d 1 . . O O4 -0.28229(3) -0.02898(12) -0.36197(7) 0.0600(3) Uani d 1 . . F F4 -0.23441(3) -0.07078(12) -0.67027(6) 0.0818(3) Uani d 1 . . F F6 -0.35691(3) -0.37908(12) -0.67886(6) 0.0882(3) Uani d 1 . . O O2 -0.48416(3) -0.14070(12) -0.36481(9) 0.0796(4) Uani d 1 . . F F1 -0.57826(4) -0.57051(14) -0.46755(7) 0.1059(4) Uani d 1 . . F F3 -0.45007(4) -0.77437(11) -0.31262(8) 0.1056(4) Uani d 1 . . F F2 -0.53110(5) -0.80613(12) -0.40746(8) 0.1213(5) Uani d 1 . . C C19 -0.30713(4) -0.14181(14) -0.50193(9) 0.0455(3) Uani d 1 . . C C18 -0.31038(4) -0.09802(15) -0.40761(9) 0.0476(3) Uani d 1 . . C C12 -0.47953(4) -0.39868(14) -0.35625(8) 0.0438(3) Uani d 1 . . C C24 -0.33582(5) -0.24260(15) -0.54698(10) 0.0546(4) Uani d 1 . . H H24 -0.359297 -0.283633 -0.518978 0.066 Uiso calc 1 . . C C5 -0.38171(4) -0.14037(15) -0.11268(9) 0.0521(3) Uani d 1 . . C C11 -0.46275(4) -0.24714(14) -0.34107(9) 0.0460(3) Uani d 1 . . C C3 -0.33177(4) -0.23110(17) -0.22433(9) 0.0559(4) Uani d 1 . . H H3A -0.340438 -0.327858 -0.249968 0.067 Uiso calc 1 . . H H3B -0.299146 -0.222529 -0.221040 0.067 Uiso calc 1 . . C C20 -0.27298(4) -0.08240(15) -0.54366(9) 0.0502(3) Uani d 1 . . H H20 -0.253370 -0.013052 -0.513025 0.060 Uiso calc 1 . . C C2 -0.35328(4) -0.11385(15) -0.28586(9) 0.0499(3) Uani d 1 . . H H2 -0.338585 -0.018539 -0.268980 0.060 Uiso calc 1 . . C C4 -0.34486(4) -0.22103(16) -0.13056(9) 0.0535(4) Uani d 1 . . C C6 -0.40911(4) -0.05403(15) -0.18551(10) 0.0533(4) Uani d 1 . . H H6A -0.401557 0.050513 -0.177655 0.064 Uiso calc 1 . . H H6B -0.440867 -0.065419 -0.178400 0.064 Uiso calc 1 . . C C23 -0.32960(5) -0.28181(16) -0.63285(10) 0.0565(4) Uani d 1 . . C C13 -0.52183(4) -0.41464(17) -0.40317(8) 0.0540(4) Uani d 1 . . H H13 -0.538970 -0.331635 -0.423176 0.065 Uiso calc 1 . . C C22 -0.29575(5) -0.22500(15) -0.67471(9) 0.0536(4) Uani d 1 . . C C1 -0.40215(4) -0.09992(14) -0.27959(9) 0.0475(3) Uani d 1 . . H H1 -0.415907 -0.027404 -0.324470 0.057 Uiso calc 1 . . C C17 -0.45477(5) -0.51907(15) -0.32590(9) 0.0517(3) Uani d 1 . . H H17 -0.425934 -0.508165 -0.293956 0.062 Uiso calc 1 . . C C10 -0.39252(5) -0.13788(18) -0.02492(10) 0.0638(4) Uani d 1 . . H H10 -0.417454 -0.083226 -0.011767 0.077 Uiso calc 1 . . C C21 -0.26781(4) -0.12459(16) -0.62926(10) 0.0537(4) Uani d 1 . . C C14 -0.53810(6) -0.5516(2) -0.41978(10) 0.0688(5) Uani d 1 . . C C7 -0.32021(6) -0.29590(19) -0.06109(11) 0.0697(5) Uani d 1 . . H H7 -0.295142 -0.350722 -0.073316 0.084 Uiso calc 1 . . C C9 -0.36760(7) -0.21340(19) 0.04277(11) 0.0756(5) Uani d 1 . . H H9 -0.375514 -0.210948 0.102072 0.091 Uiso calc 1 . . C C16 -0.47285(7) -0.65502(16) -0.34303(11) 0.0683(5) Uani d 1 . . C C15 -0.51432(7) -0.67264(19) -0.38997(11) 0.0757(5) Uani d 1 . . C C8 -0.33119(7) -0.2927(2) 0.02488(12) 0.0794(5) Uani d 1 . . H H8 -0.313866 -0.344500 0.071637 0.095 Uiso calc 1 . . loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_12 _atom_site_aniso_U_13 _atom_site_aniso_U_23 O1 0.0407(5) 0.0372(5) 0.0559(6) -0.0003(4) -0.0066(4) -0.0027(4) F5 0.0893(7) 0.0764(6) 0.0500(5) 0.0105(5) -0.0009(5) -0.0039(4) O3 0.0445(5) 0.0564(6) 0.0513(6) -0.0098(4) -0.0004(4) -0.0067(4) O4 0.0462(5) 0.0686(7) 0.0623(6) -0.0125(5) -0.0049(5) -0.0123(5) F4 0.0796(7) 0.0959(8) 0.0730(6) -0.0177(5) 0.0225(5) -0.0008(5) F6 0.0932(7) 0.0945(7) 0.0731(6) -0.0333(6) -0.0051(5) -0.0287(5) O2 0.0558(6) 0.0465(6) 0.1262(10) 0.0073(5) -0.0282(6) 0.0005(6) F1 0.0866(7) 0.1446(11) 0.0837(7) -0.0705(7) 0.0002(6) -0.0150(7) F3 0.1548(11) 0.0424(5) 0.1244(9) 0.0034(6) 0.0357(8) 0.0136(5) F2 0.1773(13) 0.0744(7) 0.1191(9) -0.0741(8) 0.0461(9) -0.0233(7) C19 0.0397(7) 0.0421(7) 0.0515(8) 0.0035(5) -0.0071(6) -0.0004(6) C18 0.0401(7) 0.0451(7) 0.0554(8) -0.0008(6) -0.0032(6) -0.0013(6) C12 0.0486(7) 0.0455(7) 0.0376(7) -0.0068(6) 0.0061(5) -0.0029(5) C24 0.0461(7) 0.0548(8) 0.0603(9) -0.0070(6) -0.0037(6) -0.0028(7) C5 0.0498(8) 0.0492(8) 0.0555(9) -0.0047(6) -0.0009(6) -0.0140(6) C11 0.0402(7) 0.0434(7) 0.0523(8) 0.0018(5) -0.0032(6) -0.0030(6) C3 0.0420(7) 0.0673(9) 0.0562(9) 0.0075(7) -0.0023(6) -0.0063(7) C20 0.0445(7) 0.0466(7) 0.0570(9) -0.0009(6) -0.0033(6) -0.0002(6) C2 0.0440(7) 0.0523(8) 0.0516(8) -0.0062(6) -0.0007(6) -0.0094(6) C4 0.0484(8) 0.0575(8) 0.0518(8) -0.0001(6) -0.0046(6) -0.0109(6) C6 0.0466(7) 0.0445(7) 0.0676(9) 0.0002(6) 0.0023(7) -0.0133(6) C23 0.0563(8) 0.0531(8) 0.0555(9) -0.0034(7) -0.0112(7) -0.0082(7) C13 0.0519(8) 0.0656(9) 0.0439(8) -0.0145(7) 0.0035(6) -0.0015(7) C22 0.0594(9) 0.0528(8) 0.0454(8) 0.0132(7) -0.0058(7) 0.0005(6) C1 0.0438(7) 0.0374(7) 0.0590(8) -0.0022(5) -0.0026(6) -0.0042(6) C17 0.0637(8) 0.0431(7) 0.0495(8) -0.0026(6) 0.0125(7) -0.0002(6) C10 0.0657(9) 0.0652(10) 0.0605(10) -0.0042(8) 0.0080(8) -0.0210(8) C21 0.0489(8) 0.0537(8) 0.0571(9) 0.0036(6) 0.0018(7) 0.0068(7) C14 0.0702(10) 0.0876(13) 0.0498(9) -0.0411(9) 0.0118(8) -0.0093(8) C7 0.0685(10) 0.0790(11) 0.0573(10) 0.0162(9) -0.0086(8) -0.0089(8) C9 0.0986(13) 0.0769(12) 0.0509(9) -0.0070(10) 0.0073(9) -0.0149(8) C16 0.1036(13) 0.0409(8) 0.0650(10) -0.0060(8) 0.0293(9) 0.0038(7) C15 0.1103(15) 0.0588(10) 0.0632(10) -0.0438(10) 0.0307(10) -0.0132(8) C8 0.0974(13) 0.0846(12) 0.0519(10) 0.0137(11) -0.0077(9) -0.0064(9) loop_ _atom_type_symbol _atom_type_description _atom_type_scat_dispersion_real _atom_type_scat_dispersion_imag _atom_type_scat_source C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' loop_ _geom_angle_atom_site_label_1 _geom_angle_atom_site_label_2 _geom_angle_atom_site_label_3 _geom_angle_site_symmetry_1 _geom_angle_site_symmetry_3 _geom_angle _geom_angle_publ_flag C11 O1 C1 . . 116.37(10) ? C18 O3 C2 . . 116.38(9) ? C24 C19 C18 . . 122.08(13) ? C24 C19 C20 . . 120.14(13) ? C20 C19 C18 . . 117.74(12) ? O3 C18 C19 . . 112.23(11) ? O4 C18 O3 . . 123.99(12) ? O4 C18 C19 . . 123.77(12) ? C13 C12 C11 . . 116.87(12) ? C17 C12 C11 . . 122.32(12) ? C17 C12 C13 . . 120.82(13) ? C19 C24 H24 . . 120.7 ? C23 C24 C19 . . 118.64(13) ? C23 C24 H24 . . 120.7 ? C4 C5 C6 . . 121.44(13) ? C10 C5 C4 . . 118.62(13) ? C10 C5 C6 . . 119.92(13) ? O1 C11 C12 . . 112.13(11) ? O2 C11 O1 . . 124.43(12) ? O2 C11 C12 . . 123.44(12) ? H3A C3 H3B . . 107.9 ? C2 C3 H3A . . 109.1 ? C2 C3 H3B . . 109.1 ? C4 C3 H3A . . 109.1 ? C4 C3 H3B . . 109.1 ? C4 C3 C2 . . 112.34(11) ? C19 C20 H20 . . 120.3 ? C21 C20 C19 . . 119.45(13) ? C21 C20 H20 . . 120.3 ? O3 C2 C3 . . 110.04(11) ? O3 C2 H2 . . 108.8 ? O3 C2 C1 . . 108.10(10) ? C3 C2 H2 . . 108.8 ? C1 C2 C3 . . 112.14(12) ? C1 C2 H2 . . 108.8 ? C5 C4 C3 . . 121.48(12) ? C7 C4 C5 . . 119.30(14) ? C7 C4 C3 . . 119.21(13) ? C5 C6 H6A . . 108.9 ? C5 C6 H6B . . 108.9 ? C5 C6 C1 . . 113.52(11) ? H6A C6 H6B . . 107.7 ? C1 C6 H6A . . 108.9 ? C1 C6 H6B . . 108.9 ? F6 C23 C24 . . 120.33(13) ? F6 C23 C22 . . 117.77(13) ? C24 C23 C22 . . 121.90(13) ? C12 C13 H13 . . 120.7 ? C14 C13 C12 . . 118.69(15) ? C14 C13 H13 . . 120.7 ? F5 C22 C23 . . 120.51(13) ? F5 C22 C21 . . 120.83(14) ? C23 C22 C21 . . 118.66(13) ? O1 C1 C2 . . 106.70(10) ? O1 C1 C6 . . 109.52(11) ? O1 C1 H1 . . 110.3 ? C2 C1 C6 . . 109.65(10) ? C2 C1 H1 . . 110.3 ? C6 C1 H1 . . 110.3 ? C12 C17 H17 . . 120.8 ? C16 C17 C12 . . 118.40(14) ? C16 C17 H17 . . 120.8 ? C5 C10 H10 . . 119.5 ? C9 C10 C5 . . 120.97(15) ? C9 C10 H10 . . 119.5 ? F4 C21 C20 . . 120.46(13) ? F4 C21 C22 . . 118.31(13) ? C20 C21 C22 . . 121.21(14) ? F1 C14 C13 . . 120.00(18) ? F1 C14 C15 . . 118.41(15) ? C13 C14 C15 . . 121.59(15) ? C4 C7 H7 . . 119.2 ? C8 C7 C4 . . 121.53(16) ? C8 C7 H7 . . 119.2 ? C10 C9 H9 . . 119.9 ? C10 C9 C8 . . 120.23(16) ? C8 C9 H9 . . 119.9 ? F3 C16 C17 . . 119.93(17) ? F3 C16 C15 . . 118.58(15) ? C15 C16 C17 . . 121.48(16) ? F2 C15 C14 . . 120.33(18) ? F2 C15 C16 . . 120.66(19) ? C14 C15 C16 . . 119.00(14) ? C7 C8 C9 . . 119.35(16) ? C7 C8 H8 . . 120.3 ? C9 C8 H8 . . 120.3 ? loop_ _geom_bond_atom_site_label_1 _geom_bond_atom_site_label_2 _geom_bond_site_symmetry_2 _geom_bond_distance _geom_bond_publ_flag O1 C11 . 1.3336(16) ? O1 C1 . 1.4606(15) ? F5 C22 . 1.3376(16) ? O3 C18 . 1.3437(16) ? O3 C2 . 1.4529(16) ? O4 C18 . 1.2050(15) ? F4 C21 . 1.3451(17) ? F6 C23 . 1.3484(16) ? O2 C11 . 1.2026(16) ? F1 C14 . 1.3468(19) ? F3 C16 . 1.3445(19) ? F2 C15 . 1.3401(18) ? C19 C18 . 1.4855(19) ? C19 C24 . 1.3874(18) ? C19 C20 . 1.3890(19) ? C12 C11 . 1.4888(18) ? C12 C13 . 1.3940(17) ? C12 C17 . 1.3813(19) ? C24 H24 . 0.9500 ? C24 C23 . 1.373(2) ? C5 C4 . 1.3963(19) ? C5 C6 . 1.512(2) ? C5 C10 . 1.396(2) ? C3 H3A . 0.9900 ? C3 H3B . 0.9900 ? C3 C2 . 1.512(2) ? C3 C4 . 1.511(2) ? C20 H20 . 0.9500 ? C20 C21 . 1.368(2) ? C2 H2 . 1.0000 ? C2 C1 . 1.5060(18) ? C4 C7 . 1.387(2) ? C6 H6A . 0.9900 ? C6 H6B . 0.9900 ? C6 C1 . 1.512(2) ? C23 C22 . 1.373(2) ? C13 H13 . 0.9500 ? C13 C14 . 1.362(2) ? C22 C21 . 1.375(2) ? C1 H1 . 1.0000 ? C17 H17 . 0.9500 ? C17 C16 . 1.374(2) ? C10 H10 . 0.9500 ? C10 C9 . 1.375(2) ? C14 C15 . 1.369(3) ? C7 H7 . 0.9500 ? C7 C8 . 1.372(2) ? C9 H9 . 0.9500 ? C9 C8 . 1.379(3) ? C16 C15 . 1.374(3) ? C8 H8 . 0.9500 ? loop_ _geom_torsion_atom_site_label_1 _geom_torsion_atom_site_label_2 _geom_torsion_atom_site_label_3 _geom_torsion_atom_site_label_4 _geom_torsion_site_symmetry_1 _geom_torsion_site_symmetry_2 _geom_torsion_site_symmetry_3 _geom_torsion_site_symmetry_4 _geom_torsion _geom_torsion_publ_flag F5 C22 C21 F4 . . . . -0.7(2) ? F5 C22 C21 C20 . . . . -179.19(12) ? O3 C2 C1 O1 . . . . 65.84(13) ? O3 C2 C1 C6 . . . . -175.63(10) ? F6 C23 C22 F5 . . . . -0.7(2) ? F6 C23 C22 C21 . . . . 179.36(12) ? F1 C14 C15 F2 . . . . -0.7(2) ? F1 C14 C15 C16 . . . . 178.44(14) ? F3 C16 C15 F2 . . . . -2.1(2) ? F3 C16 C15 C14 . . . . 178.82(14) ? C19 C24 C23 F6 . . . . -179.77(12) ? C19 C24 C23 C22 . . . . 0.5(2) ? C19 C20 C21 F4 . . . . -178.61(12) ? C19 C20 C21 C22 . . . . -0.1(2) ? C18 O3 C2 C3 . . . . -87.56(14) ? C18 O3 C2 C1 . . . . 149.68(11) ? C18 C19 C24 C23 . . . . -177.43(12) ? C18 C19 C20 C21 . . . . 177.37(11) ? C12 C13 C14 F1 . . . . -177.78(12) ? C12 C13 C14 C15 . . . . 1.3(2) ? C12 C17 C16 F3 . . . . -178.45(13) ? C12 C17 C16 C15 . . . . 0.7(2) ? C24 C19 C18 O3 . . . . -10.62(18) ? C24 C19 C18 O4 . . . . 168.10(13) ? C24 C19 C20 C21 . . . . -0.3(2) ? C24 C23 C22 F5 . . . . 179.02(12) ? C24 C23 C22 C21 . . . . -0.9(2) ? C5 C4 C7 C8 . . . . 0.0(2) ? C5 C6 C1 O1 . . . . 70.05(14) ? C5 C6 C1 C2 . . . . -46.71(15) ? C5 C10 C9 C8 . . . . 0.3(3) ? C11 O1 C1 C2 . . . . -146.63(11) ? C11 O1 C1 C6 . . . . 94.76(13) ? C11 C12 C13 C14 . . . . 178.91(12) ? C11 C12 C17 C16 . . . . -179.91(13) ? C3 C2 C1 O1 . . . . -55.64(14) ? C3 C2 C1 C6 . . . . 62.89(15) ? C3 C4 C7 C8 . . . . -178.74(16) ? C20 C19 C18 O3 . . . . 171.79(11) ? C20 C19 C18 O4 . . . . -9.5(2) ? C20 C19 C24 C23 . . . . 0.1(2) ? C2 O3 C18 O4 . . . . -0.77(19) ? C2 O3 C18 C19 . . . . 177.94(10) ? C2 C3 C4 C5 . . . . 16.95(19) ? C2 C3 C4 C7 . . . . -164.32(13) ? C4 C5 C6 C1 . . . . 17.94(18) ? C4 C5 C10 C9 . . . . -0.2(2) ? C4 C3 C2 O3 . . . . -167.43(10) ? C4 C3 C2 C1 . . . . -47.08(15) ? C4 C7 C8 C9 . . . . 0.1(3) ? C6 C5 C4 C3 . . . . -2.7(2) ? C6 C5 C4 C7 . . . . 178.61(13) ? C6 C5 C10 C9 . . . . -178.81(14) ? C23 C22 C21 F4 . . . . 179.20(12) ? C23 C22 C21 C20 . . . . 0.7(2) ? C13 C12 C11 O1 . . . . -177.72(11) ? C13 C12 C11 O2 . . . . 2.2(2) ? C13 C12 C17 C16 . . . . -0.04(19) ? C13 C14 C15 F2 . . . . -179.84(14) ? C13 C14 C15 C16 . . . . -0.7(2) ? C1 O1 C11 O2 . . . . 0.8(2) ? C1 O1 C11 C12 . . . . -179.33(10) ? C17 C12 C11 O1 . . . . 2.15(18) ? C17 C12 C11 O2 . . . . -177.98(14) ? C17 C12 C13 C14 . . . . -1.0(2) ? C17 C16 C15 F2 . . . . 178.78(14) ? C17 C16 C15 C14 . . . . -0.4(2) ? C10 C5 C4 C3 . . . . 178.74(13) ? C10 C5 C4 C7 . . . . 0.0(2) ? C10 C5 C6 C1 . . . . -163.47(12) ? C10 C9 C8 C7 . . . . -0.3(3) ? _cod_database_fobs_code 2022279